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By H R. Watling, W van Bronswijk

Of the various copper sulfides in the EarthÆs crust, chalcopyrite is by far the most common. This mineral is also the most difficult to leach, with hydrometallurgical extraction processes characterised by prohibitively slow kinetics. While a number of processes, including leaching at atmospheric pressure and temperature, pressure leaching at higher temperature, and bioleaching of concentrates in stirred tanks and whole ores in heaps have been demonstrated to some extent, there is currently no full-scale unit process for the hydrometallurgical extraction of copper from chalcopyrite ores. Titan Resources NL operated a test bacterial heap leach at Radio Hill, Western Australia in 2001, to extract nickel and copper from a mixed sulfide ore that contained significant amounts of chalcopyrite, pentlandite and pyrrhotite. A proprietary mixed bacterial culture was used to inoculate the heap, and the nickel and copper were precipitated from the resultant solution as mixed hydroxides. Although 65 per cent of the copper from the Radio Hill heap was eventually recovered, the rate of extraction followed an unexpected trend, as the initial rates of copper recovery were much slower than column tests had suggested. It was postulated that this was due to dissolved copper precipitating as covellite or chalcocite in the most poorly aerated zones within the heap, ie furthest from the aeration pipes at the base. It was further hypothesised that the lack of oxidants (oxygen, ferric iron) and the likely inactivity of bacteria in these areas limited the re-dissolution of such secondary copper precipitates. In this study the above hypothesis was tested in column experiments using the same mixed sulfide ore and a synthetic leach solution. One set of columns was aerated and another set was operated without aeration. Results showed that precipitation of copper occurred regardless of whether the column was aerated or not. The results suggested that pH of the leach solution played a significant part in the precipitation of the copper. Further column tests revealed this to be the case. These results are described here in detail.

Jan 1, 2004

SOME notes on the works of the Electrolytic Refining and Smelting Company of Australia will no doubt be of interest to members of the Institute, more especially as much of the work is new to Australasia.As many of the members who may read this paper have not been in a position to visit works of this kind, and are consequently not thoroughly acquainted with all the operations carried on, the author has taken the liberty, in some cases, to enter into explanation which would otherwise be unnecessary.The works are situated at Port Kembla (New SouthWales), about fifty miles south of Sydney, and are approachable both by rail and water. The Government has recently built a low-level jetty upwards of five hundred feet long, and intends installing at an early date an electrically operated portable crane to facilitate the handling of material to and from the boats. Thi.s will mean a considerable reduction in the length of time that boats are laid up at the jetty. There are also under construction two breakwaters, which, when complete, will materially assist shipping operations. The works as they exist are capable of turning out 1200 long tons of refined copper per month. It is gratifying here to note the unqualified success with whichthe E.S.A. refined copper met with on first being put on the market.

Jan 1, 1911

o Resource production is essential for society. o Demand for resources will increase as population grows.o Resource industries are the main consumer of trained geologists.o The lead time from(1) training to productivity(2) research to resource production is measured in years.o An adequate supply of well trained geologists and successful geological research is an important agent in ensuring cost effective, adequate supply of mineral resources for society. Therefore the main beneficiary of geological education is society itself.o Society is paradoxically apathetic or antagonistic to the resource industry because (1) it represents change(2) lobby groups working for other causes have successfully moulded a bogey man image for the resource industry in the public eye.Professional training and research for resource industries consequently lack popular support. Funding is at an absurdly low level in comparison with the economic importance of resource supply.

Jan 1, 1990

By Hughson B

The need to prevent the sterilisation of coal stems directly from the fact that it is a non-renewable resource. In N.S.W. a vast amount of coal resource is located under major public utilities such as freeways, railways, stored waters, pipelines carrying gas, water and sewage, and transmission lines. Total extraction has occurred under freeways, transmission lines and pipelines with little or no damage. Where damage has resulted, the cost of restoration was only a small fraction of the value of the coal recovered. However, coal at present is being sterilised and perhaps lost for ever under stored waters and railways. If engineering solutions are available for mining under these improvements economically and with maximum safety, then coal should be extracted and utilised to the benefit of the State.

