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By Charles E. Semler

The possible utility of selected compositions in the systems SrO-ZrO2-MgO and SrO-ZrO2-Dolomite for commercial refractory products was confirmed in this study. Specifically the compositions of interest are located in the sub-systems SrZrO3-ZrO2-MgO and SrZrO3-ZrO2-Dolomite. Both sub-systems have regions that are not affected by hydration, but the sub-system SrZrO3-ZrO2-MgO has a larger candidate compositional region. Solid state phase relations were determined for the subject systems over the temperature range 1600°C to 1300°C, with compatibility diagrams presented for each. The systems appear to show good refractory character with no apparent low melting compositions. As the compositions of commercial interest lie mostly in the higher ZrO2 portion of each system, information is presented regarding the firing treatment required to develop stabilized cubic ZrO2. A list of suggestions for further study of these systems, to further delineate the characteristics required for possible commercial utilization, is presented.

Jan 1, 1982

A spectrographic procedure applicable to the semiquantitative determination of 29 elements in tungsten is presented. The method is designed to give estimates of impurity concentrations up to 500 p.p.m. Limits of detectability range from 0.3 p.p.m. for the more sensitive elements to 100 p.p.m. for the less sensitive ones. Tungsten metal samples varying in particle size from minus 300-to 30-mesh are excited in the presence of 5 percent germanium with a direct current arc. Germanium acts to stabilize the arc, minimizes the volatilization of tungsten, and serves as an efficient carrier to sweep impurities from the tungsten into the excitation zone. Curves are presented that show the volatilization behavior of germanium, tungsten, and impurities in tungsten at different concentration levels. Data obtained were used as guides in establishing the method of analysis. In the absence of established reliable analytical procedures for determining many impurities in tungsten in the parts per million concentration range, the spectrographic method described here should prove to be helpful in evaluating high-purity tungsten.

Jan 1, 1961

By J. A. Woolf, E. S. Leaver, N. K. Karchmer

"In the cyanidation of silver ore, the need of oxygen is well recognized. Various methods have been introduced for supplying the oxygen. In usual practice, air is the source of oxygen and the methods of application are mechanical.This article gives the results of touts made to show the rate of dissolution of silver from each of the common silver minerals in cyanide solution, under conditions similar to those used in the practical recovery of silver from its ores. The effect of oxygen in aiding the dissolution of the silver from each mineral is also shown by a comparison of the methods of supplying the oxygen. Oxidation by preliminary roasting (500°C.) of each mineral sample gives the maximum extraction of the silver by treatment with cyanide.Each silver mineral5 used in these experiments was as pure as could be obtained from the mineral dealer. In their natural occurrence, silver minerals are not usually free from mineral impurities. They are usually closely associated with other minerals often forming, a complex mixture. The form of crystallization, the proportions, and properties of the diluent that incases or has been dispersed with the silver mineral may decidedly affect the dissolution rate of the silver from each mineral. While the following results should aid in the cyanidation of silver ores, each ore should be studied from the basis of the form and condition of the silver that is to be recovered.All the tests reported in this article were made on synthetic samples, prepared by mixing the particular silver mineral with clean sea sand. Each mineral was ground in an agate mortar to pass 100-mesh before mixing with the sand which had previously been ground in a porcelain pebble mill to 100-mesh. Such proportions of each mineral and the sand were used as to give a head assay of approximately 20 ounces of silver per ton to the synthetic sample.Agitation was carried on in stoppered bottles approximately one-third full of pulp, method apparently supplied all the atmospheric oxygen that would be taken up by the solution under usual conditions, because tests conducted in open bottles did not show increased recovery,"

Jan 1, 1931

By Gopala N. Krishnan

The most promising candidate for the recovery of alumina from non-bauxitic sources is the leaching of clay by HCL acid followed by crystallization of aluminum chloride hexahydrate (ACH) by hydrogen chloride sparging. Hydrothermal precipitation of boehmite ( ?-A100H) from aluminum chloride solution will simplify the process, will reduce energy consumption and will eliminate corrosion problems involved in calcination of ACH to obtain alumina. This report summarizes the results of Phase I of a program to study the precipitation of boehmite from AlC13 solutions. The amount of boehmite precipitation from dilute A1C13 solutions (5 wt%) is . negligible below 200°C. Above 200°C the precipitation increases with increasing temperature approaching 40% at 300°C. Addition of HCl acid to the dilute A1C13 solution even in small quantities drastically reduces boehmite precipitation. Solution impurities such as Fe, Ca, Mg, or Na substantially promote the precipitation of boehmite. No precipitation is observed from concentrated A1C13 solution (30wt%) representing the leach liquor.

