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By J. N. Van der Merwe, M. Mathey

"The development and mechanical characterization of coal-crete, a composite material generated from coal fragments and some binder material, is described in this paper. Coal debris was obtained from a colliery in South Africa. The binder used in the study basically consists of cement and water, and further ingredients are added to the mixtures, such as sand, fly ash and polymers, in order to investigate alterations of the mechanical properties of coal-crete.Results from over 220 mechanical tests on coal-cretes with various binder mixtures give consistent trends for the material’s behaviour. Linear relationships are suggested between the uniaxial compressive strength, Young’s Modulus and the indirect tensile strength of the coal-crete.It is shown that mechanical properties comparable to coal can be achieved. Coal-crete is therefore suitable for physical modelling of mining situations in experimental studies and for use as backfill in underground coal mines. The latter application is particularly attractive when refuse coal is used as aggregate material. The indicated trends in this study may be used as a guideline for individual coal-crete design needs. However, some uncertainty remains as to the influence of particle shape, size and gradation, coal rank and age of the coal-crete. These aspects are recommended for further research."

Jan 1, 2015

By S. W. Marcuson, P. J. Mackey

The 1973 Oil Embargo and succeeding disruptions in supply had a profound effect on energy costs and consumption patterns in the developed world. This was especially true in the USA where post World War II growth, fueled by low-cost imported oil, left the country dependent on uninterrupted oil shipments from the volatile Middle East. In this atmosphere, Professor H.H. Kellogg of Columbia University, convinced of the necessity of good environmental stewardship by the writings of the era’s leading environmentalists, developed a methodology for evaluating energy and process efficiency of metallurgical processes and wrote a series of papers describing and applying the techniques. One of these, "Energy Use in Sulfide Smelting of Copper" is recognized as a seminal work which both described the state of energy usage in copper smelting in the mid-1970’s and portended future developments. The background to these papers is examined and the current and past Cu-Ni matte smelting practices in Canada are examined in the context of the results. Data from early 20th century publications describing reverberatory and blast furnace operation is employed to show that energy consumption for much of the century was several multiples higher than that calculated for best reverberatory operation in the 1970’s.

Jan 1, 2015

By S. Pastor, S. Hahn

"As the concept of autonomous haulage systems (AHS) moves from proto-types to production-ready applications, the operating performance of the haul road will become ‘mission critical’ to the overall success of autonomy in mining. Deterioration in road performance will require remediation, human intervention and significant, albeit temporary, changes to operating procedures, to accommodate road maintenance. With autonomous trucks comes the opportunity to reduce road formation and operating width, and therefore generating potentially significantly reductions in stripping ratios and improvements to mine economics, but only if the design of the road, and it’s associated deterioration rate, is predictable and manageable, based both on the materials used to construct the road and the maintenance interventions to be carried out on the road. This paper presents the assessment of a digital photogrammetric approach to the characterization of a mine haul road surfacing, or wearing course material. Design and maintenance parameters for these roads are currently determined from physical particle size distribution (PSD) assessments of ‘in-road’ material. However, this approach does not accommodate the need, nor leverage the benefits from, AHS. The digital imaging approach is assessed in this paper, using two standard digital analysis software tools, together with in-service mine haul road wearing course samples and images which are assessed to determine the applicability and reliability of the approach to deliver a real-time assessment of haul road surfacing conditions and thus to identify the road maintenance interventions required to address deterioration. INTRODUCTION Enhancements in mine road design, construction and management for the past 20 or more years has largely been focused on short-term tactical needs. These improvements have not been matched by advances in the fundamental technologies that underpin mine road design and management, and although the quality of mine roads have probably increased, many of fundamental and longer-term issues have yet to be addressed. With AHS’s evolving from prototype to production applications, any decision to implement these systems in a mine requires a thorough evaluation of impacts, not only operational improvements, but the inter-connectivity of this autonomy technology to other organizational processes. In developing an understanding, the full interactions that may affect autonomous truck behaviour due to changes in various sub-systems or external environments, haul road conditions and operating performance is a key consideration. This is as true in autonomous as well as in conventional mine truck-based hauling systems where the mine haul road network is a critical and vital component of the production process."

