Search Documents

All companies and individuals who embark on a business venture incur costs. For the most part these costs can be conveniently categorised, firstly into capital and operating costs and then into the various elements of these major cost centres. Although the nature of expenditure naturally differs as between industries certain broad cost types are characteristic of all heavy industries. The capital costs of gaining access to an orebody, equipping a new mine, building a treatment plant and perhaps refining and smelting facilities are likened to capital expenditure by a manufacturer on new plant and equipment required for an expansion or new product innovation. Similarly the day to day costs of labour and materials employed in the running of a mining operation can be likened to similar costs in other heavy industry. There is another group of costs that are not so easily categorised. Most industries incur unavoidable costs that do not form part of the direct or capital costs of physical production. These costs include taxes and other payments to government and research expenditure. The mining industry has a particularly heavy burden of non-production costs and it is the objective here to highlight and analyse a few of them. These costs are exploration expenditure, infrastructure expenditure, royalties and income tax. This is not to suggest that these are the only major non-production costs that the mining industry needs to bear. The industry may incur significant costs for environment protection, land tenure maintenance and on liaising with Government on a wide variety of matters. It is for reasons of subject manageability that the list is confined to the four costs mentioned. For the mining industry, exploration and infrastructure expenditure, royalties and income tax have several distinguishing features. Firstly, they are generally proportionately large costs. Exploration and infrastructure expenditure for example, could well exceed mine development costs. Depending on how royalties are levied, they may be very high in relation to profits earned and many in fact exceed profits. Secondly, except for income tax, they are costs that are generally not payable by other industries. Exploration expenditure is in some respects comparable with industrial research and development. However, because mines are wasting assets exploration is necessary for survival, and it is likely to form a larger part of costs per dollar of profits or sales than R&D. It can therefore be said that exploration is of far more significance to the miner than R&D is to the typical industrial company. Furthermore, unlike exploration expenditure, R&D results are transportable and patents permitting, transferable. The infrastructure burden that miners must carry is unique to the industry. Whereas urbanised industry is not usually liable for the capital cost of power, water, transport, townships and community facilities, the miner must finance these projects himself. Neither the payment of royalties, nor of course, income tax are unique to the mining industry. Royalties are more properly described as a unique charge on some primary industries but however described, they are a charge that manufacturing and service industries do not have to pay. Whilst we all pay income tax, the mining industry's uniqueness derives from the special problem that the industry has in arriving at annual net income in view of the capital intensity of the industry, partly due to expenditure on infrastructure, the indefinite life of capital equipment and its unpredictable residual value, funds expended on exploration and long lead times associated with a mine development. The third distinguishing feature of these costs is that, with the possible exception of exploration expenditure, they are heavily influenced by the policies and actions of Government. As such the industry has a responsibility to promote the industry by emphasising its potential to improve national product including exports and by requesting that the Government provide for the industry in its long term planning and seek its co-operation to prevent the industry incurring inequitable penalties relative to other industries.Finally, exploration and infrastructure expenditure are significant because they are front-end charges on a project. When due allowance is given the time value of money and the deferment of income from a mining development to which they relate, exploration and infrastructure expenditure assume greater importance than the raw money expenditure suggests. For all these reasons, exploration and infrastructure expenditure, mining royalties and mining income tax are worthy of detailed study. This is the purpose of this paper. The objective is to examine the determinants that give rise to them and provide some thoughts on their impact on on-going and potential mining developments and, where relevant, to make some suggestions as to how they may be minimised.

