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By John Ralston, Rossen Sedev, Nicola Richards, Quinn Anthony, Geoffrey Reynolds

Derivatised 2,4-diketopyrimidine groups have been anchored to planar gold surfaces as self¬-assembled monolayers (SAMs) for chemical and photochemical studies. Three derivatives, 5-methyluracil (thymine), 5-trifluoromethyluracil and 5-nitrouracil, were chosen for the specific moiety present at position C-5, which can exert strong or weak inductive effects on the adjacent aromatic ring. The measured acidity constants decrease from 5-methyluracil to 5-nitrouracil as the inductive properties of the group at C-5 position increase. When grafted to the surface the acidity constants increase, albeit still adhering to the expected inductive trend. The functionality also exerts an influence on the surface wetting properties. Surface wettabilities indicate that the orientation of the pyrimidine groups at the surface occurs so that the C-5 position has a direct effect upon the surface chemistry. Upon dimerisation the surface contact angles increase signifi¬cantly. At pH 11 the contact angle changes reflect that the dimer has a higher pKa than the monomer. The monomer surface is deprotonated at this pH while the dimer surface is partially deprotonated, leading to changes in contact angle of up to 22 degrees. Large changes in contact angle were observed for 5-nitrouracil which were independent of surface charge and were appar¬ently due to conformational changes alone. Electrowetting of three fluoropolymer surfaces by electrolyte solutions was studied with the sessile drop method. The electrowetting curve (contact angle/potential) is analogous to the elec¬trocapillary curve (surface tension/potential) and may be described by a combination of the Young and Lippmann equations. We demonstrate that for some specific surfaces a systematic deviation occurs at positive potentials. This departure is attributed to double layer effects, namely the adsorption of hydroxide and halide anions. pH, ionic strength and polymer composi¬tion can all influence electrowetting behaviour.

Jan 1, 2003

By Jerzy Matuszewski

Under conditions of high methane content in the seams and the descending of exploitation to greater depths, methane hazard control is becoming more and more difficult. This is due both to the amount of methane released and to the technical possibilities of diluting and capturing it. The removal of excess methane from mine workings only by means of the ventilating current has become a problem. Therefore many countries designate large sums of money for research work in the field of controlling dangerous methane accumulations and for introducing this control into mining practice. In Poland the Central Mining Institute is leading in this field. Its Safety-in-Mines Institute, Barbara Experimental Mine in cooperation with collieries has recently carried out interesting investigations on the distribution of methane concentrations in gobs behind the front of longwalls mined with caving.

Jan 1, 1980

By U. F. Beichmann

INTRODUCTION The City of Oslo together with the neighbor municipalities, Baerum and Asker, are presently building a jointly owned sewage treatment plant located on the west side of the inner Oslofjord. The project is scheduled for completion late 1981. Because the location of the treatment plant is at a distance of about 20 miles (30 km) from the city center, a discharge of more than 13 yds 3/sec (10 m3/sec.) of sewage and storm water will have to be transported over considerable distances. The topography of the area and the geological conditions early indicated that the only realistic transport method had to be through tunnels. As planning proceeded, full face tunnel boring emerged more and more as a favorable alternative to conventional drill and blast medhods. Today the scheme comprises nearly 25 miles (40 km) of tunnels being excavated by full face tunnel borers. In addition a number of access tunnels and cross cuts are to be excavated by conventional methods.

Jan 1, 1979

By Augusto Andres Torres Toledo, João Felipe Coimbra Leite Costa, Luciano Nunes Capponi, Diego Machado Marques

Short-term mine planning to open pit requires defining diglines to orientate the excavation geometry. In deposits with multiple chemical variables, it is necessary to have more rigorous control over the feeding of the processing plant. This study analyzes the impact of incorporating multiple chemical variables, the risks generated by geological uncertainty, and the number and starting point locations of shovels in the sequential design of diglines. The objective is to maintain and preserve the low-grade variability, required tonnage, and continuity in sequentially selecting blocks. To achieve this, the probability distribution function of each chemical variable is used while attempting to maintain the ore grades as constant as possible. As it is difficult to maintain multiple elements with low variability simultaneously, the relevance of each chemical variable in the economic benefit is identified. Weights are assigned to signal the importance of each element based on its significance in the recovery process. Several diglines, consisting of sequential blocks, were generated on the same seed point to meet the weekly ore demand. Optimizing the stationarity of multiple chemical variables, accessing and reducing the geological uncertainty performed through geostatistical simulation of grades and transfers functions, considering the number and location of shovels, while meeting the operational restrictions of the selected blocks. The optimized digline with the multiple grades as stationary as possible is retained. The process is illustrated in a phosphate mine. The results show that the proposed method is viable and allows for a quick solution.

