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By G. M. Ritcey

Purification of solutions can involve various treatment methods. In the normal sequence of metals recovery by hydrometallurgy, the ore is initially prepared for leaching by grinding to the desired optimum mesh size as dictated by the leaching parameters. Following leaching and liquids- solids separation, the resultant solution is ready for purification. The use, or introduction of solvent extraction into a plant, can be either a major or a minor part of the metal recovery process as shown by the following list where solvent extraction is normally considered: a) recovery of a metal by a simple leaching of the broken ore, e.g., copper from dump leaching where there are only the three main steps of leaching, solvent extraction, and electrowinning (1);

Jan 1, 1978

By B. M. Larsen

IN endeavoring to put the art of the steelmaker on a more scientific basis, as a means of securing closer control of the product, we must be severely critical of the basis of any theory we use. In particular, we must be careful to distinguish between factors that are primary and those of only secondary importance. The concentration relations that determine the slag-metal equilibria, which are usually more or less closely attained, are of course of primary significance, but a clear picture of the whole process requires that the actual rates of the several reactions be taken properly into account. At the high temperature of the steelmaking furnace, all reactions might be thought to be very rapid, but some of them in fact are not; the essential causes of this condition are important to a proper understanding of the process. This paper aims to present, and to justify, the viewpoint that the most significant reaction is the oxidation of carbon in the metal, the progress of which determines the oxygen pressure levels in slag and metal and produces stirring effects, all of which influence the course of the process as a whole. REACTION RATES AT STEELMAKING TEMPERATURES General experience in reaction rates makes it almost certain that at steelmaking temperatures equilibrium is attained practically instantaneously when the reactants are well distributed in a single liquid phase -that is, in the so-called homogeneous reactions. The actual slowness of some of the reactions in the open-hearth furnace must therefore be attributed to a relatively slow rate of diffusion within the slag or metal phase, which limits the rate at which the reactants can meet each other in the liquid steel or at its surface. That the reactions can be made to go with great rapidity, by proper mixing and stirring of the reacting phases, is indicated by the following illustrations: I. In the Bessemer process there is intimate contact between air and the whole mass of metal, and the reactions are complete in a few minutes. 2. Perrin1 has demonstrated that by pouring liquid steel into slag contained in a deep ladle, and thereby producing almost a slag-metal emulsion, the phosphorus or oxygen content of the steel is adjusted immediately. 3. Barret, Holbrook and Woods observed a quite rapid rate of desulphurization when powdered calcium carbide was stirred vigorously into liquid iron. 4. When a spoonful of liquid steel is poured into a mold containing aluminum wire, the formation and precipitation of alumina occurs in the fraction of a second required to freeze the surface layer of the tiny ingot. The first three examples all show that any means of increasing the effective surface between slag and metal and promoting intimate mixture of the reacting phases, thereby obviating the limitation imposed by diffusion, will enhance the speed of the steelmaking process.

Jan 1, 1941

By A. D. Pienaar

The aqueous chemistry of niobium and tantalum compounds with hydrofluoric acid is a mature field of investigation. In contrast, very little attention has been paid to reactions of these compounds in non-aqueous environments. Similarly, reactions of elemental fluorine with niobium and tantalum compounds have received little more than cursory attention in literature. This work discusses the isothermal reaction kinetics derived from thermogravimetry, using a less redundant approach than is currently the standard. We also discuss the most likely kinetic models for this reaction.

