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Synthetic and commercial activated carbons are characterised for several chemical and physical properties. A range of techniques is used to establish correlations between physicochemical parameters and gold- adsorption activities. The most important parameter in the carbon activation process for a product with a high gold-adsorption activity is the activation temperature. High activation temperatures yield products with large micropore volumes which provides sites that are ideal in size for adsorption. The surface area of an activated carbon is not necessarily a good measure of its adsorption activity. Surface oxygen-containing functional groups are identified by Fourier transform infrared spectrophotometry to be comprised mainly of ethers and hydroxyls. These functional groups line the edges of the micropores imparting a polar character to the pore and aid in the solvation of the adsorbate. Oxidants such as nitric acid result in a proliferation of surface carboxyl groups. resulting in a negatively- charged surface that is not conducive to the adsorption of gold.

Jan 1, 1993

Because of the work of the pioneers of sampling theory, we know the principles, test work and equations to use to design sampling systems to meet targets for precision and accuracy. However, we do not see such æproperÆ systems deployed everywhere a sample is obtained around mineral processing plants. In many cases, we do not have solutions that satisfy all of the theoretical, economic and practical considerations. There are some well-known problems, such as high-volume streams with wide size distributions combined with a sparse valuable component that is heterogeneously distributed (such as gold ore SAG mill feeds). However, other difficult sampling issues are common, such as streams which vary widely over a day in flow rate and slurry density (many flotation concentrates), and loaded CIP carbon on transfer to elution. Inventory measurement issues abound, especially for leaching operations where daily inventory change is significant for metallurgical accounting. The result is that operators realise that although they issue reports daily, they do not know what is actually going on in their plant on a daily basis with sufficient confidence to quickly diagnose problems or confidently predict the benefits of potential enhancements. The industry needs practical and economic solutions that can be awarded the ætheoretically correct samplerÆ tick in order to better understand and optimise their processes.

Jan 1, 2008

By J Mavrogenes, C J. Spandler, S M. Eggins, K Worden

Major occurrences of platinum group minerals (PGM) are in crustally-contaminated, huge, layered igneous complexes (Bushveld and Stillwater) and gabbroic intrusions (Norilsk); relatively minor occurrences include arc-related æzoned Alaskan ultramaficsÆ. In terms of arc-related provenances, the recognition of alluvial PGM in river and beach deposits of southern South Island (Mitchell, 1995), in situ in the Longwoods (Cowden et al, 1990), and the ultramafic-mafic layered Greenhills Complex at Bluff (Spandler et al, 2000) raise the possibility that some economically-significant PGM deposits may exist in New Zealand. The Longwoods and Greenhills are in the Brook Street Terrane which is a remnant of a primitive intra-oceanic arc system of Late Permian-Early Triassic age. The Terrane comprises volcanogenic sequences containing plagioclase- and clinopyroxenephyric basalts, high-MgO ankaramite and dolerite dikes, trondhjemite plutons, and basaltic to andesitic volcaniclastic and sedimentary rocks. The cumulate complexes contain early-formed olivine- and clinopyroxene-rich ultramafic cumulates overlain by anorthite and hornblende-bearing gabbros. Primary (isoferroplatinum) and secondary (sperrylite) platinum group minerals are preserved in chrome-rich spinel pods in basal dunite of the Greenhills Complex. Saturation during early fractionation of primitive high-MgO magmas rather than magma mixing seems likely for the primary PGM. Together with correlative terranes in Queensland and New Caledonia, the Brooks Street Terrane is an exposed cross-section of an extensive Permo-Triassic island-arc system. Most parental magmas were primitive island-arc tholeiites, but other primary magma-types include high-MgO ankaramites and trondhjemites û the latter formed by partial melting of lower crustal clinopyroxene-rich cumulates and gabbros, respectively. The parental ankaramites fractionated to form mafic-ultramafic cumulates and primitive to evolved melts of high-Al basalt to andesite compositions (Takitimus). The Brook Street Terrane is an analogue for modern intra-oceanic islandarc systems and allows detailed study of subvolcanic arc processes.

Jan 1, 2005

By C Glassock, P Bodon, M Elias

Computer simulation is a well-accepted tool for modelling the behaviour of large or complex operating systems. Less common is the use of simulation as a design aid, but FluorÆs simulation group regularly applies discrete and continuous simulation models to assist with optimisation and risk management in a wide variety of mining, mineral processing and logistics applications. To demonstrate the wide applicability of simulation modelling as a design aid, this paper describes three case examples from FluorÆs recent work that cover both discrete and continuous operations.

