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By BUREAU OF MINES

In 1948 the United States became a net importer of oil. Coupled with an unpre- cedented domestic production of 5,900,000 barrels daily, imports approximating 500,000 barrels made available a total supply of 6,400,000 barrels a day. Thus, by herculean effort, the oil industry was able to meet an extraordinary demand at home and, in addition, to ship abroad almost 400,00 barrels daily of petroleum and products. The country's oil position now differs greatly from that prevailing at the be- ginning of World War II. Then, actual oil production averaged about 4 million bar- rels a day, and productive capacity probably was greater than 5 million barrels a day. As the demand of the military and industrial machine grew with the rising tempo of the drive toward victory, the United States not only met its own needs but pro- duced about two-thirds of the total oil requirements of the Allied Nations, excluding Russia. As a people, we can be deeply grateful that the Nation's petroleum resources were adequate and sufficiently developed to support such a tremendous effort. Even in those critical hours when immediate needs were the paramount issues, a prudent Congress paused to contemplate the importance of an assured long-term supply of liquid fuels. From these deliberations came the Synthetic Liquid Fuels Act of 1944, which authorized research and development work on new sources of oil coal, oil shale, and agricultural and forestry products. ce World War II, a civilian demand for 6 million barrels of petroleum prod- ucts has become the order of the day every day. By drilling as many as 39,000 new wells a year, the production rate has been increased enough to meet domestic require- ments by a bare margin. Some imports were necessary, however, to fill both domestic and foreign demands, and these doubtless will increase. Is this policy of exploration within the United States and the development of oil in foreign countries adequate insurance for the fulfillment of our future national needs? This question has two aspects one purely civilian and economic in character and the other significant from the standpoint of our national defense. There are now approximately 4,000 producing oil fields in this country. At first thought, it would appear that production could decline in a considerable number of these fields without materially affecting the over-all daily output. However, 48 percent of the oil comes from only 111 major fields which contain 50 percent of the total proved domestic reserves. It is apparent, then, that the flow from large fields - having proved reserves of 100 million barrels or more each must be sustained if daily production is to be kept at the present levels. Essentially, this means that new major fields must be discovered about as rapidly or perhaps more rapidly than the older ones lose productive capacity. From 1940 through 1947, only eight major fields with estimated reserves of more than 100 million barrels each, were discovered and proved - an average of one such field a year. The total estimated reserve of these eight fields was less than 1 year's supply at the present rate of use. As drilling continues, some existing fields ultimately will prove reserves larger than those now known. Without a pronounced increase in the num- ber of major discoveries, however, the prospects for increasing our present productive level are not encouraging. Any gap that appears between domestic productive capacity and demand could be filled with supplies from proved oil resources abroad. Assuming cheap pipe-line and tanker transportation to the United States, freedom from exorbitant taxes and charges

Jan 1, 1949

By Marc C. Bétournay

A number of successful proof-of-concept projects have been carried out to replace conventional power application, such as diesel and rechargeable batteries, in underground mine vehicles. This has led to the development of the world?s first fuelcell production vehicle, a mine locomotive. A mine loader project has also started and several other projects are planned. These projects are providing the mining industry with the required information to make this technology shift possible. The application of fuelcell power will yield several important benefits such as the elimination of underground diesel emissions, significant reduction in the primary extraction?s sector greenhouse gas emissions and support for a more productive scenario. This article reviews these successes, discusses ongoing and potential projects and presents the technology application benefits that could be possible for mining operations.