Jan 1, 2012

By Zhou Haizuo, Diao Yu, Zheng Gang

"The conventional design method for the embankment supported by DM columns usually assumes the simultaneous failure of all the columns. However, the progressive failure may occur in practice, especially considering that many researches have justified the critical load of DM columns is bending moment. In this study, a finite difference method was adopted to simulate the embankment on soft clay improved by DM columns. An increasing surcharge was applied on the embankment surface to investigate the mechanism of the progressive failure of columns beneath embankment. To capture the brittle bending failure of the DM columns, the model employed a cut-off method, in which the column was separated on failed section as long as the ultimate bending failure was reached. Furthermore, high-strength DM columns were used to enhance the global stability of embankment in this study. The numerical results showed that the ultimate bending failure was first reached at the column beneath embankment toe, and then a continuous collapse extended to the column beneath the embankment shoulder. It is found that the reinforcement could be obviously effective when the reinforced area of high-strength DM columns was extended to a certain area.INTRODUCTIONDeep mixed (DM) columns have been commonly used as a soil-improvement technique to increase stability and to reduce settlement of embankment. Research on failure modes of DM columns owing to embankment fill and surcharge has been the subject of interest for a number of investigators (Miyake 1991; Kitazume 2000; Han 2005; 2006).The potential failure modes of DM column include bending, inclination, shearing, rotating, soil flowing and a combination of these modes (Kitazume and Terashi 1991; Broms 1999). Many researchers have found that bending failure of DM columns was more critical than the shear failure. A centrifuge test was performed by Kitazume (2000) and the results showed that the columns failed in bending before shear failure. In addition, several numerical computations illustrated that design method using the shear strength overestimated the stability of embankment over DM columns (Han and Huang 2005; 2006; Navin 2006; Liu 2007; Wang 1996). In practice, an equivalent shear strength method based on bending failure could better reflect the stability of embankment (Zheng 2010; China Code JGJ79-2011)."

Jan 1, 2015

By W. M. Bangert, F. S. Boericke

"INTRODUCTION Determination of the thermodynamic properties of metallurgically important compounds of chromium has been one of the activities of the Pacific Experiment Station of the Bureau of Mines. Earlier reports have dealt with the entropies 4/ 5/ of chromium, chromic oxide, and chromous and chromic chlorides, with the thermodynamic properties of the chlorides of chromium, 6/ and wits the thermodynamic properties of the carbides and oxide of chromium. 7/ Evaluation of the thermodynamic properties of chromite, FeO.Cr2O3, is desirable, as this material in impure form constitutes the only natural source of chromium of any consequence.Two general methods are available for directly determining heats of formation - (1) measurement of heats of combustion and (2) measurement of heats of solution. Neither of these methods is directly applicable at present to ferrous chromite, which accounts for the lack of previous data. Combustion of a stoichiometrical mixture of iron and chromium under conditions prevailing in a calorimetric bomb yields a mixture of iron and chromium oxides rather than chromite. None of the usual calorimetric solution media dissolve chromite at temperatures low enough for solution calorimetry. Sulfuric acid and an oxidizing agent, such as MnO2 or CrO3, are known to dissolve chromite, but the possible calorimetric use of t is medium would require long preliminary investigation. Consequently, recourse must be taken to some indirect method. At the start of the present work, the most promising method appeared to be the determination of equilibria in the selective, reduction of the iron in chromite by hydrogen;"

