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By M. Paymardi, A. Foroutan, T. P. Oladele, M. Abbaszadeh

"Reducing the amount of zinc and iron in lead concentrate is one of the important aspects of processing in lead and zinc flotation plants which results in improvement of lead concentrate quality and prevents zinc loss. In mineral flotation industries, lignin sulfonates are known for their depressant properties for both non-metallic and sulfide minerals such as pyrite and pyrrhotite.This paper investigates the effect of lignin sulfonate on flotation of galena, sphalerite and pyrite in sulfidic lead and zinc bearing ores. Batch flotation tests were carried out on a high pre-activated zinc samples. The feed contains 0.9% lead, 2.3% zinc and 7.5% iron. The dosage of all reagents such as sodium cyanide, zinc sulfate, ethyl xanthate and methyl isobutyl carbinol (MIBC) were kept constant for lead flotation step except calcium lignin sulfonate (CLS) that was varied between 0 and 80 gr/ton.Results for lead rougher concentrate showed that the grade of lead increased by 2.7% while the recovery decreased around 4 % at the highest dosage of CLS. Furthermore, zinc recovery decreased by 6.3% with no significant change in grade. Iron recovery in lead rougher concentrate decreased by 2.3 % while the grade changed around 1%. In sphalerite flotation step, CLS dosage was changed in the range of 0 to 80 gr/ton while the dosage of other reagents such as copper sulfate, lime, amil xanthate and MIBC were kept constant. In this step, no decreasing in grade and recovery of zinc was observed, while iron recovery decreased. It was suggested that CLS has a depression effect on sphalerite in conjunction with other zinc depressants such as zinc sulfate and sodium cyanide. CLS was further used in plant with non-pre-activated zinc minerals. Similar trends were observed in plant.INTRODUCTIONlead-zinc sulfide minerals play an important role in the production of lead and zinc metals in the mineral processing industry (Luo, Feng et al. 2016). Due to complexity of the lead-zinc ores mineralogy, in some situations, their flotation properties vary significantly from one deposit to another one even in itself (Bulatovic 2007)."

Jan 1, 2018

By V. A. Ivanova, T. N. Perunkova, N. O. Dorozhanova, G. V. Mitrofanova

"Oxyethylated compounds are used as reagents-regulators in the flotation of non-sulfide ores, in particular, apatite-containing ores. Thus, the necessary degree of selectivity in the flotation separation of two calcium-containing minerals of apatite and calcite is achieved only by using, in addition to a collector, regulators-reagents from the nonylphenol ethoxylates class. In order to establish the most optimal structures, this paper presents a comparative assessment of the physical-chemical and flotation properties of several classes of oxyethylated compounds - alkylphenol ethoxylates, aliphatic alcohol ethoxylates and oxyethylated carboxylic acid. The authors have studied their dispergating ability with respect to the air phase and calcium soaps of the carboxylic collector. Dependences of foaming properties of regulators on the degree of oxyethylation have been determined. Adsorption isotherms of sodium oleate on apatite and calcite in the presence of regulators have been obtained. It has been shown that the presence of oxyethylated compounds in the solution reduces the amount of the adsorbed fatty acid collector. The influence of the considered classes of regulators on apatite flotation has been studied. The interrelation of flotation properties of oxyethylated compounds and their molecular structure has been established.INTRODUCTION Flotation plays a leading role in complex apatite-containing ores processing. However, two calcium-containing minerals - apatite and calcite, which compose apatite-carbonate ores, are characterized by close flotation properties. Selective separation of these minerals is a difficult task, the solution of which is impossible without using reagents-regulators. One of the ways to ensure the selectivity of the flotation separation of calcium-containing minerals is the use of reagents-depressants such as sodium silicate, starch, cellulose derivatives, and others (Liu et al., 2016; Rao et al., 1989). Another method is the application of nonionic reagent regulators (Filippov et al., 2016; Filippova et al., 2014; Ignatkina, 2017), which contribute to the adsorption of the ion collector (Filippov and Filipova, 2006 Rao and Forssberg, 1997) and stability of formed froth (Sis and Chander, 2003)."

