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Columbia University, School of Mines, New York, N. Y. For many years the School of Mines published a Quarterly containing many valuable papers on mining, geology and kindred subjects, but the publication has been discontinued for several years and copies are no longer available for general distribution Papers by members of the staff are now sent to the various scientific societies, and only longer works are published by the Columbia University Press Publications of the Columbia University Press deal almost wholly with subjects other than geology and mining but one may be mentioned: Regulating an industry, by A. H. Stockder. An account of the experience of the Germans in attempting to regulate the Rhenish-Westphalian Coal Syndicate in 1893 to 1899; $2.50. For a list of publications, address the Columbia University Press at the above address.

Jan 1, 1933

By Edgar A. Manker

"Today's market for columbium has only developed in the last two decades, and in this sense it is ""newer"" than molybdenum, vanadium and most other steel alloying elements. In this short period, it has assumed a very important role in steel alloying and in superalloys. From a few hundred thousand pounds of columbium in 1960, consumption has grown to nearly 30 million pounds per year, with a market value approaching two hundred million dollars.To assess the outlook for columbium, we will first consider the historical development of consumption and supply, particularly noting that all of today's major mines were developed during the last two decades. From current production, we will attempt to reasonably project the future. This future may well include new producers, particularly some producing columbium as a co-product with tantalum.The growth of current applications, and emerging new applications, will be considered with regard to future consumption and in relation to future trends in pricing.IntroductionThe nineteenth century was a busy time for the discovery and naming of new elements. Among those discovered were columbium in 1801 and niobium in 1844. Although it was later shown that columbium and niobium are the same element, the two names are still used today. Niobium has been pronounced the ""official"" name by the International Union of Pure and Applied Chemistry, but columbium is still widely used in commercial practice, and we have chosen to use columbium in this paper."

Jan 1, 1981

By J. E. Gill

Discovered in 1952, the deposits have been explored by diamond drilling on and near a group of islands in lake Nipissing and from under-ground workings. The ore mineral is a uranian pyrochlore. It occurs in breccia zones in association with calcite, apatite, a?cmite, feldsiiars, biotite, magnetite, sulphides, and fluorite in varying amounts. The pyrochlore concentrations occur in a steeply-dipping gneiss series with some crystalline limestone. Trends indicate a ring structure 114 miles in diameter. The main ore zone shows evidence of repeated brecciation and a succession of replacements .giving rise to a complex of rock types. Pegmatite and lamprophyre dykes cut the ore as do calcite-fluorite veins and later faults with small displacements. Columbium and uranium occur al-most exclusively in pyrochlore, but the proportions vary. There is no tantalum and only small amounts of titanium.

Jan 1, 1957

By Aram Grigoryan

This paper addresses historical aspects and construction sequencing of the subway complex under Columbus Circle in Manhattan; the structural elements of the rehabilitation and new construction; and the challenges associated with design and construction. PB is providing engineering services to New York City Transit (NYCT) for the rehabilitation of the 59th Street/Columbus Circle Station Complex that services over 150,000 customers daily. The project involves structural repairs, modifications and new construction requiring underpinning and temporary supports, custom framing details, and construction staging procedures to meet stringent limitations within the operating transit station and around the Columbus Circle street intersections.

