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By A. J. Kraemer

The twenty-fourth of a series of semiannual surveys pertaining to motor gasoline marketed in the United States was made by the Bureau of Mines in August, 1931. The first part of a report giving the results of that survey as they pertain to specification data is given in this paper. A companion report, Part II, is in preparation and will discuss the results of other determinations made on the samples, including octane number ratings on the individual samples (to be made by the Bureau of Standards) and results of the determination of gravity, color, doctor test, and "gum" content by the copper dish method and the Bureau of Mines steam-oven method. The retail price and the tax at the time each sample was taken will also be reported.

Jan 1, 1932

By Lee H. G, Li H, Hayes P

Slag from the smelting of lead can contain up to 20 per cent zinc as an oxide. An understanding of the lead smelting process and of the subsequent fuming process for the recovery of zinc is enhanced by a knowledge of the activity coefficient behaviour of zinc oxide in smelting slags. The literature presents a wide range of contradictory values. This paper critically reviews the published data and outlines new measurements being made by the authors. A consistent set of zinc oxide activity coefficient data is presented for liquid slags within the ZnO-'FeO'-CaO-A1203-SiO2 system, through a combination of present and previous measurements.

Jan 1, 1993

By C. F. Jr. Park

HOG MOUNTAIN is in the north central part of Tallapoosa County, Alabama, about 13 miles northeast from Alexander City. The Hog Mountain Mining and Milling Co. controls 1658 acres of land and is the only company operating in the district. The principal mine workings are in sections 10 and 15, T.24N., R.22E. The region has been visited by geologists many times, has been briefly described in several papers,1 and mentioned in many others. No detailed map of the mine or vicinity has been published. The field work for this report was started in March, 1934, as part of the Public Works reemployment program. About a month and a half was spent mapping both the surface and underground geology. The mine owners and operators have cooperated in every way possible to facilitate the work. N. 0. Johnson, the mine engineer, E. W. Ells-worth, J. E. McCoy and J. G. Englebert have acted as assistants for part of the work. The University of Alabama and the State Geologist's office have aided materially by permitting free use of their libraries and laboratory equipment.

Jan 1, 1935

Jan 1, 1923

By Partridge A. C

Pinched Sluices, in a variety of guises, are used extensively for the separation of minerals according to density. In the authors' work a pilot-scale sluice has been constructed with provision for splitting the discharge stream into a number of layers. The composition and flowrate of the stream can thus be analysed as a function of depth and the results presented graphically. The effects of such parameters as total flowrate, pulp composition and particle size on overall performance can be clearly seen from such data.

Jan 1, 1979

By C. A. Morais

The present work describes the development of an efficient and relatively simple process to obtain high grade CeO2 from a mixed rare earth chloride solution. The process involves cerium oxidation and precipitation by addition of a KMnO4-NaCO3 solution. The experiments were carried out at room temperature (25 1° C). The results indicated that the major parameters affecting cerium recovery are the molar ratio of KMnO4/Ce, the initial acidity of the chloride feed solution and final pH of Ce(OH)4 precipitation. In strong acid solutions (pH < 1), the oxidation of Cl to Clo took place in addition to the oxidation of Ce(III) to Ce(IV), so increasing the permanganate consumption. Conversely, low acidity (pH >3) led to coprecipitation of the other rare earth elements. Under the selected conditions, cerium was selectively precipitated as ceric hydroxide, together with some manganese dioxide. Further purification was carried out by the dissolution of Ce(OH)4 in HCl, followed by precipitation as cerium carbonate. The filtrate was neutralised with a Na2CO3 solution in order to recover the associated rare earth elements for further separation. The final product, assaying 99.7 % CeO2, was obtained with a recovery of nearly 100%.

