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By Roy Norcross, Stephen Gos

For over 100 years Degussa has worked together with the min­ing industry not only providing quality products but also develop­ing technologies to support these products through value added goods and services. For cyanide, these technologies include leach enhancement processes such as PAL™ and Solidox™, and cyanide detoxification with peroxygen based processes such as SILOX™ and Caro's acid using our DegOX™ technology. Degussa has also made important advances in how sodium cyanide is packaged and shipped with our liquid NaCN plant joint venture with MSI, CYANCO in Winnemucca, Nevada, and our Advantage SLS™ solid to liquid cyanide delivery system. All of these innovative technologies developed to support NaCN in mining, provide value to our customers and show Degussa's commitment to Responsible Care·11.1 and dedication to product stewardship. With Responsible Care and the customer in mind, Degussa has developed Advantage CCS™ cyanide control system, which will soon be available for the North American market. Currently there are several CCS units in service installed by Degussa AG (Germany), and we are in the process of designing the next gen­eration of the CCS which should be completed by late '98. Based on our experience working with gold and silver mines all over the world, there appeared to be an opportunity to further assist our customers by providing a better more automated way to control their cyanide additions. By providing the mine with an accurate method for maintaining their desired cyanide levels in their leach circuits, we could help them avoid underdosing and the associated gold and silver losses, and overdosing the cyanide which not only wastes cyanide but may increase treatment costs as well. In the early 1990's, when we began to introduce our CCS units, there were several cyanide controllers and on-line analyzers avail­able. However, they appeared to be too complicated and not made to stand the harsh conditions inside a mill. This resulted in exces­sive downtime and poor analytical results. We also found that many units would be installed but not commissioned by the sup­plier. Based on these observations, along with filtration and con­trol problems on some existing units, Degussa decided to design its own cyanide control system based on our extensive knowledge of cyanide chemistry, using the best components available worldwide.

Jan 1, 1998

By P. J. Hyde

Cyanide is a significant contributor to the cost of producing gold. Any reduction in consumption that can be achieved through more reliable measurement and/or more efficient management of dosing rates can have a significant financial impact. An automated analyser, by its mechanical nature, is not prone to the variations of human operators, particularly notice­able from shift to shift. Reducing the standard deviation of the measurement (ie, reducing noise ), the automated measurement will give the metallurgist a truer picture of the underlying patterns of usage. The combination of automated analysis with on-line operation and a control loop provides timely information that is efficiently utilised in the management of the plant. Until the release of the Chemtronics On-Line Cyanide Analyser (OTA3000) about 12 months ago, the Australian experience with automated analysers (especially on-line) had been substantially negative. Since its release, the Chemtronics instrument has outperformed both manual titrations and other automated instruments, gaining an enviable reputation for accuracy and reliability in the process. The instrument is built around the technique ofpotentiomet­ric titrations, in which the potential of an indicator electrode is measured as a function of the volume oftitrant that is added to the sample. As the cyanide in the sample is depleted, the potential on the indicator electrode changes rapidly, producing a typical sigmoidal curve. The OTA3000 takes the first differ­ential of the curve, identifies the apex of the peak as the endpoint and reports the result in parts per million of sodium cyanide. The OTA3000 accepts the peak as valid only if it exceeds a certain minimum height. That minimum height is a programma­ble parameter and is used to optimise the relationship between sensitivity and the rejection of spurious peaks. The instrument will track cyanide trends through both positive and negative slopes of any magnitude, but it will provide a warning if it the slope becomes excessive, not because it affects the instrument but because it means that something unusual is occurring in the tanks. There are a limited number of conditions under which the instrument will produce a result of zero. In these cases the OTA3000 holds any output lines at the last valid result while it repeats the titration. This feature was incorporated for reasons of stability in a feedback loop.