Jun 25, 2023

By E. A. Zawadzki

The problem of pollution of water by mine drainage is at least as old as the mining industry itself. However, research on the formation, composition, treatment, and abatement of mine water is a relatively recent historical event. At Bituminous Coal Research, Inc., acid mine drainage control has been an important area of work since 1944, at which time BCR began sponsorship of research at West Virginia University. The work at West Virginia University involved a detailed study of the acid mine drainage problem and led to the identification of iron oxidizing bacteria as important factors in the formation of acid mine water. The results of this research were summarized in 1954 by Temple and Koehler (1) who concluded that "no practical solution for the problem" of controlling acid mine drainage is yet known.?

Jan 1, 1967

By M. Kuchta

A linear integer programming (MIP) model to solve the long-and short-term production-scheduling problem for sublevel caving operations is presented. The MIP model is designed as a multi-time-period problem to provide monthly schedules that meet production, blending and sequencing requirements. One of the most important issues during the development of the MIP model was the requirement of sequencing between blocks. In this mathematical model, unique constraints that ensure sequencing of the production from sublevels are developed. A suggested method of handling a large number of variables is also given. The MIP scheduling model was implemented on a data set obtained from the Kiruna Iron Ore Mine located in northern Sweden. The initial MIP model implementation was successful and provided a solution that optimized resource recovery while meeting monthly and yearly production constraints. The scheduling results obtained based on the Kiruna Mine are further presented and discussed.

Jan 1, 2003

By Bartłomiej Bursa, Paweł Stefanek, Paweł Stefaniak, Sergii Anufriiev, Wioletta Koperska, Maria Stachowiak

The article presents the main functionality of the DSS class system for monitoring and stability assessment of tailings storage facilities. The presented demonstrator was deployed on the example of the Żelazny Most reservoir - the largest active facility of this type in Europe and the second one in the world. Considered a high-risk structure, it demands a system capable of online analysis of big data from various sources using machine learning, 3D modeling, or GIS mapping with the functions of interactive time-spatial analysis. In this paper, we present a complex calculation module with an integrated user interface.

Jun 25, 2023

By Virginia T. McLemore, Abena S. Acheampong-Mensah

Critical mineral endowment of mine wastes in two mining districts in New Mexico (Copper Flat at Hillsboro and Carlisle-Center mines in the Steeple Rock district) will be characterized and estimated. “Beta-testing” of USGS procedures was performed. Potential critical minerals at these deposits include As, Bi, Te, Zn, Co, Ni, Mg, Mn, and fluorite. pH and particle size of samples were analyzed to determine weathering and migration potential of heavy metals. Soil pH was also measured to determine the potential for Acid Rock Drainage. The pH of the waste rock piles ranged from 3.66 to 5.67 which indicates fine- grained pyrite or sulfide oxidation. The samples collected from the tailings however, showed a different range of pH, from 6.30 to 8.62, probably due to the presence of carbonates. Difference in particle size fractions and its distribution along the slope are generally influenced by natural occurrences (e.g., gravity and pre-mining hydrothermal alteration) and operational activities such as material piling or dumping. Future work includes analyses of mineralogy and particle size correlation and estimation of critical mineral endowment of these mine wastes at New Mexico.

Feb 1, 2024

By R. E. Muller, L. G. Martin, J. M. Stonehouse

Erratic distribution of values in free gold ore bodies presents severe problems in sorting material in large scale open pit mining. However, an intense program of modern blasting techniques and less than modern gold panning results in good sorting at Houston International's Manhattan mine. Blasting technique is important. If the sample location cannot be relocated because of blasted material movement, information acquired while drilling is useless. So short benches are critical to minimize dilution. Though not very accurate, panning allows for rapid analysis. The more accurate fire assay does not provide the needed speed. Panning can be fairly accurate and errors made are mostly on the low side. Samples of mixed and broken stockpile material are used as checks on pit procedure and to develop stockpile content in¬formation. Added tonnages discovered offset the higher labor costs of this careful sorting technique. The mine is located in central Nevada's Toquima Range in the small mining town of Manhattan, 322 km north of Las Vegas. The mine has four epithermal stockwork ore bodies that are mined in two pits. The mine problem was that conventional ore control was not separating ore from waste. Assays of 6-m blast-holes were used on 5-m centers. The blastholes were relocated by stadia survey after blasting. Holes assaying above the cutoff grade were flagged and mined as ore. This system is practical and useful in high concentration ore bodies or in evenly disseminated mineralization. But it was not practical at Manhattan because of large gold particles and small ore pocket sizes. Ore pockets were often missed when drilling a grid area for blasting. Also, large gold nuggets made assay results unreliable. The probability of a nugget being contained in an assay charge is small. So most results were low, compared to actual grades mined based on stockpile samples. When a nugget found its way into a fire assay charge, the result would be far higher than the actual grade of material represented. In addition, disturbance by blasting created problems in relocating ore. Because of these problems, the grade control program was intensified in September 1979. It successfully separated ore and waste in blocked out ore areas and located more ore in "waste" areas. Known reserves mined to date have increased up to 50% on some benches. The methods used are modern blasting techniques, detailed assaying, and traditional panning of samples collected from active mining faces. These methods allow mining flexibility, to match the variable mineral occurrence in ore bodies. The united effort of the geology and engineering departments has been important to the program's success.

