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By James D. Cook, Dan McCutchen

Effective overburden casting requires the efficient use of todays explosives and initiations systems if a mine is to survive. This paper uses a major coal stripping operation as an example of the proper application of explosives and initiation system to their conditions.

Jan 1, 1994

By N. A. Barcza

DC plasma-arc technology using a hollow graphite electrode (cathode) has been successfully implemented in the primary metallurgical industry in South Africa up to the 30 MW scale. Mintek has applied its expertise base, established over the past fifteen years, to testing the treatment of metallurgical wastes such as carbon- and stainless-steel plant dusts, lead- and zinc-containing slags, and residues from the base-metal industry. Favourable results have been achieved, and disposable products were produced. The evaluation of numerous wastes indicates that recovery of zinc as metal gives the best economic return from these sources. Direct recovery via a splash condenser or electrolytic zinc extraction from fume are the two preferred alternatives under review. In both instances dehalogenation is an important issue, but can be achieved by suitable treatment processes. The Enviroplas technology provides a flexible, commercially viable approach to the treatment of a wide variety of wastes. Mintek, together with its associate Pyromet CC, are installing a plasma- arc pilot-plant facility with both an ISP lead-splash condenser of about 5 t/d condensed zinc capacity and a combustion chamber to burn zinc vapour to zinc oxide. This will demonstrate the suitability of the Enviroplas technology for treating specific metallurgical wastes, so that customized industrial plants can be engineered based on large-scale testwork.

Jan 1, 1994

By Nenad Spoljaric

Greensand, greensand marl, and green earth are names given to sediments rich in the bluish green to greenish black mineral known as glauconite. The word glauconite is derived from the Greek word glaukos, meaning bluish green. The term "greensand" as a rock name for a glauconite-bearing sediment is more appropriate than "greensand marl," a term that has been doggedly perpetuated in the literature. Because of its potash and phosphate content, greensand was mined and marketed as a natural fertilizer and soil conditioner for more than 100 years. The advent of manufactured fertilizers with adjustable nutrient ratios led to a decline in the use of greensand in agriculture. The material has since been recognized as useful in water treatment. Unfortunately, despite large reserves and world- wide distribution, glauconite has not been utilized to any significant commercial extent because no major application has been found for a substance with its chemical composition and properties. This is probably due mostly to a paucity of research on its potential commercial uses. Extraction of potash received considerable attention during and just after World War I. Because of relatively high extraction costs and a generally low potash content (viz., less than 8%), glauconite lost its appeal as a source of this commodity. Historical Background Greensand was used as a fertilizer in New Jersey in the latter part of the 1700s. During the early 1800s its use became more common; applications of as much as 22.5 kg/m2 were sometimes made, although recommendations for agricultural use suggested 4.5 to 11 kg/m2 (Tedrow, 1957). Many crops, especially the forage type, were said to improve with greensand application; however, because of its slow release of potash, large quantities were required. Certain greensands that contain sulfur and sulfide minerals are harmful to plant growth, and these were classified as poison, burning, or black marls. The availability of higher grade potash salts from other mineral sources and the manufacture of prepared fertilizers displaced the agricultural use of greensand during the latter 1800s. During the mid-1800s the greensand industry, centered in a small section of the eastern United States, grossed more than $500,000/y. Toward the end of the century, however, annual production had dwindled to less than $100,000 in value. By 19 10 there were only six or eight greensand producers grossing less than $5,000/y each (Tyler, 1934). There was a brief revival of the US industry during World War I because of the curtailment of foreign potash, especially from Germany. During the latter 1940s and early 1950s greensand was again recommended as a food nutrient for plants and farm crops. Agronomic studies discussed its potential as a soil additive that gradually releases potash and many trace element nutrients essential for plant growth (Tedrow, 1957). Greensand was sold with the idea that it would condition soil and absorb and hold water while its base exchange properties would release trace elements. For a short time glauconite was used in certain parts of New Jersey as a binding additive in the brick industry, and in the 1800s it was used for making green glass (Cook, 1868). In the early 1900s the base exchange properties of glauconite were recognized for water treatment and the mineral gained acceptance as a water softener. Mansfield (1922) does not mention base exchange even though this phenomenon was known in 1916 or earlier. From 1916 through 1922 several patents for the use of glauconite as a water softening agent were granted. A method was also patented for treating greensand to improve it for water softening and ready regeneration with common sodium chloride brine (Borrowman, 1920, Spencer, 1924, Kriegsheim and Vaughan, 1930). Treated glauconite, on contact with water containing magnesia or lime, takes up magnesium or calcium ions and releases sodium ions. This exchange is limited to the outer surface of glauconite grains, and when all the surfaces have absorbed their capacity, the grains must be regenerated. Regeneration, simply stated, consists of treating or backwashing the glauconite with a sodium chloride solution, which replaces the hard water elements with sodium, thus reviving the glauconite. The process has become more sophisticated due to competition among companies in the water softening business. Greensand products for water softening generally consisted of several different grades distinguished by the particular treatment the glauconite was given during processing. The standard greensand water softener was produced from natural glauconite that was only washed and classified. Its characteristics for water softening are given in [Table 1].

