Search Documents

By Dance A

Highland Valley Copper recently implemented a system of measuring run-of-mine (ROM) ore properties and monitoring their effect on both mine and mill performance. These properties are principally ore hardness and size. For some years, Highland

Jan 1, 1998

By Offler R, Lau J, Lea J. F

The stratiform and vein-type pyritic silver-Iead-zinc-copper sulphide deposits of Sunny Corner, NSW are hosted by acid volcanic and clastic sedimentary rocks of Middle Silurian to Early Devonian age. The rocks have been subjected to low-grade regional metamorphism (prehnite-pumpellyite facies) and three phases of folding and four faulting events are recognised. Pyrite is intensely fractured, indicating brittle deformation. Chalcopyrite and galena exhibit deformation twins and slip planes indicating ductile deformation; sphalerite and chalcopyrite show straight and curved grain boundaries and dihedral angles of 120° as evidence of annealing recryslallisation. Sulphur isotope ratios for 22 samples from five deposits range from 1.7 to 10.7 per mil and average 7.4 per mil. Sulphur isotope data are similar to those from other stratiform sulphide deposits in acid volcanic rocks of Late Silurian age in the eastern Lachlan Fold Belt, especially Woodlawn and Captains Flat and together with other features of the mineralisation, suggest a volcanic exhalative origin for the Sunny Corner deposits.

Jan 1, 1984

By M Byrne, P Newman, M Lindqvist

SomincorÆs Neves Corvo Mine, one of the largest copper producers in Europe, is currently constructing a paste backfill plant in order to replace cemented rockfill in its bench and fill stopes and possibly replace hydraulic sandfill in the drift and fill stopes. A 250 m flow loop was constructed at the mine and the flow properties of various paste blends were investigated. Cycloned tailings and total tailings were both pumped successfully as pastes and were also combined with waste rock for additional testing. The pressure losses in 102 mm and 154 mm diameter pipeline were recorded at flowrates up to 60 m3/hr and are presented at slumps from 120 mm to 250 mm. The data showed the sensitivity of paste mixtures to slight changes in consistency, confirming the need for accurate control during paste production and distribution. The flow results clearly showed the different paste behaviour between cycloned and total tailings pastes and the change in properties at low and high slumps. In addition to pressure loss data, strength testing was done on 38 mm and 82 mm diameter samples. Further strength testing is ongoing at the mine using fly ash as a supplement to cement, reducing the overall binder cost. Preliminary engineering for the underground distribution system is briefly discussed, with reference to the siting of the plant. The Neves Corvo Mine is particularly shallow and alternative methods to pumping were sought in order to ensure sufficient hydraulic head for underground distribution. The comparison of options had to take into account the capital and operating costs, the operation of the plant and the impact on the future expansion of paste fill utilisation at Neves Corvo.

Jan 1, 1998

By N Davies, M J. Coward, P L. Hissey

Mount Isa Mines has four mining operations in Mt Isa with the X41 and Enterprise Mines producing copper and the Lead Mine and George Fisher producing lead zinc and silver. Each stream contributes ore to their respective concentrator at a feed rate and therefore metal ratio set out by the monthly schedule. Mine Planning and scheduling lead to a sales and operating plan (S&OP) and revenue projections which ultimately derives actual revenue /tonne and therefore cost/tonne. At Mount Isa, both the copper and lead/zinc streams produce ore from relatively new operations to be blended with material from more mature operations. It is critical to accurately predict the metal contribution from each operation in order to gauge the relative performance of each mine. Development mining ore contributions are estimated and reconciled, as are stope and bench sources. Performance is continually measured and assessed during extraction and grade adjustments are made to account for underbreak, overbreak and design modifications. It is critical to not understate or overstate the contribution from one operation relative to the other as this can produce a false picture of operational performance. Identifying process improvements are key to improving the business overall. Ore from the lead stream passes 17 measurement stations and two midstream reconciliation points before delivery to the heavy media plant (HMP), where the metallurgical circuit begins. From this point two concentrates are produced. A zinc concentrate for treatment off site and a lead concentrate for further on site processing. The lead smelter takes 100 per cent of Isa concentrates as well as a contribution from BHP-BillitonÆs Cannington Mine.