Jan 1, 1995

By William Gleason

There was a time, not too long ago, when the most daunting challenges facing those in the mining and mineral processing industries could be solved through better technologies and better practices. But now the challenges that come from the actual acts of mining and processing are just part of the bigger picture. SME?s Colorado Section of the Mineral Processing Division (MPD) hosted its 63rd annual meeting at the Broadmoor Hotel in Colorado Springs, April 25-27 and, while the conference had its fair share or mineralolgy and processing presentations that were heavy on the technical side of things, this year?s conference was also focused on the issues of permitting, regulation compliance and legislative issues. The so-called ?softer? issues, that, if not addressed, can lead to very real and very hard challenges. Under the theme ?Mine your own business - permits, startups, expansions and resources,? even the most dedicated metallurgists were drawn into the discussions of politics and legislation, and how those issues affect their business. Fittingly, Colorado Mining Association (CMA) president Stuart Sanderson was honored with the Arthur C. Daman Lifetime Achievement Award. Sanderson, an outspoken proponent for the mining industry in Colorado and beyond, also presented the keynote address to the lunch crowd where he spoke about framing public opinion toward mining and the efforts of the CMA to move the public opinion dial in a direction more favorable to mining. Sanderson explained that Colorado, once a Republican stronghold, turned after 2002 and now is controlled by Democrats who are traditionally less supportive of the mining industry. Sanderson said the deciding factor in the power shift was money, as supporters of Democrats outspent Republicans in the most recent election cycles. CMA has done its part to keep mining going in the state with a broad marketing campaign that was outlined by Sanderson.

Aug 1, 2013

By John D. Batty

With the emergence ofbiooxidation as a viable process for the pre treatment of refractory gold ores, so have the number of publica­tions on this topic increased dramatically. To a novice in the field of biooxidation, the infonnation presented is often confusing and sometimes even incorrect. Infonnation has also been published that is misleading in that it highlights a particular feature of a process that is either totally irrelevant or of no consequence to the ultimate goal viz. achieving the maximum economical gold recovery. To assist a potential user of biooxidation in evaluating the available published infonnation some guidelines or considera­tions for some of the more important aspects are given, as well as some extracts from publications that demonstrate the manner in which information has been presented.

Jan 1, 1996

By Jurgen H. L. Stuve, Rick E. M. Widelski

Any one who has been involved with the mining or the treatment of gold-bearing ores will agree that at the end of the total process, the quantity of gold recovered is never as much as was expected. These short falls are usually explained away by claiming that:- the original evaluation of the ore being mined was inaccurate the plant treatment process is not at its optimum theft is taking place excessive dilution occurs during mining The truth of the matter is that the gold is being "lost". During all the stages of its production, starting from the mining, right through to the smelting process, a certain amount of gold is not recovered. When a newly found gold deposit is being evaluated and the drilling data being analysed, cautionary factors are applied so that the grade is not over-stated. Once the decision has been taken to start mining and development is in progress, the exposed ore is sampled. When Again, when this data is being analysed more safety factors are used to ensure that when a piece of ground is given a block-value, the gold content is not over estimated. mining actually takes place and the ore transported to the plant for treatment, the metallurgical department also introduces certain safety factors when predicting how much gold will be recovered. This shows that the quantity of gold that one expects to finally recover is already a conservative figure. The actual quantity recovered invariably falls short of this figure, in fact, South African gold mines are satisfied when achieving a Mine Call Factor (MCF) of 85%. In the last few years a great deal of work has been carried out to investigate how this unaccounted for gold is lost and what steps can be taken to remedy the situation. Previously mined areas were re-swept using the traditional hand brush method; experiments were carried out with water jets sometimes in conjunction with compressed air and even small portable vacuum cleaners were tried. None of these methods were totally successful in recovering the left over gold but the use of vacuum systems showed the most potential. the In South Africa this has resulted in introduction of high-powered vacuum systems on the gold mines to suck-up this lost gold. These were initially introduced in the mining areas, particularly old areas, to recover any left over ore. The results proved extremely profitable, So much SO that presently, well over 120 suction systems are doing this type of work. This success encouraged plant operators to look at areas of potential loss in the plant itself. This has resulted in an increasing number of machines being supplied to gold plants mainly for clean-up applications with the bonus that the material sucked up invariably contains gold.

Jan 1, 1993

By Darrell M. Hladun, Linda M. Dufour

The benefits of computer simulation in the design of a refracto­ry gold autoclave facility is discussed. Three computer simula­tion programs used for autoclave design are briefly described in this paper. 1) METS IM® - A Process Simulation Software Package Developed by Proware: Mass and energy balances are conducted around the auto­clave and its ancillary processes. Results from the process simulation define process equipment requirements and are used for establishing operating costs. The p_rocess model integrates various unit operations including grinding, acidu­lation, pressure oxidation, counter-current-decantation, neutralization, cyanide leaching, and carbon-in-pulp or car­bon-in-leach. 2) ALGOR® - Finite Element Analysis (FEA): A computer software program is used in the design and analysis of brick lined pressure vessels, such as autoclave, heater, and flash vessels. This software creates a steady state thermal model, and accurately predicts temperature distribution throughout the entire vessel, including nozzles, which represent regions of high thermal intensity. 3) Compress©: A software package developed by Codeware used for the sizing of pressure vessel components, includ­ing shells, heads and nozzles, according to ASME Boiler and Pressure Vessel Code, Section VIII, Division 1.