Jan 1, 2003

By A Sellgren, M R. Carstens, R Visintainer

There is a wide variety of industrial pastes or non-settling slurries pumped in mining, dredging and reclamation projects as products, refuse and tails. The types and/or names of some of the common ones are alumina red mud, phosphate clays, tar sands mature fine tails, tar sands (CT) consolidated clays and fly ash. The pipeline performance or friction of these varies dramatically with the type, its concentration and the particulars of the actual slurry making it difficult to select pumping equipment and to design associated pipelines. The GIW Hydraulic Laboratory in Grovetown Georgia has tested a number of these slurries over the last 30 years for various mining customers. Where available in the public domain and/or where permission has been obtained, the results of those tests are presented in this paper in a form usable for pipeline and pump system designers and users.

Jan 1, 2005

The appraisal of mineral reserves by a lender is carried out at the initial stages in developing a loan for a mine. The depth of investigations is influenced by the competence of the explorer, the type of commodity and knowledge of the geological environment. The lender looks for a reserve life which exceeds the term of the loan plus contingencies for events such as cost over-runs, adverse markets and production difficulties. The physical features of importance are discussed. Factors with direct financial implications are considered for their incorp- oration in sensitivity analyses to allow risk appraisal. When satisfied, the lender can then proceed to review cash flow forecasts, the basic strength of the project, then determine with the borrower the components and alternat- ives of a loan package.

Jan 1, 1979

The BHP Billiton Cannington mine uses sequential flotation to treat a silver, lead and zinc ore supplied from an underground mine. The final products from the process plant are a silver rich lead concentrate and a zinc concentrate. Operational history of plant performance highlighted that the majority of valuable metal losses to final tailing occurred in the -5 ¦m fraction. Research completed on the flotation characteristics of this size fraction in plant feed resulted in the development of a split flotation process to improve the silver and lead mineral recoveries. Construction of a $A 9.5 million brownfield project to install the new split flotation circuit at Cannington was completed in July 2002. The circuit consists of three stages of cyclone classification to recover the ultra fine material to a final cyclone overflow stream, conditioning of this pulp to achieve optimal process conditions, and conventional rougher and three stage cleaner flotation to produce a silver rich lead concentrate. The rougher tail from the new circuit is recombined with the cyclone underflow streams and processed through the original lead-zinc flotation circuit. This paper discusses the circuit design, material properties, material selection for components of the circuit, operational practices and requirements to ensure the circuit succeeded in meeting production targets. The technology is subject of a number of patent applications including international application No PCT/AU02/00400.

Jan 1, 2003

Mineral exploration management has undergone major changes particularly in the last decade. Parallel to these changes in management, and partially responsible for them, have been the changes in governmental laws and regulations at both National and State levels reinforced by a highly competitive climate created by the exploration boom in Australia. The influence of overseas methods and approaches have been married to the Australian techniques resulting in a management climate which is not only familiar with the technical aspects of exploration, but is also familiar with the personnel, economic and legal phases associated with the expenditure of very large sums of money. The utilization of all the geosciences coupled with mathematical models and computer techniques for pre-selection and assessment of areas are now normal aids used in management decisions. Management techniques developed and being developed will ensure that successful exploration will be carried out if sufficient incentives are guaranteed.

Jan 1, 1974

Boring of a 7.5Km long tunnel under the city of Stockholm commenced in January, 1987. The 3.5m diameter tunnel will pass under the buildings and as no ground settlement is allowed, the regulation for water leakage into the tunnel is very strict. Probe drilling will be carried out continuously ahead of the boring and when water is encountered the rock has to be grouted before passing with the TBM. The tunnelling system enables probe drilling to be carried out during boring with the TBM. This has earlier been a capacity reducing factor as the whole operation has been stopped during probe drilling. The project is using a new generation TBM especially developed for hard rock formations which require higher thrust per cutter to get a high penetration rate.

