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By Francisco Alberto Marreiros da Rocha Filho

A corrosão é um fenômeno que está intimamente ligado à integridade dos metais e de suas ligas. Esta ocorre de diversas formas, uma das principais é a corrosão localizada na forma de pites, objeto de análise desse estudo, que visa estabelecer um comparativo entre as curvas de polarização cíclica de algumas ligas ferrosas e não ferrosas, ensaiadas em solução de NaCl 0,6 M, mostrando a agressividade que a solução exerce sob cada uma das ligas. Os materiais analisados nesse estudo foram os aços inoxidáveis AISI 304, AISI 444, super duplex ASTM A890/A890 M Grau 6A, o aço carbono AISI 1030, o alumínio comercialmente puro, o cobre eletrolítico e a liga zircaloy- 4. Inicialmente foram medidos os potenciais de corrosão (Ec) de cada liga através do monitoramento do potencial de circuito aberto. Foram realizados os ensaios de polarização potenciodinâmica cíclica em cada liga, comparando o aspecto superficial antes e depois do ensaio através de micrografias óticas, possibilitando que fossem observadas as diferenças entre cada material quanto à resistência à corrosão por pites. Observou-se que algumas ligas não apresentam passivação como o caso do alumínio comercialmente puro, e outras apresentaram regiões passivas e histereses bem definidas, ficando evidente que, dentre as ligas analisadas, o aço inoxidável super duplex ASTM A890/A890 M Grau 6A apresentou os melhores resultados frente aos efeitos agressivos dos íons Cl- presentes na solução, sendo o menos suscetível à corrosão por pites.

Aug 17, 2017

By E. D. Stephenson

As part of the British Steel Corporation?s development plan during the 1970?s, it was decided to concentrate its bulk steelmaking processes based on the BOS at 4 major Works with access to deepwater ore terminals, for the supply of high-grade imported ores. These 4 sites were at: - 1. Rarenscraig Works in Scotland where the ore terminal would be hilt at Hunterston on the west coast some 50 miles away. Bavenscraig was already an integrated Works but suffered from having to discharge ore 27 Glasgow tenxinus on the River Clyde, which could only accommodate vessels up to 25,000 tonnes. In the future, ore was to be unloaded at Runterston and shipped by a rail-link into Ravenscraig, The new ore terminal would have the potential to unload vessels up to 300,000 tonnes. - 2. Port Talbot Works in south Vales where the existing harbour was developed to discharge large ore carriers. This again was an existing Integrated Works and the benefits of the new harbour also applied to Llanwern Works which was another integrated Works some 50 dies to the east, which would now receive ore from Port Talbot.

Jan 1, 1980

By W. W. Adams

Two important facts stand out as features of the metal- and nonmetal-mining4 industry of the United States in 1941 as compared with 1940: First, the number of employees and man-days of employment increased; second, accident-frequency rates, both fatal and nonfatal, decreased. Reports from mining companies to the Bureau of Mines covering underground, open-pit, and surface operations for 1941 re¬vealed the largest number of men employed since 1926 and the largest number of man-days worked since 1929. The combined fatal and non¬fatal accident-frequency rate for 1941, calculated on a basis of one mil¬lion man-hours of exposure to hazard, was (except for 1931 and 1932) the lowest since 1911, the earliest year for which figures are available. During this 31-year period, only 1938 and 1939 showed lower fatality rates, and only 1931 and 1932 had lower nonfatal-injury rates. Operating companies reported that 9,620 mines were active during all or some part of the year. These employed 125,290 men, an increase of more than 4 percent over 1940. The total volume of work performed at all mines, measured in terms of man-shifts, increased to nearly 32 million, a gain of 10 percent; man-hours of employment rose to almost 254 million, an increase of 10 percent over the 231 million man-hours worked in the previous year. The year's operations resulted in an average work-year of 255 days per man, an increase of 13 days per employee over the average working time in 1940. Although the 8-hour day prevails generally at most mines, the industry as a whole averaged 7.94 hours per shift, as in 1940.

