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By R. H. Nafziger

The Bureau of Mines evaluated 18 domestic titaniferous materials with widely varying compositions, mineralogy, and physical properties in electric-arc furnaces, Techniques were devised to recover both the titanium and iron values contained in these materials so that the reliance of the United States on foreign sources of higher grade ilmenites and rutile might be decreased. Most of the tested titaniferous materials responded well to lower grade or byproduct reductants, such as bituminous coals, charcoal, and coke breeze. Sufficient slag fluidity was realized by maintaining from 8 to 12 wt-pct iron in the slags; no contaminating fluidizers were required. Fluid slags containing up to 79, 70, and 54 wt-pct Ti02 were realized from east coast ilmenites, a rock ilmenite, and a titaniferous magnetite ore, respectively. A carbon-lined furnace shell is recommended for minimum slag contamination. Good results also were obtained during extended submerged-arc furnace tests.

Jan 1, 1980

By L. B. Pankratz

Enthalpies above 298° K were determined for AgCl to 1,400° K and for AgBr to 1,200° K by copper-block calorimetry. Before melting, both compounds showed an anomalous increase in enthalpy, an effect associated with lattice defect formation. Melting points and heats of fusion were determined to be AgCl, 730° K and 2,945 cal/mole; AgBr, 700° K and 2,030 cal/mole. The heat capacity of both melted substances decreased with increasing temperature over the entire liquid ranges investigated. Enthalpies above 298° K were tabulated at even temperatures along with derived entropy increments and heat capacity values. The results were combined with the known heats of formation and entropies at 29.8.15° K to obtain values of the heats and free energies of formation over the range 298.15° to 1,400° K for AgC1 and 298.15° to 1,200° K for AgBr.

Jan 1, 1970

By W. H. Oppelt

A lignite from west-central North Dakota (Mercer County) was dried by the Bureau of Mines by the Fleissner process at saturated steam pressures to 1,500 pounds per square inch absolute (p.s.i.a.). Normally, the process is operated at pressures of 200 to 370 p.s.i.a. At the highest pressure the temperature of the saturated stearn is 596° F. The purpose of the investigation was to evaluate the influence of very high stearn pressure and temperature on moisture removal, steam consumption, and physical and chemical characteristics of the dried lignite. Two drying cycles were used: A normal cycle, corresponding to previously established standard time requirements, and an accelerated cycle, wherein time requirements were determined by boiler capacity and handling speed. Blank tests to determine stearn requirements for heating the empty autoclave were performed for each cycle and each test condition. Moisture removal, final moisture content, net steam consumption, and size stability of the dried lignite were determined.

Jan 1, 1959

By C. H. Elder

A 5-hole pattern was drilled from the surface at a site near Oak Grove, Jefferson County, Ala., to degasify the gassy Mary Lee coal bed in advance of mining. Gas and water production was monitored for 1 year, 4 months to allow gas flow to stabilize fully. A thickened water stimulation treatment was designed and applied in one hole of the pattern to evaluate this degasification technique for the Mary Lee coalbed. A gas production rate of 70,000 fts/day after stimulation treatment indicates that the use of vertical boreholes coupled with hydraulic fracturing in advance of mining the Mary Lee coalbed would provide for more rapid degasification and could provide a possible source of natural gas.

Jan 1, 1974

By Lewis M. McNay

The Bureau of Mines located and examined 292 burning coal refuse banks throughout the Nation's coal-producing regions in 1968. These coal waste fires, extending over 3,200 acres, produce poisonous, acrid gases and particulate matter that pose a threat to health and safety in the surrounding areas, damage vegetation, and cause the deterioration of nearby structures and buildings. Methods of extinguishing coal refuse fires are discussed, and an approach to eliminating future occurrences of these fires is presented.

Jan 1, 1971

By Howard P. Hamlin, John W. Sweeney

Shales , clays , and loess in Iowa were tested and evaluated to determine feasibility of producing lightweight aggregate by commercial rotary - kiln or sintering methods . Preliminary testing was conducted in a muffle furnace . Rotary - kiln tests were conducted in a 16 - inch by 14 - foot rotary kiln . Concrete cylinders and cubes were tested to determine qualities of the aggregate . Three samples made suitable lightweight aggregate by rotary - kiln methods and two by sintering .

