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By E. V. Verhoej

The proposed EU directive on the restriction of the use of certain hazardous substances in electrical and electronic equipment promotes the substitution of lead in consumer electronics to reduce emissions from lead in the end of life phase. In this paper, the consequences of substituting lead in solders is assessed using the Eco-Indicator-99 method for the examples. The base metal production system is considered as an interconnected network modeled dynamically in Simulink 4 and Matlab 6 (Mathworks Inc 2000), where the recovery and production of metal components of the assessed product partially overlap. This approach requires global modeling of metal production processes and mass balances and resulting allocation choices. It also reveals the susceptibility of LCA scores to different choices in the modeling and data availability and uncertainty. Besides the comparison between lead-free and lead-containing solders, other side effects are revealed. Lead is carrier material for the recycling and production of many co-elements in the interconnected production and recovery system. Substitution may have adverse effects such as temporary shortages of other connected metals that are often not considered in normal LCA assessments, thus leading to erroneous results. The suggested approach provides directions for including these extemal effects and for further assessment of the environmental effects of substituting lead. This paper shows that in order to assess the environmental aspects of metallurgy, dynamic modeling of the total system is required based on the fundamental thermodynamics in each metallurgical reactor, the basis of this dynamic model. With this the true environmental impact of metallurgy can be explained. In the case of lead free solder, it is shown that the mining of substitutes has a very much larger impact.

Jan 1, 2003

By K. K. Kershner, W. A. Calhoun, C. W. Funk

Future resources of aluminum may require the utilization of low grade ores to provide a more permanent protection for the nation. Aluminum minerals such as cloy, shale, and high iron laterites may become important sources. An evaluation of reserves is given. New laboratory results are reported on the Vereinigte desilication process. THIS report on future resources of aluminum metal emphasizes the necessity for investigating utilization of low grade potential ores to provide more permanent protection for the nation. Partial or complete interruption of the importation of high grade aluminum ores must be given consideration. Ultimately, aluminum minerals such as clay, shale, and high iron laterites may become the principal sources of aluminum. The development of extractive processes for treating these low grade materials is a step in long-range national preparedness that should receive more attention. In formulating such processes, the application of beneficiation methods for the purpose of classifying the several types of minerals before subjecting each type to the more expensive extractive procedures should be considered, and a careful survey of the basic factors of power sources, transportation facilities, and sources of raw material should be made. Domestic Bauxite Resources Of the domestic supply of current, treatable-grade bauxite, 95 pct comes from Arkansas. The present reserve of Arkansas bauxite suitable for metal production, including abrasive-grade, Bayer-grade, and modified Bayer-grade ores, is 34,000,000 tons. The total reserve of bauxite of all grades is approximately 75,000,000 tons. Reserves are estimated on a mined and dried basis. Data available to the Bureau of Mines in 1948 to 1949 were used in preparing Table I, which shows a breakdown by grades of bauxite for about a half of the reserves of the state. The modified Bayer ore, 10,555,500 long dry tons, is based on a cutoff of 8 to 15 pct silica. The sub- marginal 10,074,700 long dry tons is assumed to contain more than 40 pct gibbsite, more than 15 pct silica, and less than 32 pct available alumina. A considerable amount of this low grade material was consumed in 1949 and 1950. Additional tonnages of bauxitic and kaolinitic clays are indicated by the Bureau of Mines drilling project.' Applying a 50 pct factor to arrive at long tons mined and dried, the results of this project are approximately 31,500,000 tons kaolinitic clay at +35 pct Al²O3 and 11,800,000 tons kaolinitic clay at 20 to 35 pct A1,0,. Total reserves of kaolinitic clays are probably quite extensive—several times the reserves shown in the Bureau's work. Total reserves of bauxitic and high iron clays from the drilling program and previously established figures are 63,980,000 tons. The mineral dressing methods,' the lime-sinter process, he lime-sinter modification of the Pederson process," the lime-soda sinter process,"-' and the Alcoa combination processa. have been described in the literature and will not be elaborated upon here. The less familiar Vereinigte Aluminium-Werke process used by the Germans during World War 11 may require some amplification. It was used to bene-ficiate boehmite ores containing 12 to 18 pct silica for a feed to the European Bayer process. Ore was