Jan 1, 2002

By D Judkins N OÆLoughlin

"Basin Minerals Limited commenced exploring for conventional strandline hosted mineral sands (rutile, ilmenite and zircon) deposits in the Murray Basin in April 1997. This has resulted in the discovery of a major mineral sands field in the Douglas Project area, located southwest of Horsham in the Wimmera Region of Western Victoria. After the successful completion of a pre-feasibility study on these deposits in September 2000, the Douglas Project has advanced to bankable final feasibility study. This study should be completed by mid-2002 to allow a decision to commence production in 2003 at an expected rate of in excess of 500 000 tonnes of combined mineral sands products per annum. The field comprises several mineralised strandlines. The main ones of economic interest are from west to east, the four strandlines, Acapulco, Bondi, Bondi East and Echo. These strandlines at August, 2000 contain total Inferred Resources of 443 million tonnes at 4.7 per cent HM at a one per cent HM cut-off; ie 20.8 million tonnes of heavy mineral concentrate which in turn contains 11.3 million tonnes of ilmenite and leucoxene, 1.3 million tonnes of rutile and 1.6 million tonnes of zircon. The heavy mineral concentrate is coarse-grained with mean diameter grain size of the strandline deposits ranging from 130 to 160 microns in size. Major controls on the formation of mineral sands deposits in the Murray Basin are discussed with reference to the main mineral sand bearing, strand plain domains; the Central Strand Plain, the New South Wales Strand Plain and the West Wimmera Strand Plain. The Douglas Project deposits on the West Wimmera Strand Plain domain are characterised by wide zones of mineralisation with high-grade cores (>10 per cent HM), low stripping ratios, and a valuable economic heavy mineral suite comprising 60 to 80 per cent of heavy mineral concentrate. Constituent mineralogy of the heavy mineral concentrate of the overall deposits is; ilmenite (40 to 58 per cent), leucoxene (five to seven per cent), rutile (four to ten per cent) and zircon (four to 14 per cent). The Douglas Project Area appears to be endowed with significantly enhanced levels of heavy minerals compared to other areas of the Murray Basin due to its unique palaeo-geographical position. Long shore drift to the south of the basin has caused large quantities of heavy mineral to be trapped against the palaeo-cliffs and headlands of a rugged palaeo-coastline which includes in a major embayment, the Grampian Mountains, the Black Range and the Glenelg Complex. To the east, major faulting and uplift has brought the fine-grained WIM offshore deposits close to the surface and has resulted in erosional stripping of mineralised strandline deposits. This mineralisation has been recycled and reconcentrated within the younger strandlines to the west within the adjacent Douglas Project Area. These strandlines are thought to be younger than other mineralised strandlines discovered to-date in the Murray Basin. The Project Area strandlines are described; ie their morphology, geology and patterns of mineral distribution. The mineralogy of each of the strandlines is distinctive and variations are noted along strike and section."

Jan 1, 2001

By G Chen

Magnesite and dolomite are two salt-type minerals. The surface characteristics of these two minerals are almost the same. It is very difficult to remove dolomite from magnesite ores by flotation process. The present study was performed to develop a new collector and a better flotation scheme for magnesite from dolomite. The flotation tests show that there exists a significant difference in flotability between magnesite and dolomite when dodecyl phosphate synthesised with dodecanol, phosphorus oxychloride and other chemicals is used as collector. Sodium silicate was used as the modifier to improve flotation selectivity. It was found that sodium silicate selectively depressed magnesite at pH 4.5 - 7.5. The separation of magnesite from dolomite was achieved in a reverse flotation which resulted in a 76.1 per cent yield of magnesite with a grade of 47.3 per cent at 100 ppm dodecyl phosphate and 75 ppm sodium silicate. The flotation mechanism was investigated by characterising surface electrical properties and measuring the adsorption density of the reagents on magnesite and dolomite.