Jan 1, 2018

By Nina Panteleeva, Elena Afonina, Stanislav Titkov, Jury Buksha

"Flotation processing of water-soluble minerals (potassium ores, sedimentary salts of salt lakes) is currently the main method for production of potassium fertilizers and concentrated carnallite which is the initial product for production of metallic magnesium. Flotation of sylvite (KCl) and halite (NaCl) is carried out in the electrolyte solutions: KCl-NaCl-H2O and KCl-NaCl-MgCl2-H2O. The report presents the results of studies of the effect of concentration and the electrolyte type on the size of air bubbles in a flotation cell in comparison with the floatability of mineral constituents of potash ores. The floatability in electrolytes of various compositions has been studied: - of sylvite (KCl) by alkylamines, - of halite (NaCl) by alkylmorpholines, - of silicate-carbonate slimes contained in the ore by ethoxylated surfactants. The reagent modes (regimes) activating the flotation desliming of potash ores have been developed."

Jan 1, 2014

By M. Saba

In cyanide leaching procedure, achieving an acceptable efficiency for silver and gold is very time-consuming, thus, enough studies have not been performed for optimization and modeling of this process. The kinetics of cyanide leaching includes two steps: first step comprises a sharp slope while the other has a slight increasing trend. In the present study, in order to reduce the time and cost, the cyanide leaching process of a sulfide silver/gold ore was optimized in the first period. The applied parameters and their ranges are: temperature 20-40 (°C); time 1-8 (hrs); cyanide concentration 1-2 (mole cyanide / mole Cu); the percentage of solid to liquid 1-2 (%) and pH 10-12. For design of experiments fractional factorial 2(5-1) was used. Also four center points were applied to increase the accuracy of the model. In addition, by analysis of variance (ANOVA) the most effective parameters were identified and the optimized condition was determined. A regression model was proposed to describe the effects of independent variables and their interacting role on silver recovery. Results showed that the model was linear for silver and nonlinear for gold. In the gold recovery process, the two important parameters are time and pH with the former being more effective. Due to the existence of cyanide ions in the medium, temperature and cyanide concentration have less influence in the gold recovery process. Solid to liquid ratio, in addition, comprises a slight negative impact on the procedure. This emphasizes the different kinetics of silver/ gold cyanide leaching. Finally, using the optimum condition the amount of silver and gold obtained were 61% and 67% in 8 hours, respectively. While in general conditions, the results were 37% and 54% in 24 hours, respectively. Keywords: cyanide leaching, refractory gold/silver ore, modeling, optimization

Sep 1, 2012

By Andrei Yevdokimov, Ivan Sidorov, Olga Lanchakova, Olga Khmelnitskaya, Tatiana Chikina

"The paper focuses on the results of the research on development of hydrometallurgical process of gold recovery from refractory sulfide flotation concentrates based on fine and ultrafine grinding. Refractory concentrates (the degree of refractoriness is 16.9%-82.6%) were chosen for testing. The efficiency of the process based on fine and ultrafine grinding to treat flotation concentrates with gold intergrown with sulfides and rock-forming minerals was shown. Based on the test work conducted, the process option was chosen. In included grinding of flotation concentrate to the size of 98% minus 20µm in a bead mill, lime treatment with air blow, CIL, filtration and detoxification of liquid phase of the slurry. This process (compared to the basic option) provides the recovery of gold from 82.6%, up to 94.0% and decreases the residual grade in the tailings from 3.3g/t to 1.1g/t at the consumption of 12.6NaCNkg/t. Based on the results of the test work and pilot plant testing, project design criteria of flotation circuit at a Russian plant was developed."