Jan 1, 2008

By E. H. Dix

The success of the Charpy impact test in the steel industry has led those interested in aluminum alloys to investigate the possible application of this test to aluminum and its alloys. In this paper are set forth the results of a few preliminary tests made at the Lynite Laboratories of the Aluminum Manufactures, Inc. In order to study more thoroughly the significance of the Charpy test, slow-bending tests have been made duplicating the arrangement of the impact machine. Tests have been made on both notched and unnotched specimens of a series of copper-aluminum alloys. Apparatus The standard American-made Charpy impact machine delivering a blow of over 200 ft.-lb. was much too large to test aluminum-alloy specimens of the same type used for steel, so that it was necessary either to adopt a larger specimen or to have a special light-weight hammer made. Since there is no known relation between specimens of different sixes, even though geometrically similar, it was decided to adhere to the 10 by 10 mm. specimen. Accordingly, Sauveur and Boylston, the American makers of the machine, were asked to construct a special light-weight pendulum adapted to their standard machine, this pendulum to have one-tenth the capacity of the standard. The writer wishes here to acknowledge his indebtedness to Mr. H. M. Boylston for the personal interest and care exercised in constructing this pendulum. The machine with the light-weight hammer in place is shown in Fig. I. It is mounted on a concrete foundation with the concrete covering the flange on the base of the machine. Vibration is further prevented by four 5/8-in. (15.8 mm.) foundation bolts. The large standard hammer shown against the wall was also used for some of the unnotched bars that required more than 20 ft.-lb. to rupture. When the light-weight hammer was received, it was carefully cali-

Jan 1, 1921

By Jerome Alexander

The object of this paper is to show that many of the important phenomena of metals and alloys are due to the facts that, at some stage, metals and alloys, or some of their constituents, are in a colloidal state and that a portion of the metal or alloy tends to remain in this state. The so-called amorphous phase in pure metals is an isocolloid, consisting of colloidal groups of metal molecules that may be dispersed in still more finely subdivided metal; these colloidal particles are not truly amorphous, but may consist, in part, if not entirely, of ultramicroscopic crystals; as a result the expressions amorphous phase and amorphous theory might he replaced by the expressions colloidal phase and colloidal theory. Any substance is in the colloidal state when the constituent particles consist of molecular or atomic groups, whose size varies approximately from about 100 down to about 5pp, that is from just below the limit of microscopic resolvability to the dimensions commonly ascribed to the larger molecules. Colloidality involves no assumption as to the shape, internal structure, or orientation of the colloidal particles; size alone is the critical factor. A colloidal system may therefore contain crystalline groups, or amorphous groups (non-crystalline, random or haphazard clusters), or a mixture of the two. All colloids consist of at least two phases, the subdivided substance, or dispersed phase, and the substance into which this is subdivided, the dispersion medium. It is not necessary that there be any chemical difference between the dispersed phase and the dispersion medium. As molecular forces are extremely powerful, their application may produce marked changes in the physical properties of metals. It is doubtful whether metal in the interior, especially of large masses, possesses the same properties as that on or near the surface, which alone is open to inspection.

Jan 1, 1921

By P. E. Demmler

Phosphorus combines with copper in various proportions, forming true alloys, some of which are of commercial importance. These materials find wide application as deoxidizers and as a means of introducing phosphorus into other alloys, as in phosphor-bronze. Phosphor-coppers containing 10 and 15 per cent. of phosphorus are the commercial grades that are most generally offered. Each has certain advantages when used in making other alloys. The 10 per cent, grade of phosphor-copper has an advantage over the 15 per cent. in that it has a much lower melting point and can be prepared by certain methods with a much lower loss in phosphorus. The 15 per cent. grade has the advantage of lower freight rates per unit of phosphorus and, by the method to be described, a uniform product can be prepared with practically no loss of phosphorus. Alloys of copper and phosphorus containing any desired percentage of phosphorus lower than 15 per cent. can be prepared by melting together the requisite amounts of copper and 15 per cent. phosphor-copper. Processes for making phosphor-copper may be divided into two classes as follows: (1) Those depending on the smelting of phosphate rock or superphosphate of calcium with copper or copper-bearing materials, and coal or other carbonaceous material; (2) those depending on the direct combination of metallic copper and elemental phosphorus. A number of formulas for preparing phosphor-copper according to the first method have been published. The Metal Industry' gives the following: Superphosphate of calcium, 60 lb.; granulated copper, 30 1b.; finely powdered coal, 10 1b. Similar formulas are given by Brannt2 and others, and detail variations are covered by patents, such as those of L. A. Jeffs3 and H. A. Webster.4 Among the objections to this method of producing phosphor-copper are the large amounts of raw material and resulting slag to be handled, and the difficulty of getting a satisfactory fusion. S. Skowronski5 found that at 1300' C. (2372' F.) it was impossible to get a good fusion

