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By P. F. Ziemkiewicz, A. S. Knox

Large-scale use of CCBs in mine environments involves filling surface and underground coal mines with ash to address hydraulic problems, AMD, backfilling and subsidence. The environmental risk of land filling CCBs is generally evaluated by the Toxic Characteristics Leaching Procedure (TCLP) or the Synthetic Precipitation Leaching Procedure (SPLP). However, there is doubt regarding the applicability of these tests to long-term CCBs leaching behavior in groundwater associated with coal mines. The Mine Water Leaching Procedure (MWLP) was developed to provide a site specific risk assessment tool. The MWL Pprocedure is presented in this paper and compared with TCLP as a study.

Jan 1, 2003

By J. M. Richardson, A. L. Mular

Metallurgical balances are fundamental to the successful design and operation of concentration and dewatering circuits. With computerized balance techniques gaining prominence in recent years, it is essential that engineers understand the basic principles that underlie the new methods, as well as the various applications for design of new plants and analysis of existing operations. This chapter discusses two important types of metallurgical balance: (1) steady-state design (2) operating data adjustment Application of computerized steady- state design balancing is demonstrated through the example of a typical copper concentrator flowsheet. Operating data adjustment to achieve a consistent balance is demonstrated for a typical concentrator operation.

Jan 1, 1986

By M. Z. Mubarok, Z. T. Ichlas, A. T. Sugiarto, K. Sukamto

The use of ozone as an oxidant for the direct leaching of zinc sulfide (sphalerite) concentrate in sulfuric acid medium under atmospheric pressure was explored. The influence of acid concentration, feed gas injection rate, particle size distribution, stirring speed, temperature and slurry density on zinc extraction efficiency was examined. The experimental results showed that the leaching efficiency depends on all of these operating parameters except for stirring speed. It was found that essentially complete dissolution of zinc from the concentrate with the present method can be achieved in only about seven hours under the conditions of sulfuric acid concentration of 2 mol/L, particle size smaller than 74 µm, slurry density of 50 g/L, stirring speed of 420 rpm and feed gas injection rate of 1 L/min at ambient temperature. The experimental results suggest that the dissolution reactions produce independent elemental sulfur that is readily floated and can be easily separated rather than forming a layer on the surface of the reacted particle, as usually observed in a system with ferric-sulfate as oxidizing agent. It was therefore determined that the dissolved ozone play a key role in improving the rate of zinc dissolution from the concentrate. Analysis of the leaching kinetics indicate that the leaching rate follows the shrinking particle model, and the overall dissolution rate of zinc is controlled by a surface reaction.

By R. Hogg, S. Chander

An overview of various physical and interfacial characterization methods for use in mineral processing is presented in this paper. The availability of a large number of characterization techniques and commercial instruments requires that the reliability and limitation of each be carefully examined. The choice of a method may depend upon the manner in which the information is to be used, for example, in development of new processes, plant and process design, plant control, problem solving, etc.

Jan 1, 1987

By Debra W. Struhsacker, Jean Kiel, Jeffrey Thatcher

3.1 INTRODUCTION As heap leach precious metal projects become increasingly common in the United States, federal, state and local regulatory agencies are beginning to take a closer look at the short- and long-term environmental consequences of this recovery technology. From an operator's point of view, there is seemingly a confusing regulatory maze to be navigated and a plethora of permits and approvals to be obtained prior to commissioning a heap leach operation. The degree of difficulty associated with obtaining permits for a heap leach project depends largely upon the state in which the project is located. Permit acquisition is generally easiest in those states most familiar with heap leaching technology. For example, heap leaching is well understood in Nevada, and heap leach operations are relatively easy to permit, although permitting conditions in Nevada have recently become more stringent. However, many states are just beginning to become familiar with heap leach operations. Many of these states such as Idaho, Colorado, South Dakota, Oregon, Montana, Washington and South Carolina are in the process of drafting regulations and establishing guidelines for heap leach projects. In most cases, these regulations specify design and operating criteria as well as reclamation and decommissioning procedures. This chapter provides an overview of the regulatory and permitting aspects of heap leach operations. Permitting requirements for projects developed on federal land are discussed in detail. 'The state and local regulatory atmosphere and permitting requirements for various states are also presented. The chapter concludes with a generic permitting strategy. 3.2 KEY ENVIRONMENTAL CONCERNS The primary concern of most local, state, and federal regulatory agencies is the use, storage and transport of sodium cyanide (NaCn), and potential cyanide contamination of surface and groundwater resources. The toxicity of cyanide to people, fish and wildlife is also an important issue. Unfortunately, in the public eye, cyanide heap leaching has some emotional impacts similar to those associated with radioactivity and uranium mining. This perception and the general lack of understanding of cyanide can lead to unnecessary concern about cyanide contamination, further complicating the regulatory environment.

