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By K. Hardy

As part of Inco's $115 million Fluid Bed Roaster SO2 Abatement Project, a new weak acid treatment plant (WATP) was constructed to treat bleed solutions from the Copper Cliff Smelting Complex gas-cleaning circuits. The WATP produces an iron-arsenic co-precipitate, termed "basic ferric arsenate" (BFA), which requires disposal in an environmentally acceptable manner. Following analysis of many potential options, the short-listed disposal alternatives were: A) Co-disposal of the BFA?gypsum sludge with rock tailings, a portion of which would be used in mine backfill, with the remainder being sent to the tailings area, and B) Co-disposal of BFA?gypsum sludge with pyrrhotite tailings in the tailings area. Testwork showed that the addition of BFA?gypsum sludge to mine backfill samples increased the uniaxial compressive strength (UCS) of the backfill for most samples, especially those at lower binder content ratios. Extensive analysis was conducted on samples taken from the Copper Cliff tailings area, where BFA?gypsum sludge from Inco's Copper Refining Electrowinning Department has been co-deposited with pyrrhotite tailings since 1990. Pore water samples from these areas contained very low arsenic concentrations, indicating that the arsenic had remained stable in that environment. Ultimately, co-deposition with pyrrhotite tailings was chosen as the preferred option for the disposal of BFA?gypsum sludge from Inco's new WATP.

Jan 1, 2006

By Thom Mambe, Angelo Fernando

The objective of this work was to identify key parameters related to the reduction of the sulphur content in ammonium diuranate (ADU), and the identification of solid products being formed under various operating conditions. A laboratory-scale, continuous ADU precipitation circuit was assembled using a glass reactor vessel immersed in a temperature-controlled water bath. A pre-prepared uranium feed solution was fed continuously using a peristaltic pump. Anhydrous ammonia mixed with compressed air was metered and pumped using a double-headed peristaltic pump. An over-head mixer was used to keep the solids in suspension. The precipitated ADU slurry was removed from the reactor at the same flow rate as the feed solution. The slurry was sampled to generate ADU solids for chemical and physical analysis after four hours of continuous operation to ensure steady-state conditions. The following variables were studied to determine their influence on the sulphur content in the resulting ADU. (a) sulphate:uranium molar ratio in the reactor (1:1, 1:5, 1:10 and 1:20) (b) precipitation pH ( pH 6, 6.5, 6.9, 7.5 and 9) and (c) precipitation temperature (40C and 60C) A total of 18 tests covering the above parameters were conducted, and the results indicated that the sulphur content in the resulting solids was highly dependent on the reaction pH. Out of the pH levels tested, tests completed at pH 6.9 and 7.5 generated solids containing the lowest sulphur contents, between 0.5 to 1.5% S uranium basis (UB). The sulphur content in solids was found to vary linearly with the sulphate:uranium ratio in the feed solution, showing a statistically valid correlation. The impact of temperature was minor between 40°C and 60°C, with a slight advantage at higher temperatures. Tests at a sulphate:uranium ratio of 1:1 produced solids with the lowest sulphur contents. The influence of pH or temperature on sulphur content in solids was almost non-existent at this sulphate:uranium ratio. Precipitation pH is the major factor influencing ADU sulphur content, followed by the uranium to sulphate ratio.

Jan 1, 2020

By A. I. Collins, D. Danninger

Newmont has installed advanced control and online optimization on the dry grinding circuit and both roasters on its Carlin Trend refractory ore treatment plant. Subsequently, Newmont has developed a master plan for institutionalizing advanced control and optimization on all its processing units. Newmont is committed to a program of applying advanced control and optimization from crushing of ore to pouring of gold. This paper describes Newmont's experience with implementing advanced control and optimization and the benefits received. In addition, identification of advanced control and optimization opportunities and their economic justification is discussed.

