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By H. O. McDonald

The Bureau of Mines reviewed the chemical vapor deposition (CVD) literature of the group IVB, VB, and VIR elements. This review was utilized in the Bureau's research to provide erosion-, abrasion-, and corrosion-resistant coatings for valve components used in coal gasification units. This report attempts to bring together the many CVD references that have been published since 1966. Each of the group IVB, VB, and VLB metal coatings were reviewed, and some of their preparation methods, uses, and properties are given. A total of 160 references were found for the nine elements. Isotope separation, stronger steels, solar absorbers, alloys, superconductors, optical fibers, and coatings to increase the life of materials are some of the new uses for CVD.

Jan 1, 1979

By Ralph H. Cleland

Introduction The mines of northern Ontario have entered the class of deep mines. It has often been asked: How deep can operations be carried on? What will the temperature be? This paper is a résumé of a brief survey of rock temperatures made by the Ontario Department of Mines during the year 1932. Present temperatures were recorded and the geothermal gradients that now exist were determined. No alarming situations were found, but many interesting ones have been noted. Northern Ontario mines are fortunately situated as compared with most deep-level mines of the world. The mean yearly temperature, as determined from meteorological records of the Federal Department of Marine, is from 33 to 38 degrees Fahrenheit. The tables on the next page show the temperature range in and about our mining camps ( l ). As no exact figures were obtainable for Kirkland Lake, the data for Iroquois Falls, which is about 50 miles northwest, were taken as applicable there. The figures for Timmins were checked against those of Cochrane and Iroquois Falls and found to be very similar, so that the Cochrane data may be used for the Porcupine camp. The yearly mean temperature is considered to be 33.5 F.

Jan 1, 1933

By G. D. Garland

"IntroductionALTHOUGH the presence of rock salt in the Carboniferous basin of northern Nova Scotia has been known for at least one hundred and twenty years, and salt has been mined at Malagash continuously since 1919, certain characteristics of the deposits make exploration by drilling or surface examination difficult. The surface rocks of the basin are, in general, of Pennsylvanian age, while the salt occurs in the Mississippian Windsor group. The latter rocks are brought to the surface only along anticlinal folds, or as irregular fault blocks. Because of the limited areal extent of these Windsor exposures, and their complicated internal structure, geophysical surveys, especially gravimetric, can be of considerable aid in outlining the more favourable areas.The present paper describes the results of recent investigations by the Dominion Observatory, in cooperation with the Nova Scotia Department of Mines. It includes a regional study of that section of the Cumberland basin lying between Springhill and Malagash ( Figure 1), and a much more detailed survey of the immediate vicinity of the Malagash deposit itself. This deposit had been studied by Miller (6, 7) with the torsion balance nearly twenty years before, and a direct comparison between the results given by the two types of instruments is therefore possible."

Jan 1, 1955

1. Book review Economics of mineral exploration in Australia, by Brian W. Mackenzie and Michel L. Bilodeau. Australian Mineral Foundation (Private Bag 97, Glenside, South Australia 5065). 198pp. $A58. $A45 for students. Reviewer: D.G. Krige 2. Recent publications Combustion of coal liquid mixtures, by G.F. Morrison. London, lEA Coal Research, 1983, 52 pp. Hafnium: physico-chemical properties of its compounds and alloys. Vienna, International Atomic Energy Agency, 1981. 408 pp. 620 Austrian schillings. Canadian mines handbook 1984-85, edited by CD. Gardiner. Toronto, The Northern Miner, 1984. 500 pp. $24. Drilling equipment in Canadian mining and exploration- opportunities for the industry, by AJ. Jakubek. Toronto, Micromedia Limited (144 Front Street, Toronto M5J IG2, Canada), 1984. Research report 1984. Port Melbourne, Division Mineral Chemistry, Commonwealth Scientific and Industrial Research Organization, 1984. 190 pp. Surface engineering Wear is an unavoidable problem in virtually all products of the engineering industry, from the minute bearings of instruments to the cutting surfaces of earth-moving plant. Safety in mines About 50 papers will be presented at the 21st International Conference of Safety in Mines Research Institutes at Sydney from 21st to 25th October, 1985. Some 250 delegates from 30 nations are expected to attend. Professional development seminars March 18th-21st, 1985 Underground Blast-hole Mining May Ist-3rd, 1985 Mineral Processing of Gold Ores May 6th-10th, 1985 Mineral Comminution Systems May 13th-15th, 1985 Processing of Metallurgical Residues Analytical chemistry The Second Symposium on Analytical Chemistry in the Mining, Exploration and Processing of Materials is to be held in Pretoria from 15th to 19th April, 1985.