Jan 1, 1987

By G R Ryan

Dissatisfied with conventional wet processing methods for alluvial deposits, Resource Trend Pty Ltd of Cairns set out to develop a better process. After comprehensive investigation of existing dry techniques the principals have now developed a rotary dry concentrator that can handle the fine-grained fraction of alluvial deposits as well as the coarse. Four of these units have been mounted on an integrated towable treatment plant which has been in successful commercial operation for four years in northern Queensland. A second plant is now under construction for use in the United States. Grades of less than 0.2 g/lcm have been profitably mined at throughputs of about 80 cubic metres per hour and 85 per cent availability. The operation runs round the clock with an establishment of four. Major benefits, apart from lower capital and operating costs, are environmental. Ore is picked up, treated, and replaced in its original mixed condition within 25 m of its initial location. Rehabilitation is completed almost immediately behind the plant as it advances, leaving no slimes dams, coarse stockpiles, or haul roads. In 1993 the company won a Premier's Award for Environmental Excellence in the Queensland Mining Industry. The principal disadvantage is moisture, and the company is now actively seeking deposits in the deserts of the world. In Queensland mining is normally possible only for six months of the year.

Jan 1, 1994

By L Smith, R Beckie

An intermediate scale (8 m + 8 m + 5 m high) constructed waste rock pile experiment was built upon a contiguous grid of 16 gravity drainage lysimeters to investigate the flow of water in unsaturated waste rock. Average net infiltration to the uncovered waste rock pile is 55 per cent of precipitation. Large rainfall events have net infiltration of 55 per cent to 85 per cent. Net infiltration estimates range from 23 to 120 per cent of precipitation between lysimeters. Small-scale lysimeters of less than 4 m2 area are shown to be poor predictors of net infiltration for uncovered waste rock. The appropriate size for lysimeters increases with increasing flow rate. The residence time distribution has an estimated median value of 3.0 to 3.9 years under average infiltration conditions. Water flows within the fine grained matrix, within larger pores (macropores), and in matrix free areas of the pile. In situ tracer concentrations vary between pore sizes, and between spatially distinct areas of the pile, indicating water geochemistry may also be variable. Water samples collected from in situ soil water samplers are dominated by the most mobile water fractions. In situ measurements of water content and matric suction are compared to the measured outflow. The data indicate the focusing of flow in spatially distinct areas can make in situ instrumentation a poor (non-conservative) predictor of volumetric water flow.

Jan 1, 2003

A computer programming language known as GPSS is described and possible applications for the mining engineer are presented. The language is continually being upgraded with improved versions appearing about every three years. The tremendous power of the language is considered by comparing it with standard engineering programming languages, such as Fortran or Basic. Sample problems that can be solved using the language are indicated. The advantages and disadvantages of the languages are also discussed.

Jan 1, 1987

The stratigraphic sequence west of Mount Isa contains the Judenan Beds, Eastern Creek Volcanics, and May Downs gneiss. It is an incomplete sequence as major north-south faults divide the area into four separatezones containing portions of these different units. The first three zones, which occur directly to the west of the Mount Isa Fault, consist of quartzites and quartz-mica schists which are uncorrelatable between zones but have been grouped together as the Judenan Beds. The most western zone contains an incomplete section of Eastern Creek Volcanics which rests conformably on a unit believed to be equivalent to the Mount Guide Quartzite; this is again underlain by the May Downs gneiss. A detailed description of the rock types is presented, but only a broad stratigraphic correlation is possible with the very much thicker sequence to the east of Mount Isa.The age of sedimentation is believed to be Lower Proterozoic and it may not occur in the type of geosynclinal basin envisaged by previous authors.This sequence is intruded by many small basic intrusions and also the Sybella Granite with its associated microgranite and pegmatites. The Sybella Granite consists of both a massive and a foliated phase; the latteris generally restricted to the margin of the main granite mass.Four regional metamorphic zones have been identified on the basis of their pelitic mineral assemblages; these are a chlorite, biotite, biotite-cordierite, and a sillimanite zone; separating each are prominent north-south faults.This metamorphism is a regional metamorphism which accompanies the first generation folding of the area and is not associated with the emplacement of the Sybella Granite. A very localized retrogressive metamorphism is also found in some areas of second generation folding.

