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By J. M. Beeckmans, S. G. Butcher, M. Goransson

"The counter-current fluidized cascade is a novel and potentially efficient pneumatic gravity separation device. Data are presented on over 150 runs of cleaning Alberta thermal coals, covering several size ranges. The coarser sizes of coal were processed in admixture with a fluidizing medium consisting of 0.5-by 0.1-mm hematite (or magnetite) and limestone particles. The partition curves for coal particles larger than about 3 mm, mixed with fluidizing medium, showed that the sharpness of separation achievable with the cascade approaches that of wet heavy medium processes, whereas with particles in the size range of 3 by 0.6 mm the sharpness of separation was comparable to that of a Baum jig. Useful cleaning was also achieved with particles smaller than 0.6 mm , Throughput rates of up to 11 tonnes per metre width of cascade per hour were achieved, with no indication of a deterioration in performance.IntroductionPneumatic coal beneficiation has steadily lost ground vis-a-vis hydraulic beneficiation during the past quarter century, primarily because of the sharper separations achievable with the latter methods. Nevertheless, there are certain inherent advantages of pneumatic separation methods which would give them an advantage in the market place were it possible to increase their efficiency to be technically competitive with those of hydraulic processes. These advantages are a dry product, resulting in a higher calorific value per ton, and avoidance of the problems associated with treatment and storage of process waste waters. Also, although it may be necessary to dry the raw coal prior to pneumatic processing, the dry rejects produced constitute an ideal fuel for a fluidized-bed combustor, which could provide heat both for drying the coal and for other purposes."

Jan 1, 1982

By D. H. Wilton, C. I. Godwin, A. J. Sinclair

"A computer-based drill core logging system used to examine computer-based drill core logging system used to examine copper mineralization hosted in volcaniclastic rocks at the Sustut deposit, in north-central British Columbia, has many advantages over conventional logging. A relatively simple format for recording geological information allows complex, but significant, geologic parameters to be recorded consistently, accurately and quickly. This allows graphical presentations and statistical interpretation of the data that lead to rapid and detailed analyses of the control and distribution of copper mineralization at the Sustut deposit.Ore mineralization is concentrated in lens-shaped bodies and is zoned from native copper cores through chalcocite, bornite and chalcopyrite to a margin containing pyrite. Chalcocite, the principal mineral, occurs mainly in volcaniclastic agglomerate characterized by a specific grain size, a narrow range of matrix and fragment proportions, and a specific sorting.IntroductionWe report here a case history of the practical application of a detailed computer-based drill core logging system applied to the Sustut copper deposit of Falconbridge Nickel Mines Ltd. The Sustut deposit, containing a few tens of millions of tons of ore grading slightly more than one per cent copper (Church, 1975), is in north-central British Columbia about 875 km north of Vancouver. The deposit is contained in volcaniclastic sedimentary rocks of the Upper Triassic Moosevale Formation, which is within the upper part of the Takla Group (Monger and Church, 1977) of basic volcanic and associated sedimentary rocks. Takla rocks occur along the eastern fringe of the Intermontane Belt in the Canadian Cordillera (Sutherland Brown et al., 1971). The deposit consists of concentrations of copper sulphides, native copper and pyrite within pods and lenses parallel to bedding in the host sedimentary rocks. These sheet-like deposits exhibit a mineral zoning from pyrite at the fringes successively through chalcopyrite, bornite and chalcocite to native copper at the core (Wilton, 1978; Wilton and Sinclair, 1979)."

