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By Claus Becker

At the RETC 1979 in Atlanta/Georgia it was reported about the beginnings of the Hydroshield system and the first site experiences. Since that time over 10 miles of tunnels in various diameters have been built with that system, and the discussion of the two most interesting projects will be the main topics of this paper. AURELIA TUNNEL, ROME In Rome, the railway system is going to be completed and modernized. Therefore, it is necessary to tunnel through the Roman hills. Part of the new railway system is the Aurelia Tunnel, located some 100 feet below the famous Via Aurelia Antigua, close to the Vatican. The double track railway tunnel has an internal diameter of 9.44 m and a length of 2.410 m. It runs through completely differing soil conditions. (Fig. 1) The first 1000 t are situated in watertight clay, the rear part in water bearing loamy, clayey sands with interlayers of loamy clays. The figure shows the soft change-over from clay to sand. The groundwater head is between [ ]

Jan 1, 1983

By Louis C. Brichta

This report summarizes the progress made by the Federal Bureau of Mines in assembling and compiling a catalog of available logs of drill holes and maps of mine developments in the Tri-State Zinc-Lead District in northeastern Oklahoma, southeastern Kansas, and southwestern Missouri. It supplements an interim report (11)3/ published in 1955, and for convenience of the reader repeats much of the general descriptive matter pertinent to the district contained in that report. The work of procuring and recording the data was begun in August 1949 and was recessed in May 1959. The catalog preserves the records of accomplished explorations and mine developments in the district and provides a readily available source of information for individuals and firms interested in planning mineral explorations, Government agencies estimating of reserves of mineral resources, and the mining industry for general use.

Jan 1, 1960

By E. Asselin

Passivation of Fe-Ni-Co alloys during the Caron leach process is thought to result in low cobalt recoveries in ammoniacal ammonium carbonate solutions. A brief review of the available thermochemical data for the (Fe, Ni, Co)-NH3-H2O systems has been undertaken. The stability of the Co(II) and Co(III), Ni(II) and Fe(II) ammines was examined through the use of speciation and Pourbaix diagrams at 298 and 333 K and at 6 M total ammonia. Increasing the temperature reduces the stability fields of the ammines and generally constrains the thermodynamic window for the leach. The Fe(II) ammines are only thermodynamically stable under reducing conditions. Polarization experiments show that these ammines are unlikely to form if oxygen is present. Fe-Ni-Co alloy passivation may be alleviated by careful management of potential.

Nov 1, 2011

By E. Asselin

Passivation of Fe-Ni-Co alloys during the Caron leach process is thought to result in low cobalt recoveries in ammoniacal ammonium carbonate solutions. A brief review of the available thermochemical data for the (Fe, Ni, Co)-NH3-H2O systems has been undertaken. The stability of the Co(II) and Co(III), Ni(II) and Fe(II) am-mines was examined through the use of speciation and Pourbaix diagrams at 298 and 333 K and at 6 M total ammonia. Increasing the temperature reduces the stability fields of the ammines and generally constrains the thermodynamic window for the leach. The Fe(II) ammines are only thermodynamically stable under reducing conditions. Polarization experiments show that these ammines are unlikely to form if oxygen is present. Fe-Ni-Co alloy passivation may be alleviated by careful management of potential.

Jan 1, 2011

By Paul Ransom

Sullivan Production and Present Value ? Mined 150 million tonnes ? 6.0% Pb, 5.5% Zn, 2 opt Ag, + Sn, Cd, In ? May 2006 Value + US$43 Billion ? 50% of metal from first 37% (55MT) of tons ? True original size ~ 110-120 Mt @ 17%Pb+Zn ? 30MT unconsolidated fill + HW cave

May 1, 2006

By Damien Wagner

To reduce the emission of greenhouse gases by the steel industry, particularly for ironmaking, the production of DRI (Direct Reduced Iron) using hydrogen as the reducing gas instead of carbon monoxide is being considered. In this context, the reduction of pure hematite by hydrogen was studied at the laboratory scale, varying the experimental conditions and observing the rate and the course of the reaction. All the reduction experiments were performed in a thermobalance and supplementary characterization methods were used like scanning and transmission electron microscopy, X-ray diffraction, and Mössbauer spectrometry. The influence of rising temperature in the range 550-900°C is to accelerate the reaction; no slowing down was observed, contrary to some literature conclusions. A series of experiments consisted in interrupting the runs before complete conversion, thus enabling the characterization of partially reduced samples. Interpretation confirms the occurrence of three successive and rather separate reduction steps, through magnetite and wustite to iron, and illustrates a clear structural evolution of the samples. Finally, the influence of the sample type was revealed comparing a regular powder, a nanopowder and a sintered sample. The regular powder proved to be the most reactive despite its larger grain size, due to a more porous final structure.

