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Comparison of Industrial Cyanide Destruction Processes

Sep 13, 2010

Maintaining high carbon activity is vital to the efficiency of any Carbon-In-Leach or Carbon-In-Pulp process. Reduced activity can lead to longer residence times or gold losses in the tails. Regenerated carbon from the CIL circuit at Macraes Gold Mine was analysed for kinetic activity and composition over a 15 month period. An increase in kinetic activity during the time period was recorded, which was linked to reduced Na and Ca loadings. A laboratory simulation of the loading, stripping and regeneration of gold was developed and tested. Kinetic activities were obtained for synthetically fouled carbons following three circuits of the laboratory simulation. It was shown the competitive gold adsorption ability of xanthate fouled carbon (previously reported as a serious deactivator) could be significantly recovered following effective thermal regeneration. This ability was maintained in a subsequent circuit loading.

Jan 1, 1993

By C A. Feebrey, R A. Duncan

The Ebor Volcano in north eastern New South Wales is an eroded example of a central-type intraplate volcanic-intrusive complex. It is of Miocene age (19 - 20 Ma) and has similarities to other central-type volcanoes in eastern Australia which may represent manifestations of sub-lithospheric hotspot activity. Thick lava flows are exposed around the Great Escarpment and are dominated by a tholeiitic basaltic suite, ranging from ol-tholeiite to qz-tholeiite to icelandite with ages of 19.2 - 19.6 Ma. On its western edge, the tholeiitic lava suite probably overlies remnants of basanite flows belonging to the Eocene (~48 Ma) Doughboy province, but elsewhere, minor alkaline basaltic lavas may be coeval with the tholeiitic suite. Several felsic bodies were emplaced into the volcano at ~19.0 - 19.2 Ma and include subalkaline and peralkaline types. The Crescent Complex is a Miocene-age, strongly differentiated mafic to felsic intrusion in basement rocks and centrally located in pre-erosion reconstructions of the Ebor Volcano. It is interpreted to be a major feeder for the tholeiitic lavas based on age and composition. Evolution of the dominant tholeiitic suite proceeded from a parental ol-tholeiite magma, through qz-tholeiite, icelandite and small volumes of felsic rocks by fractionation of plagioclase, olivine, clinopyroxene and titanomagnetite, accompanied by enrichmentof SiO2, SFeOlMgO, alkalies and HFSE.

Jan 1, 1995

By D Craw

Previous studies of alluvial gold in Otago and Southland placer deposits have suggested a gold-mercury association for some deposits derived from Caples Terrane schist, whereas alluvial deposits on Torlesse Terrane basement typically have no mercury. A regional study of gold from Otago Schist vein deposits from both Caples and Torlesse Terranes has revealed the presence of both Au-Ag and Au-Ag-Hg alloys in both terranes. Au-Ag alloy (3 - 4 wt per cent Ag) is typical for gold found in most Torlesse vein deposits, and Au-Ag-Hg alloy (3 - 8 wt per cent Ag, 2 - 8 wt per cent Hg) is found in many Caples vein deposits. Au-Ag-Hg alloys are not exclusive to the Caples Terrane, however, as Au-Ag-Hg alloys with up to 4 wt per cent Hg are found in vein material from the Torlesse-hosted, HydeMacraes Shear Zone. In addition, not all Caples-hosted deposits have a gold-mercury association; gold grains from the Carrick and Invincible gold fields have no detectable mercury. The present study characterises gold compositions from various hard-rock vein deposits and has potential for determining placer-source relationships.

Jan 1, 2003

By P Storey, B Deans, T Lancaster

Straits completed its Feasibility study on the Whim Creek Copper Project in 1996. At this stage WCCP provided Straits with an open pit mine - heap leach - SX-EW copper project to follow on from its successful Girilambone Copper Operation (GCC). Since this time Straits has continued to review WCCP investigating a number of development and production scenarios. The development of Whim Creek, early 2004 and is on schedule to commence copper production in the final quarter of 2004. On current reserves Whim Creek will produce approximately 17 000 tonnes of copper cathode per annum for three to four years, at cash costs of The paper will cover a general description of the project, the project development and key design issues. Additional construction related issues associated with the complete relocation of the GCC plant to Whim Creek will be covered in the conference presentation.