Jan 1, 2015

By H. X. Li, A. Correa, M. M. Zhang, W. Xuan, M. Andrade

"With increasing demand for steel and depletion of high-grade iron ore deposits, more research efforts are being directed toward extending the life of existing ore reserves and developing technology to treat low-grade iron ore resources. Among all the reported technologies, biotechnologies in mineral processing – specifically bioleaching and microbially induced flotation – have emerged to be considered as low-cost, environmentally friendly potential alternatives to many of the current mineral processing techniques. This paper provides a comprehensive review of current research on the use of microorganisms for iron ore beneficiation and, further, discusses the applicability of bioleaching, bioflotation and bioflocculation for the beneficiation of low-grade iron ores.IntroductionIncreasing global demand for raw materials has led to diminishing resources of high-grade iron ore. As a result, the mining and utilization of low-grade hematite, limonite, specularite, siderite and goethite ores have attracted more and more attention. However, these types of iron ores are of complex paragenesis and fine disseminated grain size, and often contaminated by phosphorus in the form of solid solution. The distribution of phosphorus throughout the iron mineral crystals prevents the effective use of physical separation techniques, and these complex ores are at present largely untapped due to a lack of cost-effective and efficient processing methods. Chemical leaching and roasting-magnetic separation approaches have been mainly tested only on the laboratory scale and are all either cost prohibitive or ineffective when used on low-grade complex iron ores."

Jan 1, 2015

By R. Xiong, A. K. Fallaw, G. Wang, L. R. Moore, S. Dobson, J. Gu

"INTRODUCTION The Central District of the Florida phosphate industry is located in southwest Polk and southeast Hillsborough Counties, with the Southern Extension lying in western Hardee, eastern Manatee and northwest De Soto Counties. (Lawver, 1983) Figure 1 shows the major phosphate formations in Florida. Almost all Florida phosphate production has been in the Central district with additional production from a mine in the Northern District. The Central District is comprised of the Bone Valley Deposit, a relatively thin layer of high grade ore which has been the main source of phosphate mining for decades, and the Hawthorn formation, a thick but low grade formation which covers most of peninsular Florida. (Lawver, 1983) Florida phosphate producers use the Crago process where calcium phosphate is floated with anionic, fatty acid type collectors followed by cationic reverse flotation of silica with amine type collectors. The phosphate matrix is put through various size separation techniques to obtain a typical -28 Mesh (< 700 µm) particle size for fine flotation and a -16 mesh (< 1190 µm) to +28 mesh (> 700 µm) particle size for coarse flotation. In some cases this coarse fraction can be sent to shipping as an intermediate product. The +16 mesh (>1190 µm) to – ¾“ (19 mm) fraction is sent to shipping as a final product called pebble. Figure 2 demonstrates a simplified diagram of the mining and processing of calcium phosphate (matrix) through a Central Florida mine. Particle size and mineralogy are important considerations in the Crago process for two main reasons, the mass of the particle and the particle surface area. Both of which are dependent on the coordination of the anionic collector to available Ca2+ sites on the minerals’ surface. The increased surface area, and available Ca2+, of the smaller apatite particles will allow for more fatty acid molecules to coordinate than the larger particles, with a lower availability of Ca2+. So, the larger particle would require more collector to be introduced in the system to sufficiently cover the apatite particles to produce a surface sufficiently hydrophobic to attach to air bubbles allowing flotation to occur. (Guan, 2009) The Bone Valley deposit has very favorable flotation characteristics when compared to other mining ores around the world. The matrix of the Bone Valley is relatively high grade, BPL (Bone Phosphate in Lime) values typically range from 6-18%, BPL recoveries, from such a matrix, can often be achieved above 85+% with fatty acid based collectors dosed below 1 #/ton. As mentioned, the sizing is an important step as there is also high grade apatite in the +16 mesh (1mm) that is screened to a final product grade, 60-65% BPL. The lack of quartz in the larger size fraction has allowed the Central District to produce high quality, low cost phosphate product, called pebble, through effective screening with no further beneficiation. (Guan, 2009)"

