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By D. J. Fray, F. Tailoka

Microporous ceramic tubes (15 micrometre pore diameter) and PVC membranes (10 micrometre diameter) have been used as spargers in the electrowinning of copper from concentrated and dilute chloride electrolytes. At a current density of 600 A/m2 and a nitrogen gas sparging flow rate (at NTP) of 1.53 cm3/s per unit electrode length, it was possible to electrowin planar rather than powdery deposits with copper concentrations as low as 0.157 M. To obtain a planar deposit at higher concentrations of cupric chloride the most realistic optimum current density appears to be between 1 000 and 1 500 A/m2.

Jan 4, 1993

By O. A. Orumwense

The liberation of intimately disseminated impurities from the coal matrix often demands that the material be ground to a high degree of fineness. Similarly, some technologies for coal utilization require superfine particles (i.e., sizes less than ten microns). This implies additional costs for coal preparation plants due to the high energy and media costs associated with fine grinding operations. Besides, there are problems such as sever product contaminations due to media wear and impairment of the quality of coal. Hence, proper choice of grinding media type is important from the viewpoints of cost reduction and product quality.

Jan 1, 1993

Experimental Mine, Val d'Or, Quebec, Experiments on the ignition of sulphide dust clouds by explosives have been conducted in a 1 m3 explosion chamber. The explosives tested are ANFO, emulsion, aluminized emulsion and Detasheet. By controlling the composition of the ANFO and the emulsion explosive the oxygen balance could be changed in order to identify the dominant factors in the ignition of sulphide dust clouds by explosives. Experimental results, combined with theoretical calculations, show that the temperature of the detonation products is the most important parameter in the ignition of the dust cloud while the combustible detonation products are of secondary importance in the case of non-aluminized mining explosives. In the case of aluminized explosives and explosives having very negative oxygen balance the ignition of the dust cloud is assisted by the large amount of combustible detonation products.

Jan 1, 1993

By Andres Vikdahl

The Rönnsktär smelter has recently undergone a series of technical and operational changes. This changes are caused by our own will to remain and gain in competivety and to adapt to the ever changing surroundings. To be able to remain competitive in surrounding with high wage costs, high inflation and high environmental standards thorough cost management is needed. The Swedish economic policy in the beginning of the 80'ies consisted amongst other things of two devaluations. The exchange rate of the Swedish Krona was reduced with approximatively 25 %. This boosted the profits of our export industry, some even believed we entered the land of milk and honey ... And working in this promised land where everything turns into profit it is very difficult to be careful and restrictive with your spendings. Apart from some healthy and fruitful investments we allowed ourselves yearly steady increases in salary for ever reduced number of worked hours and we of course employed more people. Inflation rates went up and so did property prices. In 1986 finally reality catched up on us. Reality in the form of too high costs started to hit Swedish export industry 5-6 years after the big devaluations. Furthermore the high inflation rate also hit the domestic industry a couple of years later. Together with other important factors Sweden faced a severe home-made recession in the beginning of the 90'ies. With this background we now report and analyse our smelter's performance and operating results, shown in fig 1 The main constrictions on smelting and refining at Rönnsktär are today: * Income restrictions by governmental production level Limit * Throughput resmctions by governmental emission limit * High capital costs in the aftermath of Swedish high inflation in the recent decade * Low work force turnover Below we will illustrate how we tackled with these issues along the following lines: * People * Quality * Technology

Jan 1, 1993

By Dani J. Alldrick, Alastair J. Sinclair, Colin I. Godwin

"Abstract - The Stewart mining camp has a long history of precious and base metal mining. The camp is abundantly mineralized, with more than 200 widespread, varied, vein prospects, deposits and orebodies. These show wide variations in the mineralogy of ore, gangue and alteration assemblages, and wide variations in textures and structural settings. This report establishes the timing of the different metallogenic epochs and suggests a specific exploration application for systematic lead isotope analyses.Galena lead isotope ratios from a range of mineral occurrences indicate that all these varieddeposits formed during two main mineralizing events. Lead isotope data from the Stewart mining camp do not provide absolute ages for the formation of mineral deposits, but the relative distributions of data are consistent with dates determined in other studies. One ore-forming episode occurred in the Barly Jurassic and the other in the Middle Eocene. Both metallogenic epochs were brief, regional-scale phenomena. Sorne deposits from the younger mineralizing episode were em­ placed adjacent to or superimposed on the older deposits.Field and laboratory studies show that the two metallogenic epochs are characterized by different base and precious metal suites: Barly Jurassic gold-silver-zinc-lead-copper; and Middle Eocene silver-lead-zinc. Therefore, showings of different ages have different base and precious metal potentials and deserve different exploration emphasis. Lead isotope studies provide a reliable, cost-effective method for evaluating the age and commodity potential of small or recently discovered mineral showings and for setting exploration priorities on properties with several varied mineral occurrences . The determination of the age and metal potential of a prospect at an early stage of exploration may govern the urgency, intensity or even the necessity for further exploration work."

