Search Documents

By M. Nusheh, C. Bumby, A-H. Puichaud

"Vanadium-bearing titanomagnetite ironsand deposits occur along a 480 km stretch of the west coast of New Zealand. In the present study, the leaching behaviour of NZ ironsand was investigated in hydrochloric acid (2–10 M) solution at 50–80°C for 2 h. The resulting leaching liquors exhibited Fe/V ratios in the range 150–180. The distribution of trace element contaminants between solution and solid residue was investigated, and processing conditions have been determined for rapid and efficient dissolution of Fe, Ti and V into the leaching solution. In addition, mineralogical analysis of raw ironsand and leached residues was performed in order to study the leaching mechanism. Samples were characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy (EDX), X-ray fluorescence spectroscopy, qualitative and quantitative X-ray diffraction and inductively coupled plasma mass spectrometry (ICP). Results indicate that the dominant dissolution process follows shrinking particle mechanism. However, ironsand particles containing ex-solution lamellae exhibited a different leaching behaviour compared to homogenous titanomagnetite particles.INTRODUCTION Titanomagnetite ironsand (blacksand) forms Quaternary onshore beach and dune deposits and offshore marine deposits (Figure 1) along 480 km of coastline from Kaipara Harbour south to Wanganui on the west coast of the North Island (Christie, 2016). It attracted the attention of scientists from the earliest times (Galbreath, 1998). The principal minerals in ironsand are titanomagnetite (TTM), ilmenite, quartz and ferromagnesian minerals such as augite, hornblende, diopside, and olivine with smaller amounts of rutile and apatite (Mauk, 2016).Several large ironsand deposits have been discovered and exploited since the late 1960’s. The Waikato North Head and Taharoa mines are currently operating and they have a 2015 measured resource of 400 million tonnes in total and provide over 2 million tonnes of concentrate per year by simple cost effective magnetic separation process (Christie, 2016; Christie & Brathwaite, 1997). The concentrate contains not only 7–8% TiO2 and 56–60% SFe, but also 0.3–0.6% V2O5, is both a valuable titanium mineral and a source of vanadium. All the production is used for steelmaking industries. The other potential for utilizing more of this resource without requirement of integration into an iron and steel producing plant is to develop a hydrometallurgical route with advantages of higher efficiency along with lower emissions. Currently, there is no existing commercial process capable of extracting all three of these elements as industrial-grade commodity products. Acid leaching of TTM concentrate with higher degrees of recovery and selectivity is a key step in any possible hydrometallurgical route."

Jan 1, 2017

By D. Moradkhani, S. M. Javad Koleini, M. Abdollahy, F. Soltani

"The objective of the study was to determine the type and distribution of rare earth elements (REEs) in the phosphate flotation concentrate from the Esfordi flotation plant in central Iran, in order to understand their leaching behaviour. Samples of the concentrate were prepared and analysed using XRF, XRD, ICP, and EMPA. The Ce, Nd, La, and Y contents were 5608, 2227, 1959, and 679.7 mg/kg, respectively. The main REEbearing minerals in the concentrate are fluorapatite, monazite, and xenotime. Apatite is the chief mineral of the concentrate and the ratio of apatite to monazite is greater than 60. From EMPA analysis, monazite contains a much higher proportion of REEs than apatite, but more than 50% of the REE content of the concentrate is in apatite, as this is the main mineral constituent of the concentrate. During the leaching of REEs in the phosphoric acid production process, more than 99% of the total rare earth values report to the large amounts of phosphogypsum (CaSO4·2H2O) formed during the dissolution reaction. Accordingly, two process options are suggested for treating the Esfordi concentrate. In the first option, the concentrate is treated with 98% H2SO4 at 200–300°C. After digestion and water leaching, phosphorus and REEs are precipitated out of solution. In the second option, the concentrate is treated in a pre-leach stage. The process residue from the pre-leach stage is then subjected to acid digestion at elevated temperature for phosphoric acid production.IntroductionThe rare earth elements (REEs) comprise a set of 17 chemical elements in the periodic table, specifically the 15 lanthanides plus scandium and yttrium. REEs and alloys that contain them are used in devices such as computer memory, rechargeable batteries, cell phones, catalytic converters, magnets, fluorescent lighting, and many more (Krishnamurthy and Gupta, 2004). China supplies about 94% of the REE demand, with the remaining 6% coming from Russia and Estonia, the USA, India, Malaysia, and Brazil (Zhanheng, 2011). Increased industrial development in China has prompted the Chinese government to limit annual export quotas to approximately 35 kt of rare earth oxides (REOs), while non-Chinese annual demand is expected to reach 80 kt by the year 2015. This constriction of supply is being met by the development of many new rare earth mining projects, each of which has its own unique mining and processing challenges (Jordens, Cheng, and Waters, 2013). One of these projects is the Esfordi phosphate project, which is located in Yazd Province in central Iran. The concentrate from the Esfordi flotation plant contains 1.2–1.5% REEs."