Jan 1, 1964

By R. F. Stewart

A key step in changing coals to fluid fuels and chemicals is the conversion of coal to synthesis gas by gasification with steam and oxygen. As oxygen represents one of the largest single expenses in gasification, its cost is a vital factor in the economy of the process. At present, the most economical method for producing tonnage oxygen is by the conventional rectification of liquefied air. Several alternate methods have been proposed for producing oxygen from air: (1) methods based on physical or chemical sorption of oxygen from air by liquids or solids or (2) the oxidation of certain inorganic com-pounds to higher oxides unstable at higher temperature levels. Economic limitations are discussed by which these methods may be evaluated. Chelated metals of the salcomine type are promising chemical sorbents of oxygen from air. This report covers a study of the reversible sorption of oxygen by salcomine and other chelates. The presence of water in the salcomine structure was verified; it is the loss of this water that causes slow deterioration of salcomine during cycling.

Jan 1, 1959

By J. M. Gomes

The Bureau of Mines, as part of an effort to maximize minerals and metals recovery from domestic resources, has investigated the feasibility of recovering heavy minerals as byproducts from sand and gravel, placer gold, and industrial mineral operations in northern California. Sand samples from about 50 locations were treated by gravity separation to yield heavy-mineral concentrates (black sands). Mineral compositions of the concentrates were determined by chemical analysis and mineralogical examination. Individual zircon, ilmenite, magnetite, platinum-group metals, thoria, and silica products were prepared from heavy-mineral concentrates by selective separation using low-and high-intensity magnetic, high-tension, and flotation equipment.

Jan 1, 1979

By Sarkis G. Ampian

Crystalline silica (quartz, cristobalite, and tridyrnite) is regulated by the Mine Safety and Health Administration (MSHA) and Occupational Safety and Health Administration (OSHA) because of its potential for causing debilitating but nonmalignant lung diseases. In 1987, the International Agency for Research Against Cancer (IARC) conducted a review of the health literature and concluded that crystalline silica was a probable human carcinogen. As a result of this finding, OSHA was required to regulate crystalline silica under its Hazard Communication Standard (HCS). The standard requires that all materials handled by OSHA-regulated facilities be labeled according to the requirements of RCS and that workers receive proper training on the handling of the material if the crystalline silica content equals or exceeds 0.1 weight percent (0.1 %). MSHA currently is considering enacting its own RCS. This will be similar to OSHA's RCS. If the standard is enacted, most mineral producers will have to determine the respirable monitor filter and bulk crystalline silica contents of their ores and products so that workers and/or customers will know whether they are in compliance with the 0.1% HCS and/or the OSHA permissible exposure level (PEL) of 50 µg for an 8-hour workday for respirable crystalline silica as determined from monitor samples. Two major concerns with the RCS are the widespread occurrence of crystalline silica in nature and the suitability of current technology for routinely determining crystalline silica concentrations at the 0.1 % RCS level. Most ores are extracted from silica-bearing deposits and it is a common constituent of rocks and soils. OSHA's RCS will have the greatest impact on the producers of crushed stone, diatomite, dimension stone, gravel, industrial sand, perlite, pumice, pyrophyllite, sand, and talc because these materials frequently are shipped directly from the mill to the customer. MSHA's RCS would affect nearly all mineral producers. Those producers that have crystalline silica present in concentrations near the 0.1 % cutoff point will have the most difficulty with the analysis. Crystalline silica can be quantified at the 0.1 % level by X-ray diffractometry in simple systems containing one, two, and possibly three minerals if (1) none of the accessory minerals has X-ray diffraction reflections that coincide or overlap with those of crystalline silica and (2) the standard has a particle size distribution and crystallinity similar to those of the sample. In some instances, it may not be possible to determine the crystalline silica content of a sample with any degree of certainty using the recommended regulatory protocol. In all cases, it is recommended that a qualified mineralogist identify the minerals in a sample prior to any regulatory analysis. Additionally, the uncertainty as to whether some silica polymorphs should be classified as crystalline or noncrystalline and the suitability of metastable high-temperature standards, such as cristobalite and tridyrnite, for regulatory analysis at ambient temperatures should be addressed further. This overview is written both to highlight these problems and to serve as a guide for analysts, regulators, and industry personnel who are involved in the crystalline silica issue. It also covers some of the difficulties and/or shortcomings in quantifying crystalline silica, such as the ubiquitous mineral quartz, in the workplace.

Jan 1, 1992

By S. J. Aresco

The Bureau of Mines has been active in promoting the purchase of coal for Government use under specifications that define the requirements in terms of heating value of the coal, expressed in British thermal units, and the composition as shown by proximate analyses. To these, when required, are added the ash-softening temperature, the free-swelling index, and the Hardgrove grindability index. Under most of these specification contracts the bidders guarantee the quality of the coal, and that guaranteed by the successful bidder becomes the standard of his contract. The deliveries are sampled in accordance with instructions5/ issued by the Bureau of Mines; the samples are analyzed in the Bureau laboratory to determine whether the coal is of the quality guaranteed by the contractor and, if it is not, a price adjustment is made. Analyses of the delivered coal and tipple samples (samples collected at mine tipples as coal is being loaded into railroad cars or trucks) provide valuable data for use in evaluating future bids. In addition, the continuous sampling of coal as delivered is a check on the practical results obtained in burning the coal.

