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By K. Peri

The leaching behavior of gold in ammonical solutions with iodine as an oxidant has been investigated using cyclic voltammogram and Tafel polarization. The majority of experiments was carried out at 75°C and the results were compared with the equilibrium consideration on the iodine-ammonia system. The distribution of nine iodide containing species at various pH values in the absence and presence of ammonia was considered at three different temperatures. It was found that by introduction of ammonia into the system, the concentration of iodide (r), iodine (12) and triiodide (13') is increased substantially which in turn helps the rate of dissolution of gold. The apparent activation energy was found to be about 46 kJ/mole, indicating a chemical controlled mechanism.

Jan 1, 1999

By D Wardiman, R Benton, D Sims, T Carr, V Singh

The Kencana underground gold mine comprises two world-class epithermal vein deposits located in the North Maluku province of Indonesia on Halmahera Island. The K1 deposit has a recent extensive mining history, whilst development of the K2 deposit is in progress. Kencana epithermal vein zones have a relatively simple planar geometry dipping 25 to 45¦ towards the East and extend 400 to 600 m along strike and down dip. True width ranges from 1 m to 20 m. Economic gold grades are generally associated with two distinct mineralisation styles: Main Zone û continuous material characterised by classic epithermal vein textures including crustiform/colloform chalky white quartz- adularia sulfide banded and brecciated veining typically grading 10 to 40 g/t Au. Bonanza Zone û semi-continuous identifiable zones within the Main Zone. Characterised by brecciated quartz-adularia sulfide banded vein æginguroÆ material typically grading 80 to 200 g/t Au. Associated with this æBonanzaÆ zone are gold grades averaging around ten times higher than the surrounding Main Zone. At the resource evaluation stage, these deposits are typically drilled on approximately 25 m by 25 m spacing. This drilling density is usually adequate to allow robust estimation of global resources, including the lateral definition of æBonanzaÆ style mineralisation. It appears intuitive at the resource definition stage to separately model the æBonanza ZoneÆ using deterministic methods such as manual interpretation and wireframing. Inevitably, however, such deterministic methods result in a simplified version of reality. Whilst the geologistÆs interpretation of the overall vein volume and lateral extent of æBonanzaÆ mineralisation has proven to be remarkably accurate, close-spaced sampling and mapping of the K1 orebody has shown that this style of mineralisation exhibits extreme short-scale geometric and spatial variability. A consequence of this short-scale geometric and grade variability is the significant uncertainty with reporting these Resources and Reserves at relatively small reporting time periods such as monthly production periods. The mining method employed at Kencana often involves extracting the full width of the mineralised vein with multiple mining passes over several months. In the past it has proven difficult to achieve accurate production budgets and forecasts at Kencana as any given mining schedule based on the resource model is acutely sensitive to the quantity and location of æBonanzaÆ material. Moreover, the degree of uncertainty or risk associated with a mining schedule significantly increases as the reporting time period becomes smaller. A further deficiency of deterministic methods for geometric modelling is the inherent lack of ability to derive confidence intervals for quantifying uncertainty and risk. The use of conditional simulation techniques can help overcome this deficiency. Geostatistical conditional simulation techniques have been applied at Kencana in an attempt to model and quantify geological and grade variability in the upcoming K2 orebody based on the experience to date with mining the K1 orebody. At Kencana, conditional simulation has provided a successful means to quantify uncertainties and risks associated with various data densities and reporting time periods. The results of this project have provided managers and planners with a clearer understanding of the likely variances and risks associated with predicting gold metal production at key reporting time periods based on data at the resource model level of resolution. With corporate requirements to adhere to mining budgets/quarterly schedules, this type of analysis allows a more scientific approach to estimating grade uncertainty in the mining schedule. Until now this has been difficult to quantify due to the extreme gold metal variability. The availability of this type of analysis allows a time-efficient rationalisation on redesigns of the mining shapes and effective communication of the likely uncertainties involved.

