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By T. Egleston

THE direct process for the manufacture of iron which is principally used in the United States, in New York and New Jersey, is called the Jersey forge, the Champlain forge, the Catalan forge, the Bloomary forge or fire, and sometimes a Forge fire. Dr. T. Sterry Hunt, who has discussed the process as applied to the beach sands of Canada as well as to ores, in the Report of the Canadian Geological Survey for 1867-69, has shown that the name of Catalan forge is incorrect, as this process in no way resembles the Catalan, but is really the old German bloomary modified by long use in this country. Dr. Hunt gives the probable history of the introduction of the process into the United States, and a series of historic citations of great interest relating to it. Not¬withstanding the improvements which have been made in the construction of the furnace and its greater output, the process to-day, in all its essential features, is carried out as Karsten described it. It should now be known as the American Bloomary. The name of Jersey or Champlain forge or fire is not sufficiently distinctive. The name of Bloomary, by which the process is usually distinguished, is objectionable, not because it is incorrect but because it is indefinite, as the Knobbling fires, which are a very slight modification of the Walloon process, for making blooms either from pig iron or by sinking scrap, are also called Bloomaries, and although Knobbling fires are only used in a few localities where charcoal pig is made, and special grades of charcoal-refined blooms are required, one does not, without an explanation, know whether the blooms are being manufactured from ore or pig. The name Forge fire is equally indefinite, as it might just as well apply to any of the five direct methods of making blooms which have been in use in Europe, but which have now mostly gone out of date. The Dame of American Bloomary, however, is the one which most completely describes it, and is the one least open to objection. The names of German, Jersey, and Champlain bloomary are too local, and these adjectives are thought unnecessary by those who use the process, and we shall not therefore describe it under any of these names, but as the American Bloomary process. * Read at the Montreal meeting, September, 1879.

Jan 1, 1880

By T. Egleston

The direct process for the manufacture of iron which is principally used in the United States, in New York and New Jersey, is called the Jersey forge, the Champlain forge, the Catalan forge, the Bloomary forge or fire, and sometimes a Forge fire. Dr. T. Sterry Hunt, who has discussed the process as applied to the beach sands of Canada as well as to ores, in the Report of the Canadian Geological Survey for 1867-69, has shown that the name of Catalan forge is incorrect, as this process in no way resembles the Catalan, but is really the old German b1oomary modified by long use in this country. Dr. Hunt gives the probable history of the introduction of the process into the United States, and a series of historic citations of great interest relating to it. Notwithstanding the improvements which have been made in the constrnction of the furnace and its greater output, the process to-day, in all its essential features, is carried out as Karsten described it. It should now be known as the American Bloomary. The name of Jersey or Champlain forge or fire is not sufficiently distinctive. The name of Bloomary, by which the process is usually distinguished, is objectionable, not because it is incorrect but because it is indefinite, as the Knobbling fires, which are a very slight modification of the Walloon process, for making blooms either from pig iron or by sinking scrap, are also called Bloomaries, and although Knobbling fires are only used in a few localities where charcoal pig is made, and special grades of charcoal-refined blooms are required, one does not, without an explanation, know whether the blooms are being manufactured from ore or pig. The name Forge fire is equally indefinite, as it might just as well apply to any of the five direct methods of making blooms which have been in use in Europe, but which have now mostly gone out of date. The name of American Bloomary, however, is the one which most completely describes it, and is the one least open to objection. The names of' German, Jersey, and Champlain bloomary are too local, and these adjectives are thought unnecessary by those who use the process, and we shall not therefore describe it under any of these names, but as the American Bloomary process.

Jan 1, 1880

By E. N. Durussel

"The Fox Mine has been producing copper/ zinc ore since 1970 at a rate of approximately one million tons per year, and until 1978all production was derived from longhole open stopes. In June 1978, a trial stope using bighole mining methods was started to eliminate the development of two sublevels between 400 level and surface. The trial proved to be successful, and bighole mining is now an accepted mining method for both stopes and pillars at Fox Mine.When production blasting was started in the first stope, the biggest problem encountered was the production of large amounts of sulphur dioxide gas as a result of secondary sulphide dust explosions. This gas generation resulted in lost production time and caused minor damage to underground installations to the blast level, and to the headframe. Sulphur dioxide generation has been noted in secondary drawpoint blasts and, on rare occasions, in drift rounds.This paper discusses the occurrence of the sulphur blasts and the practices and precautions used to prevent their reoccurrence at Fox Mine.IntroductionThe Fox minesite is located 30 miles southwest of Lynn Lake, Manitoba. With production startup in 1970, Fox Mine is owned and operated by Sherritt Gordon Mines Limited.The Fox orebody occurs as a large lenticular zone of semi-massive sulphides approximately 1,500 feet long and 15 to 100 feet wide running east and west. Dipping 70 degrees to the north, the orebody tends to bottom out at the 3200-foot level and reaches to within 15 feet of surface."

