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By F. Tailoka

Bi was electrorefined from alloys containing 10-90 wt% Pb, together with Cu and Ag as minor impurities, in a basic cell and in a recessed-channel cell with 27.5:72.5 NaCl-PbCl electrolyte at 450-470 degrees C and 10 000-20 000 A/m2. The voltage in the basic cell was as high as 9 V, with some carryover of Bi to the cathode observed, whereas in the recessed-channel cell it was as low as 285-635 mV. Flow patterns observed in a room-temperature model indicated that the recesses provide both static liquid hold-up and good mixing of the alloy, enhancing cell performance in combination with the reduced anode-cathode distance of 0.90 mm. The purity of the resulting anode product is as high as 99.9%

Aug 1, 1995

By Jason N. Scott

CFA piling is a ?blind? construction process that relies heavily on the rig instrumentation to produce sound piles. If the data measured and recorded during construction can be made available to engineers and managers within hours after construction then there are many economic and quality control benefits that can be realised. A state of the art CFA instrumentation and data management process has been developed in the UK. The key components of the instrumentation, GSM data service and the central database are described. Many benefits to the business have been realised and, where possible, these are quantified.

Jan 1, 2006

By Brian Hart, Hong Zhong, Liuyin Xia, Kyle Douglas

"The application of hydroxamic acid as flotation collectors is fast becoming of significant interest for the selective flotation of oxide minerals along with upgrading oxidised based metal ores and minerals. In the hydroxamate molecule, both O and N atoms in the -CONHOH group are identified as coordination atoms in many complexes and their characteristic structure determines the strength of the chelation complex between the hydroxamate and metal ion. The chelating performance of hydroxamates with transition metals including Cu, Ni, Zn, Fe, Cr, Mn and Co, the alkaline-earth metals (Be, Ca) and heavy metal (Pb) has been studied. Cytec has developed and patented a range of alkyl hydroxamates as flotation collectors for oxidised base metal sulphides, metal oxide minerals and precious metals. This paper introduces two new structures of hydroxamate collectors (Cyclohexyl and 4-tert-butylbenzoyl hydroxamates) and evaluates their characteristics relative to alkyl and benzoyl hydroxamates. Laboratory small-scale flotation tests were conducted with ilmenite and wolframite. The use of 4-tert-butyl benzoyl hydroxamate resulted in a best flotation performance for ilmenite. A relatively low cyclohexyl hydroxamate dosage was required in the flotation of wolframite to obtain comparable results to the alkyl and benzoyl hydroxamates. It is also shown a significantly improved flotation performance with 4-tertbutyl benzoyl hydroxamate in the flotation of ilmenite plant ore in comparison to the oleic acid or fatty acid collectors typically used for ilmenite flotation.INTRODUCTIONHydroxamic acid has been reported as an effective collector in small-scale flotation tests for a wide variety of oxide minerals and ores including copper (Lee et al., 1998, Lee et al., 2009), iron (Quast, 2000), tin (Sreenivas and Padmanabhan, 2002; Wu and Zhu, 2006), tungsten (Marinakis and Kelsall, 1987; Xia et al.,2004), and rare earth metal minerals (Ren et al., 1997; Pradip and Fuerstenau, 1991; Assis et al., 1996; Pavez et al., 1996; Zheng et al., 1996; Chen et al.,2005).As part of our previous research project, a selected suite of hydroxamic acid collectors including fatty, aromatic and modified hydroxamates (naphthoyl, cyclohexyl, benzoyl, octyl, 4-tert-butyl benzoyl, salicylic hydroxamates) were tested in order to examine their potential for recovery and selectivity of rare earth minerals. In these tests it was shown that the flotation performance with the hydroxamate collectors was significantly better than the phosphoric acid collectors on no slimes removed samples (Brian, et al., 2014; Liuyin, et al., 2014 and unpublished internal technical reports). Furthermore the tests revealed that for most of the hydroxamate reagents tested, their dosage requirements to achieve recoveries at the same levels was less than that for the phosphoric acid collectors. Recovery of both La and Ce was significantly better for the salicylic hydroxamate and that Nb, Y and Zr recovery were favoured by the octyl and benzoyl hydroxamates (Brian, et al., 2014; Liuyin, et al., 2014). Comparison among the hydroxamate collectors showed that the flotation and recovery performance of cyclohexyl (CHH) and 4-tert-butyl benzoyl (TBH) was not as good as the other hydroxamates for rare earth recovery."

