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By C. Nexhip, S. Sun

Critical to understanding and controlling phase mixing and separation in metallurgical processes, is the development of reliable experimental techniques to measure interfacial properties of melt systems. A series of experiments has been carried out to determine the effect of oxygen potential on the surface tension of liquid copper. Using an electromagnetic levitation method, a surface tension-oxygen chemical potential adsorption isotherm was produced for the Cu-O system at T 1400 K. The surface tension results show good agreement with the literature values e.g. within 3 per cent for pure copper. The Belton `ideal' adsorption isotherm was applied, and the following equation derived to best fit the experimental data ? =1251-77.5 1n41+ (2.79x105 . pO1/2)](mN.m Using this equation, the surface tension of copper was calculated/predicted as a function of oxygen potential at 1400 K, and showed excellent agreement with the experimental values. This confirmed that the adsorption behaviour of oxygen in liquid copper is ideal. The saturation coverage of oxygen on the surface of liquid copper was determined to be T0 = 6.65 µmoles.m,-2 corresponding to an area per adsorbed oxygen atom of ao ? 25 Å2. These values agree well with those cited in the literature, and our experimental data cover a very wide range of oxygen potential (10-5 to 10-17 atm). Keywords: levitation melting, surface tension, Cu-O alloys, oxygen potential, adsorption isotherm, surface coverage.

Jan 1, 2004

By Vinay Kumar

The disposal of large quantities of electronic scraps generated world wide is causing not only environmental problem but also loss of resources. Therefore, R & D efforts have been made to develop a suitable process for extraction and separation of metals viz. copper, zinc, cadmium and nickel expected from the leaching of e-scraps using solvent extraction process. Different process parameters viz. pH, aqueous to organic ratio, kinetics of extraction, extraction isotherm to establish stage requirement for extraction in continuous mode etc have been studied to optimise the condition for the separation of metals. The studies showed the selective extraction of copper after iron precipitation from the sulfuric acid leach solution of e- wastes containing ~1.0 g/L Cu and minor impurities with 2-hydroxy-5- nonylacetophenoneoxime (LIX 84) above pH 2.0 in single stage. A scheme for separation of cadmium, zinc and nickel has been proposed using di(2-ethylhexyl) phosphoric acid (D2EHPA) under controlled pH of the aqueous solution. The order of extraction was found to be Zn> Cd> Ni.

Jan 1, 2009

By Francis Kendorski

The Skyline #3 Mine of Canyon Fuel Company in Utah was planning longwall mine development adjacent to and downdip of older mine workings known to be flooded. Barrier pillar geometries and widths were proposed by mining company personnel. Hydraulic conductivity testing suggested that the general characteristics of the local coal seam, dikes, and faults are only weakly conductive and that leakage through the barriers, if any, would be minor. The mechanical performance of the proposed barrier pillar design was evaluated according to (1) published empirical design methods and (2) numerical stress modeling. Comparison of the proposed design, with the range of barrier widths derived from the empirical methods, served as a first-order check on the adequacy of the proposed design. Numerical modeling was used to evaluate conditions site-specific to the Skyline #3 Mine and barrier geometry. Models were developed to quantify the relationship between barrier width and the abutment stresses onto the future workings. The models were also used to estimate the stress distribution within the barrier pillars. The hydraulic performance of the proposed barrier pillar design was evaluated according to (1) published empirical design methods for hydraulic impoundments, (2) empirical method estimates of seepage through coal barrier pillars, (3) numerical hydrogeologic flow modeling, and (4) numerical strain modeling. Using the techniques described above, and based on relevant industry experience, underground observations, knowledge of local geologic conditions, hydrogeologic measurements, and analytical results, the level of geomechanical risk associated with the barrier design as proposed was considered low and the level of hydraulic risk was considered moderate. The largest uncertainty that remained was the possibility that unfavorable geologic structures, such as faults and dikes, would act as conduits for leakage of impounded water into the new workings. Although the study indicated only minor steady-state leakage would occur through a small number of known structures, the presence and full leakage potential of threatening structures in the barrier could not be reliably known until the barrier was mined. One longwall panel has been completed adjacent to the barrier with no evidence of water flow even in fractured zones. Thus, as predicted by the modeling and analysis, it appears that abutment stresses imparted on the barrier during mining did not substantially alter the natural hydrogeologic characteristics, or leakage potential, of the barrier. The longwall coal mine water-barrier pillar design and performance are considered a success.

