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By W. H. Bassett, J. C. Bradley

Beads of metal frequently appear at the ends of cast-copper wire bars and on the sides of wedge cakes near the top. These are richer in cuprous-oxide than the rest of the casting. A micrographical study of these exudations has been made. 11 is suggested that the materical is forced through the surface while the copper is solidifying. If not eliminated in process of manufacture, it shows on the finished polished sheet copper in patches differing in color from the main body of the shad. Figures 1 to 4 show the copper exudations, at different magnifications, as they appear on the ends of cast wire bars, and on the sides, usually near the top, of wedge cakes. Sometimes the exudations are in fine "drops;" at other times, large masses of the material are found. Microscopic examination of the copper exudation indicates that it is high in oxide and of eutectic proportions. Because of the difficulty of securing a suitable sample, the protuberances have not been analyzed chemically; but the spectroscope shows no indication that there are any more metallic impurities present than in the balance of the copper. The lowest copper plus silver content of the coppers studied for this paper was 99.914 per cent.; the highest, 99.966 per cent.; so the oxygen content of the whole casting would be well under 0.07 per cent. Structure of Protuberances The segregation of oxide between grains in the interior of the cast bar, not far from the "set," is shown in Figs. 5 and 6. In general, the amount of cuprous oxide begins to increase at a point about 0.01 in. below the normal surface of the casting, i. e., the base of the drop; but it does not attain maximum concentration in the main body of the metal. Vertical sections, Figs. 7 to 12, show that there is a definite line of large cuprous-oxide globules at the base of the drops. Horizontal sections at this place show that these large globules lie in a thin billowy

Jan 1, 1926

By Lawrence Bragg

WE associate metals with hardness, toughness, and strength. But a curious paradox lies at the root of the valuable mechanical proper-ties of the metallic state: in order to be strong, a metal must be weak. This paradox, and the equally surprising fact that, in a sense, metals are not true solids at all, are among the topics here discussed by Sir Lawrence Bragg. (1) WHAT METALS MEAN TO US We employ various materials to build or fabricate the many objects we use in everyday life, choosing those whose properties are most suitable for the purpose which the object has to serve. Certain of these materials have been used from the earliest times, such as stone, wood, leather, and animal or vegetable fibres, each with its own peculiar valuable properties. Stone resists crushing and is very durable and permanent, as indeed it must be, since it has so long resisted change as a part of-the earth's crust. It is there-fore ideal for walls and buildings, and very early in his history man discovered how to make artificial stones by burning clay, with the advantage that they could be given any desired shape, and made into bricks or given elaborate forms as pottery. Wood is strong and tough and light, it resists tension as well as compression, and is nor brittle like stone. It forms beams and furniture and parts of tools or weapons. Leather is tough but at the same time iris flexible; it is ideal as straps or sheers. Vegetable fibres such as linen or cotton, and animal fibres such as wool and silk, owe their value to their flexibility and strength in resisting extension. They can be spun into yarn or rope, and woven into cloth. The technological age in which we are now living is replacing the natural products used by early man by a series of artificial products, but it is remarkable to see how in nearly every case we are copying Nature's materials. The wide use of concrete represents a developed art of making artificial stone. Artificial fibres such as rayon or ?nylon replace cotton, wool, and flax. Plastics are coming very much to the fore; they correspond to early man's use of horn, another substance with peculiar properties of roughness in all directions without the 'grain' of wood. For the most part we are following in the footsteps of our remote ancestors, though we can make for ourselves what they had to cull from wood and field. There are exceptions; for instance, we have discovered comparatively recently the number of uses to which natural rubber can be put, and are now making it artificially. This is a really new discovery; our ancestors had nothing with such remarkable powers of elastic stretching without breaking, and resistance to being abraded.