Jan 1, 2015

By L. K. Daneshmend

"Competitive pressures dictate that the mining industry moves to larger mobile underground haulage equipment with more advanced equipment mechanization, higher levels of autonomous operation of machines, and longer periods between access by maintenance personnel. Since such new machines will of necessity be more complex than existing designs, machine reliability has become a key issue in progressing toward advanced mobile underground haulage equipment. Reliability and maintainability models of such equipment are practically non-existent in the literature. This paper addresses the issue of reliability and maintainability of mobile underground haulage equipment on two fronts: reliability modelling to enhance decision making for maintenance planning; and reliability simulation to enable evaluation of more rigorous production planning scenarios. A case study from a gold mine in the Chilean Andes is presented, for which reliability models of mobile underground haulage equipment, specifically load-hauldump vehicles and underground haul trucks, are developed, and a reliability-based simulation implemented. IntroductionMaintenance accounts for 20% to 35% of the overall operating budget for a typical underground operation, and hence represents the largest portion of the mine’s controllable operating costs (Cutifani et al., 1996; Campbell, 1997; Goddard, 1998). This, coupled with the fact that industry today is faced with an ever more complex and demanding marketplace, has led to an increasing interest in methods to reduce maintenance costs.Although significant effort has gone into developing effective maintenance strategies for industry in general, application of these to the"

Jan 1, 2003

The sulphides can be arranged in a series determined by the relative amounts of ionic and covalent bonding present. This series is similar to the paragenetic series common to most sulphide ore deposits. Investigation of the surface tensions of the corresponding heavy metal iodides by the maximum bubble pressure method throws some light upon this relationship. It is shown that the surface tension of molten iodides decreases as the chemical bonding within them becomes more covalent. These results are interpreted in terms of the constitution of the melts, and are extended to cover the case of sulphides in solution in a silicate melt. It is concluded that sulphides tend to lower the surface tension of silicate melts and that this tendency becomes greater as the bonding within the dissolved sulphide groups becomes more covalent. A possible relationship between this conclusion and the origin of paragenesis in sulphide ore deposits is indicated.INTRODUCTIONIt is well known that the order of deposition, or paragenesis of sulphide minerals is remarkably similar in hypogene ore deposits throughout the world. This widespread similarity points towards the operation of some fundamental process which must be intimately connected with -the genesis of these ores. A correct interpretation and understanding of the causes of paragenesis in sulphide ore deposits would shed much light on the origin of these deposits.In Table 1 a simplified paragenetic series for sulphide minerals is presented. In most cases, only the most important sulphide of any particular element has been included. The object of this procedure is to simplify the following discussion. Furthermore, it should be realized that this series is only a generalization and that exceptions and reversals of position are quite common. Especially does this...

Jan 1, 1956

By Ahmad Ghahreman, Lin Li

Silver and cupric ions have been proven to play the roles of catalysts to promote the oxidation kinetics of chalcopyrite in acid solution. In this study, the interaction between silver ions and cupric ions during ferric leaching of chalcopyrite in sulfuric acid solution has been investigated. The electrochemical study by Tafel analysis showed a significant boost of dissolution rate for chalcopyrite dissolution in Fe3+- Cu2+ containing sulfuric acid solution after Ag+ was added in the solution. For 10 ppm Ag addition, the dissolution rate of chalcopyrite increased to 7.94 ×10-6 A/cm2 from 3.2 ×10-7 A/cm2, when Ag+ was absent. On the other hand, the effect of Cu2+ on the dissolution of chalcopyrite in Fe3+-Ag+ containing sulfuric acid solution was not obvious from electrochemical measurements. The chalcopyrite leaching tests in different acid solutions showed that silver addition had an obvious catalytic effect on promoting chalcopyrite dissolution. Comparing the leaching rates of chalcopyrite leached in Fe3+ containing, Fe3+-Ag+ containing, Fe3+-Cu2+ containing and Fe3+-Cu2+-Ag+ containing sulfuric acid solutions, it was found in Ag+-Fe3+-Cu2+ containing sulfuric acid solution, the leaching rate was highest among all the aqueous acid systems. Further leaching tests suggested that with increase of the Ag+ concentration from 0 to 20 ppm, the leaching rate of chalcopyrite in Ag+-Fe3+-Cu2+ containing sulfuric acid solution also increased and reached 57.62% with 20 ppm Ag+ addition after 24 h. INTRODUCTION Chalcopyrite is the most important copper mineral in copper hydrometallurgy and it accounts for nearly 80% of the universal copper resource (Olvera, Rebolledo, Mora, Dixon, & Asselin, 2018). The hydrometallurgy of chalcopyrite has been intensively studied with emphasis on solving the slow dissolution kinetics of chalcopyrite in acid environment. A variety of aqueous systems, such as sulfate (Hiroyoshi, Miki, Hirajima, & Tsunekawa, 2001), chlorides (Liu, Chen, & Yang, 2017), and ammonia (Hua et al., 2018) have been studied to improve copper leaching. From another perspective, chalcopyrite leaching studies have indicated that the mechanism of chalcopyrite dissolution in acid solution is essentially electrochemical (Li, Kawashima, Li, Chandra, & Gerson, 2013). Therefore, extensive studies have recently been carried out to explain the dissolution kinetics of chalcopyrite in different media by various electrochemical techniques.