Jan 1, 1986

The major coalfields of Australia are almost unique in the occurrence in some areas of CO partly or almost completely replacing CH4,t1e normal seam gas from metamorphism of coal due to time and depth of burial. This CO2 situation has some benefits but mostly it introduces particular safety problems result- ing from the high density of CO2 relative to air, magnifying problems of gas dilution in ventilation, and the greater affinity which coal has for CO2 than for CH4 increasing proneness to gas-dynamic phenomena. The occurrence of most CO2 seam gas can be directly related to igneous intrusion and to its associated pneumatolytic injections. Whilst intrusions locally increase the rank of coal by their contact metamorphic effect, normal coal metamorphism due to time and depth of burial continues after intrusion and injection together with the ongoing metamorph- ic production of CH . This new CH slowly displaces any CO to leave some present-day intruded coals with seam gas with reduced CO2 or even without any significant CO2 associat- ions. The seam gas maps of the Bowen and Sydney Basins and more detailed maps of specific areas exemplify these situations. Mining progress, plus more searching studies of igneous-coal relationships provide improved understanding of the factors involved.

Jan 1, 1986

Improvements in mechanisation should not be considered independently of safety and of environmental hazards. The need to keep gas contents within statutory limits may make the time needed to partially drain a gassy seam the effective control on face development times. Dust levels may provide an effective control on coal extraction rates on any one face. The combination of gas and dust on high output longwall faces may make it necessary for each one to be treated as a separate mine in terms of ventilation, and the faceworkers may need special protection. Mechanisation and safety can be mutually beneficial when mechanisation combined with systematic safety assessment reduces accidents, and when a thorough study of how to reduce accidents and health risks indicates the best method to improve mechanisation.

Jan 1, 1988

By Davey FJ

The Hikurangi Margin of eastern North Island New Zealand represents the feather edge of the over-riding Indo-Australian Plate at its convergent boundary with the subducting Pacific Plate. Towards the south, convergence becomes slower and increasingly oblique, and sediment supply from the Southern Alps becomes increasingly rapid. In this environment a 150 km wide, imbricate thrust, accretionary prism has grown since the Miocene, uplifting slope ridges and basins and a range of coastal hills. Offscraping of thick, axially transported, trench-fill turbidites begins in a zone of proto- thrusts, which extends up to 25 km beyond the principle, slope-toe, deformation front. On the slope, landward tilted, trench-slope basins are separated by ridges. The ridges ride up on thrusts that sole out at a major decollement. The decollement dips landwards at 3 degrees to a depth of 14 km at the coast, where it coincides with an onshore zone of high seismicity. Beneath the decollement, about 1 km of consolidated, oceanic sediment is going under the margin with the underlying oceanic basement. Some of these sediments may underplate the frontal ranges to the west and geochemical evidence of subducted sediment is found in the volcanic zone beyond. A rapid decrease in the width of the accretionary prism to the north is associated with a decrease in sediment supply and perhaps with a dislocation in the downgoing plate. To the south, the accretionary prism narrows, swings westward, and merges into the zone of very oblique collision that marks the transform between mirror image subduction to north and south of New Zealand.

Jan 1, 1987

Mount Isa Mines Ltd. annually extracts 5.6 million tonnes of copper ore from the 1100 Orebody. All production is by longhole open stoping, with an increasing emphasis on pillar recovery. Drilling and blasting prac- tices have been modified to allow more efficient pillar extraction, with the evolution of a "core and shell" approach. Blast design occurs at the stope design stage, while individual blast preparation is based on detailed ring plans. A programme of blasting research involving surface and under- ground vibration monitoring and fragmentation assessment has been car- ried out in conjunction with production personnel. Drilling and blasting practice in the orebody must continue to evolve with continued research, to suit changing conditions and take advantage of new technology.

Jan 1, 1988

The need for a carefully prepared set of special conditions, to be used with general conditions of contract or, alternatively, a purpose written contract for adoption in tunnelling work in Australia is discussed. Recent decisions on the proprietor's liability for tender information and arbitrator's power to award interest are examined. A new clause for inclusion in contracts specifically giving arbitrators power to award interest is suggested. Similarly, a new clause covering delays due to environmental disputes is suggested, particularly for marine outfall tunnels. An alternative method for the settlement of disputes by negotiation is suggested for consideration and contracts and contract administration are discussed as the possible weak point in the construction process. At the conference it is intended to present a method or process to be used in contract administration which should reduce disputes, result in a better quality and efficiency of administration and ultimately in better contracts'.

