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By K. K. Kelley, L. B. Pankratz, W. W. Weller

Mullite is a substance of prime importance in ceramic technology . Despite this fact , its thermodynamic properties have received little attention . A Bureau of Mines literature survey disclosed the absence of lowtemperature heat capacity data , the absence of an experimental entropy value for 298.15 ° K , and the lack of heat content data beyond the temperature range from 298° to 576 ° K. Data supplied in this Bureau report fill these gaps in the thermodynamic knowledge of mullite . According to equilibrium phase studies of Aramaki and Roy ,3 the mullite phase melts congruently at 2,123 ± 15 ° K , and the equilibrium crystallinephase composition extends from Al Si2013 to Al6.8 Si₂ Q4.2 . The results in this report are for the stoichiometric composition , Al Si¿Qз . • Heat capacity measurements were made over the temperature range from 50 ° to 298 ° K , and the entropy at 298.15 ° K was evaluated . Heat content measurements covered the temperature range from 298 ° to 1,800 ° K. Heat content

Jan 1, 1963

By O. C. Blade

This report on the properties of burner-fuel oils produced during 1956 was issued under a cooperative agreement between the American Petroleum Institute and the Bureau of Mines, United States Department of the Interior, at the request of the Oil-Heat Institute of America and the petroleum industry. This survey is the second for this type of fuel, the first being made in 1955. 2/ The surveys are conducted to provide information on the characteristics of burner-fuel oils now manufactured for sale. They are similar in pattern to the diesel-fuel surveys, conducted since 1950, 3/ and are not intended to conflict with but rather to supplement them. The importance of fuel oil has resulted in the need for more information by the petroleum industry, manufacturers of heating appliances, and consumers regarding the types and qualities of the fuels currently being marketed. Samples of burner-fuel oil typical of their manufacture during the early part of 1956 were analyzed by the refiners in accordance with instructions from the subcommittee on fuel surveys of the Automotive Research Committee of the American Petroleum Institute, Results of the analyses were transmitted to the Bureau of Mines where the data were studied and compiled as shown in the tables of this report.

Jan 1, 1956

The Council of the Institution of Mining and Metallurgy submitted the report of the affairs of the Institution for the session 1970-71, and the Statement of Accounts for the year ended 31 December, 1970. The statistics given in the report refer to the calendar year 1970. Details are included of membership, officers, representation on other bodies, honours and distinctions, awards, meetings, publications, library, overseas activities, fellowships and grants, the revenue and expenditure account, the balance sheet, trust fund balances, contributing companies, and schedule of investments

Dec 1, 1971

By Roy McKinstry, Mark Rantapaa, Thomas Bolles

"More efficient drilling and blasting techniques have shown measurable improvements in throughput at the Barrick Goldstrike wet grinding mill.A decrease in throughput at the autoclave, due to increasingly hard ore, was identified in early 2002. A team of individuals from the Open Pit and Process areas participated closely on the Drill-to-Mill (D2M) Continuous Improvement initiative to ensure that it would address the needs of both groups, with the target of improving throughput in future years, despite the projected harder ores. Plant studies were conducted to determine if adjustments to drilling and blasting could positively influence throughput. At the Goldstrike mill the greatest opportunity from the D2M initiative is realized on the hardest ore. Grinding throughput for softer ore, <15 kWh/st, can meet or exceed the downstream pressure oxidation requirements. Grinding throughput for harder ore, >15 kWh/st, is limited by the SAG milling capacity. Better fragmentation in the D2M ore, as demonstrated by image analysis, increased throughput 5% to 10% (25 to 50 stph) compared to the standard mining methods.Better fragmentation and a subsequent increase in mill throughput were achieved through the use of:1) Electronic caps for more precision and flexibility, as well as for allowing extremely fast shots.2) Explosives with a higher velocity of detonation (VOD), to provide for improved shock energy.3) Improved distribution of the explosives by decreasing pattern spacing.INTRODUCTIONThe Barrick Goldstrike Open-Pit group, along with the Process division, began experimenting with novel blasting technology and techniques to improve mill throughput in the spring of 2001. A series of tests were developed to determine if fragmentation and ultimately mill throughput could be influenced by optimizing the drilling and blasting program in known"