Jan 1, 2004

A fundamental component of grade control at Tarmoola Mine has been the monitoring of assaying through quality assurance programs. The programs have concentrated on issues related to accuracy and precision of leachwell and fire assay techniques, sample preparation and grade variability within a sample. An outcome of monitoring has been identification of shortcomings in the application of assaying techniques to Tarmoola ore types that contain coarse particulate gold. Leachwell has shown satisfactory precision since introduction as the primary assay technique in October 1998 but leachwell accuracy and recovery through comparison with fire assay techniques has identified bias. A bias toward higher fire assays in grades above 2 g/t invoked an investigation into the cause of the discrepancy between leachwell and fire assay. Testwork evaluated Leachwell assay recovery by varying leach time duration, which showed that by increasing the leach time improved recovery significantly. Monitoring of leachwell against fire assay had shown that a leachwell (200 g) with a one hour leach has under-called grade when compared with fire assay by up to 18 per cent, on average, for Tarmoola ore types. Alternatively, optimisation of the leachwell assaying technique using a 200 g pulp and a two hour leach has returned, on average, higher assays than fire assay by up to eight per cent. Testwork on screen fire assays, duplicate assays and fire assay to extinction has demonstrated assay variability associated with coarse, particulate gold. The variability and distribution of gold in Tarmoola ore types has emphasised the importance of high quality sample preparation for leachwell assaying to ensure liberation of gold to leaching solutions. Assay quality assurance protocols are vital to assay data integrity and enable confidence in delineation of ore-waste boundaries and provide early recognition of problematic assaying periods and isolation of grade control practices, which depart from performance standards critical to the operation.

Jan 1, 2000

By G B. Arehart, S J. Mathews, J L. Mauk

The banded nature of the quartz veins which form the Empire lode at the Golden Cross mine, is perhaps their most striking feature. Petrographic studies show that significant differences occur between the bands in terms of textures, quartz grain size, calcite, adularia and kaolinite content, and the form, concentration and mineralogy of sulfide phases.   The d18Oquartz values of individual bands within the vein material range from 7.3-10.9ë. Calculations show that the d18Oquartz values can be adequately explained by temporal variations in the system temperature, boiling and/or variations in the systems fluid/rock ratios.

Jan 1, 1995

Population growth, social inequality, pollution, global warming, poverty, overexploitation of natural resources and biodiversity loss, are a few examples of the many challenges facing the world today. Sustainable development is about meeting these challenges and improving the standard of living for the benefit of the maximum number of people. These issues concern governments, communities, environmental and social action groups and individuals all over the world. Business too, has a fundamental role to play in delivering sustainable development. In particular, sustainable development is becoming increasingly recognised as a critical issue for the oil and gas industry to address and act upon. BP is committed to positively respond to the challenges posed by the objective of sustainable development.

Jan 1, 2002

By R C. A Minnitt

This paper illustrates the use of variography and moving average plots as an aid to analysing variations in the process that can be used to direct the improvement efforts. The hydrometallurgical processes used in manganese metal production consist of sequential unit operations that include milling and reduction of manganese ores. Leaching of the reduced ore, is followed by solid-liquid separation, residue disposal, solution purification and electrowinning of manganese metal completes the process. The nearly 250 integrated process control loops rely on reports of pH, flow pressure, level, temperature and chemical analyses. Metallurgical accounting, reconciliation and process control is achieved through monitoring of the chemical and mass balances within the manganese reduction plant, requiring approximately 50 000 analyses of solids, powders and liquids each month. The largest numbers of samples are taken in the cell house. Changes and variations monitored by sample statistics ensure that the manganese products comply with predetermined specification limits. Optimising the information-value of the approximately 50 000 samples in the manganese plant is carried out in tandem with ongoing process optimisation. Variographic analysis of daily sampling data suggests that the cyclical behaviour evident in the moving average plots is only a reflection of random residual variability and not a reflection of true underlying variability related to cyclical phenomena. Low resolution in the variogram of daily sampling data masks the short-range variability that emerges when hourly data are analysed. Hourly samples collected over a 39-day period (giving 941 sample data), helped identify short-range cycles in the process. The relative distribution of variability for daily sample intervals, indicate that 57 per cent arises from V[0], 18 per cent from V[process] and 16 per cent from random residual variation. V[0] includes all the uncontrolled sampling error arising from a poor sampling protocol, the fundamental error (FE), the grouping and segregation errors (GSE), the delimitation error (DE), the extraction error (EE), etc. This confirms the suspicions regarding the suboptimality of the sampling protocol and the way it is implemented. The absence of long-term trends in the leach suggests that short-term variation (less than one day) dominates the process. While the control charts indicate that the overall processes are maintained above the lower specification limits and the target values, there is nevertheless a considerable amount of variability in the system that overhangs the processes and threatens to impact them negatively. Although the variability in the leach is above the prescribed limits, the volatility is a matter of concern because it seems to be uncontrolled. The comparison of the various sources of variability in data collected on an hourly basis suggests that the short-term random variability (V[0]) accounts for almost 50 per cent of the variability in the process. The main source of this variability is due to errors in the sampling protocol and is probably related to the size of the fundamental error (FE), the grouping and segregation errors (GSE), the delimitation error (DE), the extraction error (EE), etc. Remediation of FE and GSE will probably lead to a reduction in V[0], whereas V[process] could be mitigated by reducing the biases associated with DE and EE in particular.