Jun 1, 1945

By M. E. V. Plummer, F. E. Beamish, J. C. Hole, J. M. Kavanagh

Prior researches have shown that the iron-copper-nickel content of platinum concentrates may be reduced by carbon to form a collecting alloy for the platinum metals in a manner exactly analogous to the formation of the lead fire assay button. The nature of the iron-copper-nickel alloys with the platinum metals has been investigated. Palladium and probably some of the other platinum metals form solid solutions with this alloy. ONE of the greatest known reserves of the platinum metals is to be found in the nickel, copper, iron sulphide deposits of Northern Ontario. The very large tonnage of copper-nickel ore processed makes the Sudbury district a significant world source of the platinum metals, the latter being recovered as byproducts in the electrolytic refining process for copper and nickel. Chalcopyrite, pentlandite, and pyrrhotite are carriers of the platinum metals;' these minerals contain from 0.03 to 2.0 ppm of the noble metals. The analysis of the above ores for the platinum metals necessitates an initial concentration of the minute quantities present in the ore. The method usually employed involves the extraction of the noble metals by molten lead with or without small proportions of silver. The lead is then separated from the precious metals by cupellation, a process which involves absorption by the cupel and volatilization of lead oxide, leaving the precious metals collected in a silver bead on the surface of the cupel. The collection by lead is probably achieved by a process of dissolution followed by some degree of segregation in the lead alloy since the cold button is seldom uniform in composition. With silver-lead alloys this process of liquation has been used to re- cover pure lead since, during the cooling period, crystals of pure lead separate and silver becomes concentrated toward the center of the solid.' Platinum and gold liquate in a manner similar to silver which may account for the successful recovery of platinum by fire assay even though it is considered insoluble in a solid lead medium. 3 In the case of iridium the liquation process may be a disadvantage in that the iridium may appear in the outer areas of the button and thus be lost mechanically during the handling processes. In any case the deficient alloying characteristics of lead for the platinum metals encouraged attempts to find an improved collecting alloy, and by analogy with aqueous extractions, preferably one in which solid solutions would be readily formed. Since, beyond a certain minimum solute to solvent ratio, the formation of a solid solution is accompanied by a lattice distortion, one would expect some relationship between the atomic diameters of any two metals and their tendency to form a solid solution. In one survey5 the hypothesis was put forward that when the atomic diameter of the solute differs by more than about 15 pct from the solvent, the "size factor" is unfavorable and the formation of a solid solution is restricted. On the other hand, when the atomic diameters are within this limit the size factor is favorable and solid solutions are readily formed, e.g. the transition metals of Group VIII having similar radii form solid solutions over wide ranges of composition.6 Even with a favorable size factor, elements having different crystal structures cannot form a continuous series of solid solutions. Cell dimensions alter as the concentration of the solute increases, causing a

Jan 1, 1962

By Bing Hu, Zhu-Cheng Huang, Guang-Bin Xia, Hu Peng, Hua Wang

"The temperature rising characteristics and reaction of the reduction of iron oxide pellets with anthracite fines were studied using a MW-L0316V microwave oven and Leica-DM-RXP polarizing microscope. The results show that iron oxide pellets and anthracite fines have good microwave absorbing properties, and high temperature and reducing atmosphere in a relatively short time for reduction of iron oxide pellets can be achieved. The reduction reaction, which follows the unreacted core model, is rapid and the metallization increases from 13.41% to 56.57% as the reduction end point temperature increases from 850oC to 950oC. The iron is formed, fine grain crystals of iron are transferred and the contraction of metal phase occurs firstly at the surface of pellets, which hinders the reduction reaction at the center of pellets. The rate of reduction reaction increases slowly as the reduction end point temperature increases from 950oC to 1050oC.IntroductionIron ore direct reduction can be divided into gas-based reduction and coal-based reduction. Owing to the effect of the resource and the related economic benefits [1, 2, 3, and 4], the development of gas-based direct reduction technology is restricted, but the development of coal-based direct reduction supported by the relevant industrial policy has very good prospects for application.As a source of clean energy, in China microwaves have been applied in many fields [5, 6, and 7]. Chen Jin studied the reduction of carbon pellets under microwaves, and has made some progress on reduction kinetics and reaction mechanisms. Other countries also have related research in this field [8 - 15], for example, Kotaro Ishizaki and Kazuhiro Nagata have done research on the reduction reaction of carbon magnetite heated by microwaves. The research shows that Fe3O4 is deoxidized to FeO at about 800oC, and FeO is deoxidized to Fe at 1000oC-1025oC. Due to the very good heat absorbing properties of iron oxide pellets and anthracite fines, the selective and rapid heating of microwaves can rapidly raise the temperature of pellets and anthracite, and the iron oxide pellets can be rapidly reduced. In order to provide enough theoretical basis for direct reduction by microwave heating, this paper studies the temperature rising characteristics, behavior of the reduction reaction and the changes of the iron oxide pellets and anthracite in the microwave field."