Jan 1, 1985

By C. T. Philipp

Recycling of waste is much preferred over disposal. This paper discusses the Enviroscience, Inc. (ESI) process, now being commercialized by MetWool, Inc., to recycle hazardous wastes using an extractive metallurgical process which is followed by vitrification of non-reducible metal oxides. In this process, volatile and reducible metals are reclaimed as their respective oxides and elements.

Jan 1, 1995

By S. G. Malghan

This paper describes uses of sodium sulfide in the flotation of oxide and sulfide minerals of copper, lead, and zinc. The activation and depression effects of sodium sulfide are of particular importance because of their applications with oxidized lead and copper ores. In spite of its industrial importance; however, the nature of the heterogenious reactions between sulfide ions in solution and the surface of oxidized minerals has not been fully understood. Hence, proposed mechanisms of the sulfide action in flotation, methods of measuring and monitoring of sodium sulfide in flotation pulps, and variables influencing the sulfide addition are analyzed. A review of recent studies shows that sodium sulfide addition to flotation pulps can be monitored and hence the optimum dosage controlled using the platinum and/or sulfide specific ion electrodes. The use of these electrodes for improved reproducibility of bench-scale experimental data and plant implementation of laboratory results is described.

Jan 1, 1985

By Windsor C. R, Thompson A, Bywater S

A new high tensile strength, steel cable, that may be grouted into boreholes has been developed for use as rode reinforcement. The manufacturing technique produces a birdcage pattern in which the cross section varies along the length of the cable. The load transfer from cement grouts to birdcage cables has been demonstrated in laboratory tests to be better than that of standard 15.2 mm diameter seven wire cables. The manufacturing process also allows for a wide range of capacities which may be specified by design engineers. The various birdcage cable configurations have been applied as rock reinforcement in a number of Australian underground and surface mines.

Jan 1, 1990

By Morris Muskat, J. M. McDowell

In both production and refining operations of the oil industry many processes are controlled by the gas-liquid phase relationships of the hydrocarbon mixtures of interest. The quantitative behavior of fractionating or distillation columns and stills depends on the changes in the equilibrium distributions of the hydrocarbon components between the gas and liquid phases as the pressure or temperature conditions may vary along the length of the column or as the gross operating parameters and compositions are varied. In oil producing operations the nature and amount of gas phase developed within an underground reservoir as it is being depleted and its pressure declines also involve the basic equilibrium gas-liquid phase interactions. The influence of surface conditions of temperature and pressure and various separation procedures on the nature and amount of stock tank oil and natural gas recovered from a given well stream is likewise determined by the same basic phase equilibrium characteristics of the hydrocarbon systems. Such equilibrium separation of the gas and liquid phases in a well stream is of importance both in establishing optimum separator conditions for obtaining maximum stock tank oil yields and in the general problem of crude stabilization. The phenomena involved in these problems and their quantitative aspects can, of course, be established in each individual instance by appropriate laboratory experimentation. It has been found, however, that by associating with the individual hydrocarbon components functional characteristics de- scribing their individual gas - liquid phase equilibrium behavior, the phase properties of the composite mixtures can be predicted by mathematical computation. These characteristics have been termed "equilibrium constants", or "equilibrium ratios"," and are defined by the general equation: where K, is the equilibrium ratio for the jth component, y, is the rnol fraction of that component in the gas phase, and xj is the corresponding mol fraction in the coexisting liquid phase. Considering the Kj as representing available and measurable properties of the individual components of a mixture, and as defined by Eq. (l), it is readily shown that in a coexisting gas-liquid system the rnol fraction concentrations of the individual components in the gas phase, y,, and those in the liquid phase, x,, are given by the expressions: where the nj are the corresponding rnol fraction concentrations in the composite system, and ng is the mol fraction of the whole which is in the gas phase. The basic unknown in Eq. (2) is n,: which gives the gross separation between the gas and liquid phases. This may be determined in principle by imposing the requirement that the sums of the mol fractions in both the gas and liquid phases are unity, i.e. by the equations: The solution of the equivalent Eqs. (3) lying between 0 and 1, when inserted into Eqs. (2), provides a complete description of the compositions of the coexisting gas and liquid phases. While the Eqs. (3) are essentially equivalent to polynomial equations, such transformations are of little value when dealing with multicomponent sys-