Jan 1, 2008

By S Moradi

The aim of this study was to investigate the possibility of leaching zinc from the tailing (-2 mm) of Angouran flotation plant using sulphuric acid. The tails were first calcined at 800¦C for one hour. The effect of factors such as stirring rate, temperature, initial acid concentration and solid/liquid ratio, on zinc extraction were studied. The results obtained show that at the best conditions, about 91 per cent of zinc were leached using a stirring rate of 800 rpm, a reaction temperature of 50¦C, a 30 minute reaction time, a 100 g/L initial sulphuric acid concentration and solid:liquid ratio 1:6 g/ml. The P85 of the feed material was about 150 ¦m and acid consumption was 600 kg/t.

Jan 1, 2002

By K J. Thompson

This paper describes the work which has been undertaken at the Ohai coalfields in Southland to restore overburden heaps during past opencast mining operations, and procedures which have been adopted to ensure that restoration is achieved concurrent with present opencast mining activities. The system implemented for the treatment of wastewater from opencast mining operati6ns is also described.

Jan 1, 1981

ignitions caused by cutting tools have occurred at a rate of some 14 per year in UK coal mines since 1965, mostly on the coalface. The rate has held steady despite reducing output and number of collieries. Investigations were carried out over this period into factors affecting both the concentration of firedamp in the cutting zone and the igniting source. A study into detecting and suppressing ignitions on shearers has been undertaken and it is feasible to prevent certain ignitions from spreading outside the cutting zone. Practical measures have been adopted by British Coal to identify frictional ignition sites and to lay down working procedures to minimise risk.

Jan 1, 1988

By R A. Binns, S Murao

The PACMANUS and Jade deposits are two active hydrothermal fields that are forming massive sulphide deposits at the Pacific rim margin. Both are associated with felsic submarine volcanic rocks and both occur in back-arc settings. However, PACMANUS is associated with almost sediment-free dacites and lies on the crest of a volcanic ridge, whereas Jade occurs in a heavily-sedimented tectonic depression associated with a basement of pumiceous rhyolite. The PACMANUS deposit is richer in Cu and Au, and Jade in Pb. Zinc, Ag, As and Sb contents are similar. Sulfide textures at PACMANUS suggest formation of Cu and Zn sulfides by simultaneous double-diffusion involving inwards-moving seawater mixing with outwards-moving hydrothermal fluid. By contrast, at Jade there is a more complex history of formation where initial growth of barite on the sediment surface, probably associated with microbial activity, formed an impervious cap which trapped higher temperature hydrothermal solutions.  

Jan 1, 1995

By J B. Taylor

Geographic Information Systems (GIS) are being increasingly used by the mineral exploration industry in the search for new ore deposits. A mineral exploration GIS links geological and geophysical data by virtue of their geographic location in a digital map setting. Geological and geophysical data are categorised into a number of themes or layers within a mineral exploration GIS. These layers may include polygonal information such as rock type and tenements, line information such as faults and fold axes, point information such as mines and mineral occurences, and images such as gridded geochemistry and aeromagnetics. A mineral exploration GIS is a powerful tool to help the explorationist comprehend the spatial associations and interrelationships of his/her data. These spatial associations can be integrated with a mineral genesis model, to create a mineral prospectivity map to more effectively target exploration. Arguably a competent geologist who has a good understanding of the genesis of the local ore deposit types and knows their local geology backwards could intuitively derive a mineral prospectivity map. However, in an era of rapid data accumulation from many different disciplines, the ability to assimilate and understand is a huge task for any individual. A mineral exploration GIS enables the explorationist to spend more time analysing data and testing ideas, rather than finding and manipulating data into compatible formats.

Jan 1, 1994

By R G. Richards

The Australian glass sand industry produces some 2.8 million tonnes per annum of silica sand, of which about 2.0 million tonnes are exported and the rest is for the domestic market. Approximate production rates for each Australian state are listed. The variety of processing methods used in the currently exploited deposits reflects the size, location, and characteristics of the various deposits and the requirement of the end market/s. The industry uses to a large extent equipment developed for the separation of mineral sands, particularly as it applies to low grade heavy mineral deposits, where low cost, high capacity and metallurgically efficient equipment has proved eminently suitable for the production of the low value glass sands. The requirements of the domestic market, as well as those of the present and potential export markets are discussed covering quality requirements, distribution channels and other factors critical to success.