Jan 1, 1944

By L. W. Pommier, L. R. Plitt, F. B. Brien

L. R. Plitt (Assistant Professor of Mining and Metallurgy, University of Alberta, Canada.) — It is indeed encouraging to see rheological studies being carried out in a mineral engineering school. The bulk of the work being done today in applied rheology seems to be concerned with the behavior of polymeric solutions and thus has limited application to the solid-liquid systems encountered in mineral beneficiation. The authors have approached the problem by carrying out a dimensional analysis which showed that for power law fluids the drag coefficient, Ds, must be some function of a generalized Reynolds number which has the form: If the power law adequately describes the behavior of a fluid, the dimensional analyses predicts that the Ds - RN function should hold for all values of n' or any other dependent variable. The experimental evi-

Jan 1, 1968

By L. F. Tedsen, A. E. Flanigan, J. E. Dorn

SINCE aluminum-alloy sheet may be used occasionally at moderately elevated temperatures, the effects of temperature en the mechanical properties are of interest. Recently the short-time tensile properties of several high-strength materials have been studied at temperatures up to 375°F. This paper deals with stress-rupture and [ ] creep properties at the same temperatures. The work was done at the University of California as a portion of the project NRC-548. It was financed by the War Production Board and was supervised by the Office of Production Research and Development. This paper has been released for publication by the latter agency. The following materials were studied, all in the form of 0.040-in. sheet: Alclad 24S-T Alclad 24S-T8I Alclad 24S-T86 Alclad 75S-T R301-T (clad) [ ] Specimens were loaded in tension in the cross-grain direction. Testing temperatures included 94°F., 211°F., 300°F., and 375°F. Stress levels were selected to cause rupture in times ranging from several minutes to boo hr. In each test the following data were obtained: (I) fracture time, (2) elongation at fracture, (3) the complete strain-versus-time curve (creep curve), (4) creep rate (defined in a later section). MATERIALS Materials for specimens were obtained from the manufacturers' commercial

Jan 1, 1946

By W. Curlook, L. M. Pidgeon

THE PURPOSE of this investigation was to study part of the ternary system Co-Fe-S. Jensen ( 1) established the solubility limits of sulphur in pyrrhotite. The compound with 61.7 per cent Fe, corresponding to a formula Fe12S13, was found to melt congruently at l,192°C. Hulsmann and Weibke(2) determined the Co-S phase diagram from O to 35.2 per cent S. The solubility limits of sulphur in the com-pound Co(l-x)S were not determined. The initial object of the present in-vestigation was to determine the composition at which the compound Coci-xiS melted congruently. Once this was ascertained, it was decided to investigate the ternary system Co-Fe-S from the region of 100 per cent Co(1-x) S to the region of 100 per cent Fe12S13.

Jan 1, 1953

By H. R. Hernandez-Guerrero, S. A. Robles-Salazar, M. Marín-Pasillas, P. J. Pompilla-Rosales

Peña Colorada is a company dedicated to the exploration, exploitation, and beneficiation of iron ore, serving the national steel industry. Established in 1975 as a stateowned enterprise, it transitioned to operating as a private organization in 1991. It is jointly owned by two investors, ArcelorMittal and Ternium, each holding a 50% stake. The mining operation is situated in the municipality of Minatitlan, in the northwestern part of the state of Colima, Mexico (Figure 1). It comprises an open pit mine and a concentrator, covering an area of approximately 2,300 hectares. The pellet mill is in the town of Manzanillo, Colima state, a port on the Pacific coast, about 46 km southwest of the mine. The pellet mill occupies its own property with a total area of 60.4 hectares. A gravity-driven concentrated slurry pipeline connects the mine and the pelletizing plant, located at an average elevation of 1,020 meters above sea level and 20 meters above sea level, respectively. Currently, Peña Colorada produces 4.1 million tons of pellets and 0.4 million tons of iron concentrate annually. In 2018, due to a change in the cutoff grade, the processing volume of the beneficiation plant increased from 9 million tons to 16 million tons annually. This led to a greater amount of information to process and characterize the ore extracted from the pit before its processing in the beneficiation plant. Consequently, Peña Colorada sought new ore control technologies to enhance ore selection, optimize human resources and data management, as well as minimize discrepancies between planning and execution. To ensure adherence to quality agreements with stakeholders, it is crucial to understand the ore characteristics before initiating mining activities.

