Search Documents

By C. Heckman, M. S. Moats, A. Luyima, W. Cui

"Nucleation and growth of copper on 316L stainless steel from synthetic acidified copper sulfate was studied in the absence and presence of chloride ions and/or organic additives – HydroStar® 4208, DXG-F7® and Cyquest® N-900 – using a potentiostatic technique. The current–time data obtained at 0.16V versus the SHE were analyzed using nucleation and growth models. Scanning electron microscope (SEM) images of deposits produced at 300 A/m2 show that the addition of 20 mg/L chloride ions increased the size and reduced the number of copper nuclei. Potentiostatic current–time data from the electrolyte without organic additives, and confirmed by SEM images, indicate progressive nucleation with two-dimensional growth under diffusion control. None of the organic additives studied at a concentration of 2.5 mg/L with 20 mg/L chloride changed the nucleation and growth mechanism, but the additives increased the number and reduced the size of copper nuclei, leading to more uniform coverage of the stainless steel substrate.IntroductionElectrowinning of copper is an important process in the manufacture of high-purity copper metal. Approximately 20 percent of the world’s refined copper is produced from acidified copper sulfate solutions by electrowinning (Schlesinger, Sole and Davenport, 2011). In many plants, copper is electrodeposited on AISI 316L stainless steel substrates for a period of 6-7 days, after which the copper is stripped from the blanks. Even though the deposition time for a commercial copper electrowinning circuit is around one week, it is critically important to control the nucleation, growth and nature of the initial deposit (Sun and O’Keefe, 1992).Deposit morphology and structure are influenced by the real current density at the electrode surface. The real current density across the cathode surface is made uniform by proper design of the electrowinning cell and electrodes and careful operational practice. Even with good design and control, some current maldistribution occurs. The outcome of severe current maldistribution is poor deposits that affect product quality and/or increase energy consumption. To combat current maldistribution and create a larger operating window in terms of current density, temperature and copper concentration, small amounts of organic smoothing agents – traditionally, guar products – are added to copper electrowinning electrolytes. Moreover, these additives inhibit the growth of copper nodules and lead to improved deposit quality by producing bright, smooth and dense cathodes.Recently, the use of polysaccharides, such as HydroStar 4208 and DXG-F7, and polyacrylamides, such as Cyquest N-900, has been reported in commercial electrowinning tankhouses as replacements for guar (Ashford, Clayton and Sandoval, 2012; Robinson et al., 2013; Sandoval, Morales and Bernu, 2010). However, little information has been published on the effect of these new organic additives, especially regarding the nucleation and growth mechanisms of copper electrodeposits in their presence."

Jan 1, 2016

By A. D. Davis

The disposal of spent ore from cyanide heap-leach processing facilities is of concern to the mining industry, regulatory agencies, and the public. Disposal of several hundred million tons of additional spent ore is planned in the western United States during the next decade, with increased amounts likely if gold prices rise. In the past decade, more than fifteen million tons of spent ore have been disposed of in the Black Hills. South Dakota's off-loading criterion for cyanide has been set by the state's Department of Environment and Natural Resources at 0.5 parts per million (ppm) as weak acid dissociable (WAD) cyanide. Nitrate off-loading limits vary for each mine in the state, depending on ore type and other factors. Nitrate concentrations in leachate from spent ore depositories could be caused by conversion from other nitrogen-containing species. One likely source of nitrate is residual explosives from blasting of ore. Previous work on the combustion products of nitrogen explosives has shown incomplete 3xidation (Johansson and Persson, 1970). Another likely nitrate source is degradation of cyanide to ammonia, followed by oxidation to nitrite and nitrate.

Jan 1, 1994

By S. Borner Schweizer

An overview over SAM’s approach to assess corporate sustainability performance illustrates how sustainability challenges are linked to trends, assessment criteria and finally company performance. This process is exemplified with some general and industry specific criteria. Lastly, results of the Dow Jones Sustainability Assessment 2004 show a considerable gap between leading and average companies. Best practice examples demonstrate how lagging companies could improve their sustainability performance.

