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By Barry D. Lichter, Pierre Sommelet

High-temperature heat contents of InAs and GaAs were measured over the temperature range 400°K to temperatures above the melting points using a di-phenyl ether drop calorimeter. Smoothed values of the thermal properties have been derived and tabulated at even temperature interuals . The heats of fusion of InAs and GaAs were determined as, respectively, 8790 ± 200 and 12,590 ± 300 cal per g-atom at the respective melting points of 1210º ± and 1513º ± 1°K, yielding entropies of fusion of 7.26 * 0.16 and 8.32 ± 0.20 cal perºK per g-atom, respectively. A general discussion of the thermal properties of III-V com-pounds is given. THE low-temperature heat capacities of InAs and GaAs have been determined by Piesbergen.1Using a dynamic temperature modulation technique, Miller2 has determined the heat capacities of the compounds as well as GaSb and Ge between room temperature and 650°K; however, it has been observed that values determined by drop calorimetry for GaSb3 and for germanium4 are consistently about 5 pct lower than Miller's results. Cox and Pool10 report values for the heat content of InAs and GaAs and the heat of fusion of InAs. No value for the heat of fusion of GaAs appears to have been previously reported. This paper reports results of high-temperature heat content investigations of InAs and GaAs measured in the range 400" to above 1500°K employing a diphenyl ether drop calorimeter. These results, together with our previous results on III-Sb compounds3 as well as heat-content measurements5 of solid InP and Gap, are used in a general discussion of these compounds. EXPERIMENTAL PROCEDURES High-purity samples of the compounds, stoichio-metric to ±0.1 at. pct, were supplied in the form of crushed crystal fragments by Dr. Carl Thurmond of the Bell Telephone Laboratories. The sample preparation, description of the calorimeter, and details of the heat content measurement have been previously described.3 Samples were sealed in evacuated silica capsules and suspended by a Pt-Rh wire in a Pt-wound vertical tube furnace, heated to temperature

Jan 1, 1970

T. S. FULLER, Chairman C. H. MATHEWSON, Past-chairman W. A. SCHEUCH, Vice-chairman J. L. CHRISTIE, Vice-chairman E. M. WISE, Secretary International Nickel Co., Bayonne, N. J. W. M. CORSE, Treasurer Executive Committee H. A. BEDWORTH W. M. PEIRCE D. K. CRAMPTON A. J. PHILLIPS E. H. Dix JR. GUY C. RIDDELL R. F. MEHL J. WALTER SCOTT JEROME STRAUSS Finance Committee C. H. MATHEWSON, Chairman W. M. CORSE H. S. RAWDON ZAY JEFFRIES SAM TOUR Data Sheet Committee R. S. ARCHER Chairman N. B. PILLING Vice-chairman L. W. KEMPF JEROME STRAUSS A. J. PHILLIPS F. L. WOLF'

Jan 1, 1932

By John B. Umhau

[This !m-i~!.al survey giver, statistice.1 data res;?~dirf ~:rimay ard ?eco~- dqr or scmn tin used in thL: United St,ztas by industries an? incluclcz d;ta on stop&apos;ics, ~urchares, ard plnrt losr.c.5. It is :i ml:anwe of consq~tion in terms of fir.is1icd -prcd.~cts nz6.e iry initid ti11 Sabric:,.torc,, that is, aon- cerns that purchzse virc,in zni s~col~d&apos;l~y i.i.5 ti:; 01&apos; tin c;cra.. rav materi,als ar,d co:lrrert them into !ror?ucts such F!: ti:i plz.te, ~lloyr;, and. c?hemic?ls; comy~nias ;~urchn.&apos;.ii~; alloys, ch:rr.ic,~l::, or tin vl?.tc fcr furthcr a:mflzc- ture ?rc: ~-.f>t i~ci~~dcd. Tilit r~lqe:;tionrr::ire submit tod to consunern ar,nt:incd no dofinition of rnr.oncl.:ryr me$.-i; but, ovrirq to ti~i-: a~counti~ procedure used s.l~o~c-:t 1&apos; thu scrnn hac i~-.rtergol:e ch?rri?~ of ovinerzhip or titlo, thc rc!coverod t! n !its b~en i-c<;,r(it.!rj L.S r,e~3r;d:q met.1. Tbv tin content ~f ]

