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By Falbo A, Barbaro M, Esposito MA, Passariello B

Acidic reductive leaching is one of the best known and most widely employed chemical processes for beneficiating minerals of industrial interest. Conventional acidic leaching with sodium dithionite (Na2S2O4), employed to bleach industrial minerals used in the production of ceramics, glassware, paper etc, does not always allow products of high quality to be obtained. In the work reported here two reducing agents, ascorbic acid and oxalic acid, have been employed in a medium acidified by means of sulphuric acid. Continuous systematic tests have been performed on a kaolin sample containing 0.8 per cent Fe2O3, adopting various operating parameters such as, leaching time, temperature and reagent concentration. In each case the total quantity of bi- and trivalent iron dissolved was ascertained. Removal of 80 per cent and 100 per cent of iron with ascorbic and oxalic acid respectively was obtained, while less than one per cent of iron was dissolved in the presence of sulphuric acid only. Products having a very good degree of whiteness (92 - 94 per cent) were obtained, whereas with sodium dithionite the degree of whiteness was in the 85 to 88 per cent range. The best conditions identified were applied to a sample of quartz for the removal of ferric impurities.

Jan 1, 1993

By G Bournival, Y Saavedra Moreno, S Ata

Flotation frothers are heteropolar molecules that are preferentially adsorbed at the bubble interface to enhance the flotation performance by promoting the formation of small and stable bubbles. Frothers have different characteristics that can be used to classify them. A classification framework has been recently presented by Saavedra Moreno et al (2022) to classify non-ionic frothers by conducting a principal component analysis (PCA) and a hierarchical clustering analysis (HCA). However, for the purpose of the present research, only five frother characteristics, including molecular weight (MW), hydrophile–lipophile balance (HLB), critical coalescence concentration (CCC), the minimum Sauter mean diameter (DL), and foam stability index (DFI) were used in the PCA and HCA. All those characteristics were evaluated for a two-phase system in the absence of particles. Realising the important role that particles play in froth stability and behaviour, the effect of hydrophobic particles on the presented frother classification framework was investigated in this study. Four frothers with different characteristics, methyl isobutyl carbinol (MIBC), 1-pentanol, tri (propylene glycol) (TPG), and tri (propylene glycol) methyl ether (TPM), were chosen. The experiments were carried out in the presence and absence of silica particles esterified with 1-pentanol. It was evident that the results for 1-pentanol, TPM, MIBC, and TPG in the three-phase system agreed well with the frother classification presented for the two-phase system as frothers were clustered in the same groups. The findings from this research support the use of the frother classification system presented in two-phase system to select a specific frother for a particular application without the necessity of conducting laborious experiments in a three-phase system.

Aug 24, 2022

By P Carrasco, E Me, M Campos, J Tapia

Correct sampling practices are of vital importance to the mining industry; key decisions for the business are made on the basis of samples in all the value chain. Geology plays a relevant role in pre- and post-investment stages. Actually the understanding of natural variability is essential for geological modelling, geometallurgical modelling, mine planning, grade and process control. Improper sampling practices obstruct this objective introducing irrelevant variability components, which can cause monumental economic losses. A good approach to accomplish this understanding is the application of heterogeneity and IngamellsÆs tests, which are useful tools to quantify the variability of a certain well-delimited geological unit at different comminution scales. The application of heterogeneity test can help minimise Pierre GyÆs fundamental sampling error and to study the impact of other sampling errors. IngamellÆs test allows us to define the correct mass of sample for chemical analysis. This paper presents the results of several heterogeneity and IngamellsÆs tests done in Chilean porphyry copper deposits that belong to CODELCO Chile (Chuquicamata, Mina Sur, Radomiro Tomic, El Salvador, Andina and Teniente), in different geological units (endogenous oxides, exotic oxides, supergene sulfides and hypogene sulfides) and for several elements (Cut, Cus, Mo and As). These tests, considering the natural variability, have helped us develop accurate sampling protocols to minimise the fundamental error to acceptable levels. A major contribution of these tests (more than 30) is the generation of secure sampling protocols using the highest sampling constant obtained in the tests, for new porphyry copper deposits that donÆt have information given by heterogeneity and IngamellsÆs tests.