Jan 1, 1972

THE following paper is a description of the plant and operations of the above company in their recovery and treatment of the quartz tailings deposited as final residues by the various mining companies. at Waihi, Karangahake, and Waitekauri into theOhinemuri River. During the past few years the silting of the Ohinemuri River has increased to such an extent as to cause considerable interest and discussion, and has lately been the subject of a most extensive inquiry by a Royal Commission, to consider the best means of dealing with what is generally spoken of as a public nuisance.Ever since the commencement of mining in this district, which was opened as a goldfield in 1875, the various mines operating have been discharging their tailings into this river, it having been proclaimed a sludge channel in 1895. Up to the year 1900 the quantity of quartz crushed was not large, probably not exceeding 500,000 tons; but since that date the annual tonnages discharged have increased enormously, and at the present time would total from 550,000 to 600,000 tons per year. Records show that up to the end of 1910 at least 5,000,000 tons have been crushed, for an actual yield of bullion considerably exceeding £10,000,000 in value, and all the valuable tailings from...

Jan 1, 1911

By Graham J

The successful processing of arsenopyritic ores is difficult and will be facilitated by a better understanding of the mineralogy of gold within arsenopyrite and the type of arsenopyrite in which gold is taken up. Solid solution gold in arsenopyrite is now well documented, and is a significant cause of refractory behaviour in gold processing. Investigations of the crystal structure and stoichiometry of arsenopyrite by X-ray diffraction, electron microprobe analysis and convergent beam electron microscopy have been carried out in order to understand how the gold is incorporated into the structure. Variations in stoichiometry, particularly the As:S ratio, of arsenopyrite leads to variations in structural parameters. These variations result in slight changes in thermal behaviour. The distribution of invisible gold in an arsenopyrite grain is generally non-uniform and synthesised samples contain up to 2 wt per cent gold. A transmission electron microscopy (TEM) technique called ALCHEMI is being used to identify the substitution site. The process of gold agglomeration together with evidence of an ordered breakdown of arsenopyrite to pyrrhotite has been documented with the use of TEM. An arsenopyrite grain containing invisible gold was heated with an electron beam resulting in recrystallisation of arsenopyrite to pyrrhotite with arsenic being expelled. The gold is mostly insoluble in the pyrrhotite lattice and therefore exsolves out and combines with other gold atoms to form droplets at the boundary of the pyrrhotite.

Jan 1, 1992

University education in Australia is changing, driven by greater market orientation, reduced funding available per student, especially in the higher-cost minerals industry disciplines, and the call for more flexible delivery of subjects and courses to meet changing lifestyles and expectations. The opportunity exists for a true partnership to develop between industry, government and academia that will reshape minerals education in Australia and secure the future supply of the specialists industry needs to maintain international competitiveness. If this partnership does not emerge, it is anticipated that AustraliaÆs somewhat fragmented and unstable higher education system, especially in the disciplines of particular relevance to the minerals industry, will be put under further pressure so decreasing its effectiveness to produce quality graduates. The Minerals Council of Australia in 1998 published æBack from the BrinkÆ, a discussion paper which proposed strategies to build a world class minerals tertiary education system in Australia. Those strategies are now being implemented collaboratively with principal emphasis on the disciplines of mining engineering, metallurgy and earth science and as far as process is concerned, on the necessity to æcooperate to competeÆ. For metallurgy, the challenge is to integrate more closely undergraduate teaching with the existing world-class research centres and to link the tertiary institutions in such a manner that the strengths of all components are harnessed and then made available nationally in major population centres and at remote sites where appropriate. For industry the challenge is to build effective partnerships with the academic community that will enable and assist the agreed course of action to take place.

Jan 1, 2000

By G Ryan, Yu Nazimova

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. This paper aims to highlight the global exploration opportunities that exist in connection with Ural-Alaskan (UA)-type intrusions. The key economic importance of UA intrusions is the existence of metallic platinum (mainly iron-platinum alloys) associated generally with chromite mineralisation and located within a dunite core, especially its coarse-grained part. Being very dense and resistant to erosion, platinum can form rich placers as the intrusion erodes. Big multimillion ounce placer platinum deposits of this type have historically been successfully mined for many years (eg Russia, Colombia and Alaska).However, large-scale exploration and mining of platinum placers currently occurs only in the Russian Far East. Outside of Russia, there is now little or no understanding of this type of deposit and its economic importance. Using successful operations in Russia as examples, it is demonstrated that there are many opportunities for similar discoveries all around the world, especially around the Pacific Rim, where such intrusions tend to be concentrated. Examples of highly prospective areas in eastern Australia and New Zealand are given. There is also excellent potential in British Columbia (BC) Canada, South-East Asia (Philippines, Indonesia, Papua New Guinea and New Caledonia) and South America (Colombia and Ecuador).CITATION:Nazimova, Y and Ryan, G, 2015. Platinum potential of the pacific rim of Ural-Alaskan-type intrusions, in Proceedings PACRIM 2015 Congress, pp 665–670 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By D Lau