Jan 1, 2005

By J. Suarez Condezo, E. Herrera Alarcon

The Ilo Smelter Modernization Project will require treating the slag from the Peirce Smith converters in Slag Cleaning Furnaces using pig iron technology. Currently the slags from the converters show variable magnetite contents. The copper contained in this slag is recovered in Reverberatory Furnaces, where the smelting rate was improved due to the high silica content of the converter slag. Preliminary industrial tests where developed to clean the slag from converters using pig iron. The results showed that the magnetite content has a significant influence in this process. This work describes the actions that are being implemented in the converter operation to control the magnetite content in the slag in order to maintain the high copper recovery of the smelter when the new facilities are commissioned. This task will demand a strong control of both the slag chemistry and converter practices in order to get the copper recovery considered as the design criteria (~97.4%).

Jan 1, 2007

By P. A. Bahri, D. G. Dixon, T. M. Woodward

A comprehensive mathematical model of the Sherritt-Gordon ammoniacal pressure leaching process at K winana Nickel Refinery has been constructed. The process is comprised of six autoclaves functioning as a three-stage leach circuit, operating over the temperature and pressure ranges of 85-95°C and 750-1000 kPa, respectively. The process chemistry forms a complex series-parallel reaction network, characterised by: (1) the gas-liquid mass transfer and reduction of oxygen, (2) the oxidation of eight distinct minerals, (3) the oxidation of sulphur, and successive reactions involving various intermediately oxidised sulphur species, and (4) the oxidation of Fe(II) to Fe(III), and subsequent precipitation as a hydrated ferric oxide. Material balances were developed for species in all three phases, and an energy balance to account for all reactions and phase conversions. The multiple convolution integral (MCI) statistical reactor model was employed for the scale-up of particle kinetics. The model has been validated against plant data, and simulation results are in agreement with plant performance.

Jan 1, 2005

By Jerry Ran

When multiple levels are mined in open stope mining with delayed backfill, mining underneath fill is inevitable to achieve higher rate of recovery if no sill pillars are left for the purpose of fill separation or partial ground support. This is particularly true when the orebody has low reserves per unit vertical distance. Instability of the exposed fill back causes stope dilution, production delay and possible equipment damage and consequently increases the mining cost. Previous studies have concentrated on fill mat stability in cut-and-fill and stability of fill walls in open stope mining. Workers are exposed to the fill back in cut-and-fill and therefore smaller open spans are normally adopted and the fill mat is reinforced. In open stope mining openings with large spans are designed, workers are not exposed to the fill back and its stability has to be maintained by fill of sufficient strength. However, the required fill strength is normally determined by considering different modes of fill wall failure. The fill back stability is usually not analyzed in the fill design process. The lack of analysis on fill back stability for open stope mining is mainly due to difficulties in relating the fill properties to the fill and stope geometry. In this paper a simplified wedge model is adopted to analyze stability of the exposed fill back in open stope mining with consolidated backfill. The proposed method calculates the factor of safety of the fill back against shear failure under known fill and stope geometry and fill strength parameters in order to assess the fill back stability. It can also be used to determine the required fill strength with known fill and stope geometry. The proposed approach is indirectly validated by mining experience and observations at two operating mines. In addition there are many factors affecting the fill quality and stope configurations in an operating mine. These factors have to be considered in the analysis of fill back stability. This situation is highlighted by presenting an actual mining case where the fill back failed due to factors commonly encountered in mining operations.

