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By M. Gaft, G. Panczer

Sedimentary francolite and magmatic apatite are characterized by specific laser-induced time- resolved luminescence, which allows phosphate to be distinguished from accompanying dolomite. The "selective window" parameters are: he, = 337 nm, delay time after laser pulse is 0.5-5 ps, and detection spectral range is 400-525 nm. In the case of nonuniform distribution of phosphate minerals, it makes it possible to accomplish lasero- luminescent sorting and to receive intermediate product with a lowered dolomite contents.

Jan 1, 1999

By D. Paul Bishop, Kevin P. Plucknett, Hung-wei Liu

"Spark plasma sintering (SPS) process has been evaluated for producing the commercially pure (CP) Ti, TiAl and a TiAl-B4C composite. Comparisons were made between the materials in terms of the sintered density, resultant hardness and microstructures. In the present work, the titanium aluminide powders (Ti-48Al, producing a mixture of y-TiAl/a2-Ti3Al) were synthesised „in-house? using a simple reaction-sintering and mechanical attrition approach. This allowed various size distributions to be generated. The powders were then blended with a fine boron carbide (B4C) powder (up to 6 wt.%), and the resulting mixtures were consolidated using spark plasma sintering (SPS) under vacuum in graphite dies. An applied stress of 50 MPa was used for all SPS runs. The SPS parameters were varied in terms of the ultimate sintering temperature (up to 1300°C) and hold time (up to 10 minutes) for each material. It is demonstrated that high densities can be achieved this approach (exceeding 95% of theoretical, with optimised samples close to full density). Microstructural characterisation was conducted using optical microscopy, scanning electron microscopy, and X-ray diffraction. The B4C additions were seen to partially react with the TiAl to form reinforcements, such as TiCx and TiBx. Preliminary mechanical property assessment will also be briefly discussed.INTRODUCTION Titanium- and titanium aluminide-based alloys possess many unique properties, such as excellent corrosion resistance and high temperature strength, respectively (Cardarelli, 2001; Leyens & Peters, 2003). Compared to many other competing materials (e.g. stainless steel or Ni-based alloys), Ti- and TiAl-based alloys also have relatively low densities (~4.5 and ~3.9-4.1 g/cm3, respectively), which is critical for performance in aviation and automobile applications. However, the manufacturing cost is high, due to the expensive raw Ti material and difficulties in machining. TiAl-based alloys are particularly difficult to produce because of their limited ductility (Lütjering & Williams, 2007). To overcome those problems, powder metallurgy (PM) technologies have shown great potential as near-net shape processes for Ti- and TiAl-based alloys. The general PM process largely avoids laborious post-machining and minimises material use. In industrial production, the PM approach has been successfully utilised to manufacture aluminium- and iron-based alloys (Huo & Heath, 2008)."

Jan 1, 2017

By Dharmendr Kumar, Pradip, Sivakumar Subramanian, Beena Rai, Venugopal Tammishetti

The separation efficiency in a mineral processing plant is generally assessed and reported in terms of elemental assays constituting the minerals of interest. However, different minerals comprising of same elements behave differently under similar process conditions. Thus, it is imperative to track the mineral composition thank elemental composition of different streams in a processing plant. The availability of automated mineral analyzers such as QEMSCAN and TESCAN in recent times has made it possible. However, due to the high cost and expertise required, their adaptation in day to day monitoring of operations is not yet a common place. X-ray diffraction (XRD) profile fitting (Rietveld Refinement) is another technique which can provide estimates of mineral proportions in a sample. The results of Rietveld Refinement however are affected by coating of fines on coarse particles, method of sample preparation, particle size distribution of sample, elemental substitution in mineral crystal lattice. In the present work, we propose a simple and efficient method for quantitative estimation of minerals in iron ores using elemental assays and thermo-gravimetry analysis data. The minerals (hematite, goethite, gibbsite, kaolin and quartz) are identified using powder XRD analysis. It is also observed that goethite contains Al substitution in the crystal lattice. The samples were analyzed for %Fe, %Al2O3 and %Silica using chemical analysis. The measured Loss on Ignition (LOI) in the sample is contributed from goethite, gibbsite and kaolinite phases. LOI from gibbsite and goethite occur in temperature range 250–350°C and LOI from kaolinite occur in temperature range 400–700°C. According, LOI are determined in two different temperature ranges that are 100–400°C and 400–850°C. We have used the data to successfully determine the mineral compositions of iron ore samples. We have also employed a data reconciliation algorithm on the calculated data for further improvement and consistency of our results. Our method is very convenient for quick estimation of mineral proportions in a sample. The proposed method can also be used for quantitative phase estimation in bauxite ores and red muds.

