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By B T. Qin, C Zhu, Y W. Jia, Y Lu, F L. Li, Q L. Shi

Air leakage through rock fractures in coal mining is a major cause of coal spontaneous combustion. In order to overcome the deficiency of the existing fire control technology and prevent coal spontaneous combustion by isolating coal from oxygen, the article proposes a novel technology of inorganic solidified foam (ISF) with high expansion to fill fractures effectively. ISF consists of fly ash, cement, setting accelerator, redispersible polymer powder, water and aqueous foam. For preparing homogeneous and stable ISF, a preparation system with a pore type foam generator, a mixer device installed with a hollow shaft and helical blades, air compressor, slush pump and monitoring instruments was developed, and the working principles of key devices were elucidated. Based on a series of experiments on the different ratios of each component material and technological parameters of the preparation system, ISF with a foam expansion ratio of 8~10 and dry density of 250–400 kg/m3 was prepared. The relationship between elastic compressive strength, modulus of elasticity and density was summarised. Based on the injection experiment for fracture of loose coal pile with high temperature, the characteristics of sealing air leakage, compressive strength, thermal insulation, flow and cooling of ISF in the fresh state were investigated, indicating that ISF can effectively cut off the air leakage and cover the coal sample to reduce the temperature in the earlier stage, and ISF can remain stable and not crack. The ISF was applied to Luwa coalmine to seal small coal pillar pressure fractures and loose coal fractures in goaf. After press-casting the ISF in Luwa coalmine, the pressure-difference of inner-outer increased, meaning the effect of external conditions on the pressure-difference decreased, showing that it could plug the air leakage effectively.CITATION:Qin, B T, Shi, Q L, Lu, Y, Zhu, C, Li, F L and Jia, Y W, 2015. The novel technology of inorganic solidified foam with high expansion for preventing coal spontaneous combustion, in Proceedings The Australian Mine Ventilation Conference, pp 121–126 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By S. H. Ash

THE MAGNITUDE of the drainage problem of the anthracite industry in Pennsylvania's Western Middle field is realized when it is known that in 1951 nine pumping plants in this field pumped nearly 36 billion gallons of water to the surface. This is almost 68,000 gallons per minute pumped against an average hydrostatic head of 350 feet for that year alone. In 1948 over 20,000 gallons per minute was pumped by relay pumps against an average hydrostatic head of 265 feet. In addition to the water pumped to the surface, it is estimated that 15,000 gallons per minute overflows to the surface from underground pools in idle mines. The volume (second-feet) of water pumped and overflow water is almost 1;z times the, average mean flow of the Schuylkill River at Pottsville for the 8-year period 1944--51 (7, 13).4 Mahanov and Shamokin Creeks drain an area of 99 square miles in the Western Middle field, and all surface drainage in this area must traverse some part, of the coal measures before entering these streams. On the basis of 46.03 inches of rainfall (the weighted average of 6 recording stations for 1948), the runoff from the drainage area during that period was 51 billion gallons, approximately 1 times the volume of water pumped by all mine-pumping plants in the Western Middle field. In other words, because of the pervious strata overlying the mine workings, approximately two-thirds of the total runoff in the drainage, area becomes mine water tributary to the pumping plants.

Jan 1, 1953

By I. E. Wahn, E. A. Boutin

"The Manibridge Mill is unique in its treatment of relatively high grade nickel-copper ore because in the mill design are included one 10' diam. x 10' Maxwell cell, and three 12' diam. x 12' tank cells. These large cells are used as rougher-scavenger cells. Three 8' diam. x 8' tank cells as well are used for cleaning and recleaning of the tank cell concentrate.Flexibility of flow is the main criterion in the tank cell circuit. Targets from these cells are a high grade nickel-copper product with a minimum of talcose gangue.The operation of the tank cells has been encouraging and they have performed well with both low and high grade heads, yielding a high grade concentrate product.Manibridge Tank CellsDescription:The tank cells at Manibridge consist of one 10' x 10' Maxwell cell, three 12' x 12' tank cells, and three 8' x 8' tank cells. The four large cells are currently being used as rougher scavenger cells. The three small cells are used as cleaner cells.Both sets of tank cells consist of Denver steel tank and Super Agitator Mechanisms with steel beam super-structures. The agitator mechanism has a totally enclosed ball bearing spindle housing with a cold rolled steel shaft, and a stanclard standpipe with adjustable collar.The air rings for the tanks were fabricated by Nelson Machinery. Both large and small cells have injection rings with equally spaced air holes in the bottom centre line of the ring.Air is supplied to the tank cells by a Dresser Clark low pressure air blower.The following is a table of pertinent data on the tank cells:"