Jan 1, 2017

By Aarao de Andrade Lima

Mechanical properties typical of coal are used in the comparisons of pillar strengths based on finite elements and the empirical equations of Holland-Gaddy, Salamon-Munro, Obert¬Duvall, and Bieniawski-PSU. A correlation among the strength parameters which are employed in the empirical equations, in Mohr-Coulomb and Hoek-Brown failure criteria is established. Emphasis is given to the important distinction between the mechanical properties of small rock specimens and those related to the rock mass. An elastoplastic version of Hoek-Brown criteria has been developed and implemented in a finite elements code. The strengths calculated using the empirical equations showed a good agreement when the ratio width by height of the pillars varied from I to 8, except for Holland-Gaddy equation which exhibited lower values. Under the hypothesis of associative perfect elastoplasticity used, pillar strength calculated using Mohr¬Coulomb yield criterion became excessively high for all the models having a pillar width by height ratio above 2. The finite elements solution based on Hoek-Brown criterion predicted strengths around fifty percent larger than Bieniawski-PSU equation when the pillars width by height ration varied from 3 to 8, showing good agreement below that range. It has been concluded that, under the hypothesis of percfect plasticity, stress analysis techniques may overestimate the strength of rock structures subjected to high confining stresses.

Jan 1, 1997

By J. B. Warriner

Introduction STRIPPING is the name given to the process of removing clay, rock, or other cover from deposits of coal or ore. In this paper it is intended to cover the methods used in carrying on this operation in the anthracite coal regions of Pennsylvania. In doing this, attention will be chiefly devoted to those methods wherein practice in different sections of the region differs, or is susceptible to change or improvement, though it is intended to give as complete data as possible concerning all stages of the operation. The data from which this paper has been prepared have been collected and submitted by a committee representing the larger users of stripping methods, of which committee the writer has acted as chairman. Data and assistance have also been obtained from various mining men, engineers, contractors and manufacturers of stripping equipment, to all of whom our appreciation is clue.

Jan 1, 1917

By O. C. Baptist

The gravitational pressure gradient (GPG) in porous sandstone containing free gas was determined to define the proper GPG to use when calculating the rate of downdip flow of oil in the Sub-Scalez No, 1 sand, Elk Hills field, Naval Petroleum Reserve 1. The GPG was determined at several gas saturations using long, artificially consolidated sandstone models that were mounted vertically in some tests and horizontally, with rotation, in others. Also determined by laboratory and field tests were relative permeabilities, capillary pressure relations; critical gas saturation, water sensitivity, and depletion drive performance. The critical gas saturation in the models having an absolute permeability of 1 to 2 darcys was about 2 percent of pore volume. The GPG with the critcal gas saturation was that due to the weight of the gas-saturated oil. The GPG in the upper part of the models was reduced as gas saturation increased to a value considerably larger than the critical. The exact gas saturation at which the GPG became less than that due to the weight of the oil could not be determined but was estimated to be of the order of 10 percent of pore volume. Tests indicate that the rate of oil production is not permanently reduced by exposure of the sand to fresh water but that the rate of injection of fresh water will be considerably less than that to brine, Methods for determining the factors mentioned above are discussed.