Jan 1, 2014

By D. Jamróz, A. Surowiak, T. Niedoba, P. Pieta

"The separation of coal material of three types of coals originating from three various Polish hard coal mines (types 31, 34.2 and 35, according to Polish nomenclature, which were steam coal, semi-coking coal and coking coal) into particle size fractions and then into particle density fractions was done and then the following parameters were measured for each particle size-density fraction: combustion heat, ash contents, sulfur contents, volatile parts contents, analytic moisture. In this way a 7-dimensional vector of data was created. Using methods of factor analysis the important features of coal were selected, which decide about their membership to individual types. To evaluate the appropriateness of the applied method the Bartlett’s sphericity test as well coefficient of Kaiser-Mayer-Olkin (KMO) were used. To select important factors the Kaiser criterion and Cattell’s scree test were used. The obtained results were compared with the results obtained in previous works by means of observation tunnels method. The results showed which particular features are crucial to define the type of coal what is also important to select appropriate method of its enrichment.INTRODUCTION Coal extracted from the mine is often a mixture of coals of various quality originating, for example, from various coal layers. One of the most important issues is to determine its quality, what means to verify if it fulfills certain requirements. Usually, such parameters as combustion heat, ash contents, sulfur contents, volatile parts contents and analytic moisture decide what the coal quality is (Drzymala, 2009). Such investigations are expensive and time consuming. That is why it seems to be important to determine the mutual connections and interactions between them what would make possible to reduce the amount of the necessary parameters. This issue was already investigated with successes in several works [Jamróz and Niedoba, 2013; 2014; Niedoba, 2015]. This work is another approach to this problem. Here, the investigation of possible reduction of researched parameters was done on the basis of the factor analysis. The obtained results confirm the earlier observations."

Jan 1, 2018

By Y. De Gao, C. Gang Zhong, X. Yang Qiu, Li Wan

The chelating reagents are used as effective collectors in wolframite flotation, and certain metal cations need to be added using chelating collectors so as to activate valuable minerals and obtain good flotation indexes. Different metal cations will result in different reactivity with collectors, in order to select the effective activator in BHA flotation of wolframite, the activation effectiveness of different metal cations on wolframite ((Fe,Mn)WO4) flotation were studied using pure minerals. The results showed that the wolframite activation by Pb2+was the best among the selected cations. The maximum flotation recovery of wolframite was found to be 95.58 % under conditions of 100mg/LBHA and 1×10-4mol/L of Pb2+at pH 9. The dosage of Pb2+needs to be controlled in an optimum range. Also, the activation mechanism of Pb2+ on BHA flotation of wolframite was investigated by measurements of contact angle, zeta potential, adsorption capacity and IR spectroscopy. It was found that Pb2+ could chemically adsorb onto the wolframite surface improving the flotability of wolframite and enhancing the adsorption of BHA on wolframite. When the dosages of BHA and Pb2+ were 100 mg/L and 1×10-4 mol/L, the adsorption quantity of BHA on wolframite sharply increased up to 0.30 mg/L at pH 9 compared with wolframite treated with only BHA.

Jan 1, 2014

By Héctor X. Toro, José Francisco Cabello, Douglas Batista, Álvaro Videla, Claudio Luiz Schneider

The Minas-Rio Project, located in the state of Minas Gerais, Brazil, is currently under construction. The new plant will have a regrinding circuit that uses VertimillTM. The objective is to process itabirite iron ores and it is expected that the consumption of media will represent a large part of the plant operating cost. Many studies in the literature indicate that the size of the grinding media directly influences the grinding efficiency. The size distribution of the charge media is related to the surface area of the charge. In this study, a sample of itabirite iron ore was tested with respect to grindability in a laboratory scale ball mill. The test mill was equipped with a torque device to accurately measure power consumption, as required for the determination of energy specific kinetic parameters. Five tests were carried out with different sizes of steel balls and with SICAM (sub-inch Cast Media). The size distributions of the feed and product of the several grinding tests were used to calibrate population balance model parameters for each condition. The results confirmed that the ball charge with smaller diameter is the most efficient among the different media charge tested.

Jan 1, 2014

By Vitaly Kretov, Valery Golikov, Vladimir Ryaboy, Elena Shepeta

"The aim of the study was to develop and implement more efficient dialkyldithiophosphate collectors. A hypothesis has been formulated on the action of dialkyldithiophosphates in the flotation of sulphide ores based on the assessment of their complexing properties and surface activity at the liquid-gas border. Dialkyldithiophosphates form weaker complexes with cations of heavy metals compared to xanthates, and are characterized by a large difference in the strength of their complexes with heavy metal cations. It provides higher selectivity of dialkyldithiophosphates in the separation of non-ferrous metal sulphides and iron sulphides from them. To make a quality assessment of the impact of surface activity of the synthesized collectors on their selectivity of action and collecting power, an assessment of the surface tension of their aqueous solutions has been performed using the stalagmometer method. It is well known that a stronger collector is characterized by a greater surface activity, in contrast to a more selective collector which is characterized by a lower surface activity. Based on studies, new dialkyldithiophosphate collectors BTF 163 and BTF 1552 are suggested for use in the flotation of sulphides to increase the recovery of copper, gold and silver. The collector BTF 163 was introduced at a gold processing plant in Kazakhstan and has been undergoing industrial testing in the sulphide cycle of scheelite-skarn-sulphide ores in a factory in the far east of Russia. The collector BTF 1552, which increases the recovery of silver and gold by 3%, was approved for industrial testing in another far-eastern factory. A modification of the reagent BTF 1552, the new reagent BTF 1522, was introduced in the flotation of copper-zinc ore at a factory in Kazakhstan."