Feb 1, 2024

By M. O. Lai

"Metal matrix composite (MMC) with composition of Al-4.Swt.%Cu reinforced by IOwt.%TiB2 or ISwt.%SiC particulate has been successfully fabricated using powder metallurgy technique. Disk, compression and beam specimens were prepared with (a) layered structure containing ductile Al-4.Swt.%Cu with brittle Al-4.Swt.%Cu/TiB2 or Al-4.Swt.%Cu/SiC layers, and (b) homogenous constituent with composition of Al-4.Swt.%Cu/lOwt.%TiB2' The specimens for the fracture toughness measurement were built through three ductile-brittle-ductile alternating layers. For the beam specimens, the layers were built through brittle-ductile-brittle sequence. The brittle layer consisted of Al-4.S%Cu with fixed amount of reinforcement. Fracture toughness testing revealed an increase for layered composites although the total amount of the reinforcement was the same for all disk specimens. The increase in fracture toughness is due to the existence of ductile layers which manifests a strong influence on delaying the occurrence of fracture. It acts as a barrier to resist the propagation of crack and hence increases the fracture toughness of the layered MMC specimens, Delamination in the beam specimens was observed to be due to shear stresses. Fracture surfaces of both disk, compress and beam specimens were characterized using the SEM. IntroductionMechanical and thermal properties can be achieved by the incorporation of refractory secondary phases to constrain the plastic flow of the matrix in a metal matrix composite (MMC). The size of the reinforcement particulate incorporated must be in the range larger than the dislocation cell size and strongly bonded to the matrix (I). Particulate reinforced metal matrix composites hence provide high modulus, improved wear resistance and strength (2-4). Because of the incorporation of refractory phases which are generally brittle, the major limitation in the mechanical properties of MMCs is their limited ductility in comparison to their base metals. Cracks normally initiate from the reinforcement and voids (4, 5). Due to the lack of ductility, cracks propagate rapidly with increase in load. As a result, the interactions between reinforcement particles and propagating cracks have recently been of great research interest (6). In addition, volume fraction of reinforcement and aging condition of the matrix significantly affect the mechanical behaviour of MMCs. In the case of AI-3.5%Cu reinforced with varying volume fractions of SiC particulate, it has been found that the probability of particle fracture increased with increasing volume fraction of reinforcement (7)."

Jan 1, 1996

By I. A. Makalin, V. N. Yakovlev, S. V. Imangulov, I. V. Zyryanov

"The presented studies aimed at solving the problem of recovery of low-luminescent diamonds, which are not recovered using X-ray luminescence method of processing of diamond-bearing ore. The purpose of the studies is the determination of possibility and feasibility of recovery of such crystals using dual-energy X-ray transmission separation technology. In preparation for studies methods were developed for testing technical and process parameters of XRT-400 Aliud GmbH (Germany) sorter, manufactured according to design specifications of Yakutniproalmaz Institute, and XRT/D TOMRA Sorting Solutions GmbH (Germany) sorter, designed for processing of -50+5 mm ore, as well as RGS-1M, RGS-2 X-ray sorters, developed by JSC NPP Bourevestnik (St. Petersburg) in cooperation with Yakutniproalmaz Institute, for material size of -6+3 mm. In 2018, in-process tests of RGS-OD-3 X-ray sorter prototype on material size of -3+1 mm are scheduled. Studies to determine the content of low-luminescent diamonds and feasibility of their recovery using XRT-400 and XRT/D sorters at the Processing Plant #3 of Mirny Mining and Processing Division (MPD) were carried out. The results of the studies confirmed presence of such diamonds and possibility of their recovery using the dual-energy X-ray transmission method. In-process tests of RGS-2 X-ray graphic sorter were carried out at the Processing Plant #16 of Nyurba MPD. According to the results of sampling of RGS-2 sorter separation products, the recovery of -6+3 mm sized diamonds from tailings of X-ray luminescence sorters was achieved at the level of 96%, while the diamonds recovery was 98.5% in value terms, the concentrate yield was 0.1%. In-process tests of RGS-1M sorters at final recovery of the grease separation concentrate at the Processing Plant #3 of Mirny Division were carried out. Recovery of low-luminescent -6+2 mm sized diamonds by RGS-1M sorter amounted to 92.4% for single operation, and with the double control operation reached 99%. As a result, -6+2 mm sized base product recovery increased by 0.2%."