Jan 1, 2016

By Shunli Z, Jin X, Guanzhou Q

Flotation behaviour can be controlled, due to diminishment of granula quality and extension of specific surface area, by adding coarse particles (high- grade concentrates) to condition pulp. It has been substantiated that coarse particles can intensify fine particle flotation and its mechanisms are effects of carrier, intermedium and assistant aggregation of coarse particles. Calculation and analysis of Reynolds numbers and their variation for different size particles, under specific turbulent dynamic conditions, reveal that agglomeration among granulae is subject to specific turbulent dynamic conditions. Furthermore, sizes and adhesion strength of flocculated particles are the function of specific physical and chemical factors. Based on this research an innovative ramification carrier flotation process has been developed, which has been applied to Fankou Lead- Zinc Mine, Guang Dong province, China, etc, with satisfactory results. These results shed light on distinction between conventional flotation and fine particle flotation, meanwhile, provide a basic approach for further solution of fine particle flotation problem.

Jan 1, 1993

By A. J. Lewis, P. J. Hutcheson, M. E. Robertson, P. A. Moir, K. M. Barfoot

With the content of gold and platinum in the vast majority of ore deposits typically averaging 6 parts per million and less, the accurate and precise measurement of these metals in samples of ore and mining process streams has proven very difficult to achieve by modem spectroscopic analytical techniques. Largely because no other technique has proven suitable, the basic fire assay process has become the accepted international standard for these metals. Fire assay, however, suffers a number of disadvan­tages in the modem, competitive, high technology, and increas­ingly environmentally aware world. It is a labour intensive technique that is difficult to automate, and requires high levels of skill to ensure accuracy and consistency of results. Potentially hazardous chemical reagents are employed, of which, lead, in particular, can be a serious source of contamination to both personnel and the environment if not effectively controlled. Other dangerous elements, such as mercury and arsenic, liberated in high energy furnace operations, are further sources of possible health and pollution hazards. n contrast, the energy dispersive K X-ray fluorescence (K­XRF) technique devised by K X Technology Ltd overcomes many of the technical constraints of conventional low energy X­ray analysis, and has the potential to revolutionise assay opera­tions in precious metal mining. The technology is simply automated, requires basic operator skills, uses no chemicals, consumes less than 20kW, and is capable of detecting gold and platinum to an accuracy of O .1 parts per million by mass. The new third generation design of AZTEC laboratory instrument, released in 1994, is the result of significant technical development. Capable of analysing over 1200 samples per day, and developed primarily for grade control sampling, its applica­tions have spread to gold ore accounting from on-line conveyor belt sampling; screening of exploration samples; measurement of gold in carbon granules for Carbon-in-Pulp process control; and for conducting rapid checks to support key managemen decisions. The economic, rapid, and non destructive analysis ofup to 80g of ore for large numbers of samples, reduces sampling and sub-sampling errors, and provides improved grade estimates for ore bodies. When interfaced to a LIMS, laboratory automation and cost-savings can be further enhanced. The AZTEC design is also being modified for the analysis of platinum. The GOLDSTREAM on-line analysis system is an important new application of K-XRF to the continuous monitoring of process streams in gold ( or platinum) plants and mills. Integrat­ing the technologies of K-XRF to measure total gold, and dissolved gold spectroscopy to measure gold in solution, the insoluble fraction of gold can be deduced, and the effectiveness of the extraction process determined. Slurries are sampled automatically from selected points of the plant and pumped to the system for analysis. The information produced forms the basis for plant control and optimisation.