Jan 1, 1938

By I. R. Hanby

A simple solution to the problem of whether to round the calculated number of trucks up or down to the nearest whole number is to adopt as criterion the minimum cost per unit volume/mass moved, assuming all trucks in the fleet are of the same type. When the effects on journey time of varying haul-road slope are calculated for several rolling resistances, it is shown that the optimum angle of 7.5 degrees is moderately independent of both rolling resistance and height climbed; the lower the resistance, the lower the sensitivity to ramp angle, but if haul-road gradients do not exceed 1 in 10 (5.7 degrees) for safety reasons then travelling time will never be more than 7% greater than its theoretical minimum. Further calculations result in a graph of the maximum payload values to incur the minimum cost, for different values of total effective resistance

Jan 1, 1991

L50 Adirondack L1 Alaska L2 Arizona L58 Arkansas L66 Billings Petroleum L3 Black Hills L4 Boston L5 Carlsbad Potash L6 Central Appalachian L60 Central New Mexico L7 Chicago L8 Cleveland L9 Colorado L57 Colorado Plateau L10 Columbia LII Connecticut L55 Dallas L12 Delta L65 Denver Petroleum L13 Detroit L14 East Texas L15 El Paso Metals L71 Evangeline L45 Florida L54 Fort Worth L16 Gulf Coast L61 Hobbs L62 Hugoton L68 Illinois Pet Basin L17 Kansas L18 Lehigh Valley L52 Lou-Ark L47 Mexico L19 Mid-Continent L20 Minnesota L56 Mississippi L21 Montana L22 Nevada L64 Niagara Frontier L23 New York L67 New York Petroleum L25 North Pacific L24 North Texas L26 Ohio Valley L27 Oklahoma City L28 Oregon L63 Panhandle L29 Penn -Anthracite L30 Permian Basin L51 Peru L31 Philadelphia L32 Pittsburgh L33 St Louis L34 San Francisco L59 San Joaquin L35 Southeast L36 Southern Calif L69 Southern Calif Pet L53 South Plains L37 Southwest Texas L48 Southwest Alaska L38 Southwest N Mex L44 Spindletop L39 Tri-State L40 Upper Peninsula L41 Utah L70 Venezuela L42 Washington, D C L43 Wyoming L49 West Central Texas L46 Philippine

Jan 1, 1956

By G. L. Smith

This paper introduces and defines the concept of a linkage between long-term planning parameters (?global assumptions?) and possible future world views as conceived in scenario planning. Scenario planning, the tool that is used to arrive at plausible future worldviews, is described in the context of the platinum industry. The interpretation of the scenarios into long-term planning parameters is made, followed by an illustration of how the long-term planning process has been adapted at Anglo Platinum to include the notion of uncertainty.

