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By P. S. Arthur

The copper I SAS MELT? process is a submerged lance bath smelting technology. In the 20 years since the process was first demonstrated on a semicommercial scale at Mount Isa in north-west Queensland, Australia, copper ISASMELT? plants have been constructed to treat concentrates or secondary raw materials around the world. The process is operating in smelters in Australia, the USA, Belgium, India, Germany, China and Zambia. ISASMELT? plants have been installed to improve the environmental performance of operating smelters and reduce costs for smelting companies. A new copper furnace is being commissioned at Southern Peru Copper Corporation in early 2007, while more furnaces are under design for installation in Kazakhstan and Peru. Copper ISASMEL T? plants are supplied as complete technology packages including engineering design services for the furnace and key ancillaries, supply of core equipment, provision of intensive training programs in operating plant environments and commissioning assistance services. The proven technology transfer process ensures successful implementation of submerged lance bath smelting into large scale plants. This paper summarises developments at recently constructed copper ISASMELT? plants.

Jan 1, 2007

By D. D. Campbell

The Hat Creek coal deposit s occur within folded and faulted Tertiary (Eocene) strata of the Coldwater Group, which comprises weakly lithified shales, siltstones and conglomerates underlying the floor and lower flanks of the valley of Upper Hat Cr eek . This upland valley,16 miles in length and 2-4 miles in width, is located within the eastern foothills of the Coast Mountains, 120 miles northeast of Vancouver, approximately midway between the towns of Lillooet and Ashcroft, in the Interior Dry Belt of British Columbia . Most of the valley floor is covered by till and glacial outwash deposits ranging up to 500 feet in depth. Became of this overburden cover , the majority of the data on the coal deposit have been obtained from diamond drilling done during 1974?76 by the property owner, B .C. Hydro and Power Authority. Because of the limitations imposed by the lack of out crop, the Tertiary geology at Upper Hat Creek is imperfectly known; however, it appears from correlation with other coal-bearing Tertiary remnants in the southern interior of the province that these remnants, including Upper Hat Creek, may represent preserved segments of the western shoreline of a Tertiary continental sea along which deltaic swamps developed and were sustained for unusually long stable periods, giving rise to the world's thickest known coal beds.

Jan 1, 1977

By Larson. William

What is Lunar In-Situ Resource Utilization (ISRU)? ISRU involves any hardware or operation that harnesses and utilizes ?in-situ? resources to create products and services for robotic and human exploration In-Situ Lunar Resources ???Natural? Lunar Resources ??Discarded Materials Lunar ISRU Products and Services ??Excavation, Site Preparation, and Outpost Deployment/Emplacement ??Mission Consumable Production ??Outpost Growth and Self-Sufficiency Benefits of ISRU ??Increased science and exploration hardware (instead of consumables) ??Increased safety, crew exploration time, and self-sufficiency ??Technology spin-in/spin-offs help recycling on Earth & space economy

May 1, 2009

By A. J. Antony Chettupuzha

During a construction project, it is important to ensure that accurate and pertinent knowledge is delivered on time to appropriate personnel. The criticality of documents exchanged or referred to by various parties, evolves over the course of the project lifecycle. Determining the criticality of documents at different stages of the project can aid companies with managing the flow of information in an organized manner, while providing for the detection of potentially disruptive, erroneous material that could result in delays and costs. Therefore, it is crucial to determine documents which have the potential to disrupt a process (by virtue of being incorrect versions etc.) so that they may be isolated or prevented from entering or interfering with the active flow of information in a project, while also ensuring standard revisions of documents are recognized and accessed accordingly. Electronic Product and Process Management [EPPM] systems provide the capability to establish and map information flow between different parties in a construction project. Analyzing an EPPM system may yield information about the criticality of certain documents within an activity, as well as isolate characteristics peculiar to documents which can assist in risk mitigation. We propose methodology that identifies such critical documents.