Jan 1, 2019

By A. Himsley

"There is an ever-increasing demand these days for efficient methods of removing metals from solutions especially for selectively recovering a particular metal from a mixture of metals in solution.Up until the mid l 930's the only methods widely practiced for such separations involved precipitation techniques or electrolysis. Both these methods have limitations and indeed can only be used for certain metals.It is only within the last 40 years or so when synthetic ion exchange materials became available that chemists in industry and universities have been able to apply ion exchange techniques to a wide variety of separations that not only would be impossible by precipitation methods but which are now achieved with much greater efficiency.Ion Exchange TechniquesIon exchange is a unit process that can be applied using either liquid ion exchangers or solid resin particles. Liquid ion exchange - or solvent extraction as it is often referred to - is used in a number of special areas dictated mainly by the nature of the separation.On the other hand, ion exchange resins are much more widely used and consequently a great deal more is known about their application to a variety of metal separations.In both systems there is a loss of the ion exchange material which in the case of solvent extraction results in hydrocarbons going to waste. The ion exchange resin systems lose resin in the form of small particles, referred to as ""resin fines"", and these are insoluble.The loss of liquid ion exchanger is due to the fact that it is slightly soluble in water and consequently the loss is a function of the volume of liquid with which it comes into contact and is not related to the amount of metal processed."

Jan 1, 1975

By Y. I. Rabinovich, S. C. Brown

In the Florida phosphate industry, fatty acid collectors are used to separate phosphate ore from silica during the rougher flotation stage. However, the presence of multivalent ions (in particular Ca++) in the processing water has been reported to result in the activation of silica with respect to oleate adsorption, rendering it floatable. Hence, adequate separation may not be achieved during the rougher flotation stage. In this study, the direct measurement of surface inter-action forces via atomic force microscopy was used to delineate possible mechanisms for calcium activation under phosphate flotation conditions at oleate/calcium concentrations both above and below the calcium dioleate precipitation limit.

Jan 1, 2004

In undertaking to write a few notes on practical mining in Bendigo, the great quartz mining centre of Victoria, which just now is celebrating its fiftieth anniversary of gold mining, satisfaction must be expressed which is, no doubt, shared by all mining men and inyestors, that Bendigo has not lagged behind other Australian mining districts in the evolution of mining from its crude state, subsequent to the discovery of gold in 185 to its present more perfect state; and though it may be said that it has not yet reached the high pinnacle of perfection towards which advanced science and change of conditions may yet lead it in the course of future progress, yet, what has already been done in this respect, the adoption of the most approved methods appliances and modern machinery, tending towards greater and still greater efficiency, facility, and economy in our mining industry, must be accepted as a guarantee that in tne future as well as in the past, progress in our means of developing our mining resources will ever remain our watchword, by means of which future difficulties will be overcome as well as they have been removed in the past.The adoption of this principal, combined with a study of rigid economy, has raised gold mining here, as well as in other places, from a state of speculation, and sometimes wild speculation, to the status of a solid, stable industry, the strong supportand backbone of the country in which it flourishes. Two of the principal factors which have been to a great extent instrumental in bringing about this satisfactory state, must be specially mentioned.