Jan 1, 1952

By R. G. Gifkins

Mean boundary migration depended linearly upon creep extension under various conditions. Prolonged annealing or air-casting increased the proportion of immobile boundaries at a given stage of tests. Grain growth during annealing followed a power law. The linking of migration and sliding in creep and models for migration are examined; activation energies are calculated from these models. Segregation of oxygen to boundaries appears to be a controlling factor. THE idea that boundary migration and boundary sliding during creep are linked has often been suggested,'-5 especially when evidence has been obtained for an alternation between the two processes. In simple bicrystals sliding can occur without any migration6 but in more complex bicrystals7 it is observed. McLean' and Couling and Roberts 5 made measurements of both sliding and migration; McLean concluded that there was no linking of the two processes whereas Couling and Roberts supported the idea. McLean' also developed a model for migration during creep and annealing. The present work was initiated as part of a study of the recrystallization of lead during creep9 but has been extended to examine some aspects of the mechanism of migration. MATERIALS AND METHODS Specially refined high-purity lead* was used; the total of impurities, excluding oxygen, was 0.0008 wt pct. Oxygen was removed as far as possible by melting in vacuo, treating at 550" to 600°C with hydrogen and then casting at 450°C under a vacuum of 10-2 mm Hg; the oxygen was then believed to be 0.00005 wt pct. Specimens were made from extruded strip and then annealed at the required temperature in an air oven, controlled to 5 lac. They were then polished in a mixture of acetic acid and hydrogen peroxide. At this stage some specimens were etched to give grain contrast and their grain sizes determined by the intercept method. Migration of boundaries during creep was measured on the surface of polished (not etched) specimens, directly loaded at room temperature (22°C) or 50°C (52"C) to initial stresses of 300 to 700 1b per sq in. Twenty six vacuum-cast hydrogen-reduced specimens were used and, in addition, two specimens were from material air cast after hydrogen reduction ("partial" air cast) and two from air-cast material not treated with hydrogen ("full" air cast). Duplicates were made in the majority of tests. At intervals through the creep tests, specimens were unloaded and the migration measured, normal to the direction of migration at the point of measurement, for each boundary along standard traverses. Usually between 110 to 180 boundaries were measured at each of some twelve stages of the tests. Migration was measured on the projected image (X100) using prism illumination. Fig. 1 illustrates the method of measurement and shows the kind of variation of migration found from boundary to boundary and along particular boundaries. Fig. 2 gives an example of more extensive migration. The mean value of distance migrated was generally reproducible to *10 pct but occasional points gave a scatter of *20 pct. The correctibn applied by McLean8 to allow for the contribution sliding makes to the apparent distance of migration could not be used, for the sliding at most boundaries was too small to measure with the equipment available. There were two reasons for supposing the correction unnecessary in the present work;