Jan 1, 2014

By L. S. Zhou

Germany-made AFX-100 multi-grade fluidized classifier, with exquisite built-in structure and unique novel design, materializes not only advanced and efficient classification, but also precise particle distribution and safe operation, in addition to lower energy consumption and operational cost. It, simultaneously in place of screw grader, water cyclone, and fine mesh sieve, is equipped with multi-function, and indicates superior advantage in comparison with other else grading facilities. As the third-generation equipment, which is efficient and modern, it, in China and therefore all over the world, will find wide application in processing both fine and ultra-fine iron ore resources. Industrial test, carried out in Benxi Steel?s Waitoushan Iron Mine, shows efficient classification, i.e., ?74µm particle contents in coarse, medium and fine products come to 6.09%,11.82% and 82.73%, respectively, while qualitative and quantitative efficiencies end up by 74.38% and 87.66%, respectively. Its separation efficiencies amount to 2.2 times as many as spiral classifiers, 1.8 times as hydrocyclones, and 1.3 times as vibration high-frequency fine screens. Another industrial test, which was practiced in Anshan Steel?s Donganshan Sinter Plant, indicates that classification qualitative efficiency comes to 65.06%, equal to 1.51 times as many as hydrocyclones; yield, 55.79%; -71µm particle contents in medium and coarse products, 42.02%; -71µm content in fine product, 95.42%; and concentration, 12.33%. Estimated separation indexes are as follows: Yield for concentrate at 31.22%, up 0.22% than that from general processing line; concentrate grade at 66.42%, up 1.13%; recovery ratio comes to 65.84%, up 1.28%, which, based on pilot study, results in 20 million yuan of economic return for Donganshan Floatation Plant.

Jan 1, 2014

By G. Önal

Recovery of nickel and chromite from the tailings has been studied on the samples with 0.214 % Ni and 5.10 % Cr2O3 content and taken from Orhaneli Chromite Concentration Plant. Mineralogical examinations of the samples showed the existence of chromite, olivine, pyroxene, chrysotile, anti-gorite, chlorite, idingite, tremolite and calcite together with trace amounts of millerite, pentlandite, pyrite, pyrrhotite, hematite and limonite type iron oxide minerals in partially serpantinized dunite type particles. In order to recover chromite from Chromite Concentration Plant tailings Mozley Table and Knelson Separator are used and concentrates containing approximately 42% and 46% Cr2O3 are produced respectively with 40% recovery. Most of the nickel remained in the tailings. Therefore, acidic leaching tests are performed in order to dissolve nickel from these tailings. Effects of particle size, acid concentration, temperature, leaching time and solid/liquid ratio on the nickel leaching efficiency are investigated. The optimum leaching conditions are found as 250 g/L acid concentration, 1/5 solid/liquid ratio, 2 hours of leaching time and 60°C temperature, almost all nickel is dissolved at the optimum conditions and acid consumption is about 841 kg/t. Repeated leaching tests are carried out in order to have enough Ni content in the leach liquor for the further treatment of solutions. After repeated leaching tests, leach liquor contains 3 kg/m3 Ni, 48 kg/m3 Fe, 2.2 kg/m3 Si, 23 g/m3 Cr and 590 kg/m3 H2SO4. Ni is recovered from that solution by precipitating with H2S followed by HNO3 dissolution and precipitating Ni as hydroxide with 63% Ni content. Leach cakes are subjected to the gravity separation (Mozley table) to recover the remained chromite and a chromite concentrate with 47% Cr2O 3 content is produced with 53% recovery. As a result of the abovementioned tests, a conceptual process flow sheet is proposed for the treatment of these chromite concentration plant tailings.