Jan 1, 1921

By Philip Davidson, Wm. B. Price

The object of this paper is to present, a survey of some of the physical properties of sheet nickel silver when subjected to cold rolling and when annealed at temperatures extending from 350" C. throughout the coininercial annealing range.. A number of alloys were taken from stock and analyzed. Four of these, representing low nickel and high nickel both with and without lead, were chosen for the tests. The analyses were as follows: Alloy Copper, Lead. Iron. Nickel, ManGanese, Zinc, PeR Cent. Per Cent. Per Cent. Per Cent. Per Cent. PEr Cent. A................ 64.68 Trace 0.194 6.73 0.06 remainder B................ 65.82 1.27 0.227 6.17 0.06 remainder C................ 65.44 Trace 0.345 17.83 0.08 remainder D................ 65.60 1.08 0.238 17.77 0.06 remainder These alloys were lolled in accordance with regular mill practice to approximately No. 6 R. & 6. gage. The bars (which were then coiled) were annealed together in a mill muffle and afterwards pickled in a 10 per cent. sulfuric-acid solution and cold rolled in stages of approximately one number (B. & S.) at a time to No. 18 B. & S. gage. After each stage, suitable samples were set aside for physical tests. Additional samples were chosen for tests after the bars were rolled to Nos. 8, 10, 12, and 14 gage. These samples were annealed together in the mill muffle and, after pickling, were finished on 0.050-in. gage, yielding a series of specimens 2, 4, 6, and 8 numbers hard for the subsequent annealing tests. Tensile test pieces 9 by 1 in. (22.9 by 2.5 cm.) were cut from both lots and the central portion was milled to give a test section 2 1/2 in. long by 1/2 in. wide. A distance of 2 in. was marked off on the edge of each specimen with light punch marks. In the case of the annealed alloys, Erichsen test pieces 4 by 235 in. were also taken.

Jan 1, 1921

By F. L. Wolf, G. E. Alderson

The reclaiming of nietallics from slag and sweepings is of vital interest to every brass-foundry man, but the first cost and interest on the investment often make it prohibitive for the small foundry to enjoy the benefits of a complete concentrating unit. However, the cost of such an installation and the cost of operation are often exaggerated to such an extent that foundries dispose of their copper-bearing refuse at a great loss. This paper gives the actual costs and the returns obtained in the reclaiming plant used at the Ohio Brass Co. This plant is divided into two sections—the preliminary treatment and concentrating departments. In the former occur the screening, crushing, and hand-picking operations whereby rnost of the non-valuable and heavy metallic constituents are removed. The concentrating equipment consists of an elevator, bins, jigs, ball-mill, arid table. Preliminary Treatment The preliminary treatment varies, depending on whether the material is slag, foundry-floor sweepings, or brass casting-floor sweepings. Material of the first class is produced from the operation of six Steele-Harvey and six Schwartz furnaces; the second class represents sweepings from an average of thirty-five. molding floors per day: and the last is collected around the sprue cutters and knockout bench. Treatment of Slag The slag, analyzing 30 to 40 per cent. copper, is passed over a 3-mesh yard screen (Tyler standard mesh) stretched on an inclined rectangular frame supported by adjustable legs and equipped with a hopper which directs the undersize into a barrow. The fine product, running about 20 per cent. copper and representing 20 to 25 per cent. of the total slag, goes direct to a storage bin for concentrator frrd. The oversize is charged into a No. 2 Hill cinder crusher, which takes 175 to 200 11,. to a charge and crushes two charges per hour through 'a No. 4 riddle. It