Jan 1, 1993

By K. S. Olson

My reaction when first asked to present this paper was; "What could I possibly say that would hold the audience?s attention for 15 minutes? What could I offer that anyone familiar with the Nevada Barite Industry wouldn't already know?" Well, quite frankly I can't. The industry has certainly been anything but exciting for the past 10 years and, in fact, quite depressing. The challenge, for those few of us left in it, has been to keep it alive. At times it has felt like a doctor must feel with a terminally ill patient. All I can do is recap the past ten years, review the present state of the industry, and offer a few personal opinions and observations as to where I think we are headed.

Jan 1, 1993

By Thomas P. Battle

Titanium is the ninth most common element in the Earth's crust, yet only in this century has titanium come into use as an engineering material, particularly in aircraft structures, as the metal, and in pigments, as the dioxide. In this presentation, the metallurgical aspects of processing titanium-containing raw materials will be reviewed. Particular emphasis will be given to the ores and beneficiation techniques which lead to the production of titanium dioxide pigment, which accounts for over 90% of world titanium production.

Jan 1, 1993

By A. Warczok

The heat transfer coefficient between liquid slags and solid surfaces is important for the design and operation of metallurgical reactors. An experimental technique developed for the purpose of measuring the heat transfer coefficient between liquid slags and solid metals is described. During the initial heating up of a Ni cylinder upon immersion in a liquid slag, a layer of frozen slag initially forms, then melts. The heat transfer coefficient measured during the initial rapid heat-up of the Ni cylinder, is approximately twice as high as the heat transfer coefficient measured during the final heat-up of the Ni cylinder subsequent of the liquidus temperature of the slag. The technique was tested in various melts i) NaNO3, ii) NaCl, iii) Na3AlF6 and iv) 2FeO*SiO2, giving consistent results. It was found that the heat transfer coefficient increases with increasing bath superheat and stirring. The heat transfer coefficient during the heating up following complete remelting of the frozen slag, is related to the slag superheat(AT) and the specific stirring energy(W) per kg of slag(E) as follows.

Jan 1, 1993

By R. G. Johnston

Minerals have many uses in paint systems. These roles include use as primary and extender pigments, sheen control, film durability enhancement, and rheology control. These and other uses of minerals in paints, and the effects of mineral quality variations on coatings performance are discussed. As coatings performance requirements become more demanding, tighter consistency of important mineral properties, such as particle size distribution and purity, is becoming increasingly vital. Future directions of mineral use to meet projected environmental restrictions and performance demands on coatings, including the use of advanced minerals technologies, are examined.

Jan 1, 1993

By J. R. Goode

The first part of this paper comprises a general discussion on refractory gold ores and their mineralogy processing methods now in use are reviewed and test procedures for the important methods are discussed. Factors determining the selection of a process are outlined. The paper includes a survey of production plants using pressure oxidation, roasting and biological oxidation to process refractory ore. The status of processes under development is briefly reviewed.

Jan 1, 1993

By Ullrich Kammer

Metaleurop's secondary lead smelter at Oker produces 60.000 mtpy of lead and lead alloys. More than 8O2 % of the raw materials are spent lead acid batteries. The other 2O2 % consists of drosses, ashes, scrap lead, type metal, sludges, etc., and is processed in a short rotary furnace (SRF). Also, industrial batteries not fitting in the battery scrap treatment plant are processed in the SRF provided with gas/oxygen-burner. Till Sept. 199O2, a soda ash slag was used in the SRF-smelting similar to the rotary kiln-smelting at Oker. Facing the future problems of handling and dumping soda ash slag, Harz-Metall GmbH has improved SRF-smelting with a non¬hazardous slag, insoluble in water, easy to dump and cheap in fluxes. This slag is based on a CaO-SiO2 -Fe0-type. Aim of the slag smelting is to be within the temperature range of 2 1100° and 1200°C - the eutectic line of Olivine in the corresponding ternary system. Since Sept. 199O2 Harz-Metall GmbH has operated the SRF with an "Olivine-type slag" with good results. Although the material is a "leady" slag. HMG is optimistic of using it as a filling material for construction purposes.