Jan 1, 2008

1. Journals Marine Geotechnology, edited by R.C. Chaney. London, Taylor & Francis (Rankine Road, Basingstoke, Hants RG 24 OPR, OK), 1988. vol. 8, $50. Published quarterly. Mineral Resources Engineering, edited by C.T. Shaw. London, Taylor & Francis (address as above), 1988. vol. 1, $99. Published quarterly. 2. New publication World mining map of non-ferous metals (with 4 regional maps and a booklet). Reinhard Ryborsch (Postfach 2105, D-6053 Obertshausen bei Frankfurt am Main, West Germany). International edition: bilingual, English and German. 7 colour-print: Size (unfolded) 138 X 100 cm. US$ 19 (excl. mailing) for folded map with hard cover (Order No. 61-4); US$ 25 (excl. mailing) for unfolded (flat) map with hanging strip (Order No. 62-2). 3. Mintek reports Report M326 Crevice corosion and other localized corosion behaviour of 3CR12 corosion-resisting steel in synthetic minewaters, by D. Howarth. May 1988. 28 pp.Report M332 The carbon-regeneration furnaces at Mintek, by P.M. Cole and P.J. van Staden. Nov. 1987. 31 pp. Report M344 The flotation of pyrite with amine colectors, by R.D. Hil, E.W. Giesekke, and P.J. Haris. Mar.&apos;1988. 25 pp.Report M345 The substitution for chromium in steels: Progress and trends, by M.B. Cortie. Mar. 1988. 14 pp.Report M346 The direct reduction of sulphur dioxide to elementalsulphur, by I. Henderson. Mar. 1988. 30 pp.Report M349 The optimization of a process using weak-base resin for the recovery of gold from plant solutions and pulps, by A. Mehmet. Apr. 1988. 17 pp. Report M353 The determination, by ion-interaction chromatography, of sulphur species in cyanide solutions, by Pohlandt-Watson, M.J. Hemmings, D.E. Barnes, and a.w. PansL Jun. 1988. 7 pp. Report M355 A laboratory-scale continuous-feed resistance furnace, by K.P.D. Pery, A.S.E. Kleyenstiber, andC.T. Logan. May 1988. 9 pp. Report M357 The determination of minor and trace elements in activated charcoal, by RT. Eddy and G.J. Wal. Jun. 1988. 14 pp. Report M358 The sensitive determination of germanium by atomicabsorption spectrophotometry using electrothermal atomization, by G.D. Marshal. Jun. 1988. 11 pp. Report M92D The recovery of tin and tungsten from various zones of the Van Roois Vley deposit, including setling and filtration, by C.F.B. Coetzee. First issued Apr. 1983; reissued Apr. 1988. 40 pp. World Environment Day Symposium* Mintek auditorium in Randburg was the venue on Thursday, 2nd June, 1988, for more than 200 interested delegates at the annual World Environment Day Symposium, organized jointly by the Federation of Societies of Professional Engineers (FSPE), The Environmental Planning Professions Inter-disciplinary Committee (EPPIC), The Habitat Council, and The Associated Scientific and Technical Societies of South Africa (AS&TS). The theme &apos;Cultural and Historical Conservation&apos; was adapted from the theme of the Department of Environment Affairs for the 1988 Environment Week.

Jan 1, 1988

By G. Włoch, E. Rudnik

The oxide fraction of industrial zinc ash was characterized in terms of chemical and phase composition, leaching behavior in sulfuric acid solutions, and leaching thermal effect. The waste product contained about 68 percent zinc (Zn), 7 percent chlorine (Cl), 2 percent aluminum (Al) and less than 1 percent other metals, such as iron (Fe), manganese (Mn), calcium (Ca) and silicon (Si). It consisted mainly of zinc oxide contaminated with metallic zinc and zinc hydroxide chloride. The dissolution of metals from the zinc ash was determined for solid-to-liquid ratios ranging from 100 to 500 kg/m3, acid concentrations of 10 and 20 percent, and temperatures of 20 and 40 °C. The best result — 130 g/dm3 Zn(II) at 95 percent zinc recovery — was obtained at a solid-to-liquid ratio of 200 kg/m3, sulfuric acid concentration RI SHUFHQWDQGLQLWLDOWHPSHUDWXUHRI ƒ& 7KH¿QDOVROXWLRQVZHUHFRQWDPLQDWHGPDLQO\E\0Q ,, DQG)H ,,, ions, but the presence of cadmium (Cd(II)) and lead (Pb(II)) ions enabled electrowinning of zinc of about 99 percent SXULW\DWKLJKFXUUHQWHI¿FLHQF\RI WR SHUFHQW /HDFKLQJRIWKHPDWHULDOZDVDQH[RWKHUPLFSURFHVVZLWKUHDFWLRQ heat of about 520 kJ/kg

CHARLES KIRCHHOFF, Chairman. ALBERT SAUVEUR, Vice-Chairman. HERBERT M. BOYLSTON, Secretary, Abbot Bldg., Cambridge, Mass. John Birkinbine, J. Esrey Johnson, Jr., Felix A. Vogel, William H. Blauvelt, William Kelly, Leonard Waldo, James Gayley, . Richard Moldenke, William R. Walker, Henry D. Hibbard, Joseph W. Richards, - William R. Webster. Henry 1%1. Howe, E. Gybbon Spilsbury, Frederick W. Wood. Robert W. Hunt, A. A. Stevenson, The Board of Directors of the Institute has authorized the holding of a meeting under the auspices of the Iron and, Steel Committee in New York City, October 16 and 17, 1913. Gratifying responses have been received to the request of the Committee for contributions, the following papers being already assured: 1. H. M. Howe, Equilibrium Temperature for A, in Carbon Steel. 2. H. M. Howe, The Divorcing of the Eutectoid in Meteorites. 3. H. M. Howe and A. G. Levy, Determination Of the Position of Ae3, in Carbon-Iron Alloys. 4. G. .K Burgess, J. J. Crowe and H. S. Rawdon, Thermal and Microscopical Examination of Professor Howe&apos;s Standard Commercial Steels. 5. H. Dl. Hove, Discussion of the Existing Data as to the Position of Ae3,. 6. J. H. Hall, Shock Tests of Cast Steel. 7. H. F. Miller, Jr., The Design of Regenerators for Open-Hearth Furnaces. 8. E. Stütz, Paper on the "Scoria Process." 9. Albert Sauveur, Mayari Steel. 10. Felix A. Vogel, Briquetting. 11. J. E. Johnson, Jr., Paper on " Cast Iron."