Jan 1, 1943

By T. Boiselle, C. Gielen, P. Henry, J. M. Bier

"Hydrometal is specialized in the production of zinc sulphate from complex secondary raw materials. Electric Arc Furnace (EAF) dust is one of the more interesting potential sources to produce zinc sulphate. In order to minimize waste quantities generated from EAF dust treatment, our R&D team has developed and patented a new process to recover the Fe contained in the dust as iron oxide product to be used and sold into the pigment market. The process is based on a specific reductive leaching step of the zinc ferrite contained in EAF dust, followed by a purification step to remove impurities (Ni, Cr, Cu...) and finally the controlled precipitation of the iron oxide. The aim of the iron precipitation step is to obtain the right shape and length of crystals in order to guarantee the right color and tinting strength of the pigment. The innovative aspects of the process results in the controlled oxidation of the iron to get the right crystal size and good purity material. The iron product can be valorized as red or yellow pigment often produced by the Penniman-Zoph process.INTRODUCTION A Few Words about HYDROMETAL Hydrometal SA (Engis, Belgium) is a subsidiary of Jean Goldschmidt International SA (JGI) in Brussels. JGI is mainly involved in metal trading activities (Goldschmidt, 1995). In 1985, JGI acquired the leaching circuit of a Belgian electrolytic zinc producer located in Engis, a few kilometers south of Liège, near the river Meuse and it was decided to name this plant: SA HYDROMETAL. Hydrometal is well connected by water, rail and road from its central location in the industrial region of Liege, in the heart of Europe. The company received in 1997 an additional license to process and recycle toxic and hazardous waste. Figure 1 shows a picture of the plant."

Jan 1, 2016

The rocks of the Serranias Chilla massif of Bolivia are a suite of metamorphosed Palaeozoic basalts and associated continental sediments. Whole-rock trace element geochemistry of the basalts suggest a calc-alkaline affinity and indicate that subduction extended as far north as the Bolivian Altiplano during lower Palaeozoic time.

Jan 1, 1990

By George S. Rice, L. C. IlsLey

"A remarkable explosion of fire-damp caused by a discharge of lightning at the new shaft at the Sitalpur coal mine, has been reported by the Chief Inspector of Mines of India, who gave the following details:""The explosion occurred during a thunderstorm, and the evidence showed that a flash of lightning had, to all appearances, passed down the shaft caus¬ing disruptive discharges at certain points between the guides and the winding rope, rending the latter at two places situated respectively .228 .feet and 278 feet from the surface, The distance between the winding rope and the side of the shaft was 5 feet 4 inches, indicating a spark gap ;of this width, and an intensity of discharge which could not fail to ignite the explosive mixture of gas and air known to be present in the shaft.""The Compressed Air Magazine, January 1920 issue, which contained the above extract also goes on to state;""In 1915, M, Ferey described in a paper read before the Societe de l'Industrie Minerale phenomena of a similar character to the above. In a pit liable to sudden outbursts of gas, for the sake of safety, shot firing was carried out from the surface. During a storm, in the year 1905, shots went off in two places after the detonators had been connected to the conductors) we read in the Colliery Guardian, London. These shots were situated respectively 1,400 and 1,410 metres from the firing station, Realizing the possible danger from this cause, the precaution was taken to cut the conductors at the bottom of the shaft and to connect there just before firing, Even under these conditions a shot went off spontaneously, -.owing, it is believed, to lightning."""

Feb 1, 1920

By Almon F. Robertson

This is one of a series of reports describing investigations made within the Missouri River Basin in Montana by mining engineers of the Bureau of Mines, Minerals Division, Region II. The primary purpose of these investigations is to provide basic information to agencies of the Department of the Interior and other agencies concerned with the planning of power and other water developments in the Missouri River Basin. This report contains only such factual data as have been authorized for public distribution. Special precautions have been taken not to reveal any information or data considered to be confidential. The field investigations for this report were made during the fall of 1948 and the summer of 1949. Virtually all of the known metallic mineral deposits and some nonmetallic (industrial) mineral deposits within Judith Basin County were investigated. Most of the mines and prospects have been inactive for many years; most of the old underground mine workings now are inaccessible or only partly accessible. Consequently, much of the information on many of the mines and prospects necessarily has been obtained from available U. S. Government and State publications and from owners and local residents.

