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The first mention of the mining and use of coal in the Pittsburgh district refers to the mine under Duquesne Heights that furnished coal for the garrison at the fort at Pittsburgh in 1760. Coal had been dug and used as fuel just outside of Brownsville, Fayette county, in 1759, but this was not a regular mine as the opening was in an outcropping. Maps of Ohio in 1770 showed "Cole Mines" at various points. The Penns purchased all the coal south of Kittanning in southwestern Pennsylvania from the Chiefs of the Six Nations for a reported price of $10,000. During the Revolution, coal from Herron Hill, Mincrsville, and Coal Hill, all within the present city limits, was used in Pittsburgh. There is today one custom pit opened in Coal Hill (Duquesne Heights). The first steam engine was set up in Pittsburgh in 1794 and used coal as fuel. The first mine in the Youghiogheny gas district was opened in 1796. In 1803, the first shipment of coal by water was made from Pittsburgh down the Ohio river and landed at Philadelphia, where it sold for approximately $9.50 per ton. The mines along the Monongahela were naturally the first to be opened. With the completion of locks and dams in 1844, permitting slack-water navigation, the industry began to thrive. The No. 8 field of Ohio and the Fairmont region of northern West Virginia were opened in the period 1840 to 1855. From that time on there has been a continuous development of the coal rcsources of this district, until at present productive capacity is enough to supply 30 per cent. of the country's needs of bituminous coal. The original method of working the Pittsburgh seam was to drive under cover at some easily accessible point on the outcrop with a single entry, usually 1½ yd. wide. Rooms or gangways were turned to the right and left from this entry and ventilation was usually poor and inade-

Jan 1, 1927

By J. H. Viljoen, C. H. Graan, N. B. Strydom, J. S. Greyson

M J Martinson (Fellow) There is everywhere a lamentable dearth of quantitative information on occupational factors affecting the health and safety of mineworkers, and as the authors point out in their introduction underground lighting is one of the factors which has received little attention in South Africa prior to this welcome paper. Since the authors are to some extent pioneering, it is perhaps inevitable that the paper should raise more questions than it answers, but nevertheless it provides a provisional yardstick against which the need for, and success of, remedial action may be judged. Before commenting in detail on a few aspects of the paper it may be worthwhile to summarize the statutory provisions relating to underground lighting, contained in Chapter 15 of the Regulations promulgated in terms of the Mines and Works Act 27 of 1956. Chapter 15 is entitled `Lighting, Safety Lamps and Contraband', but in the context of the present paper only four simple regulations need be noted: firstly, no person shall work or travel in an unilluminated part of a mine unless he carries a light ; secondly, adequate stationary lights shall be provided at stations and certain other localities in shafts, winzes and places used for winding; thirdly, mechanically propelled conveyances shall be provided with an effective bright light shining in the direction of travel; and fourthly, moving machinery to which personnel have access shall be illuminated so as to be clearly visible. In all four regulations the standard of lighting to be provided is wholly subjective, and under these circumstances the wide inter- and intra-mine variations in light intensity disclosed by the study are hardly unexpected. Nevertheless the data presented in the authors' Table I raise three points (1) Is there any evidence that the 19 mines visited during the survey are representative of the 45-50 large gold mines in South Africa, or that the shafts selected are representative of the respective mines? Mine managers would scarcely be human were they not to offer better lit working places for the survey; perhaps the use of a scaling factor (e.g. tonnes or transit mineworkers per shift, kilowatts, etc.) for each working place might have helped to put the figures in perspective. (2) Looking at two of the more numerous - and probably important - of the ten working places included in the survey, i.e. stations and tips, one is struck by the marked. skewness of both intensity distributions (with higher frequencies at the lower intensities) and the abrupt cut-off in both cases just short of pitch darkness. Thus, of the 45 meaned readings recorded at 26 tips no less than 19 fall in the lowest range of 0,1-0,9 1m/ft2, with but one tip in total darkness; of 46 readings on 26 stations, 7 fall in the lowest range and none is in total dark-'1 ness. Although a light with an intensity in the range 0,1-0,9 1m/ft2 may satisfy the regulations, it is certainly arguable that in some situations it may be safer to have no light at all. (3) In view of the skewness referred to above, one wonders how meaningful are the `total average light intensities for (the gold mining) industry' quoted in Table I, which the authors compare with illumina¬tion levels found in other countries. Looking at tips again, one notes that 34 out of 45 meaned intensity readings fall below the `total average' for tips, and only 10 exceed it. From this it may be concluded that a few well-lit working places included in a `total average' may conceal a plethora in Stygian gloom. In their discussion the authors make fleeting reference to the effect of underground lighting on productivity and accident rates, without however quoting any South African experience in this regard. Intuitively it seems highly likely that better lighting (in the widest sense) would improve productivity and reduce accidents, and of course it is in these areas that the mining industry might seek economic justification for providing better lighting. It is all the more regrettable therefore that these factors were not studied simultaneously with the present investigation, especially at the Psychological Division of the Human Sciences Laboratory has recently published a study on underground accidents in the gold mining industry without making any reference whatsoever to lighting as a causal factor. In the event neither of the two studies enables us to make an economic appreciation of the situation, and this seems to be a classic example of a situation where some dovetailing of research effort would have greatly increased the useful return. On the effect of lighting on accidents, it may be noted that in 1939 Mickel presented some very interesting statistics to the Mine Managers Association of the Transvaal2, on the improvement in accident rates which followed the random issue of electric cap lamps to native mineworkers in the Hercules Section of E.R.P.M. the previous year. Based on a 12 month trial period in which 250 000 shifts were worked with carbide lamps and (contemporaneously) 307 000 shifts with cap lamps, the incidence of major accidents (at least one day in hospital among men using carbide lamps was 1,15 accidents per 1000 shifts, while the incidence of minor accidents (requiring dressing only) was 11,52 per 1 000 shifts. The corresponding figures for men using cap lamps were 0,79 and 7,31 accidents per 1 000 shifts respectively, representing a reduction of over 30 per cent in both major and minor accidents. While these figures are obviously dated - only men using cap lamps were issued with hard hats, for instance - they do indicate a need for similar research today.