May 1, 2003

By T. A. Rickard

FROM AN OLD MANUSCRIPT THE text for this contribution to the history of the Patio process is a page taken from a Spanish manuscript of Bartholomé Arzaj Sanches y Uela, now in the possession of the library of Brown University (see Figure 1). I owe the photographic print to the courtesy of the librarian. The date, as will be seen, is 1577. The subject is the treatment of silver ores at Potosi, in old Peru, but in modern Bolivia. The group of drawings (see Figure 1) is entitled "Arrangement of the machines in which the ores of silver are ground on the bank of Potosi, the one of two batteries and the other of one". First, top-left, we have the sketch of a "machine of one battery" operated by a water-wheel. From this mill the water runs in part along an aqueduct supported by pillars to the two-battery mill and in part down the hillside, where men are at work with "tubs, which are called cochas, in which are washed the charges of ore and amalgam". Along the top of the page are shown the "various offices in which are stored the copper, the salt, the ucha [llama dung, used for fuel], the lime, and other materials for the re-duction of the ores". To the right of these are "apartments and warehouses in which is stored the ore brought down from the mountain"?the cerro de Potosi. Through the arched portal come the "sheep [llamas] on which is brought down the ore". To this is added a reference to "the second gate, which closes the whole works". On the level above the aqueduct are seen six men carrying skin-bags that contain water. This is being sprinkled on the ore. On the extreme right are six more of these water-carriers. Next comes the two-battery mill. The mortero, or mortar, is marked on the right. Another description says, "Stone, on which the stamps crush the ore, which is called a mortar". To the left of these are indicated "screens of wire in which the ore is sifted after it has been crushed". Farther to the left, near the ore-washers, is a "shed, in which is placed the metallurgist to test the ore of the boxes". Along the left side of the page are sundry buildings, one of which is labelled a "shed in which are placed the cones of silver". Near it, lower, to the right, is the "furnace, in which are roasted the sulphides to facilitate treatment". Farther to the right is the "place where the Indians mix the charges of sulphide ore, which is called a buitron". Alongside is a "buitron in which the charges are prepared for reduction". Inside is a container, to which are attached the words "measure, called topo" On the extreme right is "another buitron in which the Indians mix the ores with their feet, as well as the heaps for the preparation of the reduction". Near the bottom, on the extreme left, is the "chapel where the holy sacri¬fice of the mass is celebrated". Under the first buitron is the "place where they dry the moist ores, called pãpear".

Jan 1, 1935

The Santa Rita mine is located in north eastern part of Bahia in Brazil and is owned and operated by Mirabela Mineração do Brasil Ltda. Typical SABC circuit was designed as the preferred option for the 4.0 mtpa (500tph) to produce a P80 of 125um for flotation. Although the SAG was originally designed to operate with conventional radial pulp lifters, later it was fitted with Outotec?s Turbo Pulp Lifters ? TPL (Latchireddi, 2005). The milling circuit commenced commissioning on the 24th of October 2009 and the milling circuit achieved the nameplate capacity within days. with small and relatively simple measures to rectify. Since commissioning, the SAG mill has been working in fully autogenous grinding (FAG) mode with no balls (in contrast to the estimated 10% ball charge) and has been consistently treated up to 650tph. This paper examines the comminution design process, the operating philosophies, start-up experiences, post commissioning optimization and future development works. An evaluation of mill performance relative to the design criteria for the project life to date is also included.

Jan 1, 2012

By Julian V. Simela

Conventional methods of underground surveying use theodolites/total stations and 3D laser scanners to obtain information about the underground environment. Current methods of geo-referencing these instruments to a mine reference system include triangulation, trilateration and resection. However, despite technological advancements, surveying procedures have remained slow, laborious and relatively unchanged during the last half-century. Recent innovations in the robotics community have shown that automated mapping of underground mining tunnels can be undertaken using 2D/3D laser scanners. These techniques have the potential to, in turn, improve upon current underground surveying and mapping methods. Automating surveying and mapping using current surveying tools without changing the setting up procedures or removing current constraints, or even changing the type of equipment used, does not change the status quo. The problem of moving from a static, tripod based surveying and mapping system to an unconstrained mobile surveying and mapping system is the subject of this paper. A current challenge for automated mapping is the ability to automatically geo-reference a mobile mapping system to a mine reference system. For a mobile mapping system that uses a horizontally mounted 2D laser scanner to gather data of the underground environment, the challenge of determining its position and orientation within the mine environment is magnified even more. This paper introduces Mobile Automated Scanner Triangulateration (MAST), a technique under development at Queen?s that is designed to geo-reference a mobile mapping system to a mine reference system for the purposes of underground mine surveying. MAST quickly and automatically determines scanner 2D position and orientation (azimuth) in a mine reference frame by using minimal human input.

