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By R. Roufail

In this paper, the effect of different operating parameters of high speed stirred mill on the particle breakage mode is addressed. Morphological features of broken particles is investigated and related to the types of forces generated in the mill using Discrete Element Method (DEM). The stress intensities generated in the mill are varied by changing the agitator speed. The investigated agitator speeds were 1000, 1500, and 2000 revolution per minute (rpm). The minerals considered in this study are hard minerals (quartz) and soft, sulphide minerals (galena). The morphological features examined are roughness, roundness and elongation, which shed light on the mode of breakage during the grinding process. Particles that are rough, less round and elongated would imply that they broke via fracture, along their grain boundaries. On the other hand, the smooth, less elongated particles would mean breakage occurred across the grain, which is abrasion mod. DEM study complemented the understanding of particle breakage mechanism via tracking the types of forces applied on the particles. Normal forces imply compressive loading, which is presumed to impose fracture breakage along the grain boundaries, whereas tangential forces imply abrasion loading. Stirred mill grinding has been regarded as an attrition/abrasion process, whereas, this study showed that about 60% of total particles that are morphologically analyzed for both minerals were rough particles. Such an observation indicates that the fine product, which contain a significant amount of progeny from the coarse fractions are consistently broken via fracture. The morphology results agreed with the DEM findings, which indicated that the agitator speed, mineral type, and residence time would dictate the type and mode of particle breakage. Keywords: DEM, high speed stirred mill

Sep 1, 2012

By M. N. Abdusalyamova

The Republic of Tajikistan has large mercury-antimony deposit. The Republic takes the second place in the countries of the CIS by having antimony recourses or the fourth place in the world. Recently, on the mine bottom horizons the resources of gold were found. Gold in the data ore is submitted as nanosize particles. Results of ores enrichment of bottom horizons of Djijikrut deposit are obtained by a method of flotation. The flow sheet includes the rougher flotation, two scavenging flotation and two cleaner flotation. As a result of enrichment of ore, the mercury-antimony concentrate with the contents of 51.5% of antimony and recovery 90.3% from ore with the content of mercury of 3.5% was received. The investigation of thallium, selenium, and tellurium distributions on products of enrichment was carried out. The most effective reagents are a mixture of oksafore and butyl xanthogenate. While applying this mixture of reagents it is possible to refuse of the use of activator - nitrate lead. The behavior of gold is in details investigated during enrichment. To collective flotation concentrate is extracted only 30% of gold. The basic quantity of gold concentrates in tailings of flotation and is not taken by existing traditional methods. The alternative innovative technology of gold extraction was created. Various methods of roasting of a collective mercury - antimony concentrate oxidizing and reducing are investigated. Vacuum distillation of concentrate allocation in serial sublimates mercury and antimony was designed. In the received calcine concentrates gold. At additional roasting of a calcine up to 900°? concentration of gold makes 30.6 g/t. The offered innovational technology in a complex allows to process ores and concentrates unique mercury-antimony?gold bearing raw material. Keywords: ore, concentrate, flotation, cyanidation, roasting, mercury, antimony, gold

Sep 1, 2012

By S. A. Bogidaev, M. Yu. Tiunov

"The paper describes the results of the flotation tests with complex rare metal ores from deposits in the Trans-Baikal Territory. Correlations between the quality of produced wolframite, hubnerite and mica concentrates with or without the presence of various alkaline modifiers are determined. Commonly, rare metal ores contain minerals of comparable value to main elements recovered in processing plants using gravitational methods. The paper describes the results of flotation recovery of valuable minerals – main and associated – from gravity tailings of deposits in the Trans-Baikal Territory. It was found that gravity tailings from the first deposit contained fine-grained wolframite, mica (muscovite, lepidolite etc.), feldspar; hubnerite, scheelite, beryl, fluorite, rubidium-containing muscovite from the second deposit, correspondingly. This paper presents the results of the stage flotation tests with the production of tungsten (wolframite, hubnerite), fluorite and mica concentrates from gravity tailings. Figure 1 demonstrates the flowsheet of tungsten ore minerals and mica stage flotation from gravity tailings of the first deposit.Wolframite can be floated using oleic acid with the presence of soda ash, a complexing collector (IM-50), under slightly alkaline conditions in combination with a nonpolar collector [1, 2, 3, 4]. The study included wolframite flotation using the combination of two alkaline modifiers. Flotation of wolframite was performed after pulp desliming, using tall oil saponified with soda ash. The recovery of wolframite in the concentrate of rougher flotation reached 80-85%; the concentrate contained up to 1% of tungsten oxide that can be upgraded to a saleable product using gravitational methods. This procedure was tested during flotation of wolframite, tantalite-columbite and pyrochlore, and provided high performance regardless of a season, at pulp temperatures of 8-10°C, though fattyacid collectors are significantly inefficient at such low temperatures due to low solubility, dispersion and increased collector consumption, consequently. The introduction of two alkaline modifiers in pulp appears to improve these characteristics.The first stage of the tests was focused on increase of iron-bearing tungsten ore minerals recovery from gravity tailings and stabilization of the cold pulp flotation process."