Jan 1, 1971

By S. Q. Zhu

Coal Water Mixtures (CWMs) are densed suspensions of coal particles in water. Viscosity is one of the most important rheological properties of CWMs and it is desired to be as low as possible. The slurry viscosity was influenced significantly by additive formation, the particle size distribution and the ash content of the coal. However, the influence of dispersants is most obvious. At present, there are several kinds of dispersants such as polymeric styrene sulfuric sodium, lignin sulfonate, humate, polycarboxy salt, ethylene epoxide surfactant. In this paper, a newly synthesized CWM dispersant has been reported, which is an efficient anionic surfactants of polycarboxylic acid type. The synthesis process includes three steps. At the beginning, the polyglycol acetate ester has been performed by acetic acid and polyethylene glycol (PEO) on the condition of acetic-acid/PEO ratio 1:1.1, at 368~373K for 30 minutes. Then the macro-monomer is prepared through the esterification of 85.71% acrylic and 14.29% polyglycol acetate ester, at 368~373K for 10 minutes. After that, the polycarboxylic acid CWM dispersant is polymerized using proper proportion macro-monomer, acrylic (AA) and sulfonic styrol sodium, at 368~373K for 1 hour. This new dispersants are used in the coal water mixtures formulation. Four kinds of coal used in the experiment are Shuang Yashan, Tunliu, Luning, Changcun samples. ? The highest concentration for shuanyashan coal is 70% when the dosage of dispersant is 0.4%, and the content of -200 meshes particles is 75.53%. As the dosage of dispersant de-creases to 0.25%, the Shangyashan CWM concentration is 67%. ? For Tunliu coal CWM concentrations are in the range of 76% to 75% when dosage of the dispersant changes from 0.4% to 0.25% at the same particle size distribution of 83.5% minus 200 meshes. ? The highest concentration for Luning coal is 69% when dosage of the dispersant is 0.4%, and the content of -200 meshes particles is 88.86%. ? For Changcun sample, the coal concentration of CWM is 73%~75% when dosage range of the dispersant is 0.35%~0.5%. The experiments show that the synthesied dispersant is quite promising for some coals CWM preparation, but a little bit coal-dependent. The Proximate and Ultimate analysis, surface characteristic measurement have been made to investigate the interactions between coal and additives.