Jan 1, 2014

By S. I. Anufrieva, N. A. Permyakova, E. G. Likhnikeevich

"Russia’s rare metal reserves are composed of compositionally and structurally complex ores and are characterized by an increased content of natural radionuclides due to their geochemical similarity with rare metals. For instance, concentrates of Zashikhinsky daeposit are characterized by an increased content of uranium (0,06%) and thorium (0,59%); Beloziminsky deposit holds pyrochlore-apatite-magnetite-carbonate ores characterized by increased radioactivity (130 mkR/h) and containing 0,0016-0,0025% of uranium; Etykinsky deposit is characterized by columbite-pyrochlore-microlith mineralization with an average ore grade of 0,013% of uranium and 0,0020% of thorium; eudialyte concentrate of Lovozero deposit (Alluaiv area) belongs to Class II of mineral reserves. Industrial development of these mineral reserves involves the need to comply with environmental standards, public health requirements applicable to finished core and by-products, to take into account the amount and class of the generated radioactive waste, the possibility of disposal or recycling of the radioactive production waste. Concentration processes of radioactive rare metal feeds most often lead to a concentration of natural radionuclides and their accumulation in concentrates. Comprehensive hydrometallurgical processes are currently under development for such concentrates, aimed at producing salable products compliant with the radiation safety standards. The choice of the hydrometallurgical processing method for radioactive rare metal concentrates is based on the mineralogical component of the concentrate, textural and structural features, the distribution of valuable components and impurities, and the content of radionuclides. A systemic approach to the selection of processing methods, in particular integrating several methods, is an effective solution. Methods may not only be combined, but also inextricably linked with each other. Hydrometallurgical processing methods include leaching by acidic and alkaline agents; sulfatization for selectively decomposing the minerals and moving the bulk of U and Th into solution; fluorine extraction process. Methods of precipitation and co-precipitation, extraction (by liquid and solid extractants), sorption, and ion exchange are used to decontaminate the solutions by removing thorium, mezathorium, uranium, and their radioactive decay products. Agents used in hydrometallurgical processing of radioactive rare metal ores include sulfuric, nitric, hydrochloric, hydrofluoric acid, alkali (NaOH, KOH), sorbents (for example, AB-17) for sorption of uranium and extractants (mono- and bidentate organophosphorus compounds, diamides, etc.) for the extraction separation of rare, rare-earth, and radioactive elements."

Jan 1, 2018

By M. S. Prithvi

Over the decades, mine and mineral processing plant operations for the most part, have been found to have had adverse impacts on the environment. At the same time, mineral processing and mining operations produce mineral products that are indispensable to modern society. Thus, the sector has desirable and undesirable attributes simultaneously. The situation presents itself as a contradiction (i.e.) the mineral processing and mining operations are wanted by society, and at the same time unwanted by society. The existing methods of addressing the issues raised above have evidently not been very successful in reducing the opposition to new projects and to the related activities such as land acquisition. This paper attempts to show the relevance and applicability of TRIZ for addressing the issue. TRIZ, or Teoriya Rezheniya Isobretatelski Zadach, is a Russian acronym meaning Theory of Inventive Problem Solving. TRIZ is a powerful tool that can be usefully applied to resolve such contradictions, using resources usually available within the system of interest. Accordingly, this paper introduces the issue background, followed by an introduction to some key concepts of TRIZ such as the 40 principles, separation principles and directed evolution. The paper goes on to apply the 40 principles to two case studies. The results show that TRIZ could be a useful tool to generate potentially innovative and sustainable approaches. Its most appropriate position would be as a supplement to current decision-making procedures, and as a validation tool to review existing solutions for possible improvements. Keywords: minerals, environment, TRIZ, contradiction, resources

Sep 1, 2012

By C. L. Tang

Parts of the wastewater are reused directly and the rest moderately purified and reused, so the utilization rate of wastewater of the whole processing plant reaches 100 percent. At the same time, beneficiation indicators have been improved stably, and great economic and social benefits have been achieved.