Jan 1, 2018

By N. Jovanovic, A. Vazirizadeh

"The main objective of this study is to find a solution to design a mass flow observer system with the minimum required sensors and maximum observability for a mineral processing plant. The second objective is designing a mass flow observer configuration with high reliability to manage sensor failures. This configuration will provide a robust monitoring system that increases plant availability and process measurement fault detection. Furthermore, the monitoring system is expected to improve process efficiency. In this investigation, the procedure of designing an observer system is presented along with three models to design the sensor network. The advantages and disadvantages of each models are discussed and finally the models result for an industrial case are presented and analyzed. INTRODUCTION The concepts of observability and redundancy of mass flow are directly linked with the ability to solve and estimate the mass flow. There are hundreds of streams in a process plant flowsheet, and for technical and economic reasons it is not possible to measure all mass flows. It is thus important to know for a set of measured streams, which of the unmeasured streams can be estimated. The concept of observability deals with this issue. It is also valuable to know whether a measured mass flow of streams can be estimated even if a sensor fails for some reason. Redundancy deals with this failure question. A stream is said to be observable if it can be estimated by using the measurements and/ or mass conservation equations. Also, a stream is redundant if it is observable even when its measurement is removed. Observability and redundancy analysis can be exploited for adding new measuring instruments. It can also play a useful role in efficient decomposition and data reconciliation problem (Narasimhan and Jordache 1999). The value of an observer system cannot be justified without considering its benefits. This justification is done through evaluation of data reconciliation, gross error detection and improving process performance such as outlined below:"

Jan 1, 2018

"The effect of operational conditions, such as air flow rate, impeller speed and solid concentration, as well as the effect of solids concentration and frother dosage, on the bubble size distribution produced in a lab scale flotation cell, were investigated. The cell was operated under batch conditions. The measurement of bubble size was accomplished using an automated photographic technique. The technique enabled fine and coarse bubble distributions to be measured in two-phase (liquid-gas) and three-phase systems (solid-liquid-gas). In each experiment, around ten thousand bubbles were characterized.This paper discusses the main results obtained using the new photographic technique and compares these with previous findings available in the literature. The results indicate that photographic techniques combined with digital imaging processing might become a standard technique for measuring bubble size distribution in flotation machines.HUT BUBBLE SIZE ANALYSERThe importance of having precise and reliable equipment for measuring bubble size distribution in industrial flotation machines has been widely recognized. The measurement of bubble size, particularly in three-phase systems, is rather complex due to the opaque nature of the pulp. However photographic techniques combined with ingenious sampling techniques are utilized for overcoming this difficulty. The technique named HUT, combines previously developed visualization methods with digital image processing procedures. In this technique bubbles and aggregates are exposed to a monochrome progressive scan camera. The acquired images are directly stored in a computer connected to the camera for post-processing. The sampling apparatus consists essentially of a vertical tube for collecting bubbles, a viewing chamber and a collection chamber, where particles carried by the bubbles are released. The function of the collection chamber is to maintain the viewing chamber clear for imaging purposes. Each image is automatically processed off-line, using digital image tools. In this paper the advantages and limitations of this new technique are described."