Jan 1, 2014

By P More

US 4,132,621-In the electrowinning of aluminum, the cells are aligned in a lengthwise direction so as to lessen the harmful influence of the induced magnetic fields Each cell is supplied with current from the preceding cell both via the head arid at least one side riser The output of the cathode bars is divided into two separate groups, the upstream group supplying the head of the subsequent cell arid the downstream group supplying the side risers of the subsequent cell This produces a substantial improvement in cell efficiency arid a greater regularity P Morel, J P Dugois, arid B Langon, assigned to Aluminium Pechiney. Jan 2, 1979 12 pp. (204¬243M) Filed 1-12-78 (868,861) Priority: France, 1-19-77 (77/2,213) US 4,134,806-Cells, anodes, arid methods for use in the electrowinning of nickel, cobalt, copper, zinc, or other metals from an acid ore leach solution or the like The cell is provided with vertically immersed stationary cathodes and stationary rod anodes which are noncorrodible by the electrolyte arid are electrocatalytic to the anode reaction. The spaced parallel anode rods are connected to electric current supply bars The anode rods have an electroconductive core made of a metal alloy arid a surface coating of an oxide of platinum or a platinum group metal The ratio of active cathode surface area to active anode surface area is preferably at least 3 0. De Nora arid C Traini, assigned to Diamond Shamrock Tech¬nologies, SA Jan 16, 1979 13 pp. (204-105R) Filed 9-15-77 (833,661) Priority Italy, 1-29-73 (19738 A/73). Same British 1,434,334-5, dated May 5, 1976 US 4,135,994-In the electrowinning of aluminum at a high current efficiency, the electrolytic bath is a mixed molten salt consisting of 2-15% by weight of aluminum trichloride, 15-83% of sodium chloride, 15-70% of combined calcium chloride arid magnesium chloride but riot more than 40% of calcium chloride, arid optionally up to 10% of barium chloride Preferably, plate-shaped graphite electrodes used for both cathodes and anodes are arranged in parallel inclined relation so that the axis in the lengthwise direction makes an angle of from 10° to 45° to the horizontal. T Ishikawa arid H Ichikawa, assigned to Nippon Light Metal Co Ltd Jan 23, 1979 4 pp (204-67) Filed 11-15-77(851,632) Same British 1,550,502, dated Aug 15, 1979

Jan 1, 1980

By A. L. Holley

There are regularly manufactured in the eleven Bessemer steel rail mills of the United States, 119 patterns* of steel rails, of 27 different weights per yard. This list does not include patterns which, although still largely in use, are regarded by experts as obsolete, and which would swell the number to nearly 300; nor does it include all the patterns for which rolls are kept on hand to fill a passible demand; nor does it include extra patterns rolled in one finishing groove by opening or closing the rolls so as to get different weights with the same contours. The list embraces only those separate patterns which are subject to current orders. How thoroughly modern these patterns ere, is shown by the fact that of the whole 119, there are but five patterns of conspicuously bad shape; all the rest more or less completely illustrate the standard features,—a heavy head, light web and Hanges, and a good angle to hold the fish-plate. Sixty-two per cent. of the patterns have the "Chanute" head, which was not designed until 1874.† Sixty-four per cent. of the 119 patterns are embraced under five weights per yard,; three only of these vary from standard type; there are thus 76 patterns, all of them modern and standard, to represent five different weights, for which five patterns would perfectly answer. Of the 60lb. rails, there is only one of the pear-head type, while a dozen of the bevelled head templets cannot be distinguished from each other

Jan 1, 1881

By S. Vorberg, B. Fischer, U. Glatzel, R. Völkl, D. Lupton, M. Wenderoth

Owing to their excellent oxidation and corrosion resistance, Pt and its alloys are being used preferentially at elevated temperatures and in aggressive environments. For example, an important application field is the glass industry. Alongside the discovery of new potential application fields, the knowledge of material properties is essential for computer simulations, design configuration, process optimization, research and development or quality assurance purposes. Due to the importance for technical applications high-temperature properties have been investigated for currently available Pt-base alloys with ongoing improvements. For the determination of tensile creep test data up to 3000°C, including precise strain measurement, special experimental equipment has been developed at the University of Applied Sciences Jena, Germany. An overview of the existing and newly obtained mechanical property data on pure Pt, solid-solution strengthened Pt-Rh alloy, oxide dispersion-hardened materials Pt DPH and Pt 10%RhDPH as well as cutting-edge results on Pt-base superalloys hardened by intermetallic precipitates will be presented and discussed. Furthermore, some important application examples for the abovementioned Pt-materials will be given.

Jan 1, 2006

Stillwater Mining Company (SMC) has an extensive history with tunnel boring machines (TBM) at the Stillwater and East Boulder underground PGM mines in Montana. The most recent TBM used is for the Blitz Project, where a 5.5m (18ft) diameter main beam unit, commissioned in Q3 2012, is being utilized to drive a 6,975m (22,500 ft) ventilation and haulage level East of the Stillwater Mine for the Blitz expansion project. The assembly/commissioning of the TBM, institution of the planned diamond drilling program, application of ground control systems, and the current tunneling metrics will be covered.