Jan 1, 1977

By G R. Ballantyne, M S. Powell, M Tiang

This paper reviews the proportion of energy attributable to comminution within the Australian gold and copper mining sector. The need for this is motivated by inconsistencies in the quoted energy usage data and the lack of a common basis for reporting the fraction of energy in mining that is attributable to comminution. This study should form a reliable basis from which to assess both demand and opportunities to reduce energy consumption.The proportion of milling energy was calculated for the major producers in the Australian gold and copper sector. A sampling methodology created by Powell et al (2003 - 2010) was initially used to provide an accurate and meaningful measure of the energy used in the comminution process. However, no useful method for grouping similar mines was found. Fortunately, a surprisingly large amount of high quality data was found from a number of different sources, allowing the development of robust relationships to be used to estimate a high proportion of the unknown values. The fraction of energy attributable to comminution was found to be dependent on how the total energy consumption was defined. For instance, comminution accounted for 52 per cent of the electrical energy, but only 21 per cent of the total energy publicly reported by the mines because a substantial proportion of energy used on a mine is in the form of transportation fuel (mostly diesel). Critically, the measured electrical energy consumption does not account for transmission and generation losses, while diesel energy usage is typically quoted according to its calorific value. This review proposes that diesel should instead be converted via the mechanical efficiency factor for diesel engines. Using this conversion, comminution was found to account for 36 per cent of the available energy on average. This approach allows a useful basis of comparison for mines regardless of whether milling energy is obtained from electrical or diesel generation. A summary of the results are shown in Figure 7 with other values obtained from literature. The total comminution energy assessed in this study accounts for 1.3 per cent of AustraliaÆs electricity consumption, this figure will increase as the other mineral commodities are added to the study.CITATION:Ballantyne, G R, Powell, M S and Tiang, M, 2012. Proportion of energy attributable to comminution, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 25-30 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By G Billing a, D Gribble, E Hall, D Varga

The theoretical benefits of electronic detonators have been reasonably well documented. To support this, a practical comparison was made between the performance of the standard shock tube system, NONEL, and a high precision electronic system, HotShotÖ, at the Sunrise Dam Gold Mine. The expected benefits from electronic detonators to Sunrise Dam were identified prior to the trial. Based on these, a number of objectives were set to demonstrate the value of the HotShot system. These are an improvement in fragmentation leading to an increase in productivity, less oversize rehandling, increased throughput and more uniformity in muck pile movement. To maintain the integrity of the trial, the nominal timing of the shots was kept exactly the same, thereby restricting any performance improvements to the precision of the electronics. Accordingly, adjacent shots were chosen with consistent geology. Video footage was taken of the blasts and vibration monitoring was carried out by fixed geophones throughout the mine. Spot heights of the muck pile swell were taken immediately after the blast and heave profile graphs were generated for comparison. Video footage was taken for a period of three hours for both shots to analyse cycle times of the excavator and trucks. PITRAM data was also collected for analysis. As far as practicable, the ore was taken to the same finger on the run-of-mine (ROM) pad to assist in single sourcing for the crusher and to allow oversize to be separated out. From specific metrics taken during the trials, it was shown that the expected improvements due to the high precision timing of electronics were realised in all areas.

Jan 1, 2007

By G King, Q Shu, W Cao, F Gyakwaa, H Singh, S Wang, M Huttula, T Fabritius

Metallurgical slag, such as refining slag, is essential to enhance or promote steel cleanliness. The CaO–MgO–Al2O3–SiO2 system is the primary source of oxides-based inclusions. It plays a vital role in applications in various pyrometallurgical processes. Numerous thermodynamic databases and physicochemical properties of slag studies mainly focus on quenched samples and measurements at room temperature. Consequently, the present study explored the physicochemical, structural properties and crystallisation evolution for CaO–MgO–Al2O3–SiO2 glassy slags via in situ hightemperature Raman spectroscopy and synchrotron X-ray diffraction. The study was carried out by synthesising CaO–MgO–Al2O3–SiO2 slag with varying Al2O3/SiO2 ratios. The results from the in situ high-temperature measurement demonstrated a pattern showing a transformation of a broad peak from the glassy matrix to crystalline peaks. The study showed crystallisation of dominant phases such as Ca2SiO4, Ca2Al2SiO7 and CaAl2O4 that correspond and are attributable to changes of structural units during in situ high-temperature measurements. The results further showed a correlation between an increase and transformation in crystalline phases observed from the spectra obtained from non-isothermal heating of the samples.