Jan 1, 1981

By L E. Setiawan

The mining and milling groups at Batu Hijau are tasked with increasing SAG mill throughput by approximately ten per cent. Avenues used for this process are blasting and crushing optimisation, ore blending and predicting SAG mill throughput in relation to the geological model. This is in line with traditional æMine to MillÆ studies. At Batu Hijau, mill and mine sequencing cannot readily be configured to perform the surveys traditionally required by a æMine to MillÆ study while meeting the daily production target of 140 000 tonnes per day and processing from varying ore types in one pit. A program called BOCCOST (blasting optimisation crushing conveying optimising SAG throughput) has been implemented to capture approximately 200 variables from blasting, mining and milling operations and assign them to a common point in space in the geological model in real time. Interpretive analysis of data from BOCCOST is used to model relationships between the 200 variables to determine which and how these factors affect SAG throughput. Once these relationships are determined, the blasting, ore blending and crushing process can be optimised to generate a product that maximises mill throughput. The relationships modelled from BOCCOST are also used to generate a SAG mill throughput estimator, which can be coded into the production block model. The block model can be reconciled with the geological block model for correlation by geological domain. Once this relationship is established, SAG mill throughput domains can then be established for predicting SAG mill throughput. This SAG mill throughput estimator is then used in conjunction with revenue calculations to determine an ore cut-off, which combines these two elements to maximise metal production.

Jan 1, 2002

Electrochemical investigations of the flotation of sulphide minerals are re- viewed. Flotation with thiol collectors is interpreted in terms of a "mixed poten- tial" model in which the process leading to hydrophobicity is the anodic oxidation of the collector at the mineral surface and this is driven by the cathodic reduc- tion of oxygen. Electrochemical studies have identified the products of anodic oxidation as chemisorbed collector, metal collector compounds, and dithiolates; the products formed in each situation depend on the collector used, the mineral under study, and the pretreatment of the mineral surface. Investigations on galena, pyrite, and chalcocite are discussed. Electrochemical and x-ray photoelectron spectroscopic studies have been used to determine the products of surface oxi- dation of sulphide minerals in order to elucidate the mechanism of collectorless flotation. The mixed potential mechanism allows consideration to be made of the ways in which flotation of sulphides with thiols can be inhibited. Examples of depressant action are presented. The relevance of electrochemical investi- gations to practical flotation is Discussed.

Jan 1, 1984

By Somasundaran P

Controlled modification of mineral/liquid interfacial properties by adsorption is critical for mineral processing operations such as flotation, filtration, dispersion and flocculation. Ionic/nonionic surfactant mixtures usually show enhanced surface activity and salt tolerance over ionic surfactants, and this is especially beneficial for flotation of salt type minerals in which case dissolved multivalent cations in high concentrations usually cause loss of anionic surfactants by precipitation. Adsorption of nonionic/anionic surfactant mixtures on kaolinite has been studied with sodium dodecylsulfate as the anionic surfactant and octaethyleneglycol mono-n-dodecylether as the nonionic surfactant. Synergistic interaction between these surfactants was found to cause adsorption of the nonionic surfactant with its hydrophilic chains protruding into the bulk, leading to substantial changes in flotability and dispersion characteristics of kaolinite. Similarly, hydrophobicity changes are observed also' for silica particles upon adsorption of nonionic ethoxylated alcohols owing to possible changes in the orientation of the adsorbed surfactant species at the interface. Also, based on the results obtained with surfactant adsorption, a hydrophobically modified polymer was used successfully to disperse graphite particles in aqueous solution.

