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By I. Gaballah

Decontamination of synthetic solutions of copper acetate, chloride, nitrate and sulfate containing 10, 100 and 1000 ppm of copper, using chemically treated barks has been studied. Metal percent removal from solutions depends on the pH and the initial concentration and to some extent on the salt used. It varies from 40 to 99 % of the solution initial metallic ion's content. The maximum retention capacity of the treated bark varies from 31 to 43 mg of Cu per gram of dry modified bark. Bark loaded with copper had been analysed by Scanning Electron Microscopy and lnfra Red spectroscopy. Cu is uniformally distributed in the bulk of the bark. No copper segregation is observed. It seems that copper is bound to the acidic sites of the bark. Anions are not detected on the copper loaded bark neither with the SEM or with the IR spectroscopy.

Jan 1, 1993

By C. A. Young

In-situ Fourier transform infrared/internal reflection spectroscopy (FT ?IR/IRS) has been extended to study oleate adsorption at a calcite surface. The birefringent and transmission limitations of calcite were overcome by using an appropriately designed optical setup and a near-infrared (NIR) spectrometer. An adsorption isotherm was determined at pH 9.2 and room temperature. Comparison with the fluorite/oleate adsorption isotherm determined by the same technique indicates that oleate abstraction by calcite can be as much as one order of magnitude larger than that by fluorite. Nevertheless, the hydrophobicity of the fluorite/oleate surface is greater for equivalent adsorption densities as indicated by contact angle measurements and flotation results. The monolayer region has been confirmed to be chemisorbed oleate at both calcite and fluorite surfaces. Furthermore, multichannel laser Raman spectroscopy (MLRS) showed that chemisorbed oleate at the fluorite surface undergoes a double-bond reaction with oxygen to form an epoxide/polyether complex. Such a reaction, however, could not be detected at the calcite surface. These phenomena are discussed in terms of the intrinsic surface properties of the mineral systems as well as the adsorption density and the cross-linking/polymerization reaction of the adsorbed oleate film.

Jan 1, 1993

By C. D. Secrest

Visiting Spring Canyon, a historic coal mining district near Helper, Utah, I was impressed by the great accomplishments that had taken place there. A tour book of the region tells of a period that began in the early 1900's, when the land was still very much the Old West, when settlers lived out their lives in coal company towns and produced a resource that was to build a nation (Cunningham, F., 1990). Between 1912 and the early 1970's, 11 mines had come and gone in that narrow canyon less than 15 kilometers long. Spring Canyon is a historic district now, but I could not dwell too long on the richness of its history. I was there to look for evidence of PCBs.

Jan 1, 1993

By B. E. Davis

A problem that has continued to plague the Florida phosphate industry is the loss of coarse phosphate in the flotation circuit. Attempts to remedy this problem such as floating the coarse material (plus 425 µ m) in a separate circuit have resulted in limited success, but recovery is still not optimum. The Bureau of Mines is investigating ways to improve the recovery of coarse phosphate through improvements in the conditioning step. Studies to optimize conditioning parameters such as agitation energy, conditioning time, conditioner solids, and residual clay content have resulted in improved P2O5 recovery. Optimizing these and other conditioning parameters resulted in a rougher concentrate grading 30 pct P2O5 with a P2O5 recovery of 97 pct.

Jan 1, 1993

The need for legislative reform of health and safety legislation has been recognised in New Zealand for about a decade. Previous legislation did not cover all work places, many areas were excluded from coverage, and there were at least 14 different acts and dozens of sets of regulations dealing with various aspects of health and safety.

Jan 1, 1993

By J. R. Goode

The first part of this paper comprises a general discussion on refractory gold ores and their mineralogy processing methods now in use are reviewed and test procedures for the important methods are discussed. Factors determining the selection of a process are outlined. The paper includes a survey of production plants using pressure oxidation, roasting and biological oxidation to process refractory ore. The status of processes under development is briefly reviewed.

Jan 1, 1993

By R. V. Ramani

One area of study in the Coal Mine Injury Analysis project was to illustrate and enhance the ability of mine safety management personnel to apply analytical techniques to injury experience data and to justify requests for funds for safety enhancement actions on a cost/benefit and other quantitative basis. Four volumes of this final project report detail (1) the objectives and scope of the mine safety management research, (2) the results of literature review, and case studies, and (3) models developed for mine safety management. The four volumes are titled as Volume III: Mine Safety Management, Volume IV: Analytical Techniques for Mine Safety Management; Volume V: Mine Safety Management Case Studies and Volume IX: Training Cost Model. In this volume, the quantitative procedures that have been developed for the mine-specific analyses of accident/injury experience data are presented and their applications are demonstrated in a summary form through case study examples. The quantitative procedures will aid mine safety management personnel to develop focused accident prevention strategies including training, as well as to justify the investment in such proactive programs through cost-benefit analyses.