Jan 1, 2005

By J Zhou, D M. Hunter, S M. Iveson, K P. Galvin

The recovery and concentration of ultra-fine iron ore can provide significant economic benefits. Presently, there are limited options available given the low settling rates achieved by conventional gravity separation and the relatively poor performance of reverse flotation. The Reflux Classifier is a new water-based gravity separation technology that consists of a set of parallel inclined channels positioned above a vertical fluidised section. This arrangement promotes a powerful throughput advantage compared to conventional fluidisation and a highly selective hydrodynamic basis for achieving sharp separations. A high shear rate develops within the inclined channels, which generates sufficient hydrodynamic lift to convey the lower-density particles (even if they are relatively coarse) to overflow while retaining the high-density particles (even those that are ultra-fine) for discharge to the underflow. The technology has previously been used around the world on particle sizes in excess of 0.1 mm. The present work, however, is concerned with density-based separations down to much finer particle sizes approaching 0.01 mm.A major advantage of the Reflux Classifier technology is the achievement of simultaneous gravity separation and desliming via a single-stage separation. A series of continuous experiments was conducted using an iron ore feed with head grade of 35 wt per cent FeT and nominal top size of 0.106 mm, with 59 wt per cent being below 0.038 mm in size. At a low throughput of 1.5 t/(m2 h), the Reflux Classifier produced high-grade products at a high recovery. For the entire feed, grades of 66.1 wt per cent FeT with Fe recoveries of 80 per cent were achieved in a single-stage separation. Within the 0.020–0.038 mm size fraction, grades of 68.8 per cent were achieved with iron recoveries of 94.7 per cent. Excellent recoveries of up to 57.0 per cent were achieved for the -0.020 mm size fraction. The ability of the inclined channels to retain the fine dense material further enhances the effectiveness of the Reflux Classifier by creating an autogenous dense medium effect within the vertical section. This helps to elevate large gangue particles up into the overflow.CITATION:Hunter, D M, Zhou, J, Iveson, S M and Galvin, K P, 2015. Gravity separation of ultra-fine iron ore in the reflux classifier, in Proceedings Iron Ore 2015, pp 143–148 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Medhurst TP, Trueman R, Hutchinson IN

A breaker line support (BLS) monitoring system, BLSmon, has been designed and constructed by the CSIRO and installed and commissioned at Laleham No.] Colliery, Queensland. This system was designed to record hydraulic leg pressure and canopy position measurements and relay these, in real time, to the surface. The system has shown itself to be capable of operating on the BLSs without any adverse affect on production. Analysis of the results of the monitoring exercise has shown that rate of change of leg pressures on the BLSs could be used as an aid in the prediction of adverse mining conditions. Under favourable mining conditions the supports were observed to initially unload from the set pressure, this unloading reduced with time and by the end of a typical lift cycle had either ceased or reversed slightly. This behaviour was considered to be due to one of four possible causes, these being; the compaction of floor debris, and/or compaction of the floor, and/or crushing of the roof and /or support creep. The actual cause can only be determined through detailed monitoring of both roof and support convergence. However observational data would suggest that compaction of debris and softened floor material beneath the supports was the most likely cause. The few positive loading rates recorded under these conditions were of short duration and occurred towards the end of individual lifts. Where mining conditions were unfavourable the negative rates of change of pressure, unloading of the support, were reduced throughout a lift, in both duration and magnitude, when compared with favourable mining conditions. Over the same period the positive rates of change were observed to be greater. The rate of change of loading and convergence can be utilised to identify the onset of instability in the lift area. However, before this facility can be utilised by the mine for the reliable prediction of instability more monitored data and sophisticated processing techniques are required.

Jan 1, 1992

By He BQ

Static attachment of bubbles to solids is contrasted with dynamic attachment in flotation cells. The times of contact during particle-bubble collisions in dynamic attachment are compared with the induction time determinations and the kinetics of thinning of the liquid films separating solids and bubbles. The thinning is examined mainly in terms of electrostatic and dispersion (van der Waals) contributions to the disjoining pressure existing in the films. The local heterogeneity (on a molecular scale) of charge distribution invariably present at all interfaces (even at conditions of zero zeta potential) calls for some means to minimize possible electrostatic repulsions which arise when the electrical double layer at the air-bubble interface begins to overlap that present at the solid surface, on encounter between particles and bubbles. It is postulated that dipoles of frother molecules, owing to their ability to "flip over" (polarise), replace localized electrostatic repulsion by attraction within fractions of a milli- second, as long as the structure of the frother molecules is sufficiently "bulky" to maintain diffuse films (of mixed collector-frother) at the air/liquid interface of bubbles. The relaxation times of dipoles (signifying their "flipping over" ability) have to be shorter than the collision times between particles and bubbles for particle-bubble attachment to be facilitated under dynamic Conditions.

Jan 1, 1984

By J Bang, I-H Jung

Ti is an important constituent for steels and superalloys. During the continuous casting process and ElectroSlag Remelting process (ESR), Ti in molten steel and superalloy can have chemical reactions with casting flux and ESR slag containing CaO and CaF2. In order to investigate such exchange reactions, the understanding of the (Ca,Ti//O,F) reciprocal slag system is prerequisite. In the present study, a coupled phase diagram experiment and thermodynamic modelling of the (Ca,Ti//O,F) reciprocal system was performed. In particular, the phase diagram of the CaF2-TiO2 system was experimentally investigated by Differential Thermal Analysis (DTA) experiment and quenching experiments followed by Electron Probe MicroAnalysis (EPMA) phase analysis. The Gibbs energy functions of all solid and liquid phases in the (Ca,Ti//O,F) reciprocal system were optimised to reproduce the present data and all available reliable experimental data in literature.

