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By B M. Washington, R R. Lovel, G J. Sparrow, M J. Fisher-White

"Work in CSIRO with several Australian ores has shown that?by heating a high-phosphorus goethitic iron ore and then leaching with caustic or acid, the phosphorus levels in the ore can be lowered to a commercially acceptable value of around 0.08 weight per cent phosphorus (P). With increasing heating temperatures up to 1300¦C, the extent of phosphorus removal increased. This is considered to be associated with mineralogical changes in the iron oxide phases in the ore during the heating.Little phosphorus was removed from four high-phosphorus goethitic iron ores containing 0.12 - 0.16 weight per cent P in leaches with boiling water. However, leaches with sulfuric acid removed ten to 20 weight per cent of the phosphorus and leaching with sodium hydroxide removed even more phosphorus to produce leach products containing between 0.08 and 0.12 weight per cent P from three of the ores.After heating at 300¦C, leaches at a low pulp density of 0.5 weight per cent solids with 1 - 5 M NaOH and 0.1 - 1 M H2SO4 gave leach products with 0.06 - 0.09 weight per cent P. The lixiviant concentration required and extent of phosphorus removal depended on the ore. At a higher pulp density of 25 weight per cent solids, leach residues with between 0.07 - 0.14 weight per cent P were obtained.More phosphorus was removed from ores heated at 900¦C. Leaches at both the low and high pulp densities, with 1 - 5 M NaOH and 0.1 - 1 M H2SO4, gave leach products with 0.05 - 0.09 weight per cent P. However, the lowest phosphorus levels were obtained after heating the ores at 1200 or 1300¦C and leaching with 1 M NaOH or 0.1 M H2SO4. Leach residues with 0.02 - 0.06 weight per cent P were obtained, even from leaches at the higher pulp density of 25 weight per cent solids. Leaching tests on heated samples under heap leaching conditions at ambient temperatures have shown that phosphorus levels can be reduced to similar levels to that achieved in an agitation leach within ten days.CITATION:Fisher-White, M J, Lovel, R R, Sparrow, G J and Washington, B M, 2013. Effect of temperature on removal of phosphorus from Australian Goethitic iron ores, in Proceedings Iron Ore 2013, pp 373-380 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 12, 2013

By C J. Hogan

Increasing demand for fine grinding to improve mineral liberation and metal recovery and the need for stricter control of the environmental impact of tailings deposition poses problems for tailings disposal. This has led to an increasing number of investigations of properties of tailings and their disposal. This paper describes laboratory model testing undertaken on Macraes mine flotation tailings to provide information on tailings behaviour under conditions of subaerial deposition. The in-place density or 'dry density' of the impounded tailings and the impoundment depth relationship are important for utilisation of the available impoundment storage facility and results of dry density to depth relationships are given for the Macraes mine tailings impoundment.

Jan 1, 1993

By Wesley T. Holmes

This report describes the second phase of an investigation aimed at obtaining a wider knowledge of the problems involved in smelting titaniferous magnetites. Liquidus temperature measurements were made on selected synthetic slag compositions in the Ti02 -A1203 -FeO-Si02 -CaO-MgO system. Both the hot-stage microscope and the strip furnace (melting-holding-quenching technique) were used during test procedure to determine the effects of CaO, MgO, and SiO2 on the liquidus temperature of slags. The liquidus temperatures of slags studied ranged from 1,241° to 1,900° C. The lowest liquidus temperature for each Ti02 plus A1203 plus FeO weight-percent generally occurred when the difference between CaO plus MgO and Si02 was less than 12 weight-percent. In this investigation substitution of either CaO or MgO for SiO2 and MgO for CaO raised the liquidus temperature of more than 50 percent of the reported base slags when Ti02, A1203, and FeO contents were held constant. The results of this investigation may serve as guidelines for determining flux requirements in smelting a wide variety of titaniferous magnetite concentrates or ores.

Jan 1, 1968

By Shengfan Zhou, XUEWEN WANG, Bianfang Chen, Mingyu Wang

Vanadium was leached from roasted stone coal by NaOH solution, and the effect of leaching temperature, leaching time, addition of NaOH, liquid to solid ratio, the grinding fineness of stone coal, and stirring speed on the vanadium leaching rate was studied. The kinetics analysis for the process is presented by the shrinking core model. The results show that the vanadium leaching ratio of roasted stone coal can be beyond 75% at the 6% NaOH addition, leaching temperature of 95°C, leaching time of 7h, liquid to solid ratio of 1.2mL/g, and grinding fineness of 0.111mm. The leaching process is controlled by interfacial reaction kinetics and the apparent activation energy was 59.36kJ/mol.