Jan 1, 1974

By Golaleh Riahi

An original method is used to obtain stable nanoparticles of gold-based mono- and bimetallic systems supported on an acidic zeolite. This approach has been applied to PtHY (1wt% Pt) and to bimetallic Pt-AuHY containing 1% of platinum to which is added the amount of gold required to give Au/Pt molar ratios of 20,40,60 and 80%. Metal clusters of Au or Pt-AuHY are formed inside the supercages of the zeolite framework by the thermal reduction of cations by the ligands (en = H2N-CH2-CH2-NH2) under inert gas flow at a temperature depending on the metal. The use of acidic zeolites favours the dispersion of the metal and the thermal stability of the particles. This stability is explained by chemical anchoring of metal clusters by the Brønsted sites of the support. Several techniques have proved that for a molar ratio of 20% metal particles of Pt-AuHY are bimetallic. The segregation of Pt and Au starts for molar ratio =?40%. The catalysts tested on the methylcyclopentane hydroconversion reaction reveal that the addition of gold to platinum leads to an increase in the activity and an improvement in the selectivity for isomerization of the skeleton (cyclohexane and benzene) to the detriment of hydrogenolysis. Similar results were obtained for the dodecane isomerisation to isododecane. These catalysts were also tested in CO, propene and propane oxidation. The activity of fresh catalysts is rather low. It increases after their pretreatment in oxygen or hydrogen atmosphere. In propene oxidation in the reaction mixture O2 ? H2, beside total oxidation of propene to CO2, also propene hydrogenation was observed, particularly at low temperatures. The presence of Au enhances the hydrogenation properties: high selectivities (> 90%) to propane and high propane yields on PtAu HY are observed up to ~150oC, whereas for Pt HY catalyst the selectivity and yield to C3H8 decreases rapidly with the temperature beginning from ~100oC.

Oct 1, 2003

By Young-Dae Kim, Dong-Sic Kim, Jong-Jin Pak, Kyung-Hyo Do

"Sulfur is one of the most harmful elements in stainless steel (SIS) products and the specification of sulfur content is getting more severe for high grade SIS. In order to accurately control the desulfurization reaction in high chromium containing SIS melts, it is important to know the thermodynamic interaction between chromium and sulfur in Fe-Cr melts over a wide range of chromium content. In this study, the equilibrium sulfur distribution, Ls, between a Ca0-Alz03 slag and Fe-Cr-C,.,-S melts were measured under CO atmosphere in the temperature range of 1823-1923 K. The specific effect of chromium on the activity coefficient of sulfur in the melts was determined with the consideration of carbon effect on sulfur. A separate experiment was carried to determine. Ls between a slag and FeCr- S melts (Cr: 0-30 mass%) at 1873K to check the validity of the thermodynamic parameter determined in the present study.IntroductionFerritic stainless steels containing chromium (Cr) up to 30 mass% have been developed for a good corrosion resistance and a high formability to replace austenitic SIS. Especially, Sulfur (S) causes a reduction of high-temperature strength and the hydrogen induced cracking (HlC) in stainless steel for line pipes. [l]Many studies on the desulfurization of hot metal and liquid steel have been carried out for several decades and they used HzS-H2 gas equilibrium technique for measuring the effects of many alloying elements on the activity coefficient of S in liquid iron. However, the study on desulfurization of Fe-Cr melts was very scarce.[2] In order to accurately control the desulfurization reaction of high Cr stainless steel, it is essential to know the thermodynamic relation between Cr and S in Fe-Cr melt over a wide range of Cr content and temperature.In the present study, the thermodynamic interaction between Cr and S in liquid iron was determined by measuring the equilibrium distribution ratios of S between Fe-Cr-C,.1-S melts containing a wide range of Cr up to 30 mass% and a 55 mass%Ca0-45 mass%Alz03 slag of which the sulfide capacity was pre-determined using Fe-C,a1-S melts in the temperature range of 1823-1923 K. The validity of thermodynamic parameter determined in the present study was checked by measuring the S distribution between a Ca0-Alz03-Mg0 slag of known sulfide capacity and liquid Fe-Cr-S alloy at 1873 K. Using Wagner's formalism, the results of experiment were thermodynamically considered to determine the effect of a specific concentration of Cr on the activity coefficient of S in liquid iron."