Jan 12, 1980

By Chen Bing Ching

Hsikwangshan mine is located at Lengshuijiang city of Hunan Province. It is a stibnite deposit. The orebody is gently inclined; its ore run is about 3 km in length and extends about 1.2 km along the direction of dip. The thickness of the ore body is non-uniform and varies from 1.5 to 20 m. The orebody is mined by room and pillar and cementation filling. The nine levels at the ore top have been mined out. At present, the mining operations are at the eleventh level. The mine ventilation system consist of three main fans which are installed in different shafts and are ventilated in parallel. The main fans can be connected to each other through comprehensive return air drifts. Two of the fans are located underground and the other on the surface. The general configuration of the ventilation system is shown in Figure 1. Because the operating areas are scattered and vary frequently as well, it is difficult to bring about air flow control. If the air flow cannot be varied with the variation of production in time, the air quantities are not sufficient in some areas and are excessive in others. However, it is also a problem to coordinate the three main fans with one another to obtain the optimum economic cost of operation. In order to make the air delivery fit the variation of production continuously to satisfy the ventilation requirement of the working faces and to reduce power consumption, we have made a great effort over five years to install an automatic control system for mine ventilation at the Hsikawangshan mine. The key part of this system is a microcomputer. The whole system consists of a console, which is located at the surface; the circuit network that is provided for signal transmission; air doors and ventilators at the working face; the scale air doors which are installed at the main branch airways; main fans and their speed regulating devices, as well as the sensors used for observing pressure, air quantities, temperature and the concentration of carbon monoxide, etc. This system can continuously telemeter the air quantities and carbon monoxide concentration in the main branch airways, air pressure, air quantities, electric current, the temperature of the bearings of the main fans, etc. According to the production air requirements, the system controls the ventilators or air doors which are located at the working faces and regulates the air quantity in the main branch airways. It can also choose the optimum mode of operation automatically, and regulate the rotating speed of the main fans to guarantee the least total power consumption while satisfying the total air quantity requirements. If abnormality of the observed results is discovered, the audible and flashing light alarm signal starts up automatically. The operating mode of ventilation equipment also feeds back to the control room and displays on the console. The configuration of control the system is shown in Figure 2.

Jan 1, 1987

By J. `. Spitzinger

In situ recovery (ISR) of uranium alters the baseline groundwater geochemistry in order to mobilize and complex uranium to extract and concentrate it. ISR wellfield restoration is often challenging, and primarily relies on groundwater sweep, reinjection of treated permeate, and/or injection of reductants. Greater focus should be placed on injection-based approaches (using existing infrastructure) based on established engineering concepts used for in situ remediation of groundwater plumes. Such injection-based approaches could shorten restoration timeframes consequently reducing long-term operational costs. This paper addresses various types of injection-based approaches to wellfield restoration based on in-situ remediation success with other constituents that require similar treatment. This paper describes necessary design practices for injecting reactive chemicals (e.g., reductants or biostimulants), operations and maintenance (O&M) strategies to prevent fouling of the chemical delivery system and well network, and natural constraints to restoration. Best practices for successful biostimulation strategies that minimize residual uranium, radium, oxoanions, and other trace elements are as described. Advantages of such injection-based approaches could include significant reductions in restoration times, and consequently, lower restoration costs.

