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By Suzann C. Ambrosio

The mineral industry in Burundi continued to be a minor contributor to the 1980 gross domestic product (GDP) estimated at $293 million in constant 1970 prices.2 Mineral export revenues, primarily from cassiterite, increased by a factor of 15 between 1979-80, reaching approximately $434,000 by yearend 1980. Gold, bastnasite, colombite-tantalite, and wolfremite continued to be exploited on a small scale, using manual and semimechanical methods. Despite a sharp decline in mining activities during 1979, attributed to a lack o? profitability and shortage of construction materials, the mining sector exhibited signs of recovery during 1980. The mineral exploration budget grew 32% over 1979 levels and was equivalent to approximately $42,000 in 1980. In addition, the Burundi Geographical Institute (IGE BU) was created in September 1980 and given responsibilities to collect cartographic, topographic, hydrogeologic, and other geomorphological data., SONIBUROM, the Burundian and Romanian Government joint mineral corporation, conducted mineral deposit inventories during 1979-80 and has been charged with exploiting some of these as yet unspecified resource areas. Another Burundian-Romanian effort, called Mabaya-Butahana, was initiated to search for gold deposits. Meanwhile on the Ruzizi plain, alluvial gold prospecting, with an estimated grade between 0.2 to 1.0 gram per ton, was carried out on a small scale.

Jan 1, 1982

By Sidney Katell

This study presents the economics of the hot-carbonate purification process for removing C02. It considers three variations of the process in order to meet the design specifications, which call for a feed-gas flow of 10 million standard cubic feet per hour (std.c.f.h.) with C02 inlet concentrations of 10, 20, and 30 percent and exit C02 values of 5, 2, 1, 0.5, and 0.1 percent. Inlet pressure and temperature are 350 pounds per square inch [e] (p.s.i.g.) and 300° F., respectively. Estimated capital and operating costs are shown in the following to tabulations: [ ]

Jan 1, 1960

By J. A. Ruppert

The Bureau of Mines investigated methods of refining iron-contaminated zinc to marketable quality and developed a laboratory-scale process in which aluminum, added as a refining agent, reacted with the iron, forming solid Fe2Al which floated to the surface of the melt. Solids were separated by both filtration and centrifugation, using a unique type of "dipping" centrifuge devised during the work. Typical zinc recovery was 95 percent, and iron content of the metal was lowered from 0.37 to 0.02 percent.

Jan 1, 1967

The Bureau of Mines, in an effort to improve resource conservation, mine planning and development, is currently investigating the loading behavior of pillars in multiple-seam developments. The simultaneous mining of two or more coalbeds may cause instability between room-and-pillar operations resulting in an interaction known as pillar load transfer. Although pillars may be adequately designed for single-seam mining, the development of a second seam may complicate loading conditions in both operations. If pillars are not adequately designed to contend with this load transfer, failure of the mine structure may result. To improve multiple-seam development and pillar design, the Bureau studied the loading characteristics of pillars in three separate multiple-seam operations. In all three cases, instrumented pillars recorded increasing pressure after development of the second seam. Increases in the average pillar pressure ranged from 7 to 110 pct over predicted overburden loads. An analysis of pillar loading before and after second-seam mining indicates that the ratio of overburden to innerburden thickness is a critical factor influencing load transfer. Based on this relationship, safety factors for case study pillars are calculated and alternative design considerations are discussed.

Jan 1, 1988

By S. R. Zimmerley

Recent investigations of finely ground materials have verified Rittinger's law of crushing.4, This law states that the surface produced is proportional to the work expended in the crushing operation. Thus, for a unit of work applied to crushing quartz a definite amount of surface will be produced. Obviously, this amount of work applied to some other mineral will not produce equivalent surface. It follows that in an investigation of mill practice, where ore is being crashed, the relative crushing resistance of the component minerals must be known. In a previous investigation of the Rittinger law,5 the crashing resistance that is, the work required to produce a unit of surface - was accurately determined for quartz. The surface values were obtained by means of the rite of dissolution of quartz in hydrofluoric acid.6 If it were possible so to measure surface on other minerals the determination of relative crushing, resistance would be a simple matter; however, the results obtained on minerals other than quartz by a dissolution method were not encouraging. Moreover, if accurate values could be obtained by dissolution this method could probably never be used on a mixture of minerals such as occurs in an ore.