Jan 1, 2015

By Chandrasegaran, Tamilmani

"This paper describes a case study of a retaining wall structure using a diaphragm wall to construct a stilling basin at Tanjung Bin T4 power plant in Johor Bahru, Malaysia. The stilling basin is part of the Phase IV (T4) 1x1000MW power plant’s offshore cooling water discharge culverts. The site is located close to the sea with 5m of fill on top of very soft sediments of marine origin up to 20m thick underlain by fluvial clay and metasedimentary rock. Stringent wall deflection criteria and construction program dictated adopting an efficient solution with 800mm thick diaphragm wall supported by permanent top support as the temporary prop and improved horizontal restraint provided by deep mix piles acting as a slab (ground improvement layer) below the final excavation level. The depth of excavation is about 10.12m from the existing ground level. The proposed solution kept the wall deflection below the limit of 0.7% of the depth of bulk excavation and avoided additional props leading to faster completion of the structure. With unsymmetrical loading behind the retaining walls, 2D finite element analysis was carried out to assess the wall deflection and stresses in the wall and the grout layer below. The diaphragm wall is instrumented to monitor the behavior and the findings are discussed in the paper.INTRODUCTIONConstruction in soft marine clay has always been a challenge to the engineer because of its very low shear strength and its sensitivity to disturbance. In the case of excavation projects the problem becomes even more complicated with development of excess pore pressure during excavation. Marine clay with its low shear strength and lesser passive resistance, generally leads to large wall movements and settlement behind the wall. Increased passive resistance coming from increased number of props is useful but has its limits and it is no longer the most effective way in containing or reducing the wall movements or forces in the wall. One of the solutions to these problems is to improve the soil shear strength by means of ground improvement infront of the wall at an elevation most appropriate to maximize wall performance. There are several methods adopted in improving a soil layer including mixing additives to the ground to improve the shear strength to partially replacing the weak soil while others are fully replacing the weak soil. This paper discusses the case study of approximately 10m of excavation in soft marine clay using 800mm thick diaphragm wall supported by Deep Mix Piles (DMP) being used to improve soft marine deposit to form a slab just below the formation level and thus improving passive resistance significantly. The ground improvement layer helped to reduce the wall forces and deflections making it possible to remove the need for additional temporary props leading to significant savings is time and productivity. The paper presents the various options explored before this method is adopted, the design approach, instrumentation data and the monitored results."

Jan 1, 2015

By Rob Boom, Yasuyuki Tozaki, Frank M. Wheeler

Selection of a suitable site for a metallurgical plant is crucial for the success of the business case. For a brownfield project, with the decision to locate the project on a site with existing production facilities and activities, the selection of the site has been made. For a greenfield project, important economic and logistical considerations include proximity to primary and secondary resources and/or to the market, infrastructure, and access to energy and water. National and regional aspects, including the social license to operate, can be decisive in final site selection. Key to recruiting and retaining a labour force are proximity to urban areas, along with weather and health conditions at the site. Risk factors include site geotechnical parameters and topography, contamination, as well as probability and types of potential natural disasters.

Jan 1, 2015

By N. Saeidi

"For a mine section comprising 100 different stoping activities, there are ~10158 different possible stoping sequences to explore in the mine schedule optimization search and this figure is indicative of the challenge posed in maximising profitability through mine schedule optimization. Any viable excavation timetable must satisfy all conditions that will constrain feasible sequences. In general, consideration of additional constraint will tend to reduce profitability. Geomechanical constraints on mine schedules, introduced with the aim of avoiding excavation instabilities, can be established for underground mine schedule optimization processes but, currently, this is done only rather crudely; precedence relations between excavation activities (stoping or development) are encoded to produce particular stope sequence patterns (e.g. ‘chevron’ or pyramidal sequences).The work reported aimed to investigate automated processes for formulation of such geomechanical constraints. The timetable optimization approach to the problem precipitated a fresh look at time dependent, and excavation sequence dependent, deformation. Abundant evidence emerged that supported the notion that any methodology developed that failed to account for such time and sequence dependencies was itself bound to failure. Yet, it was also recognised that any deviation at all from an assumption of linear elasticity for geomechanical numerical modeling, adopted to inform geomechanical constraint formulation, would rapidly lead to impractical levels of computational effort.Thus the approach presented here represents a compromise: the elastic stress fields induced by individual mining activities are computed for each activity, independently considered within a computational domain identical to that of all other activities. These are stored in a database. Instability risk for a specific sequence of mine activities can be assessed through superimposition of stress fields drawn from the pre-computed database. Time stamps allocated to events corresponding to the excavation processes permit the conversion of the sequence of elastic stress fields into a time table of stress fields. For specific locations within the computational domain, the aggregate effect of the sequence of mine activities leads to stress-time histories having a castellated appearance, a result of the near instantaneous response of an elastic medium to the excavation perturbations. Time dependent deformation responses are crudely allowed for through the re-profiling these castellated histories through graphical construction of curved responses, where the curve gradients are related to a viscous parameter. Such curves form the basis for a geomechanical constraint formulation to be adopted for mine schedule optimization."

