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By M Scott, J J. McEwan

Silver and silver alloys tarnish readily by the formation of tarnish on the surface when exposed to a wide range of sulphur-containing atmospheres. This tarnish is unsightly and undesirable and can be removed either with a silver polish or a chemical dip. Polishes are, however, not suitable for irregular and embossed surfaces such as on coins, medallions and jewellery items, because of uneven removal of the tarnish layer and excessive wear. Successful tarnish protection can be achieved by either storing the items away from the aggressive atmosphere or by coating/treating the exposed surfaces with a protective layer. Storage is feasible for collections but is not suitable for items that are handled or worn regularly, such as jewellery. A number of commercial coatings and treatments have been developed, but to date there has not been a systematic evaluation of tarnish protection. This paper details the performance of a range of generic coatings in an accelerated tarnish test. The degree of tarnish was evaluated by means of loss in reflectivity and change in colour. Four coatings/treatments improved the tarnish resistance of silver by more than tenfold. These include an organic lacquer, rhodium electroplating and an organic self-assembled monolayer (SAM) conversion coating. Research is continuing to optimise these coatings. Keywords: silver alloys, tarnish resistant coatings, silver polishes.

Jan 1, 2006

The Annual General Meeting of the Institute was held in Kelvin House, Johannesburg, on Wednesday, August 14th, 1974. Mr P. W. J. van Rensburg (President) was in the Chair. There were present 56 Fellows, 21 Members, 2 Graduates, 5 Associates, 16 Students, and 58 Visitors, making a total of 158. The President declared the Meeting open at 4.08 p.m. OBITUARIES The President: Ladies and gentlemen, before we start the business of the meeting, it is my sad duty to announce the deaths of the following members of the Institute since our last meeting: Dr O. A. E. Jackson, Honorary Life Fellow and Past President; C. Airth, T. L. Blunt, A. E. Frazer, C. L. Lamb, and K. Richardson, Life Fellows; and J. T. Beaumont, Fellow. As you know, there were a number of other deaths during the year, which were reported at previous General Meetings of the Institute. As a mark of respect to the memory of the deceased, and in sympathy with the bereaved, I ask you to rise and observe a few moments' silence. MINUTES The President: Ladies and gentlemen, the next item on your agenda is confirmation of the minutes of the General Meeting and Special General Meeting held on May 22nd, 1974. These will be published in the August issue of the Journal, and, since you have not yet received this, I must ask that they be held over to the next General Meeting. WELCOME The President: It is a very pleasant duty for me to welcome many members of our Institute and our guests, among whom we are particularly pleased to see the President of the Chamber of Mines, Mr Dolf Schumann, who is also Honorary President of this Institute. Mr Schumann, we are extremely pleased to have you with us today. And, we welcome an old friend of ours, Mr Dillon, Minister of Mines in Rhodesia, who has come down for our Annual General Meeting. Mr Dillon, we are very, very pleased to see you here this evening, and we look forward to seeing Mrs Dillon a little later. And we have with us, too, the presidents or representatives of many of our sister and brother associations, institutes, and societies. In particular, we welcome Mr Mike Gericke, President of the South African Council of Professional Engineers, and Professor Midgley, President of A. S. and T. S. We are also pleased to welcome the Presidents of the Mechanical Engineers, Electrical Engineers, Certificated Mechanical and Electrical Engineers, the Civil Engineers, the Joint Council of Scientific Societies, the Mine Ventilation Society, the South African Association of Consulting Engineers, the Association of Mine Managers, the Institute of Foundrymen, the Institute of Welding, the Federation of Societies of Professional Engineers, Mine Surveyors, Production Engineers (London), and the Institute of Production Engineering. We are very glad, too, to have with us a visitor from England, Professor Raynor and Mrs Raynor. Professor Raynor is Professor of Metallurgy at Birmingham University, and a very well-known metallurgist in Britain. We also have with us the Chairman of the Ferro-Alloys Association. We are expecting the Chairman of our Witbank/Middelburg Branch, the Chairman of the Engineers' Liaison Committee, Pretoria, the Director of the Witwatersrand College of Technical Education, and, of course, our old friend, Mr Eric Boden, the Manager of A.S. and T.S. It is a very great pleasure to have with us a number of persons who will receive honorary Life Fellowship at this meeting, and there are some Gold Medal winners and winners of our Student Prizes. We have apologies from a number of people who are away on business, and unfortunately some are ill. But we are extremely pleased to see those of you who are here, and we are also very pleased to see so many ladies. We expect to see many more of them later this evening, at our Cocktail Party. MEMBERSHIP The President: I have pleasure in announcing that, their names having been published in accordance with By-Law 5.2.2., the following have been elected by Council to membership in the following grades Fellows: B. Collins, D. W. Dixon, J. P. Dreyer, A. T. Hudson, and W. W. Pearce. Members: A. T. Fisher and I. F. Nagy. Associate Members : P. D. de Bruyn and H. C. Iverson. Graduates: D. P. O'Shaugnessy and M. F. Sadler. Associates: R. J. Bushell and A. MacDonald. Students : I. J. Barker, P. J. Charter, J. P. de Witt, G. S. Esterhuizen, N. Green, P. M. Jenner, M. J. R. Meyer, A. P. Nicol, W. J. C. Pothas, B. J. Robbetze, N. T. Sutherland, B. A. Statham, C. R. Thomas, N. C. Webb, M. Salamon, R. G. Jurd, and M. McChesney. Transfers to other grades of membership include the following: Member to Fellow: B. W. Holtzhousen. Graduate to Member: T. S. Schultz. Associate to Associate Member: C. L. Jordaan, H. J. L. Tomlinson, J. E. Forbes, G. H. S. Bamford, T. F. Carswell, J. W. Breidenhann, J. R. Garbutt, and L. S. Gibbs. Student to Graduate: C. J. Faueonnier and B. Lund. Student to Associate : G. P. Gooding. We welcome these new members