Jan 1, 1988

By M. SIDDARAJU, Rameshwar Sah, T. Umadevi, K. S. SRIDHARA, M. RAJU, GANESH SHETTY

With the depletion of high-grade iron ore resources, the utilization of existing low-grade iron ores, fines and tailings with effective beneficiation is inevitable to meet the iron and steel industry’s required specifications and demand. JSW Steel Limited is operating a 17-mtpa beneficiation plant at its Vijayanagar site in Bellary in Karnataka, which produces nearly 50 to 54 percent concentrate as sinter-grade fines. The sinter base mix consists of iron ore fines that are smaller than 10 mm, with 41 percent smaller than 0.150 mm; washed ore that is generally smaller than 3 mm and bigger than 0.150 mm, with 3 to 9 percent smaller than 0.150 mm; beneficiation plant concentrate, with 97 percent smaller than 0.150 mm; limestone; dolomite; coke breeze; lime; sinter return fines; direct reduced iron (DRI) fines; and micropellets produced from steel plant waste. Using more washed ore in the sinter base mix affects the sinter quality. Ball formation in the mixing and nodulizing drum is an important step in sinter making and requires sufficient quantity of smaller than 0.150 mm fines. Optimization of fines in the sinter base was carried out by replacing the smaller than 10 mm iron ore fines with washed ore. Size analysis, study of the granulation index (G index) and optimization of moisture with respect to sinter bed permeability were carried out to optimize the proportion of smaller than 0.150 mm fines in the sinter base mix as adhering material. This study explores the optimization of fines in the sinter base mix for ball formation to achieve higher sinter quality and productivity with higher sinter bed permeability.

By G. K. Hoffman

Humate, defined as weathered coal or mud-stone rich in humic acid (HA) and fulvic acid (FA) have been mined, primarily as soil amendments or drilling mud additives, in New Mexico for 15-20 years. The New Mexico humate resource is estimated to be 11 Gt, including weathered coal and organic mudstone. The HA and FA content determines the end-use, therefore a simple and consistent method of measuring organic-acid content was developed. The New Mexico Bureau of Mines and Mineral Resources method is based on repeated alkali leaching and acid precipitation. Precipitates of humate are ashed, with mass balance of solids maintained, to correct for material added during alkali-acid treatment. Analyses of upper coal member, Cleary Coal Member (Menefee Formation) and Fruitland Formation samples from the southeast San Juan Basin show ashing to be important in accurate analysis of FA content. Ash in the total FA fraction averages 70% compared to 2% in HA. The FA in weathered coal and organic mudstone are similar, although HA is significantly higher in the former. As weathering progresses, the FA content of weathered coal increases faster than in organic mudstone because of the greater total organic material in coal.