Jan 1, 1994

By E. G. Charlesworth, M. J. Robertson

"Abstract - Gold mineralization in the Main Reef Complex at Sheba Gold Mine is hosted within shear zones in a sequence of shales and greywackes of the Fig Tree Group. Competency contrasts between these rocks and a steeply dipping chert unit provided a locus for the development of right lateral steeply dipping shear zones. A set of flatter dipping shear fractures crosscut these zones with their intersections defining a system of en échelon ore shoots.Mineralization is both of vein type and disseminated strata-controlled replacement type. The latter occurs mainly within the wall rocks to the shear zones. Arsenopyrite and pyrite are the major sulfides, with arsenopyrite being confined largely to greywacke beds and pyrite to the more iron-rich shale units. Gold was introduced, together with minor sphalerite, pyrrhotite, chalcopyrite and early arsenopyrite, toward the end stages of a first pyrite phase. The mineralizing fluids were introduced along dilated cleavage planes and, emanating from these, produced a series of replacement fronts. Mineralization was syntectonic to late tectonic and occurred under conditions of progressive deformation, resulting in sulfides which are concentrated in the hinges of shear-related folds and semi­ massive sulfides within tension fractures which are folded, attenuated and fractured .An analysis of the structures shows a sequence of events in which an initial ductile simple-shear event with a steep sense of movement was succeeded by a more brittle strike-slip event. Mineralization is temporally related to the latter. This evolution in structural style was probably related to reactivation of the Sheba Fault as a transcurrent fault during emplacement of large granitoid bodies."

Jan 1, 1994

By Richard A. Heckman

Destructive Thermal Technology (DTT) is used in the management of various waste streams. DTT includes Destructive Distillation, Pyrolysis and Classical Incineration. Recent work has more clearly defined the differences in these technologies based upon a more rigorous thermochemical approach. The U.S. Environmental Protection Agency (EPA) has chosen Classical Incineration as the Best Developed Available Technology (BDAT) for the management of hazardous organic wastes. Municipal Solid Wastes (MSW) and Sewage Sludges (SS) are also managed using Classical Incineration. Three environmental problems plague the use of Classical Incineration. Destructive Distillation, on the other hand, avoids these problems. It is an environmentally benign DTT for managing a wide variety of organic waste streams, including hazardous wastes. Thermochemical analysis of the available data on the performance of three types of DTT will be discussed.

Jan 1, 1994

By D. R. Spears

The U.S. Bureau of Mines has had an ongoing interest in developing new reagent schemes for floating Stillwater, MT, chromite ore. Previous reagent schemes have been unsuccessful in achieving complete separation, primarily because little is known about the surface chemistry of the minerals in this ore. In order to design a rational reagent scheme, a study of the binding of various functional groups (R = -H, -OH, -CO2H, -NH2) on the two components (chromite and forsterite) of the Stillwater chromite was undertaken. Electron Paramagnetic Resonance (EPR) Spectroscopy was used to determine the adsorption isotherm, from a cyclohexane solution, of spin-probes which contained the functional group of interest. This was complemented by studies of the saturation surface coverage of the spin probe on the two minerals. In each case, more sites existed on chromite than forsterite; however, the forsterite sites were more strongly binding for each functional group. The results are discussed in terms of their implications for flotation.

Jan 1, 1994

By Russell J. Foster

Public awareness of, and involvement in, recycling has increased significantly in recent years. Nevertheless, recycling is generally perceived as a new development, and is familiar only in the context of municipal solid waste management. The actual magnitude and scope of metals recycling in the United States have gone virtually unnoticed. Over time, both the quantitative and qualitative aspects of secondary metals recovery and reuse have changed substantially, while the attendant regulations have become increasingly stringent. This U.S. Bureau of Mines report examines trends and developments in major metal demand and recycling, and analyzes the possible impacts of regulations with regard to recycling activities.