Jan 6, 1913

As ore deposits become finer grained the requirements for regrinding before cleaning or leaching have increased substantially. Despite this increasing need, there is no standard test to predict grinding energy requirement below 70 microns. The standard Bond Mill test applies for coarser ball milling, but is not appropriate for stirred milling with fine media grinding to 70 microns. With no industry -standard test, the energy requirement is often made on the basis of supplier estimates or benchmarking against similar applications. Yet suppliers use vastly different scale-up methods which result in widely different energy estimates. Estimates can differ by 100-300% even for similar mills. This must result in serious errors to install either too much or too little grinding power. This paper explores this by comparing the actual performance of full scale regrind mills against their original design estimate. It confirms that serious scale-up errors have been made, and have then been perpetuated by ?benchmarking?. The test conditions to achieve accurate power estimation are discussed. The essential test conditions are: continuous (not batch) tests, ensure steady state (no coarse fraction retained in test mill), correctly account for classification, measure energy directly (not inferred), and using the same media size as the full scale installation. Failure to correctly address even one of these factors can bias results by 40%; failure to address several multiplies the error.

Jan 1, 2011

By G. J. Hasenfus

This paper presents the results of an extensive hydrological and geomechanical monitoring program which Gas conducted at a longwall coal mine in W. Va. The field program included monitoring of groundwater levels. overburden hydraulic conductivity, overburden movement, and surface subsidence relative to the passage of the longwall. Overburden geology and rock strength characteristics were evaluated prior to mining. A postmining corehole was drilled to evaluate main roof fracturing. An overburden response model is proposed based on the correlations between hydrological and geomechanical data.

Jan 1, 1988

By Albert L. Toenges

[The i~ ortance o~ S3~e, fdequnt, nQ economical tr~n~po~t~t on 8ys~em Th~a bee~ e~~~~siz8d by the introduction of mechanical loading in co 1 mines, pa.rticula:c y \&apos;r~ e::-e ~o?oile loaciine; ~ac~ine!;j rrre u .... ed. This papar i tr_e . eco:1d or&apos; ?. ~eries deGcribi 1{) t:;&apos;~~11>ort:ltion G stems et1-p oyed in mech3JlizeG. f!lincs. Progre,-s ?. epo~ t J...2.t deal t ~~tirel.: ,&apos;Ii th the l:se of rail .laulagr £or c;atl:erine tran~ortc;tion, ailc, in t-!is paper &apos;Ii 11 be i acuss d c .icilY rub"col&apos;-t? ro ~ t:tto::"ing as Ie _ as ani:naJ., con-",reyor, an ot.he~ systems of rnil gatheri?1.g. ~ho l)urpo~e of this invosti-gation is, as outlined in Progress ,~ort 1, to studT . Q analyz0 v rious systems nov.: in. u"&apos;e El.I1d to derivQ cor..cl :cicn .... tllcrcfrom.]