Jan 1, 2009

By M. S. Moats, C. M. Campbell

Samples of a high impurity (90.05 wt. % Cu, 4076 ppm Pb, 1939 ppm As and 635 ppm Bi) commercial copper anode were characterized and then electrorefined in a laboratory scale cell. Anode inclusions were examined using backscatter mode scanning electron microscopy and energy dispersive spectroscopy. Hundreds of inclusions were measured for size, morphology and composition. Commonly found inclusions were copper oxide (Cu2O), complex oxides (Cu-Pb-Bi-As-O) and copper selenides/tellurides. The weight percent of lead and arsenic increased with increasing inclusion size up to 4- 5 microns. During electrorefining, starter sheet ductility was negatively impacted by thiourea addition. The importance of arsenic (V) concentration on the electrolyte concentration of bismuth was observed. INTRODUCTION Copper electrorefining is a commercial process used to produce the majority of the world’s refined copper. During this process, impure copper anodes are dissolved electrolytically, and high purity copper is deposited on cathodes. As the anodes dissolve, the impurities either accumulate in the electrolyte or report to solids that form on anodes surfaces or at the bottom of the refining cell. These solids are called slimes. Slimes contain precious metals and are collected for further processing. Slimes are also an important outlet for problem impurities such as lead, antimony and bismuth. The electrorefining process is operated in such a way to encourage the deportment of these elements to the slimes. Impurities in copper anodes have been studied extensively by Chen and Dutrizac (1990, 1993 and 2005). The most common impurities found in modern copper anodes include: Ag, As, Au, Bi, Fe, Ni, O, Pb, Sb, Se, Sn and Te. Impure copper anodes are produced by pyrometallurgical methods and have purities ranging from 97.7–99.7% Cu (Moats et al., 2019). The composition ranges of commercial copper anodes from the 2019 worldwide tankhouse survey are given in Table 1. The concentrations of anode impurities vary widely dependent on the source material and prior processing steps. Based on the work of Chen and Dutrizac, both gold and silver are predominantly found in solid solution within the copper grains while a minor amount of Ag can be found in Cu2(Se/Te) inclusions. Nickel is entirely soluble within the copper grains up to anode compositions of 2500–3000 ppm Ni; above which NiO and kupferglimmer phases are formed (Chen & Dutrizac, 1990). As, Bi, Pb and Sb are found in solid solution within copper and within oxide inclusions typically found along grain boundaries. Oxides are formed due to the presence of 0.13-0.18 wt. % O (Chen & Dutrizac, 1990). This is because during solidification of the cast anodes, impurities are enriched in the liquid phase as the copper grains nucleate and grow. The inclusions form from the last liquid to freeze, which is typically along grain boundaries (Wenzl & Filzwieser, 2007; Wenzl, Filzwieser, Mori & Pesl, 2008).

Jan 1, 2019

By Paul H. Mutschler

The Bureau of Mines sponsored a study of the impact of changing technology on the demand for metallurgical coal and coke to 1985. Individual technologies were analyzed to determine what effect each had on the demand for and the consequent consumption of metallurgical coal and coke in the steel industry. The domestic steel industry demand for metallurgical coal and coke for the production of hot metal will probably increase through 1985. Formcoke if implemented on a worldwide basis could begin to supplant the U.S. export market for metallurgical coal. The major technologies that have contributed to the decline in demand for metallurgical coke per ton of hot metal are (1) the increased usage coupled with higher iron content of agglomerates, (2) modification of blast furnace practices such as high top pressures and blast temperatures, and (3) increases in the injection of supplemental fuels. The projected demand for metallurgical coal and coke under current technology for 1985 are 109.4 and 76.0 million tons, respectively. With future technology implemented, the demand for metallurgical coal and coke will be 82.0 and 56.9 million tons, respectively. The projected domestic demand for metallurgical coke could further decrease by as much as 15 to 20 million tons by 1985 if formcoking proves technologically and economically feasible.

Jan 1, 1975

Held at San Francisco, Cal., Thursday to Sunday, Sept. 16 to 19, 1915 COMMITTEES Arrangements CHARLES W. MERRILL, Chairman EDWARD H. BENJAMIIN H. C. HOOVER FRED `V. BRADLEY W. C. RALSTON ABBOT A. HANKS G. H. CLEVENGER Excursion and Accommodations ABBOT A. HANKS, Chairman E. T. BLAKE R. H. BEDFORD C. G. DENNIS FREDERICK BRADSHAW C. E. GRUNSKY, JR. EDMUND JUESSEN ARTHUR B. FOOTE F. A. KEITH GEORGE 0. BRADLEY CHARLES JANIN E. N. ENGELHARDT R. S. HASELTINE N. CLEAVELAND

Jan 12, 1915

By J. Van Kleunen

In the Spring of 1959 the Riverside Cement Company, a Division of American Cement Corporation, placed into operation at their Oro Grande California plant a new crushing-blending-reclaiming facility. This new facility, in conjunction with other modernization in the plant, has established a degree of automation and reliability on a-plant-wide basis which heretofore had not been attained in the industry. The blending and reclaiming facilities for raw stone and cement clinker at this plant represent not only the first computer programmed materials handling system of its type in the industry, but also the first installation of specialized equipment which was designed for high capacity, fully automated operations.

