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By R. E. Lund

The design, operation, and performance of an integrated pilot plant for recovering zinc and copper from a complex sulfide ore are described. Metallurgical processing comprised selective sulfate roasting in a fluid bed, leaching in a weak sulfuring acid solution, recovering copper by cementation with scrap iron, air oxidation to remove soluble iron, more-or-less conventional purification for removal of impurities deleterious to zinc electrolysis, recovering zinc by electrolyzing solutions, and recycling spent electrolyte to the sulfating roaster. The effects of several feed preparation and roasting variables on the sulfation response of zinc, copper, and iron are set forth, together with the electrolyzing characteristics of the zinc solutions.

Jan 1, 1962

By Fathi Habashi

SELENIUM AND tellurium are by-products of electrolytic copper refining. Copper anodes contain 0.01-0.2 % Se and up to 0.04 % Te; during electrolysis these deposit as a slime at the bottom of the cell. Such slimes contain 2-15% Se and 0.5-8 % Te, as selenides and tellurides of gold, silver, and copper. The following compounds have been identified in the slimes: (Ag, Au)Te2, Ag2Se, Ag2Te, CuAgSe, Cu2Se, Cu2Te. Anodic slimes from copper electro¬lytic refining are a grayish black powder, minus 200 mesh. When this complex mixture is decomposed in an acid medium, elemental selenium and tellurium can be obtained, while in an alkaline medium, both metals go into solution. Acid leaching The slime is charged in acid digesters of 800-900 lb capacity, heated to 260°C with 78 % H2SO4, for 8-12 hr. During digestion the following reactions take place:

Jan 1, 1970

By I. Raposo, I. Moreno-Ventas, A. Palma, M. J. Díaz, M. Vázquez

The oxidative degradation kinetics of chalcopyrite have been studied by thermogravimetric analysis (TGA). The obtained data are necessary for the kinetic description of the flash fusion process, which can contribute to the optimization of the smelting process in copper extractive metallurgy. Activation energy (Ea) evolutions of the involved processes have been determined by several isoconversional methods; in this sense, the chalcopyrite oxidation processes could be adequately described, among studied models (E1641–16, Ozawa–Flynn–Wall, Kissinger–Akahira–Sunose and Friedman), by the Kissinger–Akahira– Sunose kinetic model. Using this method, Ea and A values are found to be very dependent on the conversion. Under lower conversion levels, higher Ea and A values have been calculated with respect to that found for medium and higher conversion levels.

By H. E. M. N. Moursy, M. N. Ahmad, C. R. Holland, G. M. Walker, R. D. Chandler

This work describes the effect of process parameters on the acidulation of Moroccan phosphate rock using nitric acid, i.e., the nitro-phosphate process. A series of bench scale experiments were conducted, using a stirred tank reactor (STR) system, to investigate the chemical reactions involved and optimum conditions for the formation of nitro-phosphate fertilizer. The effect of reaction time, temperature, mixing speed, acidulation ratio, and acid concentration were investigated, and were found to have an effect on the dissolution of P2O5 from the phosphate rock, using nitric acid. An increase in nitric acid concentration resulted in an increase in P2O5 dissolution, however, the dissolution was also found to be a function of acidulation ratio. A nitric acid phosphate rock ratio of 4:l ensured 90% dissolution for nitric acid concentration > 30%.

Jan 1, 2002

By John A. Herbst, Kuang Y. Lee

Coarse particle size measurement is essential for the automatic control of a size reduction process like crushing or SAG milling in order to achieve optimal process performance. However, the on-line size measurement of coarse material is not easily obtained due to the problems of material handling and sample statistics. A technique based on advanced image analysis and quantitative stereology has been successfully developed and tested in a pilot scale setting. The chord length distribution of coarse particles on a moving conveyor was measured with an image analyzer and then transformed to the mesh size distribution with a stereological model and a special numerical method. Some test results as well as the technique's industrial suitability and limitations of this method are also discussed.