Jan 1, 1949

By J. M. McDowell, Morris Muskat

In both production and refining operations of the oil industry many processes are controlled by the gas-liquid phase relationships of the hydrocarbon mixtures of interest. The quantitative behavior of fractionating or distillation columns and stills depends on the changes in the equilibrium distributions of the hydrocarbon components between the gas and liquid phases as the pressure or temperature conditions may vary along the length of the column or as the gross operating parameters and compositions are varied. In oil producing operations the nature and amount of gas phase developed within an underground reservoir as it is being depleted and its pressure declines also involve the basic equilibrium gas-liquid phase interactions. The influence of surface conditions of temperature and pressure and various separation procedures on the nature and amount of stock tank oil and natural gas recovered from a given well stream is likewise determined by the same basic phase equilibrium characteristics of the hydrocarbon systems. Such equilibrium separation of the gas and liquid phases in a well stream is of importance both in establishing optimum separator conditions for obtaining maximum stock tank oil yields and in the general problem of crude stabilization. The phenomena involved in these problems and their quantitative aspects can, of course, be established in each individual instance by appropriate laboratory experimentation. It has been found, however, that by associating with the individual hydrocarbon components functional characteristics de- scribing their individual gas - liquid phase equilibrium behavior, the phase properties of the composite mixtures can be predicted by mathematical computation. These characteristics have been termed "equilibrium constants", or "equilibrium ratios"," and are defined by the general equation: where K, is the equilibrium ratio for the jth component, y, is the rnol fraction of that component in the gas phase, and xj is the corresponding mol fraction in the coexisting liquid phase. Considering the Kj as representing available and measurable properties of the individual components of a mixture, and as defined by Eq. (l), it is readily shown that in a coexisting gas-liquid system the rnol fraction concentrations of the individual components in the gas phase, y,, and those in the liquid phase, x,, are given by the expressions: where the nj are the corresponding rnol fraction concentrations in the composite system, and ng is the mol fraction of the whole which is in the gas phase. The basic unknown in Eq. (2) is n,: which gives the gross separation between the gas and liquid phases. This may be determined in principle by imposing the requirement that the sums of the mol fractions in both the gas and liquid phases are unity, i.e. by the equations: The solution of the equivalent Eqs. (3) lying between 0 and 1, when inserted into Eqs. (2), provides a complete description of the compositions of the coexisting gas and liquid phases. While the Eqs. (3) are essentially equivalent to polynomial equations, such transformations are of little value when dealing with multicomponent sys-

Jan 1, 1949

By I. Haskett

ABSTRACT The Redwater pool, in north-central Alberta, was discovered in October, 1948, and at the end of 1950 was about 85 per cent developed. Production is from a Devonian coral limestone reef and is found at an average depth of 3,150 feet. The pool has an estimated .productive area of 37,000 acres, and a maximum oil zone thickness of slightly over 200 feet. Wide variations exist in both type and values of porosity, with the average value determined for the reservoir being 6.16 per cent. The total stock tank oil in place is about 1.24 billion barrels. The crude has a saturation pressure of 485 psig, com-pared to the original value of 1,050 psig for the reservoir, and the principal recovery mechanism so far has been the natural water drive. Cumulative production to January 1st, 1951, has been about 15.5 million barrels. These withdrawals resulted in a reservoir pressure decline of slightly over 100 psi. Predictions of future behaviour indicate that the water drive will not be of sufficient magnitude to maintain the reservoir above saturation pressure past 1953, and that, with natural depletion, the pool will be produced largely by a solution gas drive. Pressure maintenance by water injection has been considered and the possibility of raising the pressure to the original value of 1,050 psig is also discussed. INTRODUCTION WITH the discovery of the Lewduc pool, early in 1947, the Devonian limestone became the major geological formation contributing to Western Canada's rapidly growing petroleum reserves. Redwater, discovered in October, 1948, is now the largest known Devonian pool in Canada, with a recoverable reserve estimated at approximately 500 million barrels. Until recent years, the knowledge of the nature and characteristics of this type of limestone reservoir has been comparatively limited.