Jan 1, 2011

By S. W. Parr

STUDIES relating to the behavior of coal toward oxygen may have for their purpose the determination of the fundamental factors that underlie spontaneous combustion, weathering and deterioration, and the general topic of storage, as well as those properties that have to do with the underlying principles of carbonization. There is also involved the possibility of developing information relating to the constitution of coal, or at least the chemical properties inherent in the type substances of which the coal is composed. It is the purpose here to record certain FIG. 1. results bearing on this latter idea of the chemical properties that characterize the main constituents of bituminous coal. The avidity of freshly mined coal for oxygen has long been known. What happens to the coal or to the oxygen is not so clear. Is the oxygen absorbed or chemically combined, and what are the conditions as to time, temperature, texture, or components that are most involved in the phenomenon?

Jan 6, 1925

By Kokubu H, Moro-Oka A

Gaseous desulphurization from hot metal- lurgical slags containing sulphur mainly as sulphide and(or) sulphate was measured under `low at four different oxygen pressures. The total gas rate was from 1.7 to 2,8 litre/min. Crushed slag samples weighing 2 to 12 g were used for the experiments. The amount of SO2 gas evolved from samples kept at 15500 was rieasured over tires ranging from 20 to 300 min. The gaseous desulphurization rate of sul- phide sulphur becomes high as the oxygen part- ial pressure is increased, while that of sul- phate sulphur is high under low oxygen pressure. The effect of basicity on the desulphurization rate of sulphide sulphur in oxygen atmospheres is not obvious in the range of basicity from one to three. Changes in the ratio of sulphide to sulphate sulphur during the run in oxygen axe analysed. Desulphurization reactions and the rate controlling steps are discussed. De- sulphurization phenomena can be explained by inte.-¦ucia.l chemical reaction rate control.

Jan 1, 1980

By Harrison Souder

THE object of this paper is to bring to. the notice of engineers a safety detonating fuse by the use of which misfires in blasting may be eliminated and safety in blasting operations promoted. This new detonator is a French invention and is known as Cordeau detonant or detonating fuse and is sold under the name of Cordeau-Bickford. It consists of a lead tube 5 to 6 mm. in diameter, filled with trinitro-toluene. While applicable to all classes of mining it will appeal especially to those who have to do with deep-hole blasting in open-cut clines or quarries, or any operations where a large number of holes are to be shot at one time. Since the introduction of the deep-hole blasting in the Cornwall iron mines, much trouble has been experienced from misfires and many experiments were made to determine the best and safest method of blasting. Before the introduction of the detonating fuse it was found that to insure the best results, two or more high-power electric exploders, not less than No. 6, with specially insulated conductors, should be placed in each hole; the holes wired in parallel, and for a large number of holes the current to be supplied by a live wire to the bus or lead wires at about the middle of the bench. The voltage in general use is 110 to 220, but as our material is a magnetic iron ore and the holes are generally damp, we found it advisable to reduce this to about 30 volts to prevent short circuits. A No. 7 or No. 8 special insulated detonator was adopted. But with the best of care and attention to the minutest detail, we were not able to eliminate occasional misfires and the consequent ever present danger of accidents.

Jan 10, 1914

By M. Venkatraman

The limit of Hall - Petch relationship in ultra fine grained steels has been examined based on dislocation pile-up mechanism. When the grain size becomes small the dislocation multiplicity ceases resulting in very low work hardening rate in these materials. An approximate analysis of the theories of hardening indicates that H-P relation is obeyed up to 100nm. It appears that grain refinement is not the suggested approach to improve toughness as well as strength below a critical size.

