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Much of the theory upon which the Sublevel Caving (SLC) method is based was developed in Scandinavia many years ago. It was based mainly on æbinÆ theory and æellipsoid of drawÆ configurations derived from sandbox models. In many cases, classical SLC layouts influenced by these early theories obtained relatively poor results. Early dilution entry, low tonnage factors and low recoveries were commonly experienced. SLC soon gained the reputation of being a high dilution, low recovery and development intensive method. This led to SLC falling into disfavour generally, other than as a pillar reclamation method used at the end of the life of mines. More recently a number of mines, notably those in Australia, have adopted SLC as a primary extraction method and have achieved good recovery results. The reason for the better results is believed to be an outcome of modifications in some of the basic design parameters and operational procedures. This has led to questions being raised regarding the original æbin theoryÆ assumptions and classical SLC layout designs. It is clear that the fragmentation and flow characteristics occurring in a choke blast situation (compaction of waste, variable size and shape of fragmentation throughout the ring) conflicts significantly with the assumptions of regular loose flow of uniform, fine grained, material in a bin. Interactive versus independent draw conditions can also materially effect the outcome of a SLC operation. The good results obtained more recently can only be explained by using ænewÆ models of behaviour, which have to a large extent been borrowed from block caving. If these models are correct, they point to a number of design and operational changes that can be applied to improve the effectiveness of SLC. This paper discusses the factors that may not have been fully considered in early SLC design and modelling. It emphasises the importance of delayed dilution entry as a primary objective of sound SLC design and provides a basis for efficient SLC design and operation.

Jan 1, 2000

By Fathi Habashi

Extraction by organic solvents is a chemical process in which metal species in the aqueous phase react with an organic reagent to form an organometallic com- plex, thus, the metal species leave the aqueous phase and enter the organic phase from which it can be stripped back in the aqueous phase to obtain a pure and a concentrated solution. The metal in the organic phase is not bound to carbon atoms as in organometallic compounds but to oxygen, nitrogen, sulphur, or hydrogen by a co-ordination (dative) bond (Habashi, 1999).Solvent extraction was used for the first time in hydrometallurgy in connec- tion with the special and urgent materials requirements of nuclear energy during World War II. A plant was constructed in the United States for the preparation of high-purity uranyl nitrate solution. In this plant, the yellow cake (a high-grade sodium or ammonium uranate) was dis- solved in HNO,, and uranium was selec- tively extracted by ether then stripped by water to give a concentrated solution of pure uranyl nitrate. This was gradually followed by developing methods for other high-priced metals such as plutonium, thorium, niobium, tantalum, zirconium, hafnium, boron, beryllium, and molybde num. The second step took place in the 1960s when solvent extraction was applied for the first time to extract a rela- tively cheap metal-copper. At present, solvent extraction technology is wide- spread, well accepted, and highly efficient. Solvent extraction had its origin in the discovery, by Christian Friedrich Bucholz (1770-1818) in 1805, that uranyl

Sep 1, 1999

By Bert S. Hall

"The purpose of this paper is to review the evidence at hand concerning the earliest centuries of cast iron in Europe, from roughly 1400 A.D. until the second half of the sixteenth century. For the most part it is concerned with the relationship between two technologies which emerged first in China and then later appear in Western lands, gunpowder weapons and iron founding. We should not assume, as I hope to show later in this discussion, that weapons constituted the only product for which the iron founder had any market, but it is clearly true that attempts to produce weapons constituted the most severe technical challenge for the early founder. Firearms appear for the first time in Europe in the 1320s and develop into significant weapons on the field of battle by the end of the century. Theirs is a complex history, subject neither to easy summary treatment nor to simplified models of development. I hope to be able, through the analysis of the evidence concerning cast iron, to show that one important strand in the fabric of gunpowder's history concerns the materials from which cannon could be made. This question is subject to a number of shades of meaning, because ""cannon"" can be made for many purposes under a profusion of different names, and under sharply varying conditions of use. As a result, the question of materials is frequently really a question of competing materials, and involves a complex set of factors, of which production costs and the ultimate safety of the user seem the most important. Judged in this manner cast iron was an important but unsatisfactory metal for weapons purposes until 1543, at which time English founders learned to make iron muzzle-loading cannon which could rival bronze ordnance in most important performance criteria, but which cost much less to produce. With that event, the history of cast iron and the history of weapons entered into the close relationship that persisted until the advent of rifled artillery made of steel in the middle of the nineteenth century."