Jun 19, 2024

Magnesium-rich olivine is used as an additive in LKABÆs iron ore pellets in order to improve the high-temperature properties of the finished products. Olivine is only added to the pellets that are manufactured for ironmaking in the blast furnace process. The olivine comes from Minelco/LKABÆs mine at Seqi in Greenland. This dunite complex of Archean age contains about 95 - 98 per cent olivine. The grain size is typically 1 - 3 mm but much larger euhedral olivine crystals are common in the porphyritic type. The serpentinisation is absent or weak. The most common minor minerals are chromite, chlorite, talc, phlogopite, amphibole and pyroxene. The crushed olivine is transported to LKABÆs pelletising plants in Northern Sweden. After grinding, small amounts of olivine are mixed with the magnetite concentrate. The concentrate is rolled into green balls, about 10 - 14 mm in diameter. The moist green balls are transferred into the pelletising machine where the maximum temperature is about 1250¦C. The residence time in the pelletising machine is about one hour. Olivine is used in order to get pellets with better high-temperature properties. This paper deals with the olivine alteration during the pelletising process and the behaviour of magnesium following the decomposition of magnetite. The reactions are quite complex in the pellets because the physico-chemical conditions vary considerably in the process from one process step to another, and in the pellet bed from the top to the bottom. Some olivine particles in the finished product show very slight alteration, some particles are completely decomposed. The formation of the iron-rich coronas around the olivine particles is the most typical alteration. In the finished pellets the magnesium is mainly distributed between the following phases: unaltered olivine, coronas, Mg/Fe-ferrite and silicate slag.

Jan 1, 2008

Computational models are very useful for studying many of the physical mechanisms which can cause sample bias. Within such models we can predict the trajectories of all individual particles and thereby make observations which are not possible for physical systems. Physical mechanisms highlighted include congestion at the cutter aperture, particles bouncing over the cutter aperture, air drag on fine particles, waves of material being bulldozed off the belt by the upstream side of the body of square cutters, and particles being thrown by the leading edges of cross-belt cutter blades. Having identified relevant physical mechanisms for an existing cutter, we can estimate the extent to which they are likely to result in unequal representation of portions of a stream of material and thereby estimate the maximum likely sample bias.

Mar 1, 2010

By N Donnellan

The Palaeoproterozoic Warramunga Formation is notable as the host to the enigmatic, so-called 'Tennant Creek style' mineralisation. These polymetallic (but mainly Au-Cu-Bi) ore deposits typically have a close spatial association with massive ironstone bodies, and frequently also with banded ironstone, known locally as 'haematite shale'. The Warramunga Formation is a polydeformed, turbiditic succession. Partial, or complete Bouma sequences variously comprising lithic arenite, wacke, siltstone, and mudstone constitute a classic flysch sequence deposited as a proximal (sandstone lithofacies) to distal (siltstone lithofacies) fan association. The Warramunga Formation has a substantial component of volcanic detritus and has generally been attributed to an essentially contemporaneous volcanic provenance. However, lithostratigraphic revision (Donnellan, Hussey and Morrison, in press) apparently precludes outcropping volcanic rocks of the Tennant Creek Block, or indeed Inlier, as the source of detritus. Warramunga Formation geochemistry indicates rapid derivation from a fractionated, predominately felsic igneous source (Palaeoproterozoic upper crust) with a minimum of chemical weathering; together with an admixture of mafic material. Warramunga Formation geochemistry cannot, however, be reconciled with that of the Bemborough Formation, which is here taken to be representative of Flynn Subgroup felsic volcanic rocks. Similarly, the Warramunga Formation is geochemically distinct from Flynn Subgroup sedimentary rocks. Geochemistry of the banded ironstone is consistent with its interpretation as Dine-grained turbidites.

