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By Margaret M. Ragin

In a cooperative effort between the U.S. Bureau of Mines and the Florida Institute of Phosphate Research, with input from the phosphate industry, the conversion of phosphogypsum to sulfur has been investigated. The first step in the conversion scheme involves reduction of phosphogypsum to calcium sulfide. Effects of temperature, catalyst, reaction time, and type of reductant (carbon monoxide and coal) are discussed. It was determined that phosphogypsum could be reduced to calcium sulfide at 850° to 1,000° C using either coal or carbon monoxide as the reductant. The required temperature was lowered to 750° C using ferric oxide or magnetite as a catalyst for the reduction reaction. Results indicate that as the volatiles content of the coal is increased, reaction temperature may be decreased to obtain a given conversion, or if the reaction temperature is maintained constant, the conversion can be increased. Best results were 95- to 100-pct conversion using a high-volatile coal at 800° to 850° C. Addition of a catalyst increased calcium sulfide yield when low- or medium-volatile coals were used as reductants, but had little effect when high-volatile coals were used.

Jan 1, 1990

Provide exhaust face ventilation to remotely-controlled continuous mining machines making extended advances without exposing workers to unsupported roof. Approach Modify the sprayfan to move additional air to and from the coal mine face. Unmodified, sprayfans are capable of ventilating the face with 20-foot brattice setbacks. Additional sprays on the rear of the mining machine allow setbacks to be extended up to 40 feet.

Jan 1, 1988

By Robert R. Stein

Using an automated drill test fooure, the U.S. Bureau of Mines measured the sound power levels produced by a small, pneumatic, rotary roof drill. A series of tests was conducted to determine (1) the relative effectiveness of several drill muffling schemes and (2) the relationship between drill sound power and pneumatic power supplied to the drill. The influence of rotation rate (i.e., airflow) and feed thrust on the penetration rate of the drill was also noted.

Jan 1, 1989

By C. J. Thompson

Two sulfur compounds--the 2,2,5-trimethyl- and the 2,2,5,5-tetramethyl derivatives of thiacyclopentane--were identified in Wilmington, Calif., crude oil, using microdesulfurization and gas-liquid chromtography techniques.

Jan 1, 1963

By R. S. Fowkes

A study was made by the Bureau of Mines of the penetration of selected granular materials in an unconfined state by wedge-shaped tools having dimensions comparable with the dimensions of the particles composing the materials. The output force for larger particles fluctuated radically. A custom-designed integrator was used to obtain work as a function of depth of penetration in the form of smooth curves. The influence of wedge angle, depth of penetration, penetration rate, entry angle, compaction state, and particle size on the force required and the work performed was ascertained. Empirical equations describing force and work as a function of penetration were obtained for each set of experiments.

Jan 1, 1973

Reduce the costs associated with conventional treatment of acid mine water. Approach Conventional treatment of acid mine drainage consists of plants requiring large mixing and aeration tanks, mechanical aerators and large, shallow settling ponds. Such plants are usually very costly to construct, maintain and operate. The Bureau of Mines has developed a simple, low-maintenance, highly efficient system to treat acid mine drainage which mixes, aerates, and neutralizes mine water Simultaneously in the existing discharge pipeline by using the pressure generated by the deep mine discharge pumps. The mixing and aeration action of the in-line system significantly increases oxidation rates of ferrous iron. Iron and manganese are removed, even at near neutral pH levels, due to the high efficiency of this system. How It Works The In-line Aeration and Treatment System (ILS) consists of two commercially available components, a jet pump (ejector) and a static mixer. The jet pump is simply a nozzle that converts water, already under pressure, into a high-velocity stream that entrains air by Venturi action. If neutralization is required, sodium hydroxide or lime is added along with the air at the Venturi opening. The aerated and neutralized water then enters the static mixer, which is a length of internally spiralled pipe that mixes air and water together. The two components, which are both about 8 feet in length, replace the last section of discharge pipe at a point before the mine water is emptied into a pond. Along with the settling pond, these components treat the water so that it meets discharge criteria. The system has been used at surface drainage treatment facilities as well, but in such use a pump is required to provide the necessary pressure drop across the Venturi opening.