Jan 1, 1951

By Rosengren KJ

Geotechnical conditions often have a critical influence on the design of new open pit and underground mines, but they are often considered of secondary importance in relation to other factors, such as detailed geology, orebody geometry and grade distribution. As a result, geotechnical studies may not be carried out during early project investigations or, at best, may be given only superficial attention, often to the overall detriment of the project. Technically and economically, it is logical that geotechnical studies should be integrated with geological investigations as soon as it becomes evident that the particular deposit may prove to be economic. The paper discusses the use of geotechnical information in the selection of mining methods and mine design for underground mines and for wall design and assessment of excavation characteristics in open pit mines. It then considers methods of obtaining the relevant data, with particular reference to exploration boreholes. Selected case studies on the application of geotechnical data to mine design are Included.

Jan 1, 1986

By R. R. Fernández

Newmont Mining Corporation has been processing refractory gold ores by roasting since January 1995. The ores are refractory due to the association of the gold with iron sulfides, namely pyrite and marcasite, and the presence of carbonaceous components and is oxidized in an oxygen-enriched gaseous atmosphere. The structural characteristics of the calcine have a strong influence on the eventual recovery of gold by cyanidation. These characteristics are strongly dependent upon the roasting conditions, mainly the roasting temperature. Originally, the sulfides and carbonaceous matter were oxidized at a temperature that typically ranged between 535 and 560 °C. Controlling the roasting temperature within the lower and narrower range of 510 to 515 °C produced a calcine with a larger surface area(e.g. higher porosity), which resulted in a gold recovery increase of3.3 percent in 2001 equivalent to 5.1 million dollars of additional gross revenue. The new strategies of operating at temperatures never tested before are discussed. It constituted a great challenge to the control room operators for the lower operating temperature falls much closer to the ignition temperature of the sulfide ore and smaller and more frequent adjustments in operating parameters were needed to improve and maintain high gold recoveries. Based on the encouraging results that were achieved in 2001, a decision was made to install a “smart” process control system because the roaster temperature control was performed by manual inputs from the control room operators. The development and implementation of the control system to reduce or eliminate the temperature variability between the different control room operators commenced in June of 2002 and was fully operational by the end of October. Lower roaster temperatures were achieved (500 to 505 °C), which resulted in further increase of gold recovery by about two percent. The overall recovery increase equated to 8.0 million dollars of additional revenue for the first 10 months of 2002.

Jan 1, 2003

By William Cruger

OUTLINE SUMMARY A. Brief Description B. Characteristics 1. Can be highly cost effective 2. Restricted in usage 3. Political Controversy 4. Volume of Transactions 5. Users C. Mechanism 1. Five steps D. Investor issues 1. Application 2. Restricted usage 3. Discount 4. Formal or informal process 5. Restricted benefits 6. Recompense 7. Window of opportunity THE VARIOUS PROGRAMS1 A. Brazil B. Chile C. Venezuela D. Argentina E. Mexico USAGE IN THE MINING, METALLURGICAL, AND PETROLEUM INDUSTRIES

Jan 1, 1990

By G. L. Oldright

The studies previously made on Smelting in the Lead Blast Furnace have dealt with the custom smelter of the International Smelting Co. at Tooele, Utah, and on the smelter of the Bunker Hill & Sullivan Mining & Smelting Co. at Kellogg, Idaho. The International plant may be considered representative of the traditional custom smelter. The lead smelter of the future seemingly will have to treat increasingly richer lead charges. This feature was then stressed in describing the Bunker Hill plant.

