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By Duane L. Abata

Toxic gases produced by the detonation of six explosives were measured in an underground hardrock metal mine during actual mining operations. The six explosives included two semigelatin dynamites, three slurry explosives and an ammonium nitrate, fuel-oil/ammonia dynamite combination. Explosives were detonated at the face of a drift and the toxic gases produced by the detonation were trapped to the end of the drift by a bulkhead located a short distance away from the face. Toxic gas concentrations were then measured with direct readout instruments and together with the containment volume, the toxic gas volumes per mass of explosive were calculated. Toxic gas measurements were found in the following ranges (ft3/lbm): NO, 0.010-0.035; NO2, 0.003-0.019; CO, 0.08-0.30; S02, 0.00-0.05; and CO2, 0.7-1.8. Results showed that toxic gas production (ft3/lbm) correlated with the densities (kg/m3) and energy densities (kJ/kg) of the explosives tested.

Jan 1, 1979

Increasing depths and mechanization of underground mines have led to the production of large amounts of gaseous and particulate contaminants. Over 100 000 lives have been lost due to methane gas and dust explosions in coal mine workings in both the United States and Canada since 1900. There is, therefore, the need to constantly assess and evaluate the performance of existing mine ventilation systems to maintain safe and acceptable mine environmental conditions. This paper advances research initiatives in the control of methane gas in underground mine environments. It uses the results of continuous monitoring of methane gas concentrations conducted in selected coal mines in North America to assess the effectiveness of existing auxiliary ventilation systems to control methane gas concentrations. The results show that the average quantities of fresh air required to dilute, disperse and remove methane gas concentrations within set levels of one minute varied from 5.43 m3/sec. to 27.97 m3/sec. in the development headings. The average dilution times in the headings studied were less than eight minutes. The calculated dilution efficiencies of the auxiliary ventilation systems in the headings varied from 12% to 139%. These efficiencies ranged from poor to excellent. This implies that the auxiliary ventilation systems were capable of controlling the methane gas concentrations below statutory levels but may not be able to cope with large and unusual methane gas concentrations in the headings. This study is significant in the control of methane gas and coal dust explosions in coal mines.

Sep 1, 2001

By J. C. Bierlein, R. A. Dodd

Endurance strengths at 10' cycles, fatigue-hardening rates, and endurance strength/0.2 pct proof stress ratios have been determined jbr a range of Cu(Ni), Cu(Si), and S.R.0. Cu(Au) solid solutions. Some douht is cast on simple cross slip models of fatigue hardening in view of opposite composition dependencies of hardening displayed by Cu(Si) and Cu(Au). The temperature dependencies of hardening also are the opposite of predictions made on the basis of a cross slip model. A correlation apparently exists between the fatigue strength/0.2 Pc~ proof s1.re.s~ ratios and rates of fatigue hardening. An increase in PS/PS due to alloying or temperature change is accompanied by a decrease in hardening rate, and vice versa. In recent years there has been much interest in the determination of the dislocation structure of fatigued metals and alloys. The accumulated evidence, e.g., Refs. 1 to 5, suggests that the structure may be dependent on the stacking fault energy, 7, of the fatigued metal in the same way that fatigue hardening rates have also been shown to apparently depend on u .6' 7 The above research followed the various earlier theories relating crack nucleation to ease of cross slip, e.g., Refs. 8 to 131 so "ggesting that y may indeed be the parameter of principal significance in all facets of the fatigue process. However, comparatively little attention has been paid to correlating engineering fatigue data with observations of the above type. Certainly, it would be useful if potential engineering fatigue performance could be assessed from a knowledge of easily determined alloy properties, and the present research originated from this standpoint. TO investigate the widest Possible range of 7 would require the use of two solvent bases, e.g., aluminum and copper, but a reasonable coverage can be provided by copper-based solutions alone. Therefore, it was decided to work with Cu(Ni) and Cu(Si) solid solutions, the approximate stackillg fault energies of which are given in Table I. The y range extends from low, Cu(7.5 at- Pet Si), to moderately high in Cu(2-5 at. ~ct ~i) and two of the Cu(Ni) alloys. The values listed in Table I should be regarded as qualitative only, being derived as follows. Dillamore and smallman14 quote a value of 85 i 30 erg.cm-2 for the stacking fault energy of pure copper, based on an earlier value due to Howie and swannl5 corrected by Brown's formula.'' Since the ratios (alloy)h(pure copper) have been reported17,18 for Cu(Ni) alloys containing up to 30 pct Ni, approximate ) values for these alloys can be computed, and a rough estimate of 7 for Cu(50 at. pct Ni) obtained by extrapolation. The relatively low y value obtained in this way for Cu(50 at. pct Ni) coincides with the observation of Nakajima19 that the stacking fault probability is a maximum at this composition. Likewise, the y values for the three ~u(~i) alloys are estimates based on values given by Swann and Nuttingo corrected on the basis Of Brown's estimate that the true 7 values are probably 2.3 times greater than those originally computed. In addition to the above alloys it was decided to investigate short-range ordered (s.R.O.) CU(AU) alloys containing up to 25 at. pct Au. This last alloy has been shown to have a well-defined planar arrangement of dislocations when deformed,21,22 probably due to cross slip being restricted by the S.R.O. Engineering fatigue data was to be represented by the determination of endurance strengths, and these were to be correlated with fatigue hardening and mechanical property data. EXPERIMENTAL I, order to study the desired properties and property changes, the following alloys were prepared: Cu(2.5 at. pct Si), Cu(5.0 at. pct Si), Cu(7.5 at. pct Si), Cu(5.0 at. pct Ni), Cu(25.0 at. pct Nil, Cu(50.0 at. pct Ni), Cu(5.0 at. pct AU), Cu(15.0 at. pct AU), Cu(25.0 at. pct AU). The copper and gold were zone-refined, while the silicon was semiconductor grade. The nickel was of 99.95 p,t. purity.* All alloys were induction-melted in a *Kindly supplied by the International Nickel co. helium atmosphere, appropriate precautions being taken to avoid segregation in the Cu-Au series. Rod stock was obtained by rolling and swag,ng. A few Bridgman single crystals were grown for fatigue-hardening studies, but most material was machined into polycrystalline fatigue speciments of the design shown in Fig. 1, and into polycrystalline tensile and fatigue-hardening specimens of simple cylindrical design. All specimens except Cu(Au) were annealed; the latter were quenched from above T, to produce short-range order. A few of the quenched alloys were examined for long-range order by step-scanning over