May 1, 2003

By E. A. Sobering

Hydraulic filling or sand filling is a system used to fill underground excavations with a dense pulp. Milltailings are commonly used. The resultant fill, after being placed and de-watered, is known as hydraulic fill. These fills have been effectively used to (a) provide immediate support of the workings place during stoping; (b) .facilitate the recovery of pillars; (c) limit surface damage by subsidence; (d) permit the mining of parallel hanging-wall orebodies; (e) stabilize the ground in mines, thereby reducing the rock burst hazard; (f) control and prevent mine fires; and (g) solve tailings disposal .problems. The various uses of hydraulic filling have been developed during the last ninety years. In 1864 it was employed only to control surface subsidence. Since then, this system has been successfully applied to meet specific ground support problems. Methods of handling mine-fill derived from a source outside the stope include transportation ?Of the material by hand, mechanical, pneumatic, and hydraulic means, or a combination of these methods. The hydraulic method has many advantages not found in the others; a significant advantage is the low compressibility of the material when compared to other mine-fill material. The hydraulic filling operation includes the .preparation and transportation of the pulp. The underground practices in .placing the fill vary from mine to mine. The chief reason, formerly, for using hydraulic fill was the exceptional support it provided, but recently it has proven an important means of reducing mining costs. This is especially true where labour is a large part of an alternative method, or where timber consumption is greatly reduced. The indirect benefits of hydraulic filling are probably as important as the direct benefits, and few important disadvantages exist.

Jan 1, 1956

By S. S. Klima, H. Jiang, T. W. Beck, Y. Zheng

Researchers at the National Institute for Occupational Safety and Health (NIOSH) performed a series of lab tests to evaluate the respirable dust removal capacity of an industrial air-cleaning fan. Limestone and coal dust were tested separately in NIOSH’s full-scale drill table simulator at the Pittsburgh Mining Research Division (PMRD). Gravimetric samplers with Dorr-Oliver Cyclones and 37-mm filters were used at two upstream and four downstream locations inside and outside of the drill shroud chamber. There were six tests performed for both the limestone and coal dust experiments. In the limestone tests, an average respirable dust concentration of 98.86 mg/m3 was achieved upstream of the air-cleaning fan. The filter results show that the averaged respirable limestone dust reductions were 7.84%, 8.81%, 10.94%, and 18.02% at the four sampling locations downstream of the fan. In the coal tests, upstream samplers achieved an average of 129.03 mg/m3 of respirable coal dust. The averaged dust reductions were 9.54%, 9.83%, 18.54%, and 19.21% at the four downstream sampling points. The results indicate limited cost benefits of using this technology because of the relatively low dust reductions determined from this laboratory study.

Feb 1, 2023

By Kirk Ellison, Sherif Elfass, Ramin Motamed, Kevin V. Stanton

"The determination of accurate load transfer curves are essential for estimating deep foundation loadsettlement response using t-z style analyses. While recently developed semi-empirical methods from Ashour et al. (2010) and Ashour & Helal (2012) have shown promise in preliminary studies, they have not yet been thoroughly benchmarked against a more widely accepted approach. To address this issue, these recent procedures are implemented in the computer program CGI-DFSAP to predict the results of four Osterberg-cell (O-Cell) load tests. These predictions are compared to outcomes obtained following the recommendations from Reese & O’Neill (1988) for t-z analyses of drilled shafts in sand and clay which are carried out with the program TZ-PILE. Overall, the results suggest that the new approach offers improved accuracy regarding predictions of drilled shaft response to axial loading.INTRODUCTIONThe behavior of axially loaded deep foundations is often analyzed using a technique known as the t-z method. In this method, deep foundation elements are broken into multiple segments which are supported by discrete nonlinear springs to capture the contribution of both side-friction (t-z springs) and end-bearing (Q-z springs). Hence, the t-z and Q-z relationships dictate the predicted load-settlement response. A number of different approaches have been developed to estimate load-transfer curves with some relying solely on empirical data from laboratory and field experiments (i.e. Coyle & Reese, 1966; Vijayvergiya, 1977) and others based mainly on analytical frameworks (i.e. Kraft et al., 1981; Randolph, 1994). Reese & O’Neill (1988) provide recommendations which are widely used for developing t-z and Q-z curves for analyzing drilled shafts. This method is hereafter referred to as Method 1 (M1). It should be noted that these empirically derived relationships are only applicable for problems associated with drilled shafts and are therefore not appropriate for developing load-transfer curves for other types of deep foundations (i.e. driven piles). This is because of the difference in the frictional resistance which can be developed between a circular concrete-soil interface as opposed to that of other materials (i.e. steel) and/or different cross sectional geometries.The M1 load-transfer curves form the basis for the t-z analysis of drilled shafts implemented in the computer program TZ-PILE (Ensoft, 2014). In light of this, TZ-PILE is employed herein as a reference to compare against the capabilities of another method of implementing t-z style analyses. This method is based on a semi-empirical framework for soil behavior developed by Norris (1986) and is implemented using the program CGI-DFSAP (Computers & GeoEngineering Inc., 2011). More information concerning this approach, hereafter referred to as Method 2 (M2), is given in subsequent sections."