Jan 1, 2015

By P. Nos, L. Kolbeinsen, M. W. Kennedy, A. Filzwieser, R. T. Jones, A. MacRae

Modern furnace designs often incorporate extensive use of cooled elements to achieve long campaign lives at high operating intensities. However, contact between water and high temperature fluids can result in powerful Boiling Liquid Expanding Vapour Explosions (BLEVEs). Therefore cooling such elements with water carries inherent risks when used under slag and particularly below molten metal or matte. Alternative cooling media exist that can reduce or eliminate the risk of BLEVEs. These media are analysed and discussed in the context of deeply cooled furnace elements. Important factors in selecting alternative coolants are explored including: critical heat flux, thermal limits, toxicity, flammability, unit cost, etc. Key cooling system design criteria are reviewed in the context of both traditional and alternative coolants. Results of Computational Fluid Dynamics are presented for an example tap-block cooler design using a number of selected coolants. Research needs to advance the safe use of alternative coolants are presented.

Jan 1, 2015

By Iina Vaajamo, Jani Jansson, Lauri Pesonen

In pyrometallurgical operations, structural integrity of a high temperature furnace plays a crucial role in the overall safety, profitability and ecological footprint of the plant. Furnace integrity is related to how reliable a furnace is and it can be compromised, for example, by having poor operating and maintenance practices, an inefficient cooling system and flaws in the overall furnace design. These flaws and poor practices might lead to unexpected shutdowns, production losses, increased emissions, or worse. This paper presents the main factors to consider when engineering a furnace and developing its operating practices, while ensuring safe and reliable operations without compromising process efficiency and quality of the final products. In this respect, Outotec’s solutions for the cooling system and for automation systems like PROSCON, Process Advisor, Sentinel and our Smelting Information Management System, are also introduced.

Jan 1, 2015

By Chee Theng

"Mining professionals are a resilient lot. Sure, copper prices are dismal, permitting processes seem interminable and the top mining companies are shedding jobs like a Shetland sheepdog sheds hair. All the more reason to hone technical skills, reconnect with old contacts and get one’s finger on the pulse of the industry.More than 400 did just that in the balmy sunshine and among the saguaro cactus of the Tucson venue of the SME Arizona Conference.Giving the keynote speech was Patrick Merrin, vice president at Hudbay Minerals (see box), while the luncheon speaker was University Distinguished Professor Mary Poulton, director of the Lowell Institute for Mineral Resources at The University of Arizona.“Attendance was great, especially given the copper price,” said Ta Li, vice president of business development at Tetra Tech and 2001 SME President. “The luncheon speaker was one of the better ones in recent years. Her talk contained a lot of fresh ideas, and practical versus theoretical concepts.”Talk about values, not economicsPraise was unanimous for Poulton, who gave a thought-provoking talk on “The New Face of Mining: The Culture Change for Compatible Mining.” Corporate social responsibility has been embraced by the metals mining industry, and it’s being done right, she said. “So why do we have more conflict? Why are there more protests? Why does permitting take longer and longer?” Poulton made a case for an approach based on compatible, rather than sustainable, mining to present a new face of mining that can be compatible with communities, cultures and the environment, and still be profitable. When the mining industry starts to talk about compatibility between what it is doing and what “me,” as the consumer, wants, what “we,” as citizens of a community, want, and what’s good for the “world,” we’re going to see the next culture change happen, she concluded."