Jan 1, 1902

By Peter Campi, Harry R. Asche, Ian P. Callow, Edmund G. Taylor, P. Scott Smith

The US$1,850 million EastLink project is a 39km tollway and includes twin 3-lane,1.5km long, undrained driven tunnels. The hard rock tunnels are being built to avoid passing the motorway through the Mullum Mullum Valley and so to help preserve the unique flora and fauna in the area. This paper describes several of the key issues in the tunnel design and construction, including: the integration of the temporary support design with the Contractor’s tunnel excavation and support procedures, including sharing of responsibility between the Designer and Contractor for support type selection and the production of a project specific rock mass classification system to enable more objective determination of ground conditions. detailed hydrogeological assessments during the design and construction phases to allow confirmation of design loads for the tunnel lining design and the various suite of waterproofing tools in order to meet the project inflow requirements. development of a pre-cast invert solution to the main tunnel secondary lining to enable faster lining construction and to minimize risks to the tunnel membrane associated with fixing reinforcement and construction traffic.

Jan 1, 2007

By N. P. Mahumapelo

This paper is based on a study to determine the potential beneficiation opportunities for marble from Griekwastad in the Northern Cape Province. The marble was characterized mineralogically by X-ray diffraction. Major and trace elements were determined using inductively coupled plasma-optical emission spectroscopy. The sample was crushed, and the crushed material beneficiated by tumbling and polishing. The resulting beads were incorporated into a variety of jewellery and other decorative items. It is concluded that the beneficiation of Griekwastad marble presents a good opportunity for value addition and job creation, provided that an effective marketing strategy for the products can be developed..

Jan 1, 2014

By Fredrik Sarvell, Leo-Ville Miettinen, Veli-Matti Uotinen

"Abstract The continued concentration of building activities in cramped areas of city centres means more underground construction and facilities. Demand to minimize execution time and any kind of disturbance to business, general traffic, people and nearby technical structures is increasing. To answer these challenges foundation business has to develop schedule-wise and technically reliable deep excavation and foundation solutions in vulnerable surroundings and challenging soil conditions.Drilled pipe pile wall – RD-pile wall – is a combination of Ruukki drilled steel pipe piles and interlocking sections. Individual RD piles, typical diameters between 219 mm to 610 mm, are connected to each other with interlocks welded to the piles on the automated welding line at the workshop. The matching dimensions of the drilling system and interlocking sections allow the installation of RD piles through stones and boulders and even into the bedrock, if necessary, in a single operation. Installation is done by a down-the-hole hammer (DTH) using the centric drilling system and oversized ring bits or a drilling system consisting of a pilot bit and reamer wings.RD-pile walls have been used as permanent and temporary retaining walls for different kinds of demanding excavations and structures, such as bridge foundation, as quay wall and as sealing structure in rehabilitation of an existing dam. Rigidity and watertightness of the lower end of the RDpile wall is being researched as well as fire design issues examined. One of the most fascinating RDpile wall solution is to utilize the wall as a permanent underground basement wall. Reliable and rigid connection to bedrock decreases the bending moment and deflection of the wall and good fire resistance in addition to large variety of pile dimensions and steel grades gives possibilities to design and execute a cost-efficient basement wall and foundations without temporary retaining wall works. 1. IntroductionIn northern Scandinavian soil conditions, installation of sheet pile walls, or even secant pile walls, is often problematic due to the existence of hard and large boulders in the overburden, and especially when the retaining wall structure should penetrate to or into the hard bedrock. On the other hand, an efficient and reliable piling technique suitable for the demanding soil conditions described above, percussion drilling, has been developed since the 1960’s, and especially from the mid-1990’s, when the concentric drilling method with the ring bit and pilot was introduced. A new retaining wall application, the RD pile wall was developed by combining that drilling method with the widely used retaining wall solution based on steel pipe piles and welded interlocks (a pipe pile wall normally installed with vibratory or impact hammers)."