Aug 1, 2013

By Bruno Lafrance

Abstract - Quartz veins at the Mufferaw gold prospect and Komis gold deposit, northern Saskatchewan, are examples of oblique-extension veins that crystallized in shear and tensile fractures, which propagated and then opened oblique to their walls during a single continuous deformation event. The Mufferaw gold prospect consists of an interlinked mesh of conjugate shear fractures, tensile fractures, and veins. Oblique-extension veins crystallized in conjugate shear fractures, which opened during dilation of intersecting tensile fractures under the same far-field stress system. At the Komis gold mine, tensile and dextral shear fractures cut across granodiorite dikes. The tensile fractures formed perpendicular to the dike margins during stress transfer from the less-competent country rocks to the more-competent dikes. During extension of the dikes oblique to the bulk extension direction in the country rocks, the tensile fractures were reactivated as sinistral shear fractures. The reactivated tensile fractures and dextral shear fractures opened oblique to their walls, parallel to the bulk extension direction, and were sealed by the deposition of oblique-extension veins during the same deformation event.

Jan 1, 2004

By P. B. Demarsh

"Location: - Mine village of Perron, 11 miles east of Val d’Or in northwestern Quebec.Life; - Started production 1932, ceased 1951.Ore: - Flat lying quartz tourmaline veins within granodiorite. Gold values related to coarse segregations of pyrite. Specific gravity 2. 80.Capacity: - 30 tons 1932-35; 125 tons 1935-37; 350 tons 1937-51.Assay: - Heads 0.21 to 0.34 oz. per ton. Grade obtained by mining 600 tons daily, sorting belt reject 250 tons, balance to milling; tailings loss 0.003 to 0.005 oz. per ton; extraction 9 8. 5%.Grind: - 70% minus 200 mesh. Detention time 26 hours.Treatment: - Cyanidation process.Reagents: - Per ton, aero cyanide (NaCn) 0.36; unslaked lump lime 1.50; zinc 0. 03; lead acetate 0. 006; steel consumption 2. 50.Water: - Equal mixture of swamp creek water and underground seepage.Cost: - Per ton, sorting and crushing 0.21; grinding 0.31; cyanidation 0.11; filtration 0.05; precipitation 0.02; miscellaneous 0.22; total 0.92.Power: - Hydro-electric, 25 cycle, 12, 000 volts reduced to 550 volts.Labour: - 95% Maritime and European, balance Quebec and Ontario.Tailings: - Absorbed over large swampy area on barren mining claims.Personnel: - 1 7 men including supervision.Flow sheet: - Canadian Mining Manual 1947"

Jan 1, 1966

By T. A. Lloyd

"This paper indicates the extent to which Canadian coal mine operators have taken advantage of developments in the science and technology of coal that would allow them to better satisfy changing market demands through improving the properties of their products. At some mines, no attempt is made to alter the coal from its as-mined condition, but at most mines grading into various size ranges and hand-cleaning of lump sizes is undertaken.Over-all, Canada Jags behind most of the other major world coal producers in the proportion of its coals being processed in wash plants. To some extent, this is due to the fact that a high proportion of the coal production satisfies market demands without such treatment. On the other hand, a few of the coal mines in Canada, which produce about 25 per cent of the nation's total coal output, have in operation some of the most modern coal beneficiating equipment available, including jigs, flotation cells, water cyclones, centrifuges, disc filters and thermal dryers."