Aug 1, 2013

By B. K. Mishra, Avijit Biswal, B. C. Tripathy, Abhijeet Singh, K. Sanjay, T. Subbaiah

We studied theeffect of anode substrates such as pure lead (Pb), lead antimony (Pb-Sb), and lead-silver (Pb-Ag) on the structural and electrochemical properties of electrolytic manganese dioxide (EMD). X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and chemical analyses were used to determine the structural and chemical characteristics of the EMD samples. The charge-discharge profile was studied in 9 M KOH using a galvanostatic charge-discharge unit. In all the substrates the current efficiencies were more than 99% except with Pb-Sb where it was 90%. Results revealed the nature of the substrate strongly affected the morphology of the deposited material which in turn affected the electrochemical properties of the EMD samples. XRD analyses revealed that the nature of the anode did not affect the crystal structure of the deposited EMD and all the samples were predominantly ?-MnO2, which is electrochemically active for energy storage applications. The EMD deposited on lead substrate showed superior discharge capacity of 245 mAhg-1 when compared with other substrates.

Jan 1, 2014

By H. P. Dibbs

An account is given of the application of neutron activation analysis to the rapid, non-destructive determination of copper in minerals, using a 14-MeV neutron source. Elements that interfere in the determination of copper by this method are given, together with the errors in the estimation of copper that result from the presence of varying amounts of these elements. The possible use of a compact "sealed-tube" 14-MeV neutron generator for the field assay of copper in minerals is discussed.

Jan 1, 1970

By J. Jerome MacDonald, Stephen B. Flewelling

"In the base metals industry of today, operations required to continuously improve productivity and reduce unit production costs. Consistent with these goals is the improvement of the muck haulage cycle from open stopes with the No. 12 Mine.Existing haulage from open stopes occurs with LHD units experience at Brunswick indicates that LHD units have a higher unit cost per tonne mucked than loader-truck combinations when the haulage exceeds approximately 150 m.The reintroduction of open stoping at Brunswick made existing loader-truck combinations unsuitable. It was recognized that application of recent continuous loading technology could potentially result in significant unit cost savings and productivity increases.A review of the technology resulted in the testing of the Voest Alpine AL60 loader in the open stopes located on the 1000m Le vel. Testing began in January 1988 and finished in late November 1988. The test will provide experience as well as quantified production and maintenenace parameters f or the purpose of quantifying production unit costs and system productivity, ultimately resulting in a decision to further utilize or not utilize the loader as a primarymucking unit at Brunswick .INTRODUCTIONBrunswick Mining and Smelting Corporation Ltd. produces approximately 10500 tonnes per day from the No. 12Mine located 35 km southwest of Bathurst, New Brunswick Mining is the largest (single mine) producer of zinc in the world having mined over 52 million tonnes since 1964. Many years of production still remain with proven and probable reserves in excess of 90 million tonnes. Reserves grade at an average of 3.65% Pb. 8.99070 Zn, 99g/mt Ag and 0.32% Cu . The operation employs 1446 people with approximately 800underground including operations and maintenance staff.In the No. 12 Mine two major mining methods are presently utilized . The primary method is Mechanized Cut and Fill (MCF) accounting for approximately 6500 tonnes per day from four major areas. The remaining 4000 tonnes per day is produced from open stopes with the majority of 2800 tonnes per day being produced by the 1000 level.The 1000Level contains 30 million tonnes segmented into open stope blocks 30 m high, 15m and 30 m on strike , with a transverse width of 10m to 50 m (Fig. I). Stopes are organized on a primary secondary stope arrangement along strike. Primary stopes are undercut and overcut full size with the back fully cablebolted. All stope and lateral development is driven 4.0 m high. All stopes to date are flat bottom (Fig. 2). Primary stopes are filled with cemented rock- fill , secondaries with conventional rockfill, Haulage from the stopes is primarily with 8-yard LHD units ; mucking is approximately 50% conventional and 50% remote. Haul distance to date has averaged approximately 150m with current stope haul distances of approximately 300m. Haulage is presently to a small jaw crusher situated on the 1000 Level. From August 1989on, haulage will be to a set of ore passes feeding to a large gyratory crusher situated on the 1200 Level. Start up of the gyratory crusher corresponds to an increase in tonnage from 1000 Level to 4100 tonnes per day."