Feb 23, 2014

By Steven W. Hunt, Phillip U. Santacroce, Roger C. Ilsley

Consolidation grouting from the surface prior to mining a shaft is commonly performed to reduce groundwater inflows to a manageable rate. This paper describes the inflow reductions obtained within dolomite and limestone formations at several shafts and chambers due to grouting programs for the Milwaukee Water Pollution Abatement Program. The resulting inflow reduction factors are compared to results reported in the literature for other projects. Post-grouting pump tests are also evaluated as an aid in grouting assessment. Important considerations for estimating shaft inflows from pump test results are discussed. These considerations include loss of grouted mass during mining and influence of blasting and rock features on grouting effectiveness. This information should be helpful to design engineers and contractors who need to estimate inflows after pre-excavation consolidation grouting has been performed.

Jan 1, 1993

"With millions of dollars and thousands of lives at stake, the Iron Ore Company of Canada (IOC) turned to a private wireless network for help.IOC needed a network that possessed the ability to adapt to changes in a nanosecond and to function seamlessly in the most rugged of environments.Canada’s largest iron ore producer required a private wireless network powerful enough to support all mine applications and deliver all data to one central point — without any existing cellular/3G/Wi-Fi coverage.Operations at IOC, a leading global supplier of iron pellets, involved dispatch, drill management and equipment monitoring, pump control and remote video that must service three distinct pits. Due to its setup, the facility does not offer a great deal of flexibility for transmitting signals.IOC serves a robust customer base made up of North American, European and Asian steel producers. It also employs nearly 1,900 people. Catastrophic death and destruction are two very real potential consequences of system communication failure.Technology for tough terrainKinetic mesh technology was born in the wake of the 9/11 terrorist attacks on the United States, one of the most high-stakes emergency situations in U.S. history. The failure of the communications infrastructure on a massive scale that day underscored the need for networking technologies that could provide service even in the most chaotic of conditions.Kinetic mesh networks allow organizations to deploy networks at sites where communications infrastructure has been compromised, as well as quickly establish networks in places where they did not previously exist. Kinetic mesh networks have also demonstrated a better ability to adapt to network changes on-the-fly versus other types of networking technologies."

Jan 1, 2015

By L. Mao, R. Yoon

The thin film balance (TFB) technique was used to measure the equilibrium thicknesses of the water films formed between two oil phases. The measurements were conducted with dodecane at varying concentrations of dodecylammonium chloride, pH, and electrolyte concentration. The data obtained in the present work were used to calculate the surface forces acting between the two oil phases. The calculation was carried using the Extended-DLVO theory with the surface potentials calculated from the Gibbs adsorption isotherm. The results show that oil droplets suspended in water are hydrophobic and the hydrophobicity changes with surfactant and electrolyte concentrations.

Jan 1, 2004

By H. Polat

Relatively large amounts of such hydrocarbons as fuel oils are often needed in flotation of low rank coals. The amount of oil can be decreased considerably by using surfactants as promotors. The reagents which are good candidates as surfactants to promote hydrophobicity can also act as emulsifying and wetting agents. Since the physical and chemical variables influence various sub-processes in different ways, their influence on the performance parameters is complex. The results of laboratory tests are presented to show that the dual role of reagents can be judiciously exploited to increase both the recovery and grade of clean coal. The mode and order of reagent addition is critical in enhancing their efficacy as flotation promotors. The results demonstrate the benefits of proper conditioning of the pulp prior to flotation.

Jan 1, 1997

If a fire occurs outby an underground coal mine section, the immediate safe evacuation of miners from the working section should always be the first action during the rescue operation. Unfortunately, in many cases, the escape-ways (escape routes) dedicated for miners' evacuation are contaminated with fire byproducts from adjacent entries. The purpose of this paper is to present the ventilation control process that will maintain the escape-way free from contaminants and available for travel. Several scenarios in a different section on ventilation system arrangements are analyzed, discussed and presented. To perform these studies, the author used a mine-fire simulator, which provides a dynamic (in real time) representation of the fire's progress and also gives a display, a color-graphic visualization, of the spread of combustion products throughout the ventilation system. Presented and discussed in this paper, also, are ways in which the mine-fire simulator can be used as a training and teaching tool for miners and, particularly, for ventilation and safety personnel.

Jan 1, 1993

By T. C. Eisele

The separating efficiency of a flotation column is largely limited by the degree of backmixing of tailings into the froth zone, and its recovery is limited by the degree of short-circuiting of feed to the tailings. Current columns are typically made very tall, on the order of 30-40 feet, in order to limit the effects of backmixing and short-circuiting. These effects can also be reduced in a much shorter column, provided that the flow in the column approaches plug-flow. In this work, horizontal baffles were shown to improve the performance of a 6-foot tall laboratory-scale flotation column treating a difficult-to-clean, heavily oxidized coal. Tests with variation in the position of the baffles showed that for the greatest benefit, baffles are needed both above and below the feed inlet. Tracer tests with a fluorescent dye water tracer showed that the addition of the baffles reduced the amount of feed water entrained into the froth at any given coal recovery.