Jan 1, 1981

By J. H. Faulk

An examination is made of the various factors influencing drilling rate and drill bit life in various diameter holes. It is concluded that drill bits in the size range 4% to 6 1/4 in. can be used to attain substantially the some daily drilling progress as conventional size bits in soft rock drilling operations. An examination of the most important factors influencing "hazard of losing the hole" in the different hole size results in the conclusion that the smaller hole sizes can probably be drilled at reasonably low risk. However, this risk will be somewhat greater in the smaller diameter holes, requiring that special drilling and mud engineering practices be used to make small diameter holes practicable in soft rock drilling operations. An engineering analysia is made of the power and hydraulic requirements of several drill string-hole combinations to test the feasibility of drilling .small diameter holes in soft rock areas. Large econormies in rig power requirements appear possible by drilling .smaller .size holes in these operations. INTRODUCTION The industry now is re-examining the utility of small diameter holes in the light of substantial technical advances made in recent years. Faced with increasing cost of finding reserves and with proration after developing them, the industry must either develop methods of economizing or receive a lower rate of return on investments. Small diameter holes appear to involve an attractive method of economizing. Our objective is to determine if this is technically possible in soft rock operations. Soft rock, as used in this report, refers to those formations of a "drill-ability" corresponding to that of all Gulf Coast formations shallower than and frequently including much of the Eocene rock system. An important phase of technology which we shall examine is relative drilling rate and bit footage which may be obtained with various size bits. Rig operating efficiency, particularly as influenced by hazard, is also discussed in detail. The technical conclusions resulting from these examinations are used to develop sample drill string design and rig horsepower requirements for drilling holes as smaH as 4 3/4 in. and larger. The principal criterion used for the drill string design is that approximately the same daily drilling progress would be possible in all size holes in soft rock operations. This facilitates a comparison of rig size required for drilling the hole sizes in the range between 4 3/4 and 8 3/4 in. BROAD PROBLEM OF DRILLING RATE AND BIT FOOTAGE The three factors controlling daily drilling progress are: (1) drilling rate of bit while on bottom turning, (2) bit footage, and (3) rig operating efficiency. Let us look now at the first two of these factors. Drilling technology has progressed to the point that a semi-quantitative analysis of the effect of various operating variables upon these factors can be made. Those factors which apparently limit both drilling rate and bit footage for bits now in use are: (1) bit design, (2) weight on bit, (3) hydraulic cleaning capacity for bit cutting surfaces and hole bottom, and (4) rotary speed. (We neglect the effect of mud and formation properties because these factors arc the same for the various size bits.

Jan 1, 1957

By Gilbert E. Doan, William C. Schulte

An extensive program of investigation is being carried out at Lehigh University in the study of arcs and arc welds of high-purity iron1, sponsored by the Engineering Foundation. The part of that program reported in the present paper deals with welds made of high-purity iron in an argon atmosphere and for comparison with them welds made of the same iron in ordinary air. Welds of commercial steel also were made in argon and in air. The primary purpose of the study is to discover the basic physical constants of iron welds when not contaminated either by impurities in the iron or by the action of oxygen and nitrogen of the air during welding. Upon these constants can be founded such future studies as will determine what effects the various impurities and alloy elements present in steel have upon its welding characteristics, and what influence is exerted by the action of oxygen and nitrogen. The welding of steel involves such a multitude of variables, both of composition and of procedure, that development in the fabrication of this most important metal has necessarily been slow, wasteful, and in many instances discouraging. In the present investigation, the simplest possible condition has been selected; namely, iron practically free from contamination and a nonparticipating atmosphere, the inert gas argon. This simplification reduces the number of variables to a point where more rigid control of the system is possible. Although this study is significant for the contributions it makes to the science of steel fabrication, yet it is hoped that it will not be without value also in increasing knowledge of the. nature and behavior of iron and steel in general. From the standpoint of open-hearth practice, and to some extent from the standpoint of electric-furnace practice also, the conditions of melting and casting iron in this investigation are extraordinary. The casting temperature is high, the mean temperature of the metal probably reaching 2000' C. (3600' F.)? The rate of chilling of