Jan 1, 1989

By C. Hudson, D. Tremblay, A. Frey

"A discussion of the design, challenges and successes associated with the commissioning of the gravity recovery circuit at Canada’s newest open pit gold mine - Atlantic Gold’s Moose River Consolidated Project in Nova Scotia, Canada is presented. An overview of the project, its historical significance and overall flowsheet is provided with special focus given to the design and selection of the gravity circuit equipment including the scalping screen, gravity concentrators and the novel intensive leaching technology selected for the project. The performance of the gravity circuit is benchmarked against the feasibility study process design specifications and the outcomes are discussed. Challenges encountered during commissioning are also presented, including the use of third-party automation and the effects of screen sizing on overall gravity circuit performance. Mechanical modifications made to the Sepro Leach Reactor for the Moose River project are also discussed. A detailed technical review of the mechanical and operational aspects of the Sepro Leach Reactor is provided with key operational data on leach times, recoveries, reagent usage, solid-liquid separation, pregnant solution quality and its influence on bullion purity.INTRODUCTION Atlantic Gold Corporation’s Moose River Touquoy Mill in Nova Scotia, Canada was commissioned in the fourth quarter of 2017 with commercial production declared in March of 2018. The 2 Mtpa process plant uses a conventional, gravity-CIL process. This site was previously mined in the 1870s. Interest waned in the early 1900s but resumed in the 1930s and the mine was brought back into production in 1935 until an underground mine collapse in 1936. This mining district became famous after CRBC radio commenced a ground breaking, around the clock, broadcast of the rescue operations. Over 100 million people listened to the broadcast from Canada, the United States and the United Kingdom. These broadcasts changed radio, transforming it from a medium for music to on the spot, breaking news reporting. The mill was constructed by Ausenco on a fixed price EPC contract in the historic Moose River gold mining district, 95 km north-east of Halifax by road. The mill will process ore from the adjacent Touquoy pit for the first 5+ years of operation; after the Touquoy reserves are exhausted, the mill will process ore trucked 37 km from the Beaver Dam deposit for an additional 5 years."

Jan 1, 2019

By Alyson Morley

The mining sector in Canada is facing significant challenges to develop a competent workforce, including increased technical and logistical operational demands, and the imperative to promote local content. There is an increasingly unpredictable labour pool which can be aging, or have skill shortages, or non-aligned skills. As globalisation continues, companies also require efficiencies during operation across various locations. AMEC has met these challenges in the global oil and gas sector by developing our Capability Development and Competence Assurance (CDCA) program. CDCA is applicable across all process industries, including mining. CDCA supports simultaneous consistency and flexibility by defining competence at task level, with corresponding best practice blended training programs, and evaluation criteria and processes. CDCA then defines role profiles mapped to local task definition. When combined with web-based technology, this granularity allows us to manage high volume workforces, while retaining individual learning plans and progression, aiding job satisfaction, and employee retention.

May 1, 2007

By Q. G. Reynolds, R. T. Jones

The choice of furnace design parameters has a marked effect on the integrity of the furnace that is constructed. The design methodology for DC arc furnaces typically begins with the chemical reactions and feed materials that define the process. The specific energy requirement of the process, and the feedrates of the raw materials largely determine the power requirement for the furnace. A chosen value for the 'power intensity' sets the diameter of the furnace. Justification is provided for why this is a good choice of scale-up parameter. Equations are presented to quantify the resulting trade-off between thermal efficiency and the degree of error that can be tolerated in the balance between power and feedrate. This improved understanding should provide a better rationale for selecting an appropriate power intensity (or furnace diameter) for future furnaces.