Jan 1, 1980

By D. T. Randall, H. W. Weeks

The burning of coal without smoke is a problem that concerns the Government directly because of the advantages of smokeless combustion both in public buildings and on naval vessels. In addition, smoke abatement is a factor in conserving the fuel resources of the United States. Hence, as part of its general investigation of the best methods of utilizing the coals of this country, the Bureau of Mines, which is in charge of the fuel-testing work formerly carried on by the United States Geological Survey, has made extended tests to determine the conditions necessary for the smokeless combustion of bituminous coal in boiler furnaces. Bulletin 39,a a preliminary report, treats the smoke problem from a theoretical point of view, detailing the steps that are being taken by . municipalities, manufacturers, and citizens to abate smoke, also showing the possibility of a clean city. The present bulletin not only shows that bituminous coals high in volatile matter can be burned without smoke, but also that large plants carrying loads that fluctuate widely, where boilers over banked fires must be put into service quickly and fires forced to the capacity of their units, can be operated without producing smoke that is objectionable. Proper equipment, efficient labor, and intelligent supervision are the necessary factors.

Jan 1, 1912

By J. W. Paul

This paper deals with the second phase of an extensive research on coal-mine ventilation factors. A comprehensive report of the entire work is in course of preparation, but abstracts of the various chapters are being prepared in order to make the results public as rapidly as possible. Part 1 dealt with the resistance of unobstructed entries and was issued as Serial 2621 of the Bureau of Mines, in July 1924. Description of tests. After the resistance of an unobstructed entry to flow of air had been determined by tests in the Experiment mine, mine cars were; run into the test section in various arrangements and the increase in resistance was determined. The cars used were of the wooden type with loose end gate, and would hold about one ton of coal, level full. They were 7 feet long. 4 feet 2 inches wide above the wheels, 3 feet high, and had a cross-sectional area of approximately 10 square feet. The average area of the entry was about 57 square feet, the ratio of unobstructed to total area being about 17.6 per cent. The track gage was 42 inches and the wheel-base 20 inches.

Jan 1, 1924

By J. A. Taylor, H. F. Yancey

"INTRODUCTION Froth flotation as applied to coal is a process for separating desirable carbonaceous material from undesirable inorganic matter. In general, the feed must be finer than one eighth inch in size. The principal use of the process in the preparation of coal appears to be in the treatment of the fine sizes produced by breakage during mining and preparation.The Bureau of Vines in Information Circular 6714 has published general information on coal flotation, summarized investigative studies of the process, and described operating plants throughout the world with their tonnage, reagent consumption and operating costs.4ACKNOWLEDGMENTSThe present study of means for depressing pyrite and reducing ash ty froth flotation was conducted at the Northwest Experiment Station of the United States Bureau of Wines in cooperation with the College of vines. University of Washington, under the general direction of A. C. Fieldner, chief engineer, Experiment Stations Division, Bureau of Wines. Grateful acknowledgment is made for suggestions and criticisms received from W. H. Coghill, supervising engineer, U.S. Bureau of Mines Mississippi Valley Experiment Station, Rolla, Mo.; J. B. Morrow, and R. E. Zimmerman, of the Pittsburgh Coal Co.; and Dean Milnor Roberts and Prof. Joseph Daniels, of the College of Mines, University of Washington.FLOTATION AND DEPRESSIONA substance will tend to float if its surface attracts a gas film more strongly than it does a liquid film when both air and liquid are competing for this attraction. On the other hand, a substance will not float if its surface attracts a liquid film more strongly than it does a gas film. All theories of depression depend upon this fact. A wetted particle of floatable size most likely will be found in the tailings after the flotation process has been completed.The crux of flotation is the selective wetting of the undesirable material that tends to float. Two general methods 5, 6, 7 of depression are in use: One combines a chemical substance with the surface to form a wettable compound, and the other employs some colloidal or ionic substance which the surface selectively adsorbs, thereby forming a wettable surface."