Jan 1, 1929

By A. J. Kraemer

"Introduction In 1925 the Bureau of Mines published as Technical Paper 346 a discussion of typical crude oils of the Western Hemisphere. That paper was one of a series of surveys of typical crude oils, and was the first of these to deal with properties of crude oils from countries other than the United States. The paper contains comments, tabulated data, and individual analyses of crudes typical of the producing districts of Canada, Mexico, Trinidad, Venezuela, Argentina, Colombia, and Peru; for comparison, it also has analyses of typical crudes from the chief producing districts of the United States.The Bureau of Mines undertook a study of foreign crude oils for two reasons: First, foreign fields are potential sources of supply for the United States; in fact, considerable quantities of some foreign crudes have already been imported. Second, these oils are very similar in physical and chemical properties to oils found in the United States, and a study of these resemblances has scientific value.After the publication of Technical Paper 346, the attention of the Bureau was called to the fact that the two analyses of crude oil from Venezuela which appeared in that paper were not completely representative of the production of that country. Samples of other types of oil were procured through the cooperation of Mr. R. Ogarrio, manager of the Texas Petroleum. Co., Huston, Texas, and officials of the following companies operating in Venezuela; British Controlled Oilfields, Ltd., Venezuelan Oil Concessions, Ltd., Creole Syndicate, and Venezuelan Gulf Oil Co.. Samples were collected and dispatched by Mr. D. 3. Park, representative in Maracaibo, Venezuela, of the Texas Petroleum Co. The value of the interest and cooperation of these agencies in obtaining the samples is gratefully acknowledged."

May 1, 1927

By E. S. Leaver

Experiments dealing with the dissolution of silver by cyanide from various silver minerals-were reported, several years ago.4/ This work showed that the silver in some silver minerals is completely and readily soluble in cyanide solution, whereas other silver minerals must be given special treatment before or during cyanidation to obtain much dissolution of the silver by cyanide. Flotation as a method for treating silver ores has not been studied much, except in the case of base-metal ores carrying silver, Particularly lead-silver ores. However, many mills now are concentrating gold ores by flotation, and when such ores also contain silver the recovery of the silver by flotation is of considerable importance. Moreover, many mines contain ore in which silver is the principal valuable constituent. Some of these ores are amenable to cyanidation, but the cost of a cyanide plant may be prohibitive because of limited ore bodies or other factors. In such instances the successful application of flotation would mean that the property could be operated.

Jan 1, 1939

By J. D. Brown

The electron optics, vacuum system, and sample stage assembly for the Bureau of Mines? electron probe X-ray spectrograph were purchased. Four scanning curved-crystal spectrometers, two reflection- and two transmission-type, were designed and constructed by the authors. The reflection spectrometers are placed in a vacuum chamber for measurement of long-wave-length X-radiation. Detection, pulse-amplitude discrimination, and recording circuits are provided for the simultaneous measurement of four X-ray spectral lines. Minimum spot size is approximately 2 microns in diameter at 30 kilovolts and a sample-to-ground current of 5 x 10-8 ampere. At this voltage and current the limit of detection with reflection spectrometers is less than 0.05 weight-percent for most elements. The limit of detection for elements determined by transmission-type spectrometers, evaluated at 35 kilovolts and 5 x 10-8 ampere, is approximately 0.1 weight--percent for all elements having excitation voltages below 20 kilovolts. In general, reflection spectrometers exhibited satisfactory but poorer resolution than the transmission type, resolution of the spectrometers being limited primarily by crystal imperfections, with greater mosaic structure being introduced by the grinding process for the reflection crystals. Several applications of the electron probe X-ray spectrograph are described. Analysis of a uranium-steel is discussed in detail to illustrate calculation of composition from measured X-ray intensities.