Jan 1, 1980

By H. Sato, Y. Sato, T. Ooishi, K. Sakamoto

"Sumitomo Metal Mining Co., Ltd.(SMM)'s Niihama Nickel Refinery(NNR) produces high quality Nickel cathode, Cobaltcathode and other by-products using hydrometallurgical refining process called “MCLE”(Matte Chlorine Leach and Electro-Winning). In 2005,NNR started to use nickel and cobalt mixed sulfide (MS) produced by one of the SMM’s subsidiaries Coral Bay Nickel Corporation(CBNC)’s HPAL plant in Philippines, although its main and the only raw material until then was nickel matte. With start-up of the second HPAL plant at Taganito in 2013, NNR expanded its production capacity of nickel cathode from 41,000 to 65,000 tpa and finally achieved its target in 2015 by producing 65,980 tpa. SMM developed the technologies to improve poor reactivity of MS and installed new facilities to cope with increased Cobalt and Sulfur production at that time. This paper describes the technical approach to increase MS treatment with high efficiency.INTRODUCTIONThe Sumitomo Metal Mining Co., Ltd.(SMM)Niihama Nickel Refinery(NNR) produces Nickel cathode, Cobalt cathode and other by-products using Matte Chlorine Leach and Electro-Winning (MCLE) process technology. SMM uses nickel matte and nickel & cobalt mixed sulfide (MS) as raw materials for the MCLE process. Table 1 shows typical composition of these raw materials. Nickel matte had been only raw material until 2005, and with start-up of Coral Bay Nickel Corporation (CBNC) operation in the Republic of the Philippines, MS became major part of it. In 2009, when CBNC doubled its production capacity, NNR also expanded its plant capacity of electrolytic nickel from 36ktpa to 41ktpa, keeping an eye on the possibility of 65ktpa with oncoming SMM’s second HPAL in Philippines. Poor reactivity of MS was the prime concern at that time because our intention was to increase production with MS. Nickel extraction rate deteriorated with increasing usage ratio of MS in raw materials. To keep high nickel extraction rate under high ratio of MS, NNR developed a new leaching technology. Another concern arising from treatment of MS was Cobalt and Sulfur contents that are much more than those of nickel matte as shown in Table 1.NNR introduced new technology of solvent extraction process as to Co/Ni separation process in order to keep cost competitiveness instead of the conventional cobalt oxidation–neutralizing method. As to sulfur products, new sulfur productive facility was installed to improve the exposure to sulfur dust and the hot working conditions for workers. As a result of process development and installation of new facilities against the problem with MSusage,65 ktpa production was achieved in 2015."

Jan 1, 2017

By C. Liu

Corrosion behavior of the stir zone in a friction stir weld of dissimilar A12024/AZ31 alloys was investigated in the immersion test in distilled water (pH=6) for different times. Microstructures and the distribution of chemical elements were analyzed by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). Due to the difference in the corrosion potentials between A12024 and AZ31, the AZ31 alloy constituent in the stir zone was susceptible to the corrosion attack in the distilled water. The corrosion attack was found to occur in the narrow region of the AZ31 alloy adjoining the A12024 region, where there was a low ratio of anode-to-cathode surface area. The corrosion attack became more severe in the AZ31 alloy regions with increasing immersion time. The A12024 alloy region in the stir zone of the weld was protected by cathodic reactivity due to sacrificial anode AZ31 alloy.

Jan 1, 2007

By J. W. Thomson, H. J. Lloyd, R. J. Taylor

"THE HOLLINGER MINE has been producing gold and by-product silver almost continuously for forty-eight years. The value of current production is $10,000,000 annually from one million tons of ore. Its management •has, particularly over the past decade, increasingly . concerned itself with the problem of profitable operation in a time of steadily rising costs and a fixed price of gold. At one period in the life of the mine, before World War II, production resulted in yearly profit margins that were stable and relatively thick. In winning gold from a series of inconsistent vertical ore lenses, operating management was much better protected than it is today against a general rise in cost or dip in grade of ore. The tissue-like thinness of present-day margins demand more careful handling. A sharp rise in costs, if protracted, could easily rip the tissue to shreds and close down the business. The counter-measure of raising grade and gutting the mine would bring on the end perhaps more rapidly, without having contributed much to the recovery of our national re-sources, nor to community welfare. The alternative is to keep costs under control."

Jan 1, 1960

By J. E. Danoczi

ABSTRACT A diamond processing plant is being designed for the Star–Orion South diamond project in central Saskatchewan. Key to the plant is diamond liberation, which occurs in the comminution section and is the process of breaking up kimberlite rock as gently as possible to minimize diamond damage, particularly in larger, high-value diamonds. Kimberlite from the crater area of a volcanic pipe is generally softer than kimberlite from the diatreme zone. Softer kimberlite, comprising the majority of Star– Orion South deposits, can be readily broken up using abrasion and attrition by autogenous grinding mills, the preferred comminution method for minimizing diamond damage.