Jan 1, 1960

By M. H. Richman, L. M. Markowitz

MUCH of the available information on which the heat treatments of a particular steel are based is found in the isothermal-transformation diagram. Such is the case despite the fact that the usual thermal treatments involve continuous transformations, i.e., transformations which occur on cooling, rather than isothermal transformations. This rather unusual practice is continued because of the abundance of published isothermal-transformation diagrams1, 2 which are relatively easy to determine experimentally as compared to continuous-transformation diagrams.3, 4 However, this can easily lead to the production of improper micro-structures and may not allow full advantage to be taken of the inherent hardenability of a steel. A mathematical method of estimating the continuous-transformation diagram from the available isothermal data was developed by Grange and Kiefer;5 but, due to the mathematical approximations required in the calculations, the computation of continuous-transformation diagrams has been limited to individual cases and no large-scale compilation of these diagrams is available. With the present availability of high-speed digital computers, the problem of time-consuming approximations may be minimized and continuous-transformation diagrams may be constructed with the insertion of isothermal data into a basic program. It is the purpose of this report to announce the availability of such a program and compare the computed and experimental continuous-transformation diagrams for two different steels. Let us first review the method of Grange and Kiefer5 and then compare the results of the machine calculations with the experimentally determined diagrams. In order to apply this method, one requires the isothermal-transformation diagram and a set of curves representing cooling at constant rates. A section of an isothermal-transformation diagram is shown in Fig. 1 together with a cooling curve of M0F per sec. The cooling curve is constructed to start from the A1 (eutectoid) temperature if the transformation product is the eutectoid microconstituent (i.e., pearlite or bainite), from the A3 temperature if the product is primary ferrite, or from the 4, if it is proeutec-toid cementite. The cooling curve in Fig. 1 intersects the curve representing the start of isothermal transformation at a point A' corresponding to a temperature TX and a time fX. An arbitrary lower temperature To (on the

Jan 1, 1968

By J. H. Bechtold

Tensile properties of annealed molybdenum were investigated from 1000" to—200°C. In the vicinity of room temperature a well-defined transition in tensile properties occurs. Reduction in area decreases from over 80 pct to 0 pct and, simultaneously, the yield strength increases about 60,000 psi. MOLYBDENUM, tungsten, iron, and many other metals and alloys with the body-centered cubic and hexagonal close-packed crystal structures change from ductile to brittle behavior over some relatively narrow temperature range. The temperature at which this transition in ductility occurs depends on chemical composition, microstructure, and method of testing. When fine grained, completely recrystallized molybdenum of commercial purity is tested in uniaxial tension at a slow strain rate, the transition occurs at slightly below room temperature.' Iron2 and tungsten3 tested under similar conditions become brittle at temperatures close to the boiling point of nitrogen, — 195°C and at about 200°C, respectively. A sharp change in ductility is uncommon in metals with the face-centered cubic crystal structure, however, a relatively sharp transi- tion in notched bar impact properties has been observed below room temperature in a face-centered cubic copper-antimony alloy.4 A transition from ductile to brittle behavior is usually explained by the concepts originally developed by Ludwik,5 and discussed and elaborated on by others including Orowan,6 Hollomon and Jaffe,7 and Gensamer8 In brief, there are two aspects to strength, first the resistance to flow and second the resistance to fracture. Both are functions of temperature, strain, strain rate, stress system, composition, and microstructure. With decreased test temperature the flow stress required to initiate plastic deformation increases more rapidly than the fracture strength and brittle fracture occurs at that temperature where the yield strength equals or exceeds a brittle fracture strength. This investigation was conducted to determine the effects of temperature, strain, and rate of straining on the flow and fracture strengths of molybdenum above, through, and below the ductile-to-brittle transition. Other variables were held constant during testing. This information is believed to show

Jan 1, 1954

By L. P. Teas

In spite of the influx of operators into the Gulf Coast anxious to retrieve their depleted production in other fields, and in spite of very active application of the most scientific geophysical methods to locate new producing areas, the results have been very discouraging and the year has failed to produce more than the average results for a Gulf Coast year. During the year seven new oil fields, some of which are still of very little importance, and one new gas area have been discovered. These fields are Tom Ball, Greta, Cleveland, Raisin and Garwood in Colorado County; Louise and Premont in Jim Wells County, and the new producing gas area near Ace in southern Polk County. During the year salt has been found for the first time at Carlos and Esperson. New producing areas have been developed on East Stratton Ridge, Hockley, Hull, Port Neches, near Pettus in Bee County, and on the O'Connor Ranch in Victoria County. The total production for the Gulf Coast for the year was 62,837,435 bbl., an increase of 18,589,000 bbl. over 1932. During the year, 1307 wells have been drilled of which 207 were wildcats, compared with 653 wells and 141 wildcats the previous year. The total daily production at the end of the year was 165,201 bbl. At present there are 3100 oil wells producing. The average production per well is 55.5 bbl. per day. The price of crude fluctuated considerably during the year, beginning at 80c per barrel and closing the year at $1.04 per barrel. Completion data for 1933 are as follows:

Jan 1, 1934

ON p. 499 of the December issue Of MINING AND METAL-LURGY plans were announced for a memorial to en-gineers who died in overseas service during the World War and a gift to the University of Louvain on behalf of the engineers of America. In this connection it is proposed to erect a memorial tablet giving the names. of engineers who died in the foreign service. Members of the A. I. M. E. who gave their lives, so far as they are known, are listed below. It will be much appreciated if notice be given of any omissions and also if the name of some surviving relative be supplied in each case. Louis Baird, Lieut., Royal Field Artillery, British Army, killed on the battlefield, 1915. John H. Bellamy, Capt., Regimental Staff, 103rd Engi-neers, killed near Fismes, Aug. 9, 1918. Martin F. Bowles, Lieut., 1st Battalion, 355th Infantry, 89th Division, killed on the battlefield, Sept. 3, 1918. Andrew Burt, died in .active service, 1916. Stanley B. Carlisle, Machine Gun Battalion 346, 91st Divi- sion, died in France, Oct. 24, 1918.

Jan 1, 1928

The objective of this handbook is to provide the inspector with guidance for recognizing hazards from inhalation contaminants in above ground work areas of underground and surface metal and nonmetal mining and processing facilities and evaluating these hazards by collecting samples or making field determinations and interpreting the analytical results. Portions of the handbook that should prove most useful to the inspectors include a survey check list, rules for determining if sampling is required, list of most frequently encountered contaminants, list of candidate contaminants and their sampling conditions, interpretation of results, and a procedure for a health and safety inspection.

Jan 1, 2011

By J. Vance Batty

Two methods were devised and evaluated for quantitatively measuring the amount of oleic acid on flotation products and in flotation waters. One method involved use of an organic solvent to remove carbon-l4-tagged oleic acid from mineral surfaces and flotation water phases with subsequent radio-metric analysis of the extracts. Studies showed this method to be slow and subject to large variations in accuracy and reproducibility. In the second procedure, tagged oleic acid was measured directly on the surfaces of dried mineral products. Oleic acid in the water phase was determined by adsorbing it on fine mineral, drying, and radiometric counting. Quantitative analysis of oleic acid on flotation products from bench-scale flotation tests with synthetic mixtures of ore minerals and quartz and with natural ores showed this method to be fast, accurate, and reproducible.

Jan 1, 1968

By David A. Hall

We present an analysis of the propagation in a uniform tunnel of semi -circular cross section that contains two axial conductors. In particular, we show that, even if one of these conductors has high ohmic loss, one of the two propagating modes has relatively low attenuation. This corresponds to the situation where an unloaded dedicated wire is used to improve radio frequency communication in a mine tunnel that contains a heavily loaded trolley wire.

Jan 1, 1978

By A. S. Callen

These iron mines of Spain are located on the mountain ridge forming the boundary between the Teruel and Guadalajara provinces, called Sierra Menera. They form a property of 25 mines extending over an area of 1,677 hectares (4,140 acres) situated at a height varying from 1,200 m. (3,940 ft.) to 1,500 m. (4,920 ft.) above sea level. The deposit follows the direction north to south; huge masses of ore are being found both on the slopes and at the summit of the Sierra. The ore occurs among quartzites and magnesite limestone, in some places overlaid by quartzite 15 m. (50 ft.) thick; in some others (and this is more general) the ore is overlaid by earth and boulders of quartzite origin; this layer is about 8 m. (26 ft.) thick. The ore beds occupy the geological horizon of the Superior Trias or Muschelkask, which are here in direct contact with the Silurian quartzites. The lime-stones have been more or less transformed. There is ample evidence to show that these mines were worked in very ancient times—objects and tools employed in mining by the ancient Romans and Arabs are to be found plentifully in old workinigs which extend down into the deposits. It has been estimated that more than 10,000,000 tons of ore were mined in the old days in this district and carried to the primitive forges in the vicinity where iron of much renown in Spain was extracted. Remains of more than 20 of these forges are found in the neighborhood of Sierra Menera and are usually situated near waterfalls and forests. Much investigation has been carried on for the purpose of determining the quantity of ore to be found in these mines, but no exact calculations can be made at present. When the investigation is completed it will surely be found that the deposit contains a much larger quantity than the 100,000,000 tons indicated by the present workings. The mines are now worked as open quarries and this method can and will be followed for a long time, probably until the deposit is worked out. Figs. 1 and 2 give some idea of the quarries in operation and the reserves, the iron-ore stocks, screening installation and general arrangement. From these quarries 1,000,000 tons can be mined annually (987,000