Jan 1, 1999

The information age has arrived. In every aspect of life, at the end of the second millennium, computers and information technology have made significant inroads. In mining there has been huge growth in the use of digitally controlled systems. From resource evaluation to mine planning to daily operations, information is being acquired, analysed, modeled and presented, using state-of-the-art information technology. Explosives, too, have moved into the information age. Computer controlled trucks and manufacturing plants have been developed and are now a regular feature on many mine benches. The next challenge for the explosives industry as a whole is to integrate blast initiation with information technology. The benefits are there, both to the supplier and to the end-user. Much has been written in the past about the potential for blast improvement but there are other significant advantages to a digital initiation system. These include security from unauthorised use, stock control and minimisation, reliability through testability and ease of use to name a few. So why is it taking so long? Surely the complexity of an electronic initiation system is far less than that of mobile phones that have been around for a long time. The answer, it seems, lies in the level of new technologies that need to be developed. There are enormous technological hurdles to be overcome in order to put into the market a cost-effective, reliable, user-friendly electronic initiation system. The most significant of these are:Safely and reliably initiating an explosive from an electronic device powered by a small capacitor. Prior to the development of electronic detonators primary initiation of explosives was by shock tube spit or by passing large currents and voltages down a pair of wires. Electronic detonators do not have that luxury. For example the energy stored in a æBeethovenÆ exploder is more than 500 times greater than that available to an electronic detonator. Communicating to a multitude of devices over very long cables installed by miners in harsh conditions. The deployment of an electronic detonator system has been likened to building a large telephone exchange in the rain and getting it to work perfectly first time! New communications protocols needed to be developed and tested. Wiring and connection systems have to be designed to survive the mining environment. In spite of these technological hurdles most of the major explosives manufacturers have persisted with electronic initiation systems and we are now, in 1999, starting to see the results of these multi-million dollar efforts. At SMI we are often asked many questions about this technology. The remainder of this paper seeks to answer those most often asked. As with any business linked to information technology todayÆs breaking news is tomorrowÆs archive and we expect the rate of development and understanding to accelerate as these technologies become accepted by the global mining industry.

Jan 1, 1999

By P. J. Mackey

"The metal producing industries in Canada and in the U.S. in many ways owe their technical beginnings to Welsh technology. The first copper smelter in Canada started in 1849-50 with a Welsh reverberatory furnace and skilled furnacemen brought across from Swansea to operate the equipment1- The Rocky Mountain smelting industry began with the installation of furnaces resembling the Swansea smelters(2). It was only later that the North American industry developed newer and improved methods. This article briefly describes the metallurgical history of the Lower Swansea Valley, being that section of land stretching northward from Swansea along the banks of the River Tawe, and bordered by hillsides east and west of the river. The Valley has had a classic cycle of development and decline common to industrial areas of Britain which grew in the Industrial Revolution. Perhaps more than any other area today, the Swansea Valley represents a complete cycle of use from agricultural to the peak of industrial development through to decline and dereliction. The conditions which made the Tawe Valley attractive to certain industries were laid down nearly 300 million years ago with the Carboniferous swamps and forests which covered the area, later forming the south Wales coalfield. As a result of glacial action and the deposit of glacial outwater and alluvial gravels, the valley adopted the traditional configuration, with its rocky sides occasionally remaining exposed. Up to probably about the 16th century, the Lower Swansea Valley was similar in use and appearance to many other valleys in the region. From the 14th century, the natural oak woodland had provided a continuous source of timber to produce charcoal for iron making as well as for structural purposes. Agriculture was the main activity in the valley in this period, but it was likely that the farmers also mined small amounts of coal by way of ""bell pits"", and adits into the coal seams."

