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By M. G. Gorman

The effects of particle size, particle shape and degree of aggregation on n-dodecylamine flotation of -20 µ m quartz and glass beads were studied. A microflotation cell suitable for use with very fine particles was used in the flotation experimentation. Degree of agglomeration of particles was estimated by comparing size distributions of the quartz and beads in a dispersed system to size distributions in systems in which the collector was present. Results obtained show that in such flotation systems the fine particles are not generally present as individual particles during flotation but rather as aggregations. However, the quartz floats more readily than the beads indicating that there are some shape effects in the systems, considering the large specific surface areas of the materials it also appears that substantial amine consumption in the systems may limit flotation or lead to a requirement of greater reagent dosage for equivalent flotation to that tor larger particles.

Jan 1, 1990

By Garry M. Johnston, Matthew L. Sutcliffe, Nicholas J. Welham

"The predominant current processes for the treatment of oxidized copper–cobalt ores use a reductive acid leach to bring the desired metals into solution. However, the indiscriminate nature of acid leaching results in a solution, akin to a metal soup, containing not only the Cu and Co but also an extensive suite of other metals. These other metals, notably Fe, Mn, Al, Ca, Mg and Si, all have to be eliminated from solution before the copper and cobalt can be recovered. Generally precipitation processes are used, but these tend to result in significant losses of copper and/or more usually cobalt from solution, leading to reduced recoveries. The AmmLeach® process uses ammonia-based chemistry to selectively leach the target metals, leaving the rest behind in the leach residue. This approach eliminates any need to clean the solution of unwanted metals and the consequent metal losses. After solid–liquid separation, the leach solution is immediately subjected to separation and concentration of the copper and cobalt using solvent extraction and electrowinning. INTRODUCTION The Copper Belt extends through the northern part of Zambia and the southern province of Katanga in the Democratic Republic of Congo (DRC) and contains the richest and highest grade deposits of copper and cobalt remaining in the world. Whilst there are a number of mines that produce sulphide concentrates, using froth flotation, the largest deposits are those where near-surface sulphides have been weathered over time to form oxides. The oxides cannot be concentrated by conventional physical means to give high recoveries. Despite this, a number of dense medium separation plants have been installed and used to produce a higher grade concentrate which is typically exported (while the rejects, typically 2 to 3% Cu are stockpiled for treatment at a later date). These plants generally have low recoveries and can only be used on the dwindling supply of high grade materials. In exporting the concentrate, little value adding is undertaken within the country, thus greatly reducing the economic benefits to the country. Recent changes to the regulations in the DRC will effectively ban the export of low value ores, concentrates and intermediates in favour of high value metals. This will necessitate mines to install new processing circuits in order to comply with these regulations. The head grade of ores currently being treated in the DRC is slowly decreasing as the extremely high grade materials are being selectively mined out. In many cases, the removal of a small volume of high grade materials leaves a much larger volume of economically marginal ore behind. This is due to a desire for short-term profits overtaking long-term prosperity. The remaining ore, which in many cases is still of relatively high value by world class standards, is likely to be only treatable by low cost heap leaching. There are some initial trials of heap leaching within the DRC, but implementation at a large scale has yet to be adopted."