Jan 1, 1951

By Enzo Palumbo, Joël P. T. Kapusta, François Larouche

In light of the rapid deployment of bottom blowing smelting in China over the last ten years, one has to wonder why it has taken the copper industry so long to adopt ultra-high oxygen enrichment via Savard-Lee type injectors. As early as 1976, Kellogg and Henderson suggested, in their landmark paper on energy usage in the copper industry, that ‘maximum use of oxygen enrichment of process air’ was one of seven ‘energy saving features’ for copper matte smelting and converting. Yet today, shrouded injection and high oxygen enrichment has not been implemented in copper bath smelting outside China and Vietnam. In this paper, the authors explore the reasons why bath smelting processes such as the Noranda Reactor and the Teniente Converter still operate around 40% oxygen enrichment, while the bottom blowing SKS/BBS process typically runs at 65 to 75% oxygen, with all three processes producing white metal. Are there fundamental metallurgical explanations for this striking difference beyond the long-standing skepticism towards high oxygen shrouded injection and its perceived high implementation cost?

Jan 1, 2015

By John M. Gallow

Discussion of the paper of JOHN M. CALLOW, presented at the New York meeting, February, 1916, and printed in Bulletin No. 108, December, 1915, pp. 2321 to 2339. R. H. RICHARDS, Boston, Mass.-I think there is one note which would be interesting to have recorded in connection with this paper, and that is another form of flotation machine. The Minerals. Separation machine has a vortex action, with a vertical shaft and a propeller. This new frother has been developed for the Copper Queen Co. at Bisbee, Ariz. It has a horizontal shaft and a paddle wheel for a frother. It has eight cells, I think, all connected underneath in one continuous tank, and the only separation of the cells is in the upper chambers where the froth is. When this paddle wheel goes around it throws out the froth and the sand goes to the bottom and drifts over from the first to the second cell, where it is paddled again, and comes out with its froth; the sand goes to the third cell where it is again beaten. In that way the sand is continually drifting toward the last cell, while each new froth remains in its own cell. You can see in the working of this machine just the same effect that you see in Callow's machine, i.e., the earlier cell has the darker or richer froth, and the latter has the lighter or poorer froth until you get to the farthest one-which has very little froth, and is very light. JOSEPH W. RICHARDS, So. Bethlehem, Pa.-Speaking from the metallurgical standpoint, it is quite desirable, in many cases, that the oil be removed from the concentrate in order to facilitate the metallurgical work, and I think attention should be directed to the desirability of removing from zinc sulphide concentrates the oil which interferes with their subsequent roasting. The value of the oil is not large; in Mr. Callow's plant, for instance, it would be $20 a day, and it may be possible that a process might be developed which, within the limits of the value of the oil, would remove it, and thus facilitate the metallurgical treatment. LEONARD WALDO, New York, ,N. Y.-The question came up about a year ago as to why-Mexican crude was not an admirable oil for flotation. I have never heard any satisfactory answer to the question. The Mexican crude has the peculiar property of comparative freedom from dangers of fire, a very great reluctance to part with its water, and a specific gravity almost identically the same as water.