Jan 1, 2005

By J Ferreira

To speed up multivariate geostatistical simulation it is common to transform the set of attributes into spatially uncorrelated factors that can be simulated independently. One decorrelation method is the method of minimum/maximum autocorrelation factors (MAF), where a two structure linear model of coregionalisation is assumed. The transformation decorrelates the theoretical model exactly, but the actual data are only approximately decorrelated. The MAF transformation can therefore be seen as a special case of a non-orthogonal approximate diagonaliser of a set of symmetric matrices. A more general approach for approximate joint diagonalisation (AJD) has been developed in the context of blind source separation. For these AJD algorithms no assumptions are made beyond symmetry of the individual matrices and so they can be applied to a family of experimental semivariogram matrices. In their application there are no restrictions on the number of structures in the linear model of coregionalisation (LMC) thus removing one of the conditions placed on the subsequent modelling of the spatial structure of the factors. In this paper the general background for the U-WEDGE AJD method is presented. It is shown that the U-WEDGE method achieves better spatial decorrelation than the MAF method. The factors derived from U-WEDGE are simulated using conditional turning bands simulation and then backtransformed to attribute space.

Sep 26, 2011

By A Woodley, A N. Danoucaras

In 2012 the Bureau of Meteorology, under the banner of the Water Accounting Standards Board, released the Australian Water Accounting Standard 1 (AWAS 1). This standard has been in development since 2007 with key milestones being the release of the Preliminary Australian Water Accounting Standard in 2009 and the exposure draft of the Australian Water Accounting Standard in 2010. Throughout this period, the Minerals Council of AustraliaÆs Water Accounting Framework has developed concurrently with the Australian standards and the standards have informed elements of the framework. However, the framework is not identical to the standard as the objectives between the two are different. The objective of the Water Accounting Framework is to create consistency in water reporting of the minerals industry and to assist companies reporting to corporate sustainability initiatives. The objective of AWAS 1 is to provide information to water management bodies to facilitate decisions about the allocation of water resources. Companies are to report on an annual basis - not only physical flows of water but contractual requirements to supply and obtain water - regardless of whether the transaction has been fulfilled in the reporting period. In contrast, the Water Accounting Framework only reports on flows that have physically happened. The paper will provide summary information on aspects of AWAS 1 that are most relevant to the minerals industry, show the alignment and differences between AWAS 1 and the Water Accounting Framework and explain how to obtain the information for the AWAS 1 reporting statements.CITATION:Danoucaras, A N and Woodley, A, 2013. Alignment and differences between the Australian Water Accounting Standard and the Water Accounting Framework for the minerals industry, in Proceedings Water in Mining 2013 , pp 85-90 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

The paper highlights the conceptual developments in rock mechanics applied to quantify the effect of bolts in the stabilization of joints and yielding soft rocks. NOTATION Aa = stress change after excavation Eä EE, Eä = moduli of intact rock, single joint and jointed rock Eb = elastic modulus of the bolt k, = normal stiffness of joint Ab = cross section area of the bolt A, = area of influence per bolt ab = axial bolt stress e, = axial strain of the bolt eä e,, ej, = strains of intact rock, joint and jointed rock Ai = area of the joint ,r+ = shearing resistance of the bolt (at the joint) a = normal stress at the joint plane aäa3 = major and minor principal stresses c;, 4i; = cohesion and friction angle of the joint 0 = angle between the bolt and the joint a = inclination of the joint to the vertical axis P = bolt density parameter u, = convergence of unsupported tunnel section u, = convergence of bolted tunnel

Jan 1, 1992

By M I. Pownceby, N Karimian, J R. Manuel, M J. Peterson

The CSIRO ore classification scheme for Pilbara ores was used as a reference frame to target recognisable ore types/textures with potentially elevated phosphorus content for detailed analysis. Particles of each individual ore texture were separated from a Brockman high-P ore and each class was characterised using methods including XRF, XRD, EPMA and synchrotron-based XAS. Results were then correlated with optical microscopy and hand specimen identification to establish any relevant associated mineralogical phases and/or textures. This represents a more systematic approach to identification of high-P ore components based on particle and goethite type and texture. The information can then provide the basis for more targeted P-removal strategies factoring in the relationship between particle/ore texture and phosphorus deportment