Jan 1, 1936

By William C. Schulte, Gilbert E. Doan

An extensive program of investigation is being carried out at Lehigh University in the study of arcs and arc welds of high-purity iron1, sponsored by the Engineering Foundation. The part of that program reported in the present paper deals with welds made of high-purity iron in an argon atmosphere and for comparison with them welds made of the same iron in ordinary air. Welds of commercial steel also were made in argon and in air. The primary purpose of the study is to discover the basic physical constants of iron welds when not contaminated either by impurities in the iron or by the action of oxygen and nitrogen of the air during welding. Upon these constants can be founded such future studies as will determine what effects the various impurities and alloy elements present in steel have upon its welding characteristics, and what influence is exerted by the action of oxygen and nitrogen. The welding of steel involves such a multitude of variables, both of composition and of procedure, that development in the fabrication of this most important metal has necessarily been slow, wasteful, and in many instances discouraging. In the present investigation, the simplest possible condition has been selected; namely, iron practically free from contamination and a nonparticipating atmosphere, the inert gas argon. This simplification reduces the number of variables to a point where more rigid control of the system is possible. Although this study is significant for the contributions it makes to the science of steel fabrication, yet it is hoped that it will not be without value also in increasing knowledge of the. nature and behavior of iron and steel in general. From the standpoint of open-hearth practice, and to some extent from the standpoint of electric-furnace practice also, the conditions of melting and casting iron in this investigation are extraordinary. The casting temperature is high, the mean temperature of the metal probably reaching 2000' C. (3600' F.)? The rate of chilling of

Jan 1, 1936

The brown coal resources of the Latrobe Valley, which include over thirty thousand million tons of coal suitable for open cutting, provide the main source of fuel for the power generation for the State of Victoria. They also provide the basis for the development of a supply of cheap hard fuel for industrial and domestic use, and for the development of the Lurgi process for manufacture of town gas for most of the State. The production of hard char for metallurgical processes and liquid hydro carbons will each, no doubt, play its part in the industrial growth that will be based on these resources.The State Electricity Commission of Victoria, which has been allocated the task of developing these deposits since the early 1920's, is faced with problems of economic selection of deposits for development, and excavation and transport of huge tonnages of coal and overburden-in this year, 19'59, about 12,000',000 tons of brown coal will be won, and over 7,000,000' cu. yd. of overburden will be removed in the four open cuts operated by the Commission; by 1967, eight years from now, the demand will have doubled.This paper deals with the nature and importance of various factors effecting the planning of the development of these resources. It is in essence an introduction to the papers by C. S. Gloe, H. C. G. Rodgers and J. M. Alexander, also being -presented at the Institute conference in Victoria in August, 1959.INTRODUCTIONIt is the intention in this paper to define the factors that come under consideration in the planning and development of the brown coal fields in the Latrobe Valley, whose exploitation by the State Electricity Commission of Victoria was initiated almost 40 years ago. It is proposed to enumerate, and in sorile cases evaluate, the physical and economic criteria that play their part in determining planning for the future.

Jan 1, 1960

By John Fritz

TROUGH it is not a condition of the Award, the fact is that the John Fritz Medal never has been given to an engineer who had not already received one or more similar awards. This "medal for medalists," on the evening of April 20, was presented to Daniel C. Jackling at a special dinner held at the Union League Club in New York. The citation read "For notable industrial achievement in initiating mass production of copper from low-grade ores through the application of engineering principles." The present award recognizes the same accomplishment-the launching and guiding to the port of marvelous success of the Utah Copper Co., first of the so-called "Porphyries"-as did the award of the William Lawrence Saunders Gold Medal by the A.I.M.E. in 1930, and before that the Award of the Gold Medal of the Mining and Metallurgical Society of America in 1926. Following the custom a biography of the Medalist had been published in a small pamphlet as a supplement to the John Fritz Medal Book. T. A. Rickard was the au¬thor of the sketch of Mr. Jackling, an innovation being the placing of a copy of the booklet at the place of each of the diners. The committee in charge of the dinner consisted of two past-presidents: R. E. Tally, of the A.I.M.E., who was chairman; Bancroft Gherardi, of the A.I.E.E.; and Thaddeus Merriman, director of the A. S. C. E., the John Fritz Medal being a joint award of the four societies. Frederick M. Becket, President of the A.I.M.E., as chairman for the occasion, briefly stated the purpose of the dinner. He stressed his satisfaction that the award was symbolic of the cooperative professional activities of the four great national organizations of engineers. He introduced Francis Lee Stuart, past-president of the A.S.C.E. and now chairman of the John Fritz Medal Board of Award. Mr. Stuart outlined the history and purpose of the Medal established in 1902 in memory of John Fritz, of Bethlehem, Pa., one of the great pioneers of America's iron and steel industry, metallurgist, and president of the A.I.M.E. in 1894. Mr. Stuart called the roll of former John Fritz Medalists, three of whom, Ralph Modjeski, J. Waldo Smith, and Ambrose Swasey, were present to do honor to Mr. Jackling. He then introduced George Otis Smith, whose privilege it was to present the Medalist for 1933. Dr. Smith was the senior of the four A.I.M.E. representatives on the Board that last year selected Mr. Jackling for the honor. His speech follows in full.