Jan 1, 2015

By V. G. Papangelakis, A. Dani

"Alkaline pressure oxidation, particularly in the presence of trona as additive, can be used to oxidize high carbonate refractory gold ores as it prevents the formation of CO2 in the autoclave. However, the presence of silica in the ore can lead to the encapsulation of pyrite due to the solubility of silica in alkaline solutions and its subsequent reprecipitation on the reacting pyrite surface, leading to the formation of a passive layer. This fundamental study investigates the chemical composition and thickness of the passive layer on a rotating pyrite disk using XPS and SEM, as a function of process conditions at 230°C, in an aqueous slurry containing silica sand, sodium carbonate and calcium carbonate under 100 psi of oxygen overpressure.INTRODUCTIONAlkaline pressure oxidation (POX) has been used successfully to treat high carbonate refractory gold ores, which contain carbonates in addition to sulphides, most notably at Mercur and Goldstrike mines operated by Barrick Gold. There are several advantages to using alkaline POX over its acid counterpart, especially due to high carbonate content. First, it eliminates the production of CO2 in the autoclave without resorting to pre-acidification, which allows for high oxygen utilization. Second, alkaline POX suppresses the formation of elemental sulphur and intermediate sulphur oxyanions (such as thiosulphates and dithionates), which reduce gold recovery. Third, the use of sodium hydroxide or salts prevents the formation of anhydrite scale by forming soluble sodium sulphate. Other advantages are the use of cheaper materials of construction and the formation of non-acidic residue that do not require further treatment prior to cyanidation (Thomas, 2005).Sodium carbonate in particular is a promising reagent for alkaline POX because it was shown to significantly accelerate the kinetics of pyrite oxidation by molecular oxygen, when compared to other reagents such as sodium hydroxide, sodium borate and calcium hydroxide. This has been attributed to the following factors: a) the faster oxidation kinetics of Fe2+-CO3 complexes compared to Fe2+ oxidation, b) the buffering effect of carbonate ions on the acidic pyrite surface, and c) the increased solubility of oxidizing Fe(III) species due to carbonate complexation (Caldeira, 2010)."

Jan 1, 2012

By T. L. McCall

A short description of mining practice in the Sydney coal field in general is followed by a discussion of the operations in the No. 12 colliery of the Dominion Coal Company, Limited, as being typical of the trend in operating methods obtaining throughout the field. Development of longwall mining to the present system of three walls in line is outlined, together with a summary of the cycle of operations involved in systematic operation.

Jan 1, 1944

By Wei Huang, Anh V. Nguyen

"Potash flotation is an industrially proven success of flotation of soluble salts, but its collector adsorption mechanism remains elusive. In this paper, specific ion effects in NaCl-KCl flotation with carboxylate collectors were investigated. Flotation recovery and contact angle were determined as a function of brine composition of NaCl and KCl. The experimental results have shown that wettability of KCl and flotation of the soluble salts with laurate collectors were dependent on brine ion composition. Specifically, adding Na+ to brines decreased hydrophobicity of KCl crystals and their flotation recovery. Both KCl and NaCl could be floated with laurate collectors. However, flotation of NaCl was greatly enhanced by adding K+ to brine whereas flotation of KCl was significantly suppressed by the presence of Na ions. The decrease in KCl recovery upon adding Na+ is attributed to the counter-ion binding in the pulp. The flotation recovery enhancement of NaCl in the presence of K+ is explained by two effects: 1) increasing K+ concentration leads to a better dispersion of collector colloids in the pulp and 2) K+ enhances the collector adsorption at NaCl crystal surfaces. The water affinity matching rule can explain the specific ion binding behaviors and supported by the SFG spectroscopic results.INTRODUCTIONPotassium is an important fertilizer. Its primary source comes from potash ores, which are a mixture of sylvite (KCl), halite (NaCl) and many other complex double salts such as carnallite (KCl·MgCl·6H2O), alkali nitrates such as KNO3 and NaNO3, and sulfates-langbeinite (2MgSO4·K2SO4) with water-insoluble minerals such as clay and carbonate minerals. Previously, these salts were recovered with a lengthy hot leaching method, with further crystallization of potassium salts from saturated saline solutions. Selective flotation has been preferred since 1940s. Various collector adsorption mechanisms have been proposed soon after the industrial introduction of potash flotation. These include the formation of the insoluble compound model (Halbich, 1933; Singewald, 1961), an ion exchange model (Fuerstenau and Fuerstenau, 1956), a heat of solution model (Rogers, 1957), the surface hydration model (Schubert, 1988), the surface charge model (Roman, 1966; Miller et al., 1992), the interfacial water structure model (Hancer and Miller, 2000) and the colloid adsorption model (Leja, 1983; Burdukova and Laskowski, 2009). Most of the early exercises attempting to propose a unified rule on collector adsorption mechanisms can be seen as heroic endeavors due to the consideration of a vast number of salts in the pulp including alkali halides, nitrates, and sulfates, even the practically insoluble heavy earth metals. Additionally, several types of surfactants with different polarization features and alkyl chain length have been employed. As for the recent models, due probably to the preferential application of long chain amines as collectors in industrial potash flotation, most researchers are only devoted to collectors with low polarization features like amines and sulfonates (Hancer and Miller, 2000; Du et al., 2014). Collector adsorption mechanisms are therefore proposed based largely on a neglect of carboxylates as collectors. However, carboxylates remain an important collector type in soluble salt flotation systems where both salt minerals can be floated using anionic collectors and cationic collectors. Fatty acid type collectors are still one of the widely used collectors for soluble salt flotation and also one of the first to be applied on an industrial scale for the separation of potash ore (Hernáinz et al., 2003; Titkov, 2004). Here we examine some recent models that are relevant to our study to reveal a long neglected specific ion binding effects in potash flotation."