Jun 19, 2024

By U Rehm

The biggest hard rock double-shield tunnel boring machine (TBM) in the world, with a diameter of 12.4 m, is currently excavating the North-South Bypass, which includes a crossing under the Brisbane River, Brisbane, Australia, to relieve the often congested road traffic in the city centre. Ten years ago a 10.7 m Mixshield giant helped to handle the Olympic Games in Sydney linking the airport with the city centre for an improved transportation of fascinated visitors. In Shanghai, currently the biggest TBM in the world with 15.43 m diameter presents excellent performance rates; and in Paris a convertible Mixshield could be quickly changed from earth pressure balanced (EPB) to slurry type in order to handle the very heterogeneous ground conditions. In Madrid a 15.2 m EPB giant finished its tunnel job four months ahead of schedule. Large-scale TBMs have proved their economic and innovative potential to create the current and future underground architecture of mega-cities. TBM technology has made further large innovative steps in the last decade. State-of-the-art is a TBM for very heterogeneous ground conditions comprising hard and soft rock with additional high groundwater pressure. The machine concept is adapted to the various ground conditions and allows for a quick and flexible application. Ground treatment by means of additives developed to a helpful tool in this connection. To meet the special challenges of urban tunnel projects of nowadays it is of very high importance, beside applying highest developed technology of TBM, to have a comprehensive technical support during the project phase and to develop positive relationships between all participants of the project which last longer than only for one project.

Jan 1, 2008

The Mount Isa mine in North West Queens- land produces a total of nearly 10 million t/yr from separate copper and silver lead zinc orebodies. Sampling information is mainly obtained from diamond drilling on 30 to 40 metre centers in both types of orebodies. For the copper orebodies the majority of the core is analysed for copper content using a non-destructive bulk analyser developed by the Australian Atomic Energy Commission. The diamond drill core in the silver lead zinc orebodies is usually sam- pled as sawn half core and assayed in the com- pany laboratory using a variety of methods dependent upon the level of metal content and/or the elements required. Underground development is sampled where additional information is required to improve the ore reserve estimate. The copper areas are sampled using a standard 2.0 m by 2.0 m chip sample of the wall. The chips are taken on a 250 mm spacing. Lead areas are sampled using a 100 mm wide by 4 mm deep channel over intervals determined by the area geologists. The massive, irregularly shaped copper ore bodies are mined as large sublevel open stopes and pillars. Ore reserve estimation on both a production unit and global scale is routinely carried out using a geostatistical system developed in-house and running on a Sperry 1100 mainframe computer. Copper grade, tonnes and the Kriging var- iance are estimated at points on a user defined grid. The Kriging program uses 10 m assay composites from diamond drill core and underground chip samples. One average (rela- tive) variogram is used throughout the main copper orebodies. The validity of using an average variogram was verified by the original geostatistical study undertaken in the late 1970's.

Jan 1, 1987

This paper aims to provide some' new and original thoughts on tungsten carbide drill-bits and describe practices and performances, some of which are unique and most of which have not previously been described. Many theoretical and descriptive papers and articles on carbide bits have appeared during the last few years, and in the big majority conclusions such as these were made. These results are marked by premature failure of the bits, or The full or economic life of the bit is seldom reached due to the premature failure of the insert. Unfortunately those conclusions are seldom accompanied by the reasons for premature failure. In the few cases where reasons for failure have been advanced, very little, originality has been shown. The reasons usually given are that the failures are due to bad operators, bad workmanship, faulty steel or unsuitable machines, but it has been shown at Mount Isa that the chief reason for poor performnce is bad design.The first question asked will be, "What is wrong with the design of most bits?" and the answer'is, "The size of' the inserts". There may be many other small faults iiI different types of bit but Mount Isa experience indicates that the size of the insert is the most important factor influencing pit life. Under normal conditions it has been found, that there is a minimum size of insert that will give satisfactory performance, and this minimum is 5/16 in width and ? in. depth at the shoulder. A big majority of the bits at presentavailable in Australia do not satisfy these requirements.

Jan 1, 1953

The technological advancement in computing power and the increasing demand for information processing systems spread throughout many aspects of a corporation's business activities has revolutionised management information systems departments. This revolution is manifest in the proliferation of mini-computers and micro-processors as well as the planned or unplanned migration from centralised processing to distributed processing. The total data processing investment in people, hardware, software and telecommunications has reached a high level in many organisations. Therefore, the cost of inadequate planning or ad hoc growth of systems can be considerable. The concept of MIS systems planning has gained adherence in recent years; however, there appears to be a wide diversity in the effectiveness and quality of corporate systems plans. To be effective a systems plan must have the support and concurrence of executive management of an organisation. A disciplined planning approach to systems together ,with the involvement of senior user management as well as MIS management is necessary to develop a satisfactory systems plan that forms the basis of a corporation's data processing strategy.