Jan 1, 1933

By Tugba Basargan Çagatay Morall, Gülhayat Nasun-Saygili

"The aim of this study is to prepare the apatitic material using colemanite mineral (2CaO.3B2O3.5H2O) which was obtained from Eastern Anatolia, Turkey. For this purpose, colemanite mineral was reacted with different phosphate sources, namely, dipotassiumhydrogen phosphate, ammoniumhydrogen phosphate and ortophosphoric acid at various temperatures and time periods. Experiments were run in batch system. The apatitic material was prepared by a wet method and followed by heat treatment at various temperatures. Structure of the samples was analyzed by XRD, FTIR, XRF and SEM. The particle size analysis was also made for the result product. The experiments showed that reaction temperature, contact time and heating temperature are important parameters to transform the colemanite into apatitic structure. Reaction of colemanite with dipotassiumhydrogen phosphate and ammoniumhydrogen phosphate results in amorphous, non-stoichiometric hydroxyapatite type structure, while acid based phosphate source gives brushite and monetite type product before and after heat treatment, respectively.IntroductionBoron which has properties intermediate between metals and non-metals is a member of semiconductor group of elements. Its atom is very small and has three valence electrons. Boron exists in Earth's crust (from 5 mg/kg in basalts to 100 mg/kg in shale) and in the oceans (4.5 mg/l) [1]. Turkey has 60% of world's boron reserves which is mostly in the form of colemanite (2Ca0.3B203.5H20). Colemanite is the most important calcium containing commercial borate mineral with 5 mol of crystal water [2].Calcium phosphate cements are very useful for bone repair applications because of its chemical structure. They are injectable, easy to shape and can be maintained locally. Because of those reasons calcium phosphate cements are very effective to fill bone defects with an irregular shape [3]. Hydroxyapatite (Ca10(PO)6(OHh) is the major component of the bone (70 wt%). However, hydroxyapatite stoichiometry, composition and crystallinity differ in human skeleton system [4, 5].The main objective of the present work was to study the transformation of colemanite to apatitic material using different phosphate solutions at several time spans and temperatures. The experiments were run in a batch system, change in pH and also weight loss were measured after the experiments. Several analysis methods were used to investigate the chemical and structural changes."

Jan 1, 2012

Prior to 1980 the thought of the occurrence of high-level epithermal gold mineralisation occurring in eastern Queensland would have been more of a dream than a reality. In a world-wide sense the understanding of the processes and tectonic settings for epithermal gold were only beginning to be developed. Although epithermal gold deposits had been mined in the past in Queensland the significance of these deposits in a regional sense had not been appreciated. A number of companies had made cursory examinations of epithermal regions in the Mt Coolon and Cracow regions. Since the mid 1980's the search for epithermal gold mineralization in Queensland was truly on and over 30 tonnes of gold from this style of deposit has been discovered.