Jan 1, 1969

By A. Gene Collins

The demand for lithium may increase because of its potential use id lithium batteries and in the generation of electrical power by fusion. Therefore, lithium abundance in some United States oil-field brines was surveyed. Oil-field brines from numerous locations were found to contain more than 100 mg/l lithium and several exceeded 500 mg/l. An area of 25,000 km2, with a reservoir thickness of 60 m, an effective porosity of 5 percent, and a brine with a specific gravity of 1.2 containing 100 mg/l of lithium, contains about 0.75 x 106 tonnes (1 tonne = 1 metric ton = 1,000 kg) of lithium in 7.5 km3 of brine. It is postulated that the brines were enriched in lithium by lithium-rich spring water or lithium leached from volcanic rocks followed by evaporation sequences.

Jan 1, 1978

By Orr D. B

This is a case history of prospec- ting carried out by Comstaff Pty. Ltd. over the Pinnacles Area, part 4 of Exploration Licence 5/63, 9 km north of Rosebery in Western Tasmania. Evidence is presented to show that A 0 soil samp ling is a viable prospecting method for outlining polymetallic sulphide occur- rences in areas where leached organic/ glacial soils are common. Diamond drilling of low threshold anomalies has intersected base metal mineralisation.

Jan 1, 1977

By J. D. Mooney, D. L. Darnell

The accompanying chart has been drawn for the convenicncc of engineers as' a means of quickly determining the correct number of plies of conveyor belts operating under specific conditions. The calculations are based on the average safe strength (factor of safety, 15) of the various standard rubber conveyor belts. The calculations assume maximum loading conditions; that is, the belt is considered as carrying the greatest load that it will handle without spillage at ordinary belt speeds. This not only produces the most economical operating conditions, but also the maximum tension in the belt. The chart is a graphical representation of the formula: Where, p = kg W(L + 10H) p = the correct number of plies k = a constant, depending on the type of drive g = the weight 'in pounds per cubic foot of material handled W = the width of the belt in inches L = the length of the belt in feet (approximately twice the center distance). H = the difference in elevation between the head and tail pulleys, in feet. For a simple drive, with a bare pulley, k = ----1 For a simple drive, with a rubber-lagged pulley, k = --- 1 For a, tandem drivej with bare pulleys, k = 1/375.000 For a tandem drive, with rubber-lagged pulleys, k = ---1 The chart is drawn for a simple drive, with a bare pulley (k — =e)1 ; therefore, the number of plies obtained from the chart should be multi- ' plied by the factor 0.83 or 5/6 for simple, lagged drive; the factor 0.67 or 2/3 for tandem, bare; and the factor 0.55 or 11/20, for tandem, lagged. The formula p = kgW(L + 10H) has been developed mathematically