Jan 1, 2006

By A. B. Barlow, D. H. Pitcher

"The Geophysics/Geochemistry Section of the Ontario Geological Survey initiated an aerial geophysical survey in the James Bay Lowlands, Cretaceous Basin area, District of Cochrane, Ontario. The survey was contracted to Scintrex Limited and was carried out in 1978. Approximately 8000 line kilometres of airborne electromagnetic and magnetic data were recorded. The Tridem airborne electromagnetic system was employed, mounted in a twin-engined PB Y Canso aircraft. This specific Tridem system uses a vertical coaxial coil configuration and measures in-phase and quadrature components of the secondary field at 500, 2000 and 8000 Hz.The primary purpose of this survey was to map subsurface conductivities and, in particular, to search for lignite deposits. Physical property measurements show that electrical methods should detect differen ces in conductivity between the moderately conducting clay-lignite horizons and the less conducting clay, soil, muskeg and gravel horizons. A preliminary Tridem test survey, as well as surface DC resistivity soundings, confirmed this approach. The interpretation of the present survey data indicates that Tridem is a suitable electrical method to aid lignite exploration in the James Bay Lowlands."

Jan 1, 1980

By D. Moffat

Rio Algom Limited has mined uranium at Elliot Lake, Ontario for 20 years. The production of this energy-generating element results in the need to dispose of low-level radioactive solid wastes and liquid effluents. Because of the wet-temperate climate at Elliot Lake, the liquid effluents are of particular importance. Radium-226 is the isotope which requires most attention, and the current practice for its control is by addition of barium chloride and retention of the resultant precipitates in large settling ponds. Analyses of typical effluents and waste streams are discussed and typical levels of radium-226, thorium-230, thorium-232, thorium-228, lead-2iO, polonium-2iO, and uranium isotopes are presented.

Jan 1, 1979

By Nicholas Chlumecky

One of the most dangerous jobs in mining is that of resupporting the roof after a fall has occurred. The resulting cavity may be more than 30 feet high, with relatively unstable sides and roof. It is often impossible to proceed with rehabilitation without exposing men and equipment to unsupported rock. Temporary supports provide margin- ally effective protection because of the lack of available footing. Furthermore, the usual supports in rehabilitated fall locations are not permanent, require frequent maintenance, and fail to eliminate some remaining serious safety hazards. This is typically the case for high cavities where loose rock drops from considerable heights from between roof bolts. Supports made of cribbing, beams and additional cribbing to the high points of the fall in many cases do not provide good protection due to the deterioration and shrinkage of timber. In mines, high cribbing frequently loses contact with the roof and thus provides no protection against rocks peeling off the sides. This is true in spite of the fact that at time of installation the cribbing was wedged tightly to the roof. Therefore, when considering the difficulties which occur with current practices, the objective is to find alternate methods of resupporting the high roof after a fall.

Jan 1, 1981

By J. M. Singer

Thermal, mechanical, and physical properties of virgin and heat-treated Pittsburgh seam coal were determined as part of a comprehensive study of combustion of monolithic coal block. The information was sought to help characterize pyrolysis and combustion processes in underground coal mine fires but should also prove useful in the study of in situ and surface coal gasifiers. Measured properties include thermal conductivity, specific heat, thermal expansion, density, compressive and tensile strength, porosity, and permeability. The transport property data were obtained (when feasible) in two mutually perpendicular directions of the anisotropic virgin coal material, and coal samples carbonized for 5 hours at temperatures of 350° C, 475° C, 500° C, 650° C, and 850° C. Other coals (Pocahontas No. 3, Sewell, and Illinois No. 6 seams) were investigated for porosity and relative permeability. Interdependence among all properties was evident from the results; however, only a few correlations could be developed owing to inhomogeneity of coal material and specimen variation, which had the effect of reducing the accuracy of measurement and increasing data scatter.

Jan 1, 1979

By Oscar Pastor Paredes

Dado que la presión de aire comprimido en los frentes de trabajo (PACFT) es deficiente, se ha visto por conveniente evaluar qué tipo de PACFT es el más adecuado para el rendimiento de máquinas neumáticas. En este sentido, el presente trabajo describe el método de cálculo como el medio idóneo para solucionar las deficiencias detectadas en la compañía minera Condestable S.A y así visualizar el procedimiento a través de un microcomputador Casio PB 700 de lenguaje Basic.