Jan 1, 1994

By Greaves J. N

The U.S. Department of Interior, Bureau of Mines, is investigating the treatment of refractory gold ores. Chlorination in the treatment of refractory gold ores is applicable in many low-grade gold operations. When usable, this treatment provides an economic means of consuming sulfides and deactivating disseminated organic carbon. Chlorination, however, is a pretreatment technique that requires the neutralization of the chlorine prior to leaching the ore with cyanide. Research by the Bureau has extended the present chlorination technology to allow for the recovery of gold without the use of cyanide and allow treatment of some ores presently deemed untreatable by gold operators using cyanidation or chlorination/cyanidation techniques. Chlorination without carbon of two carbonaceous ores extracted between 1 and 20 pct of the gold; however, carbon-in-chlorine (CICL) treatments resulted in about 90-pct recovery with a reduction in carbon loading. A statistical design campaign for stripping metallic gold from the carbon loaded in a chlorine environment demonstrated elutions exceeding 90 pct.

Jan 1, 1991

By N Van Buc, E Coroiu

The rapid socio-economic growth of Hanoi City coincides with a corresponding growth of the transport demand. Today, the transport in Hanoi is completely dependent on private modes of transport. Because of the lack of an efficient public transport system and the expected rapid increase in traffic volumes, the movement of people and goods in the urban areas of Hanoi will cause congestion in the present city transport network. The solution of the construction of new roads, or the widening of the existing streets, is very expensive in urban areas and usually causes many social problems due to the resettlement of people. From the point of view of the number of inhabitants, Hanoi City is now over one million. Above this number the international experience shows that the public transportation must be a mass transport system with large capacity, commercial speed and also independent as much as possible from the street network. According to the Hanoi Master Plan for 2020, the Hanoi urban population will be over 3.5 million persons. Also, in the next 15 years, the distances between centre-destination points will be doubled by comparison to 1995.

Jan 1, 1999

Knowledge of the crystal chemistry of carbonate apatites is very important for the development of the concept of biomineralisation and the creation of a scientific base for new biocompatible materials for medical purposes. The present work is devoted to research results on various synthetic and biological carbonate apatites obtained at Saint Petersburg University over many years. All-important problems will be considered such as the location of CO32- ions in the apatite structure, the ionic substitutions in various biological apatites and the development of synthesis methods for their analogues. Syntheses of apatites were realised by precipitation methods and under hydrothermal conditions (from solid compounds and by calcite treatment). Biological samples used in this study were physiogenic and pathogenic apatites formed in the human organism, eg in teeth and in renal and salivary stones and dental calculi as well as apatites from fossils of different taxonomic families (brachiopods, conodonts, fishes, reptiles, mammal) with different geological ages and burial conditions. The study of the crystal chemistry of carbonate apatites has been carried out by powder (including high-temperature measurements) and single-crystal X-ray diffraction methods, IR-spectroscopy, thermal analysis and various chemical analytical techniques.

Jan 1, 2008

By M Zoorabadi, B Hebblewhite, S Saydam, W Timms

Based on the cubic law, the hydraulic aperture of rock discontinuities has the most significant effect on the hydraulic conductivity of jointed rocks. The hydraulic aperture of rock discontinuities is a stress-dependant parameter and reduces with increasing applied stress. Furthermore, the rock stress increases with increasing depth. Therefore, hydraulic aperture is a depth-dependant parameter. In this paper, new empirical equations are introduced to calculate the hydraulic aperture of rock discontinuities at different depths. These equations were developed on the basis of back analysis of compiled packer tests from different actual cases. They provide the capability to calculate range of variation and average hydraulic aperture when the orientation of discontinuity and field stress tensor are given. Furthermore, it is possible to calculate the hydraulic aperture of rock discontinuities when its value is given for another depth. A hydraulic aperture of 7.7?µm was calculated by this method, comparing well with a reported site value of 8.3?µm for rock discontinuities at the Stripa mine project at a depth of 385?m. These new equations can be used by analytical or numerical methods to estimate the hydraulic conductivity of jointed rocks.CITATION:Zoorabadi, M, Saydam, S, Timms, W and Hebblewhite, B, 2014. New empirical equations to estimate the hydraulic aperture of rock discontinuities at different depths, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 375–380 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By N K. DavT, A Coggan