Jan 1, 1993

By J. A. Bleeck

A discourse on the relationship between industrial minerals and paper production, concentrating on high grade, ultra fine ground calcium carbonate (mean particle size less than 2 microns) and precipitated calcium carbonate. The scope of the paper encompasses four basic areas relevant to the topic: 1. A tutorial overview of the papermaking process with an examination of various industrial mineral components in that process; 2. A discussion of basic technological topics pertinent to the utilization of carbonate in paper with emphasis on the relative aspect. Of natural ground calcium carbonate (GCC) and synthetic precipitated calcium carbonate (PCC); 3. An overview of paper and carbonate market, in both the United State, and Europe with emphasis on (a) current status and future growth trend. Of such market., and (b) discussion of the major influences on growth and development of such market.; and 4. Identification and discussion regarding the principal producers in calcium carbonate markets serving the paper indu.try in Europe and North America.

Jan 1, 1993

By B. W. Cavender

"World-class manufacturing" (WCM) techniques can be applied in milling operations to substantially improve productivity and reduce costs. Through the use of "just-in-time" and "total quality control" practices, WCM methods establish an environment for continual and rapid improvement in all aspects of production operations, with particular gains in product quality, costs, flexibility, employee involvement, and responsiveness to customers. This paper examines WCM techniques that can be utilized specifically in the mill, and their influence on plant configuration, organization, and scheduling practices; equipment selection and maintenance methods; training; the role of supporting staff; and methods of data collection and analysis.

Jan 1, 1993

Societal influences, needs, and uses for recyclable materials are becoming increasingly important business and economic factors in the traditional natural resource companies. Several metals (such as steel, aluminium, zinc, lead and cadmium) are amenable ro recycle which eliminates solid waste generation and decreases the depletion of natural resources. In recent years, the non-ferrous industries have begun to recycle more materials and the next decade will see even larger recycle efforts. In addition to the traditonal recyclable materials, existing metallurgical plants are, or should be, able to handle and recycle materials viewed as 'hazardous'. Unfortunately, some national and regional regulations hinder, and in some cases prevent, the recycling of certain materials. Zinc Corporation of America (ZCA) is currently the largest producer of zinc metal in the USA and one of the world's largest producers of value-added zinc products. Over the last few years, ZCA has become one of the world's largest recyclers of zinc from various diverse materials. ZCA considers these recyclable materials as valuable 'land mines' that provide economic alternatives to the depletion of natural resources while serving society in the minimisation of solid waste disposal. Using the current production facilities of ZCA as a model, this paper overviews the recycling of zinc-bearing materials with special emphasis on: 1. the amenability for recycle within ZCA's pyrometallurgical and hydrometallurgical operations, 2. the quantities and economics of recycle, 3. the problems of recycling hindered by current national and regional regulations, 4. the concepts of total recycle rather than just recovering zinc while generating a modified solid waste, and 5. the motivators for recycling.

Jan 1, 1993

Government established and financed the NZ Steel Investigating Co in 1960. Its investigations showed that a steel industry was feasible and desirable based uponNorth Island titanomagnetite ironsands, and charted a route for its establishment. The initial processing used post-1945 preheating and prereduction developments, but later innovative improvements created what was essentially a new New Zealand technology. Of the North Island titanomagnetite deposits: the small ones at Waipipi were best made available for export; those at Kawhia and Taharoa were too remote for the economic siting of a mill; that at Raglan proved too small; while at Waikato North Head three times the requirement of 50 million tons of concentrate were located in two sand areas averaging 18 per cent titanomagnetite. Economic studies showed that a South Auckland site would be ideal, close to New Zealand's biggest market. The mill site, on a basalt flow at Glenbrook, was located by a half-day's fieldwork - near both the Waikato North Head deposit, and a railhead for bringing in Waikato coal, etc, and taking out steel products.   This development was one of several since World War II which altered significantly the lives and homes of New Zealanders (others were natural gas, oil, geothermal power, epithermal gold, aluminium, opencastable lignite, etc). All had the essential ingredients of the highest government backing, direct or indirect government finance, and first-class New Zealand scientific and engineering skills (eg to create new technologies). Not one such project failed.