Jan 1, 1963

By J. F. Radavich

Many heats of steel of low carbon value have been known to produce brittle pieces of steel. The brittleness is believed to be due to the impurities located within the grain boundaries. Such brittle steels have been examined with an optical microscope to ascertain the nature and the amount of the impurities present at the grain boundaries. Due to the relatively low resolving power of the optical microscope, the impurities are not visible in fine detail. The writer obtained some sheet steel and proceeded to determine the location of the impurities and to show the application of the electron microscope to the study of grain boundaries. One sample was known to be capable of becoming embrittled, whereas another sample was believed to be much less susceptible to embrittlement. Treatment of Specimens The specimens were embrittled by annealing above the A3 point under mildly oxidizing conditions. One piece of ingot iron could not withstand a 90" bend, whereas another piece of ingot iron was not affected and could withstand a 90" bend. The brittle piece was then annealed at a high temperature in a hydrogen atmosphere. The annealed ingot iron was termed cured and could withstand a 90" bend very easily. The three specimens examined will be designated as brittle, good. and cured in the discussion that follows. Procedure The sizes of the specimens were as follows: one piece of brittle ingot iron-3/8 by 35 in.; one piece of good ingot iron-96 by 1/8 in.; one piece of cured ingot iron-36 by 54 in. The specimens were too small to be polished by hand and therefore were mounted in bakelite. The polishing procedure was carried out in the conventional manner with the use of 1/0 through 3/0 papers, and the final polish was done with alumina on a billiard cloth. The specimens were then etched in a 4 pct solution of picral in alcohol, and then they were examined through an optical microscope. An area was chosen that showed distinct grain boundaries, and an effort was made to keep near this area when pulling the replicas REPLICA TECHNIQIJE The replica technique used in the preparation of the replicas for examination under the electron microscope is described in Electron Metallography.' It consists essentially of the following steps: 1. Obtaining a suitably etched specimen. 2. Applying a swab of ethylene di-chloride on the surface. 3. Applying a formvar solution on the surface. 4. Placing a screen on any desired spot. 5. Breathing on the fornivar layer. 6. Applying scotch tape on the screen and film. 7. Pulling the film and the screen up with the Scotch tape. 8. Separating the screen from the Scotch tape. This replica technique is very similar to the one described by Harker and Shaefer. However, with the added step, the percentage of replicas removed is very much higher regardless of the length of the time from the etching of the specimen to the actual pulling of the replica. The replicas were then shadow cast with manganese at a filament height to replica distance ratio of 1 1/2:7. This produced a very high contrast replica for use in the electron microscope. One of the dificulties encountered with this study was the restricted area of the specimen. The width of the specimens was the same as that of the 200 mesh nickel supporting screen. In order to increase the effective area, the screens were cut down as shown in Fig 1. The arrow indicates the direction in which the replica was pulled. This operation made it possible to obtain a large percentage of good replicas. Fig 3 shows an electron micrograph of a brittle piece of ingot iron and a grain boundary that was polished mechanically. The surface is very rough probably due to the incomplete removal of the flowed layer by the picral etchant. The grain boundary does show evidence of impurities. It was decided to electropolish the specimens to obtain a much smoother surface than the one obtained by mechanical polishing. ELECTROPOLISHING The specimens were cut in half to expose the metal on the back side. The exposed metal had sufficient area to make good electrical contact and electropolishing was carried out easily. The conditions for electropolishing were 0.9 amp, 35 volts, and 25 sec. in an electrolyte composed of 850 cc of ethyl alcohol, 100 cc distilled water, and 50 cc of perchloric acid. The polished specimens were then etched in the 4 pct picral solution for a shorter time than was necessary for