Jan 1, 2015

By Peter Moser, Michael Messner, Florian Bauer

The existence of ammonia in underground blasting fumes was frequently measured in various field tests (6, 7). Ammonia in fumes with a TLV (threshold limit value) of around 30 ppm (slightly different in various countries) is a toxic gas but not considered to be a high risk for the underground work force as ammonia smells very itching and is extremely annoying. This might be the reason why ammonia is hardly measured in routine underground blasting fumes control. Another reason for the lacking measurement might be the circumstance that ammonia is a very reactive gas and the ammonia sensors available on the market are very cross sensitive to other gases like carbon monoxide. Nevertheless, especially since the introduction of bulk emulsion explosives in underground blasting, complaints from miners about ammonia in the blasting fumes increased. Research work by various institutions [8] around the world relates the ammonia in the fumes back to various mechanisms. Amongst others these comprise: a) non ideal (low temperature) detonation of explosives, with NH3 in the reaction products; b) reaction between rock and non detonated bulk explosives (especially when the rock is of a basic nature (high pH value); c) reaction between shotcrete and non detonated bulk explosives. Numerous blasting tests in an experimental underground set up have been made in order to check these hypotheses for ammonia origin in blasting fumes. None of them has been found to be responsible for sometimes high concentrations of ammonia in the fumes. The major reason for ammonia concentration in blasting fumes has been found in mine water of a high pH value (either natural or from using shotcrete). The mechanism identified is as follows: the moment a non detonated ammonium nitrate bearing explosive comes in contact with mine water of a high pH value, ammonia is formed immediately. The source for the undetonated explosive is twofold: firstly there is a certain spillage of explosives when the holes are charged (especially when using bulk products) and secondly not the entire explosives detonate completely. These undetonated remaining of the explosives end up in the muck pile after blasting. In case there is water of a high pH value the reaction between the explosives and the water starts immediately. This explains also the observation why ammonia can be measured in the blasting fumes quite a long time after the blast. The majority of the ammonia is not formed during the detonation; it is formed inside the muck pile even a considerable long time after the blast.

Jan 1, 2010

By Gerald Edmunds, R. K. Waring, E. A. Anderson

Brass is liable to failure under the combined influence of stress, certain corrosion media, and time, a phenomenon commonly termed season cracking or stress-corrosion cracking. The consequences of this are serious in applications of brass generally, including the important field of cartridge cases. Cartridge cases (70 Cu: 30 Zn) that fail from this cause may allow the escape of gas from the gun breech, a hazard to the shooter, and may not eject, thus temporarily putting the gun out of action. In loaded cartridge cases, the stress present is partly residual from the, drawing and necking operations and partly applied by the insertion of the projectile. Ammonia, present as a decomposition product of smokeless powder, air and moisture constitute corrosive media. The prevalence of season cracking has been reduced considerably, but not eliminated, during the past quarter of a century by low-temperature annealing to relieve stresses residual from fabrication, a method suggested by Diegel 38 yr. ago(I).2

Jan 1, 1945

By V Radmehr

Ammonia and Amonium salts have been recognized as effective leaching agents in hydrometallurgical processes due to low toxicity and cost, easy recovery and high selective recovery of metals. New research findings of considerable advantages of leaching by these agents and elimination of problems associated with acid leaching has resulted in a new approach in the world to this method. The investigations in this field indicate more frequent use of this method for extracting copper from ore and concentrate relative to other basic metals. In this paper, we have attempted to describe the basis and different ammonia leaching methods and present the major research activities in this field for copper. We have also presented the latest findings and related novel processes. Comparative assessment of advantages and disadvantages of this method relative to acid leaching method, kinetic study of copper ammonia leaching and evaluation of Eh-pH diagrams in a system containing water and ammonia are other parts of our study. Finally, by describing the studies on copper extraction from the resulting pregnant solutions, the applicable extraction agents have been reviewed.

Sep 1, 2012

By W. P. C. Duyvesteyn, B. J. Sabacky

Reprinted with revisions from Extractive metallurgy of copper, nickel and cobalt, volume I: Fundamental aspects. ed. Reddy R.G., Weizenbach R.N. Warrendale, Pennsylvania: The Minerals, Metals and Materials Society, 1993. Development work on the Escondida process, concluding with the successful operation of an integrated leach-SX-EW pilot plant and a pilot flotation plant for the upgrading of leach residues, demonstrated that all major process objectives could be achieved. Extraction of 40% of copper in concentrates containing monovalent copper was achieved with essentially no oxidation of sulphide sulphur. The Cu contents of leach residues from four different types of concentrate were successfully upgraded to the original feed grades, giving a product that has potential as a high-quality concentrate for the smelter market. A compact solvent extraction section effectively recovered the ammonia lixiviant for recycling to leaching and selectively transferred Cu into a conventional acid sulphate electrowinning system. High-quality "six-nines" copper cathode was produced on commercial-scale stainless steel blanks, demonstrating that the process will be able to compete effectively in the premium cathode market