Jan 1, 1980

By A T. Owen, F A. Benn, J D. Swift, D M. Labbett, A F. Grabsch

The AMIRA P266 æImproving Thickener TechnologyÆ series of projects has sought to provide a firm scientific basis for feedwell and thickener design, a requirement as pressures on water usage in the minerals industry increase. While advanced computational fluid dynamics modelling of feedwell processes has generated the most obvious and successful applications to improving the performance of operating units, such outcomes have drawn heavily on parallel studies into flocculation fundamentals. Central to this has been the development of a linear pipe reactor system that allows the kinetics of flocculated aggregate growth and rupture to be measured for thickener feeds under turbulent pipe flow conditions. This ensures much greater control of the intensity and duration of applied shear than is possible with conventional flocculation test procedures, offering insights into flocculation processes that would be otherwise hidden in time-averaged measurements.

Jan 1, 2009

By J Carswell, K McTyer

The Pajingo gold operation in Queensland is approximately 50 kilometres south of Charters Towers and 134km south-west of Townsville. The resource was discovered in 1983 and first open pit gold production began in 1986. The mine traditionally employed a bottom-up sequence – a combination of modified and traditional Avoca methods with run-of-mine waste backfill. This practice caused many high-grade crown pillars to be left in place, yet accessible. In recent years, these crown pillars have been extracted by injection grouting of rockfill. This process facilitated blind up-hole open stoping. To date, thirteen separate injection campaigns have been completed, of which ten were deemed successful. In general, the two key technical difficulties in this mining technique are: maintaining a consistent high-quality ground consolidation of the rock fill material; and controlling the drill and blast practices during stoping. Here, effective drill-and-blast control was found to be essential to achieve the dual aims of 100% extraction, and maximum sill pillar stability to minimise dilution. During stoping, the technical performance of the consolidated rock-fill was recorded; both to verify the design, and to identify operational improvements. The results showed that Pajingo has realised both reduced production down-time through use of early strength gain grout, and more rapid and thorough grout consolidation through changes to the emplacement method. The optimisation of consolidated rock fill has led to several quantifiable benefits to the mine, including: profitable extraction of previously sterilised crown pillars resulting in both increased ore reserves and production profile; improvements to the stability of grouted stope crowns, thereby reducing safety and production related; risks associated with open up-hole stopes; reduction in cost and time constraints, with respect to the grouting of loose fill; and reduction in grout curing time – from 14 days to 8 days – thereby minimising production down-time. This paper is a case study of the evolution and optimisation of the up-hole open stoping mining method at Pajingo. The challenges and successes are discussed in terms of their key mining outcomes. CITATION:McTyer, K and Carswell, J, 2018. Evolution of rock fill consolidation at Pajingo Gold Mine, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 66–77 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

By M S. Gallagher

In todayÆs high tech world, systems are getting bigger, faster, better. To remain at the leading edge, in any business, depends on accuratebut flexible design thereby allowing operational managers to providealternatives to improve their operations. The ultimate goal is to deliver to plan, with optimum economics. Mining is no different; with falling prices and escalating costs,improved margins become the focal objective. There are many ways toachieve this, ranging from operational efficiency improvements through production scenarios to planning initiatives. Of all, planning usually receives the least attention, yet it is the area of most influence on the Net Present Value (NPV) of the reserve. With computer technology, numerous concepts and iterations are possible thereby closing the gap between optimal and actual design. This paper discusses the application of the split shell design at the De Beers Venetia open pit in South Africa.

Jan 1, 2001

By R Brown

The Singapore Land Transport Authority Contract C917A is for the design, construction and completion of all outstanding works under the original Contract 917, including taking over the design and construction responsibility for the works carried out by previous contractor. Construction works connect the bored tunnels between the stations at King Albert Park and Sixth Avenue on the Downtown Line two in Singapore.The original contractor became insolvent leaving the works incomplete. On 29 August 2013 McConnell Dowell were awarded the completion contract following a fast-tracked tender process. The completion contract required a quick start and therefore the recruitment of some of the original workforce. A large majority of the original workforce was from Malaysia, Indonesia, China, Philippines, Bangladesh, India and Thailand. In order to ensure that the safety standards were upheld, and that the new workforce embraced a safety culture, a behaviour based safety (BBS) approach was implemented.The BBS approach was implemented to overcome the existing poor cultural safety behaviours, and to ensure that high standards and expectations for safety were implemented. This ensured that the workforce were comfortable in identifying hazards, avoiding shortcuts, and changing poor safety behaviours.This article outlines how a BBS program was delivered on the C917A project, containing defined goals, communication tools, and assessment and feedback models.CITATION:Brown, R, 2014. Behaviour-based safety with a foreign-based workforce, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 65–68 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