Jan 1, 1996

By Mike Irish, Deb Mukhapodhyay

It has been demonstrated by Arrowhead Industrial Water that a proprietary reverse osmosis technology can be used efficiently, effectively, and economically to reduce the levels of cyanide species, heavy metals, and other ions as shown in Figure 1 to allow safe discharge of a permeate solution to the environment. A simultaneous benefit of this process was the cost savings of reduction in quantities of cyanide requiring destruction by hydrogen peroxide and recovery of a concentrated gold and silver value in the concentrate solution.

Jan 1, 1992

By P. M. May, J. S. Solis, G. T. Hefter

Chemical speciation plays a critical role in many areas of gold processing. These include the formation of HCN in plant liquors, interference by copper in the extraction efficiency of gold, the recovery of adsorbed gold, and the behaviour of plant effluents in the environment. Thermodynamic modelling provides a cost-efficient method of rationalizing and even predicting of chemical behaviour. Unfortunately, because thermodynamic data for cyanide complexes are of poor quality and few are known under hydrometallurgical conditions. Such models are currently of limited use. This paper describes recent work on the thermodynamics of cyanide complexes of a range of metal ions. Data will be presented on the stabilities and enthal­pies (heats) and entropies of formation of a variety of metal ion species determined by potentiometry and calorimetry. Particular emphasis will be placed on the Cu(I)/CN- system.

Jan 1, 1995

By Peter Greenhalgh, W. Baguley, R. P. Riley

The traditional impeller system for aeration and suspension of slurries, e.g., in bacterial oxidation plants, is the vertical flat blade turbine (VFBT) . This type of impeller is energy-intensive, which results in a heavy-duty design of shaft, gearbox and drive. The VELMIX bio-reactor development programme is designed to evaluate the use of the new generation of hydrofoil impellers which consume less power and thus have poten­tial for capital and operating cost savings as well as being possibly less damaging to the bacteria. The early tests on pyrite oxidation in a 300 litre laboratory pilot tank using the Thiobacillus ferro oxidans bacteria, showed that hydrofoil impellers had superior charc­teristics to the VFBT impeller and to air­ agitated pachucas, with lower energy input. The geometry of the sparge _ring was found to be very important in optimizing the system.

Jan 1, 1990

Peru has become an established mining country. The industry and industry-related businesses account for a significant amount of the country´s revenue, on state and local levels. But like other countries with thriving mining industries, Peru has seen its mining industry revenues fall off in recent years due to a lackluster global economy. And the mining industry in Peru must also deal with increasing concerns about mining?s environmental impacts, local community and other social issues, as well as a regulatory environment that has placed more restrictions on what miners can do. That said, the Peruvian government is beginning to realize how important mining and natural resource development is to building the nation?s economy, improving its infrastructure and lifting its population out of poverty. The government support was evident during the Perumin 2013 mining convention, held in September in Arequipa. In addition to Peru?s President Ollanta Humala speaking at the closing ceremony, the country?s ministers of Energy and Mines, and Economy and Finance participated in the event, as well as numerous other federal and state authorities. Perumin is put on by the Instituto de Ingenieros de Minas del Peru (IIMP, or Peruvian Institute of Mine Engineers). The 31st edition of the convention, billed as the ?world?s largest mining convention? by the IIMP, this event was led by Abraham Chahuan CEO of Antamina and Romulo Mucho (SME member) as president of IIMP, attracted about 118,000 participants from more than 48 countries. This was more than the anticipated 75,000 attendance and well past the 51,000 people who attended the 2011 convention. The last edition of PERUMIN was led by the CEO of Compañía Minera Antamina, Abraham Chahuan and Rómulo Mucho (SME member) and representative of the IIMP. The event attracted more than 1,000 journalists from all over the world, the IIMP said. A total of 2,213 booths from equipment and machinery supplying companies from the five continents were present at the Mining Technology Exhibition (Extemin), including companies from the United States, Canada, China, South Africa, Germany, Australia, Brazil and Chile, among others. The convention has grown so large in recent years, that the IIMP shifted its location from Tecsup vocational school in Arequipa to the Cerro Juli Convention Center. The venue is 116 percent larger than Tecsup, the IIMP reported, covering about 20 ha (40 acres). It was reported by Latinomineria magazine that about 10 million Peruvian soles were invested in the new venue to create a world-class events center. It was also estimated that the event generated more than 234 million soles to Arequipa?s economy.