Jan 1, 1994

By Phillip R. Moyle

Voluminous deposits of commercial-grade phosphate occur in sedimentary strata in a 350,000 km2 (135,000 mi2) area of the middle Rocky Mountains of North America known as the Western Phosphate Field. The Permian marine strata that host the phosphate were deposited on the western margin of the North American craton and subsequently deformed, first by folding and thrust faulting of the Laramide orogeny, and then by Cenozoic Basin and Range block faulting. Carbonate fluorapatite is the primary phosphorus-bearing mineral. Organic matter is abundant in some strata, and both biogenic and non-biogenic pyrite are also present. Certain strata are enriched in several trace elements, especially in arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), molybdenum (Mo), selenium (Se), vanadium (V), uranium (U), and zinc (Zn). Phosphate has been mined from the Western Phosphate Field for nearly 100 years. Phosphate mining and processing constitutes the largest mineral industry of Idaho, producing more than $600 million in processed mineral value in 1997. Resource management agencies, phosphate producers, and others are concerned about the release of Se from phosphate mine wastes, especially at Maybe Canyon, and the potential effects that Se and other trace elements may have on the environment and on human health. U.S. Geological Survey (USGS) Mineral Resources Team scientists initiated a multidisciplinary study of the Permian Phosphoria Formation and related rocks in the south- eastern Idaho sector of the Western Phosphate Field in response to a request by the U.S. Bureau of Land Management (BLM). Studies to date reveal that Se is present in several phases, including native Se, and in an as yet unidentified form, possibly an organo-Se compound. Selenium is also present in pyrite and sphalerite. Selenium concentrations range from 1.2 to greater than 1,000 parts per million (ppm) in samples collected from exposures of the Meade Peak Phosphatic Shale Member of the Phosphoria Formation (Meade Peake) at Enoch Valley. The results suggest that Se concentrations vary spatially across strata and with depth, perhaps comparable to spatial variations of phosphate and organic carbon concentrations throughout the Western Phosphate Field demonstrated in previous studies. Some Se-enriched strata may be of adequate dimension to allow selective extraction during mining. Such units could be handled separately from the main ore process or waste streams and isolated in order to reduce the potential for release of Se to the environment

Jan 1, 2001

By R. C. Babcock

Exploration for mineral deposits in the western United States is increasing annually, and the data generated by this effort are increasingly complex, diverse, and abundant. It is obvious that to make full use of this data base, which is both private and public, the technology of the computer must be involved. To lay out the framework for discussion of the particular uses of computers in all steps of exploration, this chapter will discuss the various approaches to the reconnaissance program which might be considered, the types of data to be acquired, the interpretation of these data, and the generation of recommendations based on this interpretation. Where possible, some of those areas where computer technology is now used will be pointed out. The discussion will cover the extent to which the computer is now utilized in those areas or where it should be brought into the program to aid in these activities. However, this chapter will not present an exhaustive evaluation of this technology, but will stress the exploration job and its requirements, so that subsequent discussion of the technology itself can be placed in perspective.

Jan 1, 1979

By Y. J. Wang

The definitions of system pressure loss (mine head) and system resistance, which are traditionally associated with single-fan net- works, are applied to multiple-fan ventilation networks. The system characteristics -- relations among air power, pressure loss, air quantity and resistance -- are analyzed by introducing the concept of subsystems. These subsystems are associated with the fans located in a cutset of the network. For a multiple-fan network, the resistances for the subsystems and total system are dependent on the quantity ratios of the subsystems. In general the pressure loss of a subsystem or a total system does not vary as the square of the corresponding air quantity. If the quantity ratios of subsystems are all held constant, then the resistances become constant and the pressure losses are predictable from the quantities employing the "square law." The system resistance has a minimum value under the natural- splitting flow pattern. Being independent of the value of system quantity, the minimum system resistance provides a basis for comparing the different networks.

Jan 1, 1983

By Jae-Chun Lee, Kang-In Rhee, D. B. Dreisinger, Hyo-Shin Yu, G. A. Kordosky

The development of a process for direct synthesis of very pure ZnO powders from zinc-bearing waste was investigated. The zinc waste which contains 55% zinc was leached with sulfuric acid. After iron removal by hydrolysis from this zinc solution, purification through solvent extraction by the use of D2EHPA as an extractant was carried out. Then, loaded zinc in the organic solution was stripped and precipitated simultaneously using oxalic acid as a precipitant. Synthesized ZnC2O4 precursors by precipitation stripping were calcined to obtain ZnO powders exceeding 99.9% purity. The effects of sulfuric acid concentration, leaching time, and pulp density on the extraction of zinc were studied and optimum conditions for the solvent extraction were obtained through purification of the zinc solution. The size, morphology, and size distribution of synthesized ZnC204 powders were studied in terms of oxalic acid concentration, temperature, surfactant added, precipitation time, etc.