Jan 1, 2003

By C. L. Schneider

The problem of predicting the liberation spectra produced by a closed continuous grinding circuit is of fundamental importance for the design, optimization and control of most operations in an ore dressing plant. The only known approach through which such a calculation can be performed is the population balance model equation. The latest and certainly most significant progress made in this area is the solution proposed by King (1990), which requires one textural parameter that can be measured directly from the ore being studied. The main advantage of King&apos;s solution is that it does not require the estimation of hundreds of arbitrary parameters that cannot be independently measured, as required by the existing conventional solutions. However, King&apos;s solution relies heavily on a knowledge of the detailed internal structure of the Andrews-Milm diagram (Andrews and Mika, 1975). This has never been measured for any ore. The characterization of the internal structure of the Andrews-Mika diagram requires the measurement of the liberation spectra at several progeny sizes produced by the breakage of monosize, monograde particles at several different grades. In this paper, a procedure based on magnetic fluid fractionation for generating seven narrow-size, narrow-grade samples is presented. Each of these samples was then broken into six progeny size classes in an ultrasonic mill. The one-dimensional liberation spectra of each of the 42 progeny and seven parent particle samples were then measured by image analysis. The measured linear-grade distributions are presented in this paper. The calculation of the correspondent volumetric-grade distributions is discussed.

Jan 1, 1994

Heavy media separation serves to upgrade mill feed and reduce unit operating costs, allowing ores to be mined which could other wise be uneconomic. At the Aberfoyle mine at Rossarden in north-east Tasmania, a simple heavy media operation using a converted Akins screw classifier as a separating vessel, removes barren quartz from mineralised material. At the Cleveland mine at Luina on the west coast of Tasmania a more complex ore mix requires a versatile operation combining hydro-dynamic and static separation equipment to provide an efficient beneficiation circuit. The two operations are briefly described with a background of basic heavy media separ- ation practice.

Jan 1, 1978

By V. E. Edlund

Pyrometallurgical studies by the Bureau of Mines demonstrated the feasibllity of sintering and smelting a low-grade flotation concentrate made by pilot-plant processing 10-percent manganese ore from the Maggie Canyon deposit, Mohave County, Ariz. Under optimum conditions 85 percent of the manganese in a flotation concentrate that assayed 36 percent manganese was recovered as standard ferromanganese. A blend of this flotation concentrate with high-grade dithionate pilot plant precipitate was similarly processed with a recovery of 90 percent of the manganese. Thorough mixing and pelletizing of the charge before treatment on the sinter hearth was necessary to produce a well agglomerated product by single pass sintering. Although satisfactory sinter was produced from a variety of material combinations, best results were obtained on a charge that contained 80 percent flotation concentrate and 20 percent return sinter fines. This combination was mixed with 6 percent coke, based on weight of concentrate; and 12 percent moisture. Sintering such a charge yielded a well agglomerated product containing over 80 percent coarse material, The results of standard crushing tests showed that the product was physically comparable to iron ore sinters and manganese nodules.

Jan 1, 1962

Controlled recirculation of nine ventila- tion air is becoming an acceptable practice world-wide. A brief review of operating and planned schemes is given which illustrates the various purposes for using controlled recircu- lation in different types of mines. A de- tailed description is given of the operating and proposed schemes on South African gold mines. This is followed by a description of some theoretical and experimental work which has recently been carried out into certain important aspects of controlled recircula- tion. This includes: safety systems, dust filtration, blast contaminant removal, radia- tion hazards and the development of an expert computer program for the design of controlled recirculation systems.

Jan 1, 1988

By Vladislava A. Ignatkina, Fillip O. Milovich, Vladimir A. Bocharov

"Complex research of flotation concentrates of monomineral fractions of chalcopyrite, sphalerite, galena, pyrite, pyrrhotite included methods of adsorption of collectors, surface compounds by IR ATR, and surface films of flotoreagents by TEM. They revealed that the proportion of the parts of thionocarbamate (TC) and dithiophosphate had an effect on the adsorption rate of the components of minerals, on the presence of characteristic bands, and, what is an important, visualized surface film of organic flotation reagents on the particles of concentrates by TEM. The predominance of thionocarbamate in a composition selectively increases the adsorption rate constant of the components and recovery of chalcopyrite compared with sphalerite and galena. The highest flotation rate using TC is characteristic for chalcopyrite (0.62 min- 1) in case of individual use, and it's in combination with butyl xanthate (25% butyl xanthate or 3:1) 0.89 min-1 too. We studied the ternary blend - dithiophosphate: thionocarbamates: butyl xanthate. The increase of the proportion of butyl xanthate in combination reduces the contrast of the flotation rate among all sulfides.Practice flotation of refractory sulfide copper-zinc ores of the Urals (content sulfide iron - 75- 95%) confirmed that the use of a combination of selective collectors increases selective recovery of copper sulfide minerals up to 50% at the first fraction that is the conditioned copper concentrate. New selective sulfhydryl collectors resulted in high levels of recovery of copper into a concentrate - more than 90% - against 70-72% (butyl xanthate) from copper-pyrite ore. Low floatability of iron sulfides has been obtained by selective sulfhydryl collectors. Using weak selective sulfhydryl collectors can reduce pH into collective or selective flotation from pH 10-10.5 to pH = 7.2-7.5, which improves the quality of individual concentrates of nonferrous metals and their recovery. The same is true for polymetalic sulfide ore. The volume of gold recovery also increased."