Feb 1, 2014

By Peter J. Stewart

My first experience with carbon reactivation in the gold industry was at Whim Creek, Meekatharra some 15 years ago. Very little was known, in fact, carbon reactivation kilns in the gold room were a complete mystery. Ten years ago at conferences such as this the mystery was more as to why field kilns would not reproduce activities achieved in the laboratory. A carbon reactivation kiln manufac­turer was thought to be brave or stupid to speak at a venue such as this. Reactivation kiln design has improved dramatically in the past 10 years and with a few exceptions, most kilns operate well. May I suggest that now, the focus is on plant practice rather than kiln design, and that the basics of plant practice as it relates to carbon activity needs revisiting. As metallurgists like to talk on engineering, accountants on the Economy and vice versa, my presentation on Carbon Reactivation will focus on plant design and operation as it effects carbon reactivation. There have been some excellent papers published over the past 15 years on the basics of carbon reactivation in relation to gold processingl,2,}. Taken that kilns operate and are effective to a greater or lesser degree, plant design and operating practise have an enormous bearing on carbon activity, solution tail, carbon loss and other cost items. This presentation will not argue the merits of equipment used for the thermal reactivation of organically fouled carbon, questions on this subject are welcome over a drink after this session.

Jan 1, 1995

By Bruno Sceresini

The Filblast Cyanidation Process incorporating intense high shear mixing, high gas mass transfer efficiency and high oxygen concentrations under conditions of elevated pressure has now been been successfully applied in gold cyanidation mills since May 1993. The first commercial unit had a slurry capacity of 110 cubic metres per hour. Since then 230 and 450 cubic metre per hour units have been installed and a 1,000 cubic metre per hour unit has been designed. Laboratory and pilot plant Filblasts have also been built. The reactor is a robust, compact in-line or end-of-line device and may be constructed out of a wide range of materials including wear and corrosion resistant alloys and ceramics. The Filblast Process may be applied to high temperature leaching of refractory gold ores and base metal concentrates. The development and application of the Filblast Gas Shear Reactor as a cyanidation tool has removed the constraints of plant size in cyanidation applications in mobile or readily transportable gold plants. A 250,000 tonne per annum fully modularised gold ore treatment plant with the Filblast and AARL Pump Cell as core technologies is nearing completion. This plant includes several novel features which are predicted to achieve widespread adaptation in modem cyanidation plants. This paper presents a briefreview of the development of the technology and the principles incorporated in the Filblast system. A number of case studies are presented which show significant financial benefits due to more efficient reagent utilisation, higher recovery and increased through-put.

Jan 1, 1997

By Todd Loudin

A majority of the chemical process industry uses lime in either a powder or liquid form. Engineering and maintenance personnel often face a long and potentially expensive trial-and-error period in order to find the best process equipment to handle lime. Limestone is mined from a quarry in the form of calcium carbonate (CaCO3). Then, it is crushed and fed into a kiln at approximately 1,093° C (2,000° F), where the carbon dioxide is burned off (calcining) to make calcium oxide (CaO).

Jan 1, 2010

By O. A. Bascur

The problem of setting the proper control objectives and/or having several objectives to be met in the implementation of grinding control strategies can be resolved. The design and implementation of a distributed control system for safe operation of a grinding circuit while maximizing profit is presented. An optimal recovery/throughput target for a desired grind is accomplished by advanced control strategies at the DCS level. A mill load constraint control technique provides stable operation with a substantial increase in throughput, while the desired grind index is maintained by an inferential grind control technique without using a particle size analyzer. The integration of crushing/grinding and flotation in the overall design was the key to the success of the project. This synergistic effect was obtained by implementing a computer -plant management system in the concentrator. The overall philosophy of keeping the implementation simple but not simpler was used.