Jan 1, 1993

By Ryan CG, Ramsden AR, Sie SH, French DH, Griffin WL

Proton microprobe and electron microprobe analysis are being used in combination for in situ determination of the trace element contents of oxide, sulphide and silicate minerals in a sample of the Merensky Reef. Initial results indicate that chromites contain only Ni, Zn, Ga, Zr ar d Nb. Platinum-group elements, if present, are at concentrations less than 2 to 6ppm. Ru, Rh and Pd are the only platinum group elements to be consistently detected in the sulphides. PentLindite is the most important host for these elements with the concentration of these elements being dependant upon the mineral association in which it occurs

Jan 1, 1989

By Yushan Ma, Jiqing Wang, Hanyi Jia

The Hedong Gold Mine is located in the Yantai area, Shandong province, China. It is an underground mine with an annual gold output of some 700 000 grams. The orebody is located on the edge of the Wanger Shan metamorphism zone, and the hangingwall of orebodies is thus defined by a prominent set of fractures. The proximity of the metamorphism zone and the inclusion of the fracture set ensure that both the orebody and the country rocks are unstable. The main orebodies dip at an angle of between 40 to 45¦, with a strike length of 160 metres and a horizontal width of 50 metres. Surface subsidence in the area is not permitted. Cut and fill mining is usually practiced. As the mining operation proceeds to greater depths, the ore grade is diminishing and it is necessary to find a more efficient stoping method. Sublevel open stoping with sequential extraction and filling of each sublevel has been designed and applied in situ. This new mining method is called æsublevel open and fill stoping methodÆ in the mine. Experience to-date is that new mining method is satisfactory.

Jan 1, 1998

By Scherbatsky VB, zon BM, Babushkin NM, Kitaev BI, Shabel&apos

The structure and hydrodynamics of the raceway zone of a blast furnace was studied on a cold model representing a sector containing two tuyeres. The model differed from the usual in that it was prov- ided with continuous flow of the coke layer at pre- determined rates, had provision for changing the tuyere parameters (diameter, protrusion, inclinat- ion) and irrigation of the layer with liquid. A combination probe was developed which per- mitted simultaneous measurement of the pressure field both across the area and through the height of the layer as well as determining the topography of the raceway. The velocity fields in the layer were measured with a specially made impulse thermo- anemometer. The determining criteria of the model were taken as the relationships between the energy of the blast and the particles, the dimensions of the raceway and the cross-section of the tuyere. The model established the effects of the tuy- ere structural parameters, blast parameters and amount of liquid products of smelting on the con- figuration of the raceway, the structure of the layer, pressure and velocity fields in the vicinity of the tuyeres and in the vertical direction through the layer. The properties of the raceway formation and the structure of the layer in motion have been clarified.

Jan 1, 1981

By J Slade, R Trueman

Unplanned dilution has the potential to seriously undermine the economic viability of a mine, and in some cases results in mine closure. The effect of stress damage on dilution has become increasingly relevant as mining depths increase. In the case of narrow vein mining, the incremental extraction of long-hole rings has the potential to result in a moving high stressed zone at the stope brow. This leads the hanging wall and footwall to experience a spike in the stress to strength ratios as the brow passes. In some cases, the stress to strength ratio may be high enough to result in fracturing or damage to the rock mass. The aim of the study described in this paper was to investigate whether stress damage results in a significant increase in dilution. The study involved analysis of overbreak from 410 case studies from the Kundana Gold mine in Western Australia. Site personnel had already undertaken calibration studies of the stress levels that result in rock mass damage. This calibration, in conjunction with numerical modelling showed that stress damaged stope walls at this mine had on average 50 per cent more overbreak than stope walls where stresses had not exceeded the damage criterion. For a design mining width of 1.5 metres, and with both walls impacted, this represents 36 per cent increase in dilution. After adjustment for possible sources of bias the difference reduced to an average 0.10 metres per stope wall, representing 13 per cent dilution for the mining width under consideration. The potential for stress damage related overbreak should therefore be considered as part of any assessment of narrow vein dilution.