Jan 5, 1916

By Roy G. Stott, John A. Johnson, Floyd G. Anderson

"This information circular discusses drilling and blasting in open-cut iron-ore mines and is one of a series of papers describing iron-ore mining practices in the Lake Superior district to aid in preventing accidents in that industry.The Lake Superior district consists of the Marquette and Menominee ranges of Michigan, the Gogebic range of Michigan and Wisconsin, and the Vermilion, Mesabi, and Cuyuna range of Minnesota. Open-cut mines produce 8o percent of the iron ore mined in the district; 98 percent of the total Lake Superior district open-cut ore is produced in Minnesota and 2 percent in Michigan. The entire Wisconsin iron-ore production is from underground nines. The Mesabi range in Minnesota produced 93 percent of the open-cut iron ore and 76 percent of the total iron ore in the district in 1947.During the 8-year period 1940-47, 619,000,000 gross tons of iron ore were shipped from mines of the district, or 85 percent of the United States output. Approximately 78,000,000 gross tons of iron ore were shipped from the mines of Minnesota, Michigan, and Wisconsin in 1947.This paper is based primarily on observations daring the period July 1947 to March 1948. Thirty-two open-cut mines were visited; 28 on the Mesabi range, 3 on the Cuyuna range, and 1 on the Marquette range. In 1947, 36,100,000 tons of iron ore was shipped from these 32 mines, or 59 percent of the open-cut ore and 46 percent of the total iron ore shipped from the district. During 1947 about 90 open-cut iron-ore mines were operating in the district, and the annual production of each ranged from 25,000 to 10,000,000 tons.Many recommendations included in this paper for improving safety and preventing injuries to employees were taken from Bureau of Mines Information Circular 7387.Data were collected under the direction of Frank E. Cash, former supervising engineer, Health and Safety Division, Bureau of Nines, Duluth, Minnesota. E. W. Felegy, mining engineer, Safety Branch, gave valuable assistance in reviewing and editing the manuscript.The authors gratefully acknowledge the information and assistance given and the numerous courtesies extended to them by officials of the following mining companies:All the Lake Superior iron ores occur in bedded formations that range from less than 100 feet to over 2,000 feet in thickness. These formations are designated by one commonly applied name, ""iron formations.""4/The Mesabi range in northern Minnesota, about 70 miles northwest of Duluth, was opened to mining in 1892; it is the largest single source of iron ore in the United States. It is 75 miles long and, because of the gentle dip of the ore formation, it ranges in width from 1-1/2 to 3 miles.5/ The ore formation, which is nearly horizontal, has a maximum thickness of about 450 feet and is covered by a glacial drift that ranges from 10 to over 100 feet in thickness. Most of the ore is near the surface and adaptable to open-cut mining."

Mar 1, 1950

By N. S. Spence

INTRODUCTION WHILE TITANIUM, the element, has been known for over 150 years, titanium, the metal, is a relative newcomer to the metallurgical and industrial scene. The reasons for this chiefly lie in the refract1Hy nature of titanium compounds; the high melting point of the metal; the great activity of elemental titanium, particularly at temperatures close to .and above the melting point; and the pronounced deleterious influence of certain impurities on its mechanical proper-ties. Early efforts at production of the metal were, consequently, either unsuccessful or resulted in products having sub-metallic properties. With the considerable improvement in equipment, materials, and skills that have developed within the past twenty-five years, later investigators have had a better opportunity to overcome some of the inherent practical obstacles and to come to grips with the essential technical problems. NATURAL ABUNDANCE OF TITANIUM Titanium is one of the most abundant metallic elements. It has been estimated (1) that titanium comp-rises about 0.65 per cent of the earth's crust, and therefore ranks fourth among the structurally useful metals in the order: aluminum, iron, magnesium, titanium. It must be appreciated that the relative abundance of the element is only a crude indication of its potential availability, since a very substantial proportion is present as a minor constituent in practically all igneous rocks. By comparison, present-day ores of titanium are relatively few and are but a minor fraction of the estimated total titanium contained in the earth' s crust.

Jan 1, 1951

By Robert W. Bruhn

State and federal regulations require that surface mine overburden be investigated in advance of mining for naturally occurring earth materials that are detrimental to animal and plant life or to uses of water. Proper identification of these toxic materials is necessary to permit development of environmentally sound reclamation programs. Intensified use of present laboratory methods to meet anticipated testing demands would be both costly and time consuming. This paper discusses the desirability of and general requirements for a geophysical system capable of locating toxic zones in the overburden of surface mineable lands of the Northern Great Plains Coal Province. The paper (1) identifies the types and character of naturally occurring overburden substances that must be investigated in advance of mining, (2) discusses the economic justification for development of a geophysical system to replace or to complement conventional laboratory test methods, and (3) discusses the potential applicability of downhole geophysical methods to overburden analysis.