Jan 1, 1989

By W. Hoecker, S. Watson

The use of oxygen (Goldox™) in gold leaching has emerged as a significant modification in the past nine years. The Goldox™ process was ori gi na 11 y developed by Afrox Ltd ( part of the BOC Group) and is currently used in South Africa, Australia, Canada and the United States. Although a variety of benefits have been observed with oxygen, this paper out 1 i nes the main ones with reference to Australian plant data. The case studies were categorised into the ore type: Oxide, blends and primary ore.

Jan 1, 1992

By Peter Krag, Rob Henson

It is well known that titanium and zirconium alloys offer superior corrosion resistance in the oxidizing sulfuric acid environments present in sulfide pressure leaching operations. The use of these materials is limited, however, due to their pyrophoricity; several accidents attributed to titanium equipment have been described in technical literature, and other, minor incidents·occur regularly1 • We describe an application of a commercial titanium alloy, Nb-55 Ti, with suitable mechanical properties, corrosion resistance similar to Grade 2 Ti, and featuring a significantly reduced field of ignition conditions

Jan 1, 1992

By Vernon F. Swanson

The expansion of a fluidized bed of carbon depends on fluid velocity, fluid temperature (viscosity) and particle size of the carbon. This paper presents a mathematical model which can be used to calculate the necessary fluid velocity. It will allow the design of sufficient freeboard in the column to accommodate expected operating conditions. Although this paper is keyed towards the use of activated carbon in precious metals adsorbtion from water solutions, the model is.valid with any fluid. Additionally, the method of calculating the required suspension velocity in CIL or CIP pulps is described.

Jan 1, 1992

By Michael Botz, Craig McKenzie

Recovery of cyanide from mill tailings can be conducted to lower the overall cost of precious metals extraction, while lowering cyanide concentrations in mill discharges and potentially eliminating the need to chemically destroy cyanide. Recent applications of cyanide recovery based on acidification­volatilization-reneutralization (A VR) technology have elimi­nated the need for cyanide destruction and substantially increased the profitability at several gold and silver operations. Recent developments in the technology permits processing of scale-prone and high percent solids pulps while generally affecting cyanide recoveries in excess of 70% to 90%.

Jan 1, 1997

By James Humphrey

There is a natural resistance to change in any form. When it comes to implementing a game-changing technology like autonomous haulage on an operating mine site, the resistance can at times appear insurmountable. Whether based on real information or misguided preconceptions, it?s essential that we don?t underestimate the effort it will take to overcome this resistance, while clearly recognizing when it?s worth the effort. These realizations did not happen overnight for sites where autonomous haulage has been implemented. Nor did they happen overnight for manufacturers of autonomous mining equipment. Caterpillar, for example, began building toward autonomy more than 30 years ago and had a truck operating in the mid-1990s. Lessons learned during those early years led to the realization that there was much more to be learned ? not just about the machines themselves, but about the systems and knowledge that must be in place for a successful implementation. Working closely with customers, initiating real-life demonstrations on mine sites, having discussions with regulatory agencies and other stakeholders ? these and many other activities were necessary before autonomy could be fully and successfully launched. After decades of effort, Caterpillar?s first official commercial autonomous mine site went to work in 2011 in Farmington, NM.

Caterpillar and Fortescue Metals Group have moved forward with the delivery, installation and support of a complete Cat MineStar System at Fortescue?s Solomon iron ore mine in the Pilbara region of Western Australia. The complete technology suite was implemented for the first phase of Solomon, the 20 Mt/a (22 million stpy) Firetail manned mine, in October 2012. As part of an autonomous mining solution for phase two, the 40-Mt/a (44-million stpy) Kings Mine, eight Command for hauling Cat 793F CMD trucks were commissioned and commenced operations in the second quarter of 2013. The mine plan calls for a progressive ramp up to 45 autonomous trucks during the next several years. In addition, other Cat MineStar System capability sets, Fleet, Terrain, Detect and Health, are being used across the mobile equipment fleet, including support equipment and light vehicles. Working closely with Fortescue and its mining contractor, Leighton Contractors, Caterpillar and the Cat dealer in Western Australia, WesTrac, are providing a full solution for managing, operating and supporting Cat MineStar System and Command for hauling. The greenfield Solomon Mine has brought together the skilled team from Caterpillar, Fortescue, Leighton Contractors and WesTrac to deliver an efficient, cost effective autonomous mining solution.

Nov 1, 2013