Jan 1, 2007

By Fred V. Carrillo

Of the total quantity of secondary copper and zinc that became obsolete in the United States from 19b1 through 1970, more than 11 million tons of copper and 10 million tons of zinc were not recovered. These estimates are based on a study of the flow and recovery of old copper and zinc scrap by consumption end-use. This report describes (1) where copper and zinc are being used; (2) when they become obsolete and available as secondary metal; (3) how they are being collected for recycling; and (4) how much might be recovered from scrap that presently is not being recycled.

Jan 1, 1974

By D. T. Bergado

The uppermost subsoil profiles of the Bangkok plain can be divided into four layers, namely: weathered clay, soft clay, stiff clay, and dense sand layers. The soft Bangkok clay is a normally consolidated marine clay with built-up preconsolidation effects and overlain by a weathered crust. Up to the present, a large number of full-scale tests on excavations and pile foundations has been made by numerous investigators. Based on these results, the available data are reviewed and evaluated. The results show that for test excavations, the excess pore pressures were overpredicted by the existing theories. The vertical and lateral movements in the excavations can be predicted by the bilinear and non-linear finite elements using appropriate modulus values. Relationships among probability of failure, safety factor, and safety margin of the excavation were also obtained. In the case of pile foundations, good agreement between the measured and predicted ultimate pile capacities were obtained for long piles. The adhesion factors ranged from 0.4 to 1.0 while the average skin friction factor was found to be 0.33. The ultimate capacity of the pile was also predicted successfully by using the Dutch cone data. For lateral deflection of piles, Davisson and Gill's theory predicted well in the low deflection zone while Poulos' theory agreed well in the high deflection zone. From the probabilistic analysis of ultimate pile capacity, the probability of failure was related to the central factor of safety. The piles usually used in Bangkok area are mainly precast concrete piles

Jan 1, 2010

By Shahram Tafazoli

This article presents a novel technology for sensing the size of rocks after blasting in hard rock mines. Blast engineers require rock size statistics to carefully adjust the blasting parameters. The rock fragmentation requirements vary depending on the ore type and crusher specifications. The most popular statistical parameters in the industry are the so-called P numbers (e.g., P80 and P100). A machine vision based system is introduced here for automatic image collection and fragmentation analysis of the material right inside the bucket or dipper of mining shovels. A heavy-duty camera provides the required imaging data to an embedded computer mounted inside the cab. A custom machine vision software continuously analyzes the captured bucket images and stores the suitable ones in local storage which are then fed to a Desktop software for automatic fragmentation analysis. This technology has been developed by Motion Metrics International and is commercially available as FragMetrics?.

May 1, 2009

By P. A. Neill, O&apos

The caisson foundation for Vent Building No. 6, at the southern landfall of Boston's Third Harbor Tunnel, was installed inside an unbraced concrete cofferdam 250 feet in diameter and about 70 feet deep. As a spectacular engineering feat, the cofferdam itself certainly ranks first. However, the foundation work within was no routine caisson job and made its own contribution to the state of the art. Comprised of 5 ft. diameter caissons socketed 10 to 16 feet in sound rock, it posed serious challenges in logistics, space limitations and time, requiring development of unique, purpose-made equipment. The unexpected discovery of significant depths of shattered rock overlying acceptable sound rock, along with other surprises of lesser import, compounded the problems. How these challenges were planned for, met and overcome is the subject of this paper.

Jan 1, 1994

Assuming that a gold ore has been effectively ground to ensure maximum economic liberation of gold, the circuits that will have the most effect on the successful operation of a gold plant will be that of the leaching and carbon-in-pulp circuit (CIP). The reagent and utilities operating costs associated with leaching, adsorption, elution and regeneration would typically make up some 15% of total operating cost, whilst the capital costs associated with these areas is about 16% of the total. Although not largest (capital and operating costs associated with comminution are generally dominant) these items represent a significant proportion of capital and operating cost. Much more importantly, these plant areas represent the primary gold recovery process and their technical and operational efficiencies will have a significant impact on overall plant efficiency. The objective during process design of these sections is thus to develop a design which provides maximum technical and economic efficiency and which is robust to potential changes in ore throughput, mineralogical characteristics and head-grade. Experience has shown that, particularly for longer life and higher-grade projects typical of the South African underground gold mining industry, small changes in recovery and efficiency have a significant value over the life of the project.