Nov 24, 1986

By K. B. Chaudhuri, I. D. Webb, F. E. Rachor, F. A. Sauert

"A characteristic of all methods of copper concentrate smelting is that slags with a high copper content are produced at some phase of the operation. Recirculation to the smelting unit, electric furnace reduction or flotation are at present used on an industrial scale to recover the copper from these slags. This paper describes the application of the top-blowing technique, originally developed by KHD Humboldt- Wedag AG for refining of metallic copper, for the treatment of copper-containing slags. By this method, a mixture of a reducing gas and commercial oxygen is blown onto the melt at velocities which can be supersonic from the tip of a water cooled lance. The impingement of the reaction gas mixture on the surface of the slag forms a depression in the molten phase and a deflection of the jet which brings the slag into a rotating motion. This causes high rates of heat and mass transfer. Results of pilot-plant tests for batch and continuous treatment of slags are presented, and the potential applications of top blowing for industrial-scale operation are indicated. In combination with the cyclone as a smelting unit, this process appears to be economic for smelters of very low capacity."

Jan 1, 1980

By S. W. Miller

DURING the examination of welds made in steel by the oxy-acetylene and electric-arc processes, the writer has met with some unusual structures, which he has not encountered elsewhere. They seem to be quite closely associated with the welding methods used, and characteristic of them, and would seem to be worth noting, especially as the references to them in the literature are few, and their explanation not clear or complete. An introductory word or two about fusion welding may not he out of place. The oxy-acetylene process is based on the great and very local heat generated by the burning of acetylene in the presence of commercially pure oxygen, the two gases being thoroughly mixed before combustion. The theoretical temperature is somewhat under 4000° C., but on account of various losses, the actual maximum temperature is probably about 3000° C. 1 The electric-arc process, using a metal electrode, which is also the filling rod, generates a still higher and more local temperature. The actual temperature of the positive crater of the carbon arc is given as 3500° C.2 No figures have been found for the temperature of the arc using a metal electrode, but it would probably not be very different from that of the carbon arc, and probably higher than that of the oxy-acetylene flame. The greater localization of the electric arc is due to the fact that it is not surrounded by a large envelope flame as well as to its higher temperature; while the oxy-acetylene white cone, or welding flame, in which the carbon of the acetylene is burned to CO, is surrounded and preceded by -a long envelope flame, itself of quite high temperature, in which the CO is burned to C02, and the hydrogen of the acetylene to

Jan 2, 1918

By Allen D. Look, J. Howard Bird

"INTRODUCTION The Phelps-Dodge Corp. New Cornelia Branch open-pit copper mine operated without a fatality in the drilling and blasting department from December 13, 1937, to April 1, 1947, and continuing.Between the dates named the explosives crews had a total of 746,520 man-hours of exposure and handled 12,000 tons of explosives, over 770,000 detonators, 2,300,000 feet of fuse, and 7,700,000 feet of Primacord in loading holes to break 116,780,000 tons of material.It is the purpose of this paper to record the procautions taken to insure safe handling of explosives at this operation where safety is definitely a matter of forethought rather than chance.GENERAL INFORMATIONThe New Cornelia Branch open-pit mine operates on a large, low-grade, disseminated-copper deposit about one-half mile south of Ajo, Ariz. The pit is approximately oval; the ore body being some 4,800 feet long and 2,750 feet wide. Ore is mined with electric shovels loading into railroad cars. All benches in- the pit are 40 feet in height except two, which are 60 feet high.The New Cornelia ore body differs from most porphyry-copper deposits in being hard and siliceous. In common with the other low-grade porphyry-copper deposits, continued operation is possible only with economical handling of large tonnages. This has necessitated a great deal of study in the evolution of a safe and efficient method of handling the large quantities of explosives needed in breaking this hard-rock material."

Feb 1, 1948

By Harold Earle Cook

The purpose of this paper is to state briefly the inspection requirements of the Bureau of Ordnance, the specifications governing the inspection, and the physical and chemical properties of the steel used in the construction of ordnance for our Navy. It would be of interest to evoke discussion on points in these specifications which do not tend to insure the production of the very best material for the purpose intended. In other words, what requirements of our specifications are useless and also in what manner are our specifications deficient? It might be well at the start to answer the first criticism of this paper which will probably be made, and that is that the title does not agree with the subject matter. Considering metallographic work as covering only the macroscopic and microscopic examination of metals, this paper will have gone beyond the subject; but it is believed that a broader definition of metallography is that it is the study of the relation of the internal structure of metals and alloys to their composition and to their physical and other properties. The internal structure of steel is dependent on its physical and its chemical properties. These physical properties are dependent on the chemical composition and the mechanical and thermal treatment of the steel. So it seems that this subtitle would not be entirely necessary and that the title " Metallography of Steel for Ordnance Purposes" would cover a study, not only of what we can learn of macroscopic and microscopic examination, but broadly of the whole subject of the specifications, the fulfillment of the requirements of which produce the structural conditions revealed by macroscopic and microscopic examination. I will refer but briefly at the beginning to the microscope and its uses in our inspection. It is only very recently that the Bureau of Ordnancc has furnished certain of its inspection offices with a portable Tassin outfit for the microscopic examination of steel. Since that