Jan 1, 2017

By W. Norman Sims

A number of forces are at work that are now having an influence on coal handling systems. Changes are occurring and will be occurring at an increasing rate during the next few years. 1. Environmental concerns will dictate that dust pollution and spontaneous combustion and its resulting problems be rigidly controlled. 2. Slurry pipelines will be a reality despite the opposition of the railroads because they are economical and make good business sense. Artifical roadblocks can only survive for a limited time. 3. Coal is now and will remain the most economic fuel, particularly for power generation. This is true in most of the developed nations not just the United States. Increase in demand requires a close inspection of transportation systems. 4. A projected major increase in the export of U.S. coals may never occur without major port developments not the least of which will be the ability to accommodate large ships without demurrage time now affecting such shipments at U.S. Ports.

Jan 1, 1982

By O. T. Marzke, Robert F. Mehl

A study of the structures arising from the decomposition of the ß solid solutions in the Cu-Zn and the Cu-A1 systems is of peculiar interest in the study of the mechanism of precipitation from solid solutions. It is possible in these alloys, by varying the composition within the ß field, to precipitate from the same basic lattice phases having different lattice structures. It has been rather generally assumed heretofore that the type of structure originating from the decomposition of a solid solution— the Widmanstätten structure—-is determined by the lattice structure of the parent solid solution alone. In the first paper of this series1 evidence was advanced which threw doubt upon this hypothesis; but definite proof of the correctness or incorrectness of the hypothesis should be forthcoming from a study of these alloys, for if the structures originating, for example, from the precipitation of the a phase from ß and of the ? phase from the ß in the Cu-Zn system should be shown to be crystallographically different, the hypothesis would necessarily be held as definitely disproved. Furthermore, the newer proposal enunciated in the first paper of this series—that the origin of the Widmanstätten structure lies in a cooperation between the lattice of the parent solid solution and that of the precipitate-—which at present seems the only a1ternative hypothesis, would in such an event be given added weight. The work here reported shows that the Widmanstätten structures originating in the precipitation of the a phase from the ß and in the precipit'at.ion of the y phase from the y in the Cu-Zn system are indeed crystallographically different; and incidentally presents some new descriptive information on the Widmanstätten structure from a more general point, of view.

Jan 1, 1931

By Travis Q. Lyday

Australia was one of the world's principal producers of minerals and metals, and its minerals industry was a leading catalyst in promoting growth of the country. Australia was the world's largest producer of alumina, bauxite, diamond, ilmenite, monazite, opal, rutile, sapphire, and zircon. It was the premier exporter of alumina, coal, ilmenite, refined lead, monazite, rutile, and zircon, and was the second leading exporter of iron ore, after Brazil. Ranking behind China, the United States, the U.S.S.R., the German Democratic Republic, Poland, and the Federal Re-public of Germany, Australia was the seventh largest producer of coal (all grades) in the world. Australia was the fourth largest gold producer in 1988, after the Republic of South Africa, the Soviet Union, and the United States. It was the second largest producer of zinc, the third largest producer of nickel, the fourth largest producer of uranium, and the seventh largest producer of copper. 2 The country's mineral wealth was so extraordinary that it was virtually self-sufficient in most mineral commodities. Endowed with abundant resources of coal, natural gas, liquefied petroleum gas, and uranium, Australia was one of the few market economy countries that was a net exporter of mineral fuels. About 90% of Australia's consumption of crude oil was supplied by domestic production; this was expected to decline significantly about 1990, unless significant new oilfields were discovered.