Jan 1, 1992

By R. L. Wiegel, G. R. Oswald

The processors of Florida phosphate rock face constraints similar to those of other mineral operations--leaner ore, more complex treatment schemes and a product which sells for a penny a pound. IMC Fertilizer is a dominant producer in this market with its current operation of five processing plants. An emphasis by their management in maintaining and improving plant performance has continued unabated for some 15 years. This has resulted in a commitment to the importance of routine automatic sampling of product and in process streams, the generation of reliable assay and size distribution data, the accurate measurement of process flows, and the computerized "rendering" of this information into weekly and monthly material balances which provide consistent measures of process performance. In addition, there has been a parallel program to monitor and improve the performance of flotation reagents and to evaluate process modifications or changes in equipment. This paper will describe the evaluation techniques that have evolved over this period and indicate how the historical data base is used to identify plant problems early and help in their solution.

Jan 1, 1991

By Dave G. Osborne

With the growing exportation of coal from North America to the Pacific Rim countries and Europe, has come an increasing awareness of the need to determine economically optimized amounts of incombustibles (ash and moisture contents) for the shipped product. Despite the fact that demand bas caused a steady improvement in selling price, particularly for thermal coals, growing production and transportation costs have compelled producers to keep a sharp eye open for ways and means of minimizing the latter since this probably represents the greatest single potential for making savings. Consequently the Coal Industry has become acutely aware of the economic ramifications of eliminating moisture in particular, thereby producing further saving in the cost of transportation of product from the mine to the consumer. There is, however, a lower limit to which dewatering or drying can be taken and this relates to dustiness which is a function of the characteristics of the coal and the methods used for handling and storage during trans-shipment. Overdrying can lead to serious dust losses and difficulties in handling particularly if the coal contains a large proportion of fines. The ways and means for achieving this "happy medium" of optimization in moisture removal are seemingly undergoing gradual modification largely assisted by the following factors. a) Improvement in effectiveness of coal dewatering and drying equipment. b) Improvement in operational availability and utilization of the equipment. c) The development of surfactants, polymer flocculants and other agents which in many cases can be almost tailor made to suit specific applications.

Jan 1, 1982

By P. R. Taylor

A cyclone reactor system for the partial reduction and melting of taconite concentrate fines has been engineered, designed and operated. A non-transferred arc plasma torch was employed as a heat source. Taconite fines, carbon monoxide, and carbon dioxide were fed axially into the reactor, while the plasma gas was introduced tangentially into the cyclone. The average reactor temperature was maintained at above 1673 K (1400 C), and reduction experiments were performed under various conditions. The influence of the following parameters on the reduction of taconite was investigated: carbon monoxide to carbon dioxide inlet feed ratio, carbon monoxide inlet partial pressure, and average reactor temperature. The interactions of the graphite lining with carbon dioxide and taconite were also studied.

Jan 1, 1993

By Edward R. Torak

The Ohio Coal Testing and Development Research Facility (OCTAD) was commissioned in 1992 by the Ohio Coal Development Office and the Ohio Power Company to support evolving process technologies that will lead to increased environ- mentally sound use of coal. OCTAD is equipped with advanced physical concentration devices and processes capable of beneficiating coal to levels beyond conventional practice. The first task of OCTAD operators was to test the cleanability of the Meigs Creek Seam Coal in advanced circuitry and compare the results to conventional cleaning levels. In testing the seams, OCTAD circuitry was configured to produce middlings on the coarse and intermediate size fractions. These middlings were subsequently crushed to a finer size (28M x 0) and subjected to cleaning in fine heavy-media cyclones and advanced froth flotation circuitry. Nearly thirty-six full-scale production runs at various operating conditions were completed during the campaign. The results of the test program are examined in this paper.