Jan 1, 1962

By Raja V. Ramani, Wilson Miola

"The potential health effects of quartz-bearing airborne dust in mine and mill atmospheres point to the need for the quantification of quartz content in the source material for determining the source-sink relationships and for choosing applicable control measures. While a standard method exists from a regulatory point of view for the sampling of coal mine atmospheres for determining (i) respirable dust concentrations and (ii) the amount of quartz in the samples, there is no generally accepted standard method for quartz analysis in bulk samples of coal and host rocks. Generally, the bulk sample is reduced to a powder for producing quartz analysis samples. Extensive controls arc necessary to ensure representativeness of the analysis samples when these are very minute fractions of the bulk samples. Since the amount of analysis sample is not limited, alternative methods for quartz analysis may also be tried. It is, however, necessary to adopt a procedure which will satisfy several statistical requirements to guarantee representativeness of the quartz analysis samples.In this paper, the important factors in the preparation of quartz analysis samples from the host rocks and bulk samples are discussed. The method developed to prepare the analysis samples is outlined. The results of application of the procedures are presented. The procedure developed for quartz analysis sample preparation is based on sound statistical foundations. The procedure has been validated for reproducibility and homogeneity.The current methods used for quartz analysis in powders are the P-7 infrared spectrometry and quantitative X-Ray Diffraction (XRD). Both have similar restrictions concerning the sample characteristics and operational problems, which arc intrinsic to radiation beams, device geometry, mechanics and controls of the radiation behavior. Although improvements can be made in the spectrometers and diffractometers, some of the most important steps are the procedures for analysis sample preparation from bulk samples and for calibration of the instruments. The sample preparation process is often referred to as one of grinding and sizing the bulk sample to generate the powder for the scanning devices. The particle sizes are referred to and their influence emphasized but the representativeness of the sample is assumed. Assuring sample representativeness during the sample preparation procedures is critical.For the sampling of airborne respirable dust in coal mines, the collection devices, the collection procedures and the analysis procedures are defined. This is not true for bulk samples where weights must be reduced thousands of times to generate the analysis samples for the scanning devices. The specifications to be developed may include bulk sample amount, sample reduction procedures, sample particle size distribution and sample amounts. However, the common problem of insufficient sample amount which is often encountered with mine airborne dust samples need not exist for bulk samples. Further, the same bulk sample can yield analysis samples for several experiments. The latter, of course, requires sample homogeneity.Three concepts are important in the selection of any procedure for sample preparation and analysis. These arc accuracy, reproducibility and representativeness. The adopted procedure has to guarantee a homogeneous sample representative of the population, a defined level of accuracy and reproducibility. Important statistical concepts are embedded in these requirements, particularly with respect to estimation and dispersion errors. Accuracy and reproducibility are totally different though not independent concepts. Estimation is related to accuracy and the true value. Dispersion is related to reproducibility and is measured by the classical statistical standard deviation of the distribution of a series of measurements or analysis performed over the same lot or analysis sample. The dispersion variance (or dispersion error) does not tell a"

Mar 1, 1992

Estimate costs for projected uranium in-situ mining operations. Approach Develop a computer model and an associated data base which will allow users to supply data applicable to a specific mining site in order to estimate total capital and operating costs for a potential in-situ mining operation at the site. How the Model Works The model requires a minimal amount of input from the user. The data input must be known or estimated information about a potential in-situ mining operation. The user can also supply any additional project specifications. The computer model uses a process-engineering approach and determines through a discounted cash flow analysis the total capital and operating costs for the life of the project. This time-span measures from the start of the pilot-scale operation through to the site's restoration and reclamation. The model will determine the production cost per pound of material mined subject to the rate of return identified by the user. Conversely, it will also solve for the rate of return realized for the specific sales price per pound. [ ] Currently the model's data base can tai ns costs, rates, and specifications for Texas and Wyoming, the only states where commercial uranium in-situ mining is being conducted. However, this model can be used by anyone who is conducting in-situ leaching or who plans to leach uranium in-situ. At least part of any uranium deposit has a potential for in-situ mining.