Sep 18, 2023

Although AustraliaÆs coal mining industry is currently experiencing a pleasing period of price relief, long-term trends toward lower real prices will surely continue. Higher price levels attract expansion by existing operators and market entrance by new operators. History clearly demonstrates the relentless long-term march toward ever lower real prices. Therefore, the need for economic returns applies constant pressure to improve productivity. To be sustained, high productivity requires a systematic response based on a solid understanding of critical productivity determinants. The most powerful determinant of productivity is now widely understood to be workplace culture. Culture largely comprises a combination of behaviours, symbols and attitudes. This paper will examine and review scienceÆs latest discoveries in human behaviour. It will provide a proven, practical framework for understanding behaviour and applying this knowledge. Significantly, it will highlight why conventional approaches toward improving productivity often provide disappointing economic returns. The modern understanding of behaviour factors will cover coal face operations. More importantly, because executive and managerial levels in coal mining have significantly greater impact on industry and mine productivity the paper will concentrate on leadership. Particular emphasis will be placed on use of modern systems and in particular use of what are by far the most powerful drivers of behaviours û measurement, analysis and reporting systems. The paper and presentation will show how conventional systems rooted in antiquated American legislation from the early 1900s stifle productivity improvement and drive suboptimal and even counterproductive behaviours. These commonly used systems will be compared with accurate and effective modern methods for assessing performance to improve productivity. These principles are proven in all industries and effective application in mining will be highlighted. Actual results will be used to demonstrate practical approaches successfully applied in both metal and coal mining in Australia and overseas.

Jan 1, 2005

By M Berndt

Four siltite-argillite rock samples were characterised (particle size, chemistry, mineralogy) and subjected to laboratory dissolution testing for 36 to 298 weeks. In two samples sulfur (0.99, 1.69 wt per cent) occurred largely as pyrite, and in the other two samples sulfur (0.96, 1.93 wt per cent) occurred predominately as potassium jarosite. The observed rate of sulfate release from the pyritic samples was one to two orders of magnitude greater than that from samples containing potassium jarosite. Drainage pH values from the pyritic samples were one to two units lower and acidities were ten to 70 times higher than associated values from the potassium jarosite samples. Geochemical modelling supported the hypothesis that pH and concentrations of sulfate and potassium in drainage from the potassium jarosite samples were controlled by the limited solubility of potassium jarosite. This dissolution produced an iron-dominated mineral phase, but iron concentrations in the drainage were well below those predicted by ferrihydrite solubility.

Jan 1, 2003

By A Gerson, S Miller, R Smart, J Thomas

Environmental Geochemistry International (EGi) and the Ian Wark Research Institute (IWRI) collaborated in a three-year Australian Minerals Industry Research Association (AMIRA) research project (Project Number P387A) focussed on the prediction and kinetic control of acid mine drainage. As part of this project, single addition, and sequential net acid generation (NAG) testing was carried out on sulfide mineral samples. The test samples comprised a range of synthetic waste materials prepared using a quartz bulk and controlled quantities of the commonly occurring sulfide minerals; pyrite (FeS2), pyrrhotite (Fe7S8), arsenopyrite (AsFeS), chalcopyrite (CuFeS2), chalcocite (Cu2S), covellite (CuS), bornite (Cu5FeS4), galena (PbS) and sphalerite (ZnS). NAG test results clearly show that there are significant differences between the acid forming potential of sulfide minerals. The NAG test results for each mineral were compared with theoretical acidity values (NAPP*). The NAPP* calculation was based on stoichiometric oxidation reactions assumed for each of the sulfide minerals. Sequential NAG values for pyrite corresponds closely to predicted NAPP* values, confirming the assumption that pyrite oxidation occurs according to the stoichiometry assumed. For the pyrite sample with 5 wt per cent S, two NAG stages were sufficient for all of the sulfur to be released to solution. Since sulfides in waste materials will generally be dominated by pyrite, results also confirm the validity of including NAG testing for ARD evaluation of most waste rock. NAG testing confirms that of the sulfide minerals examined, only pyrite, pyrrhotite, arsenopyrite and chalcopyrite are acid producing, ie able to produce leachate with a pH less than 4.5. In the case of sphalerite, galena, bornite, chalcocite and covellite the pH of the final NAG solution was greater than 4.5. The significant differences between the acid forming potential of different sulfide minerals could lead to overestimation of acid producing potentials based on NAPP values calculated from total per cent S alone, ie assuming all S is present as pyrite. The oxidation of galena during the NAG test resulted in the consumption of acid. The examination of the galena surface by X-ray photoelectron spectroscopy (XPS) after oxidation in peroxide solution indicated the presence of polysulfide. The reaction of sulfide to polysulfide is acid consuming, thus explaining the net acid consuming behaviour of galena in the NAG test. This reaction pathway may provide a possible explanation for the lower than expected acid production observed for some of the other sulfide minerals examined.