Jan 1, 1916

The winning and upgrading of mineral raw materials necessarily includes size reduction, which serves the liberation and production of marketable products from highly valuable and bulk materials. For crushing, the following factors can be duly accounted for depending on material type and the selection of the suitable machine: ò producing a particular size distribution, ò producing a particular grain shape, ò selective comminution, ò gentle comminution, and ò producing a size range required by a specific process and/or for a specific product.

Jan 1, 1993

By Pei-Yung Huang, C. R. Hayward

In order to understand more fully the actual state of copper lost in copper reverberatory slags, a systematic study on the various reactions between certain metallurgically important copper compounds and synthetic copper reverberatory slags was undertaken by the authors in the Massachusetts Institute of Technology from 1942 to 1945.1 This paper, being only a part of the work completed, is published first because it furnishes the first experimental evidence of the formation of copper ferrite from reactions between cuprous oxide and copper reverberatory slags. Choice of Slag Composition The choice of the composition of the synthetic reverberatory slags to be used was much deliberated. Commercial copper reverberatory slags, neglecting minor constituents, avcrage :2,3 45 to 47 pct FeO; 38 to 42 pct SiO2; 5 to 6 pct CaO; 5 to 6 pct A12O3. Since the ternary system CaO-FeO-SiO2 has been much more thoroughly studied4 and is much simpler than the quaternary system CaO-FeO-SiO2-Al2O3, it was decided to use calcium oxide only instead of calcium oxide and alumina in the synthesis of the slags. Fortunately the composition of the average copper reverberatory slag with calcium oxide substituted for alumina lies in the region of the phase diagram clarified by the investigators. A survey of the phase diagram (Fig I) suggested two compositions: (I) the composition near the invariant point S, which is made up of 46 pct ferrous oxide, 37 pct silica and 17 pct calcium oxide; (2) the composition near the invariant point K with 45.5 pct ferrous oxide, 43 pct silica and 11.5 pct calcium oxide. Composition S has the advantage that the percentages of ferrous oxide and of silica almost exactly coincide with those of the average reverberatory slags, and that of the lowest melting point (1093º ± 3ºC) in the whole ternary system. The calcium oxide content, however, obviously is high. Since we have already substituted calcium oxide for alumina, and since calcium oxide is more basic than alumina, the fulfil- slag is decidedly too basic. Composition K has a slightly higher melting point (1150O + 3OC) and a higher silica content, but this is preferred because the slag is saturated with respect to tri-dymite and thus should not corrode siliceous refractories. Besides, it is less basic than composition S. The filial slag composition, therefore, was chosen to