Jan 1, 1999

By T. Ahokainen, J. Pitkälä, J. L. Xia, A. Jokilaakso, J. Vaamo

"The aim of the present paper is to use the two CFD codes to model the two phase flow in a water model ladle with central gas injection. The codes examined are CFX and Phoenics. An Eulerian two phase model is used and predictions are compared against the experimental data available. The results show that the codes can reasonably well predict the gas-liquid plume in the ladle, and predictions are generally in a good agreement with experimental data. However, differences do exist in predicting the gas volume fraction and velocity profiles. The results should be interpreted most carefully and cautiously, because they are very sensitive to the boundary conditions and dependent on the models for the physical phenomena involved. IntroductionSubmerged gas injection has widely been used in the metallurgical industry for more than a century. At the present, the use of gas is most effective in steelmaking industry where the advantages of the gas injection have already been long well understood. Effective mixing, large contact area between reactants, easy modifications and flexibility of the processes are the most important advantages. Disadvantages include refractory wear, blocking in the tuyeres, and splashing. These disadvantages can be reduced and advantages further improved by studying the flow phenomenon in process vessels. However, it is difficult to study flow in a real vessel because of the high temperatures and physical and mathematical modelling is therefore increasingly used in the process development work."

Jan 1, 1999

By W. M. Williams

The Canadian steel industry is now in many ways a mature one, having achieved many technical successes during its hundred-year history. It is interesting to look back over this period, to learn something of the histories of the different producers and of the people and forces that shaped their development. The following article provides a thumbnail sketch of the Canadian steel industry as it exists today. It is intended for the general reader, not for the specialist who will want to consult the several books and theses written on the development of the industry during the last hundred years. The famous Les Forges du Saint-Maurice, an important iron producer for a century and a half, provides a natural historical starting point for a look at the four major players - Dosco, Algoma, Stelco and Dofasco - who have provided most of the hundreds of millions of tonnes of steel, in every form from horseshoes to tinplate, needed in the twentieth century. The smaller companies which have sprung up in the last 20 or 30 years are dealt with briefly - but only because their history is so recent. Not so long ago the mini-mill, based on scrap rather than on the blast furnace, was thought to be specially suited to the economies of the smaller developing countries of the Third World. However, recent history has made it evident that the small plant, specializing in a few basic products (e.g. reinforcing bar) or taking advantage of special circumstances, can successfully compete with the large blast furnace/primary steel producers.

Jan 1, 1999

By E. B. Freidina

We have investigated a new electrochemical process for preparing lead-calcium alloys. Calcium metal, reduced fiom a molten chloride mixture, forms an alloy with liquid lead cathode. The addition of calcium carbonate to conventional CaC12-NaCl electrolyte enables us to avoid chlorine production on the anode and replace it with oxygen and carbon dioxide. The ternary system CaClz-NaC1-CaCO3 has a range of melt compositions, where the electrolysis can be held below 650°C. In order to prevent the side reaction of carbon deposition on the cathode we have separated the anolyte from the catholyte with alumina diaphragm. The factors, which affect the level of impurities and the current efficiency of the process, are discussed.

Jan 1, 1999

By Rita Michael

"The Marmara Ironworks was not the earliest ironworks in Ontario, but it was distinguished from other early works in a number of ways. It was established on an ambitious scale as a self-sufficient and, for the time, sophisticated community. In effect it was an iron plantation on the scale and scope of those at Hopewell, Pennsylvania and Saugus, Massachusetts(1). It was, besides, the only one of the few early ironworks in Upper Canada which operated almost to the end of the nineteenth century, albeit in fits and starts, and which used magnetic ores rather than bog iron ores (limonite). Furthermore it is the only works which has produced archaeological interest over a number of years. The ironworks is on the east bank of the Crowe River near Highway 7, on Lots 7 and 8, Concession 4, Marmara Township, Hastings County, Ontario. It is the property of the Village of Marmara, and the extant remains encompass about 2. 5 acres of the original 2000 or so which made up the original grant. The mineral riches of the Canadian Shield had been known since the days of the Jesuit missionary-explorers. A consortium headed by Alexander Henry and the Duke of Gloucester planned to exploit the copper near Sault Ste. Marie during the last part of the eighteenth century, but nothing came of the venture(2). This attempt may have grown out of Lord Dorchester's suggestion that private enterprise be encouraged in order that the iron ore which ""abounds"" in Canada might be exploited(3). John Graves Simcoe, the first Lieutenant Governor of Upper Canada was also anxious to see iron working develop. Simcoe was eager to encourage many enterprises, among which ""the development of iron mines""(4) - Governor Gore had been approached by John Mason for help with his ironworks in Norfolk County (5). Three Americans had applied for permission and support to erect an ironworks on the Gananoque River at the falls to become known as Furnace Falls. They were granted 1000 acres of land in fee simple to encourage their endeavor(6). Sir Peregrine Maitland, only a few months after taking up his duties as Lieutenant Governor in 1818, intended to visit the ""bed of iron ore on the Crow River"" (7) - Maitland was to provide a good deal of support, both moral and substantive, to Charles Hayes when he came to Canada in 1820."