Jan 1, 1916

By L. Shevenell, L. Stillings

The Acid Drainage Technology Initiative-Metal Mining Sector (ADTI-MMS) has established a Pit Lake Committee to enhance the science and understanding for the long-term management of pit lakes. Participation in this new committee is from members of federal and state agencies, industry, and academia, including numerous individuals representing 10 states. Work has begun on a pit lake literature search and review, database, classification, and sampling and monitoring procedures document. Coordination with the International Network for Acid Prevention (INAP) has been established. Future work will include preparing a prediction and assumption verification document, a report identifying variables upon which water quality is dependent, and an applied remediation technologies document, including an evaluation of the effects of backfilling.

Jan 1, 2002

By AIME AIME

PRESIDENT BASSETT'S gavel called the Annual Business Meeting to order shortly after 10 a. m. on Tuesday. On motion of Eugene McAuliffe, reading of the minutes was dispensed with and Mr. Bassett read his annual report of the year's activities as follows : During the year I have visited eighteen of the twenty- seven sections, making an average of GG 2/3 per cent. The invitation to come again has always been extended, but in only one case have I been able to visit the same section twice. Chicago entertained the president twice during 1930. Mrs. Bassett accompanied me on visits to ten sections. Everywhere we have found the most cordial hospitality and a gratifying enthusiasm for the Institute. If anyone had fault to find with the management or felt dissatisfied with what was being done, it was carefully concealed. I am happy to report to you an agreeable, helpful and progressive spirit in each of the sections visited.

Jan 1, 1931

By Guo Xueyi

The method of Substance Flow Analysis (abbreviated as SFA) provides a helpful tool for the study of the industrial metabolism of a certain metal within a regional level. In this work the flow of lead in China, 2006, was traced within the STAF model, and the situation of production, consumption and recycling of lead resources in China were introduced. The SFA is performed on lead flows during its one year life cycle in detail. As one of the biggest producer and consumer of lead in the world, China is facing a problem depletion of lead resources. How to increase the resource efficiency is a significant issue for lead industry of China. Based on the result, several suggestions were proposed in the paper, aiming to contribute important reference information for the industrial metabolism and resource management and recycling of lead industry in China.

Jan 1, 2009

Many stress measuring instruments use overcoring stress-relief principles but adopt different sensing techniques. Every technique is subject to certain limitations of rock types and conditions. To investigate the performance and reliability of the instruments in field measurement, a simple and practical approach has been developed to allow comparable laboratory results to be obtained which simulate in-situ rock and stress conditions. Four commonly used devices, the USBM deformation gauge, the CSIRO HI cell,the CSIR triaxial cell and the UNSW SI cell were thoroughly tested in the laboratory. Some conclusions have been drawn as to their suitability and reliability in different field conditions. Recommendations are provided for the choice of an appropriate technique for a given rock type and condition. A new thin-wall cell that overcomes the disadvantages of earlier devices has been developed and tested. Its laboratory performance shows that it has good prospects.

Jan 1, 1990

[This Report represents the culmination of work perfomed under Contract No. .,JG1551A8 for the U.S. Bureau of Mine.The &apos;.:o-< embeded a site evaluation, engineering E:-y- ,, esign, and preparation of specifications for construction of a Transport Research 7 :4 (HTRF)The HTRF is designed as a research facility J evaluate the hydraulic transport of large lump coal at a prototype ;e scale. The HTRF is to be constructed and operated by the Pittsburgh and Safety Research Center of ;. re U.-AN a*, their Bruceton, Pennsylvania test center. In terms of technical capability, the HTRF will have transport pipeline:: of -, twelve-, and eighteen-inch diameter _&apos; with supporting coal handling n , water forage a.^ &apos;d conveyance, mixing, pumping, and dewatering equipment, plus instrumentation and controls. Maximum design velocity 13 20 ft/sec.; solids concentration, by, volume, will; 1 be a maximum-- of sixty, percent. Each test loop is designed to accommodate solids of up to one-third the diameter e - of the pine. The Final Report Pr.-&apos;I-rents information of t HTHF,. including the site evaluation, design criteria, a description of the a description of the procedure to be used for operation of the facility, an estimate of the cost to construct the f^Cilit:r, 1 p el_~lli.&apos;iU construe`, icn Schedule, and a construction suicJ_iicaT.l_ccn&apos;. T e c011SLr?Jc&apos;.ion soecl_ i.on _ccnta_i:s technic.&apos;..i re7,uir: (-n`,s for !&apos;urr1S~ &apos;~latcr..al. and ec-uipr,ent for :":C1 C_`:_C ti on of ti,_ H ice&apos; u:&apos;.:i ._II u s(-.6 for ~.Iir: .3!7 soliciting bids. `.l_o included n cc&apos;;,art_- c?r~.air sV:et..: :s ^nd rr^.?]