Jan 1, 1995

By William T. Barrett

It is said that Thales of Miletus, 600 B.C.,1 was aware of the attraction of lodestone toward iron and highly magnetic minerals. However, the birth of magnetic concentration followed shortly after the invention of the first electromagnet by Sturgeon in 1825. Sturgeon's magnet was described in the annals of electricity.2 The first attempts to concentrate minerals by the use of magnets date back to about 18473 but the first commercial drum-concentrator was apparently invented by R. Cook in 1849. Credit must also be given to the invention of P. Righter's machine in 1867,5 and to the highly successful Wenström separator devised in Sweden in 1883.8 Since the advent of these early separators there have been virtually hundreds of patents granted covering minor modifications of drum-type magnetic separators. The more important advances from a technological viewpoint have been the design of stable power supplies for d.c. magnets, the advent of ceramic permanent magnets which are now replacing electromagnets for the concentration of ferromagnetic minerals, and advances in general magnet and machine configurations.7 One of the problems facing both the designer and the user of magnetic separators is the evaluation of the body forces acting on particles in the magnetic field of the separator. Perhaps the most elegant method of evaluating the body force associated with a drum-type magnetic separator is that recently suggested by W. F. Brown.8 Brown measures the radial component of the field intensity one-half inch from the drum surface and fits a Fourier series in the angle about the drum axis (Figure 1). Once the coefficients of the series are known, it is then possible to calculate [ ]

Jan 1, 1970

By Carlton E. Brown, William P. Yant

"INTRODUCTION Direct visual microscopic determination of particle-size distribution and number concentration of atmospheric dust is time-consuming and trying to the eyes. By using the microscope to project images of the particles at high magnification onto a screen much of the eyestrain can be eliminated and particle-size distribution results obtained with less effort and at a considerable saving in time. It also permits simultaneous observation of the images by more than one person. Microprojection requires no more skill and very little more apparatus than is required in the use of the microscope. Anyone familiar with the microscope should be able to obtain as perfect images on the projection screen as in direct visual microscopy since the same laws and limitationsThe theory and practice of microprojection are described in detail in texts. 5/6/ The procedure has been used and found to be satisfactory for measuring the particle-size distribution of sub-sieve-size substances, such as pigments and powder 7/8/ in the same size range as that of atmospheric dust. The Bureau of Mines has used the microprojector and found it to be quite satisfactory for (1) the determination of the number concentration of atmospheric dust R.I. 3289 in samples collected by the Owens jet dust counter; (2) particle-size distribution in samples of atmospheric dust collected by the Owens jet dust counter and by the electric precipitator; and (3) the particle-size distribution of dusts, blood cells, bacteria, and pollen. Work is in progress at this Bureau on the use of the microprojector in counting impinger samples. The use of different kinds of illumination, such as reflected (dark field), polarized, monochromatic, and ultraviolet, in the projection of images of atmospheric dust particles is being considered."

Oct 1, 1935

By Mark S. Stagg, Michael J. Nutting, Douglas R. Barlet

Single-row bench blasts at a reduced scale in the field were used to study the effects of delay time on fragmentation. Nine shots with a spacing of 21 in. and a burden of 15 in. (S/B = 1.4) and nine shots with a spacing of 30 in. and a burden of 15 in. (S/B = 2.0) were completely screened to determine particle size distributions. Delay intervals between holes ranged from 0 to 45 msec, corresponding to effective delay intervals ranging from 0 to 36 msec per foot of burden. Each shot was instrumented with strain and pressure gages to measure in situ blast dynamics and to evaluate interactions between blastholes. Finer overall fragmentation was produced for shots with delay intervals between 1 and 17 msec per foot of burden. Only for shots within this optimum delay range was it observed that the strains induced by stress waves constructively interacted with strains induced by gas pres- sure from an earlier detonated hole. Coarsest fragmentation resulted at delay intervals less than 1 msec/ft, where stress waves from each hole were observed to interact destructively, and at delay intervals greater than 24 msec/ft, where no inter- action between holes was observed, indicating a condition that can be considered as the firing of single hole shots independently.

Jan 1, 1986

By W. E. Horst

Historically, research organizations have made significant contributions to the development and commercialization of new chemical products for the mining industry and examples of commercial results are cited With the recent demise of research organizations within the mining industry and dynamic changes in the industry, the supporting role of R&D groups has become limited or non-existent. Cat- reduction requirements and new raw-material sources offer future opportunities for R&D organizations to continue their effective participation in the commerical development of new chemical products. Potential areas of interest for future process applications are reviewed.