Jan 1, 1999

By D. J. MacKinnon

Zinc metal was first produced in India around 1100 A.O. and a zinc industry based on retorting gradually developed in both India and China(1) . The vertical retort method for smelting zinc ores was developed in England in the 1730s; this was followed by the more fuel efficient horizontal retort process developed by the Belgians in the 19th century(2) . The horizontal retort process was the standard method of zinc manufacture until the 1950s when it became obvious that it could not compete with electrolytic zinc technology(2). The present day extractive metallurgy of zinc is dominated by the electrolytic process which now accounts for almost 80% of the world's primary zinc production. In recent years the electrolytic zinc process has seen significant improvements: the fluid-bed roasting of zinc concentrates, improved leaching and residue treatment techniques such as the jarosite and goethite processes, improved solution purification procedures, mechanization of the zinc electrolysis step and of the zinc melting and casting operation. In addition, new leaching processes have been implemented for the treatment of oxidized ores, particularly silicates, and the pressure leaching of zinc sulphide concentrates is now a commercial reality. Although the electrolytic zinc process was first used on a commercial scale in 1916, its history can be traced back to the 1860s. The purpose of the present paper is to outline the early history of the electrolytic zinc process and to trace the significant developments which led to the first successful commercial electrolytic zinc plants.

Jan 1, 1999

By G. M. Bond

Reduction of the emissions of greenhouse gases, such as CO,, is currently the subject of extensive research. A novel strategy is put forward here, based on a biomimetic approach providing accelerated deposition into carbonate form for long-term sequestration. It offers the advantages of a process that: does not require concentration of CO, from flue gases; could potentially be used in an on-site scrubber to provide a plant-by-plant solution to reducing CO, emissions; is an environmentally benign procss with an environmentally benign product; and is based on readily available, low-cost reagents (except perhaps the catalyst).

Jan 1, 1999

By S. K. Singh

"Feather edging"-a major source of injury and fatal accidents in Australia, South Africa and USA, refers to a phenomenon where the roof, at the goaf edge, falls as a thin wafer of rock often suddenly, over-riding conventional timber breakerlines. It may run down and affect adversely a working bord at distances of 15 metres or more from the goaf edge. Feather edging typically occurs in relatively massive, strong roof strata such as sandstone or conglomerate. This paper presents the results of a mine trial where a concentrated row of fully grouted bolts were able to resist the feather edging in the first comprehensive, monitored trial in an Australian pillar ('total') extraction coal mine.

