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By Rasik H. Raythatha

Calcium carbonate is perhaps the most widely used mineral in the world. With total consumption of all calcium carbonate exceeding over 25 million tom per year, within this class of filler, a relatively smaller segment of precipitated calcium carbonates (PCC) is often misunderstood as a commodity product and bundled in the same category as ground calcium carbonate. However, each material has a distinctly digerent role and characteristics. Precipitated calcium carbonates are used to influence specific performance in a specific application whereas ground calcium carbonate is used primarily to reduce cost in many applications. In this paper, attempts are made to demonstrate the role of nano-fine-PCC in improving shear-thinning characteristics of common and specialized sealants and automotive underbody coating and how such "nano-particle" cal- cium carbonate properties can be exploited to process PVC plastics while reducing overall cost. We also review the role of precipitated calcium carbonate as "nano" material and why it must be viewed as a specialty additive.

Jan 1, 2003

By Saul Escalara

Data on sulfonate adsorption by silicate minerals are very scarce in the literatures. Perhaps the only comprehensive paper written on the topic was done by Fuerstenau and Bhappu (1); this work dealt exclusively with quartz but included many important suggestions as to the form and nature of the hydroxy-sulfonate species of some cations formed during the conditioning step and their effect on the flotation response of quartz. Another paper by the same authors (2) contains additional data on the role of hydrolysis in sulfonate flotation of beryl. As postulated by Fuerstenau and Bhappu, a solid form of cationic sulfonate functions as the collecting species to produce flotation of quartz and beryl. According to the authors, the solid compound is a hydroxy-sulfonate of a given cation, where the hydrogen of the hydroxyl part provides a means for bonding of the species to the mineral surface; thus, the presence of hydroxyl in the neutral precipitated compound is of primary importance to produce flotation. Although the preceding examples illustrate the effect of a sulfonate collector in silicate systems other than plagioclases, they are important as examples of processes of hydroxy-sulfonate complex formation. Since the plagioclase minerals con¬tain Ca(II) and Al(III) cations, which are very reactive in sulfonate media (1), the formation of hydroxy-sulfonate compounds with these cations released from the solid phase may well prove to be the cause for their flotation.

Jan 1, 1973

By James C. Bradbury

Tripoli is a naturally occurring, finely divided form of silica found chiefly in midwestern and southeastern states and used commercially in fillers and abrasives. The name comes from the location of a silica deposit in North Africa and was applied in the latter part of the 19th century to similar material near Seneca, Missouri. Subsequently, the North African material was found to be diatomite, composed of siliceous skeletons of microscopic marine plants called diatoms, and the material's name was changed to tripolite. The name, tripoli, remained with the Missouri silica, which is inorganic in origin, and tripoli is now used to designate all naturally occurring silica that is similar in characteristics and origin to the Missouri material. Just to confuse things further, in commercial trade tripoli usually designates silica from the Missouri-Oklahoma field, whereas silica from southern Illinois, the other major producing area, is called amorphous silica. Each term, however, may be used commercially for any material, regardless of place of origin that has the characteristics or uses ascribed to material from either major producing area. For example, Engineering and Mining Journal routinely lists under "tripoli," prices "f.o.b. Elco, I11." and "f.o.b. Seneca, Mo. and Rogers, Ark.", and under "silica, amorphous," prices "f.o.b. I11 and "f.o.b. Dierks, Ark." "Soft silica" is another term that has been applied to tripoli from Illinois, west central Arkansas, and Tennessee, presumably to distinguish it from the more compact Missouri material. It has also been used in the ceramic trade to distinguish tripoli from "hard" silica, or silica flour, which is produced by pulverizing silica sand. Tripoli is produced mainly in extreme southwestern Illinois, in the Missouri-Oklahoma district in Newton County, Missouri, and Ottawa County, Oklahoma; and in the novaculite belt of west central Arkansas. Some tripoli is produced for local and specialized uses near Austin, Texas.