Dec 1, 1995

By Thomas Genty, Pascal Marcotte, Matthew Gillman, John Baechler

Elevated concentrations of ammonia nitrogen is a common characteristic of mine impacted water and generally results from the dissolution of undetonated explosives (i.e., Ammonium Nitrate and Fuel Oil and emulsion explosives) by contact water. Several active water treatment technologies are commercially available to remove ammonia nitrogen, but reduction of active treatment demand by promoting natural attenuation is considered best industry practice. In this paper, the results of laboratory-scale and full-scale trials of a semi-passive approach (i.e., enhanced algae growth) to remove ammonia nitrogen at the Meliadine mine are presented. Phosphorus was found to be the limiting factor to algae growth at the mine site. The addition of various concentrations of phosphorus was first tested at a laboratory scale. The samples were exposed to in-situ conditions, and ammonia nitrogen removal rates ranging from 40% to 93% were achieved over a period of 24 days. This paper also presents the methodology and results of an in-pond treatment during which a 50% ammonia nitrogen removal rate was observed after 68 days. The studied mine site uses breakpoint chlorination as its primary treatment approach for ammonia nitrogen removal. The results presented in this paper show the potential of using enhanced algae growth as a pre-treatment method, subsequently reducing the quantity of chemicals required for operating the breakpoint chlorination plant. This potential requires further investigation and additional trials are currently under evaluation.

Jan 1, 2023

By S. W. Asihene, K. Osseo-Asare

The thermodynamic data necessary for the quantitative treatment of Metal-NH3- H2O systems at elevated temperatures are lacking in the literature. As a result discussions of the chemical basis of high temperature processes, such as leaching and hydrogen reduction, have tended to rely on low temperature thermodynamic data. In this paper a critical review is presented of the available high temperature data for metal ammine formation in aqueous systems, and methods are suggested to enable extrapolation of elevated temperature stability constants from low temperature thermodynamic data. Predictions of the Van't Hoff Lsobar, the simple cation Correspondence Principle (whereby metal ammine complexes are treated as simple cations) and Helgeson's Electrostatic-Nonelectrostatic Model are compared with the available high temperature stability constants for nickel ammines. Up to 80 °C all three estimation methods yield results which are in agreement with experimental data. However, serious deviations occur at higher temperatures; the various models overestimate the stability constants in the order Van't Hoff Isobar > electrostatic-nonelectrostatic model > simple cation Correspondence Principle. Using the experimental nickel data as a basis, a method is presented which permits reasonable estimates to be made of the stability constants of metal ammine complexes for temperatures above 80 °C.

Jan 1, 2004

By F. A. Forward

"IntroductionTHE LYNN LAKE MINE, situated in Manitoba about 150 miles north of Sherridon, has been actively developed by Sherritt Gordon Mines, Limited, during the past seven years, resulting in the establishment of a proven reserve of over 14,000,000 tons of ore containing 1.223 per cent nickel, 0.618 per cent copper, and additional cobalt values. For many years, the Sherritt Gordon Company operated a copper-zinc-gold mine at Sherridon but, as this mine was approaching exhaustion and as it was proposed to use the mining and milling equipment to treat the Lynn Lake ore, a number of unusual problems were faced in transferring plant and operations from the one mine to the other, and particularly in preparing to undertake nickel production.Preliminary investigation showed that the ore could be concentrated by flotation to produce a copper concentrate containing 28 to 30 per cent copper with less than 1 per .cent nickel, and a nickel concentrate containing 11 to 14 per cent nickel, 0.3 to 0.4 per cent cobalt, and less than 2 per cent .copper, with high recovery of the three metals in .the concentrates. It was apparent that, initially, the copper concentrate could be economically smelted and refined in the usual manner. But as the nickel concentrate contained an insignificant amount of precious metals (less than 0.02 oz. per ton) and as .it had a much higher nickel content than comparable concentrates normally produced from sulphide ores, the selection of a treatment process and the location of a plant required careful study."