Jan 1, 1999

By R. E. Johnson

Seventy years after the start of the Industrial Revolution in Great Britain, as reckoned from Arkwright's water frame patented in 1769, there was a significant development of the metallurgical industry in Virginia. In Britain, crucible steel had been rediscovered by Benjamin Huntsman in 17~0, and this made spring and tool steel more generally available. The metal-turning, screw-cutting lathe, including the basic principles recognized in today's engine lathe, was developed by Henry Maudslay about 1797. Wrought iron, as manufactured by Henry Cort's process patented in 1784, was readily available. Richard Trevithick's highpressure steam locomotive had met its test on the Pennydarren tramroad in 1804, and George Stephenson had built his famous Rocket, along with several other locomotives, at Newcastle around 1828. Puddling furnaces and a rolling mill had been placed in operation at the Tredegar Iron Works in Glyn Sirhowy, Monmouthshire, Wales, in 1807. In the United States, expanding commerce and a growing population resulted in continuing development from the Chesapeake to Virginia's Blue Ridge, and this demanded improved means of transportation. Ore deposits rich in hematite had been found in Virginia's Piedmont during the Colonial period, and a number of blast furnaces now dotted that area. The products of these operations were mostly pots, kettles, stove parts and like items for local trade. The James River and Kanawha Canal was incorporated in January 1785. Its eastern leg, winding along the slope of the high bluffs overlooking the river, was completed about 1800. About two dozen railroads were chartered in Virginia between 1830 and 1837. With expanding population and steady industrial development came a need for metallurgical products. Throughout the eastern United States, numerous metallurgical enterprises sprang up, and many of these flourished. The purpose of this article is to outline the development of one Southern metallurgical company, the Tredegar Iron Works, which was to have a significant impact on the industrial development of Virginia and the fighting of the American Civil War. Although the Tredegar Iron Works no longer exists, remnants of the early operations have been restored, and the current status of the site is also presented.

Jan 1, 1999

By G. France

The Blair Athol Coal Mine (BAC) is a large open cut operation in the Bowen Basin of Queensland, Australia. Current mine capacity is about 11 million tonnes per annum (Mtpa) of export coal. On-line analysis at BAC consists of two Coalscan 9500s installed directly on the output of the crusher plant and immediately before the product stockpiles, while a third Coalscan 9500 is installed on the transfer conveyor feeding the train loading bin. The two product Coals cans have a dual purpose. The first is to provide real time coal quality data directly back to the mining operations. The second is that of modeling the product stockpile with accurate on-line information. This modeling enables both production and coal quality personnel to accurately examine the coal quality of each stockpile with a degree of resolution which previously had never been achieved.

Jan 1, 1999

By Fathi Habashi

"On August 3, 1888, German Patent No. 43977 entitled ""A Process for the Production of Aluminum Hydroxide"" was issued*. The discovery which led to the patent was made by the Austrian chemist Karl Josef Bayer (1847-1904) (Fig. 1) who was at that time in Russia, and the process became known as the Bayer Process in his honour(1)(2)- The process imediately achieved industrial success, displacing the pyrometallurgical process that had been used until that time to produce alumina. The Bayer Process involved the pressure leaching of bauxite with NaOH solution to obtain sodium aluminate solution from which aluminum hydroxide was precipitated by seeding. Today bauxite is not only the principal source of aluminum but also of gallium, both metals being effectively recovered by the Bayer Process. The purpose of this paper is to outline the historical background of this discovery and its importance to hydrometallurgy."

Jan 1, 1999

By Christian Trassy, Pierre Proulx

"Inductive plasmas are now commonly used in material processing: spraying, powder synthesis, densification or spheroidization. An inductive discharge presents, in the coil region, recirculation eddies due to the Lorentz forces, resulting in an axial backflow. If the central jet is strong enough to ""pierce"" the recirculation this axial backflow disappears on the centerline, but the external layer of the injection flow is skimmed by the remaining eddy, and particulates are rejected to the discharge periphery. To avoid this disadvantage, it is common to introduce the injection pipe inside the discharge, so that its outlet is positioned after the recirculation eddy. The powders remain confined in the axial zone, to the expense of shortened residence time.In order to increase the efficiency of the particle trajectories, a double flow injector has been designed. It enables the particles to travel closer to the axis, while the outer schrouding gas is skimmed and passes through the electromagnetic eddies. This injector is made up of two concentric tubes. The powders are injected with the carrier gas in the inner tube. A schrouding gas is injected in the annular space between the inner and the outer tubes. The powder is confined to the vicinity of the axis, resulting in a more homogeneous thermal treatment.Tungsten powders have been spheroidized with and without this device. Using the double flow injection, the spheroidization yield has been increased from 70 % up to 95 %.The design of such an injection device has. been studied and improved using numerical modelling. Another useful tool, a visualisation technique described elsewhere, has been used for the experimental study, that drastically simplifies the comparison between experimental and theoretical results: injecting yttrium oxide into the discharge results in a colorful display of the 4000 K isothenn: the ""cold"" zone, below 4000, appearing as red, and the ""hot"" zone as blue. Furthermore, it is of great industrial interest since it is a very cheap and efficient way to obtain a picture of an important isotherm."