Jan 1, 1968

By M. B. Shongwe, R. K. K. Mbaya, C. K. Thubakgale, P. Mendonidis

"A low-grade nickel-bearing ore was pre-concentrated on a SB40 laboratory model Falcon Concentrator. Three size fractions, -212+125, -125+75 and -75 µm were tested with the intent to upgrade the nickel content by reducing their content of fine silica, which becomes amorphous during leaching. Separation of silica from nickel-bearing magnesium silicate minerals; hornblende, clinochlore and talc, was more efficient in the finer particle sizes, -125+75 and -75 µm, and at high G-forces. For these two size fractions, nickel was upgraded from 0.06 to 0.07%, with a reduction in silica content from 52.12 to 50.71%. Leaching of feed samples prior to pre-concentration resulted in the formation of amorphous silica, indicative of the presence of fine silica in the samples. Leaching of nickel from the -125+75 µm fraction increased with increasing G-force and feed pulp percent solids, while that of -75 µm was not influenced. The optimum nickel recovery was 15.68% to the Falcon underflow, using the feed size fraction of -75 µm, 30 G and a feed pulp solids content of 10% solids, after 120 minutes of treatment.INTRODUCTION A low-grade South African nickel-bearing ore with about 0.06% Ni was previously studied for atmospheric pressure acid leaching using sulphuric acid. The study was motivated by the continuing search for methods to treat of low-grade ores, which appear to be an increasingly important source of valuable metals as a result of a declining production from rich sulphide ores. Nickel is a base metal that is used as an alloy in steelmaking and chemical industries because of its resistance to corrosion (Haudet et al., 2015). Nickel laterite ores with grades lower than 1.50% Ni are considered to be complex ores, accounting for 70% of the global nickel reserves (MacCarthy et al., 2016). Their complex nature may be attributed to the indefinite mineralogy of these ores, in which nickel may occur in more than one mineral host. In some cases, nickel may be finely disseminated in the ore. The grade of such an ore and complex mineralogy do not justify the application of pyrometallurgical methods for extraction of nickel (Zhu et al., 2012). This suggests that there is a need for less expensive alternative methods of extraction. This study investigates the application of centrifugal gravity concentration, using the Falcon concentrator, followed by leaching to determine the effect of pre-concentration of the ore prior to extraction by atmospheric pressure leaching with sulphuric acid."

Jan 1, 2017

By C K. Bell, L. S. Collett

An AFMAG survey was flown in 1968 over the Upper Nelson River area, Manitoba. The flight direction was northwest-southeast and flight spacing was 2 miles. In the Cross Lake Subprovince, AFMAG showed that an isolated peridotite outcrop was part of a dike that extended over 80 miles. Diabase dikes are not always marked by an anomaly, but isolated cross-overs, when used in conjunction with geological and magnetic data, permit their extrapolation. Anomalies coincide with areas of sulphide mineralization. In the Flin Fion Subprovince, known and unknown northeast-trending faults are detected. The Berry Creek fault was extended south through Tramping lake, then under the Paleozoic cover. Conductors were detected at, or near, the axes of major synclines within Amisk and Snow Group sediments. Granitic terranes have low conductivity and, because they are characterized by smooth AFMAG profiles, they can be delimited. AF.MAG is being recognized as a geophysical method that can aid geological mapping and interpretation. Its most important contribution to the geologist will be in regions where out-crops are sparse.

Jan 1, 1971

By Mohsen Mohammadi, Edward Cyr

"To date, several studies have been performed on the static mechanical properties of SLM-AlSi10Mg alloy. There have also been more recent studies on the relation between scan strategy, texture, and mechanical properties of SLM metals and composites. However, there is a huge knowledge gap in the available literature regarding texture and mechanical behavior of SLM-AlSi10Mg alloy under high strain rates. Therefore, in this study, dynamic mechanical behavior of AlSi10Mg_200C alloy manufactured by DMLS technique was investigated at high strain rates ranging from 900/s to 1700/s using Split Hopkinson Pressure Bar. Texture using X-ray diffraction technique of the initial samples were measured. The yield strength, peak flow stress, and ductility increased in all samples with increase of strain rate. TEM studies have also revealed evidence of continuous dynamic recrystallization in grains after 900/s–1700/s strain-rate tests. A Taylor polycrystal crystal plasticity constitutive model was then developed to capture and predict the texture evolution and mechanical response under dynamic loading, using plastic work as a critical parameter for the onset of recrystallization.INTRODUCTION Additive manufacturing (AM) powder techniques are among the fastest advancing breakthroughs in manufacturing in recent years, defined by a bottom-up layer by layer process of joining with energy input from lasers or electron beam (Herzog et al., 2016; Gibson et al., 2015). Among alloys fabricated by SLM, AlSi10Mg is of high interest to industry and academia due to its low density, high specific strength and excellent corrosion resistance, making this alloy a viable contender for aerospace, automotive, and marine applications. Circumstances such as car crash or bird aircraft strike hazards subject potential additively manufactured AlSi10Mg parts to impact loadings. This drives an interest in understanding and predicting dynamic behaviour of these alloys. AlSi10Mg is the AM counterpart of A360 die-cast aluminum, which possess hypoeutectic microstructure (Li et al., 2015). Up to the present time, many studies have presented the mechanical properties of SLM-AlSi10Mg alloy. The mechanical properties and microstructure of AlSi10Mg produced by selective laser melting (SLM) or DMLS techniques can be controlled using different parameters, such as feedstock powder (Asgari et al., 2017), and process parameters (Olakanmi et al., 2015). The microstructure and mechanical properties of AlSi10Mg can also be controlled using post heat treatment after SLM process Li et al., 2016). The mechanical properties of SLM-AlSi10Mg are sensitive to strain rate and can both change under quasi-static (Rosenthal et al., 2017) and high strain rates (Asgari et al., 2018). However, a significant knowledge gap in available literature regarding modeling these behaviours, and especially micromechanical modeling of dynamic behaviour."