Jan 1, 2016

By David S. Bowling

The ER-300 Series White Recorders were developed to provide on economical, yet invaluable instrument for those who desire permanent recordings of such data OS displacement, vibration, concussion (air borne effect) and velocity information. The precise monitoring of earth displacements and air blast magnitudes aids quarrymen and construction contractors in estimating safe blasting limits when operating in populated areas. A refraction model is available for recording velocities which permit the determination of weathered zone depths as well as the .depths to other subsurface formations. The dual purpose (Refroction- Displacement) systems ore utilized for velocity studies and displacement - oir blast measurements.

Jan 1, 1990

By W. H. MacLean, S. Liaghat

The Key Tuffite is a thick (0.3 m to 6 m) and laterally extensive (-10 km) cherty, sulfide-bearing tuff unit in Archean greenstones in the Matagami mining district in northwestern Quebec. It lies at the contact of the Watson Lake Group and overlying Wabassee Group volcanic rocks, and is host to major Zn-Cu volcanogenic massive sulfide deposits. The tuff component is highly altered and its volcanic precursors are not identifiable by petrographic means. The tuff is mixed with a volcanic exhalative component comprising chert, carbonate and sulfides (pyrite, pyrrhotite, and minor sphalerite and chalcopyrite). The normative mineral composition of the Key Tuffite is 33% quartz, 28% sulfides, 16% sericite, 8070 carbonate, 6% chlorite and 9% other minerals. In the vicinity of the Bell Allard and Orchan mines, the precursor tuff components are identified using immobile major and trace elements, as Watson Lake tholeiitic rhyolite (Zr/Y = 1.5 to 3.5, LaN/ybN = 1.7 to 2.8, SiO2 = 72.5 ± 1.2 wt %, and Wabassee calc-alkaline andesite (Zr/Y = 9, LaN/YbN= 4 to 8, SiO2 = 56% to 65%). Immobile element computation techniques were used to calculate mass additions and losses in the conversion of the tuff to the Key Tuffite. Average net amounts of FeP3 (27% total iron), Si02 (14%), Cao (8%), S and K2 (+ 2%), were added, Nap was removed (-2.8%), and MgO was over-all unchanged. Total net mass change was +63%, which comprises mainly exhalative additions, but also includes changes owing to hydrothermal alteration of the tuff component.

Jan 1, 1992

By N. C. Matheson

The West's Shell Pile has been used on sites with very soft ground conditions for over 60 years. Fibre reinforced precast concrete shells 900mm long are threadled onto an internal mandrel which can be extended according to the depth driven to attain the load bearing resistance. On completion of driving the mandrel is removed leaving the precast shells to form a permanent lining to the cast insitu concrete core. To give resistance to high contamination, a tar based epoxy coat is sprayed on the outside of the shells or a flexible PVC liner is installed inside the shells to protect the core. Fundamental to the resistance to contamination is the quality of the precast fibre reinforced concrete shell, the mix design and method of manufacture. A series of detailed laboratory experiments were carried out using samples immersed in concentrated acid and sulphate solution. The long term effects of exposure to contamination is recorded in the case studies of existing piles at two gasworks sites.

Jan 1, 1989

By Max Roesler

I. INTRODUCTION THE following article concerns the geological occurrence of the iron-ore deposits on the south coast of Cuba. The article is based on a detailed field study, made in the hope that some information would I gained which might be of value in the search for further orebodies, Or in the economic development of the ore already found. LOCATION The iron-ore deposits of the Firmeza district lie near the coast, in the southeastern part of Cuba, in the Province of Oriente. The orebodies of this district form part of a belt of deposits that extends from Sigua, 25 miles east of Santiago, to Sevilla, 5 miles east of Santiago, and lies on the seaward slope of the Sierra Maestra range of mountains.

Jan 10, 1916

By Dhar B. B, Gupta R. C

Grinding of iron ore is an essential step to utilise ore fines for pelletisation needed for DRI units. While preparing iron ore pellets for DRI production, the iron ore needs extensive grinding which is highly energy consuming step causing the process to become non-viable in some cases. In the present paper an attempt has been made to evaluate grinding performance of thermally treated ore compared to normal ore grinding. Such thermal pre-treatment has been found to reduce the energy requirement with lower consumption rate of grinding media. It has been observed that by applying thermal shock the ore is rendered weak with improved grindability. The stresses generated due to thermal treatment may extend existing micro-cracks in the ore and in some cases it may even nucleate fresh cracks. Experimental studies carried out on thermally treated hematitite ore reveals that the heating to 400¦C followed by water quenching can cause a reduction of 45 per cent in grinding energy. The paper gives the details of the experiment and the Results.