Jan 1, 2003

By Ming’an Wei, Chuanyao Sun, Yangge Zhu, Fayu He, Yanbo Shang, Xingrong Zhang

In order to discuss the separation mechanism of copper-molybdenum ore, surface electronic structures of chalcopyrite and molybdenite were studied in the paper, by using First Principles method of quantum chemistry. So, the separation mechanism of thioglycolic acid (TGA) with chalcopyrite and molybdenite was revealed better. The results showed that differences of the electronic structure of chalcopyrite and molybdenite could directly affect their interactions with TGA, such as band structure, density of states, Mulliken populations, and so on. And the frontier orbitals of chalcopyrite and molybdenite were also calculated by Dmol3 after the optimization by CASTEP, from which the interaction energies between minerals and TGA were obtained and compared. So, the essence of flotation separation of copper and molybdenum were well revealed.

Jan 1, 2014

By B. Z. Wu

The flotation of low-grade zinc oxide ore which from Guizhou has been researched by sulfuration- amine method. The experimental result indicated that when pH of pulp was 11, good flotation index can be achieved by using sodium silicate as dispersant, mixed amine as collector, and the do-sage of sulfur sodium was 6kg/t, and the recovery of zinc can be heightened by using copper sulfate as activator and Hydroxamicacid as collector. When the zinc feed grade was 4.84%, the zinc concentrates with grade of 39.23 % and recoveries of 75.17 % were obtained by adopting this technics.

Jan 1, 2014

By Knut L. Sandvik, Erik Larsen

Crystalline silicon solar cells are the most important solar cells manufactured today. This will most probably remain the situation the next decade. The future silicon feedstock is most likely not reject from the production of electronic-grade silicon. There will probably be a more direct solar-grade silicon route, excluding the electronic-grade silicon "detour". Estimated global solar energy demand in 2001 required approximately 5,500 tons of silicon feedstock. This required 65,000 tons of quartz. If the trend continues, the solar energy demand in 2010 would require approximately 30,000 tons of silicon feedstock and 350,000 tons of quartz, although the need for quartz probably will be lower than this. Quartzite has been regarded as the most suitable primary raw material used in the silicon solar cell production chain. This may change as the raw material requirements for the production of metallurgical-grade silicon are most likely to change. In addition, quartz or other silica-containing minerals from other rocks may be of a higher purity or contain lesser amounts of the most harmful elements. This favours increased beneficiation of primary raw materials in the future solar silicon feedstock production chain.

Jan 1, 2003

By B. McFadzean

Thiol collector mixtures are commonly used in the flotation of base metal sulfides and platinum-bearing ores. There are synergistic benefits claimed for these collector mixtures, with mixtures lowering total dosage requirements, improving coarse particle recovery and the rate of flotation. Some of the secondary collectors are known to have frothing effects. Therefore, a previous study aimed to decouple froth and pulp effects and considered only the bubble-particle attachments in the pulp. This was achieved through microflotation experiments, where various ratios of the ethyl and isobutyl chain lengths of xanthates, dithiocarbamates and dithiophosphates were used as collectors. Results from these experiments showed a marked increase in galena recovery using mixtures of xanthate with either dithiophosphate or dithiocarbamate. In the current study, the froth phase was introduced in the form of batch flotation studies to determine whether benefits noted during microflotation experiments would be carried through to a more realistic froth flotation scenario. The findings show that there was no significant difference in the flotation recovery between the best single collectors and mixtures of these collectors. In addition, single collectors that behaved poorly in microflotation experiments showed good flotation performance in the batch flotation experiments. The differences between the microflotation results and the batch flotation results are attributed to differences in particle froth stabilizing properties and/or differences in energy input between the microflotation and batch flotation cells. In addition, galena and pyrite showed marked differences in frothing effects and in their preferences for collector type. Keywords: froth flotation, collector mixtures, sulphide minerals