Jan 1, 1916

By D. J. A. Chambers, J. M. Wempen, K. D. Koper, M. K. McCarter, K. L. Pankow

"The EarthScope Transportable Array (TA) of broadband seismometers (www.usarray.org) was deployed across southwest Wyoming from November 2007 through May 2009. During this time period the Array Network Facility (ANF, anf.ucsd.edu) detected and located a total of six seismic events near the trona-mining district. This lack of seismicity is atypical compared to coal mines employing similar mining methods. In this study, eighteen months of continuous seismic data from several nearby TA stations are reexamined using conventional and correlation-based methods to detect seismic events. Waveform cluster analysis and epicentral locations are used to discriminate between mining induced seismicity (MIS) and seismic energy generated from surface blasts at nearby coal mines. The locations and magnitudes of the 143 newly detected MIS events are compared to regional subsidence as measured by Differential Interferometric Synthetic Aperture Radar (DInSAR). INTRODUCTION An abundance of natural resources and a favorable political climate have made southwest Wyoming home to multiple large mining operations. Among these operations are five underground trona mines located approximately 50 km west of Rock Springs, Wyoming. The trona mines employ room and pillar, longwall, and solution mining methods over an area roughly 900 km2, and produce a sizable portion of the world’s soda ash (Brown 1995). Historically, in the Rock Springs mining district, several relatively large magnitude seismic events have occurred. These events are thought to have been related to mining activity and have caused notable subsidence (Case 1997). The largest event in the region recorded by seismometers, ML 5.1, has been confirmed as the 1995 Solvay Trona Mine collapse (Pechmann et al. 1995). In addition, blasting at surface coal mines near Rock Springs produces significant amounts of seismicity; approximately 50% of all daytime seismic events in the Mountain time zone from 2007 to 2009 locate near an active surface mine in this region (Astiz et al. 2014). Much of the current research related to surface subsidence and induced seismicity focuses on wastewater impoundment (Ellsworth 2013) and hydraulic fracturing. The observable seismicity in geological injection environments is widely variable and McGarr (2014) has argued that, in such environments, the maximum amount of seismic energy that can be released is proportional to the injected volumes. Like injection environments, in extraction (mining) environments seismicity is highly variable depending on many geological and operational variables (Boltz et al. 2012; Carnec and Delacourt 2000; Fritschen 2010; Iannacchione et al. 2005; Sen 2013) and does not always correlate well spatially with subsidence, a surface expression of extraction at depth."

Jan 1, 2015

By Arthur J. Hudson, Lawrence W. Scott

The performance of RETIMET metal foam as a flame arrester on explosion-proof enclosures was investigated by the U.S. Bureau of Mines both in laboratory tests and at the U.S. Mine Safety and Health Administration's (MSHA's) Approval and Certification Center, Triadelphia, WV. The objective of this research was to develop a permissible pressure vent for use on lightweight, vented, explosion- proof enclosures. In laboratory tests, four grades of RETIMET, a stainless steel foam material, were evaluated: (1) 45 NC-7, (2) 45 NC-13, (3) 80 NC-7, and (4) 80 NC-13. Explosive gas mixtures were prepared by a dynamic flow system. Ignition was by a low-voltage arc. Each grade of RETIMET metal foam successfully arrested the flame front in all methane-air tests. To evaluate RETIMET metal foam on large, commercial size enclosures, a multicompartmented enclosure was designed and tested in MSHA's explosion gallery in Triadelphia, WV. Extensive explosion testing revealed that a minimum vent-area-to-enclosure-volume ratio of 11.33 in2/ft3 is required to keep internal pressure rises below 3 psig. The RETIMET metal foam functioned satisfactorily in all tests as evidenced by the absence of external ignitions.