Jan 1, 1994

Incidental to the progress of a geological survey of the Kalgoorlie goldfield during 1927 - 1928 a number of specimens of telluride minerals were obtained, chiefly with the help of Mr F G Brinsden, general manager of the South Kalgoorlie mine, and Mr Ernest Williams, general manager of the Boulder Perseverance mine. This collection was supplemented by a number of small specimens, including the rare copper telluride, which were collected and preserved from the Kalgoorlie mine by Mr A E Paton, and also by a few miscellaneous specimens from the collection of MrS F C Cook, of the Palace Hotel, Kalgoorlie.An extensive knowledge of the rare tellurium-bearing minerals was compiled during the last century from occurrences in Transylvania and Colorado. The recognition of different species has been based on chemical analyses and crystallographic measurements. In a few species there has been an absence of crystalline form, and these, together with the discoveries in this century of rickardite and 'weissite', muthmannite and empressite, have depended chiefly on the chemical analysis for identification. On the other hand, the crystalline form of nagyagite and stiitzite has been described in detail, while their precise chemical formulae were doubtfully defined.The announcement of the occurrence of tellurides at Kalgoorlie by A G Holroyd in the Kalgoorlie Mine on 29 May 1896, followed by their discovery in comparative abundance, stimulated the further study of these minerals. In this locality there is a general absence of well-formed crystals, and the knowledge gained has been confined to the record and description of previously known, but exceedingly rare, species.No new species has been recorded, but the intimate association of various species resulted in early description of two supposedly new species, kalgoorlite and coolgardite. These have been discredited since the investigation by L J Spencer in 1903, based on a collection of specimens donated to the British Museum.Spencer's list of species at Kalgoorlie comprises calaverite, sylvanite (or krennnerite), petzite, coloradoite, 'and altaite, and does not include hessite, previously mentioned by Krusch. In 1912 melonite and a copper telluride were added by J A Thomson and the presence of hessite confirmed. In 1912 there also appeared a full and detailed account by E S Simpson on behalf of the WA Geological Survey, which embraced his earlier notes on the tellurides, and which represents the state of our knowledge of the Kalgoorlie minerals, practically as far as can be attained without the use of the reflecting microscope.The position has been stationary for about 18 years, and it was thought. that the best use to which the present collection of tellurides could be devoted was an attempt by mineragraphic methods to study the mineral relationships, not only of the tellurides among themselves, but also to gold and other associated minerals. The precise mineral content and relationships become a factor of added importance with the development of flotation methods of treatment at Kalgoorlie.Moreover, the study would supplement the description of the ore deposits of the Boulder Belt that has recently been published.

Jan 1, 1994

By Tap Pryor

A very small nation with large seabed resources requires a strategy. The simplest approach is to duplicate every step taken by the United Nations (UN), in its own leasing programme. In addition, the smaller nations must sell itself and its competitive offering. It is one thing just to await applicants and/ or tenders, another to work to make the leasing seem like a very good idea. This cap be achieved through publications, correspondence, meetings (such as the Underwater Mining Institute, but especially through pro-active planning, seeking the ideal technologies in both harvesting and processing. The ideal would be some combination that could begin quickly and on a small scale. It must be within the UN environmental guidelines. To meet the "quick and small criteria," simple harvesting and physical processing methods must be given the highest priority. Once these are satisfied, then marketing studies can be completed. There is, of course, a market for every element but only careful engineering and cost analysis will determine accessibility. What is required is a stepwise approach, gaining greater and greater credibility at each step. In fact, much planning can be done for very low cost. In the Cook Islands, the first crucial step was the East-West Center publication which pulled together all facts in one volume and which found the local resource to be richer in significant ways than Clarion-Clipperton. Most seem to believe that it could be many years before full production is possible, but this has been conventional wisdom for so long that it has taken on the suspicious aura of myth. Is it real? Have all possible recent technologies such as robotics and physical processing been taken into account? Either way, it is essential that a comprehensive approach be taken so that all factors from resource to market are considered as inter-related until a single business plan emerges. When that is in hand and when its profitability and risk levels are found to be credible, adequate investment funds are available.