Feb 23, 2014

By M. P. Tixier, F. Segesman

Explanations bused on theory and laboratory tests tire offered for certain unusual features of SP logs which may befog their interpretation, namely the "sawtooth" SP and the reduction or increase of SP with time. The sawtooth SP is frequently seen in SP recordings of thick, very permeable watcr. sands of the Louisiana Gulf Coast. Using SP data from a resistor network analog, this anomaly is explained on the basis of a thin shale streak within the sand. under which the invading filtrate accumulates by gravity segregcitiorr. The electromotive force then appearing across the shale streak gives rise to the anomalous SP. Reduction of the SP on successive logging runs Ira often been observed in very permeable sands when as indicated by the resistivity curves, the invasion depth has been reduced to practically zero. Laboratory results verify that this phenomenon may be due, to the presence of air electromotive force, across the mod rake when the fluids on either side differ in activity. Also, there is, in some cases; an increase of SP deflection on successive logging runs, because the emf initially present across the mud cake disappears as the somewhat saline water just behind the mud cake is progressively flushed out by the invading filtrate.. Field example and laboratory data are presented. I N T R ODUCT1ON Some unusual features are frequently observed on certain SP logs which make interpretation difficult. The purpose of this paper is to offer explanations of several cases of interest. All of these arc related to the conditions of invasion. The cases to be discussed are as follows. 1. The sawtooth SP anomaly which is frequently seen within the thick, highly permeable saltwater sands of the Louisiuana Gulf Coast 1. Reduction of the SP deflection from the usual sand line in very permeable sections when the depth of invasion is practically nil. As will be explained, such a reduction is attributable to a membrane electromotive force across the mud cake. 3. An increase of the SP with time just after the iormation is drilled as a result of progressive flushing of the invaded zone. FUNDAMENTALS OF SP PHENOMENA An explanation of SP phenomena must begin with the following basic ideas. 1. The SP log derives its character from ohmic potential differences in the hole produced by currents flowing through the mud.' These currents are driven by electromotive forces which are primarily electrochemical in origin. Other possible types of SP-producing electromotive forces may be disregarded for the purposes of this paper. 2. The electrochemical emf's associated with permeable formations are now understood to consist of liquid-junction emf's and membrane emf's.',' As schematically shown by thc battery symbols in Fig. 1, the liquid-junction emf, E,,,, exists at the contact between waters of different chemical activities, a,,,, (mud filtrate) and tr,,. (formation water); the shale membrane emf, lS.sn. exists across the adjacent shales whcn they separate waters of different activities. The emf's just cited are additivc in producing SP currents (arrowed circles of Fig. I). Thus, neglecting for the moment any possible membrane emf across thc mud cake, the total electrochemical emf, E,, will be given by their sum, where K,., -! K,q,, = 12 + 59, or 71 at 75 °F. In the log interpretations the SP of a thick sand (i.e.. the static SP) is generally related to the activities of the filtrate and formation water through Eq. 1. by setting the static SP equal to - E,.

By Marco Fellin, Van E. Komurka

Significant cost and construction benefits were obtained from performing a bi-directional static load test prior to construction on the Russell Street Bridge Replacement project in Missoula, Montana. The project utilized 24 drilled shafts to support two three-span bridges across the Clark Fork River. A bi-directional static load test (“BDSLT”) was performed on a large-diameter production shaft to demonstrate construction methods and confirm design assumptions. Subsurface conditions consisted of gravel with sand to a depth of 20 feet (6.1 m), underlain by gravel with sand, silt, cobbles, and occasional boulders. The test shaft had a nominal diameter of 5.9 feet (1.8 m), and an embedded length of 75.5 feet (23.0 m). The geotechnical engineer of record and the BDSLT test engineer collaborated to optimize the BDSLT jack assembly location within the test shaft, determine appropriate instrumentation locations, and plan the test protocol. The maximum applied test load was 10,707 kips (47.6 kN). Significant benefits were obtained from performing the BDSLT test, including 1) reducing each production shaft’s length by using a higher LRFD resistance factor allowed by having performed the testing, 2) using test-determined unit shaft resistances to evaluate and accept two production shafts that may have otherwise required remediation, and 3) providing the Montana Department of Transportation (and other designers) with increased presumptive unit resistance values in the gravel/cobble/boulder deposits. PROJECT DESCRIPTION The project was constructed in Missoula, Montana for the Montana Department of Transportation (“MDT”). The original bridge was approximately 60 years old, and consisted of a two-lane, 420-foot-long (128-m), four-span, riveted steel plate girder design spanning the Clark Fork River. The bridge was due for replacement owing to its deteriorated state, and the need for increased traffic volume capability afforded by a four-lane structure. HDR was the structural engineer. The preferred bridge alternate was a 459-foot- long (140-m), three-span, welded steel plate girder design. The new bridge was designed to meet current standards in accordance with MDT bridge design and AASHTO LRFD criteria. The new bridge was constructed in phases to keep traffic open during construction.