Jan 1, 1980

By J. E. Gray

Before specifications are discussed it may be well to define the term "Mineral Aggregates." Professor K. B. Woods (1) defined "Mineral Aggregate--An aggregation of sand, gravel, crushed stone, slag, or other material of mineral composition used in combination with a binding medium to form bituminous and portland cement concrete, macadam, mastic, mortar, plaster, etc., or alone as in railroad ballast, filter beds, and various manufacturing processes, such as fluxing, etc. " This definition is too all inclusive for the purposes of this paper; therefore, this discussion will be confined to specifications for natural aggregates which means sand and gravel and crushed stone, and limited primarily to coarse aggregate which is aggregate larger than one-quarter inch in size. To the uninitiated, this may seem to be a very limited subject on an unimportant material. However, aggregates are essential in all types of construction. The tonnage and value of these two aggregates produced in the United States during 1959 as reported by the Bureau of Mines were as follows: Sand and Gravel 729,895,000 tons valued at $728,527,000 Crushed stone 581,721,000 tons valued at $824,411,000

Jan 1, 1961

By Barry A. Hillman

Respirable (PM-10) crystalline silica is regulated by the State of California as a carcinogen. The risk-management of this material by the State exemplifies the inherent problems in the development of regulations based on current risk-assessment practices. The influence of extremely conservative risk-assessment and risk-management can be expressed in economic impacts including the increased cost of production, reduced competition, increased prices, reduced employment and redistribution of income. This paper attempts to contrast theoretical risk- assessment and risk-management with current application using crystalline silica as an example. Based on health information pertaining to silica, the paper examines federal and State of California regulatory and public policy positions. Using current risk factors and empirical data for the Central Valley of California, the projected incidence of lung cancer in humans is examined. While such an analysis would project an extremely high incidence of lung cancer as well as silicosis, not a single case of either lung impairment has been recorded within the study area or throughout the world in the general population. This suggests that sound guidelines for the analysis of scientific information have given way to the assumption that virtually any information representing a substance as a carcinogen is to be considered valid with little or no qualification.

Jan 1, 1992

By Alen Shibu Joseph, Arvind Rajnarayan Singh, Mudila Dhanunjaya Rao, Kamalesh K. Singh

In this article, the cementation of major impurities from zinc sulphate leach solution by the addition of zinc dust was studied by considering different parameters including time, mesh size, and percentage of excess zinc dust. The output obtained from various experiments was utilized for the design of experiments. A multi-level categorical factorial design with a quadratic model was employed during this study. Results were predicted to minimize the concentration of impurity metals in the solution by altering the parameters. Furthermore, these predicted results were validated by performing another experiment. Successfully, it showed that the predicted and experimental data values were close to each other. The predicted optimized values were 40 min, 100% excess zinc dust, and 300 mesh size for copper; 42 min, 100% excess zinc dust, and 300 mesh size for cobalt; 37 min, 100% excess zinc dust, and 300 mesh size for cadmium; and 34 min, 100% excess zinc dust, and 300 mesh size zinc dust for nickel. At these optimized values, the experimental results showed 99.99%, 55.7%, 99.6%, and 76.6% cementation efficiencies for copper, cobalt, cadmium, and nickel respectively. The statistical design of experiments for the effective cementation of impurities corroborates the economic feasibility of optimizing parameters for the proposed process.