Jan 1, 1994

By Desmond Cook, Cynthia P. Dogan, Dale Govier, Gary Korth, James C. Rawers

"The microstructural and mechanical properties of iron powders processed in an attrition mill are highly dependent upon the processing environment. Extended high-energy ball milling in argon resulted in nanocrystalline bcc-Fe microstructure, while processing in nitrogen or alloying with carbon resulted in both nanocrystalline bcc-Fe and bct-Fe microstructures. In this U.S. Bureau of Mines study, both X-ray diffraction and Mössbauer analysis were used to show that the infused carbon and nitrogen concentrations were predominantly on the grain boundaries. Explosive consolidation resulted in a fully dense product with microstructure similar to the microstructure of the mechanically processed powder. Hardness values of the compacts correlated highly with grain size, independent of the processing conditions.IntroductionNanocrystalline materials have been theorized and shown to have unique properties that make them interesting for material scientists and promising for material engineering applications. Several conferences have been devoted solely to the techniques of preparing nanostructured materials have been held(l,2,3.). To date, most techniques used to generate nanocrystalline materials produce only a few grams of particles(1). High-energy ball-milling, however, is an efficient and effective technique that can produce substantial quantities of nanocrystalline materials with homogenous chemical composition that cannot be produced by conventional processing techniques(3).Applications and material evaluations of nanocrystalline materials require several grams of solid samples. Because nanocrystalline microstructures' are thermodynamically unstable, producing consolidated macro structures of nanocrystalline material has proved to be very difficult(2,3). In particular, retention of the nanocrystalline microstructure during consolidation of nanocrystalline particles has proven to be a problem. In contrast to many consolidation techniques that require elevated temperatures, explosive compaction uses a shock wave for consolidation( 4,5)."

Jan 1, 1994

By W. C. Lacy

It is the responsibility of educators to look ahead and prepare young engineers and scientists to cope with industrial and social problems of the future. We are faced with a review of history as well as prophesy of the future. The mining industry exists in a "bubble" with little interaction or communication with the outside. This isolation must be broken down if the industry is to survive in the U.S. and Canada. The ability to communicate with the general public and public officials is essential. Many changes are occurring that will require readjustments in technology and staffing. Aging population will result in raising retirement and increasing available workforce. This may force shorter working weeks to supply additional jobs. Environmental concerns will likely direct more attention not only to these concerns during mining, but to planning for post-mining land usage. Retraining and up-dating educational programs are required to cope with these changes.

Jan 1, 1994

By A. B. Cook

The South African socio-economic history started with pastoral and agrarian communities which had low levels of industrialization and small needs for energy. The discovery of diamonds (in the Northern Cape in 1867) and of gold (in the Transvaal in 1886) heralded economic and industrial development, with a concomitant demand for energy. The energy needs of the fledgling mines, and mining towns, were met by the combustion of wood, cut locally, or by coal, hauled laboriously from the primitive collieries, and sold to the mining companies and townships at high prices.

Jan 1, 1994

By S. Middlemiss

The Indentation Fracture technique is being developed as a tool for use in comminution and mineral liberation analysis. Fracture toughness measurements for a number of mineralogical materials were made and comparisons were drawn between these and properties measured with the Ultrafast Load Cell drop weight apparatus. The technique has also been used as a probe to quantify differences in fracture properties at different areas in the microstructure of a material. In both a Utah limestone and a South African quartzite, material near a grain boundary fractures very differently to that in the bulk. Ongoing work is ultimately aimed at producing a comprehensive fracture model for a multi-mineral system based on its micro-fracture characteristics.

Jan 1, 1994

By Stella Sigler

This publication contains analyses and related source data for 153 natural gas samples from 16 States. Of the total samples, 149 were collected during calendar year 1993. The remainder were collected earlier, but releases granting permission to publish were not received until 1993. None of the analyses have been previously published in annual reports. All samples were obtained and analyzed as part of U.S. Department of the Interior, U.S. Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by mass spectrometer and chromatograph.

Jan 1, 1994

By P. J. Arps

Cyanide (CN) is used to recover gold from its ores in many locations worldwide. In spite of the established history of gold mining in Alaska, modern cyanidation methods have been used at only one location, the Ryan Lode Mine at Ester Dome, near Fairbanks. Ore was processed by heap leaching between 1987 and 1989, when permitting issues caused operations to be terminated. Those issues have since been resolved, and plans to reopen the mine are currently being discussed. Plans are also proceeding to develop several other ore deposits in the state, all of which include the use of cyanide for gold recovery [6]. Since tailings and effluent water produced from these mines will require treatment, it is important to develop detoxification methods suitable for the Arctic and sub-Arctic conditions found in Alaska. Several methods exist for removing cyanide from mining wastewater. However, most industrial users prefer chemical treatment systems, and typically use sodium hypochlorite, hydrogen peroxide, or sulfur dioxide/air/copper to oxidize free and complexed cyanides [9]. Biological treatment has been used successfully at two sites in the United States [30,32] and field tested at several others [20,27,28]. In addition, one mine uses "natural processes", which include natural oxidation, photodegradation, and degradation by naturally occurring bacteria [33].