Jan 1, 1992

By F. Ebbutt

The copper-bearing waters now treated successfully at Britannia for the recovery of their copper content are almost entirely derived from what is known as the Fairview mine; this was the first extensive copper producer of the Britannia ore-bodies, and consisted of a number of almost parallel veins, carrying good copper values, the ore consisting of chalcopyrite and pyrite in a quartz gangue. These veins occur in what is known as the ?Britannia shear zone' (Schofield, S. J., G.S.C. Sum. Rept., 1918, Pt. B), developed for roughly five miles in a roof-pendant in the well-known Coast Range batholith. This .pendant is made up of Palxozoic rocks known as the 'Britannia Formation' (LeRoy, O.E., Portion of Main Coast of B.C. and Adjacent Islands; G.S.C. Memoir No. 996, 1908). These consist of dark carbonaceous slates, quartzites; and tuffs or basic flows, and within them are large quartz porphyry siJls. These Britannia rocks are sheared and altered, the resultant rock being a fissile quartz-sericite or quartz-chlorite schist. The mineralization invariably occurs in this chlorite schist, which in the more productive areas has mottles or blobs of chlorite developed. A narrow, though persistent, band of grey slate forms the footwall of the productive portions of the shear zone.

Jan 1, 1928

By Maria I. De Rosa

The major fire and fire injury findings for all metal/nonmetal mining categories for 1990-2001 are shown in tables 64-65. Table 66, partly illustrated in figure 22, shows the number of fires, fire injuries, fire fatalities, risk rates, employees' working hours, and lost workdays for all metal/nonmetal mining categories by time period. For all metal/nonmetal operations (including stone and sand and gravel), a total of 518 fires occurred during 1990-2001; 296 of those fires caused 308 injuries and 4 fatalities (Ewhr = 4,012 x 106 hr, In = 0.015, LWD = 36,204). Thirty fires and 26 injuries involved contractors. The greatest number of fires and fire injuries occurred at surface operations; the highest risk rate values were also calculated for surface operations. The number of fires increased during the first four 2-year time periods (1990-1991, 1992-1993, 1994-1995, and 1996-1997), then decreased during the last two periods (1998-1999 and 2000-2001). The number of injuries showed a decrease throughout the periods, accompanied by an increase in employees' working hours. Twenty-five firefighting interventions by mine rescue teams in underground mines and at least 30 interventions at surface operations were required to combat these fires. However, 45 fires destroyed or heavily damaged facilities and equipment (including 19 pieces of mobile equipment) because of failure of firefighting methods, late fire detection, undetected fires, or fire size. Ninety-seven fires were detected late, and 30 fires were undetected. The ignition sources that caused the greatest number of fires were flame cutting/welding spark/slag/flame (169 fires or 33% with 137 injuries), hydraulic fluid/fuel sprayed onto equipment hot surfaces (89 fires or 17% with 46 injuries and 3 fatalities), heat source/explosion and flammable liquids/ gas/refueling fuel on hot surfaces (98 fires or 19% with 73 injuries), electrical short/arcing (51 fires or 10% with 16 injuries), and spontaneous combustion/hot material (46 fires or 9% with 17 injuries). The flame cutting/welding spark/slag/flame source caused fires usually involving welders' clothing or oxyfuel/grease and other materials (including chute and dust collector liners, flammable liquids, belt material, crusher, hopper and shaker deck materials, washer plants, equipment mechanical components, stampler breaker, hydraulic fluid, rubber tires and hoses, gear boxes, bin feeder, dump rope cables, screen liner and screen panel, kiln and shaft material, pipelines, liquor pumps, wood pallets, electrical junction boxes, handrails, grease, refuse, shop and wood). The spontaneous combustion/hot material and electrical fires were usually detected late due to lack of combustion gas/smoke detection systems. At least 55 of the 89 mobile equipment hydraulic fluid/fuel fires became large fires (requiring 12 mine rescue team interventions in underground