Jan 1, 2014

By J. E. Warren, J. H. Hartsock

An asymptotic solution to the equation that describes the flow of a slightly compressible fluid in an infinite porous medium has been used to estimate the interaction between two adjacent wells producing from a common reservoir. A direct method for approximating the interference time defined by Stevens and Thodosl has been suggested. An alternative definition for the time of interference, based on the minimum pressure change in the interference region, has been proposed; also, a direct method of determination has been prescribed. Examples have been employed to illustrate the use of both methods.

On the basis of field observation, four principal styles of hydraulic breccia are recognised, and their characteristic features noted. In practice, hybrid styles are most commonly encountered. Numerous examples will be illustrated during the oral presentation, and the potential for definition of a formative environment is emphasised. In one example presented, it is suggested that more than 50 episodes of hydraulic fracturing can be recognised. In all cases at least sane useful conclusions can be drawn in the context of modeling for drill targets.

Jan 1, 1987

By Alex Doll, Derek Barratt

"There is a number of comminution tests commonly used in the mining industry. Many of the tests are used for a particular grinding model or mill sizing program and are incompatible with other tests of different models. This paper provides an overview of the commonly used grinding and crushing tests, which models (or practitioners) use a particular combination of tests and draws some relationships between the incompatible tests based on the DJB Consultants Inc. database of projects.Case studies will demonstrate similarities and differences between major mining districts with some comments about homogeneous and heterogeneous behaviour within the grindability results.INTRODUCTIONThere are a number of bench-scale grindability tests in use for sizing and predicting throughput for grinding circuits. Part of the reason for this variety is there are a number of different grinding models in use in the Industry, and those models operate using incompatible test results as input (Doll and Barratt, 2008).By using the database of testwork in the DJB Consultants, Inc. (DJB) Millpower 2000 database (see Table 1), some of the more commonly used tests are compared and relationships will be drawn."

Jan 1, 2011

By James L. Oleson, Hunter R. Propsom, Kevan J. R. Ford, Robert D. Henderson, Bob Musgrove

"Kinross’ Fort Knox Gold mine, near Fairbanks, Alaska has successfully implemented two major metallurgical continuous improvement projects resulting in growth of gold production and an extension of mine life. In 2009, Fort Knox produced 263,153 oz of gold at a cash operating cost of $543/oz. In 2010, approximately 63% of the gold will be produced from the CIP circuit, 15% of the gold from the gravity circuit and 22% of the gold from the heap leach.In 2009, a 44,000 ton per day run-of-mine valley fill heap leach facility was constructed and commissioned as a cost effective treatment option for low grade ores to supplement the higher grade mill. The heap leach facility will produce approximately 100,000 ounces of gold per year under severe winter conditions. Heap leach gold recovery, based on test work shows 30% after a 55-day leach cycle, with long term ultimate gold recovery targeted at 65%. The paper presents the heap leach design concepts and production data.Additionally in 2009, installation of a Knelson gravity concentrator unit (XD70) was completed. This together with an Acacia intense leach reactor (AILR) has increased overall mill gold recovery from 79.3% to 80.7%. A manual shaking table gold recovery operation has been replaced by batch intensive cyanidation of the high grade Knelson concentrates. Increased removal of coarse gold and difficult-to-leach gold species from the grinding circuit, via the gravity circuit, has improved gold leach recovery in the conventional whole-ore tank leach CIP circuit. The paper presents plant operating data, showing the improvements over the old flowsheet.Focus on the metallurgical properties of the high grade and low grade end components of the Fort Knox ore has resulted in significant improvement to gold recovery."

Jan 1, 2011

By D Vickers, N C. Fowke

The reduction of geological risk for planning of high production longwall faces is essential. Geological and geophysical techniques applied at Huntly West Mine before 1989 were unable to reduce the geological risk to an acceptable level. The success of a trial long-hole directional drilling programme at Huntly West Mine (Fowke et al, 1989) has encouraged the Coal Corporation of New Zealand to use the technology long-term, for seam definition. Initial drilling in 1989 completed a total of 3543 metres, with the longest borehole length being 369 metres (limited by number of rods available). A major re-interpretation of seam structure resulted from the drilling, which was able to fill in seam details between surface exploration boreholes. The undulating thick seam conditions at the mine require a refinement of drilling strategies used overseas. Long-hole directional drilling also displays potential for inseam gas drainage. Gas flows of the order of 1000 L/min were initially indicated in individual boreholes. Other gas parameters of the seam have been studied by Beamish et al (1991), and highlight the significance of the natural gas resource in the Huntly Coalfield.   The continued development of drilling technology will be of major benefit sustainable development, particularly in policy.