Sep 1, 2012

By Xubo Chen, Zhiqiang Hu, Zhijian Sun, Gaoyun Zhou

"The research aimed at developing an efficient and environmental frother,which was applied in the flotation of sulfide ores. The flotation properties of an efficient frother and pine oil have been studied relatively by flotation tests of lead and zinc sulfide ores. At the same time, the biodegradability of two kinds of frother has been studied by the method of biological respiratory curve. The test results show that the flotation properties of new frother are superior to pine oil such as flotation rate, dosage etc. and its biodegradability is superior to pine oil. INTRODUCTION Frother is a kind of important agent in flotation reagents.In practice, the criterion of the foaming performance of the frother is what is high and low according to flotation indexes. The difference of different minerals and flotation technologies has great influence on the foaming performance of frother, and it is very important to choose the corresponding frother. The type, dosage and selectivity of frother in flotation process must be considered carefully. In today's society, environmental protection and ecological protection are becoming more and more important, and the environmental and ecological damage from mine development has aroused increasingly more attention. The use of mine agents has promoted the development of mineral resources, greatly improves the recovering utilization of mineral resources, at the same time, the production and use of mine reagents also inevitably bring about pollution, and result some influence or damage in the ecological environment.The frother is a common kind of reagent in the flotation process of the concentrator. In many cases, the waste water in the concentrator can not be let out in the natural water because the higher content of the frother in the waste water results in higher index of COD.This will inevitably increase the cost of waste water treatment in the mine.Therefore, the choice of frother should not only consider its influence on the flotation index, but also consider its influence on environmental protection. Waste water treatment is a way to solve the waste water pollution, but it needs to cost a lot of fund, manpower and material resources.And the development of high efficiency pollution-free reagent is a good way to reduce the production cost of mining enterprises and reduce the environmental pollution."

Jan 1, 2018

By M. Zolghadri

MIBC and sodium metasilicate are used as a frother and a dispersant in coal flotation respectively. In order to study interaction between them, flotation experiments were performed on fine coal (<150 microns). It was found that if the frother (MIBC) dosage is in excess of a certain limit, it has an activation effect on the gangue minerals associated with coal. In addition, it was found that however sodium metasilicate can disperse clay slimes eliminating slime coating, but in the case of excess dosage, could intensify activation effect of MIBC, which is undesirable in coal flotation. Keywords: coal flotation, sodium silicate, frother, dispersion, activation

Sep 1, 2012

By Y. Nahmad- Molinari

We present a novel on line inductive sensor for the determination of the quality of the concentrates of iron ores. This device is coupled with a cheap USB Data Acquisition System that makes it versatile enough to simultaneously control up to seven fluxes at a very low cost (< $300 US dollars), and achieves a resolution better than 0.5 % on the determination of the magnetic iron content in the concentrate. A RLC circuit with its inductive element placed surrounding a sample of pure magnetite concentrate is tuned at its resonance frequency, by means of adjusting, the feeding voltage of a voltage-controlled oscillator (VCO) and several samples with mixtures of different contents of silica and magnetite are placed in order to get a calibration curve. After some signal conditioning, a National Instruments USB-DAQ NI-6008, acquires the amplitude of the signal via USB port on a PC using a Lab-View program designed for such purpose, in which the calibration curve is used for on-screen data presentation directly in percent of magnetite content. The implementation of this device for control purposes on line directly placed on the concentrators would allow better efficiency of the process and higher quality of the final concentrate by con-trolling; the rotation speed, the rising or dilution water fluxes or bypasses towards milling recirculation cycles.

Jan 1, 2014

By F. Ngoroma

Concentrators processing PGM bearing ores make use of polysaccharide depressants to reduce the recovery of the undesired naturally floatable gangue minerals, mainly silicates, present in the ore. Recent work has shown that high depressant dosages can completely depress naturally floatable gangue and thus prevent it from reporting to the concentrate. These high depressant dosages can, however, have a negative effect on the recovery of valuable minerals present in the ore by reducing the stability of the froth. In order to counterbalance the effects of depressant addition, frothers are added. It is, however, preferable to maintain independent control over bubble size and froth stability which is difficult to achieve with only one frother. An alternative strategy is, to use a blend of frothers, e.g. a weaker frother in combination with a stronger frother. Such a system allows an additional degree of freedom: changing the ratio of the two frothers, that would provide more independent control of bubble size and froth stability. This study demonstrates, through the use of batch flotation tests, how blending low molecular weight alcohols with commercially available frothers impact the solids and water recovery, as well as the valuable mineral recovery and concentrate grade in different PGM ores. Higher water and solids recoveries together with higher valuable mineral recoveries (>90% copper and >70% nickel) were obtained from tests using frother blends.