Jan 1, 2019

By Michael J. Klishis

West Virginia University researchers examined risk and exposure in the roof bolter operator's job and developed approaches for preventing accidents and for evaluating system and human performances that may be appropriate as a general application to improve safety and efficiency in the industry. Using a microanalysis of accident data and underground observations, the researchers classified bolting injuries within one of four work routines: 1) drilling bolt holes; 2) bolt installation; 3) machine tramming, (re)positioning and setting the ATRS; and 4) general face preparation. Time and motion studies were then combined with injury data analysis to develop risk and severity indices, as well as a severity-weighted index that served to determine the degree of risk and exposure by work routine. More than two dozen bolting-related problems were identified as potential situations that could lead to injuries or expose workers during their job. Approaches to avoid these situations were suggested and then applied at six mining operations to evaluate specific problems in roof bolting operations. These suggestions encompassed the three E's of Safety (Engineering, Education, and Enforcement) and emphasized the analysis of worker behaviors that lead to human error accidents.

Jan 1, 1993

By C. Chingwaru, W. Chingwaru, J. Vidmar

"Zimbabwe is endowed with rich deposits of minerals such as diamonds, platinum, coal, uranium, lithium, gold, antimony, iron, and chrome. Bioleaching has been implemented as an efficient and low-cost method to extract metals such as copper, cobalt, and gold from sulphide and/or ironcontaining ores and mineral concentrates in a number of countries around the globe. Zimbabwe, despite being a world leader in mineral wealth, has gone through years of economic stagnation which have brought with them energy shortages. Bioleaching is an innovative way to recover minerals from ores using relatively low-capital-cost and non-polluting technology. Principally, iron- and sulphur-oxidizing bacteria can be used to oxidize iron and sulphide to ferric iron and sulphuric acid, respectively, and the ferric iron oxidizes the insoluble metal sulphides to soluble metal sulphates that can be readily recovered from solution. Although some minerals such as gold are inert to biological reactions, they can be liberated using bacteria that act on certain types of ores and other minerals that co-occur with these minerals. The geology of the mineralized areas in Zimbabwe, rich in chalcopyrite / pyrite, allows a number of microorganisms to be used for the extraction of minerals by bio-oxidation. This paper reviews the potential of bioleaching in the country. IntroductionZimbabwe has rich deposits of minerals including diamonds, platinum, coal, uranium, lithium, gold, antimony, iron, and chrome. Bioleaching is defined as the use of microorganisms to facilitate the extraction of metals from sulphide or iron-containing ores or concentrates (Rawlings, 2004, 1997). Bioleaching has been shown to be an efficient (Blowes, Ptacek, and Jurjovec, 2003; Nordstrom and Southam, 1997; Schippers, 2004) and low-cost (Schippers et al., 2010) method to extract minerals in many countries around the globe. For example, aerobic Fe(II)- and sulphur-oxidizing bacteria have been shown to be up to two orders of magnitude more efficient in the oxidation of pyrite than the chemical processes (Blowes, Ptacek, and Jurjovec, 2003; Nordstrom and Southam, 1997; Schippers, 2004). Additionally, bioleaching can be used to extract minerals from low-grade ores, sulphidic waste rock dumps, and tailings efficiently (Schippers et al., 2010)."

Jan 1, 2017

By M. T. Ityokumbul

Experiments have been carried out to determine the efficacy of bubble column flocculation. An acid-base neutralization method was used to determine the mixing time in a 0.064 m x l.5 m bubble column equipped with a Mott porous sparger. The mixing times decreased as the tracer injection point approached the gas sparger. Preliminary flocculation experiments on two clay samples were carried out. The effects of frother addition and air flow rate are presented and discussed.

