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By L. A. Haas

A kinetic study of the carbon deposition reaction was undertaken by the Bureau of Mines as part of a broad investigation of metallurgical reactions in the iron ore blast furnace. The disproportionation of carbon monoxide on iron pellets was investigated at carbon monoxide pressures between 0.5 and 2 atmospheres (absolute) and temperatures from 400° to 1,075° C. Gas flow in the range from 0.25 to 0.85 standard liter per minute was found to have little effect on the reaction velocity. The addition of nitrogen and helium to caron monoxide exerted only a dilution effect on the rate of carbon deposition. However, an addition of 1 percent hydrogen increased the rate about 100 times. Small amounts of carbon dioxide in the inlet gas exerted little effect on the rate of carbon deposition. The maximum rate for carbon deposition in the first 2 hours occurred at 550° C. The apparent molar activation energies at various stages of the reaction were found to vary from 13 kcal initially to 36 kcal during the latter stages of the reaction. The reaction rate behavior was tentatively explained by an adsorption step followed by the diffusion of iron through a shell of inactive iron carbide.

Jan 1, 1968

By Thomas L. Theis

The use of a suspended growth system of T. ferrooxidans attached in a film to individual particles of bentonite and operated as a sequencing batch reactor has been shown to be a practical way of oxidizing ferrous iron in acid mine drainage. This component followed by limestone neutralization is both a technically and economically feasible approach to the treatment of these wastewaters in comparison to existing and proposed methods. The advantages, in addition to less expense, are greater safety, acceptable treatment at a lower pH, lower solids buildup, less danger of overtreatment, and greater flexibility in operational characteristics. In this report data on the continuous bench scale operation of the system under a variety of conditions shows sustained levels of oxidation in excess of 9%. A cost analysis projects capital and operating costs of $80/1,000 m3 of wastewater.

Jan 1, 1982

By D. Bienstock

To develop a rugged catalyst capable of withstanding hydraulic attrition resulting from the oil-circulation process for synthesizing liquid fuels, use of an iron catalyst containing an active coating surrounding an inert solid core of metal was investigated. This massive-iron catalyst in the form of steel shot and lathe turnings was activated by partial oxidation with steam at 600° C, impregnated with alkali, and reduced with hydrogen at 450° 6. The massive-iron catalysts were resistant to oxidation and spalling, and a 6-month catalyst life was attained. Higher operating temperatures could be employed than with fused iron oxide catalysts, resulting in greater gasoline yields. Because the lathe turnings pack with void volumes of 70 to 90 percent, it has become possible to employ a fixed bed without the danger of cementation that occurs with fused iron oxides.

Jan 1, 1963

By R. G. Lett

Gaseous products resulting from rapid pyrolysis of coal and coal/inhibitor mixture's by a ruby laser and a flash-tube were monitored on-line by time-of-flight mass spectrometry. The distribution of stable gases from the coal is not Greatly influenced by the addition of small quantities of powdered flame inhibitors. Preliminary studies of the reaction of elementary radicals with coal and coal/inhibitor mixtures are described. The different types of experiments are discussed with regard to possible modification and application to studies of flame inhibitor action.

Jan 1, 1973

By J. Sottile, J. L. Kohler

Component failures in the electrical control circuits of mining machines account for a large percentage of the total downtime of the machine. Once a failure has occurred it is always a tedious and usually a time-consuming task to locate the failed component. Moreover, the pressure to quickly locate the cause of a delay can lead to compromises in safety. Thus an onboard diagnostic system, essential for an automated machine, would be a very useful addition to existing machines. This report details U.S. Bureau of Mines development of a generic procedure for synthesizing diagnostic systems for electrical-control-circuit failures in mining machinery. A continuous mining machine is used as the testbed to illustrate the application of the developed methodology. Substantive differences among mining machine control circuits made it impossible to achieve a generic diagnostic system, but a generic approach for the synthesis of the diagnostic system was possible. As the research progressed, it became apparent that an algorithmic approach was better than an expert- system-based implementation. A prototype system was constructed and used to evaluate the diagnostic system. Prototype implementation issues are also examined.