Sep 1, 2012

By D. DePaoli, P. Zhang

"Phosphate ore is one of the most significant secondary resources for rare earth elements (REEs), and Florida phosphate is of particular interest due to its much higher ratio of heavy REEs, especially yttrium. Analyses of numerous samples from different phosphate processing streams in Florida showed that heavy REEs account for about 50% of the total REEs in Florida phosphate with yttrium accounting for approximately 30%. It was estimated that the amount of yttrium from US phosphate processing could meet the world demand for this critical element. This research aimed at recovering both REEs and phosphorus from a phosphate flotation tails. This tails is composed of mainly silica and phosphate with a small fraction of heavy minerals including monazite and xenotime. Since the specific gravity of silica is 2.6 versus 3.2 for phosphate and 4.5-5 for rare earth minerals, pre-concentration of the minerals of interest by gravity separation was investigated first. A pilot scale shaking table was used in this study. One pass gravity concentration achieved a shaking table concentrate analyzing over 600 ppm REEs at about 40% recovery. Flotation of the shaking table concentrate resulted in a product containing 1809 ppm REEs and 26.37% P2O5 with corresponding recoveries of 73% and 82%. Sulfuric acid leaching at 75oC could recover over 60% REE and nearly all the P2O5. Higher REEs (>90%) recovery was achieved by conducting leaching at higher temperature with concentrated sulfuric acid. The phosphoric acid from leaching of the flotation concentrate is of superior quality compared with that generated from regular phosphate rock.INTRODUCTION Rare earths are a group of 17 elements including those of the lanthanum series, as well as the non-lanthanides, yttrium and scandium. These elements have very specific critical uses in a multitude of markets. For example, lanthanum is used as a catalyst in breaking down crude oil to produce gasoline, diesel and jet fuel and neodymium is the core magnetic component in high-strength magnets for electric car batteries, wind turbines and hard disk drives. Rare earths are also essential for many military applications. Many of these applications have no substitute materials and the move to green technologies has dramatically increased their demand."

Jan 1, 2018

By Markus A. Reuter, Bernardete Castro, Antoinette van Schaik, Han Remmerswaal

This paper describes the inseparable relation between product design, liberation, and metallurgical recovery in the optimisation of the recycling of passenger vehicles. This is illustrated by the use of an optimisation model that uses among others a material combination matrix based on metallurgical process data, which depicts the consequences of the quality of intermediate recycling products on the metallurgical material recovery and final alloy metal quality. Various simulations will illustrate the effect of changes in product design and hence liberation on the recycling of end-of-life vehicles. Although this paper focuses on cars, the discussion is equally valid for any end-of-life product. Calibration of the model will be discussed with reference to experiments carried out in order to study the optimal recovery of aluminium applications used in passenger vehicles.

Jan 1, 2003

By M. Ito

The authors have developed the RETAC jig (a modified TACUB jig) and have reported that the RETAC jig can separate relatively low density particles such as plastics. To further improve the separation ability, a hybrid jig (a RETAC jig with an air bubbler under the particle bed), which can separate plastics having similar specific gravities by the differences in the wettabilities of the particles was developed. Surface modification of plastics with similar wettability enabling separation in the hybrid jig and the effects of wettability control of the plastics using reagents are reported.

Sep 1, 2012

By H. Z. Liu

An extra-refractory gold ore in China belongs to Carlin Type Gold Ore which is not only submicroscopic but also rich in arsenic and organic carbon. They have been proved that its floatability is not good enough and the gold in the ore could not be leached almost if it was not pretreated. The tests for the ore were carried out in accordance with flotation-concentrate preoxidation-cyanidation(or CIL) processes in order to exploit the mine. Two new depressants were discovered in the flotation tests and improved concentrate grades from about 20g/t to 32~50g/t. The methods of the concentrate preoxidation tests were alkaline atmospheric oxidation, acidic atmospheric oxidation, acidic pressure oxidation, roasting oxidation?biooxidation. The cyanidation tests after the concentrate preoxidation have proved the gold extraction of the pressure oxidation to be the highest(92.5%) and that of roasting secondary(89.3%). After fuller techno-economic comparison, it is suggested that the flotation-pressure oxidation or roasting-CIL process should be the most optimal for treating the ore. The gold recoveries of the ore were 83% for the pressure oxidation and 80% for the roasting respectively.