Jan 1, 2003

By R Cox, S Pandey

The coal seam gas (CSG) industry is expanding rapidly in the Surat and Bowen basins. CSG production involves pumping water from the coal seams to release the gas adsorbed to coal particles. The reduction in water pressure in the coal seams will cause some reductions in water pressure in overlying and underlying aquifers because there will always be some interconnectivity between the formations. The Surat Basin is a sub-basin of the Great Artesian Basin, which contains aquifers of high economic, environmental and cultural value. The Condamine Alluvium is also an important water resource, which overlies parts of the eastern margin of the Surat Basin.Under the Queensland (Qld) regulatory framework, an area of intensive CSG development involving multiple CSG operators can be declared to be a cumulative management area. For such areas the Office of Groundwater Impact Assessment develops assessments of future impacts on aquifer water pressures and develops and manages arrangements. The results are published in underground water impact reports.The Surat underground water impact report (QWC, 2012) was approved in December 2012. This paper summarises the place of the report in the Queensland regulatory framework, the content of the report and progress in its implementation.CITATION:Cox, R and Pandey, S, 2013. Managing groundwater impacts in the Surat Basin, in Proceedings Water in Mining 2013 , pp 169-174 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

By J Kinal, P Steinier

A considerable volume of work exists in the literature examining the electrochemical interactions between grinding media and sulfide minerals. Broadly, most sulfide minerals are more noble than forged steel grinding media used during comminution, therefore a galvanic couple between the media and the sulfide mineral(s) exists, which increases the corrosion rate of the grinding media. The corrosion products of the grinding media, iron oxy-hydroxide species, invariably precipitate on to the surfaces of the sulfide minerals thereby affecting their floatability. This paper explores the science behind these corrosion reactions, and provides an explanation of their impact on the pulp chemistry of sulfide mineral slurries and subsequent flotation behaviour. A number of laboratory and plant case studies are used to illustrate the benefits of changing to a more inert grinding media.

Jan 1, 2005

By J Andrina, D Richar, R Smart, A Neale

The Grasberg is a large copper and gold open pit mine operated by PT Freeport Indonesia and located in the high equatorial mountains of Papua Province, Indonesia. The climate is alpine/sub-alpine with little seasonal variation in temperature and rainfall. The annual precipitation varies from about 3000 to 5000 mm over short distances around the Grasberg, but in general, an average daily precipitation of 10 mm per day applies and leaching of the overburden is continuous throughout the year. Mining commenced in 1988, and almost all of the overburden mined up to 2003 was potentially acid forming. From 2003 to the end of the Grasberg pit operation in 2014, approximately 70 per cent of the overburden will be potentially acid forming and 30 per cent limestone. A major focus of the investigations is developing strategies to maximise the beneficial use of the limestone that will be mined. Laboratory columns and field test pad investigations have been ongoing for six years examining limestone blends. Trial dumps utilising truck placement and conveyor/stacker placement and blending of limestone and acid generating rock have recently been constructed. In addition, based on initial results, investigations aimed at further evaluating the performance of limestone covers in this high rainfall environment have commenced. A significant finding has been the identification of strong armouring layers on sulfide surfaces within well-blended material and under limestone covers. These layers effectively isolate sulfides and thus progressively slow the oxidation rate to a level where the alkalinity load from the limestone exceeds the rate of acid generating. ARD is controlled and neutral low metal drainage results. The results have demonstrated that although limestone blending is effective, it is necessary to ensure that all size fractions within the blend receive adequate acid neutralising capacity to buffer the potential acidity. Because the sulfur content generally increases and the acid neutralising capacity decreases with decreasing particle size in limestone blends, the amount of limestone required greatly exceeds the stoichiometric requirement. This paper describes the development of limestone blending specifications for potentially acid forming overburden and presents the results of the ongoing limestone cover trials at the Grasberg mine.