Jan 1, 1935

By M. C. Malamphy

A general description of the activities and results of bauxite investigation by the Bureau of Mines at its bauxite project in Saline and Pulaski Counties, Arkansas has been given in Report of Investigations 4251. The factual data obtained during the project are reported in a series of Reports of Investigation beginning with No. 4251 of which this is the tenth. The data are accompanied by maps showing the location of holes drilled and the deposits developed. Each area upon which work was done is reported by half townships. Each bauxite deposit investigated was assigned a name and a number for ready reference and identification, and its location and name are shown on the appropriate half-township map. The description of each half township is followed by a description of which deposit developed in that half township. The 14 half-township maps and 77 detail maps of the bauxite deposits in this series of reports give the locations and numbers of all the holes drilled on the project except the deep holes drilled to test the geophysical anomalies. The locations of those holes show on figure 13 in volume 1. The descriptions of the deposits developed are followed by complete detailed logs of the drill holes. Many of the widely spaced exploratory holes did not discover bauxite of minable thickness and grade. The pertinent information obtained from the widely spaced exploratory drill holes has been summarized and tabulated. and a table for each half township is given with the discussion covering that area.

Jan 1, 1948

By J. M. Gomes

The Bureau of Mines, as part of an effort to maximize minerals and metals recovery from domestic resources, has investigated the feasibility of recovering heavy minerals as byproducts from sand and gravel, placer gold, and industrial mineral operations in northern California. Sand samples from about 50 locations were treated by gravity separation to yield heavy-mineral concentrates (black sands). Mineral compositions of the concentrates were determined by chemical analysis and mineralogical examination. Individual zircon, ilmenite, magnetite, platinum-group metals, thoria, and silica products were prepared from heavy-mineral concentrates by selective separation using low-and high-intensity magnetic, high-tension, and flotation equipment.

Jan 1, 1979

By R. T. Sorensen

Research and testing in a small scale equivalent of a commercial flota-tion plant was completed on four low-grade, iron-bearing materials from the western Mesabi range. Closed circuit-flotation of calcium-activated silica with fatty acid collector developed data for comparison with the batch process and highlighted problems not evident from previous bench testing. The four ore samples contained from 27 to 39 percent Fe and were equally represented by nonmagnetic taconite and semitaconite type materials. Iron concentrates containing 6.0 percent, or less, SiO2 were made 5, all four samples. Of the two material types, the semitaconite was the ore amenable to treatment, yielding iron recoveries of about 90 percent as cc pared with 70 to 80 percent for the other. Pilot plant tests showed that concentrate grade made in batch tests could be duplicated in the closed circuit and demonstrated that the amount of recoverable middling iron varied considerably between ore samples. The continuous tests also showed that water temperature strongly influenced results in the treatment of one ore but apparently was of indifferent consequence in another. Progress in thickening and filtration of flotation concentrates was made through introduction of tapioca flour to serve the dual role of iron mineral depressant and flocculant.

Jan 1, 1966

By Robert T. Langland

The Bureau of Mines, at its Denver, Colo., research center, has developed a computer program to solve nonlinear regression problems. The program is written in a general form so that, regardless of the functional relationship assumed, the unknown parameters may be evaluated by the Newton-Raphson method of iteration. Variances and covariances of the parameters are derived, based on the propagation of errors. A creep function is established from shale test data as an example of program utility. Program accuracy is compared to the accuracies of other programs in present day use.

Jan 1, 1974

By William J. Campbell

The purpose of this investigation was to develop a rapid, accurate method of analysis for small amounts of calcium in wolframite concentrates. This analysis is necessary to determine if the wolframite concentrates meet United States National Stockpile Specification P-57R2, which limits the calcium content to 0.2 percent. Because of the small depth of the sample analyzed in fluorescent X-ray spectrography, the calcium Kaline intensity was a function of the chemical composition of the calcium-bearing particle as well as the total matrix composition. This particle-composition effect was particularly important in this analysis, as the calcium may be present as a carbonate, tungstate, phosphate, etc. Three methods of preparing the sample eliminated the variation of calcium Ka intensity with mineralogical occurrence: (1) Reduction in particle size by extensive grinding, (2) chemical fusion with sodium carbonate, and (3) solution of the calcium by an acid attack.

Jan 1, 1958

By V. Rajaram, S. Bhattacharya, M. F. Dunn

During a mine fire or other emergency, it may be desirable to reverse the airflow in order to provide an escapeway or to isolate a fire. Also, (in colder areas, the airflow may be reversed to prevent ice buildup. When reversing main mine fans, the mine operator usually does not know what operating characteristics of flow and pressure to expect. Laboratory a field tests of vane axial main mine fans in the 7- to 9-ft diameter size range were conducted to establish forward and reverse performance characteristics under controlled conditions and at typical mine installations. The data obtained suggest that reverse performance characteristics are dependent upon the blade angle and the hub to tip ratio. There is also evidence that reverse performance can be predicted for a family of blade angles and a given hub to tip ratio. Generally, quantity of air is 30% to 65% less in reverse than when operating in the normal forward mode.