Jan 1, 1961

By Will H. Coghill, Fred D. DeVaney, R. S. Dean

Part I CONTENTS

May 1, 1934

By Daniel Harrington

On the night of June 8, 1917, the flame of a carbide lamp accidentally set fire to the uncovered and frayed insulation of an armored power cable near the 2,400-foot level of the North Butte Mining CO.'s Granite Mountain shaft. How this, insulation accidentally became exposed is explained on page 15. The highly flammable oiled fabric set fire to the shaft timbers, and as this is a downcast shaft the fire spread with great rapidity, soon filling the mine workings with smoke and gas. At the time 410 men were working underground, 247 of whom escaped by various means, but most of the 163 remaining were probably overcome soon after the fire started, and perished. Only two men were actually burned. The cause of the disaster was purely accidental. The immediate effect was the unexpected reversal of normal conditions; the ultimate effect was great loss of life and the destruction of the main hoisting shaft, putting it temporarily out of service. The work of rescue and fire fighting continued eight days. The following pages present an attempt to draw some practical conclusions and suggestions from this disaster. The property of the North Butte Mining Co. consists of about 220 acres in the northeastern part of the Butte district, Montana. Next to the Anaconda Copper Mining Co. it is the largest producer of the district. In 1916, the year before the disaster, there were 1,160 men employed. The output was 560,947 tons of ore, which yielded 24,498,181 pounds of copper, 1,047,063 ounces of silver, 1,712 ounces of gold, and 412,953 pounds of zinc. The profit was $2,479,595. The total development work for that year was 21,694 feet. During the first half of 1917, the year of the accident, the daily tonnage of ore averaged 2,000, an increase of 400 tons over that of the year 1916.

Jan 1, 1922

By Donald E. Redmon

This Bureau of Mines report reviews injury experience in the nonmetallic mineral industries (except stone and coal) for 1968-69. For each of the years, 23 tables summarize disabling work injuries by department, source of injury, extent of disability, part of body injured, and nature of injury. Correlative information on employment, worktime, and operating activity is also presented.

Jan 1, 1973

By A. L. Service, C. C. Popoff

Phosphate deposits in Montana , Idaho , Wyoming , and Utah are important factors in the mineral , agricultural , and industrial economy in the western part of the Nation . This report presents background information , including geology , mining , beneficiation , processing , resources , and economics , assembled to provide a comprehensive introduction to a series of four area reports . About 20 percent of the Nation's phosphate is produced from the Western field where there were 6 surface and 9 underground mines in operation in 1963 . This region also has an estimated 58 percent of the Nation's phosphate reserves , and continuing development is assured by these abundant resources and an increasing demand for phosphate products . Long range forecasts indicate that the United States will continue to use increasing amounts of both agricultural and industrial phosphate products . Beneficiation has become an important part of the phosphate processing industry , and two flotation plants and several washing plants were in operation in 1963. Recent studies by the Bureau of Mines Metallurgy Research Center , Albany , Oreg . , have been directed toward developing flotation processes applicable to treatment of marginal phosphate rock . Other Bureau of Mines research is being directed toward improved methods of ore recovery , ground control , and mining .

Jan 1, 1964

By PHILIP A. ZANG

The rapidly increasing use of motor vehicles in the United States has introduced an entirely new problem in the proper ventilation oftunnels , subways , and other confined spaces through which such machines must pass . This problem was brought to the attention of the Bureau of Mines by the New York and New Jersey State Bridge and Tunnel Commissions with reference to the ventilation of the proposed vehicular tunnel under the Hudson River . This tunnel , consisting of twin tubes 29 feet in diameter and 8500 feet long between entrance and exit , presented an unprecedented problem in ventilation both on account of its length and on account of the traffic density , which is expected to reach a maximum of 1900 vehicles per hour . An exhaustive study by the tunnel engineers of all available data on the amount and composition of automobile exhaust gas disclosed very little information on the percentage of carbon monoxide in motor exhaust gas from the average run of automobiles and trucks under actual operating conditions on the road. It was well known that carburetor adjustment and other operating factors changed the percentage of the poisonous constituent , carbon monoxide , from practically 0 to 12 or 13 per cent ; but no safe estimate could be made of the most probable figure without further investigation .