Jan 1, 2013

By W C. Shakespeare

The Ontario Committee on Taxation is making a comprehensive study of taxation in the Province of Ontario, and in this connection has received representations concerning mining taxation from a number of interested parties. Some of the more important recommendations on mining taxation are reviewed in this article. Introduction FOLLOWING the appointment of the Federal Royal Commission on Taxation, the Ontario Government, effective in November, 1962, appointed the Ontario Committee on Taxation to review taxes and revenues available to the Province of Ontario and its local governments, to co-operate with the Royal Commission on Taxation and with any other bodies of enquiry appointed by other provincial governments, and to make such recommendations as it sees fit to the Prime Minister of Ontario and the Executive Council. The members of the Committee are: MR. L. J. SMITH, F.C.A., Toronto, (Chairman) MR. ERIC HARDY, Toronto DR. R. CRAIG MCIVOR, F.R.S.C., Hamilton MR. CARL A. POLLOCK, Kitchener MR. R. BREDIN STAPELLS, Q.C., and Toronto. Like its Federal counterpart, the Royal Commission on Taxation, the Ontario Committee has held public hearings, has received written

Jan 1, 1965

By A. H. Lang

"The Cordilleran region of western Canada includes most of British Columbia and the Yukon and pares of Alberta and the Northwest Territories. The western part of this region was for about 50 years the principal mineral producing area of the Dominion. It lost this distinction in 1907 when production from the mines of the Canadian Shield took the lead, but it continues to provide about 15 percent of the total Canadian production. In 1945 the total mineral production of British Columbia and the Yukon was valued at $65,302,900, of which about 80 percent was derived from metals.This paper is intended to serve as an introduction co the more derailed Cordilleran papers. Part I includes a brief synopsis of the complex geology and diverse types of mineralization in the region and Parr II collates the main structural principles exemplified in the derailed papers, and draws some conclusions regarding the application of this information to prospecting."

Jan 1, 1954

By P. K. Kaiser, S. Maloney, S. Yazici

"This paper focusses on the strength or capacity of cable bolts and introduces a new perspective for cable bolt design by demonstrating that mining-induced stress changes may affect cables in a detrimental manner. The concept underlying a novel cable bolt pull-out resistanceor bond capacity model is described and its practical significance is demonstrated by application to a simple two dimensional scenario of a fall-of-ground.A number of practical implications emerging from the application of this model are discussed to provide guidance to ground control personnel jar improving cable bolt support systems in mining applications. These include cable layout optimization, use of cable pre-reinforcements, assessment of embedment length requirements, need for plated cables (or straps), use of bird-caged cables (or buttons), and grout quality issues.IntroductionDuring the last decade, cable bolting has become a standard support technique in mining for handling wide spans, reinforcing are passes, preventing or reducing dilution of ore in marginally stable stopes, and for many other rock support need s.In its infancy, many deficiencies in cable bolt supports resulted from improper installation techniques and, in particular, grout quality control problems and the use of empty breather tubes (Goris, 1990). The development of special grout pumps and fail proof placement procedures (Oliver, 1992; Bourchier and O'Flaherty, 1992) have eliminated many of these early problems. Nevertheless, there are still situations where cables seem to lose their capacity during mining, and in these cases the cables do not provide the expected and needed ground support. In some instances, cables perform extremely well, whereas in others the same support layout and quality of support installation seem to be insufficient, allowing falls-of-ground or progressive cavings to occur."