Jan 1, 1995

By Roderick G. Eggert, John E. Tilton

During much of the 1970s and 1980s, world metal consumption grew more slowly than during the 19505 and 1960s. The slowdown contributed to surplus capacity and low real prices because actual consumption was consistently less than expected as new mining and mineral processing capacity came on stream. Over the last year or so, however, world metal consumption has picked up noticeably, raising the question, Has metal demand returned to the long-run growth rates more typical of the 1950s and 1960s than of the 1970s and 1980s? This paper examines this possibility and, more generally, assesses the factors that will shape demand for the major metals over the longer term. TRENDS IN METAL CONSUMPTION The extent to which metal consumption has recaptured the brisk growth rates typical of the 1950s, 1960s, and early 1970s is shown in Figure 1. This figure traces the consumption of crude steel, primary aluminum, refined copper, refined lead, and refined zinc between 1960 and 1987 for the western world, consisting of the OECD countries (including the United States), and the developing countries. Consumption increased in 1987 for all five metals, and preliminary data for the first six months of 1988 suggest even more substantial increases, at least for the United States (U.S. Bureau of Mines, 1988). However, Figure 1 also shows that the recent increases in consumption are not untypical of similar surges during earlier periods of economic expansion and thus may reflect only cyclical or temporary factors. In short, the available data are unable to provide a clear indication of whether recent increases in metal consumption reflect the beginning of a new era of faster growth or simply a cyclical and temporary upturn associated with the expansionary phase of the business cycle. Consequently, to pursue this issue, we are forced to examine the underlying forces that will shape metal demand trends over the next decade. The approach we have taken involves two steps. The first examines the prospects for overall economic growth. The expectation is, the faster the economy expands, the faster the production of metal-containing goods grows.2

Jan 1, 1989

By Duane A. Smith

Introduction From the days of the Spanish in the eighteenth century, Colorado's San Juan mining district has attracted miners and public interest. The Spanish left behind names - San Juans, La Plata, Animas, legends of lost mines, and the remains of a few scattered mining operations. They came, but did not stay. Again in 1860-61, as a spinoff of the Pike's Peak gold rush, prospectors climbed the mountains and descended into the canyons searching for gold. They found some, not enough to convince them to remain and confront the isolation, often hostile environment and the Utes, who rightfully felt this to be their home. Not until the 1870s did miners come to stay. In their wake little camps grew in the high valleys and squeezed into narrow canyons. Nowhere else in Colorado were there more rugged mountains, a higher average elevation, nor a climate that one old Swede said was "three months of mighty late fall and nine months of winter." The San Juans proved eventually to be a mineral treasure chest. At the moment, however, the prospectors sought gold. Then they discovered silver deposits and the first rush was on. It got started just in time to be completely overcome by the Leadville excitement. At Leadville, investors almost fell over themselves to buy claims and stock in the hopes of becoming another millionaire like Leadville's own Horace Tabor. The San Juaners could only look from the sidelines and speculate how it might have been had fate been kinder. Fate was seldom kind, as these pioneers quickly discovered. From the mid-1870s on, the San Juaners wrestled with some major problems. And the fate of their district rode in the balance. The problems they faced were similar to those of other Colorado districts, compounded by their geographic isolation. Every mining district needed the best transportation system available, experienced investors combined with sound investment, and mineral reserves to develop. The San Juans offered the last in abundance. It was hoped the first two would appear. Railroads - much needed transportation link Nothing was more desired than railroad connections, the penultimate nineteenth century form of transportation. Colorado's own, the Denver & Rio Grande, resolved the issue with its mountain-hugging narrow gauge. As early as the mid-1870s, the D&RG dreamed of tapping this potentially lucrative market in southwestern Colorado. A national economic depression and then the Leadville silver excitement prevented immediate construction. Not until 1879-80 did survey crews start work.

Jan 2, 1988

By J. D. Miller

"Bastnaesite is one of the important mineral resources for the production of rare earth materials, and it is typically associated with calcite and quartz as gangue minerals. Fatty acid or hydroxamic acid are recommended collectors for bastnaesite flotation. In this research, potassium lauryl phosphate was expected to provide a stronger flotation response for bastnaesite than for the calcite and quartz gangue minerals. Using potassium lauryl phosphate as collector, the results of captive bubble contact angle measurements, zeta potential determinations and microflotation experiments for bastnaesite, calcite and quartz are reported. Greater selectivity for bastnaesite was achieved using potassium lauryl phosphate than using octyl hydroxamate as collector. These results indicate that potassium lauryl phosphate might be a promising collector in the flotation of bastnaesite ores. The computation results of universal force field (UFF) interaction energies for the mineral-reagent interactions are also reported and were found to correlate well with the experimental microflotation results.IntroductionBastnaesite ((Ce,La)FCO3) belongs to the mineral class of semisoluble salt minerals, whose characteristics include ionic bonding and limited solubility in water. Bastnaesite, for the most part, contains the cerium subgroup or the lighter rare earth elements (Zhou et al., 2014). The Mountain Pass deposit in California in the United States and the Bayan Obo deposit in Mongolia in China are the two major deposits of bastnaesite (Azizi et al., 2016; Satur et al., 2016). Calcite and/ or quartz are common gangue minerals in these and many other rare earth deposits (Jordens et al., 2014)"