Jan 1, 1994

By M. U. Khan, A. D. S. Gillies

"Diesel exhaust is a major cause of large number of occupational diseases. Acute and continuous exposure to Diesel Particulate Matter (DPM) can cause numerous health issues including respiratory disease, reduced lung capacity, heart disease etc. The National Institute of Occupational Safety and Health (NIOSH) and the International Agency for Research on Cancer (IARC) consider diesel engine exhaust as carcinogenic. In large underground metal and nonmetal mining operations, regulatory compliance regarding miner’s exposure to airborne particles especially DPM is a big challenge. Complex mine networks add more difficulties in controlling DPM. MSHA relies on the NIOSH 5040 method for DPM compliance. The NIOSH 5040 method is a shift average based method which inherits some limitations. Due to these inherent limitations of the NIOSH 5040 method the concept of real-time DPM monitoring is promoted in the mining industry. Several real-time DPM monitors have been used by the researchers and efforts still continues to improve their measuring techniques and understanding. Real-time monitoring of DPM is vital to gain understanding of rapid changes in the mine atmosphere. The current study highlights the advancement in real-time DPM monitoring and mainly covers a review of several studies in which DPM concentrations were measured by utilizing real-time DPM monitors. INTRODUCTION Ventilation of underground mines is an important aspect of mining operations. Mining is a continuous activity and the ventilation networks in modern mines change with extended developments. Proper understanding of the ventilation network is a key design factor of an optimum mine ventilation plan. An important task of underground mine ventilation engineers is to provide clean air with sufficient quantity to the underground miners (Khan M. U. and Gillies A.D.S. 2015). The amount of fresh air supplied to the mine should be adequate to dilute the concentrations of contaminants present in the mine atmosphere. In the United States it is estimated that diesel powered equipment is used in thousands of mining operations (Stephenson D. J. et al. 2006). Use of diesel powered equipment is an attractive option in underground mines due to its several advantages over other available alternates. Diesel engines are rugged, dependable and fuel efficient (McKinnon 1999). It is common for diesel engines in heavy duty trucks to have a life of 1.6 million kilometers (McKinnon 1999). Looking at the developments in other energy alternatives, it can be assumed that the underground mining industry will maintain its reliance on diesel powered equipment (Anon 2001). DPM is an important source of mine air contamination in many non-gassy underground mines (Khan M. U. and Gillies A.D.S. 2015). Diesel exhaust is harmful for humans. Acute and continuous exposure to diesel exhaust concentrations can cause several health issues. Some of the health diseases caused by DPM exposure are respiratory diseases, reduced lung capacity, heart disease, and lung cancer (National Research Council. 1981, Mine Safety. 2005). In addition, NIOSH regards diesel exhaust as “potential carcinogen” (Centers for Disease Control 1988) and IARC has declared that “diesel engine exhaust is carcinogenic to humans” (IARC 2012). NIOSH has also declared that the reductions in DPM exposure would reduce cancer risks (Centers for Disease Control 1988)."

Jan 1, 2016

By Malcolm J. McPherson, Daniel J. Brunner

This paper describes an experiment conducted to investigate the law of airflow on a mechanized longwall coal face. Background to the Square Law relating frictional pressure drop and airflow is presented and deviations from this Law are discussed. The procedures used to investigate the Law of Airflow for the longwall are described and the results are presented. The results verify the Square Law relationship for airflow along a mechanized longwall face.

Jan 1, 1987

By B. DANIEL MARJAVAARA, I. A. SOFIA LARSSON, ANNA-LENA LJUNG

The flow field and coal combustion process in a pilot-scale iron ore pelletizing kiln is simulated using a computational fluid dynamics (CFD) model. The objective of the work is to investigate how the thermal effects from the flame affect the flow field. As expected, the combustion process with the resulting temperature rise and volume expansion leads to an increase of the velocity in the kiln. Apart from that, the overall flow field looks similar regardless of whether combustion is present or not. The flow field though affects the combustion process by controlling the mixing rates of fuel and air, governing the flame propagation. This shows the importance of correctly predicting the flow field in this type of kiln, with a large amount of process gas circulating, in order to optimize the combustion process. The results also justify the use of down-scaled, geometrically similar, water models to investigate kiln aerodynamics in general and mixing properties in particular. Even if the heat release from the flame is neglected, valuable conclusions regarding the flow field can still be drawn.

Apr 20, 2021