Jan 1, 1992

By E. Peters

Roasting processes are divided into several elementary mechanisms, any of which could be significant or pre-dominant in a particular roast. The elementary processes considered in-elude beat transfer, gas-solid inter-actions with accompanying mass transfer between the bed and furnace atmosphere, vapor phase transport processes in solid-solid interactions, and solid phase diffusion processes. Examples are chosen of processes in which one of these mechanisms pre-dominates and some recently obtained data is presented to support the existence and significance of these mechanisms. Proposals are also made for future research in these areas, and for utilizing the information in the improvement of roaster capacities’ OASTING of ores as a preparative treatment for smelting or leaching has been practiced for so long that its origin has been lost in antiquity, but little has been under-stood of its basic nature until fair-ly recent times. The nominal chemistry of roasting processes is now understood; that is, the initial chemical com-pounds present in the ores or con-

Jan 1, 1961

By D. A. Beck

The load-deformation response of discontinuous rock under static and dynamic loading conditions has been simulated using Explicit Finite Element models. The intent of the analysis was to investigate the effects of specimen size and confining stress on strength, dilation and comminution. The simulations allow the development of homogenised constitutive material properties for discontinuous rock masses using laboratory scale measurements and representative Discrete Fracture Networks (DFNs). A procedure for this is presented which includes a comparison of measured seismic response in a mine to the Dissipated Plastic Energy (DPE) that is released in the simulated rock masses. The models also show how confinement and scale affect the stress-strain and DPE response of the simulated rock specimens, reproducing a number of known rock phenomena that are often poorly captured in geotechnical modelling. A case study is presented showing a satisfactory match between the model-derived, homogenised material properties and values achieved by calibration of a mine-scale model where many thousands of seismic, displacement and damage measurements were available.

May 1, 2009

By E. Goodwin

"Maclaren Forest Products Inc.Lime is commonly used for the neutralization of acid, and the removal of heavy metals in mine waste waters. However, the precipitation of heavy metals as hydroxides must take place under conditions of controlled pH, to produce minimum concentrations of dissolved metals. An account is presented explaining the concepts applied to lime-treatment processes at Bell Mine during the period of a supernatant discharge to Babine Lake; October 18, 1982to January 25, 1983. IntroductionBell Mine of Maclaren Forest Products Inc., Babine Mining Division, an open-pit copper mine, is located on Newman Peninsula, Babine Lake approximately 65 kilometres northeast of the town of Smithers, British Columbia (Fig. 1).A depressed market for copper metal in 1982 forced a management decision to suspend operations at the mine for an indefinite period from October 3 I, 1982. For some time prior to the mine closing date, mine management was concerned about the increasing level of supernatant in the tailings pond , and its possible effects on the stability of the dam when cycloning of mill tailings ceased. Consideration of these potential hazards led to an application being filed with the Provincial Waste Management for a permit to discharge the excess water to Babine Lake. This large lake, an important link with several significant salmon spawning sites, is a major contributor to the British Columbia commercial fishing industry. Jurisdiction for the environmental affairs in the area is shared by the Department of Fisheries and Oceans, the Environmental Protection Service, and the Provincial Waste Management Branch. These agencies were directly concerned in the formulation of discharge permit following joint consultation, and exchange of information with the company on environmental concerns. An approval was finally granted to discharge approximately 1,000,000 cubic metres of supernatant from the tailings impoundment at Bell Mine into Hagan Arm, Babine Lake from October 18, 1982 with a daily discharge not to exceed 9000 cubic metres. Provisions were made that a particular discharge procedure be followed, and that the company would be responsible for setting up a sampling and monitoring program to safeguard the quality of the effluent."

Jan 1, 1986

By Andrew Bamber

A fast and objective spreadsheet-based model for the financial evaluation of innovative mining and processing strategies such as pre-concentration vs. a conventional base case is presented. The size and grade of the deposit must be chosen, from which a mining rate is selected. Expected operational data for the deposit as well as any mill testwork and results from the pre-concentration testwork are entered as input variables on the sheet, and cost and revenue impacts are calculated in the ?Output? sheet. A capital sum and operating costs for the initial mine and mill development as well as the pre-concentration facility are calculated. The net changes in capital and operating costs are calculated, and impacts on revenue through changes in metal recovery are also calculated. These outputs are used to calculate the overall impact on the cutoff grade and thus the size of the mineral reserve using a generic grade-tonnage model. The NPV and NPV profile of the two scenarios is calculated, with variations in basic parameters such as operating cost, capital requirements, metal price or grade as well as discount rate. Cost and revenue impacts are evaluated and compared to the baseline to establish a positive or negative impact overall. Different scenarios of grade, tonnage, mining rate, process performance, capital and operating cost structure can be explored using the model. Outcomes projected by the model for case studies conducted thus far have been calibrated against internal estimates by the sponsoring organizations and found to be accurate to within 30%, confirming the utility of the model in practice.