Jan 1, 1985

By Arnold F. Stalder

The measurement of various gas concentrations in the atmosphere at a particular location has become a problem of considerable importance. Levels that need to be monitored vary from the range of percent for constituents such as oxygen to parts per million levels for gases like nitrogen dioxide. In particular, mine air can become contaminated with noxious or toxic gases from several sources: fires within the mine, diesel-powered equipment, and explosive sources. The contaminants that result are carbon monoxide (CO), carbon dioxide (CO2), and oxides of nitrogen (NO and NO2). Additionally, oxygen (O2) may be depleted. Thus, the workman can be exposed to potentially toxic or asphyxiating atmospheres. A device was needed that will continuously monitor the mine air in working areas and provide warning of hazardous atmospheres. The Mine Air Monitor was conceived as being a portable, rugged instrument capable of measuring the concentration of the various atmospheric constituents in the mine environment. The unit was to provide both warning signals and quantitative measurements when hazardous contaminants existed at too high a level, or when the oxygen was being depleted. The initial concept involved optical sensors for all of the contaminating gases to be measured, namely CO, CO2, CH4, and NO2, and an electrochemical cell to monitor O2. When the explosion proof requirements of Schedule 2-G made the concept appear to be unfeasible from the standpoint of weight and portability, the program was redirected and a three channel monitor employing electrochemical sensors was adopted. In this case the gases to be monitored were O2, CO and NO2. The remainder of the program was oriented towards obtaining good, commercially available lectrochemical sensors for the above gases, testing them, reducing deficiencies noted during these tests, and making the necessary modifications to integrate the three sensors into a Mine Air Monitor suitable for the mine environment.

Jan 1, 1974

By R. V. Ramani, R. Bhaskar

"One of the primary means of control of health hazards from respirable contaminants in mine atmospheres is through design and operation of mines to meet mine health and safety regulations and recommended practices. A U.S. National Academy of Sciences study concluded that for significant progress in coal mine dust control, research should be directed more toward obtaining fundamental understanding of the origin, transport and characteristics of respirable coal mine dust. Theoretical and experimental studies on transport of dust · in mine airways, particularly coordinated efforts to validate theory with practice, are scarce. Some empirical models, developed on the basis of experimental data, are available but these models cannot be applied to new conditions. The purpose of this paper is to present the results of theoretical and experimental studies on the transport and deposition of dust in mine airways. This study is a part of an ongoing research project in the Generic Mineral Technology Center on Respirable Dust.In the paper, the assumptions of the modeling phase of the project and the development of a convectiondiffusion equation for dust transport in mine airways are outlined. The important aspect of the modeling effort is the capture of the deposition phenomenon. The experiments performed under controlled conditions in a typical mine airway, as well as under normal mine operating conditions, are discussed. The comparison of the model predictions with experimental results are made to identify critical areas of agreements and deviations. The implications of the findings and areas for further research and development are presented."

Jan 1, 1990

By P. L. Woolf

Three trials with oxygen-enriched unheated blast air are described. The trials were conducted in the Bureau of Mines experimental blast furnace located in Bruceton, PA. The first trial utilized moisture addition to the oxygenated blast. The second and third trial were conducted with natural gas injection. The test was basically a feasibility study and in that regard the practice was demonstrated to be feasible and also have possible advantages over hot blast operation. The testwork was conducted in 1964 and 1965 as part of a continuing study of iron making technology in cooperation with several North American Steel Companies.