Jul 18, 2022

By Y. Kurokawa, R. Kurosawa, I. Iwata, I. Fukuoka, N. Sugita

INTRODUCTION The Ningyo-toge Mine is located in the western part of Honshu, about 800 km from Tokyo. Since the discovery of uranium ore deposit at Ningyo-toge in 1955, different kinds of mining and milling tests have been carried out. A new pilot plant of milling and UF6 conversion is also being under construction. Operations are scheduled to start by the end of this year. In 1979, the uranium enrichment pilot plant was constructed at Ningyo-toge and test operations have started. Thus, the Ningyo-toge area is assigned to undertake the Research and Development of the upstream of the nuclear fuel cycle in Japan. PNC has been strengthening its security measures more than ever. This paper will focus on the disposal of wasted material, especially on the disposal of heap leaching residue, in Japan. URANIUM ORE DEPOSITS The uranium of the Ningyo-toge Mine is characterized genetically by epigenetic sedimentary type deposits. They occur in the host rock of Neogene tertiary fluviatile conglomerates and sandstones which unconformably overlies the Mesozoic-Palaeogene granitic basement covered with lucustrine deposits and volcanic ejecta. More than 12 deposits have been found over the area of approximately 160 km2, and distribution of the deposits are strongly controlled by the so-called channel structure, probably remnants of paleo-streams on the denudation surface of the underlying grantic basement. Each ore body has different shape and dimension respectively, but about 2-3 meters thickness with the average grade of 0.05-0.2% U308 is common feature of the ore bodies. The ore is soft and loose, and it is composed of common rock forming minerals of allogenic origin and their altered products. The chemical composition of the ore depends on the constituents of the country rocks or the pebbles. A primary mineral, ningyoite and secondary mineral, autunite are major ore minerals, although three primary tetravalent minerals and thirteen secondary hexavalent minerals have also been detected. MINING EXPERIMENT Since 1959, various types of underground mining tests have been carried out at Ningyo-toge Mine. The room and pillar method was safe and simple, although the uranium ore recovery was below 70%. After experiment of the retreating long-wall method and slicing mining method, it was found that the modified long wall method was the most appropriate for the underground mining of the Ningyo-toge uranium deposits. This method was completed successfully to increase efficiency up to 2 or 3 times, as compared to conventional methods. MILLING EXPERIMENT In 1964, a small test mill was constructed at Ningyo-toge, and a milling experiment using the Ningyo-toge uranium ore was started. Re-modelling of equipments and improvement of the process lead to the establishment of the technique of the so-called wet process, and produce UF4 directly from the ore. The flow diagram is shown in Fig. 1.

Jan 1, 1981

By E. Kurt

The field of percussion rock drilling is subdivided into two areas of application; that which takes place on the surface and that which takes place underground. Surface drills are used in quarrying, highway construction, and maintenance work; underground equipment in mining and tunneling work. Two basic principles are involved in the operation of all percussion drills. First, the principle that reciprocates the impacting piston and second, the principle that causes the drill steel and bit to rotate. The back and forth motion of the piston is accomplished by a self-acting automatic valve that admits air alternately to each end of the piston (Figure 1). Drill steel and bit rotation is imparted by an integral ratchet mechanism (Figure 2) in the so-called "rifle bar" machines (Figure 1) or by a separate pneumatic motor in "independent rotation" drills (Figure 3). While rock drills are subject to all kinds of physical and operational abuse, they are most sensitive to faulty lubrication. Proper lubrication is the single most important factor in the longevity of a percussion drill.

Jan 1, 1970

By John W. King

reserves are exploring to increase them.. Uranium exploration projects are known to be active or planned also in Guayana, Colombia, Ecuador, Peru, Chile, Bolivia, and Uruguay in South America; in the UAR, Nigeria, Angola, Mozambique, Malawi, Kenya, and Somali in Africa; and in Greece, Iran, Pakistan., Indonesia, and New Zealand. The above list, to which several might be added makes a total of at least 43 nations actively interested in exploration for nuclear raw materials. As we consider the distribution of the world's uranium resources, it is interesting to note that roughly one third of the total occurs in deposits that are economically dependant upon another product. The very large reserves of South Africa could not be produced for uranium alone, but gold has carried a sufficient part of the total cost that uranium can be recovered profitably. Approximately 40 percent of the US reserves, or 120,000 tons, are estimated as by-product recovery from porphyry copper and phosphate operations, but these reserves are not presently in production. The remaining two thirds of the world's uranium reserves have been sought, developed, and produced primarily for their uranium content. Those deposits are estimated to contain 613,000 tons of uranium oxide recoverable at less than $10 per pound. Nearly half of that uranium occurs in unmetamorphosed sandstone hosts, mostly of late Phanerozoic age--the Colorado Plateau type. About 30 percent is contained in the quartz pebble conglomerates of southern Ontario, Canada, and 20 percent is in magmatic-related deposits--veins, contact deposits, mineralized breccias, etc.

Jan 1, 1969

By M. J. Virnig, Marc Le Vier, Rong Yu Wan, Jan D. Miller

Although most gold production from primary resources is achieved by cyanidation, many research activities have focused on alternative processes using noncyanide lixiviants. Such research has been prompted by environmental concerns and problems associated with the processing of refractory gold ores. Numerous research projects have been conducted to search for a noncyanide hydrometallurgical process for gold extraction. In this paper, a technical review of gold recovery from noncyanide solutions is presented, and new results are reported. Gold recovery techniques that are considered include activated carbon adsorption, cementation, solvent extraction, ion exchange, and reduction-precipitation.