Jan 1, 2005

By R. Cohen-Alloro

Classical apparatus for granulometric separation generally have limited applications which are found either in the level of the size of separation or in that of the accuracy and the efficiency of the separation or in that of the rate of feed. In industrial practice, the classification of the products of coarse dimensions generally poses no problems. On the contrary, the separation of fine particles presents some difficulties, however the apparatus is used (mechanical classifiers, curved screens and sieves, hydrocyclones, etc...). These difficulties are due to hprfections of separation, rather high cost prices, and sometimes large amounts of recycled materials.

Jan 1, 1970

By L. M. English

In the past 30 years, the research arena has changed significantly in all fields, mining included. The relative representation of the topics of research, how the research is performed, and who has performed the research have all changed significantly over these decades. Although there are a lot of subjective ideas concerning these changes, and there is a fair amount of anecdotal "analysis," there has been no actual study of these trends to verify the facts. The period studied is divided into six five-year periods for the purposes of comparison. Some of the trends analyzed are as follows: ? Co-authorship ? Research areas ? Research sponsors ? Cooperative efforts

Jan 1, 1995

By Myron W. Mellor

Our efforts at McNally, to find a better way to mechanically separate particles from liquid in a slurry have led to the development of two new centrifuges. The first unit utilizes a slotted opening screen as the filter media and retains all plus 200 Mesh and most of the 200 by 300 Mesh particles. The second unit is a solid bowl centrifuge with a novel method of removing the solids and delivers an effluent containing as little as 300 PPM solids in suspension. The first unit was designed to separate particles in the range of about 1 MM x 0 or smaller top size from the liquid slurry and produce solids having low surface moisture content, and a liquid concentrate containing a low percentage of solids. A prototype of this unit has been in the field undergoing tests for over two years. A few of these test results are shown in Tables I & 11. Testing has been mostly limited to the field of coal, how- ever this does not mean that the machine would accept only coal slurries. The machine has produced a dewatered product having as low as 5.5% surface moisture, and an effluent containing as low as 1.4% solids and handled slurries containing from 15 to 50% solids by weight.

Jan 1, 1975

By R. L. Grayson

Following lip on a USBM-sponsored research project, the authors have utilized the knowledge-base structure and system concepts from the Sun Sparcstation-based worker scheduling system of the Mine Management Support System to develop a PC-based application. The new software adopts the nested-window concept to facilitate data collection and modification on personnel, their availability on a shift, and work priorities for a shift as well as to allocate manpower optimally on a work shift and delineate supervisory training responsibilities. The various components of the software are described in detail, along with enhancements made to the original system.

Jan 1, 1996

By David J. Barr

Public Law 91-190 - January I, 1970 states that, "The purposes of this Act are: To declare a national policy which will encourage productive and enjoyable harmony between man and his environment; to promote efforts which will prevent or eliminate damage to the environment and biosphere and stimulate the health and welfare of man; to enrich the understanding of the ecological systems and natural resources important to the Nation; and to establish a Council on Environmental Duality." The administrative aspects of this National Environmental Policy Act of 1969 have in essence established the requirement that all agencies of the Federal government assess the consequence of their actions with an Environmental Impact Statement. Furthermore, five states have already enacted environmental legislation, and others will surely follow. The Environmental Services Project Director for Dames and Moore has stated in the June issue of that company's publication, "Elements," that, "The nuclear power industry has perhaps been most affected to date by the Act [NEPAL but recent court decisions, legislative trends and general public concern will accelerate the spread of the Act's impact on other industries. Mining and petroleum are already involved in environmental affairs." There can be little doubt that within a very short time all environmental aspects of the minerals industry will be strictly regulated and monitored by some agency of Federal and/or state government. Indeed, it is probable that any future effort to extract natural resources will be contingent upon a favorable review of an Environmental Impact Statement. It is also quite possible that continuation of present operations will have to be justified on the basis of proof of an acceptable environmental impact. It is the objective of this paper to present some ways in which remote sensing technology can be applied toward an efficient collection of environmental data necessary for the preparation of an Environmental Impact Statement.

Jan 1, 1972

By S. J. Jung

In recent years, the use of shotcrete, a practice familiar to the mining industry, has been on the increase. This research has come about because of the recognized need for a safe, easy way to line small diameter bored raises (less then 150cm). Up until now, an operator has gone down the raise and applied the concrete lining manually, using the shotcrete method of application. With an automated system, there would be no man positioned in the bore itself. All control functions could be commanded from a central location. Shotcreting in the confined space of a small diameter bored raise presents problems that can be overcome by the application of shotcrete using a remote system.