Jan 1, 1934

By M. R. Henzinger, G. Lenz, A. Gaich, Pötsch, W. Schubert, P. Wagner

"The better the information on the rock mass and its fracture system, the better is the basis for any rock mechanical decision that is required during the excavation process. While in conventional tunnelling free view to the tunnel face is available, possibilities are limited for mechanised tunnelling using a tunnel boring machine (TBM). An approach, already formulated in 2005, is used that produces digital photographs through openings in the cutting wheel of a TBM and merges them into a circular three-dimensional image. The 3D image is then used for geometric rock mass characterisation purposes including geological mapping, for example to measure spatial orientations or determine joint spacing. In the paper the basic concept is described together with first results from a pilot test.INTRODUCTIONA three-dimensional image unites digital photographs with spatial information on the objects/surfaces it shows. Since they combine geometric and visual information they are a straightforward source for geometric rock mass analysis and geological mapping. Their obvious benefits among others are: (i) they allow spatial measurements even in inaccessible regions, (ii) they provide objective and reproducible records of the rock mass conditions, and (iii) they increase working safety (Gaich et al. 2004).Pre-requisite for the generation of 3D images is the acquisition of at least two photographs from the region of interest. From the photographs the imaged object surfaces are reconstructed by means of image analysis using methods from photogrammetry (Slama, 1980) and computer vision (Hartley & Zisserman, 2001). See also Figure 1."

Jan 1, 2015

By Richardson G. W, Yap L. C

Friction rock stabilisers (FRS) are the most common steel-based ground reinforcement used in underground mines in Western Australia. As with any other steel-based product used in underground mines they are susceptible to corrosion, particularly under aggressive minewater and mineral conditions. Because of their thin-wall tubular construction and large surface area, the potential damage resulting from corrosion is considered to be more severe for this type of reinforcement than for other forms of reinforcement made of solid steel bars. Because of the obvious safety problems which may result from corrosion, both mine operators and regulators have raised concerns regarding the long-term effectiveness of FRS installed in underground mines in Western Australia. Although corrosion has been recognised as an important safety issue, the controls of corrosion in varied underground mining environments has not been well understood. To improve the understanding of the corrosion behaviour of FRS, the Department of Minerals and Energy has initiated a research project focused on the mechanisms and extent of corrosion attacks, and their influence on the effectiveness of the reinforcement. This paper describes the research project and presents the interim results achieved To-date.

Jan 1, 1995

An integrated mining equipment development organisation is typified by Deutsche Montsn Technologic of Essen, Germany. working on improvements in reliability, production and control in coal mines. Examples of recent mining advances are in mechanised roadheading, in different approaches to cutting technology, and in low height roof bolting.On the longwall face the mechanics of cutting are related to supplied energy as well as to dust make. In conveying both armoured face conveyors and conveyor belts are monitored. Roof support is not neglected and the continuous pumping of stowage slurries provides further options for longwall support. Surveying developments, particularly the gyro-theodolite, directional drilling. and shaft vehicle monitoring provide further examples of advances in control in coal mining activities.

Jan 1, 1991

By Richard W. Markley

The predominant methods for mining coal in the USA are room and pillar and longwall. Approximately 95 percent of the coal is mined by room and pillar and 5 percent by longwall. The U.S. Department of Energy (DOE) has an ongoing program to improve the rate, quality, and cost effectiveness of stabilizing the roof for both of these mining systems. In room and pillar mining, the installation of permanent roof support is often the task which paces the system operation, and it thus controls the level of production achieved during any mining shift. Two automatic roof bolt insertion equipment developments are discussed, as well as a flexible drill for operation in thinner seams. Progress will be reported on under- ground trials of a particular flexible drill which has been combined with a bolt inserter to form a compact, reliable module for retrofitting to continuous mining machines. In longwall mining, the use of hydraulic supports on the working face provides roof stability. The DOE has several trials ongoing with shield- type supports in difficult strata conditions which are described, as well as a co-funded project with the Bureau of Mines on a resin injection remedial method for consolidating a shear zone at one site. A project to improve the match of strata conditions to shield design is also described, which involves the use of a 1360 tonne vertical load mine roof simulator.

Jan 1, 1983

By A. R. Rule

Research was conducted by the Bureau of Mines to develop a process for utilization of Idaho kyanite. A continuous gravity-flotation separation process was applied successfully to recover kyanite-group minerals from an Idaho ore containing about 21 percent combined kyanite, andalusite, and sillimanite. Dry magnetic separation of the concentrate resulted in a product containing about 90 percent kyanite at a recovery of 63 percent of the kyanite-group minerals in the ore, Alumina and silica analyses were within the range generally accepted for conversion to mullite, and the finished products had a pyrometric cone equivalent of more than 38. A recovered garnet coproduct may be of commercial value.