Jan 1, 2014

By G. Norman Owen, Roger E. Scholl, Tor L. Brekke

INTRODUCTION Underground structures are generally regarded to be safer than surface structures during strong seismic motion, except when crossing a causative fault. Recent studies of observed earthquake damage to tunnels generally support this view, although instances of severe damage and, occasionally, collapse are reported. For proposed underground construction of sensitive structures such as nuclear power plants, liquefied natural gas facilities, and nuclear waste repositories, a verification of the seismic response of underground structures will be required.. This paper discusses the stabilization recommendations used in a study of additional costs required to protect tunnels against ground motion caused by earthquakes and underground nuclear explosions (1). The study is a part of the site investigations for possible construction of a nuclear waste repository. The additional costs estimated in the study are not presented here; only the stabilization measures are presented in the present paper. The tunnels, which would constitute the underground facilities of a possible repository, are assumed to be 5.5 m (18 ft) in diameter and to be located at a depth of 600 m (2,000 ft). Three candidate geological materials are considered: argillite (shale), granite, and tuff. Several peak ground accelerations are used: 0.3g, 0.5g, and 0.7g for earthquakes, and 0.5g, 0.7g, and 1.0g for underground nuclear explosions. Potential damage due only to shaking is considered here. This paper does not discuss problems that result from creep or sudden rupture of intersected faults or from ground failures at portals.

Jan 1, 1979

By Ronald S. Conti

The Bureau of Mines conducted a comprehensive laboratory study of the thermal ignitability of various carbonaceous dust clouds with particular emphasis on various ranks of coal dust. The tests were conducted using a new 1.2-L furnace. Autoignition temperatures of dust clouds were obtained as a function of coal volatility and particle size. Dust particles and gas samples were collected by a rapid-sampling system in order to study the reactions involved in preignition and postignition processes. The autoignition temperatures measured in the new 1.2-L furnace were significantly lower and therefore more conservative than those measured previously in the Godbert-Greenwald furnace. The combined effects of thermal and electrical ignition of dust clouds were also studied in the 1.2-L furnace using electrical discharges of varying energies at ambient and elevated temperatures. The minimum spark energy necessary to ignite a dust cloud decreased significantly as the temperature of the dust cloud increased.

Jan 1, 1983

By F M. Senda

This paper highlights strategies used at the Barrick operated Kibali Gold Mine (KGM) to improve the drilling accuracy and blasting effectiveness for longhole open stoping. The mine currently uses Solo DL421 for the required stope drilling and has experienced an average deviation of 10 per cent. Strategies are raised to eliminate or at least mitigate the adverse effects of blasthole deviation and the impact of blasting induced effect at the stope faces including the stope crown. The integration of deviation trends in the design would allow the actual blastholes to be established within their required positions to then facilitate a proper energy distribution with the eventual production blasting. The implementation of stope undercutting reduces the hole length from 35 m to 30 m which in return decreases blasthole deviation by 3 per cent. Another strategy adopted to improve the drilling accuracy is to slow down the penetration rate with the use of several operating approaches, including 135 MPa percussion pressure, 65 rev/sec rotation speed and 17 MPa feed pressure. To this penetration rate, a constant k factor is applied to increase the rate when the bedding inclination is less than 45° from the horizontal or when the hole length is under 10 m. This reduces deviation by a further 4 per cent. Where the rock mass is highly jointed it is advised to use the average penetration rate over the entire length of the hole. Furthermore, the paper shows the effect of deviation on the blasting results through a prediction of fragmentation blasting model optimised with reduced deviation and highlights the effect of presplit mining and timing delay on the blasting effectiveness. Although the size pattern increases with deviation, a strategy pertaining to timing delay with blasting would be to align to the work of Grant (1990) where the optimum hole to hole delay is found to be between 7–10 ms/m of spacing, while the optimum delay between adjacent ring varied between 110–160 ms. Stabilisation of crowns and wings will perform with the implementation of presplit blasting.