Jan 1, 1994

By Warren W. Frech

11.1-FRAGMENTATION PRINCIPLES WARREN W. KRECH Energy must be supplied to rock by direct or indirect means to fragment that rock. The amount is dependent upon the properties of the rock and the type of loading system. Fragmentation energy is consumed by three main mechanisms: (1) creation of new surface area (fracture energy), (2) friction (plasticity) and (3) elastic wave energy dispersion. The loading method determines the relative proportions and the amount of energy consumed in fragmenting a given rock type. Unconfined tensile failure consumes the least energy, with an increasing amount of energy required as the rock is more highly confined within a compressive stress field during fragmentation. The way energy is applied by tools to cause rock or mineral fragmentation is important in determining fragmentation efficiency. Rock-tool interaction should always be controlled to the fullest extent possible to optimize the combination of rate of energy input and fragmentation energy requirements. While the direct cost of energy, (dollars per horsepower-hour) may at first glance appear low relative to other hourly costs, there is a tie between power consumption and other cost factors, such as maintenance and wear. A high rate of energy application utilizing a rock-tool interaction producing only unconfined tensile failure would provide the most efficient fragmentation. No tool that produces a combination of high energy input rate and a loading system that produces failure under only conditions of unconfined tensile load now exists. Present mining methods and tools produce failure under conditions of high compressive confinement, high dispersive energy loss and high frictional energy requirements. Thus, while generally applying energy at high rates, they are highly inefficient with respect to energy consumed in fragmenting rock. To best design fragmentation tools and optimize fragmentation systems it would be desirable to know how rock properties influence breakage. At present, rock properties directly- related to fragmentation are undefined. Although present testing technology- does not permit rigorous definition of in-situ rock fragmentation behavior, several properties (mechanical and physical) commonly are used to indicate the relative case with which rock breaks. The more common test is for uniaxial compressive or tensile strength of cylindrical cores taken from intact portions of the in-situ rock (testing details are provided ill Sec. 6.2, Rock Mechanics). The strength of rock is influenced by the environmental conditions imposed on the rock. Those of most importance in rock are (1) confining pressure. (2) pore fluid pressure, (3) temperature and (4) rate of load application. Increase in confining pressure, as with increasing depth beneath the earth's surface or under the action of a fragmentation tool, causes an increase in rock strength. Increases from atmospheric pressure to 10.000 psi commonly cause up to n fourfold increase in the compressive strength of crystalline rock. Apparent rock strength decreases as pore fluid pressure increases, since it decreases the effect of confining pressure. The effective stress concept of soil mechanics generally applies to rock. Although chemical effects of pore fluids influence rock strength, they geologically are small compared to the confining pressure effect, except for a small minority of rock types. Increase in rock temperature causes a decrease in rock strength. This effect

Jan 1, 1973

By Ora H. Rostad

Some gold production was obtained from placer deposits in Puerto Rico during the period of Spanish colonial rule, but most of the gold was produced prior to 1536. There had been no significant hard rock mining, other than in quarries for road metal or construction purposes or for raw materials to make cement, prior to 1954 when the government of the Commonwealth of Puerto Rico recognized that changes in the mining code were necessary to stimulate exploration for metalliferous ore deposits. The Puerto Rican Legislature passed an act (No. 6), which was approved on Oct. 6, 1954, that reiterated that the title to all "commercial minerals" is vested in the Commonwealth of Puerto Rico. The act provided for the establishment of a Mining Commission, stipulated the power% with which the Mining Commission was vested, and provided that no one may dispose of "commercial minerals" in Puerto Rico without a Commonwealth grant issued on its behalf by the Mining Commission. Act No. 6 also provided for prospecting permits, mining leases, and grants. The Mining Commission, by authority granted to it by Act No. 6, adopted regulations effective Nov. 21, 1957, relating to prospecting, leasing, and producing commercial minerals in Puerto Rico. Royalty rates were also specified for various types of deposits at different annual tonnage production levels.