Jan 1, 1941

By Albert L. Toenges

[The i~ ortance o~ S3~e, fdequnt, nQ economical tr~n~po~t~t on 8ys~em Th~a bee~ e~~~~siz8d by the introduction of mechanical loading in co 1 mines, pa.rticula:c y \&apos;r~ e::-e ~o?oile loaciine; ~ac~ine!;j rrre u .... ed. This papar i tr_e . eco:1d or&apos; ?. ~eries deGcribi 1{) t:;&apos;~~11>ort:ltion G stems et1-p oyed in mech3JlizeG. f!lincs. Progre,-s ?. epo~ t J...2.t deal t ~~tirel.: ,&apos;Ii th the l:se of rail .laulagr £or c;atl:erine tran~ortc;tion, ailc, in t-!is paper &apos;Ii 11 be i acuss d c .icilY rub"col&apos;-t? ro ~ t:tto::"ing as Ie _ as ani:naJ., con-",reyor, an ot.he~ systems of rnil gatheri?1.g. ~ho l)urpo~e of this invosti-gation is, as outlined in Progress ,~ort 1, to studT . Q analyz0 v rious systems nov.: in. u"&apos;e El.I1d to derivQ cor..cl :cicn .... tllcrcfrom.]

Jan 1, 1941

By R. R. Brandenthaler

The development of the Seminole area into one of the major oil-producing sections of the country has been accompanied by many innovations and departures from former methods of development. On July 1, 1929, two years and nine months from the date of discovery, 20,490 acres were considered proved, and additional acreage is constantly being developed. Because of its peculiar conditions, extent, and rapid rate of development, the Seminole area provided numerous problems, the solution of which necessitated research in connection with practical field operation; as a result, there was a radical departure from methods usually employed in the development of a new field in the Mid-Continent area.

Jan 1, 1930

By S. Raghavan

The thermodynamic activities of MgO in the solid solutions that can exist in the system NiO-Mg0-Zn0 are determined by measuring the EMF of the cell: O2 (g), Pt / MgO, MgF2 // MgF2 // x MgO + yNiO + (1-x-y)ZnO / Pt, O2 (g) / MgF2 in the temperature range 1190-1237 K. Equilibrium phases were prepared along the quasi- binary lines MgO/NiO = 0.1765,0.3333, 1.0,3.0 and 5.667 with the ZnO contents being 0.1, 0.2, 0.25, 0.35, 0.5, 0.75 and 0.9. The crystal structures of the phases were identified by X-ray diffraction. Results obtained so far show that a single phase MgO-rich cubic solid solution exists upto 0.2 ZnO content and for compositions above 0.25 ZnO, a second ZnO rich wurtzite phase forms in addition. Activity measurements show that for low MgO and ZnO contents, the MgO activities exhibit ideal to slight positive deviation from ideality and at higher MgO contents, a negative deviation is shown. Further studies are in progress.

Jan 1, 1993

By Budiselic C, Hefter G

The uptake of gold by activated carbon from acid chloride solutions involves the reduction of gold(IIl) to metallic gold. Deposition occurs only on the surface of the carbon at localized active sites at first, and subsequently at less active areas. The rate of uptake depends on the surface area of activated carbon, which confirms results from a recently published study (de Siegel and Soto, 1984). Increased rates of uptake were observed at higher temperatures and lower chloride concentrations due to the decreased stability of AuCI4-, the major gold(IIl) species present. Recoveries of gold approached 100 per cent for a contact time of 60 minutes at 20&#176;C in a well stirred solution initially 5 ppm in gold(III) and containing 0.5 per cent w/v coconut-shell carbon. The presence of 0.25 Mnitric acid or 100 ppm iron(IIl) had no detectable effect on either rate or efficiency of gold uptake.

Jan 1, 1985

By Luis E. Vallejo

The strength measured by the uniaxial compression test is a parameter that is widely used for the engineering classification of rocks. Sedimentary rocks such as shales, however, are difficult to evaluate by uniaxial compression tatting because the rocks slake during the preparation of the standard samples required for the tests. Indirect methods such as the point load test have been proposed to determine the unconfined compressive strength of shales and other soft rocks. It is current practice to use 24 as the conversion factor between the point load strength, Is, and the unconfined compressive strength, sf (sf = 24 Is). The present study investigated index-to-strength conversion factors for shales and sandstones obtained from surface coal mining sites in the Appalachian region. Regression analyses indicate that a conversion factor of 12.5 best correlated the strengths obtained from the point load and unconfined compression tarts in the case of shales. For the sandstones, a value of 17.4 best correlated the strengths.