Jan 1, 1989

By J. E. Burke, C. W. Mason

IN attempting to study precipitation from a tetragonal lattice using solid solutions of bismuth in tin, it was found that although a Widnmanstatten pattern is observed 1 only a qualitative analysis of the orientation relationships is possible, because of the unusual structural changes that accompany the precipitation process MICROSCOPICAL STUDIES Alloys were made from Chempur tin (Standard samples 42b and 42c, National Bureau of Standards), and bismuth (Kahlbaum C P ) by melting neighed quantities together under palm oil, stirring well, and casting in a heated graphite mold The polishing and etching techniques employed largely govern the visibility of the structural changes The preliminary surfacing operations were similar to those recommended by Villela and Bergekoff,5 through BehrManning 3/o abrasive papers, lubricated by a solution of paraffin in kerosene A rough metallographic polish was next given, using a thin cotton cloth charged with relevigated alumina (maximum particle size of about 4µ) and soap solution, repeated etching and polishing served to remove disturbed metal For high-power examination better preparation was necessary It was found that on such soft metals the threads of the fabric, rather than the abrasive, cause most of the scratching Cotton outing flannel, which had been brushed so that the nap lay down, was fairly satisfactory, but a Heavy grade of silk velvet (not the noncrushable kind) was found to be better, especially after some use A better procedure was as follows The metal lap was warmed slightly, and a 4-in circle of woolen broadcloth was cemented to its center by a thin film of melted paraffin The broadcloth was then moistened with water, and a 30 to 40 per cent solution of sodium hydroxide heated to about 50°C was poured over it, allowed to stand for 1 to 2 min and then washed off It was neither necessary nor desirable to remove all the sodium hydroxide from the cloth, since its etching action aided in the removal of the flowed layer from the sample The cloth was then charged with a paste of the relevigated alumina in water Since this lap did not remove deep scratches, it was necessary previously to polish the specimen on some material such as the silk velvet The sodium hydroxide softens and partly gelatinizes the woolen lap covering, permitting a scratch-free polish, but its action continues, and the cloth deteriorates after about 24 hr This is not serious, because a new lap can be prepared in about 5 min, and only small pieces of cloth are used Etching with a strongly acid solution of ferric chloride was found satisfactory for removing the flowed layer For the final etching, the most satisfactory reagent was that of Taffs,7 the formula for which is FeC13 6H20, 2 grams, HC1, 5 c c , H2O, 30 c c , C2H5OH (95 per cent), 60 c c This etchant reveals differences in com-

Jan 1, 1941

By L. A. Geoffrion, R. H. Perkins, J. C. Biery

Densities of cerium metal and several lour-melting binary cerium alloys were measured over the range 25° to 800°C. A rolumeter, using NaK as working fluid, was used to obtain the data. The cerium, Ce-Co, Ce-Ni, and Ce-Cu alloys all exhibited an increase in density on melting, while a Ce-Mn alloy expanded on melting. FOR the proper design of a nuclear reactor, the change in density of the fuel with temperature must be known. This is especially important in a system utilizing molten fuel, such as LAMPRE (Los Alamos Molten Plutonium Reactor Experiment), since a relatively large change in density usually occurs during the solid-liquid transition. The fuel for LAMPRE is a Pu-2.5 wt pct Fe alloy with a melting temperature of 410°C. However, limitations in reactor design with this fuel have led to consideration of other plutonium-containing alloys for use in future generations of this type of reactor. Several ternary alloys containing plutonium and cerium as two components have satisfactorily low melting points. The system that at the present time appears to be most acceptable is Pu-Ce-Co; it exhibits little change in melting temperature with wide variation in plutonium concentration. Other alloys that have received some consideration contain nickel, copper, and manganese as the third constituent. The proposed fuel alloys are difficult to handle experimentally in the 25" to 800°C temperature range since they oxidize readily, react with many solvents, and contain a poisonous fissionable material. In addition, in this temperature range the alloys pass through the solid-liquid transition. Several techniques are available for measuring the densities and volume coefficients of expansion of solids or liquids. However, the only apparatus that appears suitable for measuring expansion coefficients over this temperature range and through the phase transition is a volumeter. In a volumeter, the indicating medium must be essentially inert to and insoluble in the material being studied. It must also possess a low vapor pressure over the operating temperature range, and its coefficient of expansion must be accurately known. One material that is satisfactory in nearly all of these respects is the alloy Na-78 wt pct K, which melts at -10°C and has a vapor pressure of 860 mm Hg at 800°C. This relatively high vapor pressure at 800°C requires an overpressure of an inert gas to prevent boiling. While a volumeter is capable of determining accurately the volume coefficients of expansion of materials, it cannot be used for absolute density measurements. Therefore, a density determination at a known temperature must be coupled with the volumeter measurements to give all the desired data. The weight-loss technique using immersion in bromobenzene at room temperature proved to be satisfactory. The preliminary work that was done on this experimental program involved developing and calibrating the equipment, and measuring the densities and volume coefficients of expansion of cerium and some low-melting binary cerium alloys. The complications that are caused with the introduction of plutonium into the system were avoided until the equipment was proved to be satisfactory and until experience was gained in its operation. It is this first phase of the experimental work that is described in this report. DESCRIPTION OF EQUIPMENT AND OPERATING PROCEDURE The NaK volumeter is shown schematically in Fig. 1. Basically, the equipment consists of two weld-sealed stainless-steel containers of nearly identical volume. One container holds a tantalum crucible and the specimen being measured; the other contains a tantalum crucible and a tantalum specimen used as a control reference material. To avoid temperature gradients, the bombs are located in a copper block inside the furnace. Stainless-steel capillaries of equal length and volume connect each stainless-steel container to a glass viewing capillary. The stainless-steel containers, stainless-steel capillaries, and a portion of the glass capillaries are filled with NaK (22 wt pct Na-78 wt pct K). The NaK/gas interface in the glass capillary is viewed with a cathetometer which is accurate to *0.5 mm. The cathetometer readings are used to calculate the volume changes of the samples during a run. This volumeter is basically the same as that described by F. Knight in Plutonium 1960. 2 However, changes in equipment design and operating procedure were made to eliminate some major operating difficulties. These changes are summarized below. 1) In filling the manometer with NaK, gas was frequently entrained in the system. Evacuation of the system before filling failed to eliminate the en-