Jan 1, 1991

By Jacob Carr, Rebecca Knuth, Emily J. Haas, Marvin Cheng, Bob Bissonette

Many industries, including mining, are experiencing an increase in the use of robotic and other artificial intelligence (AI) systems to improve efficiency, productivity and precision. For example, a 2023 survey showed that mining industry executives wanted to integrate more autonomous equipment to improve productivity and alleviate workforce shortages (Haas, 2024). This feedback was coupled with an increased appetite to advance the types and uses of automation and AI in the workplace. However, there is also an increasing concern about the ways that robotic applications may unintentionally affect worker safety. Humanmachine interaction poses potential risks, especially when industrial robots operate near workers in specific environments (such as drilling, handling and transporting materials, equipment inspection and lifting heavy loads). Research has explored the unintended consequences of introducing new technologies or processes in the workplace to include incidents such as being struck by equipment and challenges around data privacy (Lööw et al., 2019; Khurram et al., 2025; Haas and DuCarme, 2015; Almeaibed et al., 2021; Zio and Miqueles, 2024). More recently, the use of digital twin technologies and simulations (hereafter referred to as digital twin systems) has been boasted as a tool that can help prevent unintended consequences around worker safety by identifying and mitigating risks before a worker completes a task in tandem with a robot or other new technology. Digital twin systems produce a virtual replica of a physical environment or process (Almeaibed et al., 2021; Zio and Miqueles, 2024; Saes, 2024). To this end, this article explores the potential role of digital twin systems in enhancing safety within mining and other similar environments. It will primarily focus on environments where robots and human workers may interact, although digital twin systems can be useful with other technology applications. First, we define digital twins and digital simulation as components of a system. Then, we highlight possible applications of digital twin systems in mining to replicate real-world processes, followed by potential benefits of their use and where more research may be needed.

Oct 1, 2025

By Rennie B. Kaunda, Robert J. Sterrett

Some people in the mining-engineering field mistakenly believe that mine-water management primarily revolves around the treatment of mine waters that fail to meet applicable water-quality standards. While water-quality control is undoubtedly important, it represents only a fraction of what constitutes comprehensive site-wide, minewater management. A more holistic perspective recognizes that it also involves mine dewatering to maintain safe and workable conditions, securing sufficient water supply for operations, strategically handling surface water within and surrounding the openpit to prevent issues like flooding, developing robust post-closure plans to mitigate long-term environmental effects, and proactively minimizing any adverse impacts on local communities and ecosystems. This article provides a brief overview of topics that fall within the concepts of mine-water management. The focus is on openpit mines, as they are generally larger than underground mines. The management of mine water is highly dependent on local and regional climate such as tropical, desert or temperate climate. Each climatic setting has its own unique challenges, but there are also commonalities.

Jun 1, 2025

By X. Yin

Surface force measurements based on atomic force microscopy (AFM) are used to describe the wettability of surfaces, specifically kaolinite basal plane surfaces at a high resolution. The kaolinite particles (~500 nm) were ordered with either the silica tetrahedral face exposed or the alumina octahedral face exposed, and surface force measurements were made between a hydrophobic diamond-like-carbon (DLC) tip and the kaolinite faces at pH 4, which is around the isoelectric point of the DLC tip. Under these conditions, the effect of electrostatic interaction should be eliminated and only van der Waals interactions and hydrophobic-hydrophobic interactions are expected to contribute to the surface force. The wettabilities of the surfaces were determined from the magnitude of the surface force. Wettabilities of the kaolinite basal planes thus determined were compared with the corresponding wettabilities of talc and mica surfaces, which are well-known to be naturally hydrophobic, and hydrophilic surfaces, respectively. The results reveal that the silica tetrahedral face of kaolinte has a modest level of hydrophobicity, which may be due to the lack of hydrogen bonding sites. In contrast, the alumina octahedral face showed no hydrophobicity, since a layer of surface hydroxyl groups is present at the alumina face, resulting in a relatively strong interaction between this surface and water molecules. It is expected that, with a better understanding of the surface properties of kaolinite, further improvements in flotation separations and dewatering may be achieved.