Jan 1, 2018

By C. L. Burrill

The forecasts presented in this paper constitute an attempt by the writer to predict the pattern of the consumption of petroleum products in the United States during the period of transition from war to peace. Although, in preparing the estimates, secular trends were not overlooked, greater emphasis was placed upon considerations of a cyclical character, or upon influences which might be peculiar to parts of the period. The estimates do not extend beyond the year 1950 because by then conditions in the industry should have returned to normal. The consumption of petroleum products is affected, of course, by changes in the condition of business in general. Before estimates of petroleum consumption could be prepared, therefore, it was necessary to predict the pattern of general business during the period under review, particularly the economic series that in the past have shown the closest relationships with petroleum consumption. It is the writer's view that business activity in this country (as measured by industrial production) will be higher on the average during the period between the end of the war and the year 1950 than it ever was before during a peacetime period of the same duration. When the war is over, consumers will have saved amounts of money that will be very large as compared with any previous accumulations. There is little question, therefore, as to the financial ability of consumers to purchase goods. The production of many durable consumers' goods, such as automobiles, refrigerators and radios, has been completely stopped since early in the war; also, many semidurable and nondurable consumers' goods have not been available in the quantities or the qualities desired. There is considerable needi therefore, for consumers to purchase goods after the war. The important question is whether consumers will purchase goods in "1arge enough quantities to keep our economy running at a high level. The writer answers this question in the affirmative. The mere existence of very large consumer savings lends considerable support to this view because, with such backlogs of " security," consumers can afford to spend more of their current earnings than they otherwise could. Also, several polls have been taken, which indicate that consumers expect to buy large quantities of a variety of goods. Some of the savings, therefore, probably will go into current consumption. Even though this percentage is relatively small, so that the bulk of the funds accumulated by consumers during the war continues to remain as savings during the period under review, spending should be great enough to start the production cycle and keep it

Jan 1, 1945

By Robert Kimutis, Ke Yang, Yi Luo, Jianwei Cheng

"Surface subsidence processes, especially those associated with a longwall mining operations, could cause operational and/or safety problems to railroads. For railroads with normal amounts of traffic, both the limited time window between traffic and the limited space available make the efforts to return the railroad back to its original state nearly impossible. In order to ensure the safe operation of a subsiding railway, the partial lifting method has been developed and applied. This paper describes the principle and application of the method. A case of applying this method to mitigate subsidence effects on a long section of railway has been demonstrated.INTRODUCTIONMaintaining an operational railway as it is experiencing a longwall subsidence process is not an easy task. The subsidence process may induce sufficient strain and curvature to cause problems to the railroad structures. Localized subsidence-induced slope often is significantly larger than the permissible ruling gradient of 0.7% for a locomotive to haul a loaded train reliably. In order to ensure safe operation, it would be ideal to instantly lift the railroad track back to its original level as it is subsiding. However, it is often impractical to do so due to the limited time windows available between railway traffic and the available space on the railroad base.A partial lifting method has been developed to keep the railroad operational under such limitations. The subsiding railroad track is raised by only a determined, partial amount of the occurred subsidence at a given time. By making such a determined adjustment, the railroad track can be maintained on a smooth and operational profile, and the high strain and curvature on the railroad structures can be reduced as well. To define a smooth railroad track profile in a subsided section the following two conditions should be met: (1) the maximum railroad gradient should be less than the permissible ruling gradient, and (2) the recommended amount of adjustment should be able to be made by the repair crew within the available time windows between scheduled railway traffic.The subsidence effects on a long section of railroad over two longwall panels have been successfully mitigated using the partial lifting method. The railroad experienced a maximum subsidence 89 of about 5 .0 ft (1.5 m) with the average subsidence along the entire length being about 3.45 ft (1.05 m). However, the average adjustment due to lifting that was made along the entire length of the subsidence-influenced railway was only 0.5 ft (152 mm)."