Jan 1, 1953

By S. -Y. Hwang

An ongoing problem for industry in Korea is effective removal of heavy metals from and safe disposal of spent power plant fly ash. This research endeavor attempts to develop selective separation of Ni from leach liquor using a selective chemical precipitation method. The research was conducted by changing two variables, the pH and the concentration of ions in solution. The effect of other ions present in the system on the separation efficiency of Ni species was also investigated by adjusting OH and NH3 concentrations. In the pH range of 7-9, the chemical precipitation method produced a high yield of Ni by precipitation from the fly ash leach liquor.

Jan 1, 2010

By I. Nishkov, I. Grigorova, M. Ranchev, S. Dzhamyarov

"Chelopech concentrator (part of Dundee Precious Metals) is located in central-western Bulgaria. The current process plant utilizes conventional primary crushing and SAG mill grinding, copper and pyrite rougher and cleaner flotation stages to produce a marketable gold-rich copper and pyrite concentrates. As in the most processing plants, the pyrite depression is carried out alkaline media using lime. The subsequent activation of pyrite mineral is achieved by adding sulfuric acid, which has an adverse effect on the flotation equipment. Therefore, a series of laboratory flotation experiment for activation of lime depressed pyrite by ammonium salts, such as ammonium chloride (NH4Cl), ammonium sulfate (NH4)2SO4 and ammonium bicarbonate (NH4HCO3), have been conducted. The obtained results showed that ammonium bicarbonate proved to be the most appropriate reagent choice for pyrite mineral activation. These results are confirmed by X-ray photoelectron spectroscopy (XPS), performed to determine the surface chemistry of pyrite in its natural state, after lime treatment and subsequent treatment by NH4HCO3. The registered XPS spectra indicate that the hydrophilic phases on the pyrite surface could be efficiently removed by using the ammonium salt NH4HCO3. The industrial use of NH4HCO3 as an activator of lime-depressed pyrite is a possible alternative for sulfuric acid replacement as a most widely used pyrite activator. Flotation experiments with addition of 200, 400, 600 and 800 g/t from each of the studied ammonium salts have been conducted. Furthermore, the impact of the flotation pulp pH within the scope of 9.00 – 10.50 was also investigated. The obtained results from the laboratory flotation experiments, showed that the pyrite activation with ammonium bicarbonate is an excellent possibility for replacing the sulfuric acid as main pyrite activator reagent, in order to eliminate the gypsum accumulation during the flotation of pyrite in Chelopech concentrator.INTRODUCTION The Chelopech deposit, located about 60 km east of Sofia is one of the largest Cu-Au deposits in Europe. The ore have complicated mineralogical and chemical composition. The main ore minerals are represented by pyrite, enargite (luzonite), tennantite, chalcopyrite and bornite. The average copper content of the mined ore is about 1.1 % and the gold content is about 4.0 g/t."

Jan 1, 2018

By Irvine G. Reilly

Results of a preliminary study of the ammoniacal leaching of covellite (CuS) in an aqueous oxidizing system in the presence of a non-miscible organic sulfur solvent are described. Up to 60% of the sulfur can be recovered from the solvent as elemental sulfur 1 while achieving high degrees of solubilization of the mineral. The effects of temperature, particle size, oxygen pressure, ammonia concentration and ammonium ion concentration on the degree of sulfur recovery were investigated. Maximum recoveries were achieved at moderate temperatures and in well-buffered systems, with a large excess ammonia concentration. Oxygen pressure and particle size were found to have little effect on fractional recovery of sulfur. A simple empirical model based on electrochemical theory correlating the effects of some of the parameters cont-rolling the degree of sulfur recovery is presented. The results of this work also confirm that in any proposed reaction mechanism for the oxidative ammoniacal leaching of copper sulfides, the primary oxidation product of the sulfide ion in elemental sulfur.