Oct 1, 2009

By F. E. Goodwin

Since the last CIM Zinc and Lead Conference ten years ago, significant technical and market forces have influenced how these metals are used, and the geographic distribution of their uses. Unprecedented price fluctuations have opened competitiveness issues, while the rapid growth of the Chinese market has created challenges both inside and outside China. Recent technical developments in battery energy storage, coatings, castings and chemical applications of lead and zinc will be reviewed together with the influence of these trends on end use markets.

Jan 1, 2008

By G. A. Bezuidenhout, J. Davis, S. M. Bradshaw, J. P. T. Kapusta, D. K. Chibwe

"This research work forms part of an assessment to complement the feasibility of implementing high pressure sonic injection into relatively small (2.25 m I.D by 3.66 m I.L) Peirce-Smith converters (PSC) used at Lonmin Plc. Work has been carried out to characterize the fluid dynamics of three-phase (air, matte and slag) fluid flow in these converters using Computational Fluid Dynamics (CFD) simulations. The investigation has been done to study the flow pattern of the three phase system at high air pressure injection achieving sonic velocity at the tuyere exit into the converter. The 2-D and 3-D simulations of the three phase system were carried out using the volume of fluid (VOF) and realizable k -e turbulence models to account for the multiphase and turbulence nature of the flow, respectively. These models were implemented using the commercial CFD numerical code FLUENT. A detailed study of the flow pattern has been presented in the form of contour plots and the results obtained are useful for understanding plume extension and velocity distribution, shear wall stress distribution, and phase distribution characteristics in the system. The results provide a basis for further development of sonic injection technology into relatively small industrial Peirce-Smith converters with the ultimate objective of achieving lower energy consumption, improved process efficiency and increased throughput of the converting process. INTRODUCTIONPeirce-Smith converters (PSC) have been used in copper (Cu) and nickel (Ni) making smelters for more than a century for the purpose of removing iron (Fe) and sulphur (S) chemically associated with copper-nickel mattes through exothermic oxidation reactions. This process is commonly referred to as conversion. In principle, conversion is a submerged injection process, where typically air (or oxygen enriched air), at subsonic velocity (typically < 150 m/s), is laterally blown into liquid matte (Cu-Ni-Fe-S system). Oxygen preferentially reacts with Fe and S to produce iron oxide (FeO), which is slagged off, and sulphur dioxide (SO2), which reports to the process off gas."

Jan 1, 2012

By E. M. De Souza, R. Penner

"Water is encountered at the majority of underground mines, both over their lifetime and during each stage of development and production. The dewatering system is one of the most important and costly components of an underground mining operation and it is often not well designed and analyzed. An effective design of a mine dewatering system will greatly reduce its energy cost as well as improve working conditions and reduce production costs. A computer-based system, called Qpump, has been developed to assist the underground operator to effectively design and/or assess over-all and local mine dewatering systems. The design features and principles used in the development of Qpump are introduced and an example which illustrates typical applications is presented.IntroductionTraditionally, dewatering operations have been given lower priority than many other operations in underground mining. Invariably water will be encountered during the sinking of the mine shaft, during development and subsequent production. The dewatering system thus becomes a very important component of an underground mine operation and, in fact, any mine manager will attest to the importance and necessity of an efficient mine dewatering system.The water problem is of varying importance at different mines. There are several factors that contribute to the water encountered. It is a function of the mining method and techniques utilized (backfill system, drilling and raising technology, dust control sprays, shaft water rings, etc.) and of prevailing conditions (ground water, rock structure and permeability). In some cases a mine may be so dry that little pumping is required while in others, the weight of water pumped may exceed by many times that of ore mined.The successful design and application of a mine dewatering system is dependent upon the operating conditions of each specific operation. There are no standard procedures and systems which can be used for all mining situations. However, an effective water system will greatly reduce the energy and production costs of a mine, improve working conditions and eliminate headaches because of flooded working places."