Jan 1, 1921

Column Bioleaching of a Low-Grade Nickel-Bearing Sulfide Ore Yellow Mountain Deposit belonging to GobiMin Inc is located in the Chinese Tianshan and Altay orogenic belts, Hami, Xinjiang Province, NW China. Indicated Mineral Resources of its reserve are estimated at 12 million tonnes averaging 0.40 per cent nickel. Mineralogical examination and chemical analysis indicated that the Yellow Mountain ore is a type of high Fe, low Mg and low Ni sulfide ore: the main sulfide minerals are ~8.0 per cent pyrrhotite (Fe1-xS), ~1.0 per cent pentlandite ((Fe, Ni)9S8), ~0.6 per cent chalcopyrite (CuFeS2), ~0.5 per cent pyrite (FeS2), and ~0.2 per cent violarite((Fe, Ni)3S4); the main gangue minerals are ~48 per cent olivine, ~28 per cent antigorite, ~3 per cent chlorite, ~2 per cent talc, ~2 per cent tremolite, and~1.5 per cent magnetite; the chemical analysis of the ore sample are Ni 0.40 per cent, Co 0.016 per cent, Cu 0.24 per cent, Fe 12.4 per cent, S 5.6 per cent, MgO 9.6 per cent, CaO 1.80 per cent, SiO2 48.5 per cent and Al2O3 10.3 per cent. Preliminary results of the shake flask test showed that pyrrhotite is easily leached and the high concentration of ferric iron would hamper the growth of bacteria which will bring a negative impact on the bioleaching conversely. This work aims to set up a method to prevent the negative impact of the ferric ion on the bioleaching of the ore. Two method were combined to prevent the negative impact of the ferric ion, they are adaptation of the mixed bacteria to iron ion and bleeding the off-solution periodically to control the levels of iron ion (depending on the tolerance of the microorganisms to the ferric ion) in the leaching solution. Using a mixed mesophiles composed of Acidithiobacillus ferrooxidans, Acidithiobacillus thiooxidans and Leptospirillum ferrooxidans under room temperature, a nickel recovery of 93 per cent and a cobalt recovery of 85 per cent were achieved in 280 days column bioleaching process with an average nickel concentration in the leaching solution of 2.6 g/L. The results showed that the negative effect of the ferric ion can be successfully controlled and the nickel can be bioleached successfully from theYellow Mountain ore.

Sep 13, 2010

By B. McFadzean, S. Geldenhuys

"Dynamic froth stability tests have found widespread application to quantify froth performance. However, little to no attention has been given to scale parameters in the performance of these measurements. One of the most frequently changing scale parameters in the laboratory scale is the column diameter as this directly influences the amount of material needed for testing. Four different column diameters (50, 100, 200 and 300 mm) were used for this study. Column diameter experiments were done on an industrial scale by means of manual tracking of froth growth versus time. An increase in measured dynamic stability was seen with increasing froth column diameter, which reached a limiting value at large column sizes. It is thought that this behaviour is controlled by the differences in drainage rates of the bulk froth compared to froth in contact with the wall. The column diameter required to represent full-scale froth stability is proposed. A ratio of column surface area to total bubble surface area was used to correct for different column diameters.INTRODUCTIONThe froth phase in flotation contributes significantly to the overall performance of the process (Zanin, et al., 2009). Numerous parameters have been investigated to quantify froth performance, most notably froth recovery (Feteris, et al., 1987; Seaman, et al., 2004; Vera, et al., 1999). Experimentally gathering data to determine froth recovery is challenging and for this reason froth stability has been highlighted as a possible alternative.Froth/foam stability is defined as the time of persistence of the froth/foam and is affected by numerous factors, such as: drainage of the liquid in the lamellae (gravitational and capillary), viscosity at the bubble surface, thickness of the electrical double layer and gas diffusion through liquid films caused by pressure differences between bubbles (Aktas, et al., 2008; Beneventi, et al., 2001). It is well documented in both froth and foam literature that froth/foam stability will heavily influence the performance and appearance of the froth/foam phase (Ata, 2012; Farrokhpay, 2011; Weaire, et al., 2005). Experimentally this has been explicitly proven as an increase in froth stability, characterised by water recovery, usually results in an increase in both valuable mineral and solids recovery (Wiese, et al., 2011; Banford, et al., 1998)."