Jan 1, 1965

By Scott A

The object of most blasting operations is to destroy the insitu structure of the rock mass so that mechanical equipment can efficiently excavate the rock fragments. In achieving this objective the blasting engineer is also concerned with minimising damage to the adjacent rock which forms the mine structure relied upon to provide support. Damage to this "structural" rock is undesirable but usually occurs as a result of two distinct processes: ò readjustment of stresses around the excavation as a result of the mining process itself ò impact of vibration and high pressure gases from blasting operations. Gross damage to mine structures from either cause is observed as visible alteration to the appearance of the rock structure in the form of cracking, slabbing, back or over break and visible displacement. Recent work at the Julius Kruttschnitt Mineral Research Centre (JKMRC) has shown that significant reduction in the strength of a rock mass can take place well before the onset of these obvious signs of damage. It has been demonstrated that the effect of blast damage on the behaviour of the rock mass can be many times more prominent than the effect of stress redistribution. This offers the blast design engineer the opportunity to significantly reduce blast induced damage to rock structure by modifying blasting practices. This paper introduces the current JKMRC postgraduate research projects investigating the evaluation and control of blast damage.

Jan 1, 1990

By Antonio Fontana

"Environmental problems encountered with the use of diesel equipment in underground mining operations are discussed. The concept and procedure o implementing the Health Effects Index equation as a means of quantitatively assessing an underground working environment is outlined and sample calculations are present ed. Advantages and disadvantages of utilizing this method are also discussed.IntroductionWith the introduction of diesel-powered mining equipment in the 1960s there arose several question s for the environmental engineer to consider. These included: 1. What are the constituents of diesel exhaust and how can they be detected and evaluated?2. What are the toxicities and long-term health effects of these constituents?3. What is the ventilating volume required to maintain the concentration of these constituents below toxic levels?Diesel engines are a class of reciprocating, internal combustion engines in which relatively high compression ratios are used to generate high air-charge temperatures, which cause ignition of fuel to occur spontaneously. Ideally, perfect combustion of the fuel would produce an exhaust consisting solely of nitrogen (N2), water (H2O), carbon dioxide (CO2) and oxygen (O2). However, because no combustion process is perfect, relatively small quantities of imperfect-combustion products, or pollutants, are also generated. These include hydrocarbons (HC), carbon monoxide (CO), nitric oxide (NO), nitrogen dioxide (NO2), carbon (C) or soot, and sulphur dioxide (SO2).Currently, the Regulations for Mines and Mining Plants, made under the Occupational Health and Safety Act (Section 176), stipulate that weekly tests shall be made to determine the carbon monoxide (CO) concentration in the undiluted exhaust and at the operator's position, and the nitrogent dioxide (NO2) concentration at the operator's position. Also, the aldehyde (as HCHO) concentration in the atmosphere, at the operator's position, is to be measured at least every three months. Threshold limit values (TLVs) have been established for each of the three combustion products, and each is regarded as a separate entity. Consequently, this does not allow for consideration of interactions and possible synergistic effects between the various exhaust components."