Jan 1, 1993

By Renato G. Bautista

The solvent extraction separation of nickel, cobalt and their associated metals have been considered for industrial application since the early 1960's. This review of the solvent extraction processes is limited to the industrial applications, pilot plant and the more extensive bench scale studies reported in the literature. The processes with their significant chemical and technological contributions are discussed in detail whenever the information are available. The application of solvent extraction to the nickel-cobalt processing has so far been limited to the secondary separation of nickel-cobalt containing feedstocks derived from other primary nickel-cobalt separation methods.

Jan 1, 1993

By J. E. Hamak

This publication contains analyses and related source data for 162 natural gas samples from 15 states and 4 foreign countries. Of the total samples, 154 were collected during calendar year 1992. The remainder were collected earlier, but releases granting permission to publish were not received until 1992. None of the analyses have been previously published in annual reports. All samples were obtained and analyzed as part of U.S. Department of the Interior, U.S. Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free-market economies. This survey has been conducted since 1917. The analyses published herein were made by mass spectrometer and chromatograph.

Jan 1, 1993

By L. R. Stark

Two wetland simulation experiments were carried out in order to determine the effects on manganese retention of several wetland design parameters, including flow rate, inlet pH, carbon supplementation, substrate type, and surface free water depth. The primary aim in each experiment was to determine if sustained manganese retention could be accomplished under the specific experimental treatments. If successful, these experiments could recommend design parameters for the construction of field wetland systems for manganese treatment. Crushed limestone clearly was superior to spent mushroom compost with respect to manganese retention. The presence of free surface water detracted from manganese treatment, while lower flow rates enhanced manganese treatment. Sustained manganese retention was achieved using crushed limestone as the substrate coupled with an absence of surface free water, under inlet water conditions of pH 7.0 and no appreciable iron. Sustained manganese retention was not achieved under reducing conditions using spent mushroom compost while varying flow rate, inlet pH, and carbon supplementation regimes. However, lowering the flow rate resulted in many significant beneficial effects on outlet water chemistry: lower outlet manganese concentrations (over the short term), higher outlet pH, lower outlet acidity, higher outlet alkalinity, higher outlet sulfide, lower outlet sulfate, and lower outlet redox potential. Supplementation of the wetlands with dairy whey resulted in lower outlet manganese concentrations (over the short term), marginally higher outlet sulfide levels, and acted to lower the redox potential under the high flow regime. Wetlands receiving a neutral pH had lower outlet acidity, higher outlet alkalinity, lower outlet sulfate, but equivalent outlet manganese concentrations than wetlands receiving an acidic pH. When manganese is the primary mine water contaminant and a passive water treatment system is to be used, it is recommended that crushed limestone with negligible surface water be used in place of composted materials. This recommendation assumes a source water with circumneutral pH and an absence of other metals.

Jan 1, 1993

By W C. Cook, S J. Mathews, A H. Purvis

The Golden Cross Gold Mine is located at the head of the Waite kauri Ri ver, 8 km northwest of Waihi near the southern end of the Coromandel Range. The mine produces gold and silver from epithermal veins hosted by Miocene andesitic flows and pyroclastics of the Coromandel Group. Golden Cross is owned in joint venture by Coeur Gold NZ Ltd (80 per cent) and Viking Mining Company Ltd (20 per cent). Mining is by open pit and underground methods. Mineralisation in a near-surface sheeted/stockworked vein zone is mined from the open pit. The deeper Empire Vein System is mined from underground where higher grade mineralisation is restricted to generally discrete veins. The open pit stockwork zone is west of and offset from the updip trend of the Empire Vein System. The Empire (hangingwall) Vein strikes generally north-northeast and dips steeply west. Dips become subvertical at greater depth. The hangingwall vein is a well developed, generally continuous structure with relatively high gold grades. A complex footwall vein system forms shallow west-dipping offshoots to the hangingwall vein. Structure and gold grades become increasingly erratic away from the hangingwall vein. The better developed footwall veins carry economic grades and high 'spot' grades over 50 g/t Au are not uncommon. Highest gold grades are associated with tightly crustiform banded sections of quartz veins and with dark fine grained siliceous breccias. The main hangingwall vein occupies a major north-northeast trending fault structure, the Empire Fault. Footwall veining forms within subordinate splinter fault zones. There has been extensive multidirectional pre-, syn- and post-mineralisation faulting. Fault manifestation is highly dependent on host rock characteristics. The central part of the hangingwall vein and surrounding silicified country rock has been shattered by a major fault structure, the West Mine Fault, forming a poorly consolidated, blocky quartz-breccia ore zone. Away from the more brittle ore zones and associated silicified envelope, wide clay-filled shears mark the major fault trends. Development of the deposit is considered to have occurred in two distinct stages related to separate episodes of dilational jog movement on the Empire Fault. The first phase reactivated the pre-existing Empire Fault as a dilational fissure with subordinate splinters on the footwall side. The Empire Vein System (hangingwall and associated footwall veining) formed during this phase. A second phase of renewed movement with further dilation resulted in more extensive fracturing of the Empire Vein and surrounding country rock and formed the sheeted/stockwork veining of the open pit. An upwards/westward migration of the hydrothermal system is assumed but fluid pathways between underground and open pit veining are unclear. Ore extraction and mining geology methods have responded to improved understanding of the grade and structural variability, and changing ground conditions inherent in the vein system. The underground mine produces ore from flatback cut and fill, post-pillar and bench stopes. Open pit and underground ores are campaign milled through a conventional CIP plant.