Mar 1, 1921

By Richard V. Ageton, Harry E. Tufft, E. A. Holbrook

When an underground excavation is made, the rock surrounding the sides and top of the opening is deprived of its natural support and tends to fall. Whenever caving takes place, the time and extent of the caving depend on the character and condition of the rock. In strong homogenous rock, such as solid granite, even a large chamber may stand indefinitely, whereas a soft material, such as clay or a loose material like unconsolidated sand, falls immediately if not supported. Weaknesses in the rocks induced by structural features, such as joints, :fissures, bedding and cleavage planes, and fractures produced by blasting, will cause the falling of insecure blocks or slabs unless means are provided to support these in place. In an unsupported mine opening, as a tunnel, the first slight settling or adjusting movement of the rocks (the "initial creep" or "set") is caused by the great weight of overlying material pressing down the rock masses above and around the roof and sides of the opening until they key together in roughly the form of an arch. The rock, after it has adjusted itself to this shape, becomes. selfsupporting. Timbering is necessa.ry in all mining only to support, therefore, those comparatively small blocks or pieces of rock which tend to loosen from the top and sides of the opening during or after the formation 'of the natural rock arch, and which lie between this natural rock arch and the opening. This statement, of course, has its limitations. For example; a layer of strong rock, like limestone, may act as a beam; then only the material under the limestone will need support. Timbering is not, as is commonly supposed by the layman, used to supp!ort the huge mass of rock between the back (roof) of an underground opening and the surface. It would be impossible to place enough timbers in a:ny underground opening to support such a mass. This fact is not'·perceived by all miners.

Jan 1, 1923

By W. A. SLOAN, G. L. Oldright, J. D. Sullivan, E. K. PRYOR, A. F. HALLET, R. S. Dean, S. L. BROWN, F. S. Wartman, A. J. Thompson

Lack of sufficient publication funds has resulted in the accumulation of considerable unpublished experimental work on copper metallurgy by the Bureau staff . The present report gives extended abstracts of this work , as well as a discussion of the best direction for future efforts . The experimental work reported in this series of papers was done in cooperation with the University of Arizona , Tucson , Ariz . The investigations covered in the third , fifth , and seventh papers were done under the direction of G. L. Oldright and the remainder under the direction of V. H. Gottschalk .

May 1, 1934

By Chas. F. Jackson

During the current business depression the Bureau of Mines has received many inquiries concerning placer mining, the prospects for men of small means to make wages by small-scale placer operations, the locations of placer deposits in the United States, methods of working placers on a small scale, and allied subjects. It has therefore seemed desirable to prepare a circular covering, in nontechnical language, the principal questions which have boon referred to the Bureau of Mines for answer. There are a number of bureau publications dealing with placer mining, most of which are now out of print, but which may be consulted in the larger libraries. Other articles on placer mining nave appeared from time to time in the technical press and several good textbooks have been written on the subject. A partial bibliography of this literature appears at the end of this paper. A recent pamphlet published by the Idaho Bureau of Mines and Geology to assist the prospector and inexperienced small operator has received wide and favorable attention and is recommended as a useful reference. In the present paper no attempt will be made to cover the subject of placer mining in a comprehensive manner, but discussion will be confined to elementary questions of particular interest to persons of limited experience.

Jan 1, 1932

By M. L. Whisman

The Bureau of Mines developed and tested in the laboratory several innovative techniques for reclaiming used lubricating oil. These processes included percolation through both chemically treated clay and ion-exchange resins, distillation through batch and continuous wiped-wall vacuum apparatus, treatment with solvent extraction systems, and chemical removal of impurities with chelating agents. In each treatment, the criteria of evaluation was oil recovery and reduction of acidic and metallic components. Both vacuum distillation and solvent treatment ranked high in their abilities to remove acidic and metallic components of the used oil with good oil recoveries. A combination of the two techniques gave the best overall results in terms of quality evaluations made by established bench tests. The methods were not ranked according to economic practicablity.

Jan 1, 1974

By Margaret R. Egan

The U.S. Bureau of Mines conducted experiments in the intermediate-scale fire tunnel to assess the influence of air velocity on the gas production and smoke characteristics during smoldering and flaming combustion of Pittsburgh seam coal and its impact on the detection of the combustion products. On-line determinations of mass and number of smoke particles, light transmission, and various gas concentrations were made. From these experimental values, generation rates, heat-release rates, production constants, particle sizes, obscuration rates, and optical densities were calculated. Ventilation has a direct effect on fire detection and development. The results indicate that, in general, increased air velocity lengthened the onset of smoke and flaming ignition, increased the fire intensity, but decreased the gas and smoke concentrations. Increased air velocity also lengthened the response times of all the fire sensors tested. Rapid and reliable detector response at this most crucial stage of fire development can increase the possibility that appropriate miner response (fire suppression tactics or evacuation) can be completed before toxic smoke spreads throughout the mine.

Jan 1, 2010