Jan 10, 1974

By V. Velicka, J. Ptacek, R. Snuparek, P. Konecny, G. Takla

Coal mining in Ostrava-Karvina coalfield is being accompanied by rockbursts. 82 rockbursts occurred within the period between 1990 and 2002. Natural and technological factors from these rockbursts were collected and analysed. They confirmed that rockbursts are complex geomechanical events and that the relations between co-acting technological and natural factors are very complicated. Der Abbau in dem Ostrava-Karvina Steinkohlenrevier wurde von Anfang an durch Gebirgsschläge begleitet. 82 Gebirgsschläge in dem Zeitabshnitt von 1990 bis 2002 erfolgten. Die Angaben über natürliche und technische Faktoren der Gebirgsschläge wurden gesammelt und analysiert. Es wurde bestätigt, dass die Gebirgsschläge komplexe geomechanische Phänomene sind und dass die Beziehungen zwischen den zusammenwirkenden Faktoren sehr kompliziert sind. L´abattage d´houille dans le Bassin houiller d´Ostrava-Karvina est accompagnée par les coups de terrains. 82 coups de terrains s´étaient produit dans la période entre 1990-2002. Les données sur les facteurs naturels et techniques ont été ramassées et analysées. Les résultats ont corroboré que les coups de terrains sont des phénomènes géoméchaniques complexes. Les relations entre les facteurs techniques et naturels coopérants sont très compliqués.

Jan 1, 2003

By E H. O Meyer, K van Dyk

Fine powders normally exhibit, to a more or lesser extent, some ability to participate in dust explosions. Zinc dust as used in the extractive metallurgy of zinc, is not known to be a reactive powder in the industry. No evidence could be found in the literature where zinc dust was involved in an explosion or explosive type event. On 3 May 2002 an explosive type incident occurred at Zincor in Springs, South Africa, which led to a fatal accident. Given the history of relative benign behaviour of zinc powders under conditions conducive to dust explosions, it was decided to share the information of this incident with industry in an effort to prevent similar incidents. Therefore, the purpose of this paper is to describe the incident that occurred at Zincor, discuss the major findings, report on corrective actions, as well as publish the results of subsequent tests that were performed to determine the conditions under which zinc powder exhibits explosive characteristics.