Feb 1, 2012

By John T. Langstaff

Rock bursts in the deep metal mines of the Coeur d’Alene district present an ever increasing problem in the safe and economic mining of the district’s silver, lead and zinc ores. Hecla Mining Company operates two mines in the district - the Star, a 1100-ton/day lead-zinc mine, and the Lucky Friday, a 750-ton/day silver- lead mine. Rock burst problems at both operations prompted Hecla management to make an all-out attempt to find a practical method of predicting and eventually controlling these bursts. Research by personnel from the Denver Research Center of the Bureau of Mines at ASARCO's Galena Mine indicated that a recognizable pattern of seismic activity preceded some bursts and this activity could be precisely monitored by present- day, off-the-shelf electronic devices. Using information gained by the Bureau and other sources, Hecla designed and installed a 24,- channel seismic monitoring system in the Lucky Friday mine. Installation was completed in December 1973 and after a year of successful operation, it was decided that a similar system would be installed in the Star mine. This second installation was completed in June 1975. Both systems are now operating and providing continuous information on underground seismic activity. Each monitoring system consists of a network of geophones with attendant amplifiers that are connected by shielded cable through an interfacing device to a computer. The origin of each seismic event is determined by the computer and a three-dimensional location is printed out. This information is plotted daily and is used to pinpoint rock burst prone areas and chart their relative seismic activity. This paper will review the causes and effects of rock bursts in the Coeur d'Alene district, the equipment and operation of the microseismic system at the Star and Lucky Friday mines, and the results obtained to date.

Jan 1, 1977

By M. P. Miano

Matching the productivity gains of continuous mining machines with the ever increasing performance levels achieved by longwall units has required creative thinking to assure that development is completed in time for uninterrupted longwall production. By using management information systems to coordinate support operations, the most productive planning decisions can be made. This paper focuses on the role of computer technology tools in achieving improved productivity from both longwall and continuous miner sections. The primary emphasis is on the planning process and the methodology developed to guarantee the best allocation of management and manpower resources.

Jan 1, 1993

By I. M. Stewart

In a proposed rulemaking regulating asbestos, nonasbestos varieties of Tremolite, Anthophyllite and Actinolite would be excluded from the regulations controlling permissible exposure to asbestos fibers. This proposed rulemaking is perceived as improving the scientific basis of the regulation of asbestos because it recognizes that there are no scientific data, either mineralogical or health related, which support the regulation of nonasbestos Tremoiite, Anthophyllite and Actinolite in the same manner as asbestos fibers. However, the proposed regulation, while representing a major advance in the treatment of AT A for regulatory purposes, does not provide an adequate analytical method for distinguishing between asbestos and nonasbestos particles, nor an adequate description of the regulated minerals. This paper addresses those topics, recommending that OSHA include an appropriate mineralogical definition, and implement a discriminate counting procedure to distinguish asbestos from nonasbestos particles.

Jan 1, 1992

By A. D. Hammond

"INTRODUCTION Vanadium deposits in Arizona are distributed all across the state, from the rim of the Grand Canyon to the Tombstone mining district in the southeast corner of the state (Figure 1). The combined past production of vanadium from Arizona and New Mexico ranks second nationwide, after deposits in the Colorado Plateau In the northeast corner of the state, in the Carrizo Mountains and Monument Valley of Apache and Navajo Counties, vanadium was produced as a by-product of uranium in deposits of the Salt Wash and Shinarump members of the Morrison and Chinle formations, respectively. The production took place between 1943 and 1970. Another source of vanadium in Arizona occurs in vanadate deposits associated with supergene enrichment of base-metal vein and replacement deposits. The most important vanadate mineral is vanadinite, a chloro-vanadate of lead. Presently, there are no primary mines of vanadium in the United States. In 2012, a small production of vanadium pentaoxide (V2O5) was reported as a by-product of uranium at the White Mesa uranium mine in Utah1. This paper describes vanadate deposits in Arizona with emphasis in three districts, namely, the Mammoth, Globe-Miami and Banner districts.VANADIUM EPIGENETIC DEPOSITS: VANADATES Almost all vanadium epigenetic deposits occur as vanadates in oxidized zones of lead, zinc and copper veins and replacement deposits. Vanadinite, descloizite and mottramite are the most common minerals in vanadate deposits. Descloizite is a vanadate of lead, zinc and copper. Wulfenite, a molybdate of lead is also present. These minerals replace supergene base-metal minerals, form crusts on faces of open cavities, or are inter-grown with residual clays in pockets. The vanadium content in vanadate deposits is believed to have been leached from the country rock by ground-water and transported through porous rocks until precipitating as a relatively insoluble vanadium compound or until the solution evaporated. Precipitation was brought about by local concentrations of cations of divalent lead, zinc or copper. Lead is a constituent part of almost all of vanadate deposits and the vanadium pentaoxide (V2O5) content in vanadate minerals seems to have a direct correlation with the content of lead in the hypogene mineral. Vanadate deposits are restricted almost entirely to the oxidized parts of vein or replacement deposits. It is rare that oxidized zones extend past 100 ft from the surface. Vanadate deposits are largely restricted to tropical and temperate zones and regions of dry climate. Arizona and New Mexico have the largest concentration of vanadate deposits in North America."