Jan 1, 2018

By T. Mulja, Michel Boily, Anthony E. Williams-Jones, Pierre Pilote

"The Preissac-Lacorne batholith is composed of suites of early metaluminous calc-alkalic gabbroic to granodioritic intrusives, three late peraluminous monzogranite plutons and numerous Li, Be and Ta-bearing granitic pegmatites. The Lacorne pluton is dominated by biotite and biotite + muscovite monzogranites containing abundant Be and Ta-bearing granitic pegmatites (40-80% volume). The pluton is surrounded by swarms of unzoned or poorly zoned spodumene-rich pegmatite dykes. The La Motte pluton is composed of biotite monzogranites, biotite+ muscovite monzogranites and rare muscovite + garnet monzogranites. Li, Be and Ta-bearing pegmatites are less abundant than in the Lacorne pluton and are commonly associated with molybdenite bearing quartz-muscovite-K-feldspar veins. In the Preissac pluton, muscovite + garnet monzogranites and muscovite + biotite + garnet monzogranites are the dominant rock types. The pluton rarely contains granitic pegmatites and these are generally barren. However, numerous molybdenite bearing quartz and quartz-feldspar-muscovite hydrothermal veins are observed.Li, Be andTa-bearing pegmatites display a crude spatial zonation around their parent monzogranites. Spodumene-rich pegmatites are generally unzoned or poorly zoned and are confined to the surrounding metasedimentary or metavolcanic rocks or crop out in the early gabbroic to granodioritic intrusives surrounding the monzogranites. Ta and Be-bearing pegmatites are usually concentrated towards the margins of their parent monzogranites. The highly fractionated nature ofmonzogranites (high Rb/Sr, low K?Rb, Ba?Sr, Zr/Nb ... ), their peraluminous composition (corundum normative and muscovite bearing) and the numerous occurrences of Ta and Be-bearing pegmatite dykes represent important criteria for the exploration of fertile granites."