Jan 1, 2018

By D. A. Huggins

Column flotation is finding increasing use in the flotation of copper, molybdenum and other heavy metals and coal. Columns have proven operational, cost and metallurgical advantages which caused us to investigate their use in the proposed Escondida flowsheet. A comparative pilot plant test with 35 tons of ore showed that one column can replace three stages of cleaning and result in a significantly higher concentrate grade with no loss in recovery.

Jan 1, 1987

By J-P Franzidis, M. C. Harris

Increasing costs, falling grades and a low gold price have caused severe problems for many of South Africa's gold mines. The need to maximise efficiency is extremely urgent. This paper describes the use of column flotation cell s to scavenge significant quantities of additional gold from flotation plant residues; in particular, very fine particles of free gold not recovered by conventional flotation. Experimental gold- specific collectors enhanced gold recovery significantly. The paper also reports the results of other plant trials, carried out on a variety of ores.

Jan 1, 1991

By Antônio Peres, Rogério Guimaraes, Lauro Takata, Harold Wyslouzil

"Serrana’s concentrator, in Araxii, has capacity of producing approximately 800,000 tomes of phosphate rock per year, with a P205 grade of 36%, from ores grading between 13% and 14% P205. The annual mining rate is around 3.5 Mt and the apatite is concentrated according to the following sequence: crushing, grinding, desliming, flotation and low and high intensity magnetic separations.Two industrial flotation columns (3.0 m x 4.5 m x 14.5 m) were commissioned in 1993 as a replacement for circuits of barite and apatite fines flotation. In 1994, four additional flotation columns of the same dimensions were put into operation, replacing 42 Wemco mechanical cells (300 ft3 each), in the barite pre-flotation, coarse apatite (two columns) and tailings regrind flotation Circuits. Overall, 66 mechanical cells (300 ft3 each) were replaced by only six flotation columns, designed by Cominco Engineering Services Ltd - CESL.The present paper describes the stages of process development, pilot plant testwork and implementation of the industrial project, highlighting the most relevant aspects of each of them. The results achieved are related to improvements in flotation selectivity, gains in P205 recovery and better process control, resulting in better quality products and lower production costs. Other benefits included a decrease in flotation reagents, electrical energy and maintenance materials consumption. These factors contributed to a significant decrease in the cost of phosphate rock production at Serrana, in Araxa - M G."

Jan 1, 1999

By Risto Lindsberg

A wide concept of flotation equipment and technologies is presented in this paper. The basis for the presentation in Outokumpu's world-wide experience in mineral processing and other related areas, and continuing research and development work done in Finland as well as abroad by Outokumpu's subsidiaries (and customers). It is understood that flotation equipment selection for a certain process stage is becoming more complicated. It is obvious that flotation equipment in grinding circuit needs different design from a multistage cleaning process. In this paper, column flotation is compared with other flotation methods. Thus three areas of flotation are discussed in this paper: 1. Flotation in the grinding circuit, Skim-Air machines 2. Rougher-scavenger flotation, conventional cells vs columns 3. Cleaning flotation, columns

Jan 1, 1988

By D. Castillo

The effectiveness of a flotation column is due principally to the addition of wash water to the froth phase. The wash water flow rate can be significant, especially so for systems yielding a high weight recovery of fine solids, e.g. zinc sulfide flotation. Therefore, it is critical to recognize and assess the impact of the water addition upon upstream separation stages. This paper examines column flotation circuit configurations using data from a portable 2 t/day pilot plant. The objective is to provide an improved basis for column design, either as a retrofit or as part of a new circuit.