Jan 1, 1993

By D. C. Seidel

The role of surface charge in soluble salt flotation, which was developed in Part 1, is extended to relate the theory to the specific phenomena of KCI- NaCl separations. Temperature-collector solubility relationships, metal ion activation, and particle size effects are discussed.

Jan 1, 1967

By M. A. Trevits

The explosion hazard presented by methane gas in coal is confronted daily in the mining industry. Research has developed several viable methods for gas control in addition to conventional dilution by ventilation. Such methods include the drilling of horizontal or cross-measure boreholes from a mine opening and vertical boreholes hydraulically stimulated in advance of mining or for gob gas drainage. The long-term production history of five gas drainage installations was studied. Three installations were completed in the Pittsburgh Coalbed: two in West Virginia and one in Pennsylvania. The remaining installations were completed in the Mary Lee Coalbed in Alabama and the Sunnyside Coalbed in Utah. The types of drainage methods utilized included horizontal and vertical boreholes. The length of production studied ranged from 860 days to 36 years. The cumulative production from the five sites was in excess of 155 Mm3, representing a significant volume of gas.

Jan 1, 1985

By J. A. Herbst

Ball mill grinding circuits can be subject to upsets that arise from variable characteristics of the feed ore. These upsets are transients in critical circuit variables such as ball mill mass holdup, circulating load, sump level, cyclone efficiency and product particle size. They may occur frequently so that the operation is continuously fluctuating or they may be of such magnitude that some of the equipment is overloaded, resulting in shutdown, or an undesirable product particle size. The feed ore characteristics that influence ball mill circuit behavior in this manner include the grindability of the ore, the eventual transport characteristics of the ore in the mills and the feed ore size distribution. Control strategies for grinding circuits using conventional proportional-integral (PI) control have limitations to their effectiveness in controlling against feed ore disturbances. The first of these are the interactive nature of two or more control loops on a single circuit. Under some circumstances they begin to fight each other, increasing control error and settling time. PI control loop gain constants can be tuned to give best response for some set of conditions but once these change, as they would with a change in the feed ore, they are no longer the "best" ones (Shinsky, 1967). Due to these limitations, alternatives to conventional PI control strategies have been investigated for grinding as well as other mineral processing operations. These alternatives, all computer-based, include self tuning regulators, decoupling control and optimal control (Herbst and Bascur, 1983).

Jan 1, 1984

It is well established that the results of emulsion flotation in which water-insoluble oily collectors are utilized depend critically on the emulsification of the collector and on its conditioning with the pulp prior to flotation. The flotation tests carried out with magnesite and fluorite using sodium oleate as collector confirmed acidic and alkaline ranges of good flotation. While the flotation results in the acidic solutions depend strongly on the conditioning time and can be very much improved when longer conditioning times are utilized, the tests in the alkaline environment do not exhibit any significant dependence on conditioning. The results obtained with sodium salts of myristic and lauric acids confirm these findings. The observed effects provide additional evidence for the role of the colloidal species which appear in the acidic solutions of weak electrolyte type surfactants, such as fatty acids. The flotation properties of sodium oleate in the pH region in which it appears in the form of oleic acid droplets are mainly determined by the properties of such droplets. The flotation in this pH region closely resembles an emulsion flotation.

Jan 1, 1993

By Lloyd C. Venburg

Analytical and computer models are used to evaluate information obtained for the design and development of mine water control systems. Geologic, hydrologic, geophysical, biological, and chemical data must be gathered for use during all stages of mine development. Models allow the geohydrologist to use these data to predict the amount of ground-water inflow, the impact of dewatering and stream diversion on the hydrologic regime, equipment needs, and dewatering schedules. Stratigraphic and lithologic changes, faults, recharge and discharge areas, and aquifer parameters should be incorporated into the model to design and develop an effective mine water control system.