Jan 1, 1986

By William Seymour, L. D. Schmidt

A preliminary survey of coke and steel plants conducted by the Bureau of Mines in cooperation with the Office of the Solid Fuels Administrator for War and with the advice of the Coke Production Committee indicated that production of pig iron could be increased. appreciably if present blast furnaces were supplied with a more uniform coke.4/ Nonvarying percentages of ash , sulfur , and fixed carbon in the coke , together with uniform physical characteristics , such as size , strength , and porosity , would aid the blast -furnace operator greatly in his trial - and - error methods of obtaining maximum production . With nonuniform raw materials he must employ certain factors of safety in operation , such as an excess of coke , an excess of limestone , and operation of the furnace below the maximum rate . Even so , he often has trouble from iron not being up to specifications , hot tops , high blowing pressures , furnace hanging up , etc. The more uniform his raw materials (of which coke is probably the most important) , the nearer to ideally can he run his furnace and thereby save raw material and increase production . One cause of nonuniformity of the coke produced by ordinary American plant practice is the prevailing lack of precise control of the bulk density ' of the coal charge in the byproduct oven . This report summarizes the available information on the subject of bulk density of crushed coal and its control . It includes brief reviews of some of the literature , some results obtained at plants visited by the authors , and results of a few preliminary tests made at the Pittsburgh Station of the Bureau of Mines .

Dec 1, 1943

By Biswajit Samanta, Pranjal Pathak

This article presents a customized genetic algorithms (GA) with new crossover and mutation operators to solve the short-term production scheduling problem of multi-mine mineral value chains (MVC). The preceding problem consists of determining the extraction sequence and destination allocation of blocks from all the mines collaboratively while closely meeting the quality and quantity requirements of the processing units subject to relevant technical and operational constraints. The short-term production scheduling is carried out at shorter scales wherein the operations are modeled in a great detail with large number of constraints. This makes the industry-scale instances of the problem computationally intractable for standard mixed-integer programming (MIP) solvers. Thus, a GA-based heuristic approach is developed to obtain nearoptimal solutions to the large-scale instances of the problem in a reasonable amount of computational time. Computational experiments show that the developed GA-based method is a promising way to handle industry-scale instances of the problem. Moreover, the sensitivity analysis on various parameter combinations of crossover and mutation operators indicates that the customized global mutation operator, when used in combination with the customized crossover operators, took on average 12.5% less time than the customized local mutation operator to converge to a solution.

May 21, 2022

Polarization phenomena associated with the use of an agitated bed of particles as an electrode for metal deposition were studied. The concentration polarization at this type of electrode is much smaller than that occurring at a fixed or moving electrode surface. Agitated particle electrodes can be used to electro-reduce copper from solutions over a wide range of concentration and at cur·rent densities up to 2000 AIsq. ft. of bed cross section.

Jan 1, 1971

By R. R. Hart, B. C. Wonsiewicz, G. Y. Chin

In recent years there has been increased miniaturization of electromechanical devices to keep pace with current trends toward smaller electronic components. A major problem facing the designer, however, is the higher stresses encountered by the material as a result of shorter springs. Hence an improvement in the elastic limit, as approximated by the 0.01 pct offset yield strength, would be highly desirable. An increase of 25 pct in the yield strength, for example, will permit a 20 pct reduction in both the length and thickness of a cantilever-type spring while maintaining the same compliance. One technique of improving the yield strength that has received little commercial attention is crystal-lographic texture strengthening.1,2 Texture strengthening is expected to be most beneficial in materials of hcp structure, but considerable gain can also be expected in cubic materials. A wire with a (111) fiber texture, for example, is expected to be 20 pct stronger than randomly oriented material, and 50 pct stronger than wire with a (100) fiber texture.293 For sheet specimens with a {110}(112) texture, characteristic of many heavily rolled fcc alloys, the (111) transverse direction is expected to be the maximum yield strength direction, about 20 pct higher than that in the (112) rolling direction.' In addition, the (111) direction is the direction of maximum modulus of elasticity for most cubic alloys. A large value of the elastic modulus could be desirable in designs where stiffer springs are required. To test the above idea, a 0.090 in. (-2.3 mm) thick commercial grade A (5 pct Sn) phosphor bronze sheet, a widely-used material for relay springs, was rolled from the spring-tempered condition (60.5 pct reduction) to various additional reductions up to a total reduction of 95 pct. Subsequently, additional material was obtained with a total thickness reduction of 97.3 pct Standard tensile specimens were prepared from the sheet material with the tensile axis parallel to and at 90 deg to the rolling direction. Tests were run on an Instron testing machine at a strain rate of about 0.050 min-l. Textures were determined by the use of the reflection pole-figure technique. Data were obtained using nickel-filtered CuKa radiation and with the aid of a Siemens pole figure goniometer. The X-ray pole figure studies show an incrzasing development of the texture toward the {110}(112) ideal