Jan 1, 1993

By C. McLean, S. G. Kolb, A. J. Erickson, S. C. Moore

The Grossschloppen vein-uranium deposit, Bavaria, West Germany, was examined with underground workings during 1980-82 by Esso Erz GmbH, an affiliate of Exxon Minerals Company (EMC). Geologic evaluation entailed dense drilling of a portion of the deposit from workings constructed specifically for the program. Discovered in 1977, the deposit was initially explored by surface diamond drillholes which allowed definition of a 30-60 m wide vein system discontinuously mineralized along a 1000 m strike length and to at least a 450 m depth. The underground program was conceived as a cost-effective procedure to answer questions on vein correlation, grade continuity and variability. A 1200 m decline allowed access for detailed sampling of approximately 10% of the known area of mineralization. Fanned drillholes, logged by gamma probe, were spaced to provide intersections of veins at 10 to 20 m intervals. Six cross-cuts also penetrate the pitchblende and uranophane mineralization which occurs in 0.1 to 2.5 m thick quartz veins. Detailed cross-sections and level plans were constructed for resource estimates of the intensively studied portion of the vein system. The program resulted in the discovery of local, high grade areas and an average grade in the evaluated area nearly double that expected from surface drilling.

Jan 1, 1992

By B. J. Arnold, B. W. Parker

Rosebud Mining Company added a classifying cyclone/spiral concentrator circuit addition to its McVille Preparation Plant, Freeport, PA, in mid-2002. This paper will describe the plant addition, which was implemented fully by plant staff, and review improvements in cleaning plant performance and economics.

Jan 1, 2003

By J. J. Moore

Combustion synthesis or self propagating high temperature synthesis (SHS) reaction systems are discussed with respect to thermodynamics and kinetics. In particular, tile effect of the process parameters, ego particle size, AHf, ignition and combustion temperatures on these self sustaining reactions is discussed. Combustion theory is used to investigate the effect of the overall activation energy of the SHS reaction on the combustion front propagation rate and in obtaining a clearer understanding of the transition from stable to unstable propagation. Finally, examples of the application of combustion synthesis to advanced materials processes are made, in particular the synthesis of Ni-Ti -X intermetallic shape memory alloys, TiC-Al2O3 and ZrB2 ?Al2O3 ceramic composite materials.

Jan 1, 1991

By Harlan N. Barton

A commercially available portable X-ray spectrograph, lightweight and of rugged construction for vehicle or field camp use, was used for the determination of Ba, Cu, Fe, Mn, Pb, Rb, Sr, and Zn in stream sediment geo- chemical samples. Investigations showed a relative standard deviation of 1-3 percent, detection limits of approximately 100 ppm; and significant matrix effects. Coefficients of correlation greater than 0.9 were obtained between portable X-ray and emission and atomic- absorption spectroscopy analyses. A geochemical map of a known mineralized area showed good agreement with maps prepared by other methods of analysis and sample media.

Jan 1, 1980

By Eudes Prado Lopes

The Mineral Resource Exploration Company - CPRM - a part-private, part-government concern jurisdictioned to the Ministry of Mines and Energy of Brazil, was founded in 1969 for the purpose of promoting the exploration of mineral and hydric resources throughout Brazil. The political-administrative framework within which it was conceived and created considering that an economic and financial balance to be maintained in all its fields of activity, CPRM set out right from the start to organize itself to perform -three basic lines of action, which can be summarized as follows: As a Service Company, to carry out those services requested by government agencies and by the private sector through of service contracts; As a Mining Company under the Brazilian Mining Code, aiming at supplementing private initiative, not beyond the field of mineral exploration;