Jan 8, 1983

By C. P. Haller, S. J. Aresco

"INTRODUCTION The Bureau of Mines has been active in promoting the purchase of coal for Government use under specifications that define the requirements in terms of heat¬ing value of the coal, expressed in British thermal units, and the composition as shown by proximate analyses. To these, when required, are added the fusing temperature of ash and the free-swelling index. Under most of these specification contracts the bidders guarantee the quality of the coal, and that guaranteed by the successful bidder becomes the standard of his contract. The deliveries are sampled in accordance with instructions./ issued by the Bureau; the samples are analyzed in the Bureau's laboratory to determine whether the coal is of the quality guaranteed by the contractor and, if it is not, a price adjustment is made.Analyses of the delivered coal and ""tipple"" samples (samples collected at mine tipples as coal is being loaded into railroad cars or trucks) provide valuable data for use in evaluating future bids. Moreover, the continuous sampling of coal as delivered is a check on the practical results obtained in burning the coal.The Government purchased approximately 5-1/2 million tons of coal in fiscal year 1951. In connection with these purchases, the Bureau analyzed 10,700 samples. These are published for the use of Government officials and the public. A series of publications s been completed on coal analyses by States, or, where production is small in any State, by groups of adjacent States. In addition to analytical data showing composition and quality of coals of the States, the publications contain brief descriptions of the geological structure of the coal basins, typical mining conditions in the various districts, the principal economic data of the industry, and the relationship of mine or channel samples to delivered and tipple samples. The present publication covers many States but deals only with the analytical data of the coals.The technical papers published by States, with their numbers are: Alabama, 347; Alaska, 682; Arizona, California, Idaho, Nevada, and Oregon, 696; Arkansas, 416; Colorado, 574; Illinois, 641; Indiana, 417; Iowa, 269 and 706; Kansas, 455; Kentucky, 308 and 652; Maryland, 465; Michigan, North Dakota, South Dakota, and Texas, 700; Missouri, 366; Montana, 529; New Mexico, 569; Ohio, 344 (and Bulletin 499); Oklahoma, 411; Pennsylvania Bituminous, 590 (Supplement, 645); Pennsylvania Anthracitic, 659; Tennessee, 356 and 671; Utah, 345; Virginia, 365 and 656; Washington, 491 (Supple¬ment, 618); West Virginia, 405 and 626; and Wyoming, 484."

Feb 1, 1953

By A. L. Engel

In previous reports5/ of ore-testing studies, teats made by established methods on typical ores selected as representative of certain mining districts have been described in considerable detail. In addition to established test procedures, such as screen analysis, Chemical analyses, microscopical examination of ores and products, sink-and-float separation, gravity concentration, floatation, and magnetic separation with or without roasting, it was sometimes necessary to apply other methods, such as leaching, in instances where physical separations were not feasible.

Jan 1, 1940

By Robert F. Chaiken

More than 500 fires are now burning in abandoned coal waste banks and coal deposits in the United States. Once established, such fires can burn for decades, and extinguishing them by conventional methods such as surface sealing to exclude air, excavation to remove fuel, or flushing to cool the fire zone is usually difficult and always expensive. Burnout Control, a technique developed by the Bureau of Mines for the control of abandoned fires, involves the accelerated combustion of coal in place with total management of the heat and fumes produced. A burning waste bank or mine is placed under negative pressure relative to the atmosphere, and heat and combustion products are drawn from the combustion zone through an exhaust ventilation system. Heat produced appears as sensible heat in the exhaust, at temperatures as high as 1,000° C (1,832° F), and can be recovered for the production of steam, hot water, process heat, or electricity. The Bureau's first field demonstration of Burnout Control was at Calamity Hollow in Allegheny County, PA (near Pittsburgh). Calamity Hollow was the site of an underground mine in the 1900's and was surface mined in the 1940's. In the winter of 1961-62, a fire of undetermined origin was discovered in the exposed coal. In 1963, the Bureau constructed a trench barrier around the fire and a surface seal over the affected area. The fire was isolated, but not completely extinguished. In 1979, when the Bureau began work on the Calamity Hollow Mine Fire Project, to demonstrate controlled burnout, the fire was still smoldering on the hot side of the trench barrier. The project, which was begun in December 1979 and ended in July 1982, consisted of the design, construction, operation, and subsequent dismantling of a Burnout Control ventilation system. This report is the fourth in a five-part series that describes the Calamity Hollow Mine Fire Project. The first report, part 1, describes the design and construction of the field installation. Part 2 will present the results of a continuous 4-month burnout operation. (Because part 2 involves the analysis of a substantial body of data, it will not be published until after publication of parts 3, 4, and 5). Part 3 describes the instrumentation used to control and monitor the progress of the burnout operation. This part (part 4) and part 5 both deal with the closeout phase of the field demonstration. The quenching of the fire is described in this report, and part 5 will describe the final excavation and backfilling of the heated zones. The reports in this series document the Calamity Hollow controlled burnout demonstration, which showed that (1) controlled in situ combustion is a feasible method for controlling underground fires in abandoned mines, (2) the resultant thermal exhaust output is sufficient for energy utilization, and (3) water injection with fume exhaustion is a potentially effective method for cooling large underground fire zones. Further trials of both Burnout Control and water injection with fume exhaustion are planned.