Jan 1, 1999

By Quentin Rhoton

To benefit two endangered fish species, waterfowl and other wildlife, and water quality in the lake and downstream, the decision was made to remove levees that had been in place since the 1950s. Because the levee material was mainly dredged up lake bottom peat, it was decided to pare down the sites chosen for breaching with dozers and trackhoes. This material was spread out onsite instead of expensive removal by dumping elsewhere. Because of the instability of the final pared down levees and the lake level being at a ten-year low, it was decided to use explosives to breach four of the sites. After over five months of earthmoving and two weeks of loading holes, the levees were detonated the day before Halloween, 2007. Somehow pumpkins showed up to be part of the explosive activities.

Jan 1, 2009

By Franz Kolmbauer

At Primetals Technologies Brazil Ltda. Rio de Janeiro Santa Cruz Workshop we electroplate mold coppers for continuous casting by tank plating. Tank plating submerges the copper in the bath of the plating solution. This is the most common method of plating and is applicable for both broadface and narrowface copper plates. Mold copper plates have a decisive impact on the product quality as well as the cost for maintenance and production. A perfect understanding of the operational influences on the plates and performance variables are the first step for the right selection of a copper plating method. Variable Hiper Coat keeps the Copper Plates 50% up to 100% longer in operation because of applying hardness on the Copper Plate where it is needed. Primetals Technologies Brazil provides the solution which meets and exceeds the requirements for todays and future demands.

Aug 16, 2017

By M. C. Ruiz, M. E. Godoy, J. B. Rivarola, M. W. Ojeda

The amount of Pd recovered from an exhausted olefin hydrogenation catalyst was found to depend on mixing technique, particle size, carbon percentage, chlorine flow, reaction time and temperature. Pd extraction was total when a sample in the 125-175 micrometre particle size range was chlorinated for 60 min at 723 K with 20 cm3 Cl2/min, for 60 min at 748 K with 30 cm3 Cl2/min and for 30 min at 773 K with 30 cm3 Cl2/min. No C addition was needed; the initial C content of the catalyst was sufficient for total recovery. Pd extraction was also affected by heat treatment in different atmospheres before chlorination. Treatment with O2, N2 and N2 with traces of O2 led to different degrees of oxidation of C and permitted the formation of oxidised Pd species. Thermal pretreatment in N2 with traces of O2 was most conducive to Pd extraction

Jun 21, 1905

By Larry H. Heflin

The Washington Metropolitan Area Transit Authority's Wheaton Station and tunnel design was completed and offered for bid in the Spring of 1983. The format was unique to the Authority: a four part, four fiscal year contract developed in response to funding limitations with construction divided into four stages allowing the maximum amount of work to be done each year for the funds available. The bid was based on the entire contract, but was orginally awarded for only the first year's work. Each year's work had a maximum funding limitation thus safe guarding the Authority from a grossly unbalanced bid. The Authority's estimate for this work was $83,871,524. The low bid came in at 61% of this for a total low bid of $51,512,058. The low bidder was ILBAU America Corporation whose home offices are in Austria. Following receipt of the bids (and resolution of objections cited by other bidders who felt that the job could not be done for the $51 Million dollar figure), a Notice-To-Proceed was given on October 5, 1983. The construction contract allows a Value Engineering Change Proposal, called a VECP which is initiated and developed by the contractor to change the drawings, specifications or other requirements of the contract. Among other things the VECP should decrease the contract price while maintaining the service life, reliability, ease of maintenance, and standardized features and appearance and not require an unacceptable extension of the contract time. A VECP must estimate the amount of the net savings

Jan 1, 1985

By D. R. Hack

Increased consumption of concrete in the Pacific Northwest has pushed aggregate resource development pressure from urban areas west of the Cascade Range to rural areas east of the Cascades. Some recent development has focused on barge and rail accessible off-reservation Indian allotments that are exempt from state and county regulations. These lands have their own unique set of challenges, especially when Federal and Tribal governments have conflicting goals and attitudes pertaining to resource development. This paper discusses issues of leasing, reclamation, Federal vs. Tribal authority, cultural resources, and the history of allotment.