Jan 1, 1990

By S. k. Kim, H. B. Trinh, R. R. Srivastava

"Spent auto-catalyst is a promising secondary resource of platinum group metals (PGMs), which are being extensively used in automobiles catalytic converters to control the hazardous gaseous emissions (CO, NOx and hydrocarbons). Several pyro or hydrometallurgical routes has been employed to recover PGMs from such spent materials but there is no proper process for recovering the other constituents metals. Therefore, it causes the loss of other major constituents like, Al and Mg along with rare earth metal Ce. In the present study, we investigate the dissolution of Al and Mg using sodium hydroxide (NaOH) roasting followed by a sulfuric acid (H2SO4) leaching; thereby concentrating the PGMs and Ce in leached residues. The effect of roasting temperature, time and amount of NaOH were varied. Subsequently, the dissolution behavior of metals in H2SO4 as a function of acid concentration was investigated from the roasted samples. At an optimal condition for roasting at 600°C with 1:1 NaOH-to-catalyst ratio and 60 min duration, the maximum of Al and Mg were dissolved in 1 M H2SO4 solution at ambient temperature (~25°C). Thus obtained leached residues containing enriched PGMs and Ce content can be treated separately for the recovery of these high-value metals.INTRODUCTION Spent auto-catalyst has been considered as a potential resource for recovering the platinum group metals (PGMs) (Jha et al., 2013). The commonly used auto-catalyst is made of cordierite (2MgO.2Al2O3.5SiO2) in which the chloro complexes of PGMs are impregnated onto the surfaces of porous washcoat of alumina substrate (Aberasturi et al., 2011). The average concentration of PGMs in ore are 2-4 g/ton for Pt, 7-2 g/ton for Pd and 0.2-0.5 g/ton for Rh, whereas, an individual catalytic converter weighing about 1 - 2 kg contains on average 1.56 g Pt, 0.62 g Pd and 0.156 g Rh (Upadhyay et al., 2013). Moreover, recovery of PGMs from spent auto-catalyst offers other advantages like, simple process, low cost and less pollution, as compared to recovery from primary resources (Dong et al., 2015).Therefore, technologies to recover PGMs from spent auto-catalyst has become attractive in the recent past and their recycling contribution has been accounted for 35% Pt, 26% Pd and 36% Rh of the quantity consumed in the production of auto-catalysts (Johnson Matthey, 2016)."

Jan 1, 2017

By J. N. Van der Merwe, M. Mathey

"The development and mechanical characterization of coal-crete, a composite material generated from coal fragments and some binder material, is described in this paper. Coal debris was obtained from a colliery in South Africa. The binder used in the study basically consists of cement and water, and further ingredients are added to the mixtures, such as sand, fly ash and polymers, in order to investigate alterations of the mechanical properties of coal-crete.Results from over 220 mechanical tests on coal-cretes with various binder mixtures give consistent trends for the material’s behaviour. Linear relationships are suggested between the uniaxial compressive strength, Young’s Modulus and the indirect tensile strength of the coal-crete.It is shown that mechanical properties comparable to coal can be achieved. Coal-crete is therefore suitable for physical modelling of mining situations in experimental studies and for use as backfill in underground coal mines. The latter application is particularly attractive when refuse coal is used as aggregate material. The indicated trends in this study may be used as a guideline for individual coal-crete design needs. However, some uncertainty remains as to the influence of particle shape, size and gradation, coal rank and age of the coal-crete. These aspects are recommended for further research."

Jan 1, 2015

"Many advances in glass technology and processing are being made and the possibilities for glass as a material in the future appear unlimited. Float glass, glass-ceramics, high-strength sheet and container glass, glass-reinforced plastics, glass for electronic equipment, aerospace glass, glass fibres, glass vehicles, glasses with selective-reflective coatings and glare-reducing glasses, to name a few, provide areas of significance at present and for the future. There appear to be great opportunities, in certain localities of Canada, to develop new sources of raw materials for an expanding Canadian glass industry.New developments in the structural clay products industry have centered around facing brick as a structural load-bearing material, prefabricated brick panels, large-sized units, isostatic pressing of sewer pipe and auto-matic settmg of brick. Fast-firing techniques, using prefired or calcined raw materials, and the development of high-strength products will result in the use of a wider range of raw materials in the whiteware and structural clay products industries.Porcelain enamel, a material used for many years in domestic appliances and for sanitary ware, now is used extensively in architecture, agriculture, water tanks, highway signs and reflectors, and in products where resistance to corrosion-plus-temperature is important. Exotic composites of ceramics and metals, and specialized ceramic coatings applied on metals by various techniques such as flame spray, plasma jet, or vapour and chemical deposition have proved useful in materials for aircraft power plants, rockets, missiles and nuclear applications."