Jan 1, 2016

By Joseph E. Matta

The Bureau of Mines conducted a field study to investigate thin suppression of respirable dust by water sprays on a continuous-mining machine. Determining the importance of the top and bottom sprays for two types of spray nozzles was emphasized. Results showed, at a 90-pct confidence level, that (1) at least 70 pct of the dust was generated during the sump cut, even though nearly half of the coal was mined during the downshear operation, (2) the water sprays on the top of the boom had little effect in suppressing respirable dust, and (3) B.D. 5 spray nozzles mounted beneath the boom reduced dust at least 33 pet more than B.D. 5 sprays mounted on top of the boom. A single-cut technique was developed that gave good reproducibility for replicate cuts (coefficient of variation of 20 pct).

Jan 1, 1976

By R. V. Mrazek, F. E. Block, S. B. Knapp

The mixed homogeneous and heterogeneous kinetics of the thermal decomposition of tungsten hexacarbonyl were studied by employing a batch reactor. The system was such that a sample of tungsten hexacarbonyl could be injected into the preheated reactor, and the progress of the reaction followed by a simple pressure measurement. Both the homogeneous and heterogeneous reactions were found to be first order, and approximate activation energies were determined for each reaction. It is shown that the dis-proportionation of carbon monoxide to give carbon and carbon dioxide cannot be the source of carbon in tungsten deposits prepared by this reaction. The kinetics of the thermal decomposition of tungsten hexacarbonyl have been investigated as part of a continuing study by the U.S. Bureau of Mines on the decomposition of organometallic compounds. Reactions involving the thermal decomposition of metal carbonyls have a potential application in the preparation of pure metals and fine metal powders. Indeed, it was these applications which provided the impetus for much of the early work involving the carbonyls of nickel1 and iron.&apos; The relative lack of study of other metal carbonyls can be traced to the comparative difficulty in synthesizing these compounds. The most common use for tungsten hexacarbonyl has been as an intermediate in vapor-phase plating.7&apos;8 However, attempts to obtain a carbon-free deposit of tungsten by this method have not been successful, and some investigators have taken advantage of the carbon contamination and used this process to form tungsten carbide deposits.lo Other investigators have studied the thermodynamic properties11"14 and molecular structure of tungsten hexacarbonyl. However, very little is known about the kinetics of this thermal decomposition, the mechanisms involved," or the source of carbon in the resulting plate. In contrast, studies have been made of the kinetics of the thermal decomposition of nickel tetracarbonyl, iron pentacarbonyl, and molybdenum hexacarbonyl.&apos;l It has been found that these thermal decompositions occur by a mechanism which is partially heterogeneous in nature. Information available on the equilibrium constants for the decomposition of tungsten hexacarbonyl was used to determine a temperature range, 500" to 560°K, in which the reaction could be expected to be essentially complete. APPARATUS The apparatus used allowed the injection of a sample of tungsten hexacarbonyl into a preheated batch reactor and the use of a simple pressure measurement to follow the progress of the reaction in the sealed reactor. The pressure was sensed by means of a pressure transducer (Consolidated Electrodynamics Corp., 0.3 pct)* capable of operating at the *Reference to specific products is made to facilitate understanding and does not imply endorsement of such brands by the Bureau of Mines._______ reaction temperature. This type of sensing element was chosen to avoid the problem of condensation of the sublimed carbonyl in the capillary tubing leading to any type of remote pressure-sensing device. stirring was provided by rotating the entire apparatus. Glass beads placed in the reactor provided a pulsating agitation. To minimize thermal gradients in the reactor walls, the reactor was constructed of aluminum. The support tube which held the reactor in the furnace was thin-walled stainless steel to minimize heat conduction out of the reactor. As a result of these measures, a nearly uniform temperature (°C) was maintained throughout the reactor. Fig. 1 is a schematic diagram of the apparatus. The small gear motor rotated the entire apparatus at about 200 rpm. The bearings shown at the ends of the air cylinder were perforated to allow air to be fed to the charging piston and to allow inert gas to be fed to the reactor during the preheating period. The sample was simultaneously injected and sealed inside the reactor by operation of the air piston. Fig. 2 shows a cross section of the air cylinder and the adjoining portion of the support tube leading to the reactor. The sample carrier is shown in place at the right-hand end of the injection rod extending from the air piston. The piston is shown in the retracted position, as it would be prior to the start of an experiment. The small Teflon gasket which encircled the sample carrier at the end of the injection rod sealed the reactor when the sample was injected. This seal was maintained throughout the test by maintaining air pressure on the piston. The sample carrier was a 2-in. section of thin-walled, -in.-diam nickel tubing with an internal blank about 1 in. from the base and with the base end sealed.