Jan 1, 2004

A group of prominent engineers and contractors of Chicago and vicinity have cooperated in forming a Joint Committee on Military Engineering. The founders are members of all of the leading engineering and contracting organizations of Chicago, including the local branches of the national engineering societies. The purposes of the Committee are to further military preparedness among engineers, contractors and their associates by the following means: (1) Courses of lectures; (2) assigned reading; (3) studies and practical instruction in military engineering;. (4) assisting engineers to qualify as officers in the National Reserve Corps of Civilian Engineers; (5) urging enlistment in and support for engineer troops of the National Guard and such other organizations as the Government may create; (6) furthering instruction in military engineering in training camps and the attendance in them of those qualified; (7) by such other means as from time to time may be deemed advisable. The Joint Committee has already prepared a program covering the vital points outlined. To date the program is practically complete for a period extending from April 20 to July 25. Something of interest will be taken up each week, including lectures by Lieutenant-Colonel W. B. Judson, Engineer Corps, U. S. Army; two lectures by Major P. S. Bond, Engineer Corps, U. S. Army; Lieutenant-Colonel Mason M. Patrick, Engineer Corps, U. S. Army, and several exhibition drills, terrain exercises and inspection trips under the direction and guidance of various officers of the Engineer Troops of the Illinois National Guard. Additions to the program will be made from time to time.

Jan 5, 1916

By S. McMurray

INTRODUCTION Towards the end of the 1890s the attention of a prospector by the name of Thomas Cullinan was drawn to the occurrence of alluvial diamonds east of Pretoria. Persistent prospecting work by Cullinan led to the loca¬tion of the source of these diamonds-a kimberlite pipe on the Elandsfontein farm. Cullinan eventually acquired the property in 1902, and during an extensive evaluation program outlined the largest diamondiferous pipe in South Africa on which the Premier mine was established. Worldwide attention was drawn to this mine in 1905 when the Cullinan diamond, which weighed 3106 carats and is by far the largest gem diamond ever discovered, was recovered. Premier mine operated with varying success until 1932 when the worldwide depression forced it to close. In 1945 the mine was reopened and since then has been a major producer of gem and industrial diamonds. During the early 1950s exploratory drilling revealed that below the 370-m level the pipe had been completely cut off by a younger gabbro sill. This sill has created major mining and metallurgical problems but the existence of vast reserves of high grade ore below it justi¬fied the establishment of virtually a new mine below the sill. Detailed planning of below-the-sill mining is nearing completion and the development of the first mining block (the L1 block) is well advanced. A full discus¬sion of this block follows. GEOLOGY OF PREMIER MINE Pipe Morphology and Country-Rock Geology As can be seen in Fig. 1, Premier mine is an elon¬gated oval shape with a long axis of 900 m on the surface and a short axis of 450 m. The pipe has a surface area of 32 hectares which decreases progres¬sively with increasing depth, so that 500 m below the surface the area is reduced to 22 hectares. The contact between the kimberlite and the surrounding country rock is sharp, with an average angle of dip of 1.48 rad (85°). From the surface down to approximately 350 m, the country rock is a felsite which grades downwards into a norite. In general both rock types are hard and massive, the felsite in particular being poorly jointed. This characteristic combined with other factors results in an extremely stable open pit, and near-vertical side¬walls are currently being maintained. The norite in general is competent but is heavily jointed in some areas resulting in very blocky ground which creates localized tunnel support problems. In the southeastern area below the sill a zone of highly altered and very unstable norite, which has also created localized sup¬port and development difficulties, lies adjacent to the pipe contact. Kimberlite Geology The Premier pipe is a complex multiple intrusion which contains in the region of 15 separate types of kimberlite, most of which are volumetrically insignifi¬cant. On a simplified basis three major types can be identified which correspond to three separate phases of intrusion. They are: Brown Kimberlite: This represents the first phase of intrusion and now occupies the eastern part of the pipe. In plan the brown kimberlite has a crescentric shape resulting from the intrusive relationship with the younger gray kimberlite which lies to the west. The brown kimberlite increases in relative area with increas¬ing depth which is a favorable factor for future mining operations since this kimberlite is the richest area of the mine, having an average grade of 70 carats/ 100 t. Below the sill this rock disintegrates extremely rapidly when exposed to air or water, to form a fine gravel-like material. This characteristic is due to a high montmorilonite clay content. As is common with clay minerals of this type, water can be absorbed into the crystal lattice with a resultant increase in volume which causes the physical decomposition of the rock. The presence of this decomposing kimberlite was a major factor governing the choice of a mining method, as well as development and tunnel support techniques. Gray Kimberlite: This is the most abundant type and represents the second major phase of intrusion. The diamond content is variable depending on the amount of waste rock dilution, and in general the rock is stable and non-decomposing. At the time of formation of Premier, the surface rock type was Waterberg quartzite, a rock formation which has subsequently been removed from this area by erosion. The explosive extrusion of the gray kimberlite caused extensive brecciation of this rock and while the kimberlite was in a mobile state huge masses of quartz¬ite, amounting to tens of millions of tons, slumped into the pipe. This quartzite became concentrated in the central area of the mine and has been a major mining problem throughout the history of Premier since, due to the irregular distribution of the quartzite, effective selective mining has never been possible. The quartzite is therefore extracted with the ore and has a significant dilution effect on the overall grade. Black Kimberlite: In the western part of the pipe a circular, pluglike body of kimberlite is intruded into the gray kimberlite. This plug consists mainly of a hard, dark-colored rock known as black kimberlite, but also contains a number of minor kimberlite variet.ies as well as nonkimberlite carbonate dikes. The Gabbro Sill The sill averages 75 m in thickness and within the confines of the pipe consists of 52 million t of rock. On average the major dip is 0.34 rad (20°) to the northeast which is across the short axis of the pipe, the range of dip being from near horizontal up to 0.52 rad (30°). Due to the pronounced dip, the sill is encount¬ered over a vertical distance of 175 m with the highest upper contacts on the 355-m horizon and the lowest bottom contact on the 530-m horizon.