Jan 1, 1989

PERSONAL (Members are urged to send in for this column any notes of interest concerning themselves or their fellow-members.) Members and guests who registered at Institute headquarters during. the period May 10 to June 10, 1915: Robert M. Keeney, Somersville, Conn. C. A. Moffett, Birmingham, Ala. Emilio Mosonyi, San Salvador, C. A: A. W. G. Wilson, Ottawa, Canada. Junjiro Nagazumi, Fukuoka, Japan. G. H. Glover, Jr., Short Hills, N. J. Francis R. Pyne, Elizabeth, N. J. R. W. Brock, Vancouver, B. C. F. C. Alsdorf, Los Angeles, Cal. J. L. W. Birkinbine, Philadelphia, Pa. W. J. Loring, London, England. Roy H. Allen, Jamesburg, N. J. R. A. Bull, Granite City; 111. Francis Andrew Thomson received the degree of Master of Science from the Colorado School of Mines at the recent commencement exercises. The subject of his thesis was Stamp Milling and Cyaniding.

Jan 7, 1915

By S. Boone, J. N. Shirlaw

INTRODUCTION Soft, near normally consolidated clays generally provide ideal conditions for tunneling using Earth Pressure Balance (EPB) shields. It is easy to turn the clay into a low permeability, viscous spoil that can be pressurized to maintain the required face pres-sure. Despite this, there are records of relatively large, and often quite variable, surface settlements over EPB driven tunnels in soft clay. To understand this variation it is necessary to identify the various factors that contribute to settlement. Tunnels in soft clay are ideal for study these effects in the field, as an unsupported void will close almost immediately, due to the low shear strength of the soil. In the short term, deformation in a soft clay will occur at constant volume, so short term surface settlements can be related to movements at tunnel level. In this paper, data will be used from EPB driven tunnels in Singapore marine clay. In all of the cases discussed the lining consisted of precast concreted segmental rings erected in the tail of the shield. The marine clay in Singapore has been studied, among others, by Tanaka et al.(2001). The clay typically has a plasticity index of 40 to 60, and the undrained shear strength (SU ) can be derived from: SU = 0.22 svo&apos; where svo&apos; is the current vertical effective stress. Figure 1 shows a summary of undrained strength/depth plots used for design on two sections of Singapore’s North East Line. The stability of a tunnel in clay can be assessed by comparing the stability number (N) of the tunnel with the stability number at total collapse (NTC). The stability number can be calculated from the equation: N = (?Z + q – Pt)/SU where: ? = the average unit weight of the ground above the springline of the tunnel Z = the depth to the springline of the tunnel from the ground surface q = the surcharge Pt = the support pressure within the tunnel The stability number at total collapse depends on the size, geometry and depth of the tunnel, and typically ranges between 5 and 9. Charts for assessing the number at total collapse are provided in Kimura and Mair (1981), based on the testing of model tunnels in a geotechnical centrifuge. For tunnels in the Singapore marine clay, the stability number of an unsupported tunnel would be over nine if the tunnel ois more than 8m deep. As a result, a support pressure

Jan 1, 2007

By J. Searra, M. Aboagye

"For new mining projects or for medium- to long-term areas of existing mines, drilling data is invariably on a relatively large grid. Direct estimates for selective mining units (SMUs), and also for much larger block units, will then be smoothed due to the information effects and the high error variance.The difficulty is that ultimately, during mining, selection will be done on the basis of SMUs on the final close-spaced data grid (grade control), which will then be available, i.e. the actual selection will be more efficient, with fewer misclassifications. However, this ultimate mining position is unknown at the project feasibility stage and therefore has to be estimated. This estimation is required because any cash flow calculations made on the basis of the smoothed estimates will obviously misrepresent the overall economic value of the project, i.e. the average grade of blocks above cut-off will be underestimated and the tonnage overestimated for cut-off grades below the average grade of the orebody. Similarly, unsmoothed estimates will be conditionally biased and will give even worse results, particularly in local areas of short- and medium-term planning or mining.This paper presents a case study of indirect post-processing and proportional modelling of recoverable resources designed for mediumand long-term mine planning at the Gold Fields’ Tarkwa Mine in Ghana. The case study compares long-term indirect recoverable mineral resource estimates based on typical widely spaced feasibility data to the corresponding production grade control model as well as the mine production. The paper also proposes certain critical regression slope and kriging efficiency control limits to avoid inefficient medium- to longterm recoverable estimates, and highlights the danger of accepting block estimates that have a slope of regression less than 0.5."

Jan 1, 2015