Jan 1, 2004

By Les Gutzwiller

Fan applications in the mining industry have changed during the last 70 years. In 1922, J.R. Robinson authored a technical volume entitled Practical Mine Ventilation. At that time, atmospheric control had only recently shifted from natural to mechanical. The large, mechanical draft fans that were used then were centrifugal. The fans ran at low speeds, about300 rpm. Most were steam-engine driven. In the late 1920s and early 1930s, mines became larger, increasing the pressure and volume requirements of the fan equipment. Axial fans were designed to run at much higher speeds (710 to 880 rpm) and were driven by electric motors. They were also smaller and less expensive to install than the cumbersome centrifugal units. However, changes in mining have resulted in progressively higher static-pressure requirements. So centrifugal fans are once again proving to be a good choice.

Jan 1, 1999

At the present time this plant is treating by direct cyanidation 1,000 tons of ore from Open Cut mining and dumps, and 1,200 tons of current flotation tailing obtained from the Sulphide Mill, per day.The following table shows the average analysis of the two feed products (see Table 1):Precipitation Process.-The pregnant solution obtained by the cyanidation of the above has the following general analysis:-Gold 0&#183;600 dwt. per tonTotal Cyanide 0&#183;050 %Free Cyanide 0&#183;045 %Calcium Oxide 0&#183;015 %KCNS 0&#183;060 %Na2S20S 0&#183;140 %CaS04 0&#183;200 %Cu 0&#183;050 %Zn 0&#183;004 0/0K4Fe (CN) 6 NilThis solution, after standard clarification, is precipitated by means of zinc dust and a soluble lead salt.

Jan 1, 1939

This method determines tellurium at concentrations down to 0&#183;01 p.p.m., with geochemical accuracy. Tellurium is volatilized from the rock at 800&#176;C in the presence of sulphur from decomposing pyrite, condensed, dissolved, and finally determined by atomic absorption in a long tube burner. The distribution of Te is shown near some gold lodes at Kalgoorlie. Lastly, a method of synthesizing Te-free pyrite from sulphur and ferrous sulphate is described.

Jan 1, 1969

By Leah Penner, Thomas J. Ruth, Paul Schaffer, François Benard, Edouard Asselin, Stefan K. Zeisler, Thomas J. Morley

"This paper details the electrodeposition of metallic molybdenum from an aqueous, acetateelectrolyte containing molybdate ions. The deposition is carried out in a highly concentrated (up to I 0 M) acetate bath in the presence of a very low concentration of bone glue (60 µg/L). The molybdenum metal deposits are up to 20 µm thick and adherent. The deposits were characterized by XRD and XPS analysis. The deposition process is very inefficient, as up to 99% of the current is used to generate hydrogen during electrolysis. The effect of acetate concentration, pH, additives and current on the deposition efficiency and physical properties of the molybdenum deposit were investigated and optimized to obtain smooth, adherent coatings.IntroductionMolybdenum has increased thermal and wear resistance properties that are often utilized in material coatings [I]. These coatings are most often manufactured by sintering, pressing or spraying molybdenum powder at elevated temperatures, as a substitute method for standard metallurgical practices, such as electroplating [2, 3]. The lack of reports describing molybdenum deposition is most likely due to the highly oxophilic nature of molybdenum and the stability of its oxides, especially in water. Previous attempts to electrochemically reduce molybdenum from molybdate (Mool·) ions to molybdenum metal have reported the production of either a poorly adherent mixed oxide [4-6], or a thin(< 0.1 µm) metallic film [7-9]. Thick metallic molybdenum is capable of being co-deposited with one of the iron-group metals (Ni [10], Co [11] and Fe [12]) to produce an alloy [13, 14]. These alloys, however, may not be suitable for applications requiring pure molybdenum as they usually contain less than 50% molybdenum (often less than 30%)."