The performance of in situ, shallow water covers in controlling acid generation was evaluated at four recently decommissioned pyritic uranium tailings sites at Elliot Lake, Ontario, Canada. The tailings are acid generating, having a pyrite content of approximately five to ten per cent and a very low to non-existent alkaline buffering capacity. Adverse market conditions led to the closure of all operating uranium mines in the early- to mid-1990s, followed by rehabilitation and decommissioning of mine and waste management facilities. In order to control acidic drainage, all new and active tailings areas at Denison, Quirke, Panel, Spanish-American and Stanleigh mine sites were re-engineered to provide in situ submersion of these tailings under shallow water covers. The tailings impoundment dams were upgraded and reinforced or in some cases reconstructed, to minimise seepages and provide a minimum 1 m depth of water cover. With the exception of Stanleigh mine, which was closed in 1996 and rehabilitated during the late-1990s, the water covered Tailings Management Areas (TMAs) at other sites have been in operation for a period of six to nine years. The surface water quality at these sites is maintained at near neutral pH conditions by periodic addition of lime slurry to the established water covers. Additional treatment of effluent is provided as required to meet the discharge water quality standards. The performance of the established water covers at the sites was evaluated by analysing the annual equivalent limestone consumption data. The results were compared with the performance of an older, decommissioned Nordic TMA, which was rehabilitated using revegetation techniques. The water covers at these sites are performing as designed and acid generation has been reduced to low levels. Based on the total amount of yearly equivalent limestone required to maintain water quality in the water cover and at the effluent treatment plant, it is concluded that acid generation rate at the Denison TMA has reduced to less than 0.15 per cent of its pre-water cover conditions during normal operation and rehabilitation periods. In comparison to the revegetated Nordic TMA, the acid generation rates at Denison and Panel TMAs have decreased to less than 1.6 per cent of that at the Nordic TMA. The acid generation rate at the Quirke TMA was comparable or only slightly lower than that at the Nordic TMA because of its unique terraced cell configuration, having tailings in five hydraulically interconnected cells at different elevations. Historic acidity and oxidation reaction products, accumulated during normal operating and pre-water cover periods, are flushing from upstream locations to downstream cells, thus requiring much higher equivalent limestone additions for acid neutralisation and effluent treatment.

Jan 1, 2003

By M Nehring, M Kizil, P Knights, A Mousavi, F Sotoudeh

A cut-off grade is used to distinguish an economically viable block of ore from non-economical ones in mining operations. In order to obtain a high Net Present Value (NPV), a strategic and precise determination of cut-off grades (mill feed/marginal, marginal/waste) is required. In recent years, the significant depletion of feed grades and increasing mining operating costs have affected the viability of new and existing mining operations. Hence, the introduction of a pre-concentration system to process ore before sending it the main processing plant has gained increasing attention for its potential improvements in resource exploitation processes, mineral processing, energy consumption and environmental impacts. The primary potential advantage of implementing a pre-concentration system is the improvement of resource utilisation and increased reserves as a result of a reduction in cut-off grade. The objective of this paper is to present a new cut-off grade method, which can be used in the presence of a pre-concentration system for underground metalliferous mining operations. The results of this study illustrate the potential economic benefits of using a pre-concertation system prior to a mineral processing operation as a result of the reduced cut-off grade and increased NPV.

Nov 10, 2020

By A Jyoti, J R. Black, R R. Haese, E O. Ansah

Copper (Cu) is a critical metal in the transition to a low-carbon power supply. Presently, low-grade copper sulfide ores account for almost 80 per cent of the global reserves. Large amounts of water are required to process these low-grade copper ores. The mining industry utilises lixiviants from recycled water from different sources to conserve water, whilst enhancing Cu recovery. Some utilise intermediate to pregnant leach solutions, sea water, and processed water from electrowinning circuits with highly variable concentrations of ions. Previous studies have highlighted the formation of precipitates that passivate the surfaces of minerals in these low-grade copper ores and/or block flow paths for lixiviant during heap leaching. In this study, we utilised concepts of phase replacement to devise an innovative means of controlling precipitation and increasing copper recovery using industrial brine as opposed to freshwater. We propose the formation of Al-rich phases (such as AlSO4 + or alunite) to replace iron sulfate and iron hydroxysulfates (such as jarosite) during the chalcopyrite dissolution-precipitation mechanism. The rationale is to have available Fe3+ throughout the chalcopyrite leaching process. We tested this method by carrying out various batch experiments using CaCl2, AlCl3, and NaCl industrial brine types compared to freshwater and explored the capacity to leach Cu from chalcopyrite. There is higher Cu recovery during oxidative leaching of chalcopyrite in industrial brine with 91 per cent recovery using AlCl3-rich brine, 84 per cent with NaCl-rich brine, and 56 per cent with CaCl2-rich brine as compared to 35 per cent recovery using freshwater. In the absence of Al3+, various forms of iron sulfates, and jarosite are formed, reducing the availability of Fe3+ for chalcopyrite dissolution. The introduction of Al3+ leads to the formation of AlSO4 + species, thus lowering sulfate activity and the tendency for K-jarosite formation.

Aug 24, 2022