Jan 1, 2010

Jan. 7, 1952, AIME, Boston Section, Massachusetts Institute of Technology, Campus Room, Graduate House, Cambridge, Mass. Jan. 8, Society for Applied Spectroscopy, 6 pm, supper, Tosca's; 8 pm, meeting, Socony-Vacuum Training Center, 63 Park Row, New York. Jan. 9, AIME, Chicago Section, Chicago Bar Assn., 29 S. La Salle St., Chicago. Jan. 13-15, Institute of Scrap Iron & Steel, Waldorf-Astoria, New York. Jan. 14-1.6, AIME, Minnesota Section, Hotel Duluth, Minn. Jan. 14-18, SAE, annual meeting, Hotel Book-Cadillac, Detroit. Jan. 1.6-18, Society of Plastic Engineers, Inc., annual national technical conference, Edgewater Beach Hotel, Chicago. Jan. 17, AIME, New York Section, Mining Club, 33 Broadway, New York. Jan. 1.7, AIME, Utah Section, Newhouse Hotel, Salt Lake City.

Jan 1, 1952

By S. H. Ash

THIS REPORT covers the second in a series of five projects into which the Conowingo tunnel system has been divided for geographical and practical reasons. It outlines the construction work contemplated-to sink two shafts on the line of the main tunnel that are designated the Nos. 9A and 11 shafts, to turn off from the No. 9A shaft the Lansford and Lykens laterals, and to drive portions of the main tunnel. An emergency pumping plant, consisting of 2 separate pumprooms, each containing 3 horizontal-type centrifugal pumps of 100,000-gallons-per-minute (g. p. m.) capacity, will be constructed at the No. 9A shaft. From the No. 11 shaft will be turned off the Trevorton lateral and portions of the main tunnel, which will connect with the section driven from the No. 9A shaft. Under the proposed project, the Lansford lateral will be driven for a distance of 2 miles, the Lykens lateral for a distance of 10.56 miles, and the Trevorton lateral for a distance of 20 miles. To drive the Lykens and Trevorton laterals for the distance indicated, several construction shafts and slopes must be sunk to permit efficient and safe construction.

Jan 1, 1955

By R. Venkataramani

Crushed stone operations have become more difficult due to rising costs of labor and equipment, with the consequent reduction in profit margins. Competition from other operators and the encroachment of vertically integrated companies place severe restrictions on available markets. The seasonal demand for stone precludes any definite production level, and changes in productivity have to be accommodated. These influence profitability, and therefore production plans must be continuously adjusted to keep pace with rapidly changing conditions. The basic problem of stone companies seeking to maximize profits is one of balancing stone production costs, costs of inventory holding and stock-piling, marketing costs and any other charges accruing over time against the selling price of stone. Because of high peak demands, slack period production must be stored and then distributed to supplement peak period production. For a multi-plant operation, there is a need to evaluate at the same time the interaction between the plants and the various marketing sectors. In a multi-plant operation with different production capacities and production costs, stone producers are interested in the answers to the following questions: 1. How much stone should be produced at each plant in each time period? 2. What should be the optimum stone shipment from each plant to each market? 3. What are the effects on net returns and shipping plans, if production capacities are altered at the plants? These questions have many different answers that, will satisfy demands. From the point of production scheduling, the minimum production cost may be the objective. From the inventory standpoint, the best solution will be to synchronize production with sales. However, when the transportation of stone is also considered, the desired end is to achieve that delivered cost which maximizes the company f s net return. Besides, only an extremely naive analysis ,wouId attempt to