Jan 1, 2014

By Alexsandro Berger

Many thickener operations continue to be constrained by their ability to process consolidated underflows with high yield stress and associated rheological characteristics. To maximise separation efficiencies within a thickener operation the use of both engineering and reagents are always considered. BASF is developing a Novel Flocculant Technology (NFT), which combines both of these aspects to enhance the performance of the thickener operation, improving the areas of pumping efficiency, underflow density and throughput. The development progression through stages of laboratory scale batch test work to pilot scale dynamic testing has demonstrated the ability of BASF NFT to maintain effective flocculation performance whilst increasing the rate of underflow consolidation, and significantly reducing the associated underflow yield stress of the treated material. This paper will present application data through full scale dynamic testing conducted on a granite washing circuit to demonstrate the performance benefits that NFT offers to a thickener operation. Compared to the conventional flocculant treatment, within the operation parameters and conditions employed during the full scale trials, the NFT produced a reduction in underflow rheology (yield stress) of around 45 % relative to a given solids and improved the underflow consolidation by providing at least 20% relative higher underflow solids loading than the upper limit of the given typical thickener operation. Keywords: flocculation, thickener operation, rheology, yield stress, underflow density, throughput, slump test

Sep 1, 2012

By J. Roth

The increasing demand of the filler industry regarding fineness and better delaminated products led to the development of a series of different grinding machines, which differentiate basically by the grinding mechanism as well as the kind of classification. Spiral jetmills grind, as it is well known preferably by delamination, therefore a spiral jetmill with integrated dynamic classifier has been developed. Especially the enhancement of the functional properties of the used industrial mineral fillers is a factor of highly increasing importance. These properties are very often bound to the platy shape of the minerals expressed by the aspect ratio. The developed Spiral Jetmill shows sufficient ability for such delamination and therefore increases in aspect ratio. In a series of comparative tests the suitability and advantages of this system regarding achievable fineness down to the submicron range as well as the conservation or even improvement of the aspect ratio of different minerals has been studied. As an emphasis on the results application tests with certain materials in the plastics field have been conducted. Due to the fact that in this range the required specific energy for achieving the necessary fineness increases exponentially another target is to optimize the grinding efficiency. A special feed control system provides on one hand a sufficient load inside the mill to obtain maximum utilization of the applied energy and on the other hand to prevent the mill from overfilling and coming with this a poor classification. The integrated classifier is a combination of a high speed motor with directly attached classifier wheels. This unit on one hand grants the necessary high circumferential speed of up to 190 m/s for providing an exact top cut of the ultrafine products and on the other hand gives the required operational reliability for continuous operation. Hard grindable impurities, which enrich inside the mill chamber, can be rejected from the process leading to an even cleaner product. Comparative tests on a talc product with certain free quartz impurities showed a significant improvement of the final product with respectively low loss on rejected material. This effect again had a beneficiary impact on the suitability of the final product when used in plastics application.

Jan 1, 2014

By Jacek Kolacz

A new sensor based sorting system has been developed, based on complex image analysis, where an image texture and a shape pattern is considered for identifying particles for separation. The sorting system employs different images generated by visual light and X-ray to provide maximal information about processed particles. Application of X-ray makes it possible to analyse the internal structure of the particles, which provides a 2D image with complicated texture, however, which contains valuable information. The advanced system for the texture and the pattern recognition is applied to analyse these images simultaneously, to provide the required identification of the particles for efficient separation. The mathematical models applied during identification and separation, are assisted by high speed calculations being specially optimised for this kind of process. This allows sorting with high capacity and high accuracy, which is critical for practical applications in mineral processing. The paper describes a number of tests during sorting of iron ore and coal with high separation efficiency.

Jan 1, 2014