Jan 1, 1985

By H. L. Burmeister

This report describes the mining and milling practices used by the Eastern Magnesia Talc Co. at its Johnson, Vt., operation. The report also contains a description of the local geology and all available information on cost and performance data. Since 1925 the mine has produced continuously at an average annual rate of 54,000 tons, and the ratio of ore hoisted to finished product is roughly 2 to 1. Ore is stoped by a combination of shrinkage and sublevel methods. In any 24-hour period the mill produces an average total of 14 grades of finished talc product, 9 by dry grinding and air classification and 5 by wet grinding and flotation methods. The mine operates one shift per day, 5 days per week and the mill operates on a 3-shift, 5-1/2-day-per-week basis. Operating costs for 1958, on a percentage basis, were mining, 22.34; milling, 54.77; ore haulage, 2.89; and all other, 20.00 percent.

Jan 1, 1963

By Fred N. Kissell, J. E. Matta, J. C. LaScola

The Bureau of Mines made laboratory absorption measurements on oil shale samples, which showed that the amount of methane absorbed is proportional to pressure and oil yield, and can be much larger than would be predicted based solely on porosity. Oil shale cores collected in the field were also measured for their gas content using the Bureau of Mines direct method, Cores taken from deep locations and far from outcrops yielded more gas than cores from shallower locations or at outcrops, when taking into account variations in oil yield, and all data indicate that oil shale mines that are both deep and far from an out- crop will emit low levels of methane gas.

Jan 1, 1977

By Emory Smith

The Victorville cement plant of the Southwestern Portland Cement Co. is located about 1 mile from the city of Victorville, Calif. Two transcontinental railway systems, the Atchison, Topeka & Santa Fe, and the Southern Pacific Railroad, afford shipped facilities. The plant is modern and well kept, as the officials, especially the higher operating officials, take pride in the appearance of the place. Dust has been practically eliminated by the installation of dust collectors and wet grinding. The plant has a rated capacity of 5,000 barrels of cement daily.

Jan 1, 1929

By G. L. Gates

Five possible sources of water for waterflooding of petroleum reservoirs in the arid San Joaquin Valley of California were considered. Three of them (water produced with petroleum, water from a shallow saline aquifer, and waste irrigation water) were analyzed chemically; laboratory information for one (sea water) had been developed during a previous study. A series of laboratory tests made on the fifth source (fresh water) determined the solubility of calcium sulfate dihydrate in water. Laboratory analyses included the following: Chemical analyses of water produced with petroleum and waste irrigation water; solubility of calcium sulfate dihydrate in water and brines; the effect of excess sulfate on the solubility of calcium sulfate in brines; the presence of sulfate-reducing bacteria; and the permeability of cores from a petroleum reservoir to air, to water from other petroleum reservoirs, and to waste irrigation water. The results showed that most of the waters and mixtures of waters are compatible with petroleum reservoir waters and are generally suitable for injection. The calcium content of some of the formation waters is quite high, and care must be taken to prevent precipitation of calcium sulfate dihydrate. The permeability of the few cores tested was about the same to water and brines as to air, indicating that formation damage due to clay swelling will not be serious. The waters most likely to be available for injection are water produced with petroleum, water from shallow saline aquifers, and waste irrigation water.

Jan 1, 1970

By W. G. Messner

Pipelines for transporting crude oil and refined products in the United States totaled 189,982 miles on January 1, 1959. This mileage was less than a 1-percent increase from the 1956 total of 188,540 miles. During the three-year period (January 1956 - January 199), 14,886 miles of new pipe and 10,649 miles of secondhand pipe was laid. Pipe taken up in the same period was 24,093 miles. The facts regarding pipeline mileage were obtained by the Bureau of Mines from pipeline companies and information provided by the Interstate Commerce Commission. Crude-oil gathering lines, as of January 1959, were 40 percent of the United States pipeline mileage and totaled 75,182 miles, an increase of 1,656 miles during the three-year period. Crude-oil trunklines totaled 70,317 miles or 37 percent of the United States pipeline mileage, a decline of 8,277 miles from the 1956 total. Some of this loss is attributed to the converting of crude lines to refined products. Refined product lines in January 1959, totaled 44,483 or 23 percent of the United States mileage, an increase of 8,063 miles during the three-year period.