Jan 1, 1993

By D. M. Ziebarth

"Normal sequence of operations to develop a new underground mine is: construct and outfit headframe for shaft sinking, sink shaft, construct and outfit shaft sump, develop shaft station and shaft bottom steel. In an effort to reduce the overall project schedule, an innovative plan was developed to install service shaft steel below station level, prior to the completion of the shaft sinking effort. To better evaluate the construction of this substantial steel tower, a preliminary constructability evaluation was conducted, including the best method of supporting the main tower; from the bottom, middle or top of the tower. The design criteria and plan involved: •,Develop access from existing service shaft, 25 km underground •,Use of materials to maximize strength while minimizing corrosion exposure •,Estimating the location of the shaft centerline •,Over excavating the station and shaft below station to allow future shaft steel repositioning •,Designing the tower steel for modular installation •,Incorporate commissioning considerations, such as suspension of the cheese weights during steel installation •,Provision for covered stair access to shaft bottom •,Enclosed shaft envelope with open panels to allow visibility and ventilation The design approach was innovative and this paper will describe the design principles and challenges encountered while providing insight into the solutions developed and implemented; especially the modular construction and installation methodology. INTRODUCTION In an effort to expand the mining operations, a plan was developed to construct a new service shaft closer to the new mine workings and convert the existing service shaft to a production shaft at the Potash Corporation of Saskatchewan Inc. (PCS now Nutrien) Rocanville Potash mine in southeast Saskatchewan. The new service shaft required a multi roped friction hoist operating a cage / counterweight, rope guided conveyances to support the operational requirements. The service shaft is an integral part of the mining infrastructure as it provides access to the underground workings, transport personnel and materials underground for operation and maintenance of the mine. The shaft also allows for services required for safe operation of the underground mine, power supply, controls, communication, dewatering and fresh water supply."

Jan 1, 2019

By M. S. Fotheringham

Recognition of the Growing Importance of Iron and Steel Few Canadians have yet become aware that Canada&apos;s vast iron ore resources, the greater part of which is only now beginning to be developed, will inevitably have a profound effect on the entire Canadian economy, benefitting in some measure the lives of all Canadians. The great iron mining developments of Ontario, Newfoundland, Quebec, and Labrador are destined to make Canada one of the world&apos;s major producers and exporters of this material, on which our industrial civilization is?based. These developments will create new employment, new communities, new transportation facilities, and new investment opportunities. Iron ore is the foundation and the keystone of modern mechanized civilization. The most prosperous nations of the world are the highest per capita consumers of iron and steel, and in these countries the per capita consumption is increasing steadily despite the advent of light metals, plastics, and other competitive materials. Three-quarters of the human race have too little steel -and consequently too little mechanization -to provide for themselves the necessities and comforts of civilized living. Progressively they will demand, and acquire, the machines, the transportation and communication facilities now lacking, and they will win them by making greater use of the world&apos;s iron resources. It is the good fortune of this generation that Canada&apos;s &apos;iron age&apos; is just getting well under way.