FaulIing west of the Mount Isa mine is described and is shown to be related to three groups of folds that have been recognized in the area. The first period of faulting postdates the first generation folding; these faulIs are regional faults (tectonic discontinuities) which are folded by second generation folds. The faulting accompanying the second generation folding divides the area west of the Mount Isa mine into four structurally and metamorphically identifiable blocks. The most prominent of these second generation faults is the Mount Isa Fault, which is characterized by a number of distinct zones of intense second generation folding and the presence of localized layers of mylonite. Only limited evidence for brittle deformation has been observed and the major movement appears to be associated with the plastic deformation of the rocks. Confined to the areas of second generation folding in the Mount Isa Fault are numerous third generation kink folds. A detailed description of the Mount Isa and other faulIs is presented together with evidence for their existence. The displacement accompanying this faulting cannot be established because of the complexity of the structure.Postdating these faults and all the folding of the area are minor cross faults.

Jan 1, 1973

By Saghafi A, Kelly M, Williams R. J

A two year program of research into the feasibility of long-hole drilling for improved gas emission control has been undertaken at Appin Colliery. State of the art equipment was employed involving cableless electronic surveying and down-hole motor drilling. The project involved the drilling of 1000 m long, in-seam boreholes in the Bulli seam and boreholes of similar length drilled cross measure and then in-seam along the underlying Balgownie seam. A new concept for gas drainage was defined, employing long-holes for both predrainage and post drainage.

Jan 1, 1988

By A J. Daniels

Macraes Mine is a large-scale open-cut and underground gold mine located in Central Otago, on the South Island of New Zealand. This paper presents the role of geological mapping in the grade control process at Macraes Open Pit as a case study, and demonstrates how systematic geological mapping can add significant value to the mining cycle. Geological mapping has proved to be a valuable foundation for orebody interpretation and analysis.Practical applications and lessons learnt are summarised, including predictive control of the orebody, improvement of geotechnical modelling, and identification of further exploration targets.

Aug 22, 2011

Pipe Jacking has been a recognised method of tunnelling in the U.K. since the early 1950's, although I understand that pipes were pushed blind by the soldiers in the first World War from trenches on the Allied side to, or adjacent to, trenches on the German side, thus allowing explosives to be used with a certain element of surprise! 'However, on its more conventional to the U.K. in the 1950's, Pipe Jacking made considerable inroads into the tunnelling market place as an alternative to timber supported headings. This success was, unfortunately, fairly short lived because, owing to its simple method of operation, contractors paid insufficient detail to the engineering (or surveying) aspects and as such the system soon had a bad reputation for unreliability and lack of accuracy. Due to these failings, the market was not exploited and, therefore, there was a lack of investment by contractors, pipe manufacturers and also by any client, or research organisation, which is client associated. The effect of this meant that the system stagnated for a number of years and was used generally only for short crossing work (i.e. railways, canals and motorways), and then only in good homogeneous ground. Albeit, a limited number of full scale sewage disposal contracts were carried out, but with the lack of knowledge and experience of the clients, contractors and suppliers, (particularly the pipe suppliers), no reasonable success, either physical or financial, was achieved on any such contract.

Jan 1, 1987

By Storey AG

Following initial plant scale work on the development and performance of 'spray' oil lances, a full scale room temperature model of the blowpipe-tuyere region of a blast furnace was built to study the basic aerodynamic features of auxiliary fuel injection procedures. Mobilwax 2305 was used as a substitute for Bunker C oil fuel in view of its similar physical properties and the fact that the atomised droplets could be frozen in flight and size, distribution analyses made for various operating procedures. It was shown that secondary atomisation processes far outweighed the importance of any primary atomisation procedures in determining mean Sauter Diameters particularly at high windrates typical of current blast furnace technology. It was also found that good spray dispersions across the blow pipe could only be obtaind for liquid fuels and that the lateral rate of spray dispersion was substantially enhanced by primary atomisation procedures. Mean particle diameters of sprays were found to be predictable on the basis of elementary stability theory and fell within the size range necessary for good combustion at all liquid fuel rates studied. The possible effects of high oil injection rates on flooding phenomena in the furnace bosh were considered. Comparisons show that high oil rates can lead to significant increases in the hanging factor (e.g. 'V 10% at 135 kg oil/thm) owing to increased gas flow rates/thm resulting from the presence of hydrogen.