Jan 1, 1967

Alfred Stansfield, Montreal, Canada:—In Professor Howe's paper on the position of Ae3, he shows its industrial importance in determining the temperature to which steel should be heated for " grain refining." Several years ago I carried out a research on the " burning " of steel and found that while hypo-eutectoid steel should be heated to Ae3, hyper-eutectoid steel that has been very much overheated must be reheated to the curve Sa on the carbon-iron diagram, in order to redissolve the pro-eutectoid cementite and thus to obtain recrystallization and grain-refining. This treatment was necessarily only partly successful, and I should like to ask whether the conditions of heat treatment for refining overheated high-carbon steels have been ascertained. Speaking of the &'Persistence of Solidificational Segregation " Professor Howe quotes an experiment made by Mr. Stead in which a bar of 1.2 per cent. carbon steel was immersed in a large mass of molten blast-furnace slag and allowed to cool with it. The steel was heated ; above the solidus (curve An on the carbon-iron diagram), but below the liquidus (curve AB). A drop of eutectic carbon-iron alloy, rich in carbon, had liquated out and hung below the bar. This agrees exactly with my own observations on the burning of steel, but my interpretation differs somewhat from that of Professor Howe. Professor Howe considers that the fusion of a part of the metal (rich in carbon) shows that the solidificational irregularities of composition had persisted through the rolling and heat treatment of the steel, as otherwise no part of the steel would have been sufficiently fusible to melt. It does not appear to me that such an explanation is necessary. A piece of steel represented in temperature and composition by any point within the area ABa will ultimately resolve itself into a solid phase and a liquid phase in equilibrium with each other. It may appear that if the steel were absolutely uniform no fusion could take place, but, the smallest nucleus of high-carbon, fusible alloy would ultimately bring about this separation into liquid and solid phases, by diffusion of the carbon from the solid to the liquid areas. A nucleus sufficient for the purpose might be provided by an area of pro-eutectoid cementite which had not become diffused during the

Jan 1, 1914

By Bryan J. Lane, Paul N. Worsey

The recommended maximum explosive weight for boulder blasting using internal charges is 0.1 O-kg/m” (3.5 oz./yd) (Olofsson, 1988). Normally this charge results in excessive scattering and flyrock, creating increased liability for the operator, especially in congested areas. An alternative technique using smaller explosive charges is being developed at the University of Missouri - Rolla. It is designed to reduce boulder scatter, flyrock and fumes and allows shooting in close proximity, using common blasting products.

Jan 1, 1999

By M Kongas, K Saloheimo

Concentrating lower and more variable grade ore resources to meet acceptable concentrate quality criteria requires removal of significant amount of gangue minerals. Monitoring plant feed mineralogy and concentrate by on-stream analysis has significant economic benefits in concentrate quality and recovery optimisation. There is a need to develop a sensitive slurry on-line analyser for silica, aluminium, magnesium and other light elements.On-line XRF elemental analysis technology, which is a routine practice in base metal concentrators is not able to measure lighter elements than calcium from slurry. Too much of the X-ray fluorescence signal from lighter elements is absorbed by water. The limitations in the direct measurement of silica and other light elements have restricted its use in some applications. Some light element slurry analysers have been developed based on prompt gamma neutron activation (PGNAA) method but they have not performed up to the expectations. This paper describes a new on-line elemental slurry analyser and the results of on-line laboratory tests.CITATION:Kongas, M and Saloheimo, K, 2013. Online light element slurry analysis, in Proceedings MetPlant 2013 , pp 93-101 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

By Jorge Ferrero, Andreas Raedle, Uhland Konrad, Michael Dutton, Keivan Pak Iman, Walter Trisi

Strabag, in partnership with Arup, is constructing the Advance Tunnel for the Scarborough Subway Extension (ATSSE); a project by Metrolinx and Infrastructure Ontario (Sponsors). The 10.7 m internal diameter single bore tunnel represents a significant departure from the traditional arrangement of twin subway tunnels in North America. ATSSE is the first-time steel fibers are used to solely reinforce a tunnel of this size in Eastern Canada. This paper discusses the challenges with design and acceptance of SFRC segments and the state-of-the-art numerical models employed to check the joint performance. The advance procurement approach for TBM and PCTL’s procurement to accelerate the project schedule is also presented.