Jan 1, 2015

By S. K. Kawatra, J. A. Halt

"Low-grade iron ores are finely ground and processed to recover iron-bearing minerals. However, the iron-rich powder is too fine to be used directly in blast furnaces and most direct reduction furnaces, and must be agglomerated or pelletized into a usable product called “pellets.” Bentonite clay has traditionally been used as a binder to make iron ore concentrate pellets, but it is expensive and contaminates the pellets. Organic binders may be a viable alternative to bentonite clay. This manuscript reviews organic materials that have been used to make iron ore concentrate pellets. Included are discussions on the development of organic binders, common pros and cons to organic binder use, organic binder structure and its effects on agglomeration, and additives to organic binders.IntroductionIron ore agglomeration turns finely disseminated, low-grade iron ores into a usable product, called pellets. During pellet production, fine-grained, iron-rich minerals are liberated from low-grade ores, concentrated, and agglomerated into round balls that are thermally hardened or cold-bonded to form pellets. Pellets are then transported to blast furnaces or direct reduction operations where they are used to produce iron; iron is further refined and shaped into the wide variety of steel-based industrial and consumer products in use today.Over the years, pellet production has become increasingly more prevalent with the increased exploitation of low-grade iron ores and increased iron and steel consumption around the world. In 2010, world iron ore pellet production was 388 Mt. It could be argued that the current pellet production process has been enabled by the use of binders – practical experience has shown that it would be nearly impossible to agglomerate iron ore concentrates using rotary drums and discs without using a binder."

Jan 1, 2015

By H. Blaha, H. Wagner

"Room and pillar workings in salt mines are preferred sites for underground waste disposal. A critical issue in selecting waste disposal sites is long-term behaviour of such workings. The long-term behaviour of salt pillars is controlled by the pillar geometry, i.e. the height, width and length of pillars and the level of pillar stress. The latter has a strong influence on creep characteristics of salt pillars whereas the width to height ratio of salt pillars determines the strength of pillars and the deformation characteristics of salt pillars.Three different regimes of pillar creep behaviour of salt pillars can be distinguished, namely a stress level below which the rate of creep approaches a value of zero, a stress range where the rate of creep is constant and finally a stress level above which the rate of creep accelerates. Long-term stability of room and pillar workings can be assured only when the pillar stress level falls within the first stress regime. Strength and creep tests on model salt pillars have shown that at stress levels below 40% of pillar strength the rate of creep approaches a value of zero, between stress levels of 40% and 65% the rate of creep is constant but increases with stress level. Above pillar stress levels of 65% the rate of creep accelerates.Long-term measurements of pillar deformation and surface subsidence above relatively shallow room and pillar workings in salt mines have confirmed these observations. Long-term strength of salt was found that be between 60% and 65% of short term strength. The evaluation of salt pillar behaviour on the basis of critical pillar stress levels was found to be superior to the traditional factor of safety concept because it allows relating pillar deformation measurements to actual pillar conditions. The approach described in the paper was used successfully to evaluate the stability of room and pillar workings in a salt mine and to design strategies to stabilise critical pillar workings."

Jan 1, 2015

By M. A. Halim, V. I. Lakshmanan

Recycling is one of the key elements for sustainable process development for the recovery of value-added products and reducing environmental impact. Process Research ORTECH Inc. has developed several innovative and sustainable technologies, which minimizes the use of water, and chemicals for the recovery of gold, vanadium and gallium from secondary sources by maximizing the recycling of reagents, and reuse of water from process effluents.

Jan 1, 2015

By S. Pastor, S. Hahn

"As the concept of autonomous haulage systems (AHS) moves from prototypes to production-ready applications, the operating performance of the haul road will become critical to the overall success of autonomy in mining. Deterioration in road performance will require remediation, human intervention and significant, albeit temporary, changes to operating procedures, to accommodate road maintenance. With autonomous trucks comes the opportunity to reduce road formation and operating width. This will, therefore, generate potentially significant reductions in stripping ratios and improvements to mine economics, but only if the design of the road, and its associated deterioration rate, is predictable and manageable, based on the materials used to construct the road and the maintenance interventions to be carried out on the road.This article presents the assessment of a digital photogrammetric approach to the characterization of a mine haul road surfacing, or wearing course material. Design and maintenance parameters for these roads are currently determined partly from physical particle size distribution (PSD) assessments of ‘in-road’ material. However, this approach does not accommodate the need, nor leverage the benefits from, AHS. The digital imaging approach is assessed in this article, using two standard digital analysis software tools, together with in-service mine haul road wearing course samples and images that are analyzed to determine the applicability and reliability of the approach to deliver a real-time assessment of haul road surfacing conditions and thus to identify the road maintenance interventions required to address deterioration.Enhancements in mine road design, construction and management for the past 20 or more years has largely been focused on short-term tactical needs. These improvements have not been matched by advances in the fundamental technologies that underpin mine road design and management and, although the quality of mine roads have probably"