Mar 29, 2023

By W. Ghyoot, J. Boonstra, H. Dijkman, C. Buisman, M. Picavet

Paques and Umicore have demonstrated the feasibility of biological treatment of the highly complex Hoboken wastewaters in a1 m3/h pilot plant at Umicore Precious Metals, Hoboken, Belgium. In the first step arsenic was precipitated from copper smelter effluent as As2S3using biogenic produced H2S. Other metals such as copper, lead and cadmium were also removed as MeS to concentrations well below the discharge levels. Subsequently, sulfate and nitrate were removed to low concentrations (<300 mg/l and < 5 mg/l respectively) in high rate engineered bioreactors. Sulfide produced in the sulfate reduction process was recycled to step 1 for metals precipitation. Selenite/selenate was partly removed in the sulfide precipitation step, whereas the excess was biologically reduced and removed as selenium to concentrations <0.2 mg/l.

Jan 1, 2003

By William C. McBee

Specialized sulfur concretes were developed by the Federal Bureau of Mines as a result of research for the beneficial utilization of sulfur in construction materials. Materials were developed for use in acid and salt corrosive environments where portland cement concrete has been found to deteriorate. Because the mineral aggregates also come into contact with the corrosive media, concretes were developed utilizing both limestone and quartz aggregates. The sulfur binder used with both aggregates was modified by reaction with 5 pct dicyclopentadiene to improve product durability. Sulfur quartz aggregate concrete was found to have moderately high strength characteristics (6,000 psi compressive) and was extremely resistant to chemical attack by both acid and salt solutions. Sulfur limestone aggregate concrete exhibited very high strength characteristics (9,000 psi compressive) and was extremely resistant to chemical attack of salt solutions. Both types of concretes maintained their strength and integrity after long-term testing in acid and salt solutions and exhibited considerable resistance to damage by the action of freezing and thawing. Potential uses include leach tanks, electrolytic cells, thickeners, bridge decking, industrial flooring, pipe, and tile.

Jan 1, 1979

By Wallace W. Roepke

The Bureau of Mines studied the cutting characteristics of point-attack bits to reduce airborne respirable dust and energy during cutting. Linear cutting of two coal types using four bit types at three depths of cut with three space-depth ratios was performed with a modified horizontal milling machine using an optical particle-size monitor for respirable dust sampling. The cutting action of one bit on a rotary hardhead mining machine was mathematically analyzed and compared with the results of the linear cutting test. Airborne respirable dust per unit mass cut (specific dust) was found to be a monotonically increasing function of specific energy. Specific dust and energy decrease with increasing depth of cut. The amount of nonairborne respirable dust was 100 to 1,000 times greater than the airborne dust. The plumb-bob bit produced the most airborne respirable dust and the highest specific energy of the four bits tested. Rotary cutting was a greater dust producer and energy consumer than linear cutting because of the constantly changing depth of cut, space-depth ratio, and attack angle of the bit relative to the horizontal bedding planes. A new cutting technique is proposed to minimize the existing problems of the rotary cutting machines by providing greater production, reduced dust, and minimized methane ignition potential at the face.