Jan 1, 1950

By Jerry H. Service, F. L. Partlo

The following investigation was undertaken to develop a method for determining with reasonable accuracy the depth of overburdens of 100 ft. or less. Seismic methods seemed to offer good possibilities. The problem differed from that of the familiar salt-dome location in that the depth of overburden to be determined is much less than is encountered in oil prospecting. This means that a much shorter time interval must be measured with accuracy. Refraction methods seem at present to offer greater possibilities than reflection. The air sound persists for from 0.1 to 0.5 sec., because of echoes, and seismic reflections coming during this time are difficult to detect. A seismometer sensitive to vertical vibrations only offers possibilities and has been used here with some success. It is hoped that the application of this type of seismometer to reflection shooting in this region may be investigated still further. The apparatus used consisted of a carbon-button seismometer followed by a three-stage, transformer-coupled, vacuum-tube amplifier and a General Radio string oscillograph. Time marks are provided by a 1000-cycle, 600-r.p.m., synchronous motor provided with five spokes which intercept the light to the camera at 1/50 sec. intervals. This motor is driven by a two-stage vacuum-tube amplifier of 3 watt output, actuated by a tuning fork. The power supply for the seismometer amplifier is one 2-volt storage and one 45-volt B battery. The motor amplifier is powered by a 6-volt storage battery and 6 to 225-volt, 15-watt motor generator. The temperature-frequency characteristics of the tuning fork have been determined and for ordinary working temperatures the error in time that would be introduced is less than M millisecond for time intervals up to 100 milliseconds. The impact is produced by a sledge blow for surface distances less than 100 ft. and dynamite for greater distances. Two steel balls with wires attached form an electric circuit through a 1-ft. piece of railroad rail upon which they rest. When the rail is struck by the sledge the balls rebound, opening the circuit and indicating the time of impact by a break in the oscillograph record line as at A, Fig. 3. When dynamite

Jan 1, 1934

By Norman C. Britz, Mortimer P. Buck

THIS PAPER DEALS WITH the practices used at the Huntington, Nest Virginia works of The International Nickel Company, Inc., in hot and cold rolling nickel and high-nickel alloys. The practical metallurgical aspects are discussed and a brief description of equipment given. The alloys covered may he divided into three main groups. based on their major constituents: 1. Nickel alloys, 2. Nickel-copper alloys. 3. Nickel-chromium alloys. The nominal compositions of the various alloys which are produced in most common mill forms are given in Table 1. Nickel, a commercially pure grade of nickel containing about 0.05 pct carbon as' the chief alloying element, is produced in all common Mill forms. "L" Nickel is commercially pure nickel in which the carbon content is held as low as possible, usually less than 0.01 pct. This grade of nickel is used chiefly for spinning and for special high temperature applications where its low carbon content enhances its corrosion resistance. "D" Nickel contains 4.5 pct manganese to provide improved resistance to sulphur embrittlement at elevated temperatures. "Z" Nickel is an age hardening grade of nickel containing carbon, aluminum, and silicon as the age hardening elements. This alloy combines the cor-

Jan 1, 1948

By Thierry De Nys

A direct leaching process of sulphidic zinc-based concentrates in aqueous sulphuric acid solutions has been developed by the V.M. R & D Department. By a very accurate control of the oxidation potential of the leach solution, this process enables a separate recovery of the zinc, copper, silver, lead and sulphur of the concentrate and makes it extremely attractive for treating more complex ores. The iron, solubilized during leaching, is eliminated out of the zinc solution by means of the V.M. goethite process. Alternative flow sheets for a conventional zinc electrolysis plant are presented.

Jan 1, 1990

By James E. Lawver

Part I describes the general geology of the Florida deposits. As the lucrative Bone Valley Formation is depleted, replacement production will move progressively into areas of total Hawthorn production. The reserves of the immediate future are a mixture of two distinct ore types referred to as the upper (high grade) zone and the lower (low grade) zone. The upper zone is somewhat similar to the Bone Valley Formation that has been Florida's source of production for the past 100 years and will respond favorably to present beneficiation practices. By contrast, the lower zone ore contains significant quantities of dolomite that must be removed in order to produce an acceptable grade pebble or flotation sized product. Part II reviews past practice and describes future trends in mining and ore transportation. This presentation (Part III) is confined to the problems of beneficiation, waste disposal, and environmental regulation.