Jan 1, 2004

By Rogerio Martelli

Os mancais de rolamento dos rolos secadores da linha de estanhamento eletrolítico da CSN são expostos a severa contaminação por água e ácido sulfúrico. O tempo médio entre falhas (MTBF) de cada rolamento da linha é de apenas 30 dias. A CSN aceitou realização de teste com um par de rolamentos autocompensadores de rolos vedados que foram montados em um rolo, com a supervisão da SKF. Os rolamentos do teste operaram por mais de 150 dias, apresentando sobrevida superior a 400% até o momento, sendo que ainda continuam em operação. Há cerca de 60 rolamentos operando simultaneamente na linha, sendo que a solução poderá ser replicada para os demais pontos, aumentando a vida em serviço dos rolamentos e reduzindo custos de manutenção.

Oct 30, 2017

By G. H. Lair, B. J. Langford, S. H. Rockwood

Volumetric reservoir analysis is dependent upon a firm relationship between porosity, connate water, and net pay. Capillary presswe data on core samples interrelate these three factors. It is shown that other reservoir problems may be resolved: (I) whether water production is indigenous or extraneous to the oil producing interval, (2) an oil-water contact is being approached, and (3) whether the oil-water contact is remotely situated. INTRODUCTION Volumetric analysis of carbonate reservoirs challenges the ingenuity of the reservoir engineer due to an absence of data on the minimum oil-bearing and oil-producing pores of a given reservoir rock. Many studies with this as the ultimate objective are available on the physical characteristics and fluid-flow behaviors of the carbonate reservoir. Some of these publications are: Hassler, Brunner and Deahl's1 study of the role of capillarity in oil production; Jan Law's' and A. C. Bulnes3 statistical treatment of core analysis data; Chalkley's method4,5 or estimating specific surface areas and porosity; Walter Rose's9 report on porosity, reserves, and recovery; Archie's78 tex-tural classification of carbonate rocks; Stewart and Spurlock's9 large core analysis; Purcell'sl0 mercury injection method in studying capillary pressure phenomena; Stewart, Craig, and Morse's" model multiple-phase flow test in investigating the relative permeability effect; and Fatt's12 illumi-nating network model of porous me-dia. The present study shows that the static reservoir parameters of porosity, connate water, and net productive thickness may be interrelated by utilizing a statistical arrangement of mercury capillary pressure data in addition to routine core analysis. This report summarizes the techniques that are followed to obtain these relations which are applicable to carbonate and sandstone reservoirs that do not contain clays. Capillary pressure statistical studies may be extended to include clay-bearing rocks by utilizing water capillary pressure data. POROSITY It is necessary that the laboratory determine the porosity value that includes the pores that are filled with hydrocarbons and water in the reservoir. This is the reservoir's total porosity. When true total porosity values are not available, correlations between porosity and capillary pressure characteristics lose their significance since they cannot be related through oil-base mud core data to the porosity and connate water values found in reservoirs. Methods used to obtain reliable porosity data will not be discussed; however, care should be exercised in selecting samples for measurement. In homogeneously porous formations, small core plugs sampled frequently will furnish adequate information. Where heterogeneity, particularly vugginess, is present, large-core porosity data may be required; in such reservoirs a suite of capillary pressure samples may be selected from small plugs. CAPILLARY PRESSURE Capillary pressure data provide a method for relating two carbonate reservoir parameters, porosity and connate water saturation, which in turn permit delineation of productive rock types necessary for selecting the third parameter, productive thickness. Specific applications of capillary pressure data to petroleum reservoirs were suggested by Archie8 and Pur-cell."' Their work demonstrated that in preferentially water-wet rock, porc