Jan 1, 2005

By R. Strydom, J. H. Selby, J. Slabbert, W. Enslin

Zircon is a naturally occurring silicate of zirconium, which is used in large quantities (~1 million tonnes per annum) for its refractory properties and its extreme chemical inertness. All zircons contain uranium and thorium bound into the crystal lattice, generally at levels up to 500 ppm of uranium plus thorium. This paper focuses on one aspect of the zircon industry—the ability to safely transport large quantities of zircon sand. Currently zircon is not classified as a radioactive material for transport purposes. However, this is because of a factor used in the exemption clauses of the IAEA code on safe transport of radioactive materials. The objective of this study was to determine the validity of this factor, and was submitted as part of an IAEA Coordinated Research Project (CRP). The study is based primarily on measured rather than modelled data and covers the transport of large quantities of zircon from producers in South Africa to customers in Europe. Both occupational exposure of workers and exposure of members of the public have been considered. The transport routes studied cover rail, road, ocean-going ship and inland barge transport of unpackaged bulk products. The study showed that the most exposed member of the public would receive 10µSv/annum,while the most exposed worker would receive 144µSv/annum of exposure. It is concluded that these levels are well below all regulatory limits for such activities involving naturally occurring materials. The study also showed that normal operational exposures are higher than those in accident scenarios, a feature which does not occur with higher activity materials. It is further concluded that the study validates the use of the factor of 10 in TS-R-1, as applied to zircon sand. Additionally it is also concluded that the exemption currently applied to the transportation of bulk zircon sand is valid.

Jan 1, 2003

Underground operators' conference. Parkvile (Australia), Australasian Institute of Mining and Metallurgy, $A25 (surface). Reviewer: G.R. Stil Reagents in the minerals industry: A review, edited by M.J. Jones and R. Oblat. London, Institution of Mining and Metallurgy, 1986, £50. Reviewer: L. Goold

Jan 1, 1986

This Spotlight gives a brief summary of the proposed 1991 tax amendments of relevance to mines and mining houses. It should be read together with the author's article South African mining tax in the 1990's', which appeared in the August 1990 issue of this Journal. A number of tax amendments of relevance to the mining industry were proposed by the Minister of Finance in his March 1991 budget speech. In addition, certain other measures that may be implemented were set out in the budget review document released at the same time. A word of caution is necessary: these measures will become law only if and when they are enacted in the appropriate legislation. When this legislation is tabled in June, it may not contain all of the measures discussed below, some of the measures may appear in modified form, and other measures not discussed at the time of the budget may well appear. Unless otherwise stated, the 1991 tax amendments will affect companies with years of assessment ending in the twelve-month period to 31st March, 1992.