Jun 13, 2023

By Scales PJ

Fatigue is the primary cause of failure of structural and mechanical components subject to dynamic loading. Recognition of this basic fact and the development of appropriate techniques and details are important in the design and repair of off highway trucks (OHTs). The frames and appendages of OHTs and other mobile plant used in the Pilbara are subject to tough operating conditions. Any fatigue-prone details quickly show up and become a maintenance liability of considerable concern. Much of this equipment is approaching the limit of its fatigue life and maintenance managers face decisions on whether to repair or replace. Even new equipment often contains some poor details which suffer distress soon after commissioning. In those cases a repair is required which will reinstate the detail to its original intended design life. Repair details must be practical and cost effective. They must also be tailored to the capability and expertise available in the field or in local manufacturers' establishments. This is particularly important where original equipment was manufactured overseas and long delivery times are involved. Lessons are drawn from components which have failed, using the evidence constructively, to provide an upgraded part or an improved substitute. With the experience now available it is relatively easy to extrapolate to cover new problem areas. This paper describes specialised techniques of mechanical fastening and detailing for low fatigue susceptibility, built up over many years of experience with OHTs and other mining plant and equipment in the Pilbara.

Jan 1, 1982

By Samuel G. Vera

INTRODUCTION The Climax Mine is a property of Climax Molybdenum Company, a division of AMAX Inc. Climax is located in the central part of the Colorado Mineral Belt on the west slope of the Tenmile Range, Lake County, Colorado at 3,425' m. above sea level. Climax Mine, the largest single producer of molybdenum in the free world, has been a cornerstone of mining in the State of Colorado for many years. Before molybdenum was known, the early hunters of gold and silver laid their hands on the outcrops of the Climax deposit and left it as low quality lead or graphite without much value. Today, 44,000 TPD of ore is extracted from the heart of Bartlett Mountain. The molybdenum, separated from the ore, is vital for mankind, being used for everything from fertilizer to fine components of aerospace ships, because of its valuable physical and chemical properties. The operations at Climax have never remained static. Constant demand for the "gray gold", and technological advancements, have converted Climax into an "open book of technology", where learning the still-hidden secrets of mining is a continuing process. (All figures related to tons are metric tons) BRIEF HISTORY The mine produced its first molybdenum ore in 1918. It was shut down in 1919, resumed production in 1924, and has been in continuous production since that time. During World War 11, a peak of 20,000 tons per day was reached, then tonnage dropped from 1945 to 1950. Since 1951, production has been in- creasing, reaching a peak of 46,000 tons per day during the month of June, 1980. Early mining used shrinkage stoping. Block caving using the grizzly system was introduced in the early 1930's. Caving methods were improved through empirical studies of rock behavior and by trial and error, evolving a very efficient mining method by the late 1940's. This form of continuous retreat panel caving, with small modifications, is still used today, and has made the Climax Mine one of the biggest underground mines in the world. The Climax Mine, synonymous with molybdenum, was essentially an underground mine until 1973 when the open pit was introduced. Since then, both mining methods have operated successfully. Current production is 60% from underground, and the remaining from the open pit. Climax has been in continuous operation for 56 years, and as of December 31, 1980, more than 386 million tons of ore have been mined. The orebody is not fully defined, and at the present mining rate, the known life span of the mine will be to the year 2020. GEOLOGY The Climax deposit is a large low-grade porphyry molybdenum deposit somewhat similar to porphyry copper deposits, with a well- mineralized quartz molybdenum stock work sys- tem. It lies within the pre-Cambrian granites and schists and the Tertiary Climax porphyry. The age of mineralization is thought to be mid-Tertiary and is characterized by fracture filling and replacement through silicification. The main economic mineral is molybdenum, with pyrite, cassiterite and wolframite as by-products. Fluorite and topaz also occur, but are not recovered at this