Jan 1, 1949

By S. Sumski, M. B. Panish, R. T. Lynch

The liquidus isotherms in the gallium-rich corner of the Ga-Al-P phase diagram have been determined from 1000" to 1200°C and at I100°C the corresponding solidus isotherm was obtained. A simple thermody-namic treatment which permits calculation of the solidus and liquidus isotherms is discussed. A technique which was previously used for the growth of GaxAl1-xAs was used for the preparation of solution epitaxial layers of GaxAl1-xP and ALP. An approximate value of 2.49 i 0.05 ev for the band gap of Alp at 300°K was obtained and the ternary phase data were used to estimate a value of 36 kcal per mole for the heat of formation 0f Alp at that temperature. The Gap-A1P crystalline solid solution is one in which there exists the possibility of obtaining crystals with selected energy gaps, within the limits imposed by the energy gaps of Gap and Alp. Such crystals are of considerable interest because of their potential value for optoelectronic and other solid-state devices. Furthermore, it has been amply demonstrated for GaAs and GaP,'-7 that device, or bulk materials grown from gallium solution generally have more efficient radiative recombination than materials prepared in other ways. This presumably due to the lower gallium vacancy concentration in such material.= Small crystals of GaXAl1-xP and A1P have been grown from solution,8-10 and A1P has been grown from the vapor," but neither have previously been grown by liquid epitaxy. In this paper we present the ternary liquidus-solidus phase diagram of the Ga-A1-P system in the region of primary interest for solution epitaxy, and discuss the thermodynamic implications of that phase diagram with particular reference to the liquidus and solidus isotherms in the gallium-rich corner of the GaxAl1-xP primary phase field and to the A1-P system. Several measurements of the absorption edge of GaxAl1-xP crystals have been made and the width of the forbidden gap of A1P has been estimated from these measurements. EXPERIMENTAL The differential thermal analysis technique used to determine the liquidus isotherms and the optical measurements used in this work are similar to those described previously12 for the Ga-Al-As system, ex- thermocouples in the thermopile for added sensitivity. The materials used were semiconductor grade Ga, Gap, and Al+ The composition and temperature range at which DTA studies could be done was quite restricted. The upper temperature was limited by the chrome l-alumel thermopile to about 1200°C, and the highest aluminum concentration to about 5 at. pct by low sensitivity caused by the reduced solubility of Gap with increasing aluminum concentration in the liquid. DTA studies were not possible at 1000°C and below because of the low sensitivity caused by low solubility of Gap in the Ga-A1-P system. The cooling rate for these studies was about 1°C per min. No heating studies were done because of limited sensitivity. Supercooling probably does occur, but our experience with other 111-V systems indicates that it is no greater than about 10 to 15.c. Solid solubilities were determined by analyzing epitaxial layers of GaxAl1-xP grown from the liquid, with an electron beam microprobe. The layers were grown on Gap seeds by a tipping technique in which the layer is grown over a short-temperature range (20" to 50°C) on the seed from a solution of known composition. The tipping technique reported by Nelsson1 for GaAs could not be used, particularly for solutions containing appreciable amounts of aluminum, because of the formation of an A1203 scum on the liquid surface. A system was therefore designed, which would effectively remove the oxides mechanically, so that uniform wetting and crystal growth could occur. This tipping technique has already been described in detail." The best control over the composition of the re-grown layer was obtained when the tipping was done at a temperature which corresponded to the temperature of first formation of solid for the solution being used. Generally, therefore, a solution was prepared by adding the amounts of Ga, Gap, and A1 required to yield a solution which would be completely liquid above the tipping temperature with solid precipitating below that temperature. For most of the work reported here, the 1100°C isotherm of the ternary was used. It was generally necessary to heat the solution to 50" to l00. C above the tipping temperature to dissolve all of the Gap in a reasonable length of time. The epitaxially grown layers were used both for optical transmission measurements to aid in the estimation of the way in which the absorption edge changed with aluminum concentration, and for the electron beam microprobe analyses to provide data for the determination of the solid solubility isotherm. RESULTS AND DISCUSSION Liquidus Isotherms in the Ga-A1-P Ternary Phase Diagram: Thermodynamic properties of the system. The only thermal effect studied in this work was that

Jan 1, 1970

By Edward C. Dowling

Froth flotation has been used industrially for many years to separate valuable minerals from their associated gangue constituents. Notwithstanding the significance of this process to the mineral industry, many of the engineering tools needed for the evaluation of the flotation process are still in a developmental stage. Traditionally, the evaluation of a flotation test on both the laboratory and industrial scale has been based largely on a rougher recovery value achieved at a sufficiently long time to give a "final" or "equilibrium" recovery value. The assumption of a time equivalency for a given recovery value between various flotation tests or between laboratory tests and industrial operation underlies this method of evaluation. Such an assumption implies that flotation is an "equilibrium engineering process" and that the time-rate recovery of material from the flotation cell is not affected by changes in the flotation system. It has been shown by Bushell (1) and by Klimpel (2) that the assumption of time equivalency between various flotation tests is unjustified. Consequently, better tools are needed for evaluating flotation test results, Because mathematical flotation models which incorporate both a recovery and a rate function can completely describe flotation time-recovery profiles, they can provide an excellent tool to evaluate flotation tests.

Jan 1, 1984

By F Clark, M Erickson, J Biggam

Unraveling geological complexity and understanding geological risk are critical components of the challenge that face any mining or exploration venture. This understanding is essential to the successful selection of mineralised domains on which grade estimation relies, so knowledge of the geological characteristics of the mineralised domains is vitally important. æNuggetyÆ mineralisation introduces a higher level of risk and geological observation and intuition may be the only option to ensure that opportunities are realised and ore/waste characterisation is undertaken successfully. Mineralisation at the world class Sunrise Dam gold mine contains a significant coarse gold component, which has necessitated the development of a systematic visual approach to decision making that enables geological staff to determine the potential gold grade in the absence of assay results, and in those instances when assay results appear implausible. The development of the Mineralisation (MZ) Code at Sunrise Dam has assisted in reducing the risk of misclassifying ore as waste and enabled geological control to prevail with confidence where complexity and ambiguity existed.

Jan 1, 2009