Jan 1, 1971

By X. Wang, Y. Luo

The propensity of coal spontaneous combustion can be evaluated using various laboratory testing methods, such as R70 adiabatic tests, thermal gravimetric analyzer (TGA) tests and critical self-heating temperature (CSHT) methods. Each of the methods has its unique characteristics and index for classifying the propensity of self-ignition of coals. Accountable relationships among the propensity indices of different methods should be established. Using the newly established R70 and TGA testing setups in our ventilation laboratory, samples from U.S. coal mines have been collected and tested. The TGA is a relatively new quantitative method. A test can be conducted in a relatively short time, within about one and a half hours, compared to the adiabatic tests. The temperature and weight of the sample can be measured with high precision and then used to determine the activation energy of the coal, which is a good indicator of the potential for self-heating. Under a specific experimental design, the TGA technique could perform the proximate analysis for determining coal quality parameters (e.g., moisture, volatile matter, fixed carbon and ash content). These parameters can be used in an empirical equation for assessing the potential for coal self-ignition. The trend of activation energies determined using TGA techniques is reasonably consistent with the trend of activation energies determined using adiabatic tests. As a case study, a comparative analysis of these two methods for determining activation energy was made on coal samples collected from Indiana. The kinetics of the spontaneous combustion mechanism has been explained. If the functional groups of a coal such as hydroxyl (-OH), carboxyl (-COOH), methyl (-CH3), etc., activate more easily with a small amount of activation energy at a relatively low temperature, the coal will have a higher potential for self-heating. With the kinetic and coal quality parameters determined by the TGA setup, it has been found that the coal with a low potential for self-ignition has low self-heating rate, a high activation energy and a high minimum self-heating temperature.

Jan 1, 2012

By Brenton Cook, Nate Long, Larry Applegate, Aaron K. McCain

"The Northgate Link Extension project is the third phase of the Sound Transit master plan to extend light rail throughout the greater Seattle metropolitan area. When completed, the Northgate Link Extension will extend the existing light rail system north by about 7 km (4.3 miles) from the University of Washington to the Northgate neighborhood. A general overview of the project alignment is provided as Fig. 1. The project was funded by a combination of federal grants and allocations from local taxes. The general contractor on the project was JCM Northlink LLC (JCM), a joint venture between Jay Dee Contractors, Frank Coluccio Construction Company and Michels Corp. SoilFreeze, Inc. was retained as a subcontractor to provide ground freezing design and construction services.The project involved the construction of two parallel 5.5-m, 25-cm (18-ft, 10-in.) (inside) diameter tunnels using earth pressure balance (EPB) tunnel boring machines (TBM) and precast segmental concrete tunnel liners. The two tunnels maintained roughly the same elevation along the alignment and were spaced roughly 12 m (40 ft) apart (centerline to centerline). A total of 23 cross-passages connecting the two tunnels were included at approximate 244-m (800-ft) intervals. Cross passage excavations were elliptical in shape with dimensions of approximately 5.6 m (18.5 ft) in height and 5.3 m (17 ft) in width. The cross-passages were 5.8 to 6.1 m (19 to 20 ft) long as measured between the exterior of the tunnels at springline elevation. Cross passages were intentionally located directly beneath public right-of-ways thus avoiding buildings. Many of the cross passages were located beneath narrow roads in residential neighborhoods with mature vegetation, existing utility structures and piping and limited parking areas. Excavation and support for each cross passage was completed using the sequential excavation method (SEM).The subsurface soil and ground water conditions at the cross-passage locations were described in the Northgate Link Geotechnical Baseline Report (GBR) prepared by Jacobs Associates and the Northgate Link Geotechnical Data Report (GDR) prepared by Shannon and Wilson, Inc. Soils along the project alignment were glacially overridden and characterized as very dense or hard. Subsurface soils consisted of cohesionless sand and gravel (CSG), cohesionless silt and fine sand (CSF), cohesive clay and silt (CCS) and till and till-like deposits (TLD)."