Jan 1, 1990

By Dempsey S. Thieman

Innovative marine bulkhead design and construction techniques were used in the fast-track design and construction of a high-capacity, deep-water dock in the highly seismic region of Alaska?s Aleutian Islands. The geotechnical investigation and design through construction phases were completed in just eight months. The adaptable OPEN CELL® design, readily available standard flat sheet pile and an experienced contractor were integral to the successful completion of the project. The cost of the structure was determined to be approximately 50 percent of a comparable pile-supported platform dock structure, allowed higher load capacity, rapid construction, less maintenance, and provided substantially more uplands. This paper details the design and construction of this unique and challenging project. The OPEN CELL structure is a vertical flexible membrane system that offers significant advantages over other structure types: ? Its flexible membrane structure is not dependent on toe embedment for stability. ? Poor soil conditions, shallow bedrock, high seismic loads, deep water, scour, etc., can be accommodated due to its adaptable design. ? It has a very high load capacity?capable of several thousand pounds per square foot. ? Allows buried utilities which results in lower cost and reduces freezing conditions ? The sheet pile tail walls can be extended to provide increased global stability if needed. ? Standard sheet pile and connectors with traditional installation techniques allow accelerated construction schedules.

Jan 1, 2008

By M Ali, E Satriawan, M Napitupulu, A Munandar

The Deep Mill Level Zone (DMLZ) panel cave mine is one of three active caving mines at PT Freeport Indonesia’s Grasberg Underground Mining Complex. The DMLZ mine is located at a depth of approximately 1,500-1800 m below the surface, making it one of the world’s deepest panel cave mining operations. This depth results in both high in-situ and induced stress that acts on the hard and massive rock mass, triggering rockburst conditions. As a result of the bursting conditions, ground support and maintaining the support capacity are an essential part of operating the DMLZ mine in an efficient and safe manner.

Apr 26, 2022

By Hendri Silaen, Charles Leatemia, Monang Napitupulu, John Kamarea, Arwin Edijanto, Riza Hasan, Avesiena Primadiansyah

The Deep Mill Level Zone (DMLZ) is the fourth panel cave mine in the East Ertsberg Skarn System, (EESS) which lies 500 m below the producing Deep Ore Zone (DOZ) mine and up to 1,700 m below the surface. The interaction between the DMLZ and DOZ is occurring as the DMLZ cave grows vertically toward the DOZ footprint. During this process, a rapid change in the global mine system stress is anticipated. This change is forecasted to drive substantial changes in the magnitude and direction of principal stresses in the DMLZ and DOZ mines at PT Freeport Indonesia. These changes will bring the mine system closer to the ultimate capacity of the excavations and can result in significant impacts to mine stability if not managed. Critical to this management, is understanding cave growth and locations, as well as how these changes will impact stress conditions.

Apr 26, 2022

By Tony Weeks, J. Loah, Ian Mcgaffin

PT Newmont Minahasa Raya (PT NMR) operates a 700,000 tonne per annum open cut gold mine in the Minahasa region of North Sulawesi. The operation commenced production in the second quaiter of 1996 and is expected to produce an average of 150 000 to 180 000 ounces of gold per year for the mine life. The deposit is predominately refractory in nature and requires a complex treatment route incorporating dry milling and whole ore roasting followed by conventional cyanidation and adsorp­tion of the gold onto activated carbon. Gold is eluted from the carbon to produce <lore bars assaying approximately 94 percent gold. A scrubbing system for the removal of mercury from the roaster off gases was commissioned in late 1997. Due to the location of the operation, close to the coast and in seismic region with high rainfall submarine tailings placement (STP) was the preferred method of tailings disposal. Prior to dis­posal into the ocean the tailings from the CIP plant are detoxified in a three stage detoxification circuit to treat cyanide, arsenic and mercury. This paper reviews some of the design and operational fea­tures of the whole ore treatment process employed at the Minahasa Gold Mine.