Jan 1, 2003

By Thompson D, Somerville JM, Brock DA

The development of a softwood alternative to the hardwood chockpiece used to build the waste-edge breakers commonly incorporated in gateroad packs is described. The results of laboratory tests on softwood prototypes and two underground trials are presented. The results of the last trial suggest that a viable alternative chockpiece has been designed, offering advantages over availability of wood, weight and given reduced wood content, price.

Jan 1, 1992

A brief review of the problems in ventilating and cooling deep and hot Australian mines is presented. An overview is given on the development of the controlled partial recirculation concept. The main part of this paper describes the first majo

Jan 1, 1994

Blasting, particularly bench blasting, uses finite length cylinders of explosive close to two free faces. The rock to be blasted is usually intersected by a complex 3-D system of joints. To fully simulate a blast, a 3-D dynamic model is required. It is shown that the static stress distribution around a long cylinder can be reproduced by superposing the static stress distribution of a suitable chain of spheres. Thus, the dynamic results for individual spheres given by Favreau (1969) can now be substituted for the static results to give a dynamic model of the stress distribution around a long cylinder. Comparison of measured and computed waveforms show that the measured waveforms are much more attenuated and dispersed than expected. The consequences for explosive evaluation and design are Discussed.

Jan 1, 1990

By G J JAMESON

The flotation cell has undergone a number of changes since the process was first introduced in Broken Hill in the early years of this century. The development of the mechanical flotation cell is reviewed, followed by a discussion of more recent developments such as the flotation column, the air-sparged hydrocyclone, the Wemco-Leeds cell, the Bahr and Deister columns and the Jameson cell.

Jan 1, 1992

By Otuonye F

An outburst is the spontaneous ejection of pulverized coal and gas from the working face in an underground mine. It is caused by overstressing the rock, due predominantly to the influence of geological structures on in situ stresses, stress concentration from the excavation and overburden load on mine openings, and large volumes of gas sorbed in the rock. The spontaneous release of high pressure gas creates intense shock waves which may cause damage to the mine ven- tilation system and the pulverized rock/coal ejected may cause injury or death to miners. The gases emitted pollute the mine air and may also result in death to miners.

Jan 1, 1988

By Barnes R. G, Agostini A, Lewis P. C

The Mineral Resources Audit is a five-year Program established to produce a comprehensive and objective assessment of the mineral resources of New South Wales, including prospective resources. The goals of the Program are to improve planning and land use decision-making; attract exploration and minerals related investment; help the Department to identify and fill gaps in knowledge; and develop methods to identify and quantify resource potential and prospectivity. To achieve the goals of the Audit it is necessary to assemble and enhance a large amount of information and it is necessary to spatially analyse this information using computer-based Geographic Information Systems (GIS) which allow the collection, storage, transformation and display of large quantities of spatial data. An extensive range of both map-based and textual data can be employed in spatial analysis and resources and geoscience modelling. In order to use this information, data sets have to be corrected and standardised. Many data sets need to be classified. An objective of the Audit Program is the spatial analysis of the State, region-by-region, and the release of cleaned-up multiple digital data sets as packages which include upgraded mineral deposit information, 'seamless' geological map layers showing lithology, structures and stratigraphy, and processed and classified geophysical map layers. These regional packages are important reference sets for the mineral resources industry and will assist delineation of regional exploration targets.

Jan 1, 1995

At the Highway gold deposit, 37 kilometres south of Charters Towers, gold mineralisation occurs in several stratiform layers and is enriched near the surface by lateritic weathering. The host rocks of the mineralisation are ferruginous and baritic, intensely sericitised, kaolinised and silicified rhyolitic tuffs and pyroclastics of the Cambrian-Ordovician Mount Windsor Volcanics. The geology of the deposit is illustrated in Figures 1 and 2.Forty-six reverse circulation percussion drill holes were completed by North-Queensland Resources N.L. for a total of 2,093 metres of drilling to further outline and test the open pit resource. The drilling indicated a resource of 171,000 tonnes averaging 4.4 grams per tonne gold and 5.0 grams per tonne silver.A shallow initial pit, approximately 30 metres deep, has been designed to mine the high grade upper portion of the western stratiform layer and part of the eastern layer. This initial pit is designed to mine 45,400 tonnes of western mineralisation at an average grade of 7.84 grams per tonne gold and 22,200 tonnes of eastern mineralisation at an average grade of 1.42 grams per tonne gold. Waste is estimated at 110,900 tonnes.

Jan 1, 1986