Jan 1, 1998

By Maria Salazar-Villalpando, Todd H. Gardner

"Efficient utilization of CO2 can help to decrease global warming. Methane reforming using carbon dioxide has been of interest for many years, but recently that interest has experienced a rapid increase for both environmental and commercial reasons. The use of CO2 provides a source of clean oxygen, which eliminates the need for costly oxygen separation plants. The product of dry reforming is useful syn-gas, which can be used to generate electrical power in a SOFC or in the production of synthetic fuels (hydrocarbons and alcohols). Hexaaluminate catalysts prepared at NETL may represent a product that can be utilized for the conversion of CO2 to syn-gas. In this work, transition metals dispersed in barium hexaaluminate have shown to be promising new catalysts for dry methane reforming. In this investigation, a series of BaNixAl12-yO19-d catalysts with varying Ni content were prepared by co-precipitation followed by calcination at 1400°C. CO2 reduction by dry methane reforming was carried out to determine catalyst performance as a function of temperature and carbon formation was also quantified after the reforming tests. Results of catalysts characterization, dispersion and surface area, were correlated to catalytic performance.IntroductionEfficient utilization of CO2 can help to decrease global warming. Methane reforming using carbon dioxide has been of interest for many years, but recently that interest has experienced a rapid increase for both environmental and commercial reasons. The use of CO2 provides a source of clean oxygen, which eliminates the need for costly oxygen separation plants. The product of dry reforming is useful syn-gas, which can be used to generate electrical power in a SOFC or in the production of synthetic fuels (hydrocarbons and alcohols). The dry reforming reaction has been known for a long time. Recent publications have reported studies over several catalysts. For example, the CO2 reforming of CH4 over mesoporous nanocrystalline zirconium powders (ZrO2–3%M2Ox; M: Ce, La and K) at 700ºC have shown methane conversion up to 60% (1). Similarly, the effect of Ni content (1–12 wt%) on the surface and catalytic behavior of bimetallic PtNi catalysts supported on ZSM-5 for reforming of methane with CO2 has been studied and report shows a maximum conversion of 16% and catalyst deactivation was observed during the first hour of time on stream (2). In another report, (3) Ni/a-Al2O3 catalyst was tested for syn-gas generation at 750ºC. The maximum methane conversion was 25%."

Jan 1, 2008

By H. M. Chance

Jan 1, 1887

By M. E. Fine, A. A. Hendrickson

The critical resolved shear stress and the strain rate dependence of the .flow stress are reported for Ag base A1 single crystals up to 6 at. pct A1 over a temperature ralzge of 4.1° to 470°K. At room temperature the solid solution strengthening is attributed brinciballv to an increase in the dislocation density on alloying. At 42°K the alloys are relatively stronger because the dislocations widen on alloying and are more difficult to cut. In a previous paper, the authors reported the characteristics of strain aging in Ag base A1 alloys.' The variation of the magnitude of the strain-aging yield drops on aging time, aluminum content, and testing temperature strongly indicated that the phenomenon is due to the Suzuki mechanism. In the present paper, the critical resolved shear stress (CRSS) and the strain rate dependence of the flow stress are reported for Ag base A1 single crystals as functions of testing temperature (4.2" to 470") and A1 content (0 to 6 at. pct). Observations on the substructure and measurements of the effect of crystal growth rate are also given. The experimental re- sults appear explainable considering that aluminum additions increase the dislocation density and dislocation width. EXPERIMENTAL METHOD The methods of specimen preparation and tensile testing were described previously.' Briefly, single crystals were grown from the melt in a vacuum (1 x lom5 mm Hg), shaped into tensile samples by a combination of abrading and acid etching, annealed at 850°C in a vacuum (1 x 10" mm &Z) for several days, and furnace cooled to 200'. The testing was done on a model TM Instron using friction grips and a strain rate of about 5 x 106 per sec unless otherwise noted. The various testing temperatures were obtained by immersing the specimens in the following media: 1) 4.2': liquid helium using the apparatus of G. Byrne;' 2) 77°K: liquid nitrogen; 3) 200"K: dry ice and acetone; 4) 415' K: ethylene glycol; 5) 460' \ to 480' : molten Stanalax. In the determination of the CRSS above 296' K, a ratio method was used; the crystals were strained initially at the higher temperature, 0.1 pct shear strain, and then tested at 296' . The ratio of the flow stress between the two temperatures was then multiplied by the average CRSS at 296' K to obtain the value of the CRSS at the high temperature. (The test at 296' showed a yield point resulting from strain aging; the flow stress at 296' K was taken as the lower yield stress.) The ratio method, we believe, is more accurate than using different crystals since