Jan 1, 1999

By Georgia J. Lysay

The Kemess Mine tailings impoundment is retained behind an earthfill and rockfill dam that, when complete, will measure about 140 m in height with a crest length in excess of 1 km. Due to weak foundation conditions, the dam must be raised at a very flat downstream slope approaching 7H:1V. This requires an enormous volume of fill to construct the downstream shell of the dam, which has a low permeability clayey till core and is raised via the centerline construction method. For the initial years of annual dam raising, from 1996 through 2002, the downstream shell of the dam was constructed with non acid generating waste rock from the open pit, 7 km distant and requiring an uphill haul with obvious cost implications. To reduce costs, and to reduce waste haulage constraints on mining schedules, feasibility studies were initiated for raising of the downstream shell using cycloned tailings sand as opposed to open pit waste. This required inclusion of flotation cells for removal of residual sulphides from the tailings to produce the non acid generating product mandated for the downstream shell of the dam. These studies were positive, and cycloned sand construction was initiated in December of 2002. This paper describes the experience gained with cycloned sand construction for the dam. Unique aspects include environmental controls given the sulphide-bearing ores, preparation of the existing shell of the dam for subsequent placement of hydraulically placed cycloned tailings sand, on-dam settling ponds, water management issues, reclamation of the sand dam for erosion control commensurate with the wet climate, and use of the system to construct an above-water beach of non acid generating tailings to increase the closure security of the structure. A particularly unique aspect of the Kemess experience is hydraulic fill operations extending throughout the coldest winter months, as compared to other operations where such placement has traditionally been considered non-viable through the winter months

May 1, 2007

This paper discusses the history and development of the system and the benefits that are being gained for Yabulu from Solar Drying. Following the end of mining of the local Greenvale and Brolga nickel deposits, QNI Yabulu Refinery is dependent upon imported ore from over 15 different mines in New Caledonia, Indonesia and the Philippines.

Jan 1, 2003

By D. B. Lovett

The work described in this report was directed toward identifying and devising methods to minimize the previously observed variability between working level hour exposures and the alpha particle track densities resulting on Track Etch films exposed to mine atmospheres containing radon and radon daughters. The disequilibrium between radon and its daughters was shown to directly affect this Track Etch film calibration factor. The wide range of disequilibrium states possible in mine situations amply explains the variability in the previous tests. A file of published mine atmosphere composition data was compiled and was used, along with atmospheric compositions derived from several theoretical models ref the atmospheric behavior, to evaluate the variability of several dosimeter configurations and concepts. A nonlinear, iterative regression analyse; was formulated that successfully predicted working levels to within 8 to 10% from only the alpha particle activities (Rn, RA, and RaC') data such as are obtainable from Track Etch films over a wide range of disequrlibrium conditions. A model expressing atmospheric concentrations as a function of radon source strength, plate out rate factor, ventilation rate and the fractional re-entry by recoil of previously platted-out daughters was derived and used in the regression program in addition to preparing a set of reference tables and graphs showing the disequilibrium behavior of the atmosphere. Other factors that can affect the Track Etch Film response writ considered and shown to he less crutial than the disequilibrium state. The results of a series of exposures of a dosimeter concept fixture in the Denver Mining Research Center radon chamber air presented and discussed.

Jan 1, 1976

By John A. Johnson

For the purpose of comparing the amounts of dust produced by various mining operations, samples of atmospheric dust were collected during a complete cycle of drilling, blasting and mucking at or near the face of the Bureau's Mount Weather testing adit while the efficiency of several types of stemming in metal-mine blasting was being investigated. ACKNOWLEDGMENTS All gas samples were analyzed in the laboratory of the Bureau of Mines Gas Section at Pittsburgh, Pa.

Jan 1, 1939

By Damon P. Vandermaat

Coupon testing allows for the rapid understanding of a material?s likely behavior in service conditions, allowing engineers and operators to make informed decisions about the likely service-life of parts when subjected to field conditions. Bend testing has been identified as the best approach for exploring rock bolt susceptibility to stress corrosion cracking (SCC) in underground mining. The bend test specimens used were 2?3 mm thick slivers of steel, cut from the outer edge of a rock bolt. For the specimens, 1350 grade steel was chosen due to its wide use in the industry. The jigs themselves are small assemblies made of stainless steel that are capable of imparting a bending load on the specimens. The jigs were installed at a coal mine located in the Western Coals West of Sydney, Australia, in such a way as to expose the test specimen to water dripping from the mine roof. It is expected that this approach will yield results pointing to the likely SCC mechanisms affecting the service life of rock bolts, as well as demonstrate the jigs? usefulness as an early warning system for SCC. Furthermore, the coupon tests will be correlated against the results of large-scale laboratory tests.