Jan 1, 1993

By W. C. Hirt

Selective flocculation was used to produce superclean zinc concentrate with minimized silica contamination. Research was carried out on a flotation concentrate from the Jersey Miniere Zinc Company (JMZ) in Gordonsville, Tennessee. The material was first dispersed with sodium silicate and then causticized tapioca starch was used to selectively flocculate the sphalerite, leaving the silica in suspension. This technique has been applied commercially to iron ore beneficiation but has never been used for processing zinc. The feed material assayed 0.45% Si02. Use of 0.56 kg/tonne (1.13 lb/st) of sodium silicate and 0.070 kg/tonne (0.141 lb/st) of causticized tapioca starch resulted in 98.2% zinc recovery in a purified zinc concentrate assaying 66.0% Zn and 0.24% silica. The present target level for silica contamination in JMZ zinc concentrates is 0.3% Si02. This work has shown that selective flocculation offers a potential method for cleaning flotation concentrates, particularly where low silica products are required.

Jan 1, 1993

By B B. Beamish

Long-hole directional drilling for in-seam exploration was introduced to New Zealand at Huntly West Mine in 1989. Following the success of this initial drilling program the Coal Corporation of New Zealand (CoaICorp) purchased its own drilling equipment and proceeded to adopt the technique with in-housetraining. From July 1991 to September 1992 a total of 15 455 metres was drilled at Huntly West Mine. During this period several modifications were made to the drilling technology to suit the ground conditions. The resulting interpretations of the drill information enabled reliable seam definition to be incorporated in mine planning. Since January 1993, the technique has been transferred to the Huntly East Mine to assist with seam definition for the planned development westwards under the Waikato River. The benefits of this drilling technique to coal mine planning are now well documented in Australia and New Zealand as well as other overseas countries. The possibilities of adapting the long-hole drilling technique to hard rock applications has been illustrated recently with successful cross-measure drilling at Huntly East Mine.

Jan 1, 1993

By Larry A. Haas

The U.S. Bureau of Mines, in cooperation with Cleveland-Cliffs, Inc. (Hibbing, MN), investigated ways of enhancing the quality (compressive strength, after-tumble and reducibility) of domestic acid and fluxed magnetite pellets by modifying the oxygen content during the preheat and induration periods of the firing operation . Oxidation of magnetite was best accomplished when sufficient oxygen and time were available before the peak induration temperature was reached. The rate of magnetite oxidation increased directly with the gas oxygen content during the preheat period at 7000 C and above. With 30 pct ( or more) O2 and a preheat rate of 2000 C/min, most of the magnetite was oxidized during the preheat period. With laboratory tube and mini-pot furnace tests, oxygen enrichment during the preheat period improved the pellet properties more in the simulated grate-kiln tests than in the simulated straight-grate tests. The longer induration period with the grate-kiln test resulted in more sintering of the residual magnetite and its reaction with the silicon compounds. When flux was present in the pellets, calcium silicates and calcium and magnesium ferrites were formed. More calcium ferrite was formed when the magnetite was oxidized early and less iron was present in the fayalitic calcium silicate slag.