Jan 1, 1976

By Alan A. Campoli

The US Bureau of Mines (USBM) conducted research to develop improved guidelines for selecting the type and pattern of roof support in different geologic environments. The goal is to minimize the over and under design of mine roof support, resulting in more productive and safer mines. To obtain the necessary data on roof behavior and support performance, USBM conducted several field studies. Each study covers roof geology, stress regime, ground reaction, support interaction and mining environment. A consistent experimental design is being used. This includes measurements of roof bolt loads and roof movements. So far, 10 studies have been conducted in several geologic settings.

Jan 1, 1996

In 2006, a total of 7,178 sand and gravel mining operations reported employment to the Mine Safety and Health Administration (MSHA).1 ? Sand and gravel mines were the largest mining sector, comprising 48.2% of all mining operations. ? Sand and gravel mines were found throughout all 50 states and Puerto Rico.

Sep 1, 2008

By B. G. Bunting, D. L. Abata, J. Robb, J. H. Johnson

Toxic gases produced by the detonation of six explosives were measured in an underground hardrock metal mine during mining operations. The explosives included two semi-gelatin dynamites, three slurry explosives, and an ammonium nitrate, fuel-oil/ammonia dynamite combination. Explosives were detonated at the face of a drift and toxic gases produced by the detonation were trapped at the end of the drift by a bulkhead located a short distance away from the face. Toxic gas concentrations were then measured with direct readout instruments and together with the containment volume, the toxic gas volumes per mass of explosive were calculated. Toxic gas measurements were found in the following ranges (ft3/1bm): NO, 0.0100-0.035; N02, 0.003-0.019; CO, 0.08-0.30; SO2, 0.00-0.05; and CO2, 0.7-1.8. Results showed that toxic gas production (ft3/lbm) correlated with the densities (kg/m3) and energy densities (kJ/kg) of the explosives tested.

Jan 1, 1983

By V. Kondic, W. M. Rumball

HUNT and Jackson&apos; have recently suggested that binary eutectics might be classified according to the entropy of fusion of the component phases. Such a classification was in fact proposed2 some time ago by the authors and the purpose of this communication is to present some supporting evidence. As pointed out by Hunt and Jackson&apos; typical metals of low entropy of fusion, ?S, tend to form normal eutectics (using Scheil&apos;s terminology3). Where one phase is metallic (low ?S) and the other nonmetallic (high AS) then anomalous structures are formed. These anomalous structures may either be regular (e.g., Bi-Sn)or irregular (e.g., A1-Si). Finally Hunt and Jackson suggest that where both phases are of high ?S regular faceted structures are formed. In the proposed classification2 the ratio of the entropies of fusion is taken as the quantitative parameter, i.e., ?Sa/?SB = E, where e > 1.0. An extensive literature survey has been carried out2,4 for reliable photomicrographs of eutectic structures. The structures, numbering 151, have been classified into two classes, viz., normal (i.e., lamellar and rodlike) and anomalous. The latter group has been arbitrarily subdivided into regular and irregular anomalous eutectics. Details and sources of the structures are given elsewhere.2,4 In the absence of better thermodynamic data the value of E has been determined for each of the systems making the following assumptions and approximations: l) The entropy of fusion of solid solutions may be calculated additively;5 ii) Inter metallic compounds are treated similarly but with the addition of the following term for fully ordered structures.5 -4.573(Ni lOg10 Nl + N2 log10 N2) where Nl and N2 are the atomic fractions. It might be argued that the entropies of fusion are meaningless as the eutectic phases form at some temperature (T,°K) below their true melting point (Ta or Tb). As AS, = Lo/To if La the latent heat of fusion of a, is assumed independent of temperature, the actual entropy change AS& is given by La/Te. The ratio of entropies of fusion then becomes Fig. 1 shows E&apos; plotted against cumulative totals for normal and anomalous systems from which it is seen that normal eutectics predominate at low values of E&apos;; e.g., some 90 pct of normal systems lie below E&apos; = 1.5 with 65 pct of anomalous systems above this value. Fig. 1 also shows that the regular anomalous structures occur mostly at low values of c&apos; possibly suggesting growth more akin to normal than anomalous growth. The choice of c as a classification parameter was based on nucleation concepts, it being observed that metals widely separated in Sundquist and Mondolfo&apos;s8 nucleation series were anomalous and those close together normal. The basis of these classification views is really outside the intended scope of this communication but it is hoped to explain them fully in the near future.7 Having arrived at this entropy of fusion classification by nucleation considerations it is interesting to note that Hunt and Jackson&apos;s ideas are based on growth considerations. Elsewhere one of the authors4 has shown that an even better classification of the metallographic structures reviewed is obtained from purely conventional heterogeneous nucleation concepts. It has been found that systems having a value of the parameter +b less than 0.28 are almost certainly normal and above this anomalous: V, is the gram atomic volume. This parameter is nevertheless closely related to c and c&apos;, these being an approximation of p. The parameter is also related to the other classification3,8,9 which have met with any success in the past. All these classifications are to be reviewed shortly by the authorsU7 A significant thing about the classifications based on