Jan 1, 1982

Improve the efficiency of stainless steel pickling (chemically cleaning) operations by providing the industry a quick and convenient method to estimate pickling solution behavior and to estimate recommended ranges of nitric and hydrofluoric acid concentrations for effective pickling of stainless steels. Background Iron, chromium, and nickel in stainless steels react with nitric and hydrofluoric acids during pickling. Ions of these dissolved metals complex or combine with the acid anions. When the total metal concentration reaches about, 50 grams per liter of pickling solution, the solution no longer serves its purpose and is considered spent. Knowledge of cation and anion species in these pickling solutions contributes an insight into pickling chemistry and allows estimates to be made of the most effective ranges of acid concentrations. The Bureau developed a computational model of the complex equilibrium chemistry occurring among iron, chromium, and nickel and the pickling solution. Total concentrations, in grams per liter, of nitrate, fluoride, iron, chromium, and nickel were used as input; output was 17 cation and anion molar concentrations. The model, in the form (if an equilibrium program on a mainframe computer, was used extensively to facilitate Bureau research by determining chemical complexes in numerous stainless steel pickling solutions. However, the program's availability to members of the stainless steel industry, its intended users, was limited because of lack of mainframe compatibility and the difficulty of program maintenance.

Jan 1, 1989

Develop a method of dewatering ultrafine mineral waste that will increase water recovery from the waste and produce a dewatered material that eliminates the need for large settling ponds. Background In the hydrometallurgical treatment of many ores and concentrates to recover mineral values, slurries of fine particles are generated. Some of these slurries settle slowly and are difficult to dewater. This inherent property causes environmental and handling problems for the minerals industry. Examples of such problem wastes are clay wastes generated during the mining and beneficiation of phosphate ores, the processing of coal to produce a low-ash material, the cleaning of bentonite, beneficiation of potash, and the recovery of mica from clay-containing ores. At the present time these waste slurries are treated by techniques such as impoundment, thickening, and thickening followed by filtration. But factors such as new environmental regulations, the loss of mineral values in the waste slurries, the need to recycle water in the processing facility, and the lack of land suitable for impounding the waste have shown that new technology will be needed in the future to handle waste slurries.

Jan 1, 1986

By J. E. Chilton, Jr. Dubaniewicz

Many mines rely on toxic gas sensors to help maintain a safe and healthy work environment. This report describes a prototype monitoring system developed by the U.S. Bureau of Mines (USBM) that uses light to power and communicate with several remote toxic gas sensors. The design is based on state-of-the-art optical-to-electrical power converters, solid-state diode lasers, and fiber optics. This design overcomes several problems associated with conventional wire-based systems by providing complete electrical isolation between the remote sensors and the central monitor. The prototype performed well during a 2-week field trial in the USBM Pittsburgh Research Center Safety Research Coal Mine.

Jan 1, 1995

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

MINE VENTLATION NETWORK ANALYSIS

Jan 1, 1977

By W. W. Adams

"A recent paper prepared by the writer summarized the results of an analysis of the accident records of 34 metal mines for the calendar year 1925. The present paper summarizes the results of a similar analysis of the accident records of 59 coal mines for the same year. This summary is based upon reports furnished to the Bureau of Mines, Department of Commerce, by operating companies that par¬ticipated in the National Safety Competition of 1925.The purpose of the Competition was to establish the lowest accident-severity rate, thus showing the smallest loss of time from accidents in proportion to total number of man-hours worked. The reports covered all lost-time accidents that occurred during the year, that is, all accidents that disabled an employee beyond the day or shift on which the accident occurred. Detailed information for each of the 59 coal mines is given in the appended table. Each mine employed at least fifty men underground; over half of than employed more than 200 men underground. Hence the accident records should be typical of those of large-scale mining operations in general where the company is devoting special attention to accident-prevention work. The mines covered by the reports are situated in eleven States: Alabama, Illinois, Indiana, Kentucky, Maryland, Ohio, Pennsylvania, Tennessee, Utah, Washington, and West Virginia.A tabulation of the reports covering the 59 mines showed an accident-frequency rate of 123 per million hours of ""exposure* and an accident-severity rate of 10.214 per thousand hours of exposure3. The total volume of exposure or employment was 29,117,561 hours, representing the equivalent of work of 12,000 men for three hundred 8-hour shifts. The records covered employment and accident above ground as well as underground, although they did not include stripping or open-pit mining. Accidents during the year resulted in 33 deaths, 1 permanent total disability, 28 permanent partial disabilities, and 3,510 temporary injuries. These accidents represented a loss of tine equal to 297,417 man days. In arriving at this lost-time equivalent, each fatality and permanent total disability was weighted at 6,000 lost days (see footnote 3), as specified in the scale adopted by the International Association of Industrial Accident Boards and Commissions; permanent partial disabilities were weighted according to nature of injury, in accordance with the scale adopted by the :Board; temporary injuries were weighted according to the actual number of calendar days during which the employee was incapacitated as a result of the injury."