Jan 1, 2015

By Lei Zhang, Shining Chen, Lina Wang, Pu Liu, Benquan Fu, Jiannyang Hwang

A PFS(polymeric ferric sulfate) coagulation-photocatalytic oxidation technology was used for advanced treatment of coking wastewater from secondary biological treatment. Effects of some key factors on TOC removal rate were investigated, and the results were compared with those of the common photocatalytic oxidation technology under the operating parameters of the photocatalytic oxidation defined. Single factor experimental results showed that TOC removal rate could reach 81%, when optimal operating conditions were as follows: TiO2 loading: 4.0g/L, irradiation time: 4h, initial pH is 5.1and PFS dosage:700mg/L. PFS coagulation and photocatalytic oxidation have synergistic effect, which is meaningful for highly efficient treatment of coking wastewater

Jan 1, 2015

By Yuzhe Zhang, Xiaodi Huang, Xinli Wang, Bowen Li, Matthew Andriese, Jiann-Yang Hwang, Zhiwei Peng

The recycling of waste tires has been a big environmental problem. About 280 million waste tires are produced annually in the United States and more than 2 billion tires are stockpiled, which cause fire hazards and health issues. Tire rubbers are insoluble elastic high polymer materials. They are not biodegradable and may take hundreds of years to decompose in the natural environment. Microwave irradiation can be a thermal processing method for the decomposition of tire rubbers. In this study, the microwave absorption properties of waste tire at various temperatures are characterized to determine the conditions favorable for the microwave heating of waste tires.

Jan 1, 2015

By E. C. L. Cardoso

Hydrocarbon polymers, as PP, made from cheap petrochemical feedstock are important in many branches of industry. However, they have an undesirable influence on the environment and cause problems due to waste deposition and utilization. Polymeric materials composites account for an estimated from 20 to 30% of total volume of solid waste disposed. Thus, there is a tendency to substitute such polymers by those ones that undergo biodegradable processes. Polypropylene (PP) is a commodity, with high melting point, high chemical resistance, low density, with a balance between physical and mechanical properties and easy processing at low cost. Nevertheless, PP shows limitations for some special applications in automotive industry and civil construction. In order to minimize this deficiency, related to rheological behavior of polymer melt, especially referring to viscosity in processing temperature, a 50% mixture with HMSPP (High melt Strength Polypropylene) was used. PP/HMSPP was blended with 10, 15, 30 and 50% of natural (sugarcane bagasse) and synthetic polymers (PHB and PLA) aiming to partially biodegradable materials. The admixtures were subjected to gamma-irradiation at 50, 100, 150 and 200 kGy and then further assessed by mechanical tests in order to evaluate their degradability.

Jan 1, 2015

By Run-sheng xu, Hai-yang WANG, Di ZHAO, Teng-fei SONG, Jian-Liang Zhang

This paper was mainly focused on the different semi-cokes and charcoal which could be new fuels for blast furnace injection. Through the comparative study with bituminous coal and anthracite coal, the properties of semi-cokes and charcoal were presented in this research. 10 indexes of different fuels were obtained by different standard experiment, including proximate analysis, ultimate analysis, igniting point, explosivity, transportation characteristic, ash properties, grindability, calorific value, combustibility and reactivity with CO2. According to the data analysis, it provided a theoretical basis for rational utilization of various blast furnace fuels, and helped to broaden the scope of the blast furnace injection fuels. This research could contribute to energy conservation, emissions reduction, and sustainable development of iron and steel enterprises.

Jan 1, 2015

By Shadia J. Ikhmayies

CdSxTe1-x and CdS1-yTey solid solutions are usually formed in the interfacial region in the CdS/CdT thin film solar cells during the deposition of the CdTe layer and/or the processing steps of the device. It is well known that CdCl2 heat treatment encourages the formation of the CdSxTe1-x alloy which improves the solar cell performance. In this work, indium doped CdS1- yTey thin films are produced by first producing CdS:In thin films by the spray pyrolysis (SP) technique on glass substrates, then annealing the films in nitrogen atmosphere in the presence of elemental tellurium. The films are characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and transmittance measurements. The transmittance is used to deduce the optical parameters such as; the extinction coefficient, refractive index, besides to the real and imaginary parts of the dielectric constant. The dispersion parameters such as Eo (single-oscillator energy) and Ed (dispersive energy) of the deposited films are also estimated and discussed.

Jan 1, 2015