Jan 1, 1998

By Larry A. Haas

The U.S. Bureau of Mines, in cooperation with Cleveland-Cliffs, Inc. (Hibbing, MN), investigated ways of enhancing the quality (compressive strength, after-tumble and reducibility) of domestic acid and fluxed magnetite pellets by modifying the oxygen content during the preheat and induration periods of the firing operation . Oxidation of magnetite was best accomplished when sufficient oxygen and time were available before the peak induration temperature was reached. The rate of magnetite oxidation increased directly with the gas oxygen content during the preheat period at 7000 C and above. With 30 pct ( or more) O2 and a preheat rate of 2000 C/min, most of the magnetite was oxidized during the preheat period. With laboratory tube and mini-pot furnace tests, oxygen enrichment during the preheat period improved the pellet properties more in the simulated grate-kiln tests than in the simulated straight-grate tests. The longer induration period with the grate-kiln test resulted in more sintering of the residual magnetite and its reaction with the silicon compounds. When flux was present in the pellets, calcium silicates and calcium and magnesium ferrites were formed. More calcium ferrite was formed when the magnetite was oxidized early and less iron was present in the fayalitic calcium silicate slag.

Jan 1, 1993

By K. C. Dean

The Bureau of Mines, following passage of the Solid Waste Disposal Act of 1965, was authorized to conduct research on methods for utilizing, stabilizing, or reclaiming mineral wastes. This report summarizes laboratory research conducted by the Bureau and cooperative field studies made with the mineral industry to reduce the environmental impacts of air and water pollution deriving from mineral wastes. Utilization research showed that both dry-press and steam-cured building bricks and ceramic tile could be made from copper mill tailings and other discarded mineral wastes. Sponge iron was produced from steel mill and amination industry wastes, and valuable mineral products were extracted from such diverse sources as flue dusts and uranium tailings. Mineral wastes were combined with agricultural and/or sewage wastes to make artificial soils that have the potential of resolving several disposal problems by production of a useful commodity. Physical, chemical, and vegetative stabilization methods were evaluated, singly and in combination, for reclamation potential on copper, uranium, lead-zinc, and asbestos tailings. Suitable methods were developed in the laboratory for overcoming major adverse conditions of these wastes such as salinity, heavy metal toxicity, acidity, basicity, lack of nutrients and organics, and unstable surfaces. Field testing of these methods was performed on a variety of mineral wastes. Costs for the various stabilization and utilization-procedures developed were also determined.

Jan 1, 1986

By Norihiko Fukatsu, Takashi Iwamoto, Noriaki Kurita, Koji Katahira, Kunihiro Koide, Teruo Ohashi