Jan 1, 1993

This volume constitutes the Survival Subsystem portion of the final report for the Coal Mine Rescue and Survival System (CMR&SS) program, which was conducted by the Westinghouse Electric Corporation under contract to the United States Bureau of Mines (Contract Number H0101262 dated June 17, 1970). The program was directed by the Special Systems Department of the Westinghouse Baltimore, Maryland, facility. The basic objectives of the CMR&SS program were to develop and test hardware to determine the efficacy of a variety of coal mine rescue and survival concepts and techniques. These concepts were drawn from two major sources: the Request for Proposal from the Bureau of Mines1 and the final report on the Mine Rescue and Survival Study conducted by the National Academy of Engineering2 (NAE).

Jan 1, 1971

By Robert L. Lappi

Eight interburden handling concepts are developed for multiple seam area mine stripping operations in central and western United States. They are based on data gathered and analyzed during field surveys, literature reviews and visits to state requlatory agencies in five states. It is concluded that improvement of reclamation practices through selective interburden handling techniques is possible at lower operating costs than currently incurred. Specific multiple seam mining systems are discussed in this report.

Jan 1, 1980

By L. A. Morely

The overall objective of the subject contract was to investigate the application, economic, and safety considerations of electrical-shock prevention techniques applied to surface and underground mines. Volume I of the four-volume final report starts by summarizing all research performed, and synopses of the three other report volumes are included. The balance of this volume concerns one major task of the contract, the protection of maintenance personnel. After specifying the scope of work for the task, electrical is defined, and needed ground-fault relay characteristics to prevent ventricular fibrillation are established. This is followed by an analysis of alternating-current systems, a comparison of these systems with respect to body currents, and the advantages and disadvantages of the various ground-fault protection techniques. An analysis of direct-current systems for off-track vehicles is then covered. These analyses form the basis for the research recommendations which along with suggestions for future research, conclude the report volume.

Jan 1, 1982

By A. R. T. Denues

[Liquid oxygen explosives are ordinarily made from a carbonaceous absorbent and from liquid oxygen of high purity. These explosives have a limited but definite field of usefulness; their properties have been described in the literature, which includes several publications of the Bureau of Mines, the most recent dealing with fire-retardant treatments.3/ It seems generally conceded that the outstanding hazards in the use of these explosives are their high inflammability and their relative sensitivity to mechanical action. Each of these topics has been studied, and some interesting practical results have been obtained. Treatments have been described that render liquid-oxygen explosives prepared from granular carbonaceous absorbents practically immune to the action of igniting agents representing or exceeding practical hazards in violence.]

Jan 1, 1941

By D. J. Dollhopf

An overburden handling dragline operation was conducted at a strip mine near Colstrip, Montana. The objective of the demonstration was to determine the degree a dragline could mix overburden inhibitory zones during the spoiling process. In order to quantify the mixing process the overburden was: 1) scatter spoiled; 2) dump spoiled; and 3) spoiled in a normal manner. This demonstration was part of an effort to investigate means of reestablishing non-polluted hydrological systems in areas where surface mining directly impacts shallow ground-water resources. When inhibitory material constituted < 5% of the total overburden volume, such material was essentially not detectable in the resultant spoil pile. When inhibitory material exceeded 15% of the overburden volume it was always found in the resultant spoil pile, generally with a smaller extent, indicating partial dilution. Inhibitory overburden zones often reappeared at the base or top of spoil piles in the potential aquifer and root zones suggesting the need for selective placement procedures. Scatter spoiling did not appear to be significantly more effective than normal spoiling, however clump spoiling seemed to produce less mixing of inimical zones. Mining activity has reduced ground-water levels within 1600 m of the active pit. The aquifer which is developing in spoils appears to have similar confinement characteristics as those that existed in the premined aquifer. To date no definite trends have been observed concerning changes in surface or ground-water chemistry associated with mining.