Jan 1, 1962

By Alan G. Mayton

Exposure to whole-body vibration (WBV) and the postural requirements of the job have been identified as important risk factors in the development of musculoskeletal disorders of the back among workers exposed to a vibratory environment. This paper focuses on preliminary results of WBV data collected for two groups of haulage trucks ? four older trucks from manufacturer A (MFR-A) and two newer trucks from manufacturer B (MFR-B). All of the trucks and their respective seats were considered to be in good working order during the study. Measurement periods for the truck groups had similarities, but varied from 2 to 58 minutes. Sampling times for the older trucks included a mean of 19.5 minutes and a standard deviation (STD) of 6.5 minutes compared to a mean of 40.8 minutes and a STD of 12.1 minutes for the newer trucks. Data collection coincided with the approximate delivery and first operation of the new trucks, and occurred approximately 12 months apart under similar weather and road conditions, and with the same drivers except an additional driver was included with the older trucks. Truck routes were somewhat different in that quarry production had changed location in the time between data collection activities. Overall, the results suggest that the newer trucks may provide better overall isolation to drivers/operators from WBV exposure compared to the older trucks operating at the quarry; although, this will need to be confirmed with additional measurements. Considering the higher variability and shorter sampling times for the older trucks, the results should be viewed with caution. For two of seven trials, the older trucks showed that seats amplified vibration, i.e., a transmissibility (T) >1.0. Seat T for the older trucks ranged from 0.31 to 1.17 with a mean of 0.77 and STD of 0.32. This contrasted with the newer haulage trucks where seats amplified vibration in 3 of 8 trials. In this case, T did not vary greatly and ranged from 0.87 to 1.05 with a mean of 0.97 and STD of 0.07. Regarding older trucks, in five of seven trials, the seat (output) data of weighted root-mean square (RMS) acceleration (wRMSZ) for the dominant z-axis exceeded the action level of 0.5 m/s2 action level recommended by the European Union Good Practice Guide for WBV (EUGPG) and levels exceeded the recommended exposure limit of 1.15 m/s2 in two of the seven trials. The wRMSZ values for the older trucks varied from 0.41 to 1.83 m/s2 with a mean of 0.99 and STD of 0.57. Similarly, newer trucks indicated a narrower range of wRMSZ from 0.38 to 0.95 m/s2. The mean wRMSZ was lower for the newer trucks at 0.58 m/s2 with a STD of 0.23 m/s2. Similarly, newer trucks indicated wRMSZ reached or exceeded the action level in four of eight trials. None of the trials with the new trucks showed wRMSZ levels that reached or exceeded the recommended 1.15 m/s2 exposure limit. As an indicator of driver/operator discomfort, overall weighted total RMS acceleration (vector sum) values seem to show a ?rougher? ride for the older trucks. The vector sum values for these trucks ranged widely from 0.70 to 2.59 m/s2 and, in four of seven trials, showed levels greater than 1.40 m/s2. The mean vector sum was 1.44 m/s2 with a STD of 0.75 m/s2. Comparatively, the newer trucks exhibited less variation with a range from 0.69 to 1.59 m/s2. The mean vector sum was 1.02 m/s2 with a STD of 0.35 m/s2. Vibration dose values for the dominant z-axis (VDVZ), gave a sense of vehicle jarring/jolting conditions. All trials with the older trucks were within the recommended EUGPG action level of 9.1 m/s1.75. On the other hand, in three of eight trials, both newer trucks exceeded this action level with values of 9.18, 12.58, and 13.21 m/s1.75. Neither truck group showed VDVZ that exceeded the exposure limit of 21 m/s1.75. A statistical analysis was not conducted, since the differences reported between truck groups may not be statistically significant owing to the relatively small sample size. Road conditions, changes in the truck routes, and driver/operator differences (e.g., stopping and turning) are possible factors in the higher VDV for the newer trucks.

Jan 1, 2008

By Wagner Aldeia, Duclerc Fernandes Parra, Danae Lopes Francisco, Ademar B. Lugão, Lucilene Betega de Paiva

The inorganic nanotube halloysite (HNT) is a promising type of natural occurring filler for polymers. Its characteristics, such as high aspect ratio (10–50), small size, and high strength (elasticmodulus—140GPa) suggest that HNT shave a potential use in high-performance polymer nanocomposites. Compared to other nanoclays and nanosilica the relatively low content of hydroxyl groups on their surfaces makes HNTs relatively hydrophobic, although, sometimes, this is not sufficient for guaranty a good interfacial adhesion in composite systems. Further hydrophobic treatment is required to improve HNTs compatibility with polymer matrixes, maximizing interfacial interactions. In the present study, different percentages of EPB (2,2-(1,2-ethene diyldi-4,1-phenylene) bisbenzoxazole) was used to perform anon-covalent functionalization of halloysite, based on electron transfer interactions. The functionalization is characterized by specific surface area (BET), thermogravimetric analysis (TG) and water/toluene extraction experiment.