Jan 1, 1976

By G. C. Broadhead

The lead district of Southeast Missouri covers an area of over 3000 square miles, including Maries County on the west, Jefferson on the east, Franklin on the north, and part of Madison on the south, or parts of ten counties. A general section of the rocks of the southeast part of this region would be about as follows, numbering from the top: 1. Sandstone (the second of Missouri geologists),.... 20 feet. 2. Chert beds—beds of passage below,...... 126 " 3. Magnesian limestone, chert, and quartzite,. .. 100 to 300 " 4. Lower magnesian limestone,......100 to 150 " 5. Gritstone and lingula beds,....... 50 " 6. Ozark marble beds,........5 to 20 " 7. Sandstone and conglomerate,. .. .. 5 to 90 " 8. Porphyry, Archæan 9. Granite, The thickness is approximate, for it is not possible to obtain the correct thickness of the various beds. No. 1 may be seen as detached outliers or loose masses of a hard sandstone or quartzite, and is found on the hilltops in the southern part of Madison County, in like topographical position in Reynolds County and the western part of Washington County. No. 2 consists of alternations of chert, clay, and quartzite. It is the formation which contains most of the limonite deposits of Central and Southern Missouri. In Reynolds County shafts have penetrated it 75 feet. Outcrops there and in Madison would indicate it to be at least 125 feet thick. Fossils obtained in various places prove it clearly to be of the age of the calciferous saudrock of the New York system, and Nos. 1 and 2 may also be referred to the age of the second sandstone of Missouri. No. 3 consists chiefly of thick beds of ash, drab and flesh-colored magnesian limestone, both coarse and fine-grained. These beds, where they occur, in Washington, Jefferson, and the southern part of Madison Counties, contain a good deal of quartz in drusy cavities. In Washington County the limestones are beautifully ramified by a system of connected drusy cavities generally lined with minute quartz crystals arranged in botryoidal and mammillary forms, and called " mineral blossom " by the miners. This is the lead-bearing rock of Washington County, but in the southern part of Madison it does not appear to be galeniferous. It is also undoubtedly the equivalent of

By Wils L. Cooley

Several aspects of coal mine safety-ground system operation are studied. Evaluations of two sophisticated ground-wire monitors are presented, along with a detailed report of development work on a modular ground-wire monitor. A portion of the report covers stray current flow in the safety-ground system, analyzing in detail conditions surrounding the generation of both dc and ac ground wire current. Considerable detail is provided concerning studies of mine ground beds. Additional progress is reported in the development of a. continuous ground-bed monitor, and new techniques are developed for the design of ground beds and their resistance measurement. New methods of accurately measuring electrical parameters of finite layered conducting structures are also reported. The effects of stray currents in ground beds is included. Touch-and step-potentials associated with mining equipment are analyzed, and methods are presented for determining earth voltage gradients around structures contacting earth. Instrumentation to determine gradients easily is suggested. Finally, an extensive effort is described dealing with lightning transients on open-pit coal mine ground systems. The nature of the transients, their expected frequency of occurrence, and the ways in which they damage equipment are analyzed in detail.

Jan 1, 1977

By Jeffery L. Kohler

This final report on Bureau of Mines Contract J0338028 presents the results of a research effort to predict incipient failure in electric-power-system components. The development of continuous monitoring techniques to detect an incipient failure would represent a significant improvement in system maintainability, availability and safety, This report describes the analytical and experimental aspects of the project. Mathematical models have been developed to study the behavior of cables and motors which are undergoing a deterioration process. These models allow a detailed study of the effect of deterioration on the component&apos;s terminal characteristics and performance. The efficacy of using negative-sequence monitoring is a reliable indication of deterioration has been established. Techniques for assessing the sensitivity of the prediction algorithm to component deterioration have been presented. An approach for modelling electrically-excited vibrations, and including these in the algorithm, has been presented.

Jan 1, 1987

Bernard MacDonald, Guanajuato, Mexico (communication to the Secretary*):—Mr. Iceyes&apos;s paper is very interesting to me because of my personal experience with the development of the ore-deposits of Lake Valley.