Nov 1, 1926

By T. A. Henrie

The Federal Bureau of Mines has investigated methods of sodium reduction of titanium chlorides to produce high purity titanium metal (14).4/ This investigation was made to obtain a better understanding of the reactions involved in sodium reduction of titanium chlorides and was part of the Bureau's activities toward improving the technology of titanium. Theoretical and experimental evidence show that sodium reduction of titanium tetrachloride occurs by stepwise reactions. The first stage reduction between sodium vapor and vapors of titanium chlorides produces titanium di-and trichlorides which subsequently condense with sodium chloride to form a salt mixture. The second stage reduction takes place in the condensed salt mixture between sodium and titanium subchlorides. Final reduction is a heterogeneous reaction between two separate phases, the a phase which consisted of sodium dissolved in sodium chloride and the ß phase titanium subchlorides dissolved in sodium chloride. The mechanism of the heterogeneous reaction between these phases is electrochemical in nature. The model proposed is a galvanic reaction at the interfacial region.

Jan 1, 1960

This publication summarizes, for potential contractors and other interested parties, the research, development, and demonstration contract projects programed by the Bureau of Mines for fiscal year 1980 (October 1, 1979 - September 30, 1980) under its Minerals Health and Safety Research program. The objective of these projects is to provide an ordered and sequenced series of advances toward the Bureau's overall goal of providing the system technology required to create a healthier and safer working environment for the Nation's mining and minerals processing workers.

Jan 1, 1980

By Thomas P. Mucho, Dennis Dolinar, Christopher Mark

During the 1990s, the former U.S. Bureau of Mines conducted a number of field studies in which the performance of different types of roof bolts were evaluated in different geologic environments. The studies used a standard suite of measurements, including multipoint extensometers, strain-gauged roof bolts, and roof bolt load cells. The sites were chosen to investigate the effect of a variety of parameters, including installed tension, bolt capacity, grout annulus, and horizontal stress orientation. Although not fully successful, the measurements provided valuable insights into each of these issues. They also showed that instrumentation and monitoring have important advantages over observational methods for comparing the performance of different roof bolting systems.

Jan 10, 2000

By E. M. Tignor

A research program to aid development of improved methods for increased production of petroleum from partly depleted reservoirs is a vital part of the Bureau of Mines effort to effect true conservation of that mineral resource. This report presents results of an investigation to identify the clay minerals within some Appalachian petroleum-reservoir sands, the effect of clay content on the fluid-flow behavior of those sands, and the use of brines in water-flooding operations. Permeability measurements using kerosine, calcium chloride brine, simulated oilfield brine, potassium chloride brine, sodium chloride brine, and distilled water were made on reservoir-rock cores. Clay fractions were separated from sand grains of disaggregated portions of each core sample, and the clay minerals were identified by the differential thermal analysis method. Relations of the permeability to various fluids were developed.

Jan 1, 1957

By Donald W. Fausett

This Bureau of Mines publication presents a system of thermal decompositions providing an adequate description of the mechanism of oil shale pyrolysis. Specific rate constants for systems of thermal decompositions studied are estimated via a least-squares procedure. The estimates thus obtained provide a mathematical model of the corresponding thermal decomposition system. A model that generates a good fit to published Bureau of Mines experimental data, in comparison with other models studied, is based on a thermal decomposition system consisting of two first-order reactions and three second-order reactions. Values computed for the specific rate constants corresponding to this system are shown to exhibit a temperature dependence that is in good agreement with the Arrhenius equation.

Jan 1, 1974