Jan 1, 1984

By Russell R. McLellan

The Tertiary channel gravel deposits in northern California were selected Or detailed investigation by the U. S. Bureau of Mines as part of a national program to locate potential sources of gold that might be developed rapidly by large-scale mining operations. Five bureau research centers representing mining and metallurgy subsystems coordinated their efforts in a team operation to identify and investigate possible solutions to the problem area, that long have discouraged the resumption of large-scale mining in the deposits. This report summarizes the individual investigations, conclusions and recommendations conducted and prepared by all mining subsystems research groups after the completion of two years of field work at the deposits on San Juan Ridge in Nevada County, California. The studies indicate that modern mining technology can cope with the environmental problems that closed the immense hydraulic mines in 1,884. however, they also indicate that mining can be conducted with only marginal profits its unless the price of gold remains substantially above $70 per ounce or unless sufficient by-products can be recovered and sold to place the average value per cubic yard of gravel into a positive commercial range. The by-product potential of the Tertiary gravels remains to be investigated in more detail.

Jan 1, 2012

By J. R. Thoenen

This paper outlines briefly results of seismic measurements recorded in the vicinity of quarry blasting under practical operating conditions. The data cover field work done from January to the middle of August 1930, during which time records were made of 61 blasts in 19 quarries. Of the tests made, one was in biotite-gneiss, two in dolomite, two in a flintlike volcanic complex, three in gabbrodiorite, five in trap rock, and six in limestone. One quarry was in Alabama, two were in South Carolina, two in New York, four in Kentucky, five in Connecticut, and five in Massachusetts. Explosive charges ranged from 0.30 pound to 41,900 pounds, and the method of shooting varied from mud caps through hammer and wagon drill holes to churn drill holes and coyote tunnel shots.

Jan 1, 1937

By Arthur L. Murray

"While serving as surgeon with rescue car No 11 of the U. S. Bureau of Mines, the writer visited the principal metal-mining camps of Utah during the latter part of 1919. In visiting the mines, meeting and conversing with miners, and talking over the medical situation with physicians in the various camps, the number of cases of lead poisoning encountered was great enough to attract attention.With a view to procuring more definite information as to the number and distribution of cases of lead poisoning throughout the State, a study of the records of the State Board of Health was undertaken. Utah had no ordinance re¬quiring the reporting of occupational diseases, so it was not possible to secure data an cases A study of the mortality records by years gave the following results.:Year Deaths from lead poisoning.1910,11911,01912,21913,11914,61915,41916,11917,31918,11919,2These few deaths would seem to indicate a fairly low case rate, but when it is realized that lead poisoning is rarely an immediate cause of death and that the train of sequelae in this disease frequently leads to chronic involvemeets of the digestive, nervous, circulatory or genito-urinary systems, it is apparent that the number of deaths showing lead poisoning as the cause can not be taken as an index of the cases prevalent. The time elapsing between the presence of the active signs of lead poisoning and the terminal illness from pathologic conditions excited by lead absorption may be years, and the initial cause, lead poisoning, is frequently lost sight if entirely, hence the death certificate shows no evidence of the primary cause."

Aug 1, 1921

By W. I. Nelson

This paper describing the mining practices at the Engels mine is one of a series being prepared by the United States Bureau of Mines on mining practices, methods, and costs in the various mining districts of the United States. The Engels Copper Mining Co. operates two mines about 3 miles apart in Plumas County. Calif. Both mines send ore to the same mill, and the methods of the larger, or Engels mine, are described in this paper. Between 800 and 1,000 tons of 1-3/4 to 2-1/2 per cent copper ore are mined daily from this mine by a shrinkage method. Connection is made with the Western Pacific Railroad at Paxton by the Indian Valley Railroad, which is 22 miles long and operates a daily mixed train to the mine.

Jan 1, 1930