Jan 1, 1975

By Han Zhao, FENGLIANG WU, Tong Wang

Calibrating an entire mine ventilation network model from survey data has long been considered a challenging and sometimes impractical task. This paper proposes a solution to this issue with the development of a quadratic programming optimization model. The optimization model takes the minimum modification of input resistances as the objective function, uses the mesh pressure equations as equality constraints, and incorporates the lower limits of airway resistances as inequality constraints. A two-step method is developed to solve the model, which includes finding an initial feasible solution and iteratively solving the final solution using the active set method. A computer program has been developed to implement the optimization model. To demonstrate its practicality, a study case using a 35-branch ventilation network is presented, which indicates that the solution process converges after only 57 iterations, a significant improvement over the times of trial and error, which could reach 3.4 × 1010 for the worst-case scenario. Additionally, it is shown that considering only the equality constraints results in negative resistances, while incorporating the lower limits of resistance ensures that the corrected resistances are within a reasonable range. Using the resistance corrected by the optimal model to simulate the ventilation system via traditional methods generates quantities and fan pressures that perfectly match the measured values, eliminating the tedious process of manually adjusting airway resistances repeatedly.

Jan 13, 2024

By Joseph Matoney, B. K. Parekh

INTRODUCTION The term "dewatering" refers to removal of water from coal. Water associated with coal can be categorized as "free or surface" and "inherent or chemically bound" moisture.' The free moisture is found on the surface of coal, in capillaries and small spaces between two or more particles. The inherent or chemically bound water is found in the interior of the coal and as part of coal structure. A significant amount of free moisture can be removed by mechanical dewatering techniques. However, inherent moisture can only be removed by applying energy intensive techniques, e.g., direct or indirect heating. Moisture in the coal offsets some of the benefits of coal cleaning. Extra water in clean coal adds to extra cost in transportation, heat lost during vaporization, and plugging of chutes. From a utility perspective, a 1 % increase in moisture can offset a 4.5% decrease in ash.2 Mechanical dewatering can be classified into two major process categories according to the principles involved, namely, 1. Sedimentation-liquid is constrained and particles move freely. 2. Filtration-particles are constrained by a medium and the liquid flows through. Each of the process categories is composed of various separation techniques shown in Fig. Equipment currently being used by the mechanical dewatering of coal of varying size ranges and final moisture content is illustrated in Fig. 8-2. This figure indicates that sizes larger than 13/, in. (37.5 mm) present no particular dewatering problem. Shaker screens of the very crudest types and designs are capable of producing these sizes at low surface moistures. High-speed vibrators are used for the intermediate sizes and can be used for smaller sizes down to 0.02 in. (0.5 mm) if high moistures (15% surface moisture or greater) can be tolerated in the product. Usually, however, the vibrator is not used below 3/, to 3/, in. (9.5 to 6.3 mm) because of the moisture associated with these fine sizes. At this level, centrifugal force is usually employed to aid dewatering. Centrifuges of various types and designs are used practically

Jan 1, 1991

By P. Somasundaran, J. T. Kunjappu

Spectroscopic techniques are becoming increasingly popular for characterizing the interior of adsorbed layers of surfactants and polymers at solid- liquid interface as well as in the identification of com- pounds on mineral surfaces. This review encompasses the application of fluorescence and ESR spectroscopic techniques to reveal the microscopic environment of the adsorbed layers of surfactants and polymers on minerals with a special reference to the adsorption of anionic surfactants (e.g., sodium dodecyl sulfate) and polyelectrolytes (e.g., polyacrylic acid) at positively charged mineral (e.g., alumina) - water interfaces. Finally, the utility of XPS and auger techniques to identify the surface elemental composition of different mineral species has been related to their flotation efficiency.

Jan 1, 1987

By A. K. Bakshi

An on-line rheometer, suitable for use with slurries, has been developed at Michigan Technological University. This rheometer can be used with both Newtonian and non-Newtonian slurries, and produces complete shear-rate/shear stress curves which characterize the time-independent rheology of the slurry. The sensor utilizes the Hagen-Poiseuille equation and Boyle's Law to calculate the shear rate, slurry flowrate, and shear stress from a series of pressure measurements. The design of the unit allows the measurement sample to be continuously collected from operating process streams in the often-hostile on-line environment. The shear rate/shear stress curves can be used to conveniently calculate the apparent viscosity at any given shear rate, and also to measure any yield stress or other deviations from Newtonian behavior.

Jan 1, 1999