Mar 1, 2018

By Auguste J. Rossi

We cannot expect, within the limits of this paper, to treat this subject exhaustively, but will endeavor, in the following, to present it in as concise a manner as is consistent with a clear exposition of its importance. Ores of titanium, titaniferous iron-ores (that is, iron-ores containing a notable amount of titanic acid, TiO2,, say not less than 5 per cent., generally 10 to 20 per cent., and frequently more, up to 40 per cent. or thereabout), occur all over the world in immense quantity, " in mountain masses," constituting in some localities, as in Sweden, Norway, Canada, the Adirondacks (N. Y.), in North Carolina and other States of the Union, the geological formation itself, the igneous rocks having, in many places, been so permeated with the metallic oxides as to justify their being called iron-ores. As a rule they are Bessemer ores, quite free from phosphorus and sulphur, though not invariably so. When the percentage of titanic acid is very high, that of the iron is low, but the proportions do not necessarily vary in the same ratio; that is, a rich ore may contain more titanic acid than one lower in iron. The percentage of iron varies, being as low as 35 to 36 per cent. in real ilmenite. It is more generally not less than 50 to 55 per cent., reaching often an average of 58 to 60 per cent., and as high as 63 to 65 per cent. It is obvious that if these ores were to be considered in the same light as other iron-ores, equally rich in iron, they would form an excellent stock for blast-furnaces for years to come, as their supply might be called inexhaustible, and they could

Jan 1, 1903

By R. A. Graham, R. W. Rohde, J. R. Holland

In a shock wave compression study of a martensitic Fe-30 pct Ni alloy, Graham, Anderson, and Holland' found a region of unusual compressibility extending from a few kilobars up to about 20 kbars. This region was characterized by a continuously decreasing shock wave velocity with increasing stress. In this note, we report the results of a study initiated to determine the source of this unusual compressibility. In earlier shock-loading experiments on martensitic Fe-30 pct Ni, Loree et a1.' determined that a phase change occurred at about 80 kbars. Subsequently, Bowden and elly found that samples of a similar material shock-loaded at about 100 kbars experienced a martensite-to-austenite transition. Their crystal-lographic analysis showed the transition was a direct reversal of the established martensite system to the austenite phase. The shock loading in the present experiments was accomplished by precisely controlled plane impact between two discs of the sample material. This configuration created a state of uniaxial strain in the two the front of a projectile which was accelerated to various velocities. Planarity between the impacting discs was controlled to 5 x 10-4 rad, and impact velocities were measured to 0.5 pct. From a knowledge of the Hugoniot relationships of the material and the impact velocity, the shock-wave stress can be calculated. Samples were shocked at 18, 50, 70, and 100 kbars. The specimen discs shocked at 18 and 50 kbars were instrumented with quartz gages to observe the stress time profile. A more detailed description of the experiment has been given previously.4 The shock-loaded specimens were recovered intact by decelerating them in a catcher filled with soft wood. Discs of Fe-30 pct Ni nominally 12.7 mm thick and 64 mm in diam were cut from bar stock. Chemical analysis of the material provided the following composition in weight percents: 29.5 Ni, 0.50 Mn, 0.21 Si, and 0.10 C, with traces of Cr, Cu, Mo, Al, and Co. The discs were austenitized at 650° C for 2 hr at a pressure of less than l0-' torr, and furnace-cooled. Martensite was then produced by quenching the discs at -196" and holding 168 hr. The initial martensitic structure formed is shown in Fig. l(a). Typical microstructures of samples shock-loaded at 18 and 100 kbars are shown in Figs. l(b) and l(c). The banded structure with the austenite regions running parallel to the shock propagation direction was characteristic of samples shock-loaded at all stresses. No such banding was found in samples that were not shock-loaded. Comparison of Figs. l(b) and l(c) shows that, although under the optical microscope the two microstructures are quite similar, the martensite plates of the specimen shocked at 100 kbars etched in a distinctly different manner. This unique etching behavior of martensite in samples shock-loaded above the 80 kbar transition point has also been observed by Leslie el al.' These investigators determined from X-ray and electron microscope studies that fcc martensite, similar in appearance to normal bcc martensite, had been formed under shock loading. A quantitative determination of the amount of austenite present after shock loading was made by X-ray techniques. Both the methods of Lindren' and Miller' were utilized. The results are shown in Table I. The error limits are those experimentally observed from two independent analyses of each sample and represent the precision of the experiment. The absolute error, which should be similar for each sample, is believed to be about 10 pct. It is seen that as the shock stress increases the amount of austenite present also increases. On the basis of the X-ray and microscopic observations, we conclude that shock loading below the 80 kbar ersal will initiate a martensitic reversal: the amount of reversal that occurs increases with in-

Jan 1, 1969

By W. S. Ayres