Jan 1, 2012

By Paykan Safe

?? Background ?? WorleyParsons Gas Cleaning ?? PT Inco Smelter ?? Process Design Considerations ?? Furnace Control and Combustion ?? Combustion Chamber ?? Spray Chamber ?? Draft Control ?? Baghouse ?? Secondary Ventilation ?? ID Fan ?? Dust Handling Equipment ?? Project Execution ?? Heat Recovery ?? Conclusion ?? WorleyParsons Gas Cleaning ? Irving, TX ?? Formerly Gas Cleaning Technologies ?? Acquired by WorleyParsons in 2005 and now part of a global EPCM company ?? 14 years experience in off-gas system design for ferrous and non-ferrous facilities worldwide

May 1, 2008

Alkaline leaching with sodium carbonate solution adjusted to pH 9&#183;5 to 10&#183;0 preferentially dissolves thorium from a mixture of rare earth and thorium hydroxides. Rare earth sodium carbonates form in the alkaline leaching stage.These are converted to rare earth oxides for use as optical and ophthalmic polishing agents. Quadrivalent cerium is extracted under similar alkaline leaching conditions.INTRODUCTIONAustralia has made significant contributions to mineral chemistry and mineral dressing. As often happens with an industrially immature country, research investigations often outstrip the ability or desire of commerce to exploit them. It is wrong to think exclusively in terms of export of raw materials. Imagination assists in developing world trends. The chemical utilization of mineral sands has interested a group of investigators, chiefly at the Commonwealth Scientific and Industrial Research Organization (C.S.I.R.O.) and, more recently, in the mining industry itself. From an international point of view the highlight of this work was Newnham&apos;s (1960) process for the separation of hafnium from zirconium. Earlier work at C.S.I.R.O. investigated the chlorination of rutile, zircon, and monazite. Assuming that titanium tetrachloride would be available in large quantities in the post war years, extensive work was done by Kraitzer, McTaggart, and Winter (1948) on organic compounds of titanium. This work led to the development of heat resistant paints, plastic compositions, and improved organic protective coatings that predated overseas work by up to seven years. (Post, Shiihara and Schwartz, 1961; Anon, 1955). Contributions were made to the production of refractory hard metals (Kraitzer, 1949; Kraitzer and Newnham, 1956). Pilkington and Wylie (1947) and Urie (1947) investigated the production of rare earths from monazite by an acid process.

Jan 1, 1963

By N. Zouridakis

Radon is an established lung carcinogen and remains the most important environmental radiation exposure. It was estimated that inhalation of radon and its short-lived decay products accounts on average for about one half of the effective dose equivalent from all natural sources of radiation. Radon contained in household water can transferred into room air as a result of agitation or heating. An indoor air concentration of 400 Bq/m3 is obtained if the radon concentration in household water is 4 kBq/L. A typical concentration of radon in ground water is about 1000 times lower than this concentration but sometime elevated concentrations of some kBq/L in ground water are reported. In this work a Liquid Scintillation counting system is used to obtain fast and accurate measurements of radon (222Rn) in water samples from Argolida, Greece.