Jan 1, 1991

By L. L. Godirilwe, and A. Shibayama, G. Danha, K. Haga, Y. Takasaki

Selective extraction through leaching of an amorphous slag obtained from a base metal smelter plant in Botswana is investigated in this paper, where the main objective is to optimise the experimental variables that would result in the maximum selective extraction of the three base metals (Ni, Cu and Co) from the slag waste. Mineralogical tests showed that the sample is composed mainly of fayalite (Fe2SiO4), with a total entrapped metal sulphides content of about 1.0 wt.% occurring as fine occlusions in the fayalite phase. In our experimental program, we compare the effectiveness of two common leaching techniques. In the first method, we use sulphuric acid to carry out atmospheric beaker leaching tests, and in the second method we use high pressure oxidative leaching. The effects of acid concentration, oxidant addition/oxygen partial pressure and pulp density on metal dissolution rate are examined. The optimal Ni, Cu, Co extractions of 80.5%, 81.9 and 98% respectively were obtained under high pressure oxidative leaching conditions (150 oC, 0.6 M H2SO4, 0.5 MPa O2), with substantially low dissolved Fe of 9.6%, the majority of which was removed as jarosite in the residue. Atmospheric beaker leaching yielded poor extractions of Ni below 40% when sulphuric acid combined with hydrogen peroxide (1.0 M and 0.6 M respectively, 65 oC) were used for leaching, while Fe, Cu and Co dissolutions were each about 80%. Therefore, using high pressure oxidative leaching provides a possibility to effectively extract Ni, Cu and Co while producing an environmentally benign residue, thus alleviating the current adverse environmental issues associated with the abandoned smelter slag. Keywords: Slag, amorphous, fayalite, atmospheric beaker leaching, high-pressure oxidative leaching, extraction

Jan 1, 2020

By R. Romano, E. Montalar, J. B. Serón

The SMR geomechanics classification system (adaptation of RMR for slopes) is reviewed with data from 87 actual slopes in Valencia. In a research project, SMR has been applied by a GIS system, as a method to forecast stability problems in future road construction. As a result of this work a methodology for GIS application has been developed. On revient sur la classification geomechanique SMR ( une adaptation du RMR pour talus et pentes) avec les dates de 87 talus existant autour de Valencia. Dans le cadre d’un projet de recherche SMR a été appliquée, avec un système GIS, comme méthode de prévision de stabilité problèmes dans la construction de futures routes. Une méthodologie pour l’application du GIS a été développe. Das Geomechanische Einteilungssystem SMR (eine Anpassung des RMR an Böschungen) wird an Hand der Daten von 87 Böschungen im Gebiet von Valencia überdacht. In einem Forschungsprojekt wurde das SMR in einem Geographischen Informationssystem (GIS) als Methode zur Vorhersage von Stabilitätsproblemen bei zukünftigen Straßenbauprojekten eingesetzt. Das Ergebnis dieser Arbeit ist die Entwicklung einer Methodologie für die GIS-Anwendung

Jan 1, 2003

1. Book reviews Dislocations and properties of real materials, edited by M.H. Loretto. London, The Institute of Metals, 1985. 392 pp. Reviewer: F.R.N. Nabarro Au &Ag heap and dump leaching practice, edited by J.B. Hiskey. AIME, 1984. 162 pp. $20 (member), $15 (student member), $30 (non-member) plus $3.50 for postage and handling. (Order from SME Books, Caller no. D, Littleton, CO 80127, U.S.A.). Reviewer: R.A. Snodgrass The cost and availability of Colombian coal, by Eric D. Jamieson, with the assistance of Kathleen Jamieson. London, lEA Coal Research (14/15 Lower Grosvenor Place, London SWl W OEX). £50 (in member countries), £100 (in non-member countries). Reviewer: W.C. Mather Extraction Metallurgy '85. London, The Institution of Mining and Metallurgy, 1985. £42. Reviewer: R.A. Snodgrass 2. Recent publications Mining annual review 1985. London, Mining Journal, Jun. 1985. 600 pp. £26.50 (surface), £39.50 (air). High heat production (HHP) granites, hydrothermal circulation and ore genesis. London, The Institution of Mining and Metallurgy, 1985. 593 pp. £27 (members), £30 (non-members). Potential mineral resources of Egypt. 144 pp. US$10. Available from Bendix Field Engineering Corporation-MPGAP, Box 1237, Grand Junction, CO 81502, U.S.A. 3. Mintek reports Report M212 South African costs of equipment for the metallurgical industry (1984). Report M213 The response of as-rolled 3CR12 steel to heat treatment. Report M214 A computer programme for use in the development of multi-element X-ray-fluorescence methods of analysis. Report M221 Commodity profiles for selected metals. Report MIO7D Upgrading of alaskite rock to feldspathic sand. (First issued Jun. 1983; reissued Nov. 1985). IMM awards Given below are details of the trust funds to which applications are invited for grants, etc., payable in 1986. Application forms, which must be returned to the Secretary before 17th March, 1986, are available on request. Applicants should note that, in general, preference will be given to members of the Institution.