Jan 1, 2014

By T. Inoue, K. Okaya

"Movement of mill charge in the centrifugal mill is essentially different from that in the vibration mill with circular path despite the apparently similar mode in the motion of mill body. As proved e.g. in [11], this results in substantial advantage regarding the comminution intensity of the centrifugal mill over the conventional vibration mill accounting approximately to one order of magnitude.Back in 1983, Bradley et al. presented a model of the centrifugal mill based on the kinetics of the mill charge by regarding it as a lumped mass. On the other hand, numerical modeling by ‘discrete element method (DEM)’ enabled us to observe the movement of each ball in the centrifugal mill with an extremely minute time intervals (Inoue et al., XX IMPC in 1997). The former approach rendered simple, even though approximate, expression of the mill behavior, while the latter method was advantageous in describing the behavior of the mill in terms of individual events taking place in the mill body, even though the result did not reduce to a simple expression. The characteristics of the centrifugal mill described by both these approaches proved to be in a degree of agreement. Thus, the kinetic approach was capable of presenting the overall view of the mill, while the DEM model was informative of the details that could not be depicted well enough by the simple math expressions."

Jan 1, 2003

By Polezhaev S. Yu, I. V. Ukraintsev, Boduen A. Ya, Saburbayeva L. Yu

"Comparison studies of different technologies are performed when selecting optimum option for gold ore and concentrate processing. Methods of ultrafine grinding, oxidizing roasting, bacterial leaching and pressure oxidation are used to extract gold from refractory ores and concentrates. Refractory gold flotation concentrate produced from pyrite-arsenopyrite ores of Bestobe deposit is a case study in this paper. The results of the experimental tests of the direct leaching of flotation concentrate and pre-oxidation products using different methods (oxidizing roasting cinder, pressure oxidation and bacterial leaching cakes) are the following: - cyanidation of original flotation concentrate provides recovery of Au at 46.6 %; - oxidizing roasting increases gold recovery from 46.6 % to 85 %; - BIOX increases gold recovery up to 86 %; - preliminary pressure oxidation of flotation concentrate ensures steadily high Au extraction in the follow-up cyanidation at 94.9-96.5 %. Pressure oxidation and bio-oxidation has changed dramatically the strategy of refractory gold ore processing. These solutions provided for development of ore deposits that considered earlier non-commercial. However, refractory ore processing has a complex character in terms of developing process flowsheet and requires large amount of studies to be performed for each new project. Gold extraction is the basic but not the only criteria to technology selection for gold ore and concentrate processing. Opex and capex, ore reserves, regional geography, developed infrastructure and skill personnel should be considered. Process studies and feasibility study of the developed technology shall be provided for each specific gold ore deposit. INTRODUCTION Due to changes in available feedstock and depletion of easy-to-process ores, refractory ores containing finely disseminated gold and silver in sulphides (primarily, in pyrites and arsenopyrites) are more and more involved into processing. Experts say that such ores amount above 40 % of the world’s gold reserves. Conventional technologies of gold extraction from refractory ores include flotation, roasting and cinder cyanidation (Fraser etal., 1991). However, today’s best available practice for refractory gold ore processing are bacterial (BIOX) and pressure (POX) oxidation."

Jan 1, 2018

By Yang Xiao, Zhang Yimin, Bao Shenxu, Liu Chun

Stone coal is a unique vanadium-bearing resource in China. Many techniques, such as salt roasting-water leaching, blank roasting-acid leaching, direct acid leaching etc. have been developed for vanadium extraction from stone coal. The vanadium leaching rate can reach 74.9% for stone coal from Jiangxi, but only about 27% of vanadium is leached for Hubei ore by applying salt roasting-water leaching technique. This paper investigats the vanadium occurrence in stone coal by microscope observation and electron probe, and compares the minerals components of stone coal from Jiangxi and Hubei. Although most vanadium exist as an isomorphism by replacing Al(III) from dioctahedral structure in mica group minerals in stone coal from two regions, the free vanadium is remarkably abundant in Jiangxi stone coal than in Hubei stone coal, which results the fact that vandium is relatively readily extracted from former. Moreover, the content of calcite in Hubei stone coal is much higher than that in Jiangxi stone coal. Calcium can react with V2O5 to form water insoluble calcium vanadates during roasting and this may be the reasone why the water leaching rate of vanadium is low for Hubei ore. Acid leaching is more beneficial to the vanadium leaching but other extra methods, such as adding aid-leaching agent and/or increasing acid concentration is need for the ore where vanadium is embeded firmly. This study can effectively guide the selection of vanadium extraction techniques for stone coal from different regions.