Jan 1, 1968

By F. R. Morral

INDUSTRY has yet to find a universal solution to the problem of engineer personnel selection. Today, the choice of the right man for the right job is even more pressing than ever before. The age of the hard apprenticeship seems to have passed. In its place one finds the interviewer who must determine through personal contact and evaluation of college grades whether a graduate engineer will fit into his company&apos;s scheme. The problem, as it is constituted today, may be broken into four parts: Need for better use of human resources (there is a shortage of engineers, scientists, and skilled workers), productivity with higher efficiency, encouragement of personal pride in work performed, and employee&apos;s happiness on the job and away from it.

Jan 4, 1953

By C. M. Flynn

The Bureau of Mines prepared and investigated xanthated sawdust adsorbents to determine their effectiveness in removing heavy metal ions from dilute aqueous solutions, mine-drainage waters, and brines. Stripping of the metal values from the metal-laden adsorbent was also investigated. The treated sawdusts had an adsorption capacity of 0.3 to 0.4 meg/g dry adsorbent for Mn, Co, Ni, Cu, Ag, Zn, Cd, Hg, or Pb from feed solutions with pH 5 to 6. The feed solutions tested included mine-drainage waters and geothermal brine. Effluent metal concentrations as low as 0.05 to 0.1 mg/l were obtained at effluent pH values of 6 to 9. The order of affinity of metals for the sawdust adsorbent is Na«Ca~Mg~Mn<Zn<Ni<Cd<Pb~Cu. The presence of Ca, Mg, or Na in concentrations as high as 2 g/l does not seriously impair the heavy-metal adsorption. Metals were desorbed from the metal-laden adsorbent by elution with dilute mineral acids, sodium cyanide, or salts of ethylenediaminetetra-acetic acid.