Jan 1, 1990

By H. Soto, P. Lacombe, R. del Villar

"During the summer of1989, Les Mines Selbaie, with the cooperation of Université Laval initiated a research project to evaluate the column flotation technology for its concentrator near Joutel, Quebec. The experimental work involved both a 5 cm by 11 m laboratory column and a 45 cm by 10 m home-made pilot unit Amenability tests were conducted using both units on various streams of the plant. Results showed that columns are not suitable for the copper cleaning circuit because the loss of precious metals, associated with the rejected pyrite, overcome the improved copper metallurgy. On the other hand, column testing at the zinc circuit showed improved zinc selectivity.Scale-up testing was', therefore, conducted on the first zinc cleaner concentrate using the laboratory-size column. The influence of variables such as porous parger grain size, wash water flow rate, airflow rate and froth depth values on column performance was' first assessed. Scale-up parameters were then determined using the optimal operating conditions from the previous tests. Simulation facilitated the determination of the most convenient plant-scale column arrangement.A number of conclusions concerning the experimental determination of scale-up parameters are also presented."

Jan 1, 1993

By F. Villanueva Araya

Compania Minera Disputada de las Condes (CMD), an Exxon Affiliate stewarded by Exxon Coal and Minerals Company, operates two' copper mines and concentrators in Chile. Pilot plant studies were initiated in 1984 using a 0.46 meter and a 0.91 meter diameter column for the cleaning of copper concentrate. This eventually resulted in the design and operation of a rectangular column with an area of 6.8 m2, increasing the final copper concentrate grade from about 30% to almost 32'1. Cu without any loss in copper recovery. Evaluation studies of a commercial bubble generator as against the previously used filter cloth air sparger are now in progress.

Jan 1, 1990

By R. Stratton-Crawley, S. W. Wilson

"Inco's Matte Separation Plant is a unique mineral processing facility having no process tailings stream. Each product is a high-grade concentrate with strict assay specifications which are defined by the downstream refining route. The most recent column application in the flowsheet, copper scavenging in the production of a high quality nickel concentrate, is described in detail. Testwork in pilot-scale columns (0.038 m, 0.051 m and 0.10 m in diameter) was used to develop a model of the copper scavenging system. This data was then used to simulate the performance of plant-scale equipment. The relationships thus established were confirmed by a series of plant tests in a 1.8 m diameter column. Column results consistently exceeded conventional cell performance. The modelling was extended to assess full plant production requirements and, as a result, a 2.1 m diameter column was specified for this application. Engineering design for this column is currently underway and the column is scheduled to be commissioned later in 1991.INTRODUCTIONMatte SeparationINCO's Matte Separation Plant is a part of the Copper Cliff Smelter complex near Sudbury Ontario. The flowsheet and the development of column flotation within it have been described previously (Feeley et al., 1987, Wilson et al., 1989). The plant feed is a synthetic Bessemer Matte from the Nickel smelter. This matte is slow cooled to promote grain growth and typically assays 46-52% Ni, 23-27% Cu. These elements are present primarily in sulphide form (Ni3S2 and Cu2S respectively) with some metallic alloy also precipitating from the sulphur deficient matte. Minor amounts of iron, precious metals, and nuisance elements are also present.The matte separation process is, in concept, relatively simple. Following magnetic removal of the metallic alloy from the feed, the flowsheet is designed to float a high grade copper concentrate from the nickel sulphide matrix. A simplified flowsheet of the process is shown in figure 1."

Jan 1, 1991

By B. V. Clingan

A practical application of recent design concepts makes it possible to design a column cell to fit a specific set of conditions. The design and operating parameters Of a column cell installation that replaced a conventional two stage copper flotation cleaning circuit at MAGMA COPPER COMPANY, SAN MANUEL, ARIZONA using these design concepts is described. A survey of other mineral processors using column cell technology was conducted. The results of this survey will also be discussed.

Jan 1, 1987