Traditionally X-ray diffraction (XRD) has not been significantly used by the cultural heritage sector, as the most commonly used technique, X-ray powder diffraction (XRPD), requires sample removal from the artwork or artefact, followed by grinding of the sample to a fine powder. With the development of micro-X-ray diffraction (micro-XRD) and other associated advances, non-destructive, in situ analysis of crystalline pigments on micro-areas of paintings and artefacts has become possible. This is illustrated with the application of this technique to the in situ analysis of propriety paints, paint cross-sections and small paintings. However, workers have noted that XRD can be insufficiently sensitive with pigment mixtures, due to matrix effects. This study obtained X-ray diffractograms of 17 single pigment preparations and determined relative amounts of crystalline content. The purity of single pigments was compared with Joint Committee on Powder Diffraction Standards (JCPDS) database diffractograms. The impact of pigments with high X-ray absorption coefficients on the detection limits of pigments with low X-ray absorption coefficients was further investigated by building on work done with the chromium oxide-zinc oxide series with the preparation of a second series of binary mixtures of zinc oxide (which has a high absorption coefficient and is almost fully crystalline) and ultramarine blue, which has a lower absorption coefficient but which is more crystalline. Semi-quantitative analysis, where baseline and absorption factor corrections are made, confirm detection limits as low as five per cent for chromium oxide and ultramarine blue when in a binary matrix with zinc oxide. However, this type of analysis is very time consuming. So in order to theoretically simulate issues that will be encountered with binary pigment mixtures, the single phase diffractograms were used to theoretically investigate the matrix effects of the three white pigments with the various coloured pigments. This illustrated that detection limits can be as low as five per cent or in non-ideal conditions, such as with partial peak clashes or where there are large differences in relative peak intensity, as high as 50 per cent. These results have significant implications for the analysis of painted surfaces on artworks or artefacts. It has been demonstrated that ideally this method is more suited to the investigation of surfaces where there is minimal mixing of pigments or where there is not a significant difference between the absorption coefficients of the mixed pigments.

Jan 1, 2008

By J B. Farrow

The AJ Parker Cooperative Research Centre for Hydrometallurgy carries out research on behalf of, and in collaboration with, the Australian mining industry. As might be expected, much of its research is directed towards improving the efficiency of alumina and gold processing plants. However, the Centre also carries out research of relevance to base and other metal producers. A key element in its work is the successful transfer of its technology to the companies with which it is working. In general, this is achieved in the following five steps:definition of the problem through discussions with the company commissioning the research; execution of the research; assessment of the research findings; testing of the research findings by pilot plant or on-site trials; and implementation of the results on the full-scale. This pattern is exemplified by the work carried out by the Centre to improve the performance of gravity thickeners which are used throughout the minerals industry for solid-liquid separation. The research has focussed mainly on ways to optimise the use of flocculants (long chain polymers) to enhance thickener performance. It has been shown that the way the flocculant is mixed with the slurry is of profound importance. Computational fluid dynamics modelling of the feedwell region of thickeners and laboratory and plant flocculation studies have been used to determine better ways to contact the flocculant with the feed slurry. Implementation of these and other findings on the full-scale confirmed that improvements in thickener performance were indeed possible. As a result of this AMIRA funded thickener technology work, there have been considerable savings to a number of Australian mineral processing companies, through improved operation, higher throughputs and flocculant savings.

Jan 1, 2000

By W Lunwongsa, S Meffre, S Nuanla-ong, K Zaw, R James, A Salam

Gold and silver mineralisation at the Chatree low sulfidation deposit is hosted in andesitic volcanic and volcaniclastic rocks and characterised by multiple hydrothermal alteration assemblages and quartz-carbonate (chlorite-adularia) replacements, veins and breccias. The ore-bearing veins are influenced by intersecting structures and host rock lithologies. Emplacement of the host succession occurred at 250 ¦ 6 Ma (dated with laser ablation ICP-MS U-Pb zircon techniques), which was closely followed by mineralisation at 250.9 ¦ 0.8 Ma based on the analysis of adularia from coarse-grained quartz-sulfide (chalcopyrite-pyrite- sphalerite) veins using laser ablation Ar-Ar methods. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008