Jan 1, 1986

Most processing plants use automatic samplers to extract ore aliquots along a producing shift. These aliquots are combined into a sample normally sent to lab analysis. The sampler used in the extraction of an aliquot from a continuous flow of ore, i.e. a belt conveyor is required to be both precise and accurate. Surprisingly, not all commercial automatic samplers exhibit these two mandatory properties. Consequently, it is recommended the development of a procedure able to check sample assays reproducibility obtained using a given sampling protocol. This paper uses the Gy’s sampling theory to evaluate coal quality control practices at a washing plant using an automatic sampler extracting coal increments from the ROM feeding belt conveyor. Gy’s theory provides the means to establish the precision limits for a given sampling protocol. Various ore properties are required to be determined in combination with sample mass and mass of the lot sampled. All this information leads to the definition of the precision limit. The precision limit obtained was checked via an experiment mimicking what happens in situations where both miner and consumer use the same and appropriate sampling practices. The experiment demonstrates that sampling theory precision limits were valid if unbiased samplers are used by both parties, i.e. miner and consumer. Keywords: sampling, quality control, coal

Jan 1, 2003

By R Kroukamp

Horizontal belt filters are typically used for separation of relatively free filtering solids where good post treatment is required. He horizontal belt filter is a continuous filter with an endless cloth supported on a grooved carrier belt. The belt and cloth are driven around two rollers across a series of evacuated suction boxes. The feed suspension is introduced at one end of the filter and deliquored to produce a cake at the other end. The benefits of using horizontal belt filters are good cake washing, continuous and visible processing, fully automatic operation, flexibility, high capacity and relative high speeds of operation. If required, horizontal belt filters enable efficient counter-current washings to minimize the usage of wash liquid. The horizontal belt filter has applications in the following: [? Metal concentrates ? Mineral sands ? Tailings ? Coal ? Iron ore ? Alumina ? Chloride processing ? Nickel and Cobalt refining ? Platinum group metals ? Zinc processing ? Many other applications in the Mining and Metallurgy industries ] 2. Operating Principle of a Horizontal Vacuum Belt Filter 2.1 Cake Forming The slurry to be dewatered is evenly distributed onto the filtering surface. Gravity assists the cake formation and the feed can be introduced in multiple stages. 2.2 Cake Washing Once the cake is formed, wash liquor/water can be introduced onto the top of the cake via a wash launder or sprays. Multiple wash stages, co-current, counter-current or direct washing can be added by increasing the length of the filter.

Jan 1, 2007

On behalf of the Council and staff of The South African Institute of Mining and Metallurgy, it is my privilege to wish all members and subscribers a very Happy Christmas and a Prosperous New Year.

Jan 1, 1988

The Gordonsville Operation of Pasminco US Inc. along with the Center for Advanced Mineral and Metallurgical Processing (CAMP) at Montana Tech studied, developed and implemented a pilot scale hydrometallurgical facility for the industrial recovery of germanium and gallium. This paper describes the joint testing and engineering program that culminated in this successful process. 1. Introduction The Pasminco US Inc. (PAS), Gordonsville Operation, has been producing zinc concentrate continuously since 1975. Within the zinc concentrate, several byproduct elements were found to be significantly concentrated including gallium and germanium. The gallium and germanium replace zinc and other metals within the crystal lattice structure of the zinc mineral (sphalerite) and are concentrated in the same manner as the zinc mineral. This concentrate is then sent to the Pasminco Clarksville Zinc Refinery for further processing. Within the hydrometallurgical zinc-processing plant at Clarksville, a residue is formed that contains a majority of the impurities that would otherwise contaminate or hinder the zinc process. Approximately 5,000 tons of residue is formed annually containing approximately 0.80% gallium and 0.60% germanium along with significant quantities of iron, zinc, silica, and lead. Pasminco currently sells this residue for the germanium value. Until recently, no revenue for the gallium was obtained from the sale of the residue.