Jan 1, 1979

By W. M. McKewan

Magnetite pellets were reduced in flowing hydrogen at pressures up to 40 atm over a temperature range of 350° to 500°C. The rate of weight loss of oxygen per unit area of the reaction surface was found to be constant with time at each temperature and pressure. The reaction rate was found to be directly proportional to hydrogen pressure up to 1 atm and to approach a maximum rate at high pressures. The results can be explained by considering the reaction surface to be sparsely occupied by adsorbed hydrogen at low pressures and saturated at high pressures. PREVIOUS investigation1,2 have shown that the reduction of iron oxides in hydrogen is controlled at the reaction interface. Under fixed conditions of temperature, hydrogen pressure, and gas composition, the reduction rate is constant with time, per unit surface area of residual oxide, and is directly proportional to the hydrogen pressure up to one atmosphere. The reduction rate of a sphere of iron oxide can be described3 by the following equation which takes into account the changing reaction surface area: where ro and do are the initial radius and density of the sphere; t is time; R is the fractional reduction; and R, is the reduction rate constant with units mass per area per time. The quantityis actually the fractional thickness of the reduced layer in terms of fractional reduction R. It was found in a previous investigation2 of the reduction of magnetite pellets in H2-H,O-N, mixtures, that the reaction rate was directly proportional to the hydrogen partial pressure up to 1 atm at a constant ratio of water vapor to hydrogen. Water vapor poisoned the oxide surface by an oxidizing reaction and markedly slowed the reduction. The enthalpy of activation was found to be + 13,600 cal per mole. It was also found that the magnetite reduced to meta-stable wüstite before proceeding to iron metal. The following equation was derived from absolute reaction-rate theory4,8 to expfain the experimental data: where Ro is the reduction rate in mg cm-2 min-&apos;; KO contains the conversion units; Ph2 and PH2O are the hydrogen and water vapor partial pressures in atmospheres; Ke is the equilibrium constant for the Fe,O,/FeO equilibrium; Kp is the equilibrium constant for the poisoning reaction of water vapor; L is the total number of active sites; k and h are Boltzmann&apos;s and Planck&apos;s constants; and AF is the free energy of activation. Tenenbaum zind Joseph5 studied the reduction of iron ore by hydrogen at pressures over 1 atm. They showed that increasing the hydrogen pressure materially increased the rate of reduction. This is in accordance with the work of Diepschlag,6 who found that the rate of reduction of iron ores by either carbon monoxide or hydrogen was much greater at higher pressures. He used pressures as high as 7 atm. In order to further understand the mechanism of the reduction of iron oxide by hydrogen it was decided to study the effect of increasing the hydrogen pressure on rebduction rates of magnetite pellets. EXPERIMENTAL PROCEDURE The dense magnetite pellets used in these experiments were made in the following manner. Reagent-grade ferric oxide was moistened with water and hand-rolled into spherical pellets. The pellets were heated slowly to 550°C in an atmosphere of 10 pct H2-90 pct CO, and held for 1 hr. They were then heated slowly to 1370°C in an atmosphere of 2 pct H2-98 pct CO, then cooled slowly in the same atmosphere. The sintered pellets were crystalline magnetite with an apparent density of about 4.9 gm per cm3. They were about 0.9 cm in diam. The porosity of the pellets, which was discontinuous in nature, was akrout 6 pct. The pellets were suspended from a quartz spring balance in a vertical tube furnace. The equipment is shown in Fig. 1. Essentially the furnace consists of a 12-in. OD stainless steel outer shell and a 3-in. ID inconel inner shell. The kanthal wound 22 in. long, 1 1/2, in. ID alumina reaction tube is inside the inconel inner shell. Prepurified hydrogen sweeps the reaction tube to remove the water vapor formed during the reaction. The hydrogen is static in the rest of the furnace. The sample is placed at the bottom of the furnace in a nickel wire mesh basket suspended by nickel wire from the quartz spring. The furnace is then sealed, evacuated, and refilled with argon several times to remove all traces of oxygen. It is then evacuated, filled with

Jan 1, 1962

By M. Pakala, Z. Fan, Ray Y. Lin

Deposition of hard chromium coatings using electrodeposition is accompanied by emission of hexavalent chromium mists which is a carcinogenic. Hence alternative chromium deposition technologies are being investigated. Sputter deposition is a strong candidate to economically deposit hard chromium coatings in an environmentally friendly way. Chromium coatings of 2-3 µ m thickness were deposited on plain carbon steel coupons using RF magnetron sputter deposition. Depositions were carried out with 0 to 22 vol% nitrogen in the plasma. Structure of the coatings was studied using x-ray diffraction analysis With increasing nitrogen contents, formation of the two nitride phases was observed. The pure chromium phase was detected in coatings with up to 7% nitrogen in the sputtering gas. The solid solution of nitrogen in the pure Cr phase coating was identified by shifts of Cr x-ray diffraction peaks to higher d-spacing. The microhardness of the coatings deposited at a substrate temperature of 200°C showed an increase in hardness with increasing nitrogen content from 600 kgf/mm2 (5.9 GPa) at 0% nitrogen to I250 kgf/mm2 (I2.25 GPa) at 9.5 % nitrogen and a subsequent decrease in hardness to I 100 kgf/mm2 (11 GPa) beyond 9.5 % nitrogen in the sputtering gas. This corresponds to the formation of the hard Cr2N phase, at 9.5 % nitrogen, and CrN phase, at I5.7 % nitrogen. The reported bulk hardness values of Cr2N and CrN are I600 kgf/mm2 (I5.7 GPa) and I 100 kgf/mm2 (11 GPa) respectively. For pure Cr phase coatings, there is a slight increase in hardness for coatings deposited at 7. I % nitrogen from that without nitrogen in the sputtering gas. This could possibly result from the solid solution strengthening of the Cr lattice by nitrogen. For films deposited at 200°C, phases of the deposited films seem to be the overwhelming factor in controlling the microhardness.

Jan 1, 1998