Jan 1, 2007

By Paterson R. G, Compston W

The Mine granite at the Ardlethan tinfield is dated by Rb-Sr on a muscovite concentrate at not less than 417 &#177; 2.5 Ma (2s), consistent with the intrusion of this granitic body into folded Late Ordovician sediments. A combination of Rb-Sr and K-Ar evidence suggests a slightly younger age, 41O &#177; 2.5 Ma, both for the neighbouring Ardlethan Granite and for the hydrothermal alteration of the Mine granite, with which the tin is associated.On this basis, the somewhat high 206Pb/204Pb of two galena samples from within the hydrothermal alteration zone is best explained by an increase in U/Pb of order 10 per cent during a geochemical event in the Late Precambrian, in the rocks which eventually yielded the Pb to the mineralising fluid. This earlier event probably increased Th/U in these rocks as well, by as much as 5 per cent. If these reconstructions are valid, the lower-than-average U/Pb implied for the original Precambrian source rock bespeaks a mantle component of marginally greater proportion than for &quot;average orogene&quot;.

Jan 1, 1982

By A. Dogan Paktunc

Abstract - The Mechanic Settlement pluton is a small body of mafic and ultramafic rocks of tholeiitic affinity, occurring in the Late Neoproterozoic volcanosedimentary rocks of the Avalon terrane of the Appalachian Orogen. The lenticular-shaped intrusion is layered and consists of ultramafic and mafic lithologies in at least six cyclic units that are relatively thin or short-lived. The lowermost exposed portion of the intrusion is characterized by the cumulate sequences of olivine and olivineclinopyroxene and display relatively flat rare earth element profiles. In the overlying lithologies, plagioclase is the dominant cumulus phase following olivine in the crystallization sequence. Olivine ranges in composition from Fo73 to Fo85 and plagioclase from An62 to An89. Variations in the compositions of orthopyroxene and clinopyroxene are within Wo0-4En52-87Fs11-45 and Wo39-50En23-50Fs3-19. These mineral compositional variations in part reflect cryptic patterns and correspond to normal fractionation trends in cyclic units. Elevated Pt and Pd concentrations of up to 2.6 ppm occur in ten zones within the central cyclic series in association with both the peridotitic and gabbronoritic rock types. The mineralized zones are about several meters thick and appear to have lateral continuities over several hundred meters, suggesting that they are stratiform. Platinum-group elements (PGE) occur as discrete platinum-group minerals (PGM) including vysotskite, merenskyite, michenerite, sperrylite, stillwaterite, and hollingworthite that are associated with magmatic sulfides composed of pentlandite, pyrrhotite, and chalcopyrite. PGM grains range in size from a few micrometers to well above 20 µm. Sulfur isotope ratios and the Se/S ratios of the mineralized rocks are typically higher than the mantle values. Sulfide saturation probably occurred as a result of assimilation of crustal rocks and magma mixing during emplacement of subsequent pulses of magma. Repetition of the PGE mineralization in rather thin cyclic units suggests that the replenishing magma probably had high PGE levels and was saturated with respect to sulfide during emplacement. Ingression of the replenishing magma into the chamber in a turbulent plume and its mixing with the resident magma was probably responsible for the formation of the PGE mineralizations in the Mechanic Settlement pluton.

Jan 1, 2000

By Jean R. Garcia, Paulo J. R. Albuquerque, Renato P. Cunha, Osvaldo Freitas Neto