Jan 1, 2005

By B G. Lottermoser

Phosphate induced stabilisation has been used to create passive iron phosphate coatings on pyrite and pyrrhotite. The formation of solid phosphate coatings on sulfide grains thereby inhibits sulfide oxidation. The aims of the study were to determine whether phosphate induced stabilisation could control sulfide oxidation and metal mobility in partly oxidised, polymineralic, sulfidic mine wastes. Waste materials were obtained from the acid mine drainage generating, abandoned Montalbion silver mine site, far north Queensland, Australia. The waste consists of quartz, kaolinite/illite, sulfide minerals (galena, chalcopyrite, tetrahedrite, sphalerite, pyrite, arsenopyrite), and pre- and post-mining oxidation products (hydrated Fe, Cu, Pb and alkali mineral salts). SEM observations of waste material treated with potassium orthophosphate showed that metal, metal-alkali and alkali phosphate coatings developed on all sulfides (with the exception of tetrahedrite). The abundance of phosphate phases was dependant on the availability of cations in solution for complexation with the phosphate anion. In turn, the release of cations was dependent on sulfide oxidation or the dissolution of efflorescent mineral salts. Experiments aiming to dissolve these phosphate coatings û using a strongly oxidising solution û showed that the phosphate coatings remained stable, preventing acid generation and metal release. The results of this study demonstrate that liquid phosphate stabilisers can suppress sulfide oxidation and immobilise metals in partly oxidised, polymineralic mine wastes.

Jan 1, 2003

By P Trotta

The paper provides a structured methodology to investigate metallurgical problems within the operating concentrators. The strategy uses classical metallurgical data analysis as well as pulp, solution and surface analysis to determine the reasons for particular behaviours. The approach applies equally to all mineral-processing operations. To demonstrate its effectiveness a case study, based on work conducted at Pasminco Rosebery Mine, is described. In this work, the classical metallurgical analysis indicated that a significant amount of sphalerite reporting to the lead concentrate occurred as liberated particles. A combination of pulp, solution and surface analysis supported the hypothesis that the liberated sphalerite was recovered by inadvertent activation by lead ions. Laboratory studies have indicated that the use of sodium carbonate, by itself and in combination with zinc sulphate and sodium cyanide, when added to the lead regrinding mill can depress sphalerite flotation, resulting in an improvement in the lead grade/recovery curve. When this approach was tested in the plant other more dominant issues masked any positive effect the addition of sodium carbonate may have had. The plant trial highlighted the real need for additional regrinding capacity.

Jan 1, 2002

By M Wortley, A Cantarutti, G J. Clarke, C

As part of a broad program to optimise the performance of their grinding circuit, BHP Billiton Cannington have installed an OCS¬ Expert system together with three VisioRockÖ online particle size analysis cameras. The main purpose of the system is to stabilise grind size and feed to the flotation circuit. This particular application of OCS¬ is the first installation to incorporate Metso Minerals Process Technology-Asia PacificÆs (MMPT-AP) Dynamic SAG/AG Mill Model, which is able to predict numerous mill parameters that were previously unable to be measured with the existing plant instrumentation. Integrated into the logic of the control algorithm are online vision based, particle size measurements of the AG mill feed and recycle crusher product. This paper will describe the history of the project from initiation to date, the model and OCS¬ logic configuration, and demonstrate the significant benefits realised at Cannington mine.

Jan 1, 2007

Launching the Queensland Water Plan 2005 - 2010 in August 2005, Premier Peter Beattie compared the stateÆs water resources with liquid gold. QueenslandÆs peak industry body for the minerals and energy sector, the Queensland Resources Council (QRC), believes the analogy is appropriate. During early development of an industry water strategy, it has become apparent that water is like liquid gold, in that it is revered, hoarded, recycled, priced on purity, a magnet for speculators, both difficult and expensive to transport effectively, heavily regulated and fundamentally linked to issues of security. To date it has generally been economic and relatively straightforward for the resources sector to secure water. Although production has not been compromised, this must not be grounds for complacency as there is every indication that water will continue to become increasingly expensive, more tightly regulated and, relative to a growing demand for a finite water supply, increasingly scarce. During 2006, QRC has developed and is implementing a voluntary industry water strategy to address a range of challenges confronting the resource sectorÆs security of access to water. As a consequence of, at times, protracted community consultations over QueenslandÆs catchment-based water planning processes it has become clear that many community stakeholders have outdated perceptions of the stateÆs resources sector. Once established, QRCÆs water strategy will incorporate a community engagement campaign to present the industryÆs credentials as a leader in water resource management. The development of QRCÆs water strategy, and the challenges the strategy is designed to address, provides insight into the fundamental reforms that are occurring in how water is managed and regulated in Queensland. These reforms have implications for how government policies are designed and administered and also for how industry engages with communities during this transition process.

Jan 1, 2006