Dec 1, 2018

By L. L. Tavlarides, N. V. Deorkar

"Recovery/Recycling of metal ions from industrial process waste streams is a preferred alternative to disposal by conventional techniques. This paper presents methods for preparation of inorganic chemically active adsorbents to be used in fixed bed adsorbers. Methods for immobilization of chelating agents on the inorganic supports are discussed. The prepared adsorbents are characterized to determine coverage density of functional groups, effect of pH on metal ion removal efficiency, regeneration efficiency and uptake capacity. Results from the laboratory scale and bench scale experiments are presented here.IntroductionRemoval of heavy metal ions from processing wastes in various industries is an important problem. Waste streams in electroplating, electronic, catalyst preparation and hydrometallurgical industries contain metal ions such as copper, nickel, chromium, lead, tin, cadmium, silver, gold and platinum. One major concern for the non-ferrous metal industry is secondary recovery of precious metals and cyanide from cyanide leachate from smelter residue and hydrometallurgical waste streams.Recovery methods recently considered include evaporation, electrolyte metal recovery, reverse osmosis (1), adsorption, ion exchange (2,3), membrane separation (4,5) and Solvent extraction. These processes have met with various levels of limited success. The use of liquid ion exchange molecules to selectively extract metal ions for on-site treatment of these waste streams is currently receiving substantial interest (6,7). This interest seems from an awareness of the advances made in the development of commercial extractants for metal ion separation in hydrometallurgical industries (8). However, separation by solvent extraction processes is generally considered to be economical in the range of aqueous metal ion concentrations from 0.01 to 1.0 mol/lit (9). In order to exploit the selectivity of chelating agents, the idea of immobilizing chelating agent into a solid matrix has attracted growing attention in recent years. Many supports such as inorganic oxides, organic polymers, cellulose powder and polyurethane foam can be used for immobilization of chelating agents. Over the last decade, considerable efforts have been directed toward attachment/introduction of chelating agents into a polymer matrix (10,11). Inorganic supports as compared to polymer supports provide high mechanical strength, chemical and thermal stability, and high reaction rates due to open pore structure. On the contrary, organic resins shrink and swell, thus affecting mass transfer (12). Many of the disadvantages of polymer supports can be excluded by the use of inorganic supports. Innovative use of immobilization techniques can produce inorganic chemically active adsorbents with comparable capacity, stability and reaction rates. Consequently, the objective of our program is the development of inorganic chemically active adsorbents to be used in a fixed-bed unit operation as an alternative heavy metal ion recovery process. Methods of preparation of inorganic chemically active adsorbents, (ICAAs) characterization and applications are discussed in this paper. A brief summary of the results from laboratory scale studies and bench scale studies is presented."

Jan 1, 1996

By James Coull, Brian Wilson, David Siddle

"In 2012, Golder Construction Inc. was awarded a Design-Build contract for the design and construction of an extensive, deep ground improvement scheme to support up to 20 metres (66 ft) high Mechanically Stabilized Earth walls and bulk earthworks required for the development of the proposed Kitimat Liquefied Natural Gas (LNG) facility at Bish Cove, British Columbia (BC). Utilizing Cutter Soil Mixing (CSM) to construct barrettes consisting of overlapping rectangular panels of in-situ cement-treated soils, a deep mixing scheme, covering an area of approximately 12,900 m2 (15,430 yd2) and comprising some 1645 CSM panels to depths of up to 30.7 m (101 ft), was developed to provide the required static and seismic stability for the LNG structures, and meet the project-specific performance criteria.CSM panels were constructed through varying thicknesses and discontinuous layers of fine-grained, very soft to soft marine deposits, and loose to compact sands, with occasional interbeds of dense sands and gravels. Panel completion criteria was based on soil response factors, as measured by the CSM equipment, with the design requiring a typical embedment of about 2 m (7 ft) into dense silty sand to sand and gravel to provide the required bearing. A total volume of approximately 73,900 m3 (96,660 yd3) of soil was treated with cement to consistently yield average unconfined compressive strengths exceeding 2.5 MPa (363 psi).This paper outlines the challenges associated with the construction and quality control of this large deep mixing scheme in highly variable geotechnical conditions at a remote location with barge-only access, and limited communication facilities. Specifically the paper will discuss the logistical challenges faced and solutions adopted for the project; equipment redundancy requirements for a 24/7 operation; the impacts of wear and tear, as well as variability in subsurface conditions on productivity; quality control processes adopted for the project, including the value of provision of an on-site laboratory; and materials handling issues, and their impacts on mix design and quality control."