Jan 1, 2002

A New Technology of Applying SLon-2500 Magnetic Separator to Recover Iron Concentrate from Abandoned Tails

Sep 13, 2010

By . Jaime G Tapia Aguirre

La Unidad Minera Rosaura del Grupo Glencore fue considerada la mina subterránea más segura del país durante los años 2005, 2006 y 2007. Sin embargo, cuando el Grupo Glencore adquirió la concesión de Rosaura, el panorama minero era de una mina marginal, de bajas leyes. Por esta razón, el único metodo a ejecutar para hacer de Rosaura una mina rentable era el de utilizar un método masivo. Em ese semtido, el presente texto señala la operación de mina cone el análisis y conocimiento de causa raíz en la prevención de caída de roca.

Sep 12, 2011

By D Gelling

Mineral sands dry plants consist of a large number of repetitive unit operations with significant transport delays, in the form of stream pipes, conveyors and elevators. As part of the P255 mineral sands sponsorship and using the JKMRC developed conductor/non-conductor (CNC) gauges, control loops have been implemented at the multi-duty dry plant of Cable Sands Limited at Bunbury. This paper describes the loops for kV control on a rougher high tension roll machines (HTR). The options available are product grade control and ratio control using the JKMRC CNC gauges, which measure the percent conductors in a stream. The purpose of control is to stabilise the circuit operation against disturbances such as atmospheric and feed disturbances.

Jan 1, 2001

Pillars in underground limestone mines are required to support the overburden and provide a safe, stable working environment for mining personnel and equipment. Pillar stability was assessed by the National Institute for Occupational Safety and Health in underground limestone mines in the Eastern and Midwestern United States. It was found that current mine layouts have been successful in providing support to the overburden, while a small number of isolated pillar failures were observed. The stable pillar layouts and failed pillars were plotted on a chart that demonstrates the relationship between pillar width-to-height ratio and pillar stress. The results show that pillar failures occurred at the lower range of width-to-height ratios and can occur at relatively low stress levels. Zones indicating the potential risk of pillar instability are shown on the chart, based on hazards associated with the onset of rib spalling, large angular discontinuities and unconfined pillars. The chart can assist limestone mine planners to evaluate potential instability in current or new pillar layouts that are similar to those included on the stability chart.

Jan 1, 2008

The Elura Orebody consists of a number of parallel, vertically oriented pipe-like structures of pyrite-sphalerite-galena mineralization located at the core of a structural dome. Concentric zoning of the mineralization into an outer Siliceous, intermediate Pyritic and inner Pyrrhotitic Zone has been previously recognized and is used in routine geologic modelling of the lead, zinc and silver grades.Statistical analysis of the metal grade distribution in the orebody has confirmed the importance of the mineralogical zones in the understanding of grade trends. The gradational nature of intra-zone boundaries, especially those related to the subjective definition of the Siliceous Zone, are apparent in the statistics.

Jan 1, 1990

By J. D. Bliss

The discovery that triggered the current gold rush in southeastern Peru was made in about 1975 along the Rio Madre de Dios in Madre de Dios Department (Fig. 1). About 5000 to 10,000 miners (called chichiqueros) were working in the area as of 1990. Placer mining is the principal source of revenue for people living along the Rio Inambari and west of Puerto Maldonado. As in past gold rushes, working and living condition are harsh. Supplies are expensive, and the area has poor access compared with other areas in Peru. Food, fuel and all mining supplies are trucked over dirt roads from Cuzco, a three-to-five-day trip (Fig. 1). Some material also comes from Brazil. Many placers have a similar life cycle, beginning with small-volume mining (surface or underground). At the end of this small-scale mining, the placer is exhausted or it has a sufficient volume of gravel high enough in gold grade to be worked by large-volume methods, which lead to exhaustion of the resource. The level of maturity of a placer can be determined from its gold grade. The amount of gold production from large-volume mining can be predicted, given detailed, cumulative gold-production data on placer deposits during small-scale mining (Bliss et al., 1987). Using this general model, the authors analyzed the placers in the Rio Madre de Dios area. Small-volume mining Most placer mining in the Rio Madre de Dios area is in alluvial deposits either in or bordering the major rivers. Locally, some placer mining is in terrace deposits above the rivers. All minerals (including the subsoil) in Peru belong to the state. However, a mining claim (denuncia) is easily obtained for mineral exploitation. It is separate from property ownership.

Jan 1, 1992

Study on the Mineral Processing Technology of Low-Grade Refractory Lead-Zinc Oxide Ores Containing Argillaceous and Carbonated Gangue in Yunnan

Sep 13, 2010