"The galvanic cell-type hydrogen sensor employing CaZro.9Ino.t03-a. as the solid electrolyte was designed for the measurement of hydrogen activities in molten copper under industrial .conditions. The sensor probe consists of the cap-shaped solid electrolyte with porous platinum electrode on the inside and alumina refractory tube. The gas mixture of the composition 4%H2-0.5%02-Ar was made to flow on the inside electrode. The hydrogen sensor probe was inserted directly into molten copper and the melt was used as the outer electrode. The effect of oxygen activity gradient to EMF was eliminated theoretically by measuring the oxygen activity in the melt simultaneously with an oxygen sensor. The high stability of output and excellent response to the change of hydrogen activity were obtained over the wide range of industrial copper melting conditions.IntroductionIn the metal casting process, hydrogen easily dissolves in molten metals from water vapor in the surrounding atmosphere. Owing to the large difference in hydrogen solubility between liquid and solid metal, dissolved hydrogen becomes a cause of the defects of blowholes in castings or ingots. It is necessary to control the hydrogen content in the molten metals [l]. Using proton-conducting ceramics as a solid electrolyte, high temperature-type hydrogen sensor can be constructed [2]. SrCe03- and BaCe03-based perovskite-type oxides exhibit appreciable proton conduction under hydrogen containing atmosphere at high temperature [3-5]. A hydrogen sensor for molten aluminum using CaZro.91no.103-a. has been developed and widely used in the ·process control in the aluminum melting industry [6,7]. The same type of hydrogen sensor has also been expected in the copper melting industry. .. However, CaZro.91no.103-a shows ·not only proton but also oxide ion conduction in the high temperature and at low oxygen activies like the copper melting· conditions. Then we studied the oxide ion conduction in CaZro.91no.103-a. iit · detail [8]. From the consideration on the EMF of the galvanic cell employing this material as electrolyte, it was shown that the unknown hydrogen activity may be precisely determined from cell potential which is corrected for the effect of oxygen potential gradient And the hydrogen sensor based in this principle was constructed and tested in laboratory-scale [9,10]. We repeated the similar tests in factory-scale and developed the sensor system for practical uses [11, 12]. In this report, the structure and system of the hydrogen sensor for molten copper will be introduced first. The reliability of the sensor will then be demonstrated from the results of experiments for sensor probes carried out in TYK's laboratory."

Jan 1, 2000

By J Boland

Polycrystalline diamond compacts (PDC) have been widely used as cutting elements in the drilling tools for the oil, gas, civil and mining industries because of their faster penetration rates and longer bit life. US Department of Energy reports that PDC bits account for more than one-third of the total footage drilled worldwide (US Department of Energy, 2004). However, non-thermally-stable diamond composites (NTSDC) have seldom been applied to geothermal drilling, since premature failures of such PDC cutters have been observed in hard rock formations. Several factors need to be considered to prevent premature failure of cutters and improve cutting performance when using PDC-based bits and other rock cutting tools. The first set of factors consists of the strength, density, stiffness, toughness and thermal resistance of the PDC and the rock. A second set relates to the complex behaviour of the bonding between the PDC cutter and the bit matrix, or the pick and the pick holder, which is vital in maintaining stable, reliable and durable adhesion of the cutters to their hubs. Finally, based on a better understanding of the cutting processes, the formulation of a predictive model would assist in further development of cutter design.

Jan 1, 2004

By Dianyuan Dang, Guihong Han, Wenjuan Wang, Tao Jiang, Yanfang Huang

In this study reduction kinetics and swelling behaviors in "two-step process” were investigated by weight-loss technique and visualizing physical changes of pellet. Results showed that reduction degree (r) increased with increasing temperature and time. According to the dynamic calculation, when reduction temperature was lower than 1000°C the reduction process was controlled by chemical reaction with apparent activation energy of 72.27 kJ/mol. When reduction temperature was higher than 1000 , the equation of t/[1-(1-r)1/3] against [1+2(1-r)-3(1-r)2/3]/[1-(1-r)1/3] followed straight lines, demonstrating that reduction was mixed-controlled. Swelling experiments indicated that the maximum swelling index increased with the increase of reduction temperature and CO content.

Jan 1, 2016

By S. A. Allen

The Eufaula bauxite district of Barbour and Henry Counties in southeast Alabama covers an area approximately 14 miles long, 6 miles wide at the eastern extremity near the Chattahoochee River, and 10 miles wide at the western end near the east fork of the Choctawhatchee River (see figs. 1 and 2). The long axis of this polygon bears a little south of east.