"Abstract Results obtained from in-situ load tests carried out on drilled displacement piles sunk in a porous, lateritic and unsaturated soil deposit, are analyzed in this paper. Three slow-maintained load tests were performed on deep instrumented piles with a diameter of 0.37 m and around 12 m long. The soil deposit consists of a superficial, silty clay “porous” layer 6 m thick, with an average standard penetration blow count (NSPT) of 4 and cone tip resistance and sleeve friction (qc and fs) of 1.5 MPa and 48 kPa, respectively. Under this layer there is a residual stratum 10 m thick, geotechnically consisting of a “porous” clayey silt with an average NSPT of 7 and qc and fs of 2.4 MPa and 202 kPa, respectively. The water table was reached at a depth of 17 m below ground level. The results of the field load tests yielded a maximum pile load (average for the tests) of 1428 kN, which is twice as high as corresponding experimental values from standard bored piles with similar geometric conditions. Exhumation of one of the tested piles was carried out after the test, in order to check integrity and shaft conditions. Numerical finite element analyses, using the commercially available French Code LCPC Cesar®, were performed in order to back-analyze the geotechnical soil parameters for a post execution pile condition. The results permitted a better understanding of the improvement of the subsoil given the intrinsic execution characteristics of this particular pile. It was also possible to note that drilled displacement piles have great potential to become an economically viable solution in tropical soils, given the enhanced behavior of such piles when compared to alternative (cheaper) techniques. In fact, it has several advantages which should make it a key foundation type in the Brazilian market in the future.IntroductionMost buildings in tropical soils use, as the main type of foundation, deep bored or auger type piles. These types of foundations can be performed in various ways, for example with or without soil extraction, with or without bentonite mud and so on. Two main processes maybe formulated: the first execution process is typified by bored pile types, continuous flight auger piles etc., which do not cause excessive soil displacement during excavation. With respect to the second process, one could mention, amongst others, driven piles (precast concrete or steel), Franki piles and drilled displacement piles, which do displace the soil during excavation by pushing the soil laterally around the hole in order to allow either the penetration of the pile or the excavator auger."

Jan 1, 2014

Silica reacts with cryolite at 1010&#176;C in two stages. The first stage is the formation of a sodium aluminosilicate of composition consistent with the mineral jadeite (Na20.AI20s.4Si02). The formation proceeds by atleast two different reactions. Formation of alumina or an aluminosilicate proceeds to its limiting value in the first 30 min while the formation of jadeite proceeds at a steady rate until quantitative conversion is achieved after 150 min. The net overall reaction can be expressed by the equation 6 Si02+2 Na3AlF6? (Na20.AI20s.4Si02) +2 SiF4 +4NaF.The second stage involves a slow reaction that proceeds with the evolution of a little SiF4, The net result is the formation of sodium aluminosilicates that are soluble in 30 per cent AlCIs-HCI solutions. While this could be explained by disproportionation of jadeite to form albite (Na20.Al203.6Si02) and nepheline (Na20. AI203.2Si02), it is more likely that it is due to further but limited reaction between the oxides and fiuoroaluminates.

Jan 1, 1972

[A Aamodt, H. C., A55 C Sales, Great Lakes Carbon Corp., 18 E. 48th St., New York, N.Y. Aamot, Olav Crone, M29 2126 M4, Galveston, Texas Aaronson, Hubert I., M47 E Prin Res Engr, Ford Motor Co., Met. Dept., Sci. Lab., Engrg. Staff, P. O. Box 2053, Dearborn, Mich. Aase, Glenn D., M54 D Prin Engr, Air Pollution Control Dist., 1480 Mission St., San Francisco 3, Calif. Abbett, W. A., Jr., M56 8629 Beverly St., Duluth 8, Minn. Abbey, Robert G., M56 138 Dartmouth Rd., Bala Cynwyd, Pa. Abbott, A. G., Jr., J52 E Test, Dev Engr, Chrysler Corp. Missile Div., P. O. Box 2628, Detroit 31, Mich. Abbott, Mark L., A58 Rep, General Refractories Co., 208 S. LaSalle St., Chicago, Ill. Abbott, W. K., J58 E Dev Met, Int&apos;l Nickel Co., Inc., 67 Wall St., New York 5, N.Y.]