Jan 1, 2008

By B. K. Loveday

The South African Institute of Mining and Metallurgy hosted a School on 'The Practical Design of Comminution Processes' at Megawatt Park (near Johannesburg) on 14th to 16th May, 1991 Derek Barratt, a Senior Consultant of Wright Engineers, Canada, and the main speaker, provided a good insight into how Wright Engineers design milling circuits, particularly large semi-autogenous mills. He was ably assisted by Jens Lichterof Allis Mineral Systems, who described some interesting examples of pilot-plant testwork and summarized South African milling practice. Mike Moys of the Witwatersrand University spoke on the influence of pulp viscosity on mill performance, and Johan Engelbrecht and Jeremy Bosman of Multotech

Jan 1, 1991

By J. Lux, B. Clermont

Magotteaux, with the co-operation of Anglo Platinum, has erected a fully instrumented pilot plant at Frank concentrator, which is being used to study the influence of a variety of grinding parameters. This paper will discuss only the influence of mill speed and pulp density on secondary stage grinding. A Ø0.82 x1 m open circuit mill was used with reclaimed Merensky tailings as feed. The conclusions apply to this pilot plant but further investigation needs to be done to verify whether the same trends will be applicable to a large industrial-scale mill.

Jan 1, 2004

By J. M. Sabio, A. W. Stalberg

Keywords: Pyrometallurgy, furnace, calcium carbide, acetylene, Newcastle The manufacture of calcium carbide in Newcastle, South Africa, was started in the late 1950s by a company called South African Carbide, at the Ballengeich site. In 1978, this operation was bought by the forerunner to the present AECI Ltd, a large producer of commodity chemicals at the time. Production continued at this site until 1992. In the meantime, Karbochem, an operating division of Sentrachem Ltd, was also manufacturing carbide in Newcastle, as a building block for the manufacture of synthetic rubber. In 1990, the Karbochem calcium carbide operation was closed down. In 1992, the AECI carbide business and the Karbochem production facility were amalgamated, and production continued under the Karbochem name. In 1997, the Dow Chemical Company bought the holding company of Karbochem, and the carbide business continued operations until 2003. In June 2003, the business was sold to a management consortium as SA Calcium Carbide (Pty) Ltd. Later, in October 2004, 100% of the shares were acquired by the Andina Group. Today, the Andina Group, consisting of SACC from South Africa, CIL from UK, and ANDINA from Argentina, has become a global leader in the manufacture and supply of calcium carbide and calcium silicon, ferro silicon 75% and derivatives, recarburizers with low nitrogen content, acetylene, carbon black, micro-silica, and silicon metal. The production facilities at Newcastle comprise a 52 MVA submerged arc furnace of a closed design, carbon monoxide gas recovery, recovery of fine raw materials via a hollow electrode system, and an extensive computer-controlled process. These all enable an efficient state-of-the-art operation. The downstream processing facilities consist of screening and drumming facilities, milling facilities, an acetylene generation plant, and an acetylene carbon black plant. Clearly, SA Calcium Carbide (Pty) Ltd has a long history of supplying quality calcium carbide to the industries that it proudly serves.

Jan 1, 2006

Termination of membership In accordance with By-Law 7.6.1. of the Constitution of the Institute, the names of the undermentioned members have been removed from the membership register. Colloquium and General Meeting A General Meeting and Colloquium on 'Heavy-medium separation and ore sorting' was held on 18th September, 1974, at 09h15, in Kelvin House, Johannesburg.