Jan 1, 1949

By A. A. Lavrinenko, N. I. Gluhova, L. M. Sarkisova, D. V. Makarov

"The purpose of the study is to study the feasibility of using sodium diisobutyl dithiophosphinate (DDP) to enhance the recovery of platinum group elements from low-grade refractory copper-nickel ores characterized by a portion of nickel and platinum group elements (PGEs) locked in the dominant sulfide mineral — pyrrhotite. These ore characteristics dictate the need to produce a bulk PGE-containing sulfide concentrate due to the difficulties of producing selective concentrates without a significant loss of the metals.New data on the adsorption and flotation performance of DDP-containing collectors were obtained by measuring the electrode potential, hydrophobicity of the sulfide mineral surfaces and by means of extraction spectrophotometry and flotation studies. The interaction between DDP, pyrrhotite, and pentlandite leads to the formation of surface hydrophobic layers consisting mainly of disulfide and a small amount of metal compounds. These adsorption layers are formed by the reaction with butyl xanthate. In the case of cooperite, DDP reacts with the surface, forming not only disulfide, as in the case of butyl xanthate, but also a complex platinum compound. DDP-containing agents demonstrate stronger collecting properties with respect to sulfide minerals of copper-nickel ores compared to butyl xanthate, which is explained by a stronger hydrophobizing effect and foaming properties.The addition of a combination of DDP-containing agents and butyl xanthate at a ratio of 3:1 for the recovery of sulfides and PGEs in the bulk flotation of copper-nickel ore made it possible to improve the recovery of Ni, Pt, and Pd by 13.6, 9.2, and 9.4%, respectively, relative to the recovery achieved in flotation with butyl xanthate.Bulk flotation with the addition of a composition of DDP-containing agents and butyl xanthate allows the most complete recovery of all valuable elements and is the only technologically feasible method for processing of lowgrade ores, when it is impossible to produce without loss high-grade selective concentrates suitable for smelting."

Jan 1, 2018

By A. S. Emanuel

A correlation has been developed for calculating the phase behavior of, gas-condensate systems at reservoir conditions. The correlation is based on the principle of corresponding states and has been coded for an IBM 7094. Experimental K-values were determined for several gas-condensate systems at reservoir conditions to evaluate various semi-empirical parameters of the correlation. The approximate range of application of the correlation is 150 to 300F and 1,500 to 6,000 psi. INTRODUCTION The rapid development of digital computers during the past several years has made feasible the calculation of hydrocarbon phase behavior by methods based on rigorous thermodynamic principles. Good correlationsl have been developed for low to moderate pressures, but these techniques have not yet been extended successfully to reservoir fluids at high pressures. Consequently, the determination of phase behavior of oil and gas systems at reservoir conditions is still based almost entirely on generalized data correlations or on experimental studies of the fluid in question. While these methods have been used successfully many times, they do have inherent limitations that restrict their applicability. Generalized correlations, such as the NGShlA K-charts, are limited to the range of pressure, temperature and components for which the data were determined. The accuracy of these correlations is often questionable because the effect of total system composition is not well defined. Experimental studies offer a reliable method for determining phase behavior, but usually the studies are costly and time consuming. Recently, Leland and co-workers presented a new approach to calculating phase behavior from the principles of corresponding states.6-8 Corresponding states methods determine the thermodynamics properties of a given system by comparison with a reference substance whose properties are known. The accuracy of this approach depends on close chemical and structural similarity between the reference substance and the system in question and between components within the system itself. For high accuracy, it is usually necessary to correct for chemical and structural dissimilarities. In principle, however, the corresponding states method should be no less accurate at high pressures than at low pressures, provided reference substance properties are known. This paper describes an empirical modification of the basic correlation proposed by Leland, et al.6 for the specific purpose of calculating the phase behavior of gas-condensate fluids at reservoir conditions. The modified correlation, which has been programmed for an IBM 7094, may be used for either approximate or precise determination of fluid behavior depending on the amount of analytical and, experimental data available for the system. BASIC THEORY The basic theory of the corresponding states phase equilibria correlation was first published by Leland, Chappelear and Gamson.6 Subsequently, Leland, Chappelear and Leach published methods for improving the accuracy of the original theory.7-9 The aim of the correlation is to calculate the K-value of each component of a given system as a function of pressure, temperature, and over-all composition, where Once the K-values are known, the phase behavior may be determined directly by an appropriate flash calculation. The basic equation for calculating component K-values was taken from the work of Joffe. 4 For any component i of a mixture, the K-value is given by

Jan 1, 1969