Jan 1, 1978

By R. L. Nyirenda

One of the problems with ammoniacal-ammonium carbonate leaching of EAF carbon steelmaking flue dust is that zinc present in spinel phases is not leached. This paper presents results of test work in which prior to leaching, EAF dust was reduced with CO containing gas to decompose the spinels into zinc oxide and iron bearing phases, mainly metallic iron and wustite. From such reduction products, the amount of zinc leached increases but the iron co-leached becomes extensive. The effect of various leaching parameters such as liquor concentration and redox potential on zinc and iron dissolution has been investigated. Supplementary experiments utilizing pure zinc oxide and pure iron phases were also carried out. Results show that the co-dissolution of iron from severely reduced EAF dust cannot be prevented. This is because the wustite phase contains zinc which can only be leached when iron also dissolves. Further, the zinc bearing wustite phase is not totally soluble so that the residue cannot be made zinc free. In the absence of air, dissolution of metallic iron hardly occurred, though in leaching experiments of a long duration its transformation to a spinel structure was observed.

Jan 1, 1992

By Louis W. Towle

A brief history of the use of Ammonium Nitrate in explosives and blasting agents is given. Methods of manufacture and physical properties of the various types of Ammonium Nitrate are given with particular reference to their use in blasting agents Important properties of blasting agents discussed are sensitiveness, methods of initiation, velocities of detonation, strength, density, products of detonation, rate of pressure development, and borehole pressure.

Jan 1, 1959

By Adolph V. Mitterer

International Minerals and Chemical Corporation operates one of six potash mines in the Carlsbad potash basin. More than 90 percent of America's potash is produced at Carlsbad and IMC accounts for about one-fifth of that amount, Since the Company began operations in 1941 it has mined nearly 50 million tons of ore. Of the two types of ore mined at Carlsbad the principal tonnage is sylvinite in which sylvite-potassium chloride-is the ore mineral. It is produced by IMC as well as by all other mines in the area, In addition to sylvinite IMC is the exclusive producer of langbeinite ore--potassium-magnesium sulfate. From its two ores, International produces a spectrum of 8 high-quality agricultural and industrial chemical products.

Jan 1, 1959

By Agung Wibowo

The incident of Ammonium Nitrate explosion in Beirut on August 4, 2020, became a wake-up call to Ammonium Nitrate stakeholders for mining and construction regarding the deadly risks associated with explosives management. This is a very expensive a lesson learned for all parties involved in the storage of explosives.

Feb 1, 2020

By J. Petersen, T. Moyo, D. Maharaj

This study investigates the effect of ammonium thiosulfate on the leaching of gold from the contacts of unpopulated cut electronic printed circuit boards (PCBs). Studies in the literature show ammonium thiosulfate to be a viable option in comparison to the commonly used but hazardous cyanide leaching route. However, the simultaneous dissolution of Cu interferes with the Au leaching reaction, often limiting the extraction to moderate levels. To optimize the system, an ammoniumthiosulfate system containing 0.5M ammonia, 0.5M ammonium thiosulfate, and Cu(II) sulfate at varying concentrations was studied as an alternative hydrometallurgical option for the recovery of gold from PCB. Tests were done with unpopulated standardized model PCBs (cut to 15 x 30mm pieces). Gold extraction of 47.3% was achieved after a 24-hour leaching experiment with a 0.02M copper background concentration. Further experiments focused using different initial background Cu concentrations (0M – 0.1M) to determine its effect on both gold and copper extractions. An initial Cu concentration of 0.045M resulted in the highest gold extraction, with 93.7% extraction after 6 hours of leaching. Further analysis of the data shows that the kinetic rate of gold leaching is correlated in a first-order dependence with the actual copper concentration in the solution, which increases with the concomitant dissolution of copper and gold from the PCBs. A lower threshold of 0.017M and an upper threshold of 0.15M copper in solution were determined, in between which gold extraction shows this first-order rate increase. The upper threshold is potentially linked to the onset of copper precipitation, which blinds the metal surfaces, slowing further leaching. The findings of this study suggest that in an industrial recovery operation of gold from waste PCB using the thiosulfate method, copper concentrations need to be carefully monitored, and the process should preferably operate with uncut or coarsely cut untreated boards to minimize exposure to copper circuits.