Jan 1, 1909

By E. P. Abrahamson

The effect of transition element binary solid solution additions upon the re crystallization temperature of nickel has been investigated. All additions raised the re crystallization temperature. Both the rate of change of re crystallization temperature with at. pet solute and the limit of initial linearity are found to correlate with the free atom ground state outer electron configuration of the solute element. A comparison of all of the correlations for the transition elements studied has yielded a set of empirical relations, which allows the prediction of the effect of dilute binary transition elements on the recrystallization temperature of other transition elements. The work of Abrahamson, et al.1-7 on dilute binary solution alloys indicated a correlation between the free atom ground state electron configuration of the solute and both the brittle-ductile transition and re-crystallization temperature. Further, it has been shown3,4 that the limit of initial linearity may also be correlated with the solute electron configuration. Since previous studies have dealt with bee and hexagonal base elements, this study is made to note what effect, if any, the fee base structure might have. Nickel also serves to give a solvent configuration which will allow the comparison of all of the transition element solvents. Olsen8 has studied the effect of some trace elements upon the recrystallization of nickel. He included only Ti, Zr, W, Mn, and Co of the transition elements. The differences in change of recrystallization temperature were attributed to the solute atom size and to the solubility of the solute in nickel. PROCEDURE All alloys were made using 99.9 + pet Ni with 0.003 C, 0.015 Fe, 0.007 0, and 0.0007 H. The solute elements were 99.9 + pet pure. According to the published binary phase diagrams9 and metallo-graphic examinations at X750, all solute elements were in solid solution. The alloys were arc melted and remelted four times in the form of cubic 200-g buttons under an argon atmosphere. They were then hot forged at 800oC to 0.750 in. diam, machined to 0.60 in., vacuum annealed for 1 hr at 700°c, swaged to 0.40 in. and annealed at 700oC for 1 hr in vacuum. The grain size was checked and found to be 77 * 20 grains per sq mm. The specimens were then swaged to 0.187 in., yielding 76 ± 1 pet cold work. All alloys were then chemically analyzed for the solute addition. The interstitial contents remained at the values of the starting material when checked on random alloy specimens. The swaged rod was cut into 8.25 in. lengths and heat treated in a gradient furnace for 1 hr. The gradient was maintained at 250" to 850°C over an eight inch length, recorded by twelve thermocouples. Control was ± 3oC, accomplished at the hot end. The recrystallization was determined metallo-graphically over the entire specimen. The criterion chosen was that point on the specimen showing the first recrystallized grain at a constant magnification, X200. Specimens were repeated, and the agreement was found to be generally ± 3oC.

Jan 1, 1962

By D. Hodouin

The paper reviews approaches to estimate in a real time fashion consistent mass flowrates and assays, using data from the on-stream analyzers and flowmeters of a flotation circuit. Results obtained with one algorithm operating on-line with an industrial flotation circuit are presented.

Jan 1, 1996

By V. E. Antonov

Hydrides of iron and iron-based alloys are thermodynamically stable only at hydrogen pressures in the gigapascal range and rapidly loose hydrogen under ambient conditions. At low temperatures, however, these hydrides can be retained in a metastable state at atmospheric pressure after being cooled under the high pressure to liquid nitrogen temperature. This review will discuss the current state of studies on phase transformations in the Fe-H and related systems and also on the composition, crystal structure and physical properties of the hydrides, both under high hydrogen pressures and in the "quenched" metastable state at ambient pressure. The studies at ambient pressure include magnetization measurements, X-ray and neutron diffraction, Mossbauer spectroscopy and inelastic neutron scattering. In the sections on Mossbauer and structural investigations of hydrides of Fe-Cr and Ni-Fe alloys new experimental results will be presented.

Jan 1, 2002

By Michael R. Brown

A facilities success or failure of doing well during a regulatory inspection is typically measured by the number and type of citations that result, and financial liability resulting from those citations. The success of a facility during an inspection depends on several factors including, the preparation prior to an inspection, behavior and activities during and inspection, and finally, action taken following the inspection. This paper contains suggestions for improving inspection results and establishing an attitude of compliance at manufacturing and mining facilities.

May 1, 2002

University of Alabama University, Alabama Mining and Metallurgical Society Meets first and third Mondays each month JOHN MACLEOD MCKEE, President WILLIAM L. ALLMAN, Secretary J. R. CUDWORTH, Faculty Sponsor RICHARD L. BOWRON, Counselor University of Arizona Tucson, Arizona Millers&apos; Society LA MONT WEST, President AL WALLACH, Secretary J. B. CUNNINGHAM, Faculty Sponsor B. R. HATCHES, Counselor

Jan 1, 1939