Jan 1, 1981

By J. E. Garlanger

Each year, Florida mines approximately 40 million tons of phosphorite, most of which is ultimately converted to various commercial fertilizers. The phosphorite is mined from within the bottom portion of the 40-to 60-ft. thick surficial aquifer, using open pit mining techniques. The ore zone or "matrix" is generally overlain by relatively permeable fine sand to silty and slightly clayey fine sand. The ore itself is highly variable in nature but, in Central Florida, typically consists of less permeable clayey phosphatic sands and sandy clays with stringers of permeable sand. The ore is much more sandy in the north Florida mining area.

Jan 1, 1990

By O. W. Ellis

Introduction During the month of September, 1928 enough money had. been promised by private individuals and corporations to comply with the Research ?Foundation Act 1928 (Chapter 57, 18 George V) of the Province of Ontario. The Ontario Research Foundation (referred to below as O.R.F.) may be said to 1iave come into being at that time. Under the terms of this Act, the Treasurer of the Province was empowered to match dollar for dollar of the sums subscribed by private .corporations and individuals up to a limit of $1,000,000. However, the response to the appeal for this by the Premier of the Province, the Honourable Mr. G. Howard Ferg uson, was so exceptional that the Act was amended in 1929 so as to empower the Treasurer to increase the maximum contribution on the part of the Province to $2,500,000. In March, 1933, the Chairman of the Foundation, Sir Joseph Flaville, Bart., was able to report that, in the interval between the Premier's appeal and December 1st, 1932, private enterprise had paid ?into the treasury of the Foundation $1,670,050, and that the Provincial Treasurer had assumed responsibility for a like sum. The endownment Fund of the Foundation was, therefore. $3,340,100. This sum was ?invested a lm~ s t entirely in Government securities, in securities guar. anteed by the Government, and in 1mmicipal securities. Sir Joseph Flavelle remarked at that time that "The payment of $1,670,050 to the Endowment of the Foundation by private persons and corporations is a somewhat remarkable performance when it is remembered that for three of the five years the business of the country has been suffering from a severe depression". Since that time it has been the consistent policy of O.R.F. to live within the income derived (1) from the investment of its Endowment Fund and (2) from fees collected for services rendered.

Jan 1, 1950

By R. E. Wade

The Butte, Anaconda & Pacific electrification is of peculiar interest, in an incidental way, to the entire mining fraternity, and especially the engineering branch, not only in this great Northwest country but throughout the entire Western mining country, which is rich in minerals and water power. It is probably fair to say that the prime object of mining and smelting engineering is to reduce the cost of production, and in the case in hand the relative location of mines and smelter brings the cost of transportation of ore to the front. While some might assign this item to the railway people, it is inseparably a part and parcel of the general scheme of the production of metal from the ore. In considering the electrification of the B., A. & P. railway the mining and smelting engineer, above all, wants to know what saving will be effected by the change in motive power. Unfortunately the new power has been in use during a very limited period and on the Smelter Hill section of the road only, and no reliable data, from actual service conditions, can be obtained until the entire electrified section has been in service for a reasonable length of time. Any remarks on this subject at the present time, therefore, must of necessity be general in nature and more or less descriptive. The railway, electrical and mining worlds and the country in general are indebted to the B., A. & P. railway for the pioneer work it is now doing, as it undoubtedly marks the beginning of the electrification, within the comparatively near future, of all transcontinental roads between the Missouri river and the Pacific coast. Together with this goes the development of an untold wealth in water power and all natural resources within the same territory. For the first time in the history of electric railway work, in this country, direct current at a potential of 2,400 volts is being used. With this potential there is a great saving in transmission of energy to the locomotives and there are only two substations, one at either end and 26 miles apart, for supplying the power for the movement of trains of heavy tonnage over the main line and for switching movements at terminal and intermediate yards, and comparatively little feeder copper is required.