Jan 1, 1961

By Charles A. Bankston, John C. Rowley, Robert J. Hanold, Joseph W. Neudecker

The basic concepts and processes of soil and rock melting as applied to excavation technology are reviewed. The electrically heated, small diameter prototype penetrator development sequence is presented. Emphasis is placed on the different methods of handling the fluid rock and soil melts and their significance in providing new solutions in hole support and debris handling problems. The refractory materials requirements, penetrator life and electrical heater technology are presented. Consolidating penetrators, which form stable glass-lined holes in low density rocks and soils, require no debris removal and will find applications in horizontal holes for utilities, cables, and pipeline installations. Extruding penetrators are being developed to make holes in dense, hard rocks. Melt is conditioned into a variety of debris forms, i.e., glass rods, pellets or rock wool, selected to match appropriate debris handling systems. Unique use in drilling into very hot rock or magma for geothermal exploration or production wells is projected. Some of the results of laboratory and field tests of these devices are compared with theoretically derived operating performance. Coring-consolidating penetrators for geological sampling in alluvium are projected to larger diameter self-propelled and guided coring devices for prospecting along proposed tunnel alignments. Application to the melting of annular shafts for pipeline support piles in difficult conditions such as permafrost has been scoped. Conceptual design studies of large diameter tunneling equipment have indicated the system contributions and economic aspects of rock melting relative to material comminution, wall and roof support and materials handling.

Jan 1, 1974

Coals from the Southern Coalfield of New South Wales treated in the Port Kembla coal preparation plants of Australian Iron and Steel Pty. Ltd. differ supstantially in their characteristics. Knpwledge of performance not only enables comparison and promotes better control, but also provides the means for predicting results.Evaluation of performance of cleaning equipment has been made in terms of probable error (Ep). Results for Baum jigs, a Chance cone, heavy medium cyclones, and water washing cyclones were examined. The efficiency factors derived from the probable error were applied to the float and sink analysis, mathematically simulating operating conditions. This method was applied to the Balgownie seam.The Balgownie seam lies between the Bulli and Wongawilli seams in the coal measures of the South Coast and mining on a large scale began recently in the Bulli area. It is known locally as the Four Foot seam and exhibits rather difficult washability characteristics, due to a comparatively high middlings content. These properties and the relatively high inherent ash make careful selection of cleaning equipment essential for optimum recovery. The prediction technique is used to determine the possible results when this coal is cleaned in the Port Kembla plants. Predicted values are compared with results from full scale trial washings demonstrating the validity and accuracy of the technique.Applications of result forecasting are listed.

Jan 1, 1971

By H. O. Hofman

(Canal Zone Meeting, November, 1910.) I. INTRODUCTION. IN a previous paper,1 The Behavior of Calcium Sulphate at Elevated Temperatures with Some Fluxes, we published the results of our investigation, into the behavior of calcium sul-phate in air; that, is, under oxidizing conditions. The results as a whole hold good for a neutral atmosphere, or one which has no chemical effect upon calcium sulphate. The present paper deals with the behavior of calcium sulphate under reducing conditions, the reducing-agents employed being carbon monoxide and carbon, and the changes the calcium sulphide formed undergoes when it is subjected to an oxidizing-roast. Technical literature deals very sparingly with the subject. The information furnished by the recent leading chemical manuals is general. Thus Dammer,2 Moissan,3 and Abbegg,4 quote Berthier as having reduced, in 1823, calcium sulphate with carbon, and Stammer as having done the same in 1851 with carbon monoxide; Gmelin Kraut 5 add Leplay and Laurent (1848) as third investigators. Metallurgical authorities confine their statements to the known fact of reduction by carbon. II. PREPARATION OF RAW MATERIALS. 1. Calcium Sulphate.-This salt was prepared in the same manner as described in our previous paper,6 and was found to be chemically pure. * Professor of Metallurgy, Massachusetts Institute of Technology. + Metallurgical Instructor, Imperial Technological Institute. 1 Trans, xxxix., 628 to 653 (1909). 2 Handbuch der anorganischen. Chemie, vol. ii., part 2, p. 309 (1894). 3 Traité de Chimic Minérale, 1904, vol. iii., p. 543. 4 Handbuch der anorganischen Chemie, vol. ii., part ii., p. 116 (1905). 5 Handbuch der anorganischen Chemie, vol. ii., part 2, p. 233 (1909). 6 Trans., xxxix., 630 (1909).