Jan 1, 1982

By Earle Faig

Earle Faig Along with other transportation modes, the barge industry will be greatly affected by trends in domestic coal production. Traditionally, coal has been one of the major commodities moved by barge. Now, because of events in the international energy market, coal is finally getting the recognition it deserves as a major component of the country's energy program. Perhaps even more significantly, a series of events has caused other countries to turn to the United States as a source of coal. Although the outlook for coal demand is optimistic, it will be greatly influenced by the ability of the transportation sector to handle the additional traffic. Because of its long experience in moving large quantities of coal, the barging industry is in an excellent position to capitalize on coal's increased popularity. A brief description of the barging industry should facilitate the discussion of coal as it relates to that industry. Barge companies operate on a river system that is over 40 Mm (25,000 miles) long. It includes the East and West Coasts and the Mississippi River System comprised by the Allegheny, Monongahela, Kanawha, Ohio, Illinois, Missouri, Tennessee, Cumberland, Arkansas, Warrior-Tombigbee, and Mobile Rivers, and some smaller tributaries. The Gulf Intracoastal Waterway stretching along the Gulf Coast from Brownsville, TX, to Apalachicola, FL, also is considered part of the inland waterway system. Approximately 1,800 companies operate on the inland river system and have a combined fleet of about 4,400 towboats and 28,000 barges. The fleet of towboats represents 4.8 GW (6.4 million hp) of power. The towboats comprising this fleet vary in size from a small harbor boat to a large line haul boat with 7.5 MW (10,000 hp) of power. The choice of size and power of the boat depends on a number of factors, including the size of the river and operational constraints, such as lock size, river-current rate, and water level. The choice also depends on the tow size. A single tow on a river capable of locking through 15 barges at a time handles up to almost 20 kt (22,000 st), whereas a tow on the lower Mississippi, which has no locks, can accommodate up to 41 kt (45,000 st) of cargo. Because the quality of coal is not typically damaged by exposure to the elements, it is usually moved in open hopper barges, although covered barges are used occasionally. The most frequently used size is the jumbo barge that measures 59 m (195 ft) long by 11 m (35 ft) wide by 4 m (12 ft) deep and can handle up to 1.4 kt (1,500 st) of coal. Advantages of Barge Transportation Barging offers several inherent advantages in transportation of bulk commodities like coal. First, barges can carry large quantities of product. A single jumbo hopper barge can handle 1.4 kt (1,500 st) of cargo while it takes 15 91-t (100-st) capacity rail cars or 57 trucks hauling 24 t (26 st) each to move an equivalent amount of cargo. Thus, barges can move more tonnage with less equipment than competing forms of transportation. Second, barging offers the most fuel efficient means of transportation. Less energy is required to push a load over water than to pull a similar load over land. The amount of pollution attributable to barge traffic is minimal because barges consume less fuel. Third, barging is an inexpensive form of transportation. The inland waterway industry transports about 12% of the nation's freight for about 2% of the total freight bill. This can be attributed to competition between the large number of companies on the river system and competition with other transportation modes. Fourth, barging is an environmentally safe method of transportation. Inland river routes expose fewer urban areas to hazardous substances than rail or truck. And barge spills occur less frequently than rail or truck spills. The industry does pose some disadvantages. The waterway system is constrained by the natural river network, so barges cannot travel on the most direct straight-line route. This means that barging is usually an incomplete form of transportation requiring interface with truck or rail. The industry's market is limited to those geographical areas that are located on or near the rivers. In addition, it is a time-consuming transportation mode, making it impractical for many types of commodities.