Jan 1, 1969

By Krishna Nand

For assessing the safety of structures during underground explosions, ground particle velocity gives the best damage criteria, and 100 mm/see of ground particle velocity has been internationally accepted as the threshold value of safety (no damage). Results of extensive controlled underground explosion experiments conducted by the author to study the effects of ground vibrations on specially prepared concrete blocks, and also on low rise buildings and dams showed that no damage normally occurred when ground particle velocities were less than 100 mm/sec. Analysis of a large number of accelerograms from a dam site in India also indicated that no damage occurred to normal structures when integrated ground particle velocities were less than 100 mm/sec. Major damage in well built structures like a dam was noticed for ground particle velocity as high as about 350 mm/sec. These results are also generally substantiated from damage data obtained for various structures during other earthquakes, including Elcentro (1940), Taft (1952), Parkfield (1965), and San Fernando (1971). These studies, therefore, suggest that the damage criteria during underground explosions and earthquakes are similar; and 100 mm/see of ground particle velocity seems to be the general threshold value of safety (no damage) against ground vibrations.

Jan 1, 1988

By Jheison Lopes dos Santos

Neste trabalho, pela primeira vez, o sistema cerâmico Al2O3-Nb2O5-LiF teve suas propriedades mecânicas investigadas. Foram investigadas diferentes composições, em peso, para o composto (Al2O3–4%Nb2O5)–nLiF, com n variando entre 0 e 1,50%, a três temperaturas de sinterização diferentes (1300, 1350 e 1400 ºC). Como caracterização mecânica, avaliou-se a microdureza Vickers para todas as composições. A adição de LiF que apresentou os maiores valores de densificação teve seus módulos de Young e de cisalhamento, e as velocidades de ondas elásticas determinadas. Os resultados mostraram que todas as adições de LiF elevaram a microdureza do composto Al2O3–4%Nb2O5. Este fato pode estar relacionado com a densificação e fases obtidas após a sinterização. A adição de 0,5% de LiF ao composto cerâmico Al2O3-4% Nb2O5, promovendo maior densificação, quando sinterizado a 1300 ºC obteve valores de propriedades elásticas comparáveis aos obtidos por Al2O3–4%Nb2O5 sem LiF, sinterizado a 1400 ºC. Os resultados relevaram ainda uma coerente correlação entre dureza, módulo de elasticidade e densificação. Dessa forma, a adição de fluoreto de lítio ao sistema cerâmico alumina-nióbia possibilitou a redução em pelo menos 100 ºC na temperatura de sinterização, com propriedades mecânicas comparáveis.

Oct 30, 2017

By M. M. Fine

A laboratory mineral-dressing investigation of manganese ore from the Martin mine, Independence County, Ark., succeeded in recovering ferrograde manganese products. Sintered flotation concentrates analyzing 40.7 and 41.4 percent manganese at overall recoveries of 54.6 and 47.7 percent, respectively, were produced from preconcentrated feed, Preconcentration of the ore for flotation included treatment by magnetic separation and by a combination of magnetic separation and heavy-medium processing. The mineral-dressing study of the Martin mine rhodochrosite ore was part of a general program of the Bureau of Mines to develop domestic sources of strategic minerals, including manganese. Several such potential sources of manganese exist in the Batesville, Ark., district, one of which is represented by the Martin mine. Although the Martin mine area has not been delimited with respect to total reserve tonnage, it is considered to be one of the more important occurrences of manganese in the district. It is estimated that several 100,000 tons of manganese carbonate ore are present in this and similar properties.