Jan 1, 1959

By James J. Hanslovan

Stresses that damage coal mine trailing cables were investigated to obtain a quantified description of cable-stress locations, magnitudes, and frequency of occurrence. Stresses occurring in operating mining sections were measured and observed. Answers to questions that arose during the underground investigations were pursued under controlled conditions, both in the field and in the laboratory. Cable-handling suggestions that minimize or eliminate the stresses are summarized in the form of recommendations to mine operators.

Jan 1, 1979

Ten years ago we surveyed in "Uspekhi Khimii" the mechanism of the synthesis of hydrocarbons from CO and H2 (1).5 With new data obtained since then, mostly by Soviet researchers, our previous work (2), dealing with new forms and catalysts of the synthesis, is brought up to elate by reviewing research in this field. FORMATION OF CARBIDES The hypothesis that carbides are intermecliates in the synthesis assumes that carbon monoxide reacts with the metals of the eighth group and that this reaction is connected with the reversible reaction 2CO[=]C +CO2 (1) in a certain range of temperatures (3).

Jan 1, 1958

By P. T. Brooks

A process for extracting 69 percent of the vanadium from weathered Nevada dolomitic shale containing about 1 percent V205 was developed on a laboratory scale by the Bureau of Mines. The process essentially is comprised of salt roasting, leaching with dilute sulfuric acid, solvent extraction, and precipitation of vanadium as ammonium metavanadate. Carbonaceous unweathered shale was less amenable to treatment. A preliminary cost estimate for mining and processing 1,500 tons per day of weathered shale indicated a production cost of about 1 dollar per lb of V205. Considering recent sales at nearly $1. 75 per lb of contained V205, larger scale testing to obtain more definitive process design and evaluation data may be warranted.

Jan 1, 1974

Maintain good blowing face ventilation while taking deeper cuts with a radio-remote, scrubber-equipped miner. Approach A six week in-mine study of face ventilation effectiveness was made by comparing the existing MSHA-approved blowing curtain setback distance of 25 ft with brattice set back distances of up to 50 ft. Effectiveness was determined by measuring methane levels at the face and in the immediate return. How It Works Blowing ventilation systems are commonly used in mines because the high velocity air stream created by these systems rapidly mixes with and dissipates methane generated during the cutting of coal. A drawback to blowing ventilation is that the work area is placed in return air and this may create dust compliance problems for the shuttle car and mining machine operator. To clean dust from the return a number of mining machine manufacturers supply dust scrubbers built into the machine. Dust-laden air is drawn into ducting at the front of the mining machine's boom and is ducted to a scrubbing unit located on the machine's main frame. The clean air from the scrubber is discharged as a high velocity jet toward the return, generally from the left fender of the mining machine. When taking cuts deeper than 20 to 25 ft with a scrubber-equipped machine, the machine's discharge is in by the mouth of the blowing curtain, creating a concern by mine workers that a loss of air to the face could result. However, Bureau of Mines research found that the push or throw of air toward the return by the scrubber discharge jet allows good face ventilation to be maintained with extended curtain setbacks.

Jan 1, 1984

By Rustu S. Kalyoncu

A major goal of the Bureau of Mines is to conserve the Nation's mineral resources by developing improved performance materials. In support of this mission, a survey of the state of the art of chemically bonded refractories has been made, covering the scientific literature, government reports, and patents. This review includes research and development results for phosphate, silicate, oxychloride, oxysulfate, and other bonding agents used in refractories manufacture. A significant finding of the review was that references on bonding mechanisms, bond formation kinetics, and other important process parameters and conditions were few and universally vague. As a result, recommendations are made to expand research efforts to investigate the kinetics and mechanisms of reactions in chemically bonded refractories.

Jan 1, 1982

By O. W. Terry

The Skene mine, in the Elizabeth District, Illinois, produced lead are from 1901 to 1907. Three exploratory holes drilled just north of the mine were said to have penetrated 40 feet of good zinc are. During the summer of 1944, the Bureau of Mines drilled check holes close to what appeared to be two of the three old holes. They also drilled two holes to the south of the mine and one into the core of the deposit. Results of the investigation are given in this report.

Jan 1, 1948