Jan 1, 1978

By C. L. Brown

"INTRODUCTION The heavy loss of life from mine fires in some coal mines recently has focused attention on the importance of maintaining reliable communication systems between the active working sections of mines and the surface. A study of conditions following disasters in mines indicates that in several instances lives could have been saved if telephone communication had been available. Communication systems were not installed in some of these mines where disasters occurred, and in other mines they were installed in such a manner as to be rendered useless following a mine explosion or fire. Lives have been lost because of the inability of the rescue crews or persons di-recting the rescue to communicate with trapped men. Cases are known where many lives might have been saved had it been possible to give instructions for escaping or for location of barricades.More than 500 major disasters in which 5 or more lives have been lost have occurred in mines in the United States. The total number of lives lost in these disasters has exceeded 13,000. Some of the victims died instantly; but for many it was hours and in some instances days before death occurred. Evidence found in recovery operations following some of the disasters indi¬cates that many died needlessly because of the lack of suitable means of communication between the underground working areas and the surface.A localized gas and dust explosion in a coal mine in 1930 resulted in the death of 82 men; 2 were killed outright by the force of the explosion, 6 by a combination of burns and afterdamp, and 74 by afterdamp. About 140 men escaped or were rescued following the explosion, Of these, 119 escaped with little or no assistance, 2 were rescued promptly following the explosion, and 19 were rescued from behind a barricade. Seven bodies were re-covered from behind an ineffective barricade in another place; subsequent investigation proved that these men might have been guided to a safe location had an effective communication system been available."

Oct 1, 1946

By Fredrick L. Johnson

The Bureau of Mines, under Congressional mandate, conducted a mineral survey on the Park Range WSA (Wilderness Study Area) in 1984 and 1985. The WSA, located about midway between Tonopah and Ely, encompasses 47,268 acres. No mineral resources were delineated, nor were workings found, during the investigation. There has been, however, exploration in and near the north end of the study area. ASARCO is actively exploring a block of 41 claims for hot-spring type, low-grade, large-tonnage gold deposits. Their claim block is almost entirely in the study area. The Morey mining district, 7 miles southwest of the study area, produced silver and lesser amounts of gold and lead sporadically from the mid-1860&apos;s through the mid-1960&apos;s. The WSA is underlain by Tertiary rhyolitic and latitic volcanic rocks and by Paleozoic sedimentary rocks. The Paleozoic rocks have been faulted, silicified, brecciated, and hydrothermally altered, and have anomalous concentrations of precious metals and pathfinder elements. Additional exploration in the north part of the Park Range WSA may lead to delineation of gold resources.

Jan 1, 1986

The investigation summarized in this report addressed two primary issues: the determination and use of correction factors, and the development of guidelines for velocity measurement site selection. Other ancillary issues which were addressed include a comparison of measurement methods and devices, aircourse cross-sectional area measurement, and characteristics of mine airways. An exhaustive literature search and analysis was performed; extensive in-mine experiments were conducted; a quantitative analysis of the data was used to develop correction factor tables and site selection guidelines. The reported results of other researchers who have examined the correction factors and site selection criteria, were analyzed in light of the results of this study. The measurement devices included in the experimental phase were: vane anemometer, vortex shedding anemometer, a prototype thermoanemometer, smoke tube, and, oil of wintergreen. The measurement methods include single-point centerline, timed¬-point traverse, continuous traverse for the anemometers, and various distances and cloud positions for the smoke tube and oil of wintergreen devices.

Jan 1, 1983

By Thomas Novak, Robert Goldstein

The analysis of a machine-luminaire configuration is a time- consuming process requiring the construction of a machine mockup, installation of a designated lighting arrangement, and an extensive set of illumination measurements. This entire process, however, is well suited to computer analysis. By simulating the machine geometry and the characteristics of the desired luminaires, the incident light levels can be calculated at the required set of points. This Bureau of Mines paper presents a general description of the techniques involved in performing this simulation.

By J. L. Thompson

The U.S. Bureau of Mines conducted a water-jet-studies program using a single-bit, in-seam test unit to determine effects of a moderately high-pressure (up to 10,000 psi) water-jet-assisted cutting system on rock weakening. The in-seam test unit was used to obtain cutting force data in tangential, normal, and side force directions. Conical continuous miner and radial longwall miner bits were used to penetrate test samples of coalcrete, Berea sandstone, and Indiana limestone with unconfined compressive strengths of 4,600, 8,000 and 10,000 psi, respectively. Depth of cut in the coalcrete tests was 1 in, with 2-in cut spacing (2:1 ratio). Because of cutting equipment and instrumentation limitations, the Berea sandstone and Indiana lime-stone were cut using a 0.5-in depth of cut and 2-in spacing (4;1 ratio). Bit velocity was maintained at 25 ft/min for both bits. Each specimen and bit type was tested using 0.3-, 0.6-, 0.8-, and 1.0-mm-diam nozzles and water-jet pressures of 2,500, 5,000, 7,500, and 10,000 psig. Water-jet-assisted cutting decreased average resultant conical and radiallongwall bit cutting forces 6.4 and 8.4 pct in coalcrete, 5.5 and 1.4 pct in Berea sandstone, and 2.0 and 5.5 pct in Indiana limestone. Slight reductions of power requirements resulting from water-jet assist were ascertained during these experiments.