Jan 1, 2014

By P. Bevilacqua

In this paper the possibility to complete the copper recovery and to enrich in PVC a mixture of plastic granules obtained by grinding electrical cables are investigated. The recovery of a large part of the copper still present among the plastic granules was possible by means of a mechanical screening, the finer polymeric fraction was collected, at the same time. In order to complete the copper polymer separation the following techniques were employed. Counter current separation in water, static dense medium separation with zinc chloride solution and copper extraction with nitric acid and subsequent electrolytic deposition. A Tri-Flo® dynamic dense medium separator was employed in order to separate the lighter polymeric fraction, from the heavier polymeric fraction, mainly PVC. Water or a salt-water solution was employed to feed the separator device.

Jan 1, 2014

By Silvia França, Hudson Couto

"In this paper, an alternative beneficiation process was developed to recover nickel minerals from low-grade weathered ores. The studied sample, 0.3% Ni grade, is essentially composed of nickel sulfides (pyrrhotite and pentlandite); magnetite and silicates (mostly talc and amphibolites) are the primary gangue minerals. The particle size distribution was controlled using a grinding operation to avoid producing an excess of fine particles by overgrinding. The sample underwent a grinding step for the fine degree of liberation. The slimes (-20 ?m) were removed via two desliming stages in hydrocyclones (diameters of 1.5" and 2"); the ground material, which was classified in a range of (-150+20) ?m, was processed by column flotation in three different stages: rougher flotation for magnesium silicates, rougher flotation for sulfides, and cleaner flotation for sulfides, using pilot flotation columns (2" and 6" in diameter and 20 ft high). The goal of using the preliminary magnesium silicate flotation step was to remove hydrophobic minerals (mostly talc) that would float naturally with the sulfides, which would decrease the Ni grade in the concentrate, as well as to reduce the MgO content because this compound is considered harmful in metallurgical processes when a grade greater than 9% is used. The final concentrate obtained in the cleaner flotation step reached up to 2% Ni and 7.0% MgO. The global and flotation recoveries in the process were approximately 30% and 60%, respectively, due to the losses of Ni during the desliming process. Despite this low global recovery, the adopted beneficiation process can be considered an interesting alternative to produce nickel concentrate from tailings or waste materials."

Jan 1, 2014

By Hong Zhong, Shuai Wang, Zhanfang Cao, Ting Dai

"Manganese is widely used in industries such as the steel industry and is now an essential element in modern industry. Technologies for the efficient and clean utilization of manganese resources must be developed and employed to ensure the sustainable growth of the manganese industry. Our research focuses on the use of beneficiation technologies to improve the grade of ores or the replacement of low-grade manganese carbonate ores with high-grade manganese oxide ores, and thus, to reduce reagent and energy consumption and the yield of electrolytic manganese residues from metallurgical processes; the study of leachate purification technologies; the study of electrochemical behaviors during electrolysis and energy-saving electrolysis methods; the development of chromium-free passivators as alternatives to the highly toxic potassium dichromate passivator; the non-hazardous treatment and resource utilization of electrolytic manganese residues and other manganese by-products; and the development of new manganese products. INTRODUCTION Manganese is widely used in the steel industry, nonferrous metallurgy, the chemical industry, electronics, batteries, agriculture, etc. Globally, more than 90% of manganese is consumed by the steel industry, and thus, it is said that ""No steel industry without manganese""(Banerjee et al. 2017, Zhang et al. 2017). Current manganese resources mainly include manganese ores, marine manganese nodules and waste catalysts. The total global output of manganese ore from land deposits is 18 million tons (metal volume), and the reserves, most of which is in the form of manganese oxide ores, are estimated to be 620 million tons (metal volume). More than 400 manganese ore deposits with a total reserve of 1.22 billion tons have been discovered in China. These deposits are predominantly manganese carbonate ores. Marine manganese nodules exist on the surface of the deep seabed at depths of 2000-6000 m. These nodules, which are also called polymetallic nodules, manganese balls, manganese aggregates and manganese tumors, are mainly composed of iron and manganese oxides. The total reserves of these resources add up to more than 3 trillion tons. Furthermore, the manganese in manganese-containing catalysts can be recycled after they become inactive."

Jan 1, 2018