Jan 1, 1983

By R. S. Sandhu, L. E. Baker, W. Y. Shieh

The finite element method of analysis was introduced by Clough.1 Within a short period, it has developed into a powerful solution technique in structural and continuum mechanics. It has been used to solve boundary value problems in two and three-dimensional elasticity.2-5 Anisotropy and heterogeneity of materials were allowed for at the earliest stages. 1,4 Its application has been extended to allow for cracks,5 creep and viscoelasticity, 6,7 incremental construction,6-8 nonlinear elasticity3,9 effect of joints in rock,10 and to materials with different behavior in tension and compression.7 Because of its versatility, the finite element method has found increasing application in the field of rock mechanics. In fact, several of the more significant developments have been motivated by problems in this field. Elasto-plastic material behavior based on the incremental or rate-type theory of plasticity rather than the deformation theory was considered by Reyes and Deere11 A material law based on a generalization 12 of the Mohr-Coulomb criterion was used. In this chapter, the formulation of material laws developed by Reyes and Deere 11 is used. An efficient analysis procedure, incorporating recent developments in finite element analysis, is developed for plane-strain conditions. To demonstrate its effectiveness, the procedure is applied to three cases, one for which an exact solution is available, another for which field observations had been made, and a third one for which a parallel study was made, using an accepted limit-equilibrium method.

Jan 1, 1970

By Thomas C. Patton, Eric S. Cheney

L-D gold mine is 3 miles south of Wenatchee, central Washington. Recognition of locally mappable conglomerates, sandstones, and shales within the Paleocene (?) Swauk formation led to the discovery that the known epithermal gold mineraliza¬tion is limited to a previously unknown imbricate thrust zone of unknown displace¬ment cutting the open folds o f the area. Hypabyssal intrusions also are most nu¬merous along the trace of the thrust faults. Yakima basalt of Miocene age uncon¬formably overlies the Swauk formation, thrust faults, and the intrusions. The L-D mine is in a northwesterly trending imbricate fault block of nearly vertical strata. Microscopic native gold, electrum, and naumannite occur in quartz veins and as low¬grade disseminations in the well-silicified portions of arkosic sandstones. Fault gouge on the "footwall fissure" limits ore to the hanging-wall block of the fault. Epithermal mineralization and alteration are spatially related to the nearby intrusions. Right lateral north-south faults offset the ore a maximum of 300-400 ft along any one fault. From 1949 until January 1967, when the L-D mine closed, 1,036,572 dry tons of ore valued at $14,962,305 and averaging 0.396 oz Au per ton and 0.607 oz Ag per ton were mined. Recognition of the structural control of the mineralization and altera¬tion within the Swauk formation suggests several areas within and outside of the mine that warrant further exploration. For example, the high-angle faults, imbricate thrusts, and the intrusions of this area are on strike with similar features along the major Entiat fault zone 10 miles to the northwest. The L-D gold mine (previously called Squilchuck, Wenatchee, Golden King, Gold King, and Lovitt) is located in Squilchuck Canyon about three miles south of Wenatchee, Chelan County, Wash. (Fig. 1) on the eastern edge of the Cascade Mountains. The major stratigraphic unit in the area is the nonmarine early Tertiary Swauk formation, which is predominantly com¬posed of arkosic sandstone. The lack of laterally per¬sistent units and the paucity of outcrops heretofore have precluded all but the grossest subdivision of the Swauk.' As a result, the true significance of the open folds in the Wenatchee area was not recognized, and although the geology within the mine was known, the structural setting of the mine was virtually unknown. During the present investigation, several locally map¬pable units were discovered within the Swauk which, in conjunction with mine maps, indicate an imbricate thrust zone. The epithermal gold mineralization, most of the hypabyssal intrusions, and the zones of hydrother¬mal alteration are located within or near this thrust zone. The purpose of this paper is to: (1) to describe this structural setting, rather than the detailed mine geology already presented by Lovitt and Skerl,2 and (2) to sug¬gest that from an exploration standpoint, this struc¬tural setting may be repeated in areas inside and outside of the mine area. Stratigraphy and Structure of the Swauk Formation General: The Swauk formation contains three distinct lithologies. Typical Swauk sandstone is gray on fresh surfaces, poorly sorted, weathers tan, and is cross¬bedded; it consists of 40-60% quartz, 20-40% feldspar, and up to 10% muscovite and biotite 9 The typical shale is gray to dark brown, very soft, and interbedded with silty sandstones; sharp contacts exist between the

Jan 1, 1972

By George Hufford

An investigation is made into the applicability of queueing theory to simulating the operation of a large open pit copper mine in the southwestern United States. Actual data from a working mine was used to construct curves for truck loading time, haulage and return time, and dumping times. Known results of investigations of queueing models (Koenigsberg - 1958, Gordon and Newell - 1967, Cabera and Maher - 1973) were used to simulate the actual operation. These did not give acceptable results so commonly used probability distributions were fitted to the actual data. A large computer program known as Q-GERT was used with the various parameters obtained from fitting the curves. Kolmogorov- Smirnov tests were run that showed that this was not satisfactory either. Finally, Q-GERT was used with the actual data from the mine. An appropriate correction factor is then found to apply to the exponential probability distributions tested previously and satisfactory results are obtained.