Jan 1, 1982

By E. L. C. Martins, M. J. Nicol, D. Majuste, A. D. Souza

The effects of organic compounds on the current efficiency (CE), morphology, crystal structure and mechanical properties of the metal deposited during the electrowinning of zinc are described. A flotation collector and lubricating oil were selected based on observations made during the industrial production of zinc from silicate ores, in Brazil. The analysis by Fourier transform infrared spectroscopy of these compounds, which may be present in minor amounts in the electrolyte solution, indicated the presence of a polar amine group in the collector, while the lubricating oil is a non-polar compound. The average CE value obtained from organic-free industrial solution was 91.15 ± 0.26 %. The CE dropped to 54.35 ± 0.73 % in the presence of 100 mg·L-1 of collector in the solution, and a negative effect was also observed in the presence of similar amounts of oil (88.84 ± 0.61 %). The characterization of the deposits by scanning electron microscopy and X-ray diffraction revealed the formation of pores in deposits obtained from solutions containing the oil, while a different growth pattern (perpendicular zinc platelets) was identified when the flotation collector was added to the industrial solution. In the presence of these contaminants in the solution, guided-bend tests revealed that the deposits have a higher resistance to deformation, but lower ductility, properties that may affect the performance of the stripping stage. As a result of this work, simple control and optimization actions were applied in the industrial plant, which resulted in important improvements in the electrowinning process.

Jan 1, 2014

By Paul Sterling

1. INTRODUCTION. THE general impression regarding the preparation of merchantable anthracite is that it is confined to a colossal, grimy structure, called a "coal-breaker." This name is misnomer; for the desired result is not to break the coal, but to prevent its being broken. Preparation may be said to begin at the face of the chamber, with the mining and loading of the coal. Local conditions vary, not only in the same field or basin, but also in the same mine, so that there is no fixed empirical rule governing the method of blasting or cutting coal. Tests should be made, when possible, to determine the explosive, or the mechanical coal-cutter, which will produce the largest percentage of what are locally known as " lump " and " prepared sizes " of anthracite. The prepared sizes are those mostly consumed for domestic purposes. All other sizes might be called by-products of the anthracite industry; for they are not especially desirable, being the degradation resulting from the mining and handling of a brittle or laminated material. Being low in volatile combustible matter, anthracite burns most successfully when nearly of a uniform size, permitting the easy passage of air through the voids. This accounts for the large number of sizes into which the coal is separated. Table I. gives the various sizes, the diameter of ring over and through which each size is made, and the usual purpose for which it is employed.

Oct 1, 1911

By T. F. Anstett

The Bureau of Mines investigated the availability of platinum from known major deposits in market economy countries. Fifteen of these deposits contain demonstrated resources totaling 302 million troy ounces of platinum. Detailed geologic, engineering, and cost evaluations were performed on each deposit to determine its potential for platinum production. There are large amounts of demonstrated platinum potentially available from market economy deposits that were not analyzed owing to lack of adequate data or to technological limitations. These include 297 million troy ounces contained in the UG2 and Platreef of the Bushveld Complex, South Africa. This analysis indicates that about 11 0 million troy ounces (2.3 million ounces annually) of platinum are potentially available at the January 1980 producer price of $420 per troy ounce, nearly all from South Africa. An additional 85 million troy ounces occurring in Zimbabwean deposits would become available only through more than a quadrupling of that price. In order to meet projected world demand of 3.5 million troy ounces in 1990, platinum price may have to increase. Only one domestic deposit, the Salmon River in Alaska, is capable of producing platinum at $420 per troy ounce. Regardless of price, at assumed production capacities, domestic deposits could supply less than 10 percent of annual U.S. requirements.