Jan 1, 2012

Conservation and environmental issues are raising their profile with respect to both demand restraint and electricity supply options. In New Zealand, conservation pressures and energy efficiency need to be seen in relation to the supply system currently in place which has capacity for economic supply of electricity in quantities substantially in excess of the current market. Consequently, energy efficiency and conservation need to be interpreted in relation to the supply system as well as in relation to end use. The relationship between the environment and conservation is strongest when new generation is required. New Zealand's electricity supply system consists of a large proportion of hydro production and this has significant environmental benefits when considered in relation to concerns of global wanning and the greenhouse effect. However, environmental trade-offs in supply options need to take account of both the efficiency of electricity end use, the trade-off between hydro and thermal generation and the inter-regional effects of shifting development options from one region to another. The Electricity Corporation has a high level of consciousness with respect to environmental and conservation issues and this paper demonstrates its own moves to maximise energy efficiency and illustrate the environmental trade-offs for supply.

Jan 1, 1990

Tunnel damage from explosion and earthquake excitation is correlated with strain and particle motions. Critical strains and motions are then correlated with focal distance, which is so small that permanent strains are highly likely. The shaking process is then numerically modeled to investigate the effects of excitation frequency and joint orientation. The models confirm that near cavern blocks slide intermittently only at relatively high particle velocities during periods of low joint normal stress. Larger displacements occur with relatively small shear wave lengths or relatively high frequencies. Variation in joint orientation and rock mass dilation result in changes in displacement.

Jan 1, 1985

By Kyoosang Yoo

The report presents the results corresponding to the analysis of a lining system for tunnels in soil and soft rock in creep-active ground. The purpose of the analysis is to evaluate the performance of a lining at each construction stage. The steps include: 1. Accurate representation of the initial undisturbed state of stress 2. Excavation, 3. Lining installation 4. Injection of mortar and its curing, and 5. Short-, medium- and long-term creep behaviour in the surrounding soil/rock. The response of a prototype tunnel is simulated using the computational finite element framework MSC.marc2008.

Jan 1, 2010

By J. B. Seymour

This paper provides an overview of the current use of backfill for ground support in underground metal mines in the United States and a summary of recent accident data reported for these mines by the Mine Safety and Health Administration (MSHA). Backfill mines comprise a major part of the underground metal mining industry and are particularly important in terms of the fatalities and injuries impacting this workforce. Ground falls are the leading cause of fatal accidents at these mines accounting for 50 percent of the total fatalities (4 out of the 8 fatalities that occurred from 2006 through second quarter of 2011). MSHA reported several different types of accidents involving backfill at these mines. While backfill ground falls do not occur frequently, these accidents result in a much higher proportion of fatalities than host rock ground falls. Backfill ground fall accidents are especially hazardous in underhand cut-and-fill mining operations where employees work directly beneath the backfill. An analysis of recent MSHA accident data supports the need for further cooperative research with the mining industry to identify and address ground control problems in underground metal mines using backfill.

Feb 27, 2013

By David Siu

Many problems were encountered with the mechanical wedge-type splices used for the 15-inch square precast prestressed concrete piles installed at an industrial plant site. Many of the wedges were breaking during installation of the splices and after pile driving resumed following splicing. Dynamic monitoring of the piles and uplift loading tests confirmed that the problems were associated with cracked or damaged wedges. More ductile, annealed wedges were subsequently used, and, while not completely satisfactory, they were found to perform better than the original more brittle wedges. Introduction Long precast prestressed concrete piles were installed to support heavy, settlement-sensitive structures at an industrial plant in Port Alberni, British Columbia, Canada. The piles were driven through soft compressible silts and clays to toe bearing in a dense sand and gravel deposit or on bedrock. Each pile consisted of two or three segments joined with mechanical wedge-type splices trademarked DYN-A-SPLICE. Shortly after construction began, problems arose during pile installation, and these problems were, later, identified to be related to the wedges, or clamps, used to connect the splice plates.

Jan 1, 1991

By V. Bondarenko

The forecasting of floating earth inrush into the working is to a great extent connected with the investigation of the rock mass stressed-deformed state around the working. The aim of such investigations is to estimate the carrier ability of the protective layer (which is stabilized by the physico-chemical mode of fixing) and to determine it's thickness, which is to be sufficient to present the floating earth inrush into the working. We consider the protective layer to have exhausted it's carrier ability if the rocks of this layer reached the overlimit phase of deformation and it's greater part (section), which adjoins the working. is destroyed up to the limit of the remaining strength. So, the aim of investigations is to determine the size of the rocks inelastic deformation zone in the roof of the working. It is necessary to take into account the presence of water saturated seam in the roof and the overlimit characteristics of the rocks, their ability to lower the carrier capacity up to the level of the remaining strength.

Jan 1, 1996