Jan 1, 1981

By Yanhui Sun, Yanan Zeng, Kaike Cai

"Hot ductility of Nb-V-containing steel has been studied by theoretical calculation and thermal simulation experiment. Meanwhile, microsegregation and precipitates were analyzed. The results showed that segregation degree of elements S, P, 0 is greater in mushy zone, while, the hot ductility was deteriorated by inclusions of Fe(S,O), (Fe,Mn,Si,Al)(S,O) in the interdendritic region. At the temperature 1100°C, a few NbN particles, 60-70nm, have little effect on mechanical property. In the temperature range 1000°C to 975°C, R.A declined rapidly from 82.36% to 69.61% with the diameters decreasing from 20 to 10nm and quantity of particles increased 23 to 45inds/µm2, respectively. In the temperature range from 900°C to 850°C, R.A reduced unobviously from 34.27 % to 30.01 % with ferric films thickening gradually. The critical stress, 52.38MPa, was equal to tensile strength at 975°C. Intergranular fracture was easy to occur with higher critical stress below 975° C.IntroductionProductivity and product quality of slab are seriously affected by cracks during continuous casting and the influencing factors of cracks are various[l]. From microcosmic angle, resisting deformation ability of initial solidification shell decreases obviously with solute elements segregation which can urge the low melting point ofliquid film to form at grain boundaries[2, 3]. Meanwhile, with temperature decreasing, particles would precipitate as the practical solubility product is greater than equilibrium solubility product. The carbonitrides would lead to stress concentration at austenite grain boundaries. Therefore, the transverse cracks of microalloyed steel would form during the straightening operation in the continuous casting process. The hot ductility of steels in the temperature of mushy zone was characterized by microalloy elements segregation, zero strength temperature (ZST) and zero ductility temperature (ZDT). The nature, shape, and size of precipitates have been investigated by TEM (JEM2100). Hot tensile test with low strain rate was simulated by Gleeble-1500. The objective of present study is to provide reference for zero defect of microalloyed steel during continuous casting process."