Jan 1, 1982

By S. I. Anufrieva, N. A. Permyakova, E. G. Likhnikeevich

"Russia’s rare metal reserves are composed of compositionally and structurally complex ores and are characterized by an increased content of natural radionuclides due to their geochemical similarity with rare metals. For instance, concentrates of Zashikhinsky daeposit are characterized by an increased content of uranium (0,06%) and thorium (0,59%); Beloziminsky deposit holds pyrochlore-apatite-magnetite-carbonate ores characterized by increased radioactivity (130 mkR/h) and containing 0,0016-0,0025% of uranium; Etykinsky deposit is characterized by columbite-pyrochlore-microlith mineralization with an average ore grade of 0,013% of uranium and 0,0020% of thorium; eudialyte concentrate of Lovozero deposit (Alluaiv area) belongs to Class II of mineral reserves. Industrial development of these mineral reserves involves the need to comply with environmental standards, public health requirements applicable to finished core and by-products, to take into account the amount and class of the generated radioactive waste, the possibility of disposal or recycling of the radioactive production waste. Concentration processes of radioactive rare metal feeds most often lead to a concentration of natural radionuclides and their accumulation in concentrates. Comprehensive hydrometallurgical processes are currently under development for such concentrates, aimed at producing salable products compliant with the radiation safety standards. The choice of the hydrometallurgical processing method for radioactive rare metal concentrates is based on the mineralogical component of the concentrate, textural and structural features, the distribution of valuable components and impurities, and the content of radionuclides. A systemic approach to the selection of processing methods, in particular integrating several methods, is an effective solution. Methods may not only be combined, but also inextricably linked with each other. Hydrometallurgical processing methods include leaching by acidic and alkaline agents; sulfatization for selectively decomposing the minerals and moving the bulk of U and Th into solution; fluorine extraction process. Methods of precipitation and co-precipitation, extraction (by liquid and solid extractants), sorption, and ion exchange are used to decontaminate the solutions by removing thorium, mezathorium, uranium, and their radioactive decay products. Agents used in hydrometallurgical processing of radioactive rare metal ores include sulfuric, nitric, hydrochloric, hydrofluoric acid, alkali (NaOH, KOH), sorbents (for example, AB-17) for sorption of uranium and extractants (mono- and bidentate organophosphorus compounds, diamides, etc.) for the extraction separation of rare, rare-earth, and radioactive elements."

Jan 1, 2018

By Heihachi Kamura

The reduction of iron oxide, such as Fe203, to iron in the blast furnace is performed principally by carbon monoxide, but partly by solid carbon by the two following reactions: Fe2O3 + 3CO = 2Fe 4- 3CO2 2Fe2O3 + 3C = 4Fe + 3CO2 It is known that reduction by carbon monoxide takes place at a much lower temperature than reduction by carbon and that the reducing action of earbon monoxide progresses to the inside of the ore in lump form by gaseous diffusion. In the reduction by carbon, however, the reducing action takes place only at the contact surface of the ore and carbon, so that the more complete the reduction by carbon monoxide, the more efficient is the operation. However, the reduction does not progress as shown in the foregoing equation, because carbon dioxide acts oxidizingly on the metallic iron to such a degree that when the gaseous composition reaches a certain proportion of carbon dioxide to carbon monoxide, the reduction practically stops, even though the gases are moving slowly through the heated ore. The proportions of carbon monoxide and carbon dioxide in the gas depend on the kind of iron oxide and the temperature of reduction, also on the duration of time in the reaction. The longer the time of the reaction, the higher the proportion of carbon dioxide obtained in the gas, but finally it will attain to a condition of equilibrium. Chemical Equilibrium of Iron, Oxygen, and Carbon Investigations concerning the equilibrium between iron, oxygen, and carbon have been carried out by E. Baur and A. Glaessner,1 who deter-

Jan 1, 1925

By E. C. Truesdale

IN recent years various problems in connection with research work on the preparation and properties of zinc-base alloys have required reliable information concerning the constitution of the zinc-rich portion of the iron-zinc equilibrium diagram. On numerous occasions rather positive indications were obtained that, for example, the solubility of iron in zinc was incorrectly represented on the current equilibrium diagrams. A careful study of all the available literature relating to the iron-zinc system led to the conclusion that much of the early work was unsatisfactory as measured by present standards of experimental accuracy, and as a result it was decided to redetermine the location of the liquidus curve and of adjacent portions of the diagram. Part I of this paper comprises a description of the experimental methods and a summary of the results by means of which the zinc-rich end of the iron-zinc diagram has been revised in the following ways: 1. Measurements of the solubility of iron in liquid zinc by several different sampling methods, leading to a relocation of the liquidus curve. 2. Microscopic, conductivity, and X-ray studies of the solid solubility of iron in zinc, which, together with thermal analyses, have resulted in new values for the solid solubility and the eutectic temperature and composition. 3. Heating and cooling curves, obtained by a refined differential method, leading to new locations for the two peritectic horizontals. In Part II of the paper the attempt is made to review all of the pub-lished work having a bearing on the constitution of the iron-zinc system, and to correlate the present results, and some recently published data

Jan 1, 1935