Jan 1, 2015

By T. R. Hughes

How do you fit a processing plant underground with minimal change to mine infrastructure and yet maintain economic recovery, operability and maintainability? By combining fine crushing, continuous-gravity recovery and flotation. A modular, transportable processing plant has been designed that is capable of being installed in underground drives/drifts or on the surface. The Python processing plants have been designed to treat 20 or 50 tons per hour of ore to a particle size of approximately 500 µm and recover gold and sulfides into the concentrate. The plant is only three meters wide (including bolt-on platforms) and can be installed on a 1:50 slope, making for very simple installation. Test work carried out by Gekko Systems Pty. Ltd. has indicated that up to 50% of ores tested to date would achieve gold recovery rates of over 90% using this method. The projected benefits of this strategy are numerous and include low overall capital and operating cost, significantly less power consumption compared with traditional milling circuits and low environmental footprint.

Jan 1, 2010

By E. D. Gálvez, L. A. Cisternas, A. López-Valdivieso, F. Lucay

"The floatability of molybdenite fines in saline solutions was investigated through microflotation studies using a modified Hallimond tube. In addition, the effect of pH and gypsum precipitation from calcium ions (Ca2+) and sulfate ions (SO4 2-) ions in saline water on the recovery of the molybdenite was analyzed. It was found that the floatability of molybdenite fines significantly increased with the ionic strength of the saline solutions and is independent of pH above 0.5 mol/L ionic strength. The high floatability of molybdenite in saline solutions is explained as being due to the low electrostatic repulsion between bubbles and the edges of molybdenite particles, which is exceeded by interactions due to van der Waals and hydrophobic forces. The precipitation of Ca2+ and SO4 2- ions as gypsum had a detrimental effect on the natural floatability of molybdenite because of gypsum crystal attachment on the faces of the molybdenite particles. This precipitation phenomenon may be initiated in copper–molybdenite flotation circuits that use recycled saline water, like seawater containing Ca2+ and SO4 2- ions.IntroductionWater availability is a significant factor in mining projects. Water, particularly fresh water from rivers and underground water, is becoming a scarce resource for mining operations and new projects. Under these circumstances, the use of water with high concentration of salts in flotation plants is becoming increasingly important (Cisternas and Moreno, 2014). The use of seawater has been studied as a sustainable solution for many mining companies in dry areas located near the sea. Notably, using seawater in mining operations is how mining companies in Chile have coped with the problem of water resources (Cisternas and Gálvez, 2014). In 1930, small plants in Chile used seawater to float chalcopyrite from high-copper-grade ores. In 1975, the results of tests in pilot plants for the flotation of copper minerals with seawater were reported. It was found that froth formation in seawater at pH 9.5 was suitable to make the rougher circuit work properly, even without frothers. The Cenizas mining group successfully floated chalcocite, bornite and chalcopyrite in the Las Luces plant in Taltal in Chile using seawater (Moreno et al., 2011). Minera Centinela (Antofagasta Minerals S.A. Chile) is currently processing porphyry copper ores using a seawater mixture consisting of 20 percent fresh seawater and 80 percent recycled water. Lower consumption of flotation reagents was reported in both seawater and salt water. In addition, studies performed with synthetic seawater showed that certain frothers increase the froth volume, whereas others decrease it. Additionally, the froth produced with seawater carries a high amount of gangue, and low-quality concentrates are obtained, requiring more cleaning stages."

Jan 1, 2015