Jan 1, 1973

By Joseph Cervik, Gerald L. Finfinger

The Bureau of Mines conducted an experimental degasification project in Island Creek Coal Co.'s Virginia Pocahontas No. 5 mine. Methane from the over- lying Pocahontas No. 4 coalbed was entering mine workings in the Pocahontas No. 3 coalbed through fractures in the roof rock. Small-diameter (1-5/8-inch) holes were drilled into the overlying coalbed to reduce the gas pressure and intercept methane flows, which were piped to the surface through an under- ground 6-inch-diam steel pipeline. The total methane flow rate from the vertical holes averaged 150,000 ft3/day for the first month. Methane flows into the mine were reduced by 47 pct, thereby demonstrating the effectiveness of this form of degasification in reducing ventilation requirements and providing a safer working environment.

Jan 1, 1979

By J. E. Miller, W. E. DeVaney, L. Stroud

During a recent phase study of a natural gas, two stable equilibrium liquid phases were observed at temperatures below —200°F and pressures above 200 psi. This paper reviews the published literature on the occurrence of multiple equilibrium liquid phases and presents analytical data for the vapor and two equilibrium liquid phases of the liquefied natural gas at five experimental conditions. In addition, data for 30 conditions of two-phase equilibria are included. INTRODUCTION The low-temperature phase behavior of gases, most of which contained helium, has been investigated in the laboratories of the Helium Activity for many years. Since 1952, experimental studies of these systems have been continuous as part of the research program at Amarillo, Tex. Because of their value to private industries interested in participating in the Helium Conservation Program, several "Open File" reports containing phase equilibria data for heliurn-bearing natural gases have already been released by the Helium Activity. A paper containing information on the general phase behavior, operating criteria and extensive vapor-liquid data for two helium-containing systems was recently published.2 Additional publications presenting experimental data on the phase relationships of various gas systems are now in process and will be available in the near future. PREVIOUS EXPERIMENTAL WORK Although the formation of multiple liquids has been reported for various systems, to our knowledge this paper is the only substantiated evidence of a vapor-liquid-liquid equilibria in a naturally occurring gas. In 1940, Vink, Ames, and others13 reported the presence of two liquid phases in a hydrocarbon system consisting of mixtures of crude oils, solvents and natural gas. Eilerts and co-workers; published data on the recombined fluids from a gas-condensate well. This condensed gas, containing approximately 76 per cent methane and 24 per cent ethane-plus, exhibited two distinct liquid phases. Weinaug and Bradley 14 observed "unusual" phase behavior in a reservoir mixture. These workers postulated that the anomalous phase behavior was due to the "imminent formation of a second liquid phase". Botkin, Reamer, Sage and Lacey 1 studied two California crude oils that exhibited multiple phases. Kohn and Kuratal0 recently reported two equilibrium liquid phases in the methane-hydrogen sulfide system. Roof and Crawfordl1 and Eakin, et a16 also have reported experiments with binary systems that formed two stable equilibrium liquid phases. APPARATUS AND PROCEDURE A U. S. Bureau of Mines Phase Equilibrium Apparatus was used in conducting this study. The apparatus and procedures employed in its operation have been previously described3 and will not be repeated in detail ill this report. Briefly, the apparatus consists of a windowed cell which can be maintained within ±0.5°F for temperatures between room temperature arid -320°F. Pressure within the cell can be maintained within 0.1 per cent of gauge reading up to 800 psig. Equilibrium vapor and liquid samples are obtained in special containers4 for analysis by a mass spectrometer. Although the accuracy of the analyzer is about ±0.1 mol per cent, the reproducibility of the phase-equilibrium apparatus is considered relatively poor. Values reported from methane and nitrogen are considered accurate to ±l.0 and ±0.6 mol per cent. Data for ethane-plus in the vapor are accurate within 0.2 mol per cent; liquid-phase data for this aggregate compolnent are accurate within 1.5 mol per cent. For helium in the vapor phase, the analytical data are accurate within 0.2 mol per cent; liquid-phase analyses for this component were obtained by the charcoal adsorption method described by Frost8 and are accurate within 0.006 mol per cent. All of these references to the accuracy of reported values are conservative estimates based upon a statistical treatment of reproducibility data obtained with the apparatus.