Jan 1, 1970

By John W. Bell

The aim of the laboratory experiments described in this paper was twofold: 1. To measure as accurately as possible the maximum amount of crushing that can be effected by 1 hp. acting for 24 hr., by the two proposed methods for measuring the amount of crushing, namely: (a) by Rittinger's method; (b) by Stadler's method, based on Kick's law. 2. To show, if possible, that by one of these methods, the amount of crushing produced by 1 hp. in 24 hr. is a constant amount throughout a wide range in the diameter of the piece crushed, and that by the other method, the amount of crushing is a variable quantity over the same range of diameter; or else show that neither of the proposed methods for measuring the amount of crushing indicates a fixed relation between power and crushing and consequently a new method for computing this amount will have to be found to permit the establishment of a law of crushing. Experimental Methods Testing machines, calorimetric methods and commercial types of rock-crushing machines were considered with reference to their value for measuring power used in crushing. The following electrically driven crushing machines, installed and available in the McGill Ore-dressing Laboratory and which had been used in previous rock-crushing tests, on the whole seemed especially suited to the investigation: (1) Comet "A" crusher; (2) 7 by 9-in. Dodge crusher; (3) 10 by 16-in. rolls. In later tests a 3 ½-ft. Huntington mill was used.

Jan 1, 1918

By R. K. Singhal

In 1990, Canada produced 69.4 million tonnes of coal of which some 65 million tonnes was produced by surface mining methods. The two Western Canadian provinces, Alberta and British Columbia produce approximately 55 million tonnes of coal by surface mining. These two provinces also provide the bulk of the metallurgical coal for export. The geological conditions in the Western provinces particularly in the mountain region are complex. The coals are friable and the seams are steeply inclined, sheared, intensely folded and faulted. There may be as many as 15 to 20 coal seams present with true thickness ranging from 2.5m to over 8m. Most of the Canadian surface mines are large (over one million tonnes per annum) using modern mining equipment such as shovels, high capacity trucks and draglines. At present the industry is going through another of its up and down cycles but has continued to make impressive gains in productivity. This has been achieved through greater mechanization, better management practices and a will to succeed in a highly competitive world market. This paper presents an insight into the current status of the Canadian Coal Industry and essentially updates the information given by the authors at previous SME meetings.

Jan 1, 1992

By Shaoyang Yan, Xinming Chen, Huazhe Jiao, Huaibao Chu, Chang Wang

In terms of the technical problems of rib spalling in large mining height coal face, a long-distance advanced pre-grouting layer flexible reinforcement technology is proposed in this paper. Based on the mechanism and failure mode of rib spalling in the coal face, the mechanical properties of the aluminum plastic composite pipe were analyzed by using the tensile and compression experiment. The deformation and strength characteristics of “flexible pipe + grouting” specimens were studied by uniaxial compression test, splitting test, and shear test. The UDEC numerical simulation software was used to simulate the reinforcement effect of “flexible pipe + grouting” at different positions. Combined with the field application, the feasibility of long-distance advanced pre-grouting layer flexible reinforcement technology was verified. The test results show the following: The coal face has the characteristics of brittle and large deformation. The aluminum plastic composite pipe has the characteristics of good elongation and tensile strength, which can endure the large deformation of the coal face. The “flexible pipe + grouting” can improve the tensile and shear strength of coal. The UDEC numerical simulation analysis indicated that the grouting hole layout of “flexible pipe + grouting” has a significant difference in the reinforcement effect of the coal face. Compared with single row grouting reinforcement, the reinforcement effect of double row grouting holes 1.5 m and 3.0 m away from the roof is better. According to the field application, it is feasible to use aluminum plastic composite pipe as a flexible grouting pipe to reinforce coal seam with 80–100 m long-distance pre-grouting. Long-distance advanced pre-grouting layer flexible reinforcement technology can improve the daily production of coal and reduce the support cost of the coal face. As a new method of reinforcement, long-distance layered flexible reinforcement has a significant effect on the prevention and treatment of rib spalling in large mining height coal face.