Jan 1, 2017

By Jeff Easton, J Johnson, D. Foot

The Mina Santa Rosa mine in Panama was the victim of a mine closure 24 years ago that left the community in dire straits. The mine showed the potential resources of greater than 1M ounces of gold and 4.5M ounces of silver. Veragold Mining Company decided to reopen the mine and address all the issues that were involved in the startup of an historic mine. This paper provides methods to restore the community trust, provide a transparent process, and develop an environmentally sound flowsheet. Immense scrutiny surrounded the Tailings Storage Facility, and the company developed a plan focused on paste thickening and surface stacking to eliminate the need for a conventional tailings’ facility. Paste thickener principles and benefits are also provided.

Feb 1, 2024

By I. Ward, E. Milosavljevic, M. Botz

"The silver nitrate titration method is a rapid and acceptably accurate means of analyzing for cyanide in leach solutions that contain primarily free cyanide. However, in leach solutions containing elevated levels of copper, the titrimetric method overestimates the concentration of free cyanide and underestimates the concentration of weak and dissociable (WAD) cyanide. The authors have developed a modified potentiometric (MP) titration method for determining WAD cyanide that overcomes issues associated with high copper levels in solution. The new MP-WAD method involves addition of a chemical ligand to the sample prior to silver nitrate titration to release cyanide bound to copper. Once released from copper, cyanide in solution is no longer affected by the presence of copper, and titration results are quantitative rather than empirical. In multiple laboratory trials with synthetic solutions and complex actual leach solutions, analytical results obtained with the new MP-WAD method were found to be within about ±5% of analyses obtained with the USEPA OIA-1677 WAD cyanide analytical method.IntroductionThe silver nitrate titration method is widely used to estimate the concentration of cyanide in leach solution for purposes of cyanidation process control. Cyanide determined by silver nitrate titration is commonly referred to as “free” cyanide, but frequently should be referred to as “titratable” cyanide. By definition, free cyanide is the sum of the concentrations of aqueous hydrogen cyanide HCN(aq) and the cyanide anion CN- (ASTM, 2010). Titration will only yield a reasonably accurate measurement of free cyanide when metal-cyanide complex concentrations (e.g., cadmium, copper, mercury, nickel, silver and zinc) in solution are low. In other words, titration will only yield a reasonably accurate measurement of free cyanide if the solution primarily contains free cyanide."

Jan 1, 2015

By J. C. Motz

The advantages of producing a fine mill feed have been recognized for many years. The extent to which fine crushing can be carried out will vary and depends on the ore characteristics, plant and crusher design. Unfortunately, the ore characteristics are generally beyond our control, so the concentration of effort lies primarily on the plant arrangement, equipment design and operation Where fine crushing should stop and grinding begin is controversial and is influenced greatly by personal opinions and experiences. Often, this break point will be different if consideration is being given to a new plant in comparison to a modest expansion. Most new plant designs employ the largest and most efficient equipment. The modification of existing plants becomes more complex because of the space requirements and the related equipment already in operation. Fine crushing is, of course, a relative term. Obtaining a final crusher product of minus 3/4" is commonplace today and can occasionally be obtained in an open circuit final crushing stage.

Jan 1, 1980

By V. M. Torres

Arapiraca ore deposit has a mixed chalcopyritelbornite mineralogy, with a copper head grade of 0.7%. The reserve size does no allow profitable exploration by grinding/flotation. The technical feasibility of exploring the reserve by heap leaching was studied. Preliminary agitation tests indicated 85% copper recovery. To simulate heap leaching, column tests were performed. The tests included different ore types and acid addition levels. Operating at pH range 1.6-1.8, 67% copper extraction was achieved. Also, it was found an empirical correlation between the operation pH range, copper extraction and acid consumption.