Jan 1, 1993

By Gordon T. Austin

The combined value of production of natural abrasives, which include tripoli, special silica stone, garnet, staurolite, and emery, increased in 1993. The increase in the value of tripoli production was the result of an increase in total production. Special silica stone experienced an increase in unit value but decrease in the quantity produced. Garnet showed a 19 % decrease in quantity and an 8 % decrease in value. Staurolite increased about 51 % in the quantity produced and 136 % in value compared with those of 1992. Staurolite's significant increase in value of production resulted from a 56 % increase in the unit value. The fused aluminum oxide industry showed an 8 % decrease in the quantity produced and a 13 % decrease in the value of production. The silicon carbide industry saw an 11 % decrease in the quantity produced and an 8 % decrease in the value of production. Combined, the industries decreased 9 % in quantity and 11 % in value compared with those of 1992.

Jan 1, 1993

By Gordon T. Austin

The combined value of production of natural abrasives, which include tripoli, special silica stone, garnet, staurolite, and emery, increased about 4% in 1990. The increase in the value of tripoli production was the result of an increase in the unit value. Emery increased owing to an in? crease in the volume of the material produced and an increase in the unit value. Special silica stone experienced a decrease in unit value and an increase in the quantity produced. Garnet showed a 10% in? crease in quantity and a 73% increase in unit value. Staurolite decreased about 8% in the quantity produced, and the value of production decreased about 10%. The fused aluminum oxide industry showed a 5% decline in the quantity produced and in the value of production. The silicon carbide industry saw a 10% decrease in the quantity produced and a 9% decrease in the value of production. Production for both industries decreased 7% in quantity and value compared with those of 1989.

Jan 1, 1993

By L. J. Barnes, R. O. Koch, J. H. Versteegh, P. J. H. Scheeren, F. J. Janssen

Following two years of laboratory research with bench scale reactors, a 9 m3 experimental process demonstration reactor was installed at Budelco's zinc refinery to treat their underlying groundwater. A 600-fold scale-up was successfully achieved. It has demonstrated that this anaerobic microbial process can remove a wide range of heavy metals and sulphate to the required levels. Extended operation of the demonstration unit has shown that the process is robust, can withstand wide variations in feed composition, rapidly recovers from operational upsets and is easy to start up and shut down. The metal sludge produced can be processed in a metal refinery to recover both metals and sulphur.

Jan 12, 1992

By J. V. Wood, P. Davies, J. L. F. Kellie

A new range of wear-resistant materials is being produced by technology that has been used to develop high performance metal-matrix composites. These include steels and aluminium alloys that can be made as sheet, plate, rod or bar. The incorporation of hard, wear-resistant particles in an alloy matrix is achieved by reactive casting, spray deposition and powder metallurgical techniques. For example, large particles of TiC can be homogeneously distributed in steel during casting and the subsequent product can easily be rolled to plate. Similarly, up to 20% alumina particles and SiC can be injected, respectively, into steel and wear-resistant aluminium alloys by spray deposition. The current state of development of the process is reviewed and indications are given of the projected applications of such materials.

Jan 12, 1992

By P. Danson, D. A. White, S. Bashir

Composite ion exchange materials made of SnO2, TiO2 and MnO2 can be used to remove radioactive contaminants from nuclear waste streams. In several cases their selectivity and capacity are enhanced by mixing hydrous silica into the matrix. MnO2-SiO2 materials are especially useful for a number of reasons, such as their selection of heavy elements over caesium. Distribution constants and determinations of exchange capacities show that in many instances the properties of the composites are better than those of the oxides alone, while the presence of a chelating agent has been found to reduce the uptake of nuclides considerably. Methods are being developed for the bulk manufacture of the materials. Further work on sorption mechanisms is required to explain anomalous results, particularly the variation in exchange capacity for different elements and the ability of the oxides to sorb colloidal material in alkaline solution.

Jan 8, 1992