Jan 1, 1990

The sedimentary basins of this region developed in the collision zone of thePacific Ocean plate and the continent. Stresses were transmitted thorough wedge-like lithospheric blocks, such as the Okotsk Sea, East Kamchatka, Aleutian and other smaller blocks. Compression and inversion were more active at the boundaries: ***INSERT EQ*** and ***INSERT EQ*** in places. Tension, rifting and the increase in the rate of sedimentation were marked in P1-2, P3, N12, and also in N2 û Q in places. Structural plan changes of the sedimentary basins and possible oil, gas and fluid migration occurred more actively at the boundaries: ***INSERT EQ***.

Jan 1, 1995

Laboratory-Scale Magnetohydrostatic Separator for High Resolution Density Analysis of Plastic and Other Wastes Recycling and reuse of different plastic wastes is still a current problem to solve for process engineers and it is true for seeking industrial applications as well as for smaller laboratory-scale, where a given waste sample, plastic or even metallic, has to be precisely separated into narrow density fractions to gain data for industrial design or for scientific research. The principle of magnetohydrostatic separators are known even there are industrial size machines but our primary aim was the development of a laboratory-scale separator for analysis of particles of densities up to 6 kg/L and sizes up to 8 mm. Main parts of the built experimental equipment are the ferrite core with two high power coils. The shape of the ferrite core at the two sides of the separator channel was specially designed to produce isodynamic magnetic field. In these places the ferrite core was constructed from laser cut ferrite sheets. The development of the high power electric supply for the two coils was a real challenge because the high voltage and current (400 V, 30 A) and because it had to be precisely regulated for being able to set discrete relative forces on the particles. Two separator channels were made from transparent plastic. The magnetic fluid is circulated by a centrifugal pump, fresh feed is supplied by a vibrated feeder and products can be taken by built in samplers. The velocity profile in the separator channel is measured by an ultrasonic Doppler velocity meter. Paper reports about the development and itself of the magnetohydrostatic separator and about some fundamental and applied laboratory experiments with different reference particles and wastes from used cars and electrical appliances.

Sep 13, 2010

Research on the Design and Processing Characteristics of 320 m3 Air-Forced Mechanical Flotation Cell

Sep 13, 2010

By S Smit, P J. J Strobo

ZINIFEX Century Mine is a zinc, lead and silver concentrate producer. Flotation is the primary method of minerals separation in this circuit. The flotation circuit is quite large with 79 flotation cells. The levels in each of these interconnected cells are controlled at more than 45 level control stations. Due to the multivariable interaction throughout the circuit, good level control was found to be difficult to achieve by just using normal Proportional-Integral-Derivative (PID) control. As a first step in advanced process control, the FloatStar Level Stabiliser, a multivariable controller developed specifically for flotation circuits, has been commissioned at Century mine to solve the level control problems. The first section of this paper therefore discusses and shows the results and improvements obtained by using the FloatStar level stabiliser. The results and benefits of the FloatStar Flow Optimiser are discussed in the second section of this paper.

Jan 1, 2004

Platinum-group minerals (PGM) are recorded from a number of localities along theWaiau River, western Southland, and the south coast of the South Island, New Zealand. At each locality, small amounts of PGMs were recovered as by-products of historical gold mining operations. During the period 1890-1950 an estimated 1000-2000 oz. of æplatinumÆ were recovered from the region, the only area within New Zealand where PGM have been commercially exploited. The PGM suite of southern New Zealand consists of Pt-Fe alloys, IPGE (iridium subgroup, platinum-group elements) alloys, sperrylite (PtAs2), cooperite (PtS) and braggite ((Pt,Pd)S). The composition of Pt-Fe alloy exhibits considerable variation and two compositional populations are recognised. Some Pt-Fe alloy grains are chemically zoned. Iridium is the most abundant IPGE alloy phase and often contains considerable Pt, in contrast to osmium and ruthenium alloys. Cooperite and braggite grains are characterised by extremely low concentrations of Ni.   Exsolution of osmium and iridium from Pt-Fe alloy and Pt-Fe alloy from iridium is observed Several PGM host mineral inclusions which vary from single to poly-phase, display rounded to equant outlines and range in diameter from greater than 100 ¦m to less than 5 ¦m. Olivine and Ni-sulphide inclusions are only present within IPGE alloys. Pt-Fe alloy, cooperite, braggite and sperrylite host Cu-Fe sulphides, a wide variety of PGM, clinopyroxene, amphibole, magnetite and plagioclase within inclusions. Sperrylite also hosts Pd bismuthiotellurides, gold and several potassium-rich silicate phases. Similarities in inclusion phases and mineral chemistry from several localities suggest that the PGM are derived from a single (as yet unidentified), probably calc-alkaline magmatic source. This source is situated somewhere along the margins of the western Southland sedimentary basin where PGM liberated by erosion are transported down the Waiau River and dispersed eastwards along the coast by strong longshore currents.

Jan 1, 1995