Jan 1, 1981

By Frew J. A, Harris M. C, Manlapig E. V

The recovery achieved in a flotation process is a function of both the characteristics of the feed stream and the operating conditions within the flotation cell. In this paper, the flotation characteristics of the streams within the Red Dog le

Jan 1, 1997

By P. Ruz

A melt transfer ladle was 3D modeled by means of a mathematical fluid dynamics and heat transfer program. Internal temperature profiles were calculated as a time function for a normal ladle and for a pre-heated refractory lined ladle. It was shown that in a normal ladle the molten metal cools down quickly forming accretions. By using an inner lining there are practically no accretions build up within a typical time of operation. Therefore, by applying a refractory lining to a melt transfer ladle and keeping it at a moderate to high temperature it is possible to reduce cold dope circulation in the smelter.

Jan 1, 1999

By N. N. Clark

Pachuca tanks are used widely as reactors for treating gold slimes, and for alumina digestion and uranium leaching. In some designs, slurry mixing in the tank is achieved by introducing air at the base of a draft tube, which is the full height of the tank. A buoyant air-slurry mixture rises in the draft tube and is discharged at the top. The slurry flows back through the bulk of the tank volume. Little information is available to predict the relationship between slurry flow rate in the draft tube, and the volume of air added at the base of the tube. Most current designs are based on the energy balance proposed by Lamont 25 years ago. Recent two-phase flow theory is used to develop a momentum balance for the flow in the draft tube, and a new, accurate design equation is derived. Bubble slip, frictional (wall) losses, entrance losses, and acceleration effects all contribute to the pressure gradient in the draft tube. None of these factors may be neglected under typical operating conditions. The new design equation accounts for all of these factors, and finds good agreement with Lamont's experimental example. Also, the new equation demonstrates that it is uneconomical to operate the draft tube with high airflow rates.

Jan 1, 1985

Two significant TBM boreability predic- tion models are outlined. Predicted advance rates are compared with actual advance rates taken from twenty case histories. The results show that a simple low cost method that uses one machine parameter and one rock parameter compares very favourably with a high cost sophisticated method which also includes information regarding discontinuities in the rock mass. The effect of rock texture on drillability is also examined. A method of quantifying rock texture has been developed and is outlined. Experimental results show that the developed TEXTURE COEFFICIENT returns highly statisti- cally significant correlations with drilla- bility data in a wide range of rock types.

Jan 1, 1987

By C. W. Tomlinson

The analyses which have been made by the writer according to the method described below were made as part of Professor Withey's investigation of the concrete aggregates1 of Wisconsin, in the hope of throwing light on the extent and nature of the influence of the mineral-ogical constitution of aggregates upon the properties of the concrete and mortar made from them. This method was found most satisfactory after four weeks of experiment and modification. It attains an accuracy quite sufficient for the purpose of the analysis, and is fairly rapid. mineralogical analyses may be thus made at a cost considerably less than that of chemical analyses of a similar degree of completeness. The results obtained by this method should not vary in any item by more than 1 per cent. of the total weight of the sample, and may be made very much better than this by the exercise of greater care in the microscopic counting (see below). The accuracy of the hand sorting is of course dependent upon the experience and carefulness of the analyst. After a month's practice, the writer was enabled to turn out these analyses at the rate of four in 33 hr. of working time. It was found most economical to handle four samples at once. The samples analyzed weighed from 290 to 340 g. each. The same method could be applied to larger or to smaller samples, within reasonable limits. The following list covers the necessary apparatus and equipment: 1 good balance capable of weighing accurately to tenths (or, better, hun- dredths) of a gram, and of handling quantities up to 200 g. in weight. 1 Westphal balance, registering densities to two or three decimal places. 1 Meker or Bunsen burner, and gas supply. 1 nest of sieves, 10, 20, 40, and 100 meshes to the inch.

Jan 1, 1916