Jan 1, 2016

By K. Thuro, L. Wilfing, H. Kasling

"In mechanized tunneling, performance prediction is a crucial issue for estimating excavation costs and construction time of a tunnel project. The aim of this work is to compare the calculated parameters by penetration prediction models with the results of penetration tests during excavation by a Tunnel Boring Machine (TBM) at actual tunnel projects. This comparison helps to improve the existing prediction models (Gehring, 1995 and Rostami (Colorado School of Mines), 1997.) and to develop a new, so-called “Alpine Model” (research group ABROCK; Schneider et al., 2012).On-site penetration tests are a common tool to determine performance of a TBM in certain geological environments. During a test, the TBM is operated under defined conditions that allow comparing the results of different projects and machine types. There are two different types of penetration tests in use. The more common type, described by Bruland (1998a), is based on test drives at different thrust levels. The tests in this study are performed as start-stop-tests, meaning that the TBM starts from zero to the maximum possible thrust and reverse with slowly increasing respectively decreasing steps (Frenzel et al., 2012). To gain information about the interaction between TBM and rock mass, a detailed geological documentation including an analysis of the discontinuity pattern and laboratory testing for rock strength characterization are mandatory.Within the last year 16 penetration tests have been performed. The results are thrust- penetration curves (Figure 2) showing that up to a certain penetration rate only crushing occurs (subcritical penetration). From there the desired rock fragmentation process called chipping takes place (Frenzel et al., 2012). These two different fragmentation processes can be described best by a bilinear function as seen in Figure 3. Both, CSM- and Gehring-model, do not fit to the trend of the penetration rates determined during the excavation process as they are using potential or simple linear functions.Another parameter that has to be implemented into the new prediction model is the influence of discontinuities. In case of favorable orientation and spacing, discontinuities reduce the required thrust at same penetration rates. In contrast, unfavorable discontinuity systems can cause blocky faces and hence worse performance than predicted. Besides discontinuities, the toughness of rocks has to be taken into account when predicting the penetration as tough rocks need more energy to obtain complete failure than brittle rocks.Key advantage of these tests in comparison to existing are more data points in less time. By improving respectively extending the existing penetration prediction models with the stated parameters, the penetration prediction for TBMs can be more accurate and also wear calculation can benefit from this approach."

Jan 1, 2015

By Ho-Sung Yoon, Jyothi Rajesh Kumar, Chul-Joo Kim, Sung-Don Kim

A recovery process for rare earths (REs) such as dysprosium and neodymium from the leach liquor of permanent magnet scrap (PMS) was developed. The two hydrometallurgical routes namely liquid-liquid extraction (solvent extraction) and selective stripping were implemented. The present study deals with the separation and recovery process development by using organo-phosphorous based extractant di-(2-ethylhexyl phosphoric acid (D2EHPA) as reagent for REs processing. Initial studies considered the influence of time on the extraction process, as well as pH and extractant concentration effects. This suggested the aqueous mechanism and separation factors played a role in process during development. McCabe-Thiele diagrams for extraction isotherms were developed. Counter current extraction (CCE) using various phase ratios influenced metals separation. Maximum loading capacity of the D2EHPA was determined. The loaded organic generated by the CCE process was water washed followed by a scrubbing process to remove the other metal ion from targeted metal. Finally, a stripping process was tested using various mineral acids.

Jan 1, 2015