Sep 27, 2022

By Huimin Lu, Shi Zhou, Lisha Yang

"The Zeolitic imidazolate frameworks (ZIFs) were successfully synthesized by applying a combination of ionothermal synthesis and microwave energies for rapid synthesis. The synthesis was proceeded under various conditions including different raw materials, reaction temperature as well as microwave irradiation time. Zeolitic imidazolate frameworks (ZIFs), also known as coordination polymers, are new type of porous materials formed by inerratic polyhedral in three-dimensional. They are the ideal crystalline substances for gas separation and storage. The assynthesized samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), thermal gravimetric analysis (TGA) and C02 adsorption test. Results illustrated that the synthesized samples had stable structure, high thermal stability (up to 530 °C) and C02 adsorption capacity (10.2 cm3/g at 0°C under ambient pressure). This novel method also showed great advantage with high energy efficiency, safe synthesis conditions, and rapid crystallization time (60 minutes).IntroductionNowadays, carbon dioxide capture has become imperative due to the global warming caused by the increase of C02 in the atmosphere, especially produced by the concentrated sources such as power plants [1]. Zeolitic imidazolate frameworks (ZIFs), also known as coordination polymers, are ideal crystalline substances for gas separation and storage due to their structure diversity, high thermal and chemical stability [2-5]. They are formed by inerratic polyhedra in threedimensional with large cages and small apertures. Traditionally, ZIFs are synthesized by solvothermal method in a sealed autoclave under autogenous pressure [6-9]. However, in order to generate the products, the solvothermal temperature should not be lower than 100°C according to the sovlothermal mechanism. Moreover, at such a temperature, molecules with a low boiling point (such as water) may generate high pressure in reactor which might cause danger [9]. Thus the synthesis requires the equipment to possess resistance to autogenous pressure and corrosion. Further, conventional solvothermal methods need a long time to prepare products, usually a few days, which is a large energy consumption and inefficiency. So it is interesting to synthesis ZIFs through other ways under mild reaction condition with high energy efficiency."

Jan 1, 2012

By T Casten

Freeport IndonesiaÆs DOZ (Deep Ore Zone) mine is scheduled to commence production in the second half of 2000. The DOZ will produce 25 000 tpd using mechanised block cave mining methods and will have a number of major improvements when compared to previous block cave mines in the district. The DOZ will have an independent and improved ventilation system, a flexible and efficient truck haulage system, and a more reliable crushing and conveying system than in previous underground mines in the district. This paper will describe the mine plan, haulage, and ventilation systems, and compare them to those used in other operations in the district.

Jan 1, 2000

By L. M. Kaas

El presente artículo señala el uso de la computadora desde 1950 y sus avances a lo largo de la historia industrial y de producción. En este sentido, anteriormente ninguna fase de los procesos de minería y de molienda ha quedado sin investigar para encontrar nuevas aplicaciones de este aparato. Hoy, los problemas de geología, minería, preparación de minerales y gestion -muchos hasta hace tiempo imposibles de tratarse han resuelto satisfactoriamente con el empleo del computador.

Jul 1, 1971

By B Sno, P A. Cockburn, R C. West, C U. Jones

Clyde Materials Handling (CMH) and WorleyParsons have developed a concept for a flash furnace feed system using the specialist pneumatic conveying equipment expertise of CMH and the flash furnace process experience of WorleyParsons. CMH has developed a proprietary volumetric feeder (called a Rotofeed), which is extremely accurate and overcomes many of the problems inherent with loss-in-weight screw feeders and drag chain conveyors, previously regarded as state-of-the-art. Initial indications are that the Clyde-WorleyParsons feed system could deliver the following benefits to flash furnace operation: accurate pulseless delivery of feed material to the head of the burner leading to improved combustion performance and process stability; highly accurate split to the individual quadrants of a conventional burner tube, or provision of a smooth hollow curtain to a burner without guide vanes; decreased pressure pulsation in the furnace due to improved combustion control and performance; and decreased temperature fluctuations in the furnace due to improved combustion characteristics and hence reductions in refractory thermal stress and wear.

Jan 1, 2005