Dec 11, 2024

By C. Dorfling, P. Albertyn

"Hydrometallurgical recovery of metals from printed circuit board waste typically involves multiple leaching stages; conventionally, base metals dissolution by mineral acids is followed by leaching of gold using cyanide or halide based lixiviants. Alternative lixiviants for gold leaching can reduce the potential hazardous nature of operation. The aim of this study was to investigate the feasibility of using thiosulfate as lixiviant for gold leaching from waste printed circuit boards. Batch leaching tests were performed to investigate the effects of thiosulfate concentration (0.1 – 0.2 M), ammonium concentration (0.2 – 0.4 M), pH (9 – 10.5), solids content (25 – 50 g/L), and copper content of the feed material on the gold leaching behavior. The concentrations of metals in liquid samples were determined by means of inductively coupled plasma atomic emission spectroscopy, and high pressure liquid chromatography was used to evaluate thiosulfate degradation/consumption. The ratio of thiosulfate to ammonia was found to have the most significant effect on the extent of gold leaching, with the best gold extraction observed at a ratio of 0.5 mole thiosulfate per mole ammonia. The lower pH range of 9 – 9.5 generally produced better Au leaching, while low copper extraction during the first stage base metal leaching stages has proven to be detrimental to gold leaching from the residue. Thiosulfate degradation/consumption increased and gold extraction decreased with higher residual copper in the feed. An optimum gold extraction of 78.5 % from base metal leach residue was achieved with 0.2 M thiosulfate, 0.4 M ammonia, and 0.02 M cupric ions at 25°C in the pH range 9 – 9.5.INTRODUCTION Background and Aim The recycling of e-waste is becoming increasingly important as it provides certain economic benefits apart from the obvious environmental benefits. Printed circuit boards (PCBs) are found in most forms of e-waste and contain especially high concentrations of base and precious metals. Hydrometallurgical processes are often considered for the recovery of valuable metals from PCBs; these processes normally implement several leaching stages to selectively recover certain metals."

Jan 1, 2018

By William A. Gibson, Kenneth P. Neumann

In 1967, development of the Cyprus Thompson Creek molybdenum deposit began near Challis, ID. The first mining claims were staked on an intrusive rock out-crop. Exploration continued for 14 years. In 1978, the decision was made to develop the deposit. In Dec. 1980, approval was received for the environmental impact statement and facilities construction and waste rock removal began. By the middle of 1983, 126 Mt (139 million st) of rock had been removed and all facilities completed. Location The Thompson Creek project is located about 58 km (36 miles) southwest of Challis in Custer County, in south central Idaho. The mine and mill are situated between 2.2 and 2.6 km (7,217 and 8,530 ft) in elevation. The project is located in an isolated area. Surrounded by mountains, it is adjacent to the Sawtooth National Recreation Area. The Salmon river is 8 km (5 miles) south of the project. The project claim block is lo-

Jan 1, 1984

By Francis Foley

FROM the point of view of the metallographist, the adaptation of x-rays to the study of the crystal structure of metals is of the greatest importance. While one may hardly consider the findings resulting from x-ray study as revolutionary, their positive nature, compared with the deductions we have been forced to accept from the work that had gone before, gives firmer ground on which to build and furnishes new fields for speculation. Prior to the advent of the crystallogram, the best work on the crystal structure of steel was that of Osmond and Cartaud.1 They concluded, from their investigation with percussion figures formed at various temperatures, that alpha, beta, and gamma irons belonged to the cubic system and that they showed well-marked specific characteristics and could not have the same internal structure. What the internal structures were, they had no direct method of determining; but from a consideration. of the fact that the 001 plane (that parallel to the cube face) is a plane of perfect cleavage and minimum hardness in alpha iron and that the 111 (octahedral) plane is by far the most important in the crystallography of gamma iron, they were led to suggest the simple cubic arrangement as that of alpha and the face-centered cubic arrangement as that of gamma iron. They suggested the body-centered cubic arrangement as that of beta iron. The atomic arrangement of the various crystal forms of iron has been quite definitely determined in recent years by means of x-rays and the work of Westgren2 and Westgren and Phragmèn3 has been rather conclusive. They not only determined the atomic arrangement of alpha, beta, and gamma iron but also that of the high-temperature modification delta.

Jan 10, 1925