Jan 1, 1975

By Hosking JW, Muir DM, Ruane M, Smith I. Hinchliffe WD

Maintaining carbon activity is critical to the satisfactory recovery of gold in the Carbon-in-Pulp (C.I.P.) process. Reduced activity can lead to gold losses in tails and lower tonnage throughput.Carbons from a number of W.A. C.I.P. circuits have been examined for the extent of fouling by inorganics such as calcium, magnesium, copper, nickel and silicon. Many of these carbons have exceedingly low activity leadingto low gold loading and excessive contact times. The relative importance of these fouling agents and cyanide levels on carbon activity is discussed. Mathematical modelling shows that relatively small improvements in kineticactivity lead to much lower tank volume require-ments and carbon residence times.

Jan 1, 1984

By Sullivan T. D, Lohe E. M

Geological structure is one of the main controls on ground conditions within mining. It has a significant impact on the mining conditions and productivity of coal mines within the Sydney - Bowen Basin. The three main types of faults common to this region, normal, reverse and strike-slip systems, each present distinct challenges to mining. These systems effect a wide range of geotechnical and mining conditions within the mines. These include coal quality, strata stability, goat and caving behaviour, productivity and maintenance schedules of mining equipment, mine design and mine-site stress fields. A better understanding of the regional, local and mine-scale structural setting, timing relationships of structural events and the mechanisms of fault formation will greatly aid industry's push for greater productivity and competitiveness.

Jan 1, 1991

By M Suzuki

Although several models for the surface tension of molten oxide slag have been proposed, suitably accurate predictions of this property are not yet possible. The surface tension, or surface excess free energy, of molten oxides is largely determined by the ionic coordination induced by surface relaxation. However, the associated mechanism of surface structural relaxation for molten oxide mixtures such as slag is complex and not yet fully understood. To allow a better evaluation of surface relaxation characteristics, the present work analysed the ionic coordination associated with the surface-relaxed states of several oxide mixtures. This work especially focused on calcium aluminate slags because these materials exhibit complex relationships between composition and surface tension. The effects of incorporating low concentrations of SiO2 as a surface active component on the surface ionic coordination were also examined. X-ray absorption techniques were used to assess oxygen and cationic elements in glassy samples after surface relaxation treatments, and molecular dynamics simulations based on a polarisable ion model of molten slag with vacuum/melt interfaces were also performed. The X-ray absorption techniques provided data related to electron yields (which are primarily associated with surface features) and fluorescence yields (which evaluate the bulk material). Thus, the ionic coordination characteristics of both regions were investigated. The results of molecular dynamics calculations allowed statistical analysis of the distributions of Al- or Sicentred polymorphs as well as the bond angles between cations and oxygen anions in the vacuumexposed and bulk regions in the equilibrated melt. The results indicated that bridging oxygen ions were preferentially distributed in the relaxed surface region rather than non-bridging oxygens. These bridging oxygen ions represented vertex connections between AlO4 or SiO4 tetrahedra. In the case of the calcium aluminate slags, the addition of one Ca2+ ion as charge compensation for two Al3+ ions was found to be necessary to form two AlO4 tetrahedra. This specific feature of surface ionic coordination could be responsible for the complex trends observed in surface tension data. The incorporation of low concentrations of SiO2 reduced the proportion of tetrahedrally-coordinated Al ions such that higher coordination states become dominant in the bulk of the material, whereas AlO4 tetrahedra were preferentially distributed in the surface region. SiO4 tetrahedra were the preferred Si-centred polymorph and were likely connected to one another to form bridging oxygen ions at the surface. On the basis of these results, a model to predict slag surface tension was proposed, and the energy of the formation of the ionic clusters resulting from surface relaxation was taken into account.

Aug 21, 2024