Jan 1, 1993

By A. P. Cook

Methane drainage on a mine-wide scale is a relatively new technology to South African coal mines. Shallow seams and apparently low methane contents have been assumed to result in less methane problems than experienced in other countries. The introduction of deeper mines however, has now resulted in methane drainage taking on a higher priority. Methane contents in the region of 12 m3\t have resulted in one colliery introducing drainage as a ventilation support. Although a low seam permeability initially indicated reduced potential for drainage, early borehole flows of 90 m3\m\year have since increased to 450 m3\m\year. Rapid inflow of methane into goafs and sealed areas from seams surrounding the main production seam at another colliery have warranted extensive evaluation of the methane properties of these seams with the projected introduction of predrainage from surface. Methane pressures in excess of 1000 kPa and contents in the region of 10 m3\t again give methane volumes suitable for drainage. Coal seam drainage ahead of mining is becoming more significant and is likely to see an increase in the near future. INTRODUCTION Methane gas is an everpresent hazard associated with underground coal mining. Safe working levels of methane in the mine atmosphere are normally maintained by ventilation practises, ensuring sufficient dilution of the gas. However in some cases the ventilation must be assisted by methane drainage, either from the mined seam, or from adjacent seams and strata, or from goafed areas. South African collieries have practised only limited methane drainage until now. Relatively shallow mining depths, and apparently low in-seam methane contents have been assumed to result in fewer problems with methane than are the normal for other countries. This is now being shown to not necessarily be the situation. Work carried out by the Coal Mining division of COMRO (Cook and Erwee, 1991) indicates South African production coal seams have very similar methane retention properties to those of coals in other countries, with seam gas contents of up to 12 m3/t. This awareness, as well as greater mining depths, and higher degrees of mechanisation, has resulted in higher priority being given to methane emission problems throughout the industry. Increased levels of safety, as well as possible commercial applications, are the main reasons for the interest now being shown in methane drainage. Not only is there possible applications in the present production coalfields, but South Africa has vast areas of coal reserves which are presently non-mineable, now being seen as possible alternative energy sources. Limited methane drainage is practised within the industry, but only on collieries that have identified specific methane problems that can be alleviated by drainage. Historically this has been restricted to surface drainage of longwall goafs, reducing emissions onto the faces. More recently, horizontal in-seam holes have been drilled, until now for bord and pillar sections, but the results are being evaluated for later application to shortwall faces. Adjacent seams pose problems at some sites and vertical and cross measure boreholes are now being considered.

Jan 1, 1993

Planning for the Macraes Extension project highlighted the need for additional tailings storage availability. The possible solution of developing new tailings impoundments in Northern Gully, in tum, led to concerns being expressed by the regUlatory authority over the assimilative capacity of Deepdell Creek. Philosophical differences over the appropriateness of applying a seepage model used to set standards in consents for the original project resulted in the company re-evaluating the whole monitoring system associated with tailings disposal and seepage control. Re-evaluation indicated problems arising from the existing in-stream water quality monitoring in respect of protection of the aquatic ecological system and verifiability of results. A new monitoring system was designed relocating the compliance monitoring point out of the stream and into the gully containing the tailings impoundments giving greater certainty of monitoring results to all parties and providing improved protection for the aquatic ecology of Deepdell Creek.

Jan 1, 1993

By A. E. Petersen

The United States Bureau of Mines conducted research on high-intensity magnetic separation methods for upgrading tantalum concentrates from Alabama. Process flow sheets were studied to maximize tin removal and minimize tantalum loss. Using laboratory-scale equipment, concentrates were produced which contained over 65% combined Ta2O5-Nb2O5. Up to 78% of the tin was recovered as a byproduct, containing about 70% SnO2. Only 1 to 5% of the tantalum reported with the tin byproduct. The producer subsequently incorporated high-intensity magnetic separation into its process flow sheet to provide concentrates for the National Defense Stockpile.

Jan 1, 1993

By J. W. Evans

Mathematical modeling has now become a standard technique in the development of new technology and the improvement of existing technology in the processing industries. Physical modeling has a longer history but a smaller following at present. The paper reviews some examples of the application of both types of modeling in non-ferrous metal extraction, particularly within the copper and aluminum industries. The objective is to show that well founded models can lead to results that have practical consequence in scaleup, design and operation.

Jan 1, 1993

By J. A. Bleeck

A discourse on the relationship between industrial minerals and paper production, concentrating on high grade, ultra fine ground calcium carbonate (mean particle size less than 2 microns) and precipitated calcium carbonate. The scope of the paper encompasses four basic areas relevant to the topic: 1. A tutorial overview of the papermaking process with an examination of various industrial mineral components in that process; 2. A discussion of basic technological topics pertinent to the utilization of carbonate in paper with emphasis on the relative aspect. Of natural ground calcium carbonate (GCC) and synthetic precipitated calcium carbonate (PCC); 3. An overview of paper and carbonate market, in both the United State, and Europe with emphasis on (a) current status and future growth trend. Of such market., and (b) discussion of the major influences on growth and development of such market.; and 4. Identification and discussion regarding the principal producers in calcium carbonate markets serving the paper indu.try in Europe and North America.

Jan 1, 1993

By R. F. Hammen

Heavy metal contamination of water is a problem of immense national and international proportions. However, effective cleanup is complicated both by the toxicity and the low concentrations of metals in wastewater streams. Using high performance chelation chromatography, the solid phase extraction and purification of extremely dilute metals from water was highly effective. The process is based on selective displacement of metals from a chromatographic column containing a chelating resin. The resin is characterized by extremely efficient adsorption kinetics which allow rapid and complete removal of the metals.

Jan 1, 1993