Jan 1, 1967

By J. E. Hawley

"IntroductionA STUDY of the trace elements in the ash •of coals from nine seams in the Sydney coalfield, Nova Scotia, was undertaken at the suggestion of Dr. W. A. Bell, Geological Survey of Canada, as a part of a larger study of these and other Nova Scotia coals being made by the Geological Survey and the Nova Scotia Department of Mines under the direction of Dr. P. A. Hacquebard.The main purpose of this investigation has been to •determine if a knowledge of the trace element distribution might be of assistance in the recognition of individual seams, the distinction of which is not always easy or positive in folded and faulted strata by ordinary stratigraphic and structural means.The study has been so conducted as to afford information on the variation of trace elements in individual petrographic intervals or divisions in each of the seams examined, intervals determined by Dr. Hacquebard on the basis of their banded ingredients, vitrain, clarain, durain, fusain, etc, as observed under the microscope in polished sections. The results, as well, indicate the trace element composition of the coals of the area as a whole, and quantitative data for fifteen elements are given, along with concentrations of thirteen other elements, stated in terms of intensity ratios. Data on distribution of germanium, though considered here along with other elements, are dealt with elsewhere*."

Jan 1, 1955

By C. H. G. Bushell, G. Brown, C. J. Krauss

1N FLOTATION, copper sulphate is used universally for the activation of sphalerite and marmatite and, to some extent, for the activation of other minerals. The copper activated surface readily adsorbs standard collectors such as the xanthates and dialkyl dithiophosphates whereas untreated zir~ sulphide does not. With the host of reagents available, making a mineral float is seldom difficult. The problem is to achieve selective flotation. In zinc flotation, the great value of copper sulphate results from its ability to activate zinc sulphide preferentially to gangue minerals. At the Sullivan Concentrator of The Consolidated Mining and Smelting Company of Canada Limited, the most abundant gangue mineral in the lead-zinc ore is pyrrhotite, and the zinc mineral is marmatite of somewhat variable zinc to iron ratio. For this Cominco study, selectivity between marmatite and pyrrhotite was therefore the most interesting aspect of copper sulphate activation.

Jan 1, 1961

By Peter K. Kaiser

Planning and design of deep underground mines involves a process of complex three-dimensional data integration utilizing information from exploration (geology, rock mass characteristics), engineering (mining method, excavation geometry, stress) and operations (time, in the form of sequencing). As new logging and monitoring technologies are being developed, the amount and data complexity becomes overwhelming and decisions are often made based on only a small part of the available data. Recently, Laurentian University opened a state-of-the-art Virtual Reality Laboratory (VRL), a Mining Exploratorium that is unique in the world of mining and offers an exceptional data interpretation environment for mine planning and design. The Mining Exploratorium combines a large format spherical stereoscopic projection system, equipped with high definition projection providing the highest resolution of active stereo in the world today, with advanced features of earth modeling software. Combined, this creates the first virtual reality facility geared specifically to the interpretation of mine geometry, geology, geochemistry, microseismicity, geomechanics and mining data sets. This paper demonstrates how value can be added to the mine planning and design process by utilizing this unique tool in the mining decision-making process via better comprehension of spatial relationships of data and by interpreting the data in a collaborative immersive virtual reality environment.

May 1, 2002

By A. R. Sorta, D. C. Sego

ABSTRACT The settling, shear strength, and index properties of oil sands fines-sand mixture tailings (FSMT) for a wide range of solids and fines content are investigated. Results indicate that the liquid limit of FSMT obeys a linear mixture law. The fines-water ratio (FWR) governs the permeability of composite tailings (CT) and CT with comparable geotechnical behaviour can be produced from the same initial FWR mixtures. A phosphogypsum (PG) dosage > 900 mg/kg does not improve the dewatering behaviour of CT. The undrained shear strength of FSMT at the liquid limit is approximately 2.4 kPa, but is dependent on fines content at the plastic limit.