Jan 1, 1951

By W. J. Li, L. Kong, G. L. Li, X. M. Xi, J. Qiu

"A novel hydrothermal method was applied to prepare the precursor of LiMn2O4 using pre-treated electrolytic manganese dioxide (EMD) and lithium hydroxide as the main raw materials. The precursor was subjected to heat treatment between 400 and 900ºC to obtain spinel Li1.05Mn1.95O4 and Li1.035Co0.035Mn1.930O4 positive materials for lithium ion batteries. The structure and morphology of the obtained powder materials were studied in detail by means of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is found that the precursor has an amorphous structure and a high reactivity, which is easily transferred to spinel structure during heat treatment, obtaining a positive material with an uniform structure and good performances. The XRD patterns reveal that single phase spinel Li1.05Mn1.95O4 can be obtained from the precursor after heat treatment at 600°C in air. The final Li-rich Li1.05Mn1.95O4 product obtained showed a well-defined stable spinel structure and distinctive crystal faces with particle size between 200 and 300 nm. The as-prepared Co-doped spinel sample exhibited a excellent electrochemical performance with an initial discharge capacity of 113.0 mAh/g and 93.8% of its original value was retained after 100 charge-discharge cycling at 0.5 C.INTRODUCTIONThe increasing demand for portable electronic devices and hybrid or full electric vehicles is driving the development of cheap, efficient, compact lightweight and environmental friendly rechargeable batteries systems (Chung et al., 2002; Scrosati, 1995). Lithium ion secondary batteries have satisfied this demand to a greater degree than other battery systems. The cathode material plays a critical role in the performance of Li-ion batteries. The high cost and toxicity of cobalt compounds for the cathode material of LiCoO2 has prompted a search for alternative materials. LiMn2O4-based spinels offer a potentially attractive alternative to LiCoO2, due to its abundance, low price, ease of preparation, environmentally friendly characteristics, better thermal stability, and its effortless recycling (Tarascon et al., 1991; Yabuuchi and Ohzuku, 2003; Amatucci et al., 1999; Tsai et al., 2003). Some achievements have been created to meet the requirements (Guo et al., 2010; Kang et al., 2005; Park et al., 2008; Takahashi et al., 2006; Lee et al., 2001; Yoshio et al., 2001; Arumugam et al., 2008). However, the largest obstacle encountered in the practical applications of LiMn2O4 is its fast capacity fading during long term cycling, which is due to Jahn-Teller distortion of the [MnO6] framework, the electrolyte decomposition at high potentials and manganese dissolution into the electrolyte (Fey et al., 2003). The electrochemical performance of LiMn2O4 is also strongly dependent on its morphological properties, such as crystallinity, phase purity, surface area, grain shape and particle size distribution, etc. All these morphological properties are closely related to the material synthetic routines and heat treatment processes (Huang et al., 2000; Myung et al., 2000; Takada et al., 1998)."

Jan 1, 2012

By B. Hohenstein, B. McBain, B. de Jong

"The automated fire assay system (Fast In-line Fire Assay or FIFA) has not found acceptance in the Au mining industry as the lower measurable limit of 0.20 ppm did not allow Au tailings to be measured with confidence. The development of arrested cupellation has overcome this hurdle which was a limiting factor in the FIFA 1 process. In the new automated fire assay process, automated sample preparation, fluxing, fusion and separation of a Pb button are essentially similar to the FIFA 1 process, albeit with some improvements. However, the game-changer is the development and incorporation of arrested cupellation into the automated system, now called FIFA 2. The purpose of arrested cupellation is to reduce the 50 g Pb button to a 5 g Pb button by partial cupellation in a specially developed arrested cupellation system thereby concentrating the Au in the Pb by a factor of 10 and in so doing moving them into higher concentration ranges in the mini-button where they can be read on the spark spectrometer. Results show that concentrations down to 0.02 ppm Au in geological materials can now be determined using arrested cupellation in the FIFA 2 process, an order of magnitude improvement over FIFA 1.INTRODUCTION Traditional fire assay for Au has remained virtually unchanged for 3000 years. It has survived for so long because it is accurate, has relatively low detection limits and is relatively inexpensive. However, it is labour intensive, has a long turn-around time (typically at least 7 hours), is environmentally unfriendly and exposes assay operators to potentially unsafe conditions (toxic fumes, toxic dust and extreme heat from furnaces). The NiS collection method is not as effective for the assay of Au as it is for the PGEs. A rapid, accurate, cost-effective method for the determination of Au and the Platinum Group Elements (PGEs) in geological materials would be a tremendous benefit to mining companies. Many of these objectives have been met by the FIFA 1 (Fast In-line Fire Assay) developed some 15 years ago in which automated methods have replaced the manual procedures which are part and parcel of conventional fire assay. However, concentrations below 0.2 ppm have been very difficult to achieve with sufficient reliability."

Jan 1, 2017