Jan 1, 1991

By Rafael C. Castro, Geoffrey Hughes, Fredrick (Rick) Vincent, Philip H. Albert

Seven pairs of drop and ventilation shafts, between two and nine feet in diameter, will convey combined sewer flow to a 230-foot-deep, 26-foot diameter storage tunnel. This paper will present case histories for each site. Discussion will include functional requirements, program and site access constraints, structural design, geology, the variety of excavation and lining construction methods used, and lessons learned. Noteworthy observations include the importance of assuring competent ground sup-port at the soil-bedrock interface and of achieving tight verticality tolerance using both top-down and raise bore excavation methods.

Jan 1, 2007

By N. D. L. Burger

An effective prototype face support system to minimize rockfalls in rockfall-prone mines was developed and patented during a project sponsored by the Mine Health and Safety Council (MHSC). An experimental development model (XDM) roof support unit was developed and evaluated. Mines with rockfall problems in the face areas can use the roof support system to reduce fatalities and injuries in the face area of stopes. The roof support system consists of two similar support units connected to each other via two crank mechanisms. Each unit consists of a headboard supported by a ?wishbone? structure (top and bottom leg). In the first design a threaded bar with struts similar to a scissors jack keeps the legs apart. (In the final version that was field trialed, the threaded bar mechanism was replaced with a hydraulic cylinder). All the components are manufactured from steel. To move the system forward the first support unit is collapsed, the second remaining in the loaded position. The first unit then hangs from the second unit to which it is connected. The first collapsed unit is then manually cranked forward and prestressed. If the required position is still not achieved, the other unit is released and moved forward. The specification for the system was determined and presented at a workshop with industry participants. Different concepts were developed and evaluated against the system specifications. A technology demonstrator was then developed and tested on surface. The technology demonstrator development process included detail design, building and testing of components and subsystems, design reviews and the building and commissioning of the technology demonstrator. The testing of the technology demonstrator was done in a 500-ton hydraulic press, in a mock-up stope and underground. A risk analysis, in which technical, logistical and economic aspects were assessed, was done to determine the critical areas of the system. During the next phase of the project working prototypes were developed for underground tests and evaluation. This process indicated that it was necessary to adjust the system specifications and a redesign was called for. In an iterative process test units were built for purposes of evaluation, specification verification and field trialing. After the successful conclusion of the trials the equipping of a complete production stope started for purposes of integrating the system into the current mining process.

Jan 1, 2008

By Zhibao Li, Kunming Zhai, Yan Zhang

The hydration kinetics of MgO, namely magnesia or magnesium oxide, obtained by calcination of magnesite MgCO3 or synthetic MgCO3·3H2O has been studied. Nesquehonite (MgCO3·3H2O) was prepared by the reaction of MgCl2 with Na2CO3 in a mixed-suspension mixed-product removal (MSMPR) crystallizer at 40 °C. Three magnesium oxide samples were obtained by calcination of magnesite MgCO3 or synthetic MgCO3·3H2O in muffle furnace at 900, 1100 and 1300 °C for 3 h, respectively. The hydration experiments of MgO samples were investigated at 25, 35 and 45 °C for 24 h in a stirred batch reactor. The hydration results indicate that the rate and extent of hydration of magnesia decreased remarkably with hydration temperature and increased with decreasing calcination temperature at a constant hydration temperature. The whole hydration reaction of magnesia was supposed to experience the promotive period and declining period. An empirical kinetic model ( k t p -?ln(1-??) ??) and a modification of the classical shrinking core model for diffusion control ( k t b d -?-?3 2 ????1 [1 (1 ??) ] ) have been applied to fit the experimental data of hydration in two stages, respectively. The values of kinetic parameters ( p k and d k ) were obtained by regression analysis and the activation energy of the sample at 900 °C was estimated to be 34.23 kJ/mol. The comparison between MgO from calcination of synthetic MgCO3·3H2O and a commercial MgO used in silicon steel production was carried out, indicating that special silicon steel grade MgO can be obtained by calcination of MgCO3·3H2O below 900 °C.

Jan 1, 2014