Jan 10, 1982

By A. J. Farstad

The current emphasis on energy needs in the United State sand abroad has placed an increased demand on the coal mining industry. The United States is fortunate to have abundant coal reserves. However, coal mining techniques and technology have not kept pace with the increased demand for coal. Consequently, coal mining in the United States continues to be one of the most hazardous industries. One of the daily hazards faced by coal miners is the sudden and unexpected occurrences of roof falls. The research program described in this final report focuses attention on the problems of unstable roof conditions in coal mines and describes prototype equipment which, with further development, has potential of being able to warn miners of impending roof falls in mines. Westinghouse Electric Corporation, Geophysical Instrumentation Systems Group was awarded a contract to develop and test a microseismic roof fall warning system based on general specifications derived from earlier Bureau of Mines research [1], [2]. During the first year of this two year effort (Contract H0242045) the electronic monitoring systems were de signed and built while the second year of the contract was devoted to equipment field testing in working coal mines.

Jan 1, 1976

By Edmund W. Murphy

At the first workshop on Surface Subsidence Due to Underground Mining (1 981 ) , Yarbrough delivered a paper (1 ) describing the mine subsidence insurance program in Illinois operated as the Illinois Mine Subsidence Insurance Fund (IMSIF) . In this paper we will present claims data and describe changes that have occurred in the Illinois Insurance Code during the first six years the IMSIF has been in existence. The change in the original Illinois Public Act 80-1 41 3 that most affected the public was an amendment increasing the maximum amount of mine subsidence insurance avail- able on a structure from $50,000 to $100,000. Seventy-two counties in Illinois have been undermined for minerals, primarily bituminous coal. In Franklin County (.in the southern part of the state) 36 percent of the land area has been undermined for coal extraction. In St. Clair and Madison Counties , two counties that include the St. Louis Metropolitan area along the western border of the state, 10 percent and 7 percent of the land surface have been undermined. Most of the undermined area in the two counties is beneath urbanized land. In 34 counties, approximately 1 percent or more of the land surface has been undermined (2). The first shaft mine in Illinois was sunk in the city of Belleville (east of St. Louis) in 1842, and the mines of early vintage have initiated the majority of the mine subsidence claims. Data compiled from the first six years reveals that most Illinois mine subsidence events that affect structures occur over abandoned mines where early methods of high- extraction mining practices were used. Maps of these mines operated in the 1800s reveal irregular development of room and pillar areas and poorly defined production areas (panels). Rooms in the mines varied from 15 to 40 feet in width and the pillars varied in width from 5 to 40 feet. The pillars were often long and narrow. Recovery rates in mines that operated prior to 1900 generally averaged 50 per- cent, and extraction rates as high as 80 percent have been documented (2). Some pillar robbing occurred.