Jan 1, 1958

By G. St. J. Perrott

AN explosive of, balanced composition might be expected, on first consideration, to develop maximum propulsive strength.1 This hypothesis is based on the assumption that an excess of oxygen would act simply as an inert material with a consequent lowering of flame temperature, also that a deficiency of oxygen would tend toward incomplete reaction of the combustible materials, thereby preventing development of the full strength of the explosion. Actually, however, it can be shown both theoretically and experimentally that an explosive having a certain oxygen deficiency will develop the greatest propulsive strength. This fact has been known to the technical staffs of explosives manufacturers for many years, but it has not always been recognized by explosives engineers in the field. For example: There: is a fairly widespread opinion that the wrapper of a stick of dynamite is merely a container for the explosive and that it plays little if any part in the development of propulsive strength. Actually, it can be shown that the wrapper enters fairly completely into, the explosive reaction. In the case of most gelatin dynamites, a given weight of explosive from which the wrappers have been removed will develop considerably less strength than the same weight of explosive plus wrapper, in spite of the fact that the latter combination contains less weight of the actual explosive ingredient. It can also be shown that a cartridge 7/8 in. in diameter may be stronger, weight for

Jan 1, 1928

By H. Kolcz, G. S. Dobby, R. Stratton-Crawley, S. W. Wilson

"The Matte Separation plant at Inco's Copper Cliff Smelter Complex is described. The continuing implementation of flotation column technology in the flowsheet in various applications is reviewed. Comparative studies on 0.038, 0.10, 1.1 and 1.8 m diameter columns have been carried out. It was demonstrated that consistent metallurgical performance was obtained with both pilot- and plant-scale units. Grade-recovery relationships for plant columns can be predicted with confidence from data obtained from test equipment. The work indicates further areas of the flowsheet in which columns present an attractive alternative to conventional cells. INCO’s MATTE SEPARATION PROCESSNickel concentrate from Inco’s Sudbury area mills has been processed in the Copper Cliff smelter for sixty years. Prior to that, Sudbury ores had been smelted directly. Historically, copper-nickel separation from smelter converter matte was achieved by the classical Orford process. In the mid-1940s Inco developed an improved separation scheme based on mineral processing methods, the Matte Separation Process. A generalized Copper Cliff Smelter Complex flowsheet is shown in Figure 1.Iron sulfide and gangue contained in the nickel concentrate are rejected in the smelting-converting process. The molten product, typically containing 50% Ni, 25% CU and 22% s, is cast at about 1000 ºC, into floor moulds and allowed to slowly cool for four days. During this period nickel sulfide (heazlewoodite, Ni,S,), copper sulfide (chalcocite, cu,S) and a copper-nickel metallic alloy precipitate and form a coarse grain structure that is amenable to separation by physical means. The phase chemistry of this system has been described previously by Sproule et al (1). This matte then becomes the feed to the Matte Separation Process.A simplified block flowsheet of the Matte Separation Process is shown in Figure 2. Matte ingots, typically weighing 20 tonnes each, are broken and crushed in a three stage crushing plant to approximately minus 0.01 m and conveyed to the Matte Separation building. Grinding is carried out in two parallel circuits each consisting of a rod and ball mill in series producing a flotation feed which is 65% minus 44 microns. Typical throughput of each grinding circuit is 650 tonnes/day. The metallic fraction of the feed is recovered by magnetic separation. This product, containing about 66% Ni and 15% CU, is a major component of the feed to the Copper Cliff Nickel Refinery."

Jan 1, 1990

By J. L. Eakin

The works and opinions of experts on well stimulation and related problems are summarized in this paper. The material is devoted to stimulative work in petroleum and natural-gas wells exclusive of the generally applied pressure maintenance and secondary-recovery methods. Its purpose is to review a collection of recent and available material on well-stimulation methods and techniques. Each separate discussion is accompanied by a selected bibliography. An author index is included.

Jan 1, 1964