Nov 1, 1910

By H. F. Ramstad, F. D. Richardson

The equilibria (a) SiOz +Hz =SiO +H20 and (b) Si + SiO, = 2Si0 have beet1 studied at temperatures of 1425"to 1600°C ad 1310°to 1485°C respectively. The stattdard free energy changes for the tzrro reactions are given by the equatiotts Combination of the results for both equilibria leads to tiotz removes certain anomalies in existing high-terlzperature data for equilibria involving silica and silicon in iron. In many metallurgical processes and in many laboratory investigations silicon monoxide undoubtedly plays an important role. It is unfortunate therefore that wide differences exist between the results obtained by different investigators1-7 in their studies of such equilibria as In an attempt to put our knowledge of SiO on a surer basis, an exhaustive study has been made of equilibria [I] and [2] at temperatures ranging from 1300" to 1600°C. Reaction [I] was studied by measuring the amounts of silica which could be condensed from streams of Hz or Hz + HzO which had previously been brought into equilibrium with silica at temperatures ranging from 1425" to 1600°C. Reaction [2] was studied by measuring the material that could be condensed from streams of Hz or argon which had been brought into equilibrium with mixtures of silicon and silica at temperatures ranging from 1310" to 1485°C. EXPERIMENTAL Materials. The silicon was "superpure" grade and contained less than 0.1 pct impurities. The silica was prepared from pure mineral quartz; this was crushed and treated with concentrated hydrochloric acid to remove particles of iron, washed with water, and finally dried at 120°C. For the hydrogen + silica reaction, the silica was sized to —20+100 mesh. For the silicon + silica reaction, the two materials were ground to a fine powder in an agate mortar. The hydrogen and argon were commercial oxygen-free gases. The gas streams were controlled with capillary flow meters and the volumes were measured by wet gas meters. After passing through the meters, the gases were partially dried by silica gel. The hydrogen for the HZ + SiOz reaction was then passed through palladised asbestos at 300°C and dried with magnesium perchlorate. The efficiency of oxygen removal was checked throughout the experiments by passing the gas over an electrically heated strip of nichrome, used as an indicator as described by Rathman and de itt.&apos; When mixtures of HZ + Hz0 were required, the partial pressures of water vapor (1.8 to 22 mm) were obtained by passing the hydrogen through oxalic acid dihydrateg&apos; lo held at various controlled temperatures, O.l°C, by means of a water bath. The hydrogen for the Si + Si02 reaction was purified by passing it over a mixture of 3 parts of magnesium to 5 of lime heated to 600°."l1 u The argon for this reaction was passed through titanium powder (-3/16 in. + 100 mesh) heated to 900°C. The nitrogen used to prevent the reaction products escaping from the condenser (see later), was deoxidized by copper or iron at 600°C. All these gases were finally dried with magnesium perchlorate. Furnace, Temperature Contr01, and Measurement A molybdenum resistance furnace was used for both sets of experiments. The reactions were conducted inside a high-grade alumina tube, 36 in. long and 1 in. in diam as indicated in Fig. 1. With this arrangement an even temperature zone (2"C) 4 cm long was satisfactorily obtained. The temperatures were kept constant by means of a proportional controller actuated by a Pt-Pt 13 pct Rh thermocouple. This was placed between the two alumina tubes, so that the temperature at the junction was 1400" to 1450°C. Up to 1485"C, the temperatures were measured with Pt-Pt 13 pct Rh thermocouples. For higher temperatures an optical pyrometer was used, this being sighted (through the glass window 1 in Fig. 1) on the end of the alumina tube, that held the SiOz or Si +SiOz mixture, 10 in Fig. 1. The optical pyrometer was recalibrated whenever a change was made in any part of the apparatus situated in the hot zone. Successive readings with the optical pyrometer were reproducible to within 1"C. Equilibrium Apparatus and Procedure. Hydvogen and Silica Reaction. The apparatus is shown in Fig.

Jan 1, 1962