Jan 1, 1982

By M. P. Fahey

A significant amount of silca is recovered in the rougher stage of anionic flotation of Florida apatite. This recovery, in the past, has been attributed to both entrainment and cation activated flotation. This study shows that by using a transport factor, it is possible to determine the contribution of each mechanism towards silica recovery. Further, it is shown that the concentration of cations in the conditioning water significantly affects both the amount of silica recovered due to entrainment and true flotation. Further confirmation of this phenomenon was obtained by Ca++ doping of the conditioning water and by using a sodium silicate depressant.

Jan 1, 1996

By S. Middlemiss

The Indentation Fracture technique is being developed as a tool for use in comminution and mineral liberation analysis. Fracture toughness measurements for a number of mineralogical materials were made and comparisons were drawn between these and properties measured with the Ultrafast Load Cell drop weight apparatus. The technique has also been used as a probe to quantify differences in fracture properties at different areas in the microstructure of a material. In both a Utah limestone and a South African quartzite, material near a grain boundary fractures very differently to that in the bulk. Ongoing work is ultimately aimed at producing a comprehensive fracture model for a multi-mineral system based on its micro-fracture characteristics.

Jan 1, 1994

By J. R. Nawrot

Reclamation of potentially acid producing coal processing waste requires a 4-foot cover, and/or treatment to allow vegetation establishment. If not planned properly, soil covering alone does not prevent refuse acidification or formation of acid seeps. Adequate neutralization enhancement prior to soil covering can maintain an alkaline environment in the soil refuse interface and prevent acidification. Direct vegetation establishment using only limestone amendment (without soil cover) can successfully reclaim aged and weathered fine (Blurry) and coarse (gob) refuse if adequate neutralization treatment is provided for the oxidized surface zone. Acid seeps, representing an "after-the-fact" verification of an imbalance of acid-base equilibrium may also be corrected using upslope alkaline recharge techniques. Concentrated alkaline recharge pools have been constructed above previously soil covered acid gob at the Peabody Will Scarlet Mine to abate acid seeps. Preliminary monitoring results (1989-1992) from a concentrated alkaline recharge pool demonstration project in the Pit 4 area of the Will Scarlet Mine have documented a 50 to 80 percent reduction in acidity in the principal recharge pool groundwater zone. A 22% reduction in acidity has occurred in the primary seeps located downslope from the alkaline recharge pools. The initial improvements in water quality are seen as a positive indication that groundwater acidity will decrease further and amelioration of the acid seep will continue.

Jan 1, 1993

By Joseph Kuti

Longwall mining is the term used for the underground extraction of a wide and deep panel of coal. Such a panel may be blocked out by one or more entries on either side ("head" and "tail") of a longwall face. If all the entries are pre-driven, the panel extraction is termed longwall retreat mining. With one exception, all the longwall faces in the United States are of this type. (1) prior to the general decline in the rates of production with Continuous Miners, the development of the multiple entries generally kept ahead of the longwall extraction rate. This is no longer the case: longwall extraction rates far exceed the rate of development. In addition to this problem, in newly established mines, the development of a haulage and bleeder system based on multiple entries results in a lead-time of three years or more before longwall mining can be applied. This is one reason why earlier projections and much of the optimism attached to longwall mining as a principal "savior" in the energy crisis should be viewed with some caution.

Jan 1, 1978

By D. J. Torpy

With copper at its host depressed price in several years, producers are looking at every opportunity to cut costs in order to continue operating. Some of the measures that have been applied by different companies include reduction in manpower, high grading, and in some cases partial shutdowns. The most beneficial cost cutting measure implemented by Southern Peru Copper Corporation was to steepen the slope of the final pit limit from a conservative 37 degrees to an average of 48 degrees. By doing so, substantial cash outlays were saved. Southern Peru Copper Corporation (SPCC) operates two open pit copper mines and concentrators in the southern part of Peru, about 150 kilometers from the Chilean bordar. The Toquepala Mine went into production in 1960 and the Cuajone Mine in 1976. Both mines use shovel, truck and train operations. The trains, which haul ore to the crusher or waste to the dumps, are loaded either directly by shovels or by a transfer system. The Toquepala Concentrator treats an average of 43,000 tons per day and the Cuajone Concentrator an average of 55,000 tons per day. Concentrates are shipped via a 200 kilometer railroad to the port city of Ilo where the SPCC smelter is located. The annual production in the smelter from both mines is 290,000 tons of blister copper.

Jan 1, 1987