Blasting in Norwegian mines is often carried out by contractors who tend to look for the cheapest solution, without concern about fragment quality. The requirementsfor a contractor are usually only related to the maximum size of boulders and the quantity per month. Even when the owners of the mine are responsible for blasting, very little effort is made to optimise the blasting process. This paper presents test methods which were used and results from small-scale and full-scale blasting tests. In the small-scale tests, cubes 500 x 500 x 500 mm of four different rock types were blasted in a chamber, using two types of dynamite explosive. The velocity of detonation (VOD) for the dynamite explosives was 3000 m/s and 6000 m/s respectively. Three cubes of each rock type were blasted with each type of explosive, and a total of six cubes of each rock type was used. The entire muckpile (approximately 350 kg) was- sieved and weighed after each blast and fragments between 8-16 mm were tested for impact values and flakiness. The results of these tests clearly showed improvement in fragmentation the closer the acoustic impedance ratio of the explosive (VOD x density) over the rock (Cp density) was equal to one. The results also showed that the quality of the fragments (in terms of impact values) tends to be better when the cubes are blasted with the high velocity dynamite.

Jan 1, 1995

By Richard E. Sylwester

Evaluating surface and subsurface conditions for marine foundations (bridges, causeways, terminals, etc.) is often done with a limited amount of data. Subsurface information for these projects is primarily acquired using traditional methods, such as boreholes, test pits or divers, which tend to be expensive and limited in the area of coverage. A number of geophysical methods, including precision bathymetry, sidescan sonar, and seismic reflection or subbottom profiling are extremely cost-effective and obtain significantly more data than can be acquired using traditional intrusive methods. These geophysical methods provide detailed surface images and continuous profiles of the subsurface stratigraphy. This information can be invaluable for selecting the best location for geotechnical boreholes and to map potential geohazards such as submarine slides and filled or open scour holes. Offshore investigations conducted for a proposed highway bridge (Knik Arm Bridge, Cook Inlet, AK), the retrofit of two existing bridge (Antioch and Dumbarton Bridges, CA) and a proposed cruise ship terminal (Ketchikan, AK) used a combination of geophysical methods to map water depth, detect and map debris on the seabed, map the thickness of unconsolidated sediment, determine the depth to bedrock and identify potential geohazards such as scour holes. The results of the geophysical investigations will be used to select locations for obtaining geotechnical borings, to extrapolate geologic information between existing or proposed boreholes, evaluate the potential depth of scour and design a pile support pier. Geotechnical engineers, offshore contractors and bridge designers are realizing the importance of the early use of offshore geophysics for (i) site characterization, (ii) to reduce the uncertainty of geotechnical conditions thus avoiding designs that may be overly conservative and thus more expensive and (iii) to assist in selecting locations for geotechnical borings.

Jan 1, 2013

By N. Sauret-Szczepanski, G. Patry, S. Gauthier, G. Potvin, C. Munger

Adsorption/thermal desorption with sorbent cartridges and analytical method using gas chromatography coupled to mass spectrometry (GC/MS) was developed for the determination of tetrafluoromethane (CF4) and hexafluoroethane (C2F6) emitted from primary aluminum smelters. A customized cartridge was built like a packed column with a stainless steel tube filled with a specific resin. The optimization of adsorption and desorption parameters was carried out to support the PFC sampling for all aluminum production technologies. The proposed method showed good linearity for concentrations ranging from 10 to 500 ppbv for CF4 and from 5 to 500 ppbv for C2F6 with correlation coefficients above 0.999. In certain conditions, the detection limits of the analytical method reached 0.3 ppbv for CF4 and 0.15 ppbv for C2F6- Using this methodology, a field campaign was carried out using a sequential sampler allowing the simultaneous sampling of PFC with cartridges and sampling bags. The results showed no significant difference (t-test) between the two sampling technologies and no breakthrough was observed from the cartridges .

Jan 1, 2006