Jan 1, 1989

By John L. Schaller

The Bureau of Mines, U.S. Department of the Interior, has investigated the extraction of alumina from domestic kaolin clay by leaching with boiling 26 wt-pct hydrochloric acid. Acid leaching of crushed calcined kaolin feed yields slurries that are slow settling and difficult to filter because of the presence of fine particles generated in crushing, calcining, and leaching. Laboratory research showed that tumbling and moistening crushed raw kaolin on a pelletizing disk caused the fines to agglomerate on the surfaces of the larger particles, while the sharp edges and corners of the larger particles were rounded off. Minus 16-mesh crushed raw kaolin was misted on a 36-in-diam, 8-in-deep pelletizing disk at rates of 175 to 250 lb/hr, and was calcined in either a rotary or a fluidized-bed calciner; negligible degradation occurred. The physical properties of the misted calcined kaolin were evaluated in the leaching system of the clay-hydrochloric acid miniplant. Only minor attrition occurred during leaching, and the slurry was readily filtered on a continuous belt filter.

Jan 1, 1982

During the period 1979 thru 1982, Multi Mineral Corporation conducted a mining research program at the United States Department of the Interior&apos;s Bureau of Mines Oil Shale Mining Environmental Research Facility in the Central Piceance Creek Basin, Rio Blanco County, Colorado. The program consisted of mining, environmental and geotechnical research data and. the results are described in this report.

Jan 1, 1983

By Michael J. Beus

This Bureau of Mines report describes the development of load cells for measuring compressive loads in timber and lock-bolt support systems commonly used in. coal; metal, and nonmetal mines Design and evaluation is covered in detail to insure a reliable, accurate, and practical instrumentation scheme. The load cells are relatively inexpensive and adaptable to various size support systems. User-oriented procedures are emphasized, and design equations were reduced to a series of nomographs. Laboratory evaluation, destructive testing, environmental testing, and tests to determine the effect of extraneous loads were conducted. Field performance was evaluated in conjunction with ongoing Bureau projects at a metal mine in North Idaho and a coal mine in Utah. Load cells utilizing a titanium alloy as the cell body and weldable strain gages as the strain-sensing components satisfied the basic design and performance criteria, and with minor design modifications, the load cells can be adapted to many mining applications.

Jan 1, 1974

By F. J. Prokoski

The COALSTAR Project, which operated from November 1981 to December 1982, was a research and development project aimed at providing a reliable and inexpensive means of monitoring various waste site conditions via the GOES satellite system. The GOES system provides data transfer from unattended isolated sites where neither power nor telephone lines exist. The reliability and resolution of the data received while using the satellite link were excellent; however, the site instrumentation gave considerable trouble. The disastrous failure of a large coal waste embankment in 1972 led the Bureau of Mines to undertake a comprehensive program to reduce the likelihood of such an occurence again. Part of this program involved the installation of instruments to monitor the stability of a specially-selected embankment operated by Armco Incorporated near Montcoal, West Virginia. Initially, the instruments were monitored by normal telephone lines and used normal commercial power from the local utility. The project described here was initiated to replace this monitoring system with an unmanned, solar-powered data collection system which transmitted data via satellite to a central computer facility. The satellite data network is the National Earth Satellite Service of the National Oceanic and Atmospheric Administration.

Jan 1, 1984

By David A. Summers

The use of high pressure fluid cavitation is investigated as a means of breaking an ore into its constituent grains. This Cavitational Rock Dissagregation (CRD) is found to be possible and effective in breaking down galena ore, both in sandstone and dolomite host material. The technique did not work as well in comminuting and cleaning oil shale, because the cavitation drove the oil into emulsion with the water. The presence of dominant bedding in the rock also caused preferential breakage to these lines, rather than to the individual grain boundaries. This problem was also encountered in tests on igneous ore where weakness plants of the overall ore proved weaker than the boundaries of the individual grains. It was found that the prevailing expression of cavitation erosion dependence on pressure was not absolutely valid. In contrast it was found that CRD is much more sensitive to jet flow diameter, and when this was recognized it was found possible to erode rock with compressive strength of up to 350 MPa with operating jet pressures of 10 MPa.

Jan 1, 1982