Jan 1, 2013

By S. F. Reiter

The paper presents isothermal recrystallization curves for 0.08 and 0.15 pct C steel at subcritical temperatures following small amounts of plastic deformation. The effects of deformation, temperature, and aging on nucleation and growth rates ore described. The free energy of activation for grain boundary migration in steel is given. SEVERAL excellent reviews of the literature have appeared concerning the recrystallization of metals.'-' The present investigation follows the approach advanced by Mehl, Stanley, and Anderson,6-7 in which the rate of recrystallization was analyzed in terms of N, the rate of nucleation, and G, the rate of growth of recrystallization nuclei. Two lots of low carbon, capped steel of the analysis given in Table I were studied. Each lot consisted of a 150 lb coil which had been hot rolled to 0.083 in. and then cold rolled to 0.042 in. at the mill. Strips 0.930 in. wide were sheared perpendicular to the rolling direction. Both steels were normalized before studying their recrystallization characteristics. The strips were cleaned, painted with a magnesia-acetone paste, and made into packs of equal weight, wrapped in 0.002 in. copper foil. The packs were placed in a salt bath at 900°C for 30 min and air cooled. A relief anneal followed in a second salt bath for 15 min at 650°C. The relief anneal was found necessary from early tests in which a longer incubation period and slower rate of recrystallization were observed in relief-annealed lot A steel than in similar material which was strained and recrystallized directly after being normalized. This effect, which indicates the presence of transformation and/or cooling stresses in steel air cooled from above the A, temperature, has also been observed by Samuels8 and Masing.9 Figs. 1 and 2 show the microstructure of lot A and B materials and illustrate the rather uniform No. 8 ASTM grain size produced by this heat treatment. Winlock and Leiter10 observed that strip specimens which had their sharp edges removed elongated more uniformly than those which were not polished. Similarly, when the sheared edges were removed on a belt grinder, it was found in the present investigation that such samples recrystallized more uniformly than did unpolished strips. Therefore, all strips were carefully rounded prior to their extension. The approximate strain limits for the production of large recrystallized grains are from 6 to 12 pct extension." It was found that for the purpose of this investigation, 8 and 9 pct elongation were suitable deformations. The strain rate employed was 0.01 in. per in. per min and produced a yield point elongation of 4 pct. Winlock and Leiter found that mild steel of No. 8 ASTM grain size gave the same yield point elongation when extended at 0.012 in. per in. per min. All of the lot A and B strips extended in tension developed a straight, stretcher strain line at each grip when the upper yield point was reached. The lines were parallel and made an angle of 55" with the edge of the strip. They approached each other with increasing strain and met near the center of the sample at the end of the yield point elongation. Immediately thereafter, a small drop in load was observed and then the load increased in a regular manner with increasing extension. The grips were initially 8 in. apart. After extension, the 6 in. gage length was carefully cut into 1 in. samples. The remainder of the strip was discarded. After a flash pickle in hot 50-50 hydrochloric acid, six samples, each of which had been taken from a different strip, were placed in a basket and submerged in a lead pot for isothermal recrystallization. Although no recovery effect was observed, strain aging did occur after extension. Therefore, samples were always recrystallized within 24 hr after their cold deformation. After recrystallization, the samples were etched with a solution comprised of one part by volume of nitric acid with three parts of water. Bromide printing paper was exposed directly at low magnifications and later used with a mask to measure the desired quantities. First, the average diameter of the largest grain visible in each sample was determined using dividers. Next, the number of recrystallized grains per unit area was counted and recorded as n. Then, for each sample, the combined area of the recrystallized grains was measured by transcribing the grain outlines to standard graph paper. Many determinations of the area of the recrystallized grains were repeated five times and indicated a standard error that was not greater than 25 pct. The average area for six samples was divided by the area of the mask to yield the percentage recrystallized. Recrystallization of 0.08 Pct C Steel The progress of recrystallization at 670°C after 8 pct elongation of lot A steel is shown in Fig. 3, a through f. The shapes of the growing crystals are approximately equiaxed, as is assumed in the

Jan 1, 1953

By E R. Ramanaidou, C Tessarolo, M Verrall

Garnierite mineralogy in saprolitic ore of the Goro lateritic nickel deposit, New Caledonia , was investigated using X-ray diffraction (XRD), optical and scanning electron microscopy (SEM) and electron microprobe (EMP) analyses. These conspicuously, green-coloured phases occur either as submillimetre to centimetresized veins or as æbookletsÆ arranged in, macroscopic (subcentimetre sized), accordionlike structures supported in an undifferentiated matrix of mixed ÿ7+ and ÿ10+ phases. Within the veins, nickel for Mg solid solution increased from ten wt per cent NiO at the edge to 34 wt per cent NiO at the core, with vein edges comprising Ni-kerolite with <1.5 Ni per formula unit (pfu) grading to pimelite containing >1.5 Ni pfu at vein cores. The æbookletsÆ comprised nTpouite of formula, (Mg0.67Ni1.59Fe3+0.05)(Si2.17Al0.22)O5(OH)4 and averaged 30 per cent NiO. SEM element mapping highlighted the distribution and mineralogical association of Ni and Mg and emphasised the inverse relationship between Ni and Mg at the macroscopic (thin-section) scale. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By S C. Bhowmik, R Gupta

This paper presents the ventilation problem faced by Jaduguda uranium mine, operated up to a depth of 905 m. The first two stages of the mine workings are up to 555 m, which are nearly exhausted. The third stage of the mine is from 555 m to 905 m and presently most of the stopping and development activities of the mine are carried out in the third stage. The total available intake quantity in the third stage was only 21 m3/s. As a result, the mine was facing a radiation hazard. The different instruments and the methods used for monitoring of radiation levels are also presented in the paper. It was observed that the average individual effective dose (external + internal) of radiation workers in Jaduguda mine increased from 6.93 mSv/y in 1995 to 9.5 mSv/y in 2001 and during this period the average individual effective dose of mine workers of the world was less than 5 mSv/y. Keeping this problem in view, a detailed ventilation investigation has been carried out in this mine. Initially the requirements of intake air quantity have been assessed by carrying out field investigation in different stopes and it was found that the third stage workings require nearly 100 m3/s. A detailed ventilation survey has been carried out in the total ventilation network and a basic ventilation model of the mine has been prepared. Different alternative schemes for effectively ventilating the third stage workings of the mine were simulated and a set of recommendations were made for implementation. The recommendations were partially implemented in 2002. As a result the total intake quantity to third stage workings increased to nearly 70 m3/s and the average individual effective dose (internal + external) of mine workers came down from 9.5 mSv/y in 2001 to 6.65 mSv/y and 6.60 mSv/y in 2002 and 2003 respectively. The implementation of remaining recommendations is in progress. Finally, a mathematical model has been formulated from the first principle for predicting air quantity requirements in cut and fill stopes in uranium mines and this model is being validated for further use.