Jan 1, 1914

Bigger is indeed better in today's surface mining operations. That is especially true regarding haul trucks. Building larger, "supersize" trucks, however, means designing more powerful engines and drive systems that are also more efficient and environmentally friendly. And miners are demanding that these trucks have longer service lives with minimum maintenance. So truck makers are teaming with engine manufacturers and mining customers to design these larger trucks that will ultimately lead to reduced mining costs. About 180 of those truck makers, engine designers and miners gathered in Tucson, AZ in September to discuss the state of haul trucks in today's mining environment. Haulage 2000 was sponsored by World Mining Equipment and attracted attendees from around the world. Manufacturers described the latest in haul truck advancements. These included the design of more powerful engines, improvements to mechanical and ac and dc drive systems and suggestions on how to reduce maintenance spending. Technology improvements in tires for larger struck was discussed as was the cost efficiency of new, lighter-weight bed liners. The following is a summary of a handful of the presentations.

Jan 1, 1997

By Baafi EY

Open cut mining in Australia is facing the greatest challenge in its history in attempting to compete not only with other operations internationally, but also with underground operations domestically. Most flat dip and shallow depth surface-mineable coal reserves have been depleted during the last two decades and new open cut operations must extract deeper coal deposits. As open cut coal mines move into deeper areas and the stripping ratios increase, the relative cost of overburden removal also increases. It therefore becomes even more important to design the mine around the optimum overburden removal scheme. The deeper mines are usually multi-seam operations with a more complex geology and with more geotechnical and hydrological problems. Deeper mines are subjected to greater problems requiring more detailed mine planning and design, such as selection of the optimum mining method and pit layout. In planning and design of such operations, the number of alternative methods which need to be considered is consequently greater.Dragline productivity and its stripping capabilities are directly affected by the selection of digging method, strip layout and pit geometry. Every mine has a unique combination of geological conditions. The operating methods that work well at one mine may not necessarily work at another site. Selection of an optimal stripping method, strip layout and pit geometry for a given dragline must be considered with respect to the geological conditions of the mine. With increasing geological complexity of Australian strip mines, it is becoming more important to use sophisticated techniques such as computerised mine planning methods to assist in optimising dragline operations.

Jan 1, 1998

By Reinhold A. Errath

The Antamina Concentrator plant was one of the first plants in the world, where about 60 Megawatt only in Milling Power was installed. As a consecuence of the use of Gearless Mill Drives the speed of the mills is adjustable, which allows the operators react to the different ore grades correspondingly, in order to get the best results in terms of milling efficiency. In this sense, this paper describe the basic idea of a Gearless Mill Drive, the construction of it, the manufacturing facilities, the transport, the installation and the function in detail. It gave enough insights to understand why Gearless Mill Drives are so reliable and used as an adjustable speed drive, why it counts with the highest efficiency of all drive systems.But it did describe as well the overload capabilities, the reaction to the network, the reason why the maintenance of the drive system is proven as a minor issue, and finally it was self- explaining why the Gearless Mill Drive is called a working horse.

Sep 12, 2005

By D. K. Crampton, H. l. Burghoff, J. T. Stacy

The study of copper alloys of the age-hardening type has received considerable attention, and, among the alloys which the authors have, considered, those containing small amounts of nickel and phosphorus as essential constituents seem especially interesting. Such alloys have attractively great capacity for being hardened and also have relatively high electrical and thermal conductivity in the hardened state. In addition, it has been found that the increase in hardness and strength imparted by aging can be greatly augmented by cold-working, so that excellent combinations of conductivity and strength are obtainnble. In view of the possible importance of the alloys, it was considered desirable to investigate the solubility relationships in the copper-rich portion of the copper-nickel-phosphorus system. This paper present's some of the results obtained in this investigation to date and also gives propertics of typical alloys that appear to be of commercial interest,. Review of literature Copper-nickel System,.—The binary coppcr-nickcl system has long been known to consist of a series of simple solicl solutions, copper and nickel being miscible at all tempcrat'ures and concentrations. This was establisl~cd by Guertler arid Tammannl in 1907 and confirmed by Tafel2 in 1908. Copper-phosphorus System.—The copper phosporus system has been studied by numerous investigators, so that the copper-rich portion is now definitely known. As most recently determined by Lindlief," his system has a cutectic at 8.38 per ccnt P, cuteetic temperature being 714° C. Components of the cutectic are Cu3P and alpha solid solution. Solid solubility of phosphorus in copper, according to Mertz arid Mathewson decreases from a maximum of about 1.75 per cent at 714' C. to about 0.6 per cent at 300' C.