Jan 1, 1986

By Vernon F. Swanson

Several laboratory flotation tests were conducted by the Bureau of Mines on a sample of unweathered diorite from the B. F. Camden property, Amherst County, Va. Results showed that an ilmenite concentrate analyzing 45.5 percent Ti02 (titania), 0.07 percent P205 (phosphorus pentoxide), and 2.21 percent Si02 (silicon dioxide) could be produced from a feed containing 7.72 percent Ti02 and 3.94 percent P205. Ti02 recovery in the concentrate was 47.6 percent in a batch test. The weathered saprolite material overlying the diorite required scrubbing and desliming to remove argillaceous material and preliminary flotation of apatite followed by flotation of ilmenite. The resulting concentrate analyzed 47.3 percent Ti02, 0.19 percent P205, and 0.99 percent Si02 from a starting feed of 8.99 percent Ti02 and 3.37 percent P205; TiO2 recovery was 54.5 percent.

Jan 1, 1963

By Mistra M, Hu JS, Wadsworth ME

The fluorite/oleate system has been studied extensively since the begin- nings of flotation research. The well-defined relatively simple crystal structure of fluorite and its ionic bonding make it a model system for study. Our understanding of fluorite/ oleate flotation chemistry continues to grow but as yet remains incomplete. Besides a review of our understanding of this system, recent findings are presented in this paper, and new research horizons are identified.

Jan 1, 1984

By E. E. Mason

The Canadian National Railway system is completing construction of the first major tunnel in North America to use the coarse-aggregate (+ ½ -in.) shotcrete technique of primary support and lining. The tunnel was driven 29 X 20 ft in cross section, 10,760 ft long, passing under an industrial and residential area of Vancouver. With the exception of 1400 ft in soil (mainly impervious tills), the tunnel passes through a very young series of flat-lying sedimentary beds, to a large extent so incompletely consolidated as to fall apart on exposure. For a conventional steel-support system, it was estimated 8 WF, 28-lb steel should be used at 5-ft centers. Cost of erection including lagging would amount to $120 per linear ft of tunnel at 304 per lb. With 8-in. concrete cover on the steel, lining would cost $280 per linear ft at $82 per cu yd. Thus, minimum cost of support and lining would have amounted to $400 per linear ft. It is now estimated that at least 90% of the rock tunnel would have required support and 100 % required lining. Specified shotcrete support was 6 in. in the arch and 4 in. in the walls. Cost of this work was roughly $100 per linear ft. In addition, another $10-$12 per ft has been incurred in drainage and waterproofing wet areas and in measures to correct experimental and operational errors, thus finalizing the support as a lining (Fig. 1). The tunnel was driven three shifts five days weekly, no blasting being allowed by city ordinance between midnight and 7.00 a.m. A six-drill jumbo was used to drill a 10-ft round, 110 holes blasted three times daily. A 2-in. layer of shotcrete was applied to the newly blasted arch commencing within 45 min of blasting. This was done from a flying deck that extended over the muck pile from the jumbo (Fig. 2). Also during the mucking cycle, the preceding incomplete arch support was brought up to 6-in. specification. The walls were sprayed 4 in. thick during the drilling cycle (Fig. 3). The shotcrete machines and aggregate bins were mounted on the jumbo.

Jan 1, 1970

By Fabjanczyk M. W

The design of underground mine roadways (tunnels) requires a detailed understanding of the in situ stressfield, the rock failure modes, the performance characteristics of reinforcement or support members and assessment of the stress state about the roadway. Definition of these factors, together with monitoring of roadway behaviour during both development and extraction operations, allows rational design procedures to be undertaken.The design approach utilised computational techniques to simulate the behaviour of the strata about the opening for a range of anticipated stressfields and various reinforcement options. Field validation studies are conducted to confirm the design expectations.

Jan 1, 1993