Jan 1, 2013

By C. M. Clapperton, K. E. Darke, A. J. Boyce, C. M. Rice, S. D. Redwood

"Abstract - The Kori Kollo gold deposit is hosted by a c.15 Ma sericitized dacite stock in the La Joya district on the Bolivian Altiplano. The mineralization is of the Bolivian polymetallic vein (BPV) type, with a significant amount of the gold reserves contained in the oxide cap. Field and microscopic studies, K-Ar dating, ??34S values of pyrite, alunite and jarosite, and ??18O values of alunite and jarosite demonstrate that some of this gold is supergene. Two types of supergene gold are present: minute gold grains, 1 to 10 microns across, of high fineness and associated with jarosite and iron oxy-hydroxides; and ‘invisible’ gold, which is probably sorbed onto minerals such as jarosite and iron oxy-hydroxides.Pyrite ??34S values fall in the limited range -3.5 ± 0.6‰, consistent with a magmatic origin. Sulfate ??34S values are homogeneous and overlap closely with those of pyrite (-1.2 ± 2.1‰), which supports petrographic evidence that sulfates replaced pyrite. By contrast, sulfate ??18O values are inhomogeneous with a large range (alunite +2 to 26‰, jarosite -5 to +18‰). These data are interpreted as reflecting kinetically controlled reactions involving various proportions of atmospheric oxygen and local meteoric water. This is typical of supergene alteration and is due to the seasonally dry climate of the Altiplano.The oxide-zone mineralogy is dominated by sulfates and iron oxy-hydroxide minerals with some phosphates and halides, which indicates that the groundwaters were acidic, oxidizing and relatively saline. Under these conditions the most likely complexes responsible for gold mobilization are halides.Geological data and K-Ar ages indicate that oxidation of the BPV deposits began at least around 11 Ma and possibly up to 15 Ma ago, and that supergene alteration lasted until around 4 Ma. During this period, erosion was minimal. Although supergene processes have been active on the Bolivian Altiplano since the Middle Miocene, in contrast to Northern Chile, enrichment of gold has not occurred."

Jan 1, 1997

By C. M. Clapperton, K. E. Darke, A. J. Boyce, C. M. Rice, S. D. Redwood

"The Kori Kollo gold deposit is hosted by a c.15 Ma sericitized dacite stock in the LaJoya district on the Bolivian Altiplano. The mineralization is of the Bolivian polymetallic vein(BPV) type, with a signi?cant amount of the gold reserves contained in the oxide cap.Field and microscopic studies, K-Ar dating, ??34S values of pyrite, alunite and jarosite, and ??18O values of alunite and jarosite demonstrate that some of this gold is supergene. Two types of supergene gold are present: minute gold grains, 1 to 10 microns across, of high fineness and associated with jarosite and iron oxy-hydroxides; and ‘invisible’ gold, which is probably sorbed onto minerals such as jarosite and iron oxy-hydroxides.Pyrite ??34S values fall in the limited range -3.5 ± 0.6‰, consistent with a magmatic origin. Sulfate ??34S values are homogeneous and overlap closely with those of pyrite (-1.2 ± 2.1‰), which supports petrographic evidence that sulfates replaced pyrite. By contrast, sulfate ??18O values are inhomogeneous with a large range (alunite +2 to 26‰, jarosite -5 to +18‰). These data are interpreted as reflecting kinetically controlled reactions involving various proportions of atmospheric oxygen and local meteoric water. This is typical of supergene alteration and is due to the seasonally dry climate of the Altiplano.The oxide-zone mineralogy is dominated by sulfates and iron oxy-hydroxide minerals with some phosphates and halides, which indicates that the groundwaters were acidic, oxidizing and relatively saline. Under these conditions the most likely complexes responsible for gold mobilization are halides.Geological data and K-Ar ages indicate that oxidation of the BPV deposits began at least around 11 Ma and possibly up to 15 Ma ago, and that supergene alteration lasted until around 4 Ma. During this period, erosion was minimal. Although supergene processes have been active on the Bolivian Altiplano since the Middle Miocene, in contrast to Northern Chile, enrichment of gold has not occurred."

Jan 1, 1997