Jan 1, 2005

By Clement K. Chase

Since the dam of cyanidation leaching techniques for precious metals, certain manganese-bearing silver ores have been a problem due to low silver extractions. Since simultaneous occurrence of silver and manganese is common in nature, this situation has made many otherwise attractive silver deposits uneconomic in the past. Several older techniques have been useful but at $1.29 per ounce of silver, the economics were unfavorable. With the new look in silver prices and some improvements in processing technology, neglected silver districts offer new promise.

Jan 1, 1981

By J. E. Moyle

Introduction In October 1983, Rio Algom Ltd. decided to develop the East Kemptville tin deposit. This decision was the result of intensive geological and metallurgical evaluation work, as well as careful studies of environmental and marketing aspects. The property is located about 54 km (34 miles) northeast of Yarmouth, Nova Scotia, near the village of East Kemptville. Geology The geological setting is a granitic intrusive at the contact with metasediment. The tin mineralization is in the form of cassiterite (SnO2), which is about 80% tin. Sulfides are associated with the deposit containing silver, copper, and zinc, which are recoverable as byproducts. The mineralization is associated with quartz veins and greisen alteration. In the center of the deposit, the zones are so close together they have the appearance of a massive or porphyry type deposit. Ore Reserves The mine plan is based on 56 Mt (62 million st) at 0.165% tin. Up to the ninth year, mill feed will average about 0.2% and lower grade material will be stockpiled. In later years, the average grade will be 0.16% tin. A 0.08% cutoff grade is planned for the entire 17 years of production. East Kemptville is a relatively low grade tin deposit, and only a combination of favorable circumstances has made it economic. • The ore body is situated at, or very close to the surface, permitting mining by open-pit methods at a very low stripping ratio. • The tin occurs in relatively large crystals that allow for good recovery by gravity techniques. • It is ideally located in a well-settled area, with all essential infrastructural requirements already in place. • The positive and cooperative response from various governmental agencies involved are encouraging. Mine Plan The mine plan incorporates an initial pit, followed by three expansions to the ultimate pit. Mining will be at 14 kt/d (15,000 stpd) and will include 9 kt (10,000 st) of ore plus 5 kt (5,500 st) of waste and low grade. After five years, the mining rate will increase to 21 kt/d (27,500 stpd). It is planned to drill vertical 165-mm (6.5-in.) blast holes on a 6-x 6-m (20- x 20-ft) pattern. Bulk slurry explosives will be used to break the rock. Loading will be with hydraulic shovels into 70 t (77 st) haulage trucks. The trucks will deliver the ore to a 13 x 20 m (42 x 65 ft) gyratory crusher, where it will be crushed to 150 mm (6 in.). Secondary and tertiary cone crushers will be used to further crush the ore to 13 mm (0.5 in.). Process Design Tin extraction technology is practically unknown in North America, but Rio Tinto Zinc, which has a 53% ownership in Rio Algom, is involved in tin production in the UK. Rio Algom has used this experience and expertise in metallurgical evaluation work and in tin-related aspects of plant design. Mineralogical and metallurgical test work have been performed, both on laboratory and pilot plant scales. Mineralogical work was done largely in the UK, the laboratory test program was carried out at the Lakefield research facility in Ontario, and pilot plant work was conducted in Australia. This program has resulted in significant improvements in recovery and concentrate grades, over best projections that could be made before this work was carried out. Concentrating Process The concentrator is being designed to process about 9 kt/d (10,000 stpd). The first step is to reduce the size of the ore to -700 µm (-24 mesh) in a rod mill/ball mill grinding circuit. The ball mill will operate in closed circuit with high capacity banana-type screens. The screened product will be deslimed to 30 µm (560 mesh) with cyclones, then passed over the pri-

Jan 4, 1984