Jan 1, 1940

By D. K. Crampton, H. l. Burghoff, J. T. Stacy

The study of copper alloys of the age-hardening type has received considerable attention, and, among the alloys which the authors have, considered, those containing small amounts of nickel and phosphorus as essential constituents seem especially interesting. Such alloys have attractively great capacity for being hardened and also have relatively high electrical and thermal conductivity in the hardened state. In addition, it has been found that the increase in hardness and strength imparted by aging can be greatly augmented by cold-working, so that excellent combinations of conductivity and strength are obtainnble. In view of the possible importance of the alloys, it was considered desirable to investigate the solubility relationships in the copper-rich portion of the copper-nickel-phosphorus system. This paper present's some of the results obtained in this investigation to date and also gives propertics of typical alloys that appear to be of commercial interest,. Review of literature Copper-nickel System,.—The binary coppcr-nickcl system has long been known to consist of a series of simple solicl solutions, copper and nickel being miscible at all tempcrat'ures and concentrations. This was establisl~cd by Guertler arid Tammannl in 1907 and confirmed by Tafel2 in 1908. Copper-phosphorus System.—The copper phosporus system has been studied by numerous investigators, so that the copper-rich portion is now definitely known. As most recently determined by Lindlief," his system has a cutectic at 8.38 per ccnt P, cuteetic temperature being 714° C. Components of the cutectic are Cu3P and alpha solid solution. Solid solubility of phosphorus in copper, according to Mertz arid Mathewson decreases from a maximum of about 1.75 per cent at 714' C. to about 0.6 per cent at 300' C.

Jan 1, 1940

By R. M. Bird

Few persons outside of the foundry trade have any conception of the great variety of sands now regularly specified and furnished, nor of the differences in foundry practice frequently resulting from apparently minor changes in sands. Conditions in each locality where the sands are mined and prepared necessitate special equipment designed to perform the work efficiently. The description that follows of the foundry-sand producing operations is typical of the areas in New York and New Jersey, and particularly refers to the operations of the George F. Pettinos Co. A few years ago the so-called Albany sands were dug by simple methods and hauled by horsecart to railroad. Depletion of sand near railroad sidings and extended use of automotive power have appreciably extended the area from which sand is now being dug. It is not unusual to haul 5 miles to the railroad. As stripping is quite shallow, 6 to 18 in., and the banks of usable sand generally run from 12 in. to 4 ft., it is economical to work the bank by benches so narrow that the overburden can be thrown by hand shovel to the exposed bottoms. In effect the top soil goes back to where it was, but on a lower level. Consequently the general surface appearance of a mined acreage is the same as before. This condition is in fact cutomarily required when a farm owner sells his sand in the ground. After such replacement, in the course of 3 to 5 years the soil is no less fertile than it was before mining. The sand itself varies as to grain and bond vertically and also along the breast. No mechanical equipment has been developed to compete with hand shovels and no machine has as yet been devised that grades the sand as required. Uniformity of sand, as shipped, depends first, last and all the time on the man on the job. Mixing equipment can change the appearance of the sand and mask its lack of uniformity, but it will never correct wrongly graded sand, dug from the bank. Modern methods of testing are helpful in setting up standards against which the man in the bank can compare his sands, but a good bank foreman is the only assurance that the sand, as dug, matches the required sample.

Jan 1, 1926