Jan 12, 1975

By Piotr M. Kapias

Keywords: extraction, lead refining, Pb-Tl solutions, PbCl2-TlCl solutions. The theoretical part of the paper presents an analysis of the conditions of Tl extraction from Pb using different extractants and determines the activity coefficients in liquid solutions of Pb-Tl and PbCl2-TlCl. The dependence of the solution activity coefficients upon the composition and temperature is presented in the form of Krupkowski and Krupkowski-Fitzner equations. An analysis and evaluation were made of the influence of the methods of PbCl2 introduction into a Pb-Tl solution upon the efficiency of the Tl extraction process under thermodynamic equilibrium conditions. The analysis made it possible to formulate relevant equations describing the dynamics of the process of Tl extraction from Pb under stirring conditions as well as under the extractant injection into the liquid Pb-Tl solution conditions. In the part concerning experimental work, results are given for tests on the Tl extraction process from Pb-Tl liquid solutions of initial Tl content of approximately 0.05% mass using PbCl2 or, alternatively, Cl2(g) conducted in laboratorial scale. The tests made it possible to establish the influence of time, temperature, mass and the method of introducing the extractants into the liquid upon the level of Tl extraction from a Pb-Tl solution. Labels used in the text. WT1m - TI content in metallic phase, % mass WT1s - TI content in chloride phase, % mass wpTlm - TI content in metallic phase in initial state, % mass W°Tlm - TI content in metallic phase in equilibrium conditions, % mass m°m - initial mass in metallic phase mm - mass in metallic phase mPbC12 - lead chloride mass fed to the system MPbC12-TIC1 - mass in chloride phase MPb - lead atomic mass, g/mole MT1 - thallium atomic mass, g/mole K - Nernst distribution coefficient Xi - mole friction of solution component X°PbC12 - mole friction of PbC12 in saturated solution X°T1C1 - mole friction of T1C1 in saturated solution T - temperature, K R - gas constant, J/(mole K) k - kinetic equation constant, 1/(%-min.) ?i - solution component activity coefficient e - extraction rate, %

Jan 1, 2008

By K. -I. Higuchi, M. Mizutani, K. Haga, A. Shibayama, A. Batnasan

In recent years, the quality of iron ores has decreased due to the increase in the content of impurities, namely quartz, aluminum, phosphorus, and sulfur. It indicates that the removal of impurities from iron ore is an extremely challenging task. In particular, the high amount of phosphorus in iron ore could be a problem for energy consumption and CO2 emission in the steelmaking process. To reduce the impact of phosphorus, mainly two approaches: the utilisation of low-phosphorus iron ore, or dephosphorisation of high-phosphorus iron ore using mineral processing technology, have been suggested. In this paper, the removal of phosphorus from a low-grade high-phosphorus iron ore containing 0.1 mass% P and 57.5% Fe by alkaline roasting and wet grinding is discussed. The iron ore consists mainly of hematite, goethite, and quartz. Effects of sodium hydroxide concentration used as an alkaline source, roasting temperature, grinding time, and particle size on the dephosphorisation of highphosphorus iron ore were investigated. The dephosphorisation efficiency, iron loss, and mineralogical components of low-grade high-phosphorus iron ore under various experimental conditions were characterised by using XRD, SEM-EDS, and particle size distribution analysis. Results showed that the phosphorus content was lowered from 0.1 mass% to 0.034 mass%, while the iron grade reached 59.8 mass% from 57.5 mass% by alkaline roasting with 0.05 w/w NaOH at 300 °C for 2 h, followed by wet grinding in an attritor with water for 30 seconds at room temperature. Under the experimental conditions, the dephosphorisation rate was about 54.7%, and the solution obtained by wet grinding contained 22.7 mg/L of phosphorus and 21.5 mg/L of iron. The recovery rate of iron by this process reached 99.9%. Keywords: Iron ore, phosphorus, dephosphoriszation, alkaline roasting, wet grinding

Jan 1, 2020