Jan 1, 1996

By L. R. Hossner

Chemical and physical properties of surface soils and overburden materials must be evaluated prior to strip mining activities. This information can be used to assess whether subsurface overburden can be equal in quality to the existing surface soils, especially when these soils are classed as prime farm lands. In Texas, materials from the Carrizo, Calvert Bluff, Simsboro, and Hooper Formations overlie the lignite. The Carrizo Formation consists of thick clean sands with poor water and nutrient retention capabilities. These materials are least suited for placement of the surface of reclaimed land. The oxidized, medium textured overburden from the Calvert Bluff and Simsboro Formations possess adequate water and nutrient properties and are better suited for sustained plant growth. Non-oxidized Calvert Bluff and Hooper sediments generally have acceptable properties for reclamation. However, caution must be exercised in vegetating these materials since they may contain acid forming sulfide minerals.

Jan 1, 1982

By John L. Shafer

Often an in situ leach is the only practical economic method for copper recovery from small low grade oxide deposits. The decision to develop a copper property by an in-situ blast and leach is strongly dependent on ore grade, tonnage, hydrology, and the copper extraction and acid consumption rates. The inherent "leachability" of the ore will in part determine the desired amount of fracturing of the ore deposit by the blast in order to obtain a copper extraction rate that is economical. For the last several years Occidental Research Corporation (ORC), the corporate R&D for Occidental Petroleum has under-taken a modest effort to address the question of "how to best identify and determine the information necessary to predict and control the operation of an in-situ leach for the economic recovery of copper."

Jan 1, 1977

By John A. Dearinger, Fred D. Wright, Robert C. Howell

INTRODUCTION The rock mechanics study of the shortwall mining system at Beth-Elkhorn corporation's Hendrix No. 22 Mine is being conducted under contract with the U.S. Bureau of Mines. The objective of the study is to obtain data on surface subsidence over a portion of the mined area, strata subsidence in the mined area, and underground stress changes and displacements in and near natural support elements of the mining system. This study is currently in progress, and only a portion of the results are being presented at this time. The Hendrix No. 22 Mine is located in the moderately rough mountainous terrain of Letcher County in eastern Kentucky. The nearest mine workings to the shortwall area are approximately 1,900 feet distant. The depth of cover over the mined shortwall area varies from 770 feet at Panel 1 to 170 feet at Panel 5 (Figure 1). The strata in the shortwall area is summarized in the three core logs shown in Figure 2. Hole no. 2 is located in approximately the center of the mined shortwall area (Panel 3, Line C, Figure 1). The coal seam in the shortwall area is approximately 4 feet thick and horizontal, although one major ‘roll’ intersects all panels.

Jan 1, 1977

By Robert C. Dunne, Jeffery P. Vaughan

The Archean ores of Western Australia are in total the largest producers of gold in Australia. In addition to numerous small and medium sized deposits, the province also contains the giant Kalgoorlie Golden Mile deposits. A variety of different gold ore mineralogical associations has lead to the development of a number of different processing routes for both refractory and non-refractory ore types. Intense weathering and lateritization of Archean greenstones in the semi-arid Yilgarn region have resulted in the development of a deeply oxidized profile (60-100m) above most sulphide orebodies. Residual and re-deposited supergene gold within iron oxide/silica gangue of this zone responds well to CIP, CIL, heap and vat leaching techniques. Although gold is easily liberated in principal from oxidized gangue, in practice recoveries are sometimes affected by iron oxide coatings on gold grains, and by clay minerals which can interfere with plant performance. Refractory ore types in the Eastern Goldfields fall into three main categories - pyritic, arsenopyritic and telluride-bearing. Pyritic ores may be either free milling or require roasting. The difference appears to depend largely on whether gold occurs along grain boundaries or fractures, which can be liberated by grinding, or whether gold occurs as inclusions within pyrite grains and therefore cannot be satisfactorily liberated by grinding. Arsenopyrite bearing ores are not well understood and are complicated by what appears to be a variable degree of gold solid solution, in addition to included gold. Gold occurring in complex gold-silver telluride assemblages has traditionally been recovered by roasting in the Eastern Goldfields.

Jan 1, 1987