Jan 1, 1994

By H. B. Miller

Contract Incentives have long been employed in the underground hardrock industry as a tool to influence employee performance, enhance productivity, and control labor costs. While traditionally structured to establish a direct correlation between performance and compensation, many contract programs have evolved into elaborate systems that promote strategies often viewed as independent of productivity. This paper presents the findings of research into these contract incentives and was conducted with the cooperation of 33 mines utilizing a spectrum of employee compensation and incentive programs. Emphasis of this analysis focuses on the types of production contracts observed and their role with respect to employee earnings.

Jan 1, 1994

By J. Hartikainen

19 papers were allocated to this session by the paper classification committee, 8 related to bored piles, 5 to continuous flight auger piles (CFA piles), 3 to slurry trenches, 2 to both bored piles and slurry trenches, one of them also dealing with root piles. There were no papers dealing with root piles only, as root filling is a different technique. One paper concerns sheet piling (Table 1). Table 1. Papers for session 1: Recent Technological Developments in Deep Foundations with Soil Excavation. [ ] Table 2. Classification of pile type in Belgium - van Impe W.F. /10/. [ ] Trends in piling Trends in piling in Central Europe were studied by van Impe for his brilliant lecture to the Finnish Civil Engineering Society. He claimed that bored piling is on the decrease and CFA pilling on the increase (Table 2). Thus the numbers of papers presented here do not conform to recent developments or trends. The papers submitted arc of course influenced largely by the fact, observable in Table 3, that bored piling is

Jan 1, 1994

By Ronald B. Stotelmeyer

This report summarizes studies of 28 National Forest roadless areas in Montana completed by the U.S. Bureau of Mines (USBM) in the period 1974-1993. It also briefly describes 20 areas for which field studies have not been conducted. All 48 of these roadless areas have been recommended for addition to the National Wilderness Preservation System or proposed as special management areas by the U.S. Forest Service (USFS) or the Montana congressional delegation. The Bureau studies indicate which parts of the roadless areas have a high likelihood for mineral-resource development. They also show where mineral production has occurred in the past and where abandoned mine workings (possible hazards) would be encountered. The number of mine and prospect workings found are a measure not only of surface disturbance, but of areas not wilderness in character. For the purposes of this report, mine refers to a property which produced (or is currently producing) a mineral commodity, a prospect is a property which has been explored but has no record of production.

Jan 1, 1994

By R. F. Hammen

Copper is one of the most widely used metals in industrial processes and is also present in most mining operations. Extraction of copper from solutions often proves difficult due to the presence of complexing agents. ChromatoChem, Inc. has developed a Solid Phase Extraction (SPE) support (HiPAC) for removal and recovery of metals from wastewater. The HiPAC SPE support employs chelating agents covalently coupled to a long linker molecule. Several solutions containing copper and complexing agents were tested including 1) copper and carbonate, pH 9.8, 2) mixed metals and anions with copper and cyanide, pH 11, and 3) copper and the chelating agent EDTA, pH 11. The copper was extracted from solutions one and two at high pH, but the EDTA containing solution needed the pH lowered to make the copper available for capture. In each example, the copper concentration was significantly reduced by HiPAC SPE treatment.

Jan 1, 1994

By Derek Ellis

Volume II of this two-part series on Submarine Tailings Disposal (STD) as a tailings management option for coastal and island mines contains descriptions of lesser known case histories. The Misima gold mine (Papua New Guinea) and the Black Angel lead-zinc mine (Greenland) are described in some detail as the best documented cases. Atlas copper mine (The Philippines) is less fully described due to relative lack of documentation. The Misima and Atlas STD systems are working to their design criteria. At Black Angel the system adopted did not prevent contamination for a number of reasons, which are now understood. Two cases are described where STD is being developed. They are the Cayeli Bakir copper mine Turkey), and the Toquepala and Cuajone mines (Peru). There is excellent documentation available for both cases. Three case histories are described where tailings have reached the sea either through beach or river discharge. In one case the STD option has been explored (Marcopper Mine, The Philippines). In the others we explore in hindsight whether STD might have been a viable alternative using the Screening Criteria that this Volume develops - see below. The mines are Bougainville Copper Mine in Papua New Guinea, and Jordan River Mine (Canada). There is potential for STD at all three sites. Finally, the Volume presents Screening Criteria for appraising STD, based on the experience in design, operation and environmental impact reviewed in the case histories.

Jan 1, 1994