Jan 1, 2017

By G. H. Alani, H. T. Kennedy

One of the major difficulties in predicting the performance of oil reservoirs from their early pressure history lies in the uncertainty of estimating the volume of the liquid hydrocarbons contained in them. As a first step in filling this need, an equation was developed to determine the Inolal liquid volume of pure hydrocarbons over a wide range of temperature and pressure. The second step consisted of adapting the equation to apply to mixtures, with the heary hydrocarbons expressed as c The equatious are similar in form to van der Waals equation. hut the constants a and b tire considered as furnctions of temperature. In addition to the gas constant R, there are four constants characteristic of each hydro- When comptired with experimental values jound in the literal the. the average absolute deviation in the calculated molal volumes is found to be a Maximum of 0.33 per -cem for any of the pure liquid hydrocarbons studied. This maximum deviation was that found when comparing the calculated and observed values over a temperature range of 86° to 482°F and a pressure range from the bubbl-point ro 10,000 psis. The equations expressing the correlation for. mixrurrc were developed from 647 experimental measure-rilents of volume on 47 bouom-hole samples covering ; temperature range of 72" to 250°F and a pressure znge from bubble-point ro 5,000 psig. The average absotute deviation was found to he 1.6 per cent with the maximum for any measurement of 4.9 per cent. INTRODUCTION Accuratc information of the pressure-volume-temper-iiture behavior of hydrocarbon liquids is of considerable importance in the field of both applied and theoretical science and, especially, in the solution of petroleum reservoir engineering problems. These PVT relationships can be expressed graphically, in tabular form or as equations of state. Equations of state for gases have been developed based on the ratio of pressure, temperature and volume to the pressure, temperature and volume at the critical points of the hydrocarbons. These equations have been successful in yielding values fairly accurate for reservoir engineering purposes. For liquids, however, relations of this type are more complex and have not yielded useful results. The composition of reservoir liquids is normally expressed in terms of the moles of hydrocarbons C,? C,. C,. elc, per mole of mixture. The composition must include the fraction of a mixture such as C,,, which cannot be separated with reasonable time and effort into specific hydrocarbons. Although there are several equations of state having variable degrees of accuracy applicable to pure liquid hydrocarbons, none includes a means for estimating the volume of mixtures as a function of temperature. pressure and composition expressed in this manner.

By N. Sinclair

"In open pit dozer bulk push operations, the material left resting against the highwall after blasting poses an issue. This is because dozers cannot physically get in behind the waste to begin the bulk pushing process. Instead, an excavator can be used to side-cast this waste for the dozers to access. An alternative technique is to have the dozers ‘side-cut’ the material, which involves the dozers running parallel to the wall, digging out the material, and eventually rotating their blades to begin bulk pushing. Industry practices suggest the latter technique is less productive and economical than using an excavator. However, such excavator sidecasting ‘economic viability’ assumes that smaller/ancillary type excavators are used (i.e. less than 23 m3 bucket capacity). So, what happens if some mine sites are restricted to using relatively larger excavators (> 23 m3 bucket) that are preferred for higher priority digging tasks? When can they avoid using their excavator? This paper explores multiple scenarios that have been designed and developed to simulate data results, which identify conditions in which the dozer side-cutting technique becomes more economically viable than excavator side-casting in terms of decreased unit cost per loose cubic metre. IntroductionOptimizing the cost of waste removal operations is important for the profitability of opencast coal mines. In the past decade, dozer bulk pushing has emerged and taken over from traditional waste removal operations such as dragline and truck-and-shovel methods at various sites around the world (Beatty, 1994). In a typical bulk push operation, once the bench has been blasted, waste is left resting against the highwall, which can either be cleared using a loading unit or by having the dozers ‘side-cut’ the highwall.Dozers perform most effectively when slot dozing side-by-side, perpendicular to the highwall. However, when dozers are required to remove material off the highwall, they must push parallel to the highwall, rather than perpendicular, hence ‘side-cutting’ the material to ensure a clean face. While dozer sidecutting is possible, it has been found that the majority of mine sites use a loading unit in this situation to avoid dozer inefficiency. Other perceived issues with dozer side-cutting include higher maintenance requirements and safety risks to dozer operators working in close proximity to the highwall."

Jan 1, 2019