Jan 1, 1954

By E. J. Roberts, E. B. Fitch

THE mechanism of classification by settling pools is most simply shown in the case of batch sedimentation such as was analyzed by Oden.1 The batch model will be considered, therefore, and it will be shown that the same mechanism applies to continuous operation. Classification in Batch Settling Pools: Consider a beaker or tank of slurry containing particles so dispersed that they can settle independently of one another under the influence of gravity. Originally all particle sizes are uniformly distributed throughout the suspension. All particles start immediately to settle towards the bottom at rates determined by their size, shape, and density—among other factors. Particles reaching the bottom settle out of suspension. After some given time the slurry above the deposited solids is siphoned off or otherwise removed, leaving the deposited solids behind. The deposited solids, together with entrained and any unremoved supernatant slurry, represent the underflow of a classifier. The slurry removed represents the overflow. There is a certain separation, size of particle which during the sedimentation has just time to settle from the top surface of the slurry to the level at which underflow and overflow are parted. All particles with a faster settling rate will have dropped to below this level, no matter where in the beaker they started from originally, and therefore will be absent from the overflow. Particles with a slower settling rate will not reach this level if they started from the top of the slurry, but a portion of them,

Jan 1, 1957

By G. G. Campbell

"HistoricalBARYTES was mined in Nova Scotia as early as 1874 from a deposit at Five Islands, on the north shore of Minas Basin. The first record of the presence of the mineral at the Walton site appears in a report by Selwyn in l893, who states: ""Barytes in considerable quantity occurs in veins in lime-stones at Walton and Pembroke"". The exact site of the present workings was marked •on a map published by Fletcher in 1905.The economic •possibilities of this deposit, however, were not recognized until 1940, at which time we were at war with Germany, who up to that time had supplied 50 per cent of the world's requirements.At that time the Nova Scotia Department of Mines, recognizing the need for certain strategic minerals, induced Canadian Industrial Minerals, Limited, to send prospectors into 'the area to look for manganese. No manganese deposits were found, but a deposit of barytes was directed to their attention, and exploration and development work on the occurrence was proceeded with.IntroductionThe south shore of Minas Basin between the Avon river at Windsor and the Stewiacke river at Maitland has long been known as a potential source of mineral wealth. It had attracted the attention of mineralogists and in the past had produced considerable tonnages of manganese ore and gypsum. Depletion of ore in surface and near surface deposits resulted in a dwindling production, until today only deposits of gypsum are worked."

Jan 1, 1952

By B. D. Nash

The Bureau of Mines continued its research into the recovery of fluorine by the phosphoric acid acidulation defluorination of phosphate rock concentrates. A small process development unit with a capacity of about 10 kilo-grams of charge per hour was operated, and concentrates from both Idaho and Florida were processed. Over 80 percent of the fluorine was evolved and recovered as a dilute fluosilicic acid solution. Phosphate extraction from the concentrates always exceeded 98 percent. The fluorine was converted to a synthetic fluorspar product (3CaFa?SiOa) suitable for use as a slag conditioner in electric furnace steelmaking operations.

Jan 1, 1977

By Keith J. Henley, Nicholas C. Clarke, Paul Sauter

A detailed investigation of the stability in cyanide solutions of native gold and gold-silver tellurides in a flotation concentrate from the Golden Mile, Kalgoorlie, has been undertaken to assess whether leaching under different conditions can be used to quantify the distribution of Au between native gold and gold-silver tellurides, as suggested by, for example, Chryssoulis and Cabri (1990). The leaching was carried out on +20 µm native gold and gold-silver tellurides separated from a high-grade flotation concentrate and then diluted with barren quartz. The material leached assayed 270 ppm Au and 118 ppm Te and the leach conditions used were:- Stage 1: Leaching in dilute cyanide (0 .1 % ) at pH 9 .5 for 24 hours to dissolve native gold but not gold-silver tel­lurides. Stage 2: Leaching the residue from Stage 1 in strong cyanide (2%) and pH 12.5 for 96 hours to dissolve gold-silver tellurides.

Jan 1, 1995