Jan 1, 1999

By D. J. MacKinnon

"The Canadian Copper Company, formed in 1885, began mining the nickel-copper ores of Sudbury in 1887 and producing nickel-copper matte from its smelter in 1888(1). Although it was quickly appreciated that the separation of nickel and copper (i.e. refining) was critical to the production of a marketable nickel product, refined nickel was not produced in Canada until about 1918. From the beginning of the industry, there was considerable political agitation to refine nickel in the Province of Ontario(2). The companies, however, claimed that the existing processes, viz. the sodium sulphide ""tops and bottoms"" process operated by the Orford Copper Company of New Jersey, U.S.A.(1,3,4) and the carbonyl process(5,6) developed by the Mond Company at Clydach, Wales, were too costly to operate in Canada. Nickel was first refined in Ontario about 1918 when the International Nickel Company opened a nickel refinery at Port Colborne, Ontario(6). Initially, however, the refinery at Port Colborne employed the Orford sodium sulphide process, and the first electrorefined nickel in Canada was produced in 1920 by the British America Nickel Corporation whose mine and smelter were located in Sudbury, Ontario, but whose electrorefinery was located at Deschenes, Quebec, near Ottawa, Ontario. The purpose of this article is to outline the early history of nickel electrorefining and to trace the significant developments which led to the first successful commercial electrolytic nickel refinery in Canada. The development of an electrolytic process for refining nickel is due largely to the efforts of four individuals, viz. Carl Hoepfner, Hans A. Frasch, D.H. Browne and ultimately N.V. Hybinette, and the contribution of each is discussed separately below."

Jan 1, 1999

By B. Cavender

Investments in new technology are often intended to improve the production or cost performance of existing operations. The economics used to justify these projects can be flawed, however, if they do not adequately consider the potential benefits of the alterative: the fully optimized use of the facility's present equipment and personnel. While new technology can be effective, dramatic improvements in production performance can also be achieved through the rigorous application of standard industrial engineering and operations management practices. An intermediate approach may also be effective: many basic improvements In the mine or plant necessary to support new technology will be equally effective when implemented for the facility's present operators. Firms who optimize their present operations are able to save the capital and avoid the risk associated with new technology. These firms will also be able to capitalize more quickly on new technology when it is implemented.

Jan 1, 1999

By J. L. Delplancke

During copper electrowinning in sulphate electrolyte, intense oxygen evolution takes place at the anode. Lead alloy anodes are progressively replaced by dimensionally stable anodes in order to avoid the cathode contamination by dissolved lead. The electroactive coating of these anodes has to be as cheap as possible, adherent to the substrate, electrochemically stable and has to be efficient at high current density and high temperature. This requirement is even demanding in case of copper electrodeposition for the production of thin copper foils for the electronic industry. The production of thin (20 µm thick) copper foils for the printed circuit boards requires high purity copper electrodeposited at a current density as high as 7,000 A/m2. The choice of a long term coating composition is driven by economics. The purpose of this paper is mainly to review the anode compositions suitable for copper electrowinning and for copper electrodeposition at high current density. A short description of preliminary results obtained with a new anode coating on a titanium substrate is also presented.

Jan 1, 1999

By W. Hitchcock

To enable the analysis of stability for a mine feasibility study a variety of geotechnical engineering parameters need to be obtained. At the early stage of a project it is usual for those responsible for the study to require a wide spatial distribution of RC holes in order to define a resource at the lowest possible cost. By the time a geotechnical study has commenced drilling priorities have usually switched to improving the definition of a resource, by drilling with diamond coring methods in the central area of the main orebody. The usual timing for geotechnical data collection is therefore after a wide distribution of holes have been drilled but which contain little geotechnical information. Conventional methods employed usually involve estimation methods, including book values and examination of disturbed core, or expensive additional drilling. With downhole geophysical methods we can economically take advantage of existing holes to obtain continuous values for density, defect orientation and ranking, elastic modulus values, unconfined compressive strength estimates and fracture frequency. This paper presents the results of